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Pawandeep Singh
Pratyush Srivastava
o   Alloy steel is steel that is alloyed with a variety of
    elements in total amounts between 1.0% and 50%
    by weight to modify or improve its mechanical
    properties.
o   The definition of alloy steel does not include those
    effects which are negative or cure of ills that the
    steel might possess were the alloying element(s)
    not added.
o   The term "alloy steel" is the standard term
    referring to steels with other alloying elements in
    addition to the carbon. Common alloyants
    include Mn, Ni, Cr, Mo, V, Si and B . Less
    common alloyants include Al, Co, Cu, Ti, W, Sn,
    Zn, Pb and Zr.
Alloy steel has some of its properties better than
   carbon steel. They are as follows:-

o   Tensile strength
o   Hardness
o   Toughness
o   Wear Resistance
o   Creep
o   High Temperature Resistance
o   To achieve some of these improved properties the
    metal may require heat treating.
o   low-alloy steels : increase strength and hardenability
o   high-alloy steels : improves corrosion resistance and stability at
    high or low temperature.
o   Most commonly, the phrase "alloy steel" refers to low-
    alloy steels.
o   One more classification method is based upon the
    composition
o   Simple alloy steel is alloy steel containing one alloying
    element, for example, simple nickel steel.
o   Quaternary alloy steel is alloy steel that contains two
    alloying elements, as, Chromium Vanadium steel.
o   Complex steel is alloy steel containing more than two
    alloying elements such as high speed tool steel.
It’s a complex and highly specialized process which can be
                            summarized as :-
   Electric Arc furnace/Mini Blast Furnace
   Ladle Furnace
   Vacuum Degassing
   Continous Casting
   Hot Rolling
   Downstream Processing(recovery and purification)

Alloy Steel may be supplied in:-
  As rolled condition
  Heat treated
  Cold finished
  Smooth turned
  Centre less Ground
Alloy steels are manufactured in the form of:
   Bars
   Wires
   Wire Rod
   Bright Bars
Sizes
   Alloy steel products are manufactured in size ranging from 5mm
    to 400mm width or diameter.
Shapes: Alloy Steel products are manufactured in the following
    shapes:
   Square
   Round
   Rectangle
   Hexagon
   Flat
   Customized Shapes
   Alloying elements are added to achieve certain
    properties in the material.
   added in lower percentages (less than 5%) to
    increase strength or hardenability
   added in larger percentages (over 5%) to
    achieve special properties, such as corrosion
    resistance or extreme temperature stability.
   Mn, Si, or Al are added during the steelmaking
    process to remove dissolved oxygen, sulphur
    and phosphorus from the melt.
   Mn, Si, Ni, and Cu are added to increase
    strength by forming solid solutions in ferrite.
   Carbon:
-   Fe is alloyed with carbon to make steel and has the
    effect of increasing the hardness and strength by heat
    treatment but the addition of carbon enables a wide
    range of hardness and strength.
   Manganese
-   added to steel to improve hot working properties and
    increase strength, toughness and hardenability.
-   It is an austenite forming element and has been used as
    a substitute for nickel in the A.I.S.I 200 Series of
    Austenitic stainless steels (e.g. A.I.S.I 202 as a substitute
    for A.I.S.I 304)
-   Used as deoxidizer.
   Nickel
-   added in large amounts, over about 8%, to high
    chromium stainless steel to form the most important
    class of corrosion and heat resistant steels.
-   the tendency of nickel to form austenite is responsible
    for a great toughness and high strength at both high
    and low temperatures.
-    Nickel also improves resistance to oxidation and
    corrosion.
   Chromium
-   to increase resistance to oxidation. This resistance
    increases as more chromium is added.
-   When added to low alloy steels, chromium can increase
    the response to heat treatment, thus improving
    hardenability and strength.
-   Increase strength by forming second-phase carbide.
   Molybdenum
-   when added to chromium-nickel austenitic steels,
    improves resistance to pitting corrosion
-   When added to low alloy steels, molybdenum
    improves high temperature strengths and hardness.
   Titanium
-   The main use of titanium as an alloying element in
    steel is for carbide stabilisation as it forms TiC in solid
    phase.
-   Thus tends to minimize the occurrence of inter-
    granular corrosion, as with A.I.S.I 321, when adding
    approximately 0.25%/0.60% titanium
   Copper
-   Improves corrosion resistance
   Phosphorus
-   Phosphorus is usually added with sulphur to improve
    machinability in low alloy steels,
-   Phosphorus, in small amounts, aids strength and corrosion
    resistance.
-    Phosphorus additions are known to increase the tendency to
    cracking during welding.
   Sulphur and Selenium
-   improves machinability.
   Silicon
-   used as a deoxidizing (killing) agent.
-   contributes to hardening of the ferritic phase in steels and for this
    reason silicon killed steels are somewhat harder and stiffer than
    aluminium killed steels.
   Cobalt
-   improves strength at high temperatures and magnetic
    permeability.
-   But Co containing steel cannot be used in Nuclear plants as it is
    radioactive.
Density (1000 kg/m3):               Around 7.85


