XPS is a surface-sensitive technique that uses X-rays to eject electrons from the surface of a sample. It can be used to determine the elemental composition, empirical formula, chemical or electronic state of elements present in the surface. The principle is based on the photoelectric effect where X-rays eject core shell electrons of an atom. The kinetic energy of these photoelectrons is measured to determine the elemental identity and chemical state. XPS provides information down to 10-100 Angstroms from the surface and is useful for applications like failure analysis, corrosion studies, and analyzing thin film coatings and polymers.
X-ray photoelectron spectroscopy (XPS) or Electron spectroscopy for chemical analysis (ESCA) is used to investigate the chemistry at the surface of the samples. The basic mechanism behind an XPS instrument is that the photons of a specific energy are used to excite the electronic states of atoms at and just below the surface of the sample.
There are several areas suited to measurement by XPS:
1. Elemental composition
2. Empirical formula determination
3. Chemical state
4. Electronic state
5. Binding energy
6. Layer thickness in the upper portion of surfaces
XPS has many advantages, such as it is is good for identifying all but two elements, identifying the chemical state on surfaces, and is good with quantitative analysis. XPS is capable of detecting the difference in the chemical state between samples. XPS is also able to differentiate between oxidations states of molecules.
XPS has also some limitations, for instance, samples for XPS must be compatible with the ultra high vacuum environment. XPS is limited to measurements of elements having atomic numbers of 3 or greater, making it unable to detect hydrogen or helium. XPS spectra also take a long time to obtain. The use of a monochromator can also reduce the time per experiment.
X-Ray photoelectron spectroscopy, XPS was used to investigate the chemistry at the surface of the samples. The basic mechanism behind an XPS instrument is that the photons of a specific energy are used to excite the electronic states of atoms at and just below the surface of the sample.
There are several areas suited to measurement by XPS:
1. Elemental composition
2. Empirical formula determination
3. Chemical state
4. Electronic state
5. Binding energy
6. Layer thickness in the upper portion of surfaces
XPS has many advantages, such as it is is good for identifying all but two elements, identifying the chemical state on surfaces, and is good with quantitative analysis. XPS is capable of detecting the difference in chemical state between samples. XPS is also able to differentiate between oxidations states of molecules.
XPS has also some limitations, for instance, samples for XPS must be compatible with the ultra high vacuum environment. XPS is limited to measurements of elements having atomic numbers of 3 or greater, making it unable to detect hydrogen or helium. XPS spectra also take a long time to obtain. The use of a monochromator can also reduce the time per experiment.
X-ray photoelectron spectroscopy (XPS) or Electron spectroscopy for chemical analysis (ESCA) is used to investigate the chemistry at the surface of the samples. The basic mechanism behind an XPS instrument is that the photons of a specific energy are used to excite the electronic states of atoms at and just below the surface of the sample.
There are several areas suited to measurement by XPS:
1. Elemental composition
2. Empirical formula determination
3. Chemical state
4. Electronic state
5. Binding energy
6. Layer thickness in the upper portion of surfaces
XPS has many advantages, such as it is is good for identifying all but two elements, identifying the chemical state on surfaces, and is good with quantitative analysis. XPS is capable of detecting the difference in the chemical state between samples. XPS is also able to differentiate between oxidations states of molecules.
XPS has also some limitations, for instance, samples for XPS must be compatible with the ultra high vacuum environment. XPS is limited to measurements of elements having atomic numbers of 3 or greater, making it unable to detect hydrogen or helium. XPS spectra also take a long time to obtain. The use of a monochromator can also reduce the time per experiment.
X-Ray photoelectron spectroscopy, XPS was used to investigate the chemistry at the surface of the samples. The basic mechanism behind an XPS instrument is that the photons of a specific energy are used to excite the electronic states of atoms at and just below the surface of the sample.
