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School of Civil and Environmental Engineering, Faculty of Environmental Sciences; Institute for waste management and circular economy
Biological waste treatment /
Biogas from waste
2
TABLE OF CONTENTS
• Renewable Energy in Germany
• Biomass and Substrates for biogas production
• Demands on biogas plants
• Examples
SUSTAINABLE ERNERGY PRODUCTION
RENERWABLE ENERGY IN GERMANY 2014
reference: http://www.erneuerbare-energien.de/inhalt/39831/42038/
Waste-to-Energy in the city of
tomorrow 4
WHY BIOGAS PRODUCTION?
Avoidance of emissions
Waste Treatment
Production of Renewable Energy
Safe of fertilizers for
agricultural production
Waste-to-Energy in the city of
tomorrow 5
NUMBER OF BIOGAS PLANTS IN
GERMANY
reference: Biogas Basisdaten Deutschland, FNR, 2015
Electric
capacity
(installed
[MW]
Number
of
biogasplants
Waste-to-Energy in the city of
tomorrow 6
BIOMASS
• Manure
• Green waste like grass, leaves, branches
• Biowaste
• Sewage sludge
• Industrial sludge
• Energy crops
POSSIBLE OPPORTUNITIES OF USAGE OF BIOMASS
biomass
Sampling, Transport, Mechanical Treatment
Thermal-chemical physical-chemical biochemical conversion
conversion conversion
carbonazation
gasification
liquefaction
pressing/
extraction
Alcoholic digestion
Anaerobic
degradation
Aerobic degradation
Solid fuel liquid fuel gaseous fuel
Solid
fuel
Additional use of energetic potencial of biological rediues
and Renewables and subsequent utilization
reference: Kaltschmitt, Reinhardt, 1997 (moved)
SUBSTRATES
Sewage
sludges
landfillig
Energy
plats
Waste
water
Industrial
residues
Municipal
residues
Agrycultural
remnants
Biogas-
produc-
tion
• Industrial high
polluted waste
water
• Sewage
sludge
• Industrial
sludges
• Household
waste
• Industrial
waste
• Renewables
• leftovers
• Superimposed and taken
back food
• Marked residues
• Production remnants
(e.g. beer-, sugar-,
wine-, milk-, fruit-,
vergaetableprocessing,
biodiesel- / Ethanol-
production)
• Separated biowaste
• Loopings
• Landscape conservation
• Residual waste
• manure
• agryculture
• plants
DISTRIBUTION OF SUBSTRATES FOR
BIOGASPRODUCTION IN GERMANY
Industrial
remnants
6%
municipal
remnants
9%
landfill
6%
Agricultural
remnants
39%
Sewage sludge
7%
Waste water
3%
Energy plants
30%
• main importance:
agrycultural subsrates
industrial municipal substrates
• different qualities Eigenschaften are responsible for different technical requirements
TYPES OF ORGANIC WASTE AND OTHER
SUBSTRATE FOR BIOGASPLANTS
0
1000
2000
3000
4000
5000
6000
7000
8000
Liquid
manure
Residual
waste
Waste
food
Biowaste
Clarification
sludge
Waste
from
processing
Fruit
and
vegetables
Organic
waste
from
from
parks
and
gardens
Marc
and
preclarifiied
effluent
from
wine
manufacture
pot.
biogas
yield
[mio.
m³/
a]
Biogas potential
of organic waste
(approx. 4,300 MWel.)