Elastic Modulus (GPa):              190-210


Poisson's Ratio:Yield Strength      366-1793
(MPa):
Thermal Expansion (10-6/K):         9.0-15


Melting Point (°C):                 1371-1454  


Thermal Conductivity (W/m-K):       26-48.6


Specific Heat (J/kg-K):             452-1499

Electrical Resistivity (10-9W-m):   210-1251


Tensile Strength (MPa):             758-1882



Percent Elongation (%) :            4-31


Hardness (Brinell 3000kg):          149-627
Alloy Steels are specifically produced for sophisticated engineering
   applications. Alloy Steels finds its applications in various areas:
 Automotive                     Transmission Parts, Engine Components, Steering
                                Components, High Tensile Fasteners, Fuel Injection
                                Pumps, Bearing Axles, Gears, Crankshaft,
                                Transmission Chains, Springs, Combustion
                                chamber, Axles, Wheel Hubs

 Engineering                    Cutting Tools, Structural Steel

 Industry                       Mining Machinery, Energy exploration machinery,
                                food-processing units(non-corrosive environment)
 Construction                   Reinforcing Bars
 Agriculture                    Tractor Parts
 Home                           Utensils, Decorative purposes
 Railways                       Wagon Axles, Crankshafts, Cushioning Device
                                Components, Steel Liners, Traction Gears
 Military                       Ordnance, gun barrels, projectiles, missile
                                components
   The application of alloy steel is increasing everyday.
   Wide use in Automotive industries
   The other major consuming sectors like auto ancillary,
    seamless pipes and tubes, engineering and railways
    etc. have also consumed rising quantity of alloy steel.
   Forging industry is the largest consumer of alloy steel,
    which in turn caters to the need of automotive and auto
    ancillary sector.
   The industry has registered a growth of over 15% p.a.
    for the last two years.
   CARE(Credit Analysis & Research Limited) Research
    expects the domestic alloy steel demand to grow at a
    CAGR of 13.6% during the period FY11 to FY16.
   Pakistan authorities have allowed import of only alloy steel
    items through Wagah border, banning entry of non alloy
    steel items through this route.
   South Africa’s imports of alloy steel is increasing at a high
    rate.
   Mr Wang Yong chairman of Xiwang Special Steel Co. a
    subsidiary of Shandong Province based China steelmaker
    Xiwang Group has stated that construction work on the
    company high strength alloy steel pipe project will start
    early in the second half year of this year with
    commissioning expected in the third quarter. The planned
    annual output capacity is 2 million tonnes.
   Iran produced 307,300 tonnes of alloy steel last calendar
    year which ended on March 19th 2012 showing 11.3%
    increase on the previous year. It expects to increase its
    production capacity by 80% in next few years.
   Iran exported 180,000 tonnes of alloy steel previous year
   According to provisional data released by Joint Plant Committee, given below are
    the production, import, export and consumption figures for alloy steel for April
    2012.
   (all data is in ‘000 tonnes)
   Alloy steel (including stainless steel) constitutes only
    approx. 10% of the overall annual steel production in India.
   But its share is approx. 20% in terms of value since the
    products are substantially value added for specific end
    users.
   Alloy steels are specifically produced for use in
    sophisticated engineering products for various critical
    applications such as :-
-   machined components
-   engine parts
-   steering components and bearings
-   automobile industry.