There are several areas suited to measurement by XPS:
1. Elemental composition
2. Empirical formula determination
3. Chemical state
4. Electronic state
5. Binding energy
6. Layer thickness in the upper portion of surfaces
XPS has many advantages, such as it is is good for identifying all but two elements, identifying the chemical state on surfaces, and is good with quantitative analysis. XPS is capable of detecting the difference in chemical state between samples. XPS is also able to differentiate between oxidations states of molecules.
XPS has also some limitations, for instance, samples for XPS must be compatible with the ultra high vacuum environment. XPS is limited to measurements of elements having atomic numbers of 3 or greater, making it unable to detect hydrogen or helium. XPS spectra also take a long time to obtain. The use of a monochromator can also reduce the time per experiment.
X-Ray photoelectron spectroscopy, XPS was used to investigate the chemistry at the surface of the samples. The basic mechanism behind an XPS instrument is that the photons of a specific energy are used to excite the electronic states of atoms at and just below the surface of the sample.
There are several areas suited to measurement by XPS:
1. Elemental composition
2. Empirical formula determination
3. Chemical state
4. Electronic state
5. Binding energy
6. Layer thickness in the upper portion of surfaces
XPS has many advantages, such as it is is good for identifying all but two elements, identifying the chemical state on surfaces, and is good with quantitative analysis. XPS is capable of detecting the difference in chemical state between samples. XPS is also able to differentiate between oxidations states of molecules.
XPS has also some limitations, for instance, samples for XPS must be compatible with the ultra high vacuum environment. XPS is limited to measurements of elements having atomic numbers of 3 or greater, making it unable to detect hydrogen or helium. XPS spectra also take a long time to obtain. The use of a monochromator can also reduce the time per experiment.
Photoelectron spectroscopy
- a single photon in/ electron out process
• X-ray Photoelectron Spectroscopy (XPS)
- using soft x-ray (200-2000 eV) radiation to
examine core-levels.
• Ultraviolet Photoelectron Spectroscopy (UPS)
- using vacuum UV (10-45 eV) radiation to
examine valence levels.
Instrumentation presentation - Auger Electron Spectroscopy (AES)Amirah Basir
Group 5-AES
Normaizatul Hanissa Binti Hamdan
Amirah Binti Basir
-Introduction/Backgroud /History, fundamental/basic principle and
elaboration of the principle, related pictures, related
equations/expressions/derivations, components and it functions,
related models/brands, technologies and applications
X-RAY PHOTOELECTRON SPECTROSCOPY AND ELECTRON SPIN RESONANCEKishan Kasundra
INTRODUCTION OF XPS
MECHANISM OF XPS
CHEMICAL SHIFT IN XPS
STRENGTHS AND LIMITATIONS OF XPS
INTRODUCTION OF ESR
MECHANISM OF ESR
PRESENTATION OF ESR SPECTRUM
APPLICATION OF ESR
ADVANTAGES AND DISADVANTAGES OF ESR
X-Ray photoelectron spectroscopy, XPS was used to investigate the chemistry at the surface of the samples. The basic mechanism behind an XPS instrument is that the photons of a specific energy are used to excite the electronic states of atoms at and just below the surface of the sample.
There are several areas suited to measurement by XPS:
1. Elemental composition
2. Empirical formula determination
3. Chemical state
4. Electronic state
5. Binding energy
6. Layer thickness in the upper portion of surfaces
XPS has many advantages, such as it is is good for identifying all but two elements, identifying the chemical state on surfaces, and is good with quantitative analysis. XPS is capable of detecting the difference in chemical state between samples. XPS is also able to differentiate between oxidations states of molecules.
XPS has also some limitations, for instance, samples for XPS must be compatible with the ultra high vacuum environment. XPS is limited to measurements of elements having atomic numbers of 3 or greater, making it unable to detect hydrogen or helium. XPS spectra also take a long time to obtain. The use of a monochromator can also reduce the time per experiment.
Photoelectron spectroscopy
- a single photon in/ electron out process
• X-ray Photoelectron Spectroscopy (XPS)
- using soft x-ray (200-2000 eV) radiation to
examine core-levels.