Reference: Wittmaier, 2010
BIOGAS COMPOSITION
Concentration (Vol-%)
Methane CH4 50 - 75
Carbon dioxide CO2 25 - 45
Water H2O 2 – 7 (20…40°C)
Nitrogen N2 < 2
Oxygen O2 < 2
Hydrogen Sulphide H2S < 1 (500 – 20.000 ppm)
Hydrogen H2 < 1
ENERGY FROM BIOGAS – DATA BASE
1 m³ Biogas 5.0 – 7.5 kWhsum
1 m³ Biogas 1.5 – 3 kWhel
1 BAU 6.6 – 35 t manure/a
1 BAU up to 250 m³ methane/a
Gas power station degreeel 30 – 40 %
Gas power station degreeth 40 – 60 %
Gas power station degreesum ca. 85 %
reference: Biogas Basisdaten Deutschland, FNR, 2008
ENERGY FROM BIOGAS – DATA BASE
For the production of 1 MW of electricity there is a demand on:
• about 16,000 t/a Maize silage is grown of about 400 ha farm land
Or:
• about 16,000 t/a Biowaste
1,0 MW of electricity can be used for:
• up to 2000 families (in Germany) for electricity and
• 1000 families for heating
every ha farm land
• can produce more than 20,000 kWh electricity by the use of biogasplants or
• five Families can be provided with electricity one year
reference: Friedmann and Zellmann, 2006
USE OF BIOGAS
Incineration of
Biogas in gas power
stations (BHKW)
Additional outcome
in the gas power
station (BHKW)
Biogas from 1 ha
Maize silage: natural
gas-car goes about
70,000 Kilometres
(double length of the
equator)
About 10 perecent
of the german use
of natural gas are
replacable by
biogas (usable
Potencal)
Biogas
electricity heat diesel gasnet
Biogas is nessesary for mobility and for production of energy
Reference: Biogas Fachverband, 2010
about 4,700 BGP About 33 BGP
about 2 BGP
USE OF DIGESTER OUTPUT
Biogas plant Separation
composting
Ultrafiltration /
Reverse osmosis
Nutrient solution
(fertilizer)
drying
(pelletizing )
Products
(fertilizer, soil)
Org. fertilizer
Output solid
Output liquid
reference: Wilken, 2010
USE OF BIOGAS FOR ELECTRICITY AND HEAT
Heat
electricity
Fuel
(fuel cell)
Treatment
Reduction of
H2S, CO2 and H2
Net for
Natural gas
USE OF BIOGAS FOR THE GASNET OR AS FUEL
DEMAND ON USE
Amount /
grow /
harvest
Biogas-
production
storage
Transport
transport
of
digested
sludge
storage
output
production
of heat and
electricity
heat
elec-
tricity
Pre-treatment
Transport
to the
gasnet
production
of heat and
electricity
heat
elec-
tricity
fuel
Demand on logistics
Demand on physically
qualities
Demand on biochemical
qualities
Legal demands / restrictions
Demand on use of
digested sludge
reference: Scholwin, DBFZ Leipzig, 2006
DEMAND ON LOGISTICS - AVAILABILITY OF
SUBSTRATES
 Collection of biowaste in the municipalities
 Amounts of manure, other agricultural waste and energy crops
 Biogasproduction is an continouesly process! – Possibility of
sorage of substrates
 Avoidance of emissions and losses during intermediate storage
 keep Temperatures low to avoid biological activity
control of biomass-quality
DEMAND ON PHYSICAL PROPERTIES
 Area for growing for microorganisms (TS, solid state)
 Temperature – homogeneously distribution in the fermenter
 Water content
 Viscosity
DEMAND ON PHYSICAL PROPERTIES –
PROCESS GUIDING OF BIOGAS FERMENTATION
Mesophilic
30 – 37°C
thermophilic
50 – 55°C
dry fermentation
18 – 40 % TS
wet fermentation
5 – 18 % TS
dry fermentation
18 – 40 % TS
One step One step two steps One step
Classification of operation methods
DEMAND ON BIOCHEMICAL QUALITIES –
FLOW CHART OF THE ANAEROBIC FERMENTATION
biomass
polysacharides
proteins
fats
sugar
amiono acids
fatty acids
carboxylic
acid
alcohol
acetat
biogas
CH4/CO2
H2/CO2
hydrolysis phase acidogenic phase methanogenic phase
Hydrolysis digestion acetat production
Macro-molecules intermediate products methan production
hydrolytic fermentative acetogenic methanogenic
microorganisms microorganisms microorganisms microorganisms
DEMAND ON BIOCHEMICAL QUALITIES