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Alloy Steel

  • 2. o Alloy steel is steel that is alloyed with a variety of elements in total amounts between 1.0% and 50% by weight to modify or improve its mechanical properties. o The definition of alloy steel does not include those effects which are negative or cure of ills that the steel might possess were the alloying element(s) not added. o The term "alloy steel" is the standard term referring to steels with other alloying elements in addition to the carbon. Common alloyants include Mn, Ni, Cr, Mo, V, Si and B . Less common alloyants include Al, Co, Cu, Ti, W, Sn, Zn, Pb and Zr.
  • 3. Alloy steel has some of its properties better than carbon steel. They are as follows:- o Tensile strength o Hardness o Toughness o Wear Resistance o Creep o High Temperature Resistance o To achieve some of these improved properties the metal may require heat treating.
  • 4. o low-alloy steels : increase strength and hardenability o high-alloy steels : improves corrosion resistance and stability at high or low temperature. o Most commonly, the phrase "alloy steel" refers to low- alloy steels. o One more classification method is based upon the composition o Simple alloy steel is alloy steel containing one alloying element, for example, simple nickel steel. o Quaternary alloy steel is alloy steel that contains two alloying elements, as, Chromium Vanadium steel. o Complex steel is alloy steel containing more than two alloying elements such as high speed tool steel.
  • 5.
  • 6. It’s a complex and highly specialized process which can be summarized as :-  Electric Arc furnace/Mini Blast Furnace  Ladle Furnace  Vacuum Degassing  Continous Casting  Hot Rolling  Downstream Processing(recovery and purification) Alloy Steel may be supplied in:-  As rolled condition  Heat treated  Cold finished  Smooth turned  Centre less Ground
  • 7. Alloy steels are manufactured in the form of:  Bars  Wires  Wire Rod  Bright Bars Sizes  Alloy steel products are manufactured in size ranging from 5mm to 400mm width or diameter. Shapes: Alloy Steel products are manufactured in the following shapes:  Square  Round  Rectangle  Hexagon  Flat  Customized Shapes
  • 8.
  • 9. Alloying elements are added to achieve certain properties in the material.  added in lower percentages (less than 5%) to increase strength or hardenability  added in larger percentages (over 5%) to achieve special properties, such as corrosion resistance or extreme temperature stability.  Mn, Si, or Al are added during the steelmaking process to remove dissolved oxygen, sulphur and phosphorus from the melt.  Mn, Si, Ni, and Cu are added to increase strength by forming solid solutions in ferrite.
  • 10. Carbon: - Fe is alloyed with carbon to make steel and has the effect of increasing the hardness and strength by heat treatment but the addition of carbon enables a wide range of hardness and strength.  Manganese - added to steel to improve hot working properties and increase strength, toughness and hardenability. - It is an austenite forming element and has been used as a substitute for nickel in the A.I.S.I 200 Series of Austenitic stainless steels (e.g. A.I.S.I 202 as a substitute for A.I.S.I 304) - Used as deoxidizer.
  • 11. Nickel - added in large amounts, over about 8%, to high chromium stainless steel to form the most important class of corrosion and heat resistant steels. - the tendency of nickel to form austenite is responsible for a great toughness and high strength at both high and low temperatures. - Nickel also improves resistance to oxidation and corrosion.  Chromium - to increase resistance to oxidation. This resistance increases as more chromium is added. - When added to low alloy steels, chromium can increase the response to heat treatment, thus improving hardenability and strength. - Increase strength by forming second-phase carbide.
  • 12. Molybdenum - when added to chromium-nickel austenitic steels, improves resistance to pitting corrosion - When added to low alloy steels, molybdenum improves high temperature strengths and hardness.  Titanium - The main use of titanium as an alloying element in steel is for carbide stabilisation as it forms TiC in solid phase. - Thus tends to minimize the occurrence of inter- granular corrosion, as with A.I.S.I 321, when adding approximately 0.25%/0.60% titanium  Copper - Improves corrosion resistance
