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ARAMID FIBERS
SOBH THEBO
1
DEPARTMENT OF TEXTILE ENGINEERING
MEHRAN UNIVERSITY OF ENGINEERING &
TECHNOLOGY JAMSHORO
CONTENTS
 INTRODUCTION
 TYPES OF ARAMID
 PRODUCTION
 APPLICATIONS
 REFERENCES
2
 FIBER PROPERTIES
3
POLY-AMIDE FIBERS
Synthetic fibers of polymer containing amide linkages.
There are two types of Polyamide:
 NYLONS
Polyamides containing less than 85% amide linkages directly attached two
aromatic rings.
 ARAMIDS
Polyamides containing atleast 85% amide linkages directly
attached two aromatic rings.
INTRODUCTION TO ARAMIDS
“A manufactured fiber in which the fiber-forming substance is a long-
chain synthetic polyamide in which at least 85% of the amide (-CO-NH-)
linkages are attached directly between two aromatic rings”.
The term “aramid” is short for “aromatic polyamide”.
4
5
Aramid fibers of commercial stage are only four :
 poly(m-phenylene isophthalamide) (MPDI),
 poly(p-phenylene terephthalamide) (PPTA),
 copoly(p-phenylene-3,4-diphenyl ether terephthalamide) (ODA-PPTA), and
 poly[5-amino-2(p-aminophenyl) benzimidazole terephthalamide] (SVM).
PRODUCTION
Produced by reaction of aromatic diacid chlorides with diamines in a
solvent.
Polymers are dry spun or wet spun, followed by stretching.
6
• Spinning Solution
– 10-20 wt%
polymer
– 100% H2SO4
TYPES OF ARAMID
● Nomex (Meta-Aramid)
● Kevlar (Para-Aramid)
7
 Poly-m-phenyleneisophthalamide was commercialized by
DuPont in 1967 as Nomex.
 poly (m-phenylenediamine isophthalamide called MPDI.
 Famous for thermal and electrical insulation.
NOMEX
8
9
NOMEX
 Synthetic para-aromatic polyamides led to the commercial
production of Kevlar aramid fiber by DuPont in 1971.
 Kevlar fibres are poly (p-phenylene terephthalamide)
(PPTA).
KEVLAR
 Famous for high modulus and high tenacity (HM-HT).
10
KEVLAR
11
● High modulus
● High tensile strength at low weight
● High chemical resistance
● High toughness
● High cut resistance
● Flame resistant
● Low electrical conductivity
ARAMID FIBER PROPERTIES
12
Kevlar
Nomex
13
ARAMID FIBER PROPERTIES
DENSITY Nomex : 1.35 g/cm²
Kevlar : I .45 g/cm²
Nomex : Heat Resistant
Kevlar : High Strength & High Modulus
Moisture absorption Nomex : upto 4.3%
Kevlar : 6.5%
UV light absorption Nomex : low
Kevlar : High
COLOR Nomex : White
Kevlar : Golden
Dye Substantivity Nomex : Low
Kevlar : Low
APPLICATIONS
Composites: Ship building, civil engineering & ports good.
Protective apparels: Flame retardant textiles & cut protective apparels.
Tyres: Truck and aircraft tyres & High speed tyres.
Mechanical rubber goods: Conveyor belts ,Transmission belts & Hoses for automotive.
Friction products: Brake linings, clutch facings & industrial paper.
Ropes and cables: Aerial optical fibre cable, electro cable & Mechanical construction
cable.
Life protection: Bullet proof vests, helmets & vehicle protection.
14
REFERNCES
 “High performance fibres” by JWS Hearle.
 https://www.slideshare.net/sakhizar/aramid-fibers-
47983957?next_slideshow=1.
 Bhattacharyya, D., & Fakirov, S. (Eds.).
(2012). Synthetic polymer-polymer composites.
Carl Hanser Verlag GmbH Co KG.
15
THANK YOU!