 Conditions for the single microorganisms
 Choise of substrates (Mono / Co-fermentation)
 Pre-treatment of substrates
 Concentration of nutrients and trace elements
 pH-value
 Inhibition substances
DEMANDS OF THE USE OF DIGESTED SLUDGE
Use as fertilizer and soil
 Supply of nutrients
 Load on heavy metals and
organics
 Demand on area
Rerence: Budewig, 2010
Biogas_fom_waste.pdf

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Biogas_fom_waste.pdf

  • 1. School of Civil and Environmental Engineering, Faculty of Environmental Sciences; Institute for waste management and circular economy Biological waste treatment / Biogas from waste
  • 2. 2 TABLE OF CONTENTS • Renewable Energy in Germany • Biomass and Substrates for biogas production • Demands on biogas plants • Examples
  • 3. SUSTAINABLE ERNERGY PRODUCTION RENERWABLE ENERGY IN GERMANY 2014 reference: http://www.erneuerbare-energien.de/inhalt/39831/42038/
  • 4. Waste-to-Energy in the city of tomorrow 4 WHY BIOGAS PRODUCTION? Avoidance of emissions Waste Treatment Production of Renewable Energy Safe of fertilizers for agricultural production
  • 5. Waste-to-Energy in the city of tomorrow 5 NUMBER OF BIOGAS PLANTS IN GERMANY reference: Biogas Basisdaten Deutschland, FNR, 2015 Electric capacity (installed [MW] Number of biogasplants
  • 6. Waste-to-Energy in the city of tomorrow 6 BIOMASS • Manure • Green waste like grass, leaves, branches • Biowaste • Sewage sludge • Industrial sludge • Energy crops
  • 7. POSSIBLE OPPORTUNITIES OF USAGE OF BIOMASS biomass Sampling, Transport, Mechanical Treatment Thermal-chemical physical-chemical biochemical conversion conversion conversion carbonazation gasification liquefaction pressing/ extraction Alcoholic digestion Anaerobic degradation Aerobic degradation Solid fuel liquid fuel gaseous fuel Solid fuel Additional use of energetic potencial of biological rediues and Renewables and subsequent utilization reference: Kaltschmitt, Reinhardt, 1997 (moved)
  • 8. SUBSTRATES Sewage sludges landfillig Energy plats Waste water Industrial residues Municipal residues Agrycultural remnants Biogas- produc- tion • Industrial high polluted waste water • Sewage sludge • Industrial sludges • Household waste • Industrial waste • Renewables • leftovers • Superimposed and taken back food • Marked residues • Production remnants (e.g. beer-, sugar-, wine-, milk-, fruit-, vergaetableprocessing, biodiesel- / Ethanol- production) • Separated biowaste • Loopings • Landscape conservation • Residual waste • manure • agryculture • plants
  • 9. DISTRIBUTION OF SUBSTRATES FOR BIOGASPRODUCTION IN GERMANY Industrial remnants 6% municipal remnants 9% landfill 6% Agricultural remnants 39% Sewage sludge 7% Waste water 3% Energy plants 30% • main importance: agrycultural subsrates industrial municipal substrates • different qualities Eigenschaften are responsible for different technical requirements
  • 10. TYPES OF ORGANIC WASTE AND OTHER SUBSTRATE FOR BIOGASPLANTS 0 1000 2000 3000 4000 5000 6000 7000 8000 Liquid manure Residual waste Waste food Biowaste Clarification sludge Waste from processing Fruit and vegetables Organic waste from from parks and gardens Marc and preclarifiied effluent from wine manufacture pot. biogas yield [mio. m³/ a] Biogas potential of organic waste (approx. 4,300 MWel.) Reference: Wittmaier, 2010
  • 11. BIOGAS COMPOSITION Concentration (Vol-%) Methane CH4 50 - 75 Carbon dioxide CO2 25 - 45 Water H2O 2 – 7 (20…40°C) Nitrogen N2 < 2 Oxygen O2 < 2 Hydrogen Sulphide H2S < 1 (500 – 20.000 ppm) Hydrogen H2 < 1
  • 12. ENERGY FROM BIOGAS – DATA BASE 1 m³ Biogas 5.0 – 7.5 kWhsum 1 m³ Biogas 1.5 – 3 kWhel 1 BAU 6.6 – 35 t manure/a 1 BAU up to 250 m³ methane/a Gas power station degreeel 30 – 40 % Gas power station degreeth 40 – 60 % Gas power station degreesum ca. 85 % reference: Biogas Basisdaten Deutschland, FNR, 2008
