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You are the superintendent of a 10 MGD potable water treatment facility. It has been brought to
your attention that your source water is excessively hard. Using a combination of lime
(Ca(OH)2) and soda ash (Na2CO3) you will soften the water for use in your distribution system.
Chemical analysis of the water revealed the constituent concentrations in the table below. (a)
Complete the table below and use the results to (b) sketch a meq/L bar graph that indicates the
acid/base balance in the water prior to softening, and (c) calculate the quantity of softening
materials required on a daily basis (assume 24 hr operation).concentration mg/Lmolecular weight
in g/mol# of equivilentsequivilent weight in g/mol eqequivilent concentration
meq/Lconcentration as CaCO3CO28Ca2+40Mg2+14.7Na+13.7Alkalinity135SO4 2-29Cl-17.8
Solution
Cations
Anions
Ion
MW
Charge
Conc
Equiv.
Ion
MW
Conc
Equiv.
(mg/L)
(meq/L)
(mg/L)
(meq/L)
CO2
44
2
8.8
0.40
Ca2+
40
2
40
2.00
Alk (HCO3–)
50
1
135
2.70
Mg2+
24.3
2
14.7
1.21
SO42–
96
2
29
0.60
Na+
23
1
13.7
0.60
Cl –
35.5
1
17.8
0.50
Check charge balance:
Total cations:
3.81
Total anions:
3.81
Hardness =
3.21
meq/L
160
mg/L as CaCO3
Strong bases =
3.81
meq/L
190
mg/L as CaCO3
Strong acids =
1.11
meq/L
55
mg/L as CaCO3
Alk =
2.70
meq/L
135
mg/L as CaCO3
Carb hardness =
2.70
meq/L
135
mg/L as CaCO3
Ca carb hardness =
2.00
meq/L
100
mg/L as CaCO3
Mg carb hardness =
0.71
meq/L
36
mg/L as CaCO3
Non-carb hardness =
0.51
meq/L
25
mg/L as CaCO3
Mg NCH =
0.51
meq/L
25
mg/L as CaCO3
Lime requirement:
Component
mg/L as
meq/L
Lime as
CaCO3
CaCO3
Lime for CO2
CO2
20
0.40
20
Lime for Ca CH
Ca(HCO3)2
100
2.00
100
Lime for Mg CH
Mg(HCO3)2
36
0.71
71
*
Lime for non-carb hardness
NCH
25
0.51
25
Total lime needed
Total
181
3.62
216
Total lime as CaO
121
mg/L as CaO
Plus excess lime
35
mg/L as CaO
Total lime including excess
156
mg/L as CaO
Cations
Anions
Ion
MW
Charge
Conc
Equiv.
Ion
MW
Conc
Equiv.
(mg/L)
(meq/L)
(mg/L)
(meq/L)
CO2
44
2
8.8
0.40
Ca2+
40
2
40
2.00
Alk (HCO3–)
50
1
135
2.70
Mg2+
24.3
2
14.7
1.21
SO42–
96
2
29
0.60
Na+
23
1
13.7
0.60
Cl –
35.5
1
17.8
0.50
Check charge balance:
Total cations:
3.81
Total anions:
3.81

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You are the superintendent of a 10 MGD potable water treatment facil.pdf

  • 1. You are the superintendent of a 10 MGD potable water treatment facility. It has been brought to your attention that your source water is excessively hard. Using a combination of lime (Ca(OH)2) and soda ash (Na2CO3) you will soften the water for use in your distribution system. Chemical analysis of the water revealed the constituent concentrations in the table below. (a) Complete the table below and use the results to (b) sketch a meq/L bar graph that indicates the acid/base balance in the water prior to softening, and (c) calculate the quantity of softening materials required on a daily basis (assume 24 hr operation).concentration mg/Lmolecular weight in g/mol# of equivilentsequivilent weight in g/mol eqequivilent concentration meq/Lconcentration as CaCO3CO28Ca2+40Mg2+14.7Na+13.7Alkalinity135SO4 2-29Cl-17.8 Solution Cations Anions Ion MW Charge Conc Equiv. Ion MW Conc Equiv. (mg/L) (meq/L) (mg/L) (meq/L) CO2 44 2 8.8 0.40 Ca2+ 40 2
  • 3. mg/L as CaCO3 Strong bases = 3.81 meq/L 190 mg/L as CaCO3 Strong acids = 1.11 meq/L 55 mg/L as CaCO3 Alk = 2.70 meq/L 135 mg/L as CaCO3 Carb hardness = 2.70 meq/L 135 mg/L as CaCO3 Ca carb hardness = 2.00 meq/L 100 mg/L as CaCO3 Mg carb hardness = 0.71 meq/L 36 mg/L as CaCO3 Non-carb hardness = 0.51 meq/L 25 mg/L as CaCO3
  • 4. Mg NCH = 0.51 meq/L 25 mg/L as CaCO3 Lime requirement: Component mg/L as meq/L Lime as CaCO3 CaCO3 Lime for CO2 CO2 20 0.40 20 Lime for Ca CH Ca(HCO3)2 100 2.00 100 Lime for Mg CH Mg(HCO3)2 36 0.71 71 * Lime for non-carb hardness NCH 25 0.51 25 Total lime needed Total
  • 5. 181 3.62 216 Total lime as CaO 121 mg/L as CaO Plus excess lime 35 mg/L as CaO Total lime including excess 156 mg/L as CaO Cations Anions Ion MW Charge Conc Equiv. Ion MW Conc Equiv. (mg/L) (meq/L) (mg/L) (meq/L) CO2 44 2 8.8 0.40 Ca2+ 40 2 40