Explain why the vapor pressure of a solution made with a nonvolatile solution must be less than the vapor pressure of the pure solvent? Solution Escaping of solvent molecules from the surface of liquid to space is called vaporization. The vapors are then condensed. When there is an equilibrium between vaporization and condensation, the pressure exerted by the vapors of the liquid over the liquid is called vapor pressure. In a pure liquid, the entire surface is occupied by the molecules of the liquid whereas in the case of solution, the surface is occupied by the liquid molecuels and nonvolatile solute molecules. So, the number of solvent molecules escaping from the surface is reduced compare to the pure solvent, thus, the vapor pressure of solution is reduced. Hence, the vapor pressure of a solution of nonvolatile solution is less than the vapor pressure of the pure solvent..