1. Experiments show that the hydronium ion, H3O, is actually further hydrated so that the proton may have several water molecules associated with it. Why then do we use H3O\', and even more frequently H\', to represent the aqueous proton? Solution Actuall H + does not exist in aqueous solutions it is always exist as H 3 O + (aq) and this is correct way of representation. Further, hydronium ion is not a unique species and can pick up additional waters of hydration to form, for example H 5 O 2 + . So, while H 3 O + is more correct than writing H + , it is not prefectly correct. However, we will most often use H + , since more H 2 O is present, as compared with H + when we deal with weak acids for example HA is a weak acid and dissolved in water now we have HA (l) + H 2 O (l) <==> H 3 O + (aq) + A - (aq) dissociation constant K a = [H + ][A - ] / [HA] only H 3 O + (aq) <==> H + (aq) + H 2 O (l) Hope this helped you! Thank You So Much! Please Rate this answer as you wish.(\"Thumbs Up\") .