  • 13. ENERGY FROM BIOGAS – DATA BASE For the production of 1 MW of electricity there is a demand on: • about 16,000 t/a Maize silage is grown of about 400 ha farm land Or: • about 16,000 t/a Biowaste 1,0 MW of electricity can be used for: • up to 2000 families (in Germany) for electricity and • 1000 families for heating every ha farm land • can produce more than 20,000 kWh electricity by the use of biogasplants or • five Families can be provided with electricity one year reference: Friedmann and Zellmann, 2006
  • 14. USE OF BIOGAS Incineration of Biogas in gas power stations (BHKW) Additional outcome in the gas power station (BHKW) Biogas from 1 ha Maize silage: natural gas-car goes about 70,000 Kilometres (double length of the equator) About 10 perecent of the german use of natural gas are replacable by biogas (usable Potencal) Biogas electricity heat diesel gasnet Biogas is nessesary for mobility and for production of energy Reference: Biogas Fachverband, 2010 about 4,700 BGP About 33 BGP about 2 BGP
  • 15. USE OF DIGESTER OUTPUT Biogas plant Separation composting Ultrafiltration / Reverse osmosis Nutrient solution (fertilizer) drying (pelletizing ) Products (fertilizer, soil) Org. fertilizer Output solid Output liquid reference: Wilken, 2010
  • 16. USE OF BIOGAS FOR ELECTRICITY AND HEAT Heat electricity
  • 17. Fuel (fuel cell) Treatment Reduction of H2S, CO2 and H2 Net for Natural gas USE OF BIOGAS FOR THE GASNET OR AS FUEL
  • 18. DEMAND ON USE Amount / grow / harvest Biogas- production storage Transport transport of digested sludge storage output production of heat and electricity heat elec- tricity Pre-treatment Transport to the gasnet production of heat and electricity heat elec- tricity fuel Demand on logistics Demand on physically qualities Demand on biochemical qualities Legal demands / restrictions Demand on use of digested sludge reference: Scholwin, DBFZ Leipzig, 2006
  • 19. DEMAND ON LOGISTICS - AVAILABILITY OF SUBSTRATES  Collection of biowaste in the municipalities  Amounts of manure, other agricultural waste and energy crops  Biogasproduction is an continouesly process! – Possibility of sorage of substrates  Avoidance of emissions and losses during intermediate storage  keep Temperatures low to avoid biological activity control of biomass-quality
  • 20. DEMAND ON PHYSICAL PROPERTIES  Area for growing for microorganisms (TS, solid state)  Temperature – homogeneously distribution in the fermenter  Water content  Viscosity
  • 21. DEMAND ON PHYSICAL PROPERTIES – PROCESS GUIDING OF BIOGAS FERMENTATION Mesophilic 30 – 37°C thermophilic 50 – 55°C dry fermentation 18 – 40 % TS wet fermentation 5 – 18 % TS dry fermentation 18 – 40 % TS One step One step two steps One step Classification of operation methods
  • 22. DEMAND ON BIOCHEMICAL QUALITIES – FLOW CHART OF THE ANAEROBIC FERMENTATION biomass polysacharides proteins fats sugar amiono acids fatty acids carboxylic acid alcohol acetat biogas CH4/CO2 H2/CO2 hydrolysis phase acidogenic phase methanogenic phase Hydrolysis digestion acetat production Macro-molecules intermediate products methan production hydrolytic fermentative acetogenic methanogenic microorganisms microorganisms microorganisms microorganisms
  • 23. DEMAND ON BIOCHEMICAL QUALITIES  Conditions for the single microorganisms  Choise of substrates (Mono / Co-fermentation)  Pre-treatment of substrates  Concentration of nutrients and trace elements  pH-value  Inhibition substances
  • 24. DEMANDS OF THE USE OF DIGESTED SLUDGE Use as fertilizer and soil  Supply of nutrients  Load on heavy metals and organics  Demand on area Rerence: Budewig, 2010