• Ultraviolet Photoelectron Spectroscopy (UPS)
- using vacuum UV (10-45 eV) radiation to
examine valence levels.
Instrumentation presentation - Auger Electron Spectroscopy (AES)Amirah Basir
Group 5-AES
Normaizatul Hanissa Binti Hamdan
Amirah Binti Basir
-Introduction/Backgroud /History, fundamental/basic principle and
elaboration of the principle, related pictures, related
equations/expressions/derivations, components and it functions,
related models/brands, technologies and applications
X-RAY PHOTOELECTRON SPECTROSCOPY AND ELECTRON SPIN RESONANCEKishan Kasundra
INTRODUCTION OF XPS
MECHANISM OF XPS
CHEMICAL SHIFT IN XPS
STRENGTHS AND LIMITATIONS OF XPS
INTRODUCTION OF ESR
MECHANISM OF ESR
PRESENTATION OF ESR SPECTRUM
APPLICATION OF ESR
ADVANTAGES AND DISADVANTAGES OF ESR
Students, digital devices and success - Andreas Schleicher - 27 May 2024..pptxEduSkills OECD
Andreas Schleicher presents at the OECD webinar ‘Digital devices in schools: detrimental distraction or secret to success?’ on 27 May 2024. The presentation was based on findings from PISA 2022 results and the webinar helped launch the PISA in Focus ‘Managing screen time: How to protect and equip students against distraction’ https://www.oecd-ilibrary.org/education/managing-screen-time_7c225af4-en and the OECD Education Policy Perspective ‘Students, digital devices and success’ can be found here - https://oe.cd/il/5yV
The French Revolution, which began in 1789, was a period of radical social and political upheaval in France. It marked the decline of absolute monarchies, the rise of secular and democratic republics, and the eventual rise of Napoleon Bonaparte. This revolutionary period is crucial in understanding the transition from feudalism to modernity in Europe.
For more information, visit-www.vavaclasses.com
Instructions for Submissions thorugh G- Classroom.pptxJheel Barad
This presentation provides a briefing on how to upload submissions and documents in Google Classroom. It was prepared as part of an orientation for new Sainik School in-service teacher trainees. As a training officer, my goal is to ensure that you are comfortable and proficient with this essential tool for managing assignments and fostering student engagement.
This is a presentation by Dada Robert in a Your Skill Boost masterclass organised by the Excellence Foundation for South Sudan (EFSS) on Saturday, the 25th and Sunday, the 26th of May 2024.
He discussed the concept of quality improvement, emphasizing its applicability to various aspects of life, including personal, project, and program improvements. He defined quality as doing the right thing at the right time in the right way to achieve the best possible results and discussed the concept of the "gap" between what we know and what we do, and how this gap represents the areas we need to improve. He explained the scientific approach to quality improvement, which involves systematic performance analysis, testing and learning, and implementing change ideas. He also highlighted the importance of client focus and a team approach to quality improvement.
How to Split Bills in the Odoo 17 POS ModuleCeline George
Bills have a main role in point of sale procedure. It will help to track sales, handling payments and giving receipts to customers. Bill splitting also has an important role in POS. For example, If some friends come together for dinner and if they want to divide the bill then it is possible by POS bill splitting. This slide will show how to split bills in odoo 17 POS.
The Indian economy is classified into different sectors to simplify the analysis and understanding of economic activities. For Class 10, it's essential to grasp the sectors of the Indian economy, understand their characteristics, and recognize their importance. This guide will provide detailed notes on the Sectors of the Indian Economy Class 10, using specific long-tail keywords to enhance comprehension.