  • 13. Phosphorus - Phosphorus is usually added with sulphur to improve machinability in low alloy steels, - Phosphorus, in small amounts, aids strength and corrosion resistance. - Phosphorus additions are known to increase the tendency to cracking during welding.  Sulphur and Selenium - improves machinability.  Silicon - used as a deoxidizing (killing) agent. - contributes to hardening of the ferritic phase in steels and for this reason silicon killed steels are somewhat harder and stiffer than aluminium killed steels.  Cobalt - improves strength at high temperatures and magnetic permeability. - But Co containing steel cannot be used in Nuclear plants as it is radioactive.
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  • 15.
  • 16. Density (1000 kg/m3): Around 7.85 Elastic Modulus (GPa): 190-210 Poisson's Ratio:Yield Strength 366-1793 (MPa): Thermal Expansion (10-6/K): 9.0-15 Melting Point (°C):     1371-1454   Thermal Conductivity (W/m-K): 26-48.6 Specific Heat (J/kg-K): 452-1499 Electrical Resistivity (10-9W-m): 210-1251 Tensile Strength (MPa): 758-1882 Percent Elongation (%) : 4-31 Hardness (Brinell 3000kg): 149-627
  • 17. Alloy Steels are specifically produced for sophisticated engineering applications. Alloy Steels finds its applications in various areas: Automotive Transmission Parts, Engine Components, Steering Components, High Tensile Fasteners, Fuel Injection Pumps, Bearing Axles, Gears, Crankshaft, Transmission Chains, Springs, Combustion chamber, Axles, Wheel Hubs Engineering Cutting Tools, Structural Steel Industry Mining Machinery, Energy exploration machinery, food-processing units(non-corrosive environment) Construction Reinforcing Bars Agriculture Tractor Parts Home Utensils, Decorative purposes Railways Wagon Axles, Crankshafts, Cushioning Device Components, Steel Liners, Traction Gears Military Ordnance, gun barrels, projectiles, missile components
  • 18. The application of alloy steel is increasing everyday.  Wide use in Automotive industries  The other major consuming sectors like auto ancillary, seamless pipes and tubes, engineering and railways etc. have also consumed rising quantity of alloy steel.  Forging industry is the largest consumer of alloy steel, which in turn caters to the need of automotive and auto ancillary sector.  The industry has registered a growth of over 15% p.a. for the last two years.  CARE(Credit Analysis & Research Limited) Research expects the domestic alloy steel demand to grow at a CAGR of 13.6% during the period FY11 to FY16.
  • 19. Pakistan authorities have allowed import of only alloy steel items through Wagah border, banning entry of non alloy steel items through this route.  South Africa’s imports of alloy steel is increasing at a high rate.  Mr Wang Yong chairman of Xiwang Special Steel Co. a subsidiary of Shandong Province based China steelmaker Xiwang Group has stated that construction work on the company high strength alloy steel pipe project will start early in the second half year of this year with commissioning expected in the third quarter. The planned annual output capacity is 2 million tonnes.  Iran produced 307,300 tonnes of alloy steel last calendar year which ended on March 19th 2012 showing 11.3% increase on the previous year. It expects to increase its production capacity by 80% in next few years.  Iran exported 180,000 tonnes of alloy steel previous year
  • 20. According to provisional data released by Joint Plant Committee, given below are the production, import, export and consumption figures for alloy steel for April 2012.  (all data is in ‘000 tonnes)
  • 21. Alloy steel (including stainless steel) constitutes only approx. 10% of the overall annual steel production in India.  But its share is approx. 20% in terms of value since the products are substantially value added for specific end users.  Alloy steels are specifically produced for use in sophisticated engineering products for various critical applications such as :- - machined components - engine parts - steering components and bearings - automobile industry.