16

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Aramid fibers.ppt

  • 1. ARAMID FIBERS SOBH THEBO 1 DEPARTMENT OF TEXTILE ENGINEERING MEHRAN UNIVERSITY OF ENGINEERING & TECHNOLOGY JAMSHORO
  • 2. CONTENTS  INTRODUCTION  TYPES OF ARAMID  PRODUCTION  APPLICATIONS  REFERENCES 2  FIBER PROPERTIES
  • 3. 3 POLY-AMIDE FIBERS Synthetic fibers of polymer containing amide linkages. There are two types of Polyamide:  NYLONS Polyamides containing less than 85% amide linkages directly attached two aromatic rings.  ARAMIDS Polyamides containing atleast 85% amide linkages directly attached two aromatic rings.
  • 4. INTRODUCTION TO ARAMIDS “A manufactured fiber in which the fiber-forming substance is a long- chain synthetic polyamide in which at least 85% of the amide (-CO-NH-) linkages are attached directly between two aromatic rings”. The term “aramid” is short for “aromatic polyamide”. 4
  • 5. 5 Aramid fibers of commercial stage are only four :  poly(m-phenylene isophthalamide) (MPDI),  poly(p-phenylene terephthalamide) (PPTA),  copoly(p-phenylene-3,4-diphenyl ether terephthalamide) (ODA-PPTA), and  poly[5-amino-2(p-aminophenyl) benzimidazole terephthalamide] (SVM).
  • 6. PRODUCTION Produced by reaction of aromatic diacid chlorides with diamines in a solvent. Polymers are dry spun or wet spun, followed by stretching. 6 • Spinning Solution – 10-20 wt% polymer – 100% H2SO4
  • 7. TYPES OF ARAMID ● Nomex (Meta-Aramid) ● Kevlar (Para-Aramid) 7
  • 8.  Poly-m-phenyleneisophthalamide was commercialized by DuPont in 1967 as Nomex.  poly (m-phenylenediamine isophthalamide called MPDI.  Famous for thermal and electrical insulation. NOMEX 8
  • 10.  Synthetic para-aromatic polyamides led to the commercial production of Kevlar aramid fiber by DuPont in 1971.  Kevlar fibres are poly (p-phenylene terephthalamide) (PPTA). KEVLAR  Famous for high modulus and high tenacity (HM-HT). 10
  • 12. ● High modulus ● High tensile strength at low weight ● High chemical resistance ● High toughness ● High cut resistance ● Flame resistant ● Low electrical conductivity ARAMID FIBER PROPERTIES 12 Kevlar Nomex
  • 13. 13 ARAMID FIBER PROPERTIES DENSITY Nomex : 1.35 g/cm² Kevlar : I .45 g/cm² Nomex : Heat Resistant Kevlar : High Strength & High Modulus Moisture absorption Nomex : upto 4.3% Kevlar : 6.5% UV light absorption Nomex : low Kevlar : High COLOR Nomex : White Kevlar : Golden Dye Substantivity Nomex : Low Kevlar : Low
  • 14. APPLICATIONS Composites: Ship building, civil engineering & ports good. Protective apparels: Flame retardant textiles & cut protective apparels. Tyres: Truck and aircraft tyres & High speed tyres. Mechanical rubber goods: Conveyor belts ,Transmission belts & Hoses for automotive. Friction products: Brake linings, clutch facings & industrial paper. Ropes and cables: Aerial optical fibre cable, electro cable & Mechanical construction cable. Life protection: Bullet proof vests, helmets & vehicle protection. 14
  • 15. REFERNCES  “High performance fibres” by JWS Hearle.  https://www.slideshare.net/sakhizar/aramid-fibers- 47983957?next_slideshow=1.  Bhattacharyya, D., & Fakirov, S. (Eds.). (2012). Synthetic polymer-polymer composites. Carl Hanser Verlag GmbH Co KG. 15