For more information, visit-www.vavaclasses.com
2024.06.01 Introducing a competency framework for languag learning materials ...Sandy Millin
http://sandymillin.wordpress.com/iateflwebinar2024
Published classroom materials form the basis of syllabuses, drive teacher professional development, and have a potentially huge influence on learners, teachers and education systems. All teachers also create their own materials, whether a few sentences on a blackboard, a highly-structured fully-realised online course, or anything in between. Despite this, the knowledge and skills needed to create effective language learning materials are rarely part of teacher training, and are mostly learnt by trial and error.
Knowledge and skills frameworks, generally called competency frameworks, for ELT teachers, trainers and managers have existed for a few years now. However, until I created one for my MA dissertation, there wasn’t one drawing together what we need to know and do to be able to effectively produce language learning materials.
This webinar will introduce you to my framework, highlighting the key competencies I identified from my research. It will also show how anybody involved in language teaching (any language, not just English!), teacher training, managing schools or developing language learning materials can benefit from using the framework.
The Roman Empire A Historical Colossus.pdfkaushalkr1407
The Roman Empire, a vast and enduring power, stands as one of history's most remarkable civilizations, leaving an indelible imprint on the world. It emerged from the Roman Republic, transitioning into an imperial powerhouse under the leadership of Augustus Caesar in 27 BCE. This transformation marked the beginning of an era defined by unprecedented territorial expansion, architectural marvels, and profound cultural influence.
The empire's roots lie in the city of Rome, founded, according to legend, by Romulus in 753 BCE. Over centuries, Rome evolved from a small settlement to a formidable republic, characterized by a complex political system with elected officials and checks on power. However, internal strife, class conflicts, and military ambitions paved the way for the end of the Republic. Julius Caesar’s dictatorship and subsequent assassination in 44 BCE created a power vacuum, leading to a civil war. Octavian, later Augustus, emerged victorious, heralding the Roman Empire’s birth.
Under Augustus, the empire experienced the Pax Romana, a 200-year period of relative peace and stability. Augustus reformed the military, established efficient administrative systems, and initiated grand construction projects. The empire's borders expanded, encompassing territories from Britain to Egypt and from Spain to the Euphrates. Roman legions, renowned for their discipline and engineering prowess, secured and maintained these vast territories, building roads, fortifications, and cities that facilitated control and integration.
The Roman Empire’s society was hierarchical, with a rigid class system. At the top were the patricians, wealthy elites who held significant political power. Below them were the plebeians, free citizens with limited political influence, and the vast numbers of slaves who formed the backbone of the economy. The family unit was central, governed by the paterfamilias, the male head who held absolute authority.
Culturally, the Romans were eclectic, absorbing and adapting elements from the civilizations they encountered, particularly the Greeks. Roman art, literature, and philosophy reflected this synthesis, creating a rich cultural tapestry. Latin, the Roman language, became the lingua franca of the Western world, influencing numerous modern languages.
Roman architecture and engineering achievements were monumental. They perfected the arch, vault, and dome, constructing enduring structures like the Colosseum, Pantheon, and aqueducts. These engineering marvels not only showcased Roman ingenuity but also served practical purposes, from public entertainment to water supply.
2. Introduction
• XPS is also known as ESCA (Electron Spectroscopy for Chemical Analysis).
• Useful to find chemical composition, chemical state and electronic
configuration of material.
• Reveal information about thin film structures and surface layer.
• XPS is based on Einstein's idea about photoelectric effect which was
presented in 1905.
• Very simple and widely used technique and data obtain from it is analyzed
easily.
3. Principle
The working principle of XPS is ejection of electron from the surface of sample in
UHV condition when it is expose to the soft x-rays.
Elements present in sample can be identified on the basis of kinetic energies and
binding energies of their photoelectrons.
Intensities of photoelectron provide information about concentration of element in a
sample.
The electrons emitted from atoms near the sample surface (10-100 Angstroms) can
escape the sample surface. This depth is about twenty atomic layers.
4. Photoelectric effect
1 s 2 s 2 p
K
L
Photoemission
1 s 2 s 2 p
K
L
Relaxation
1 s 2 s 2 p
K
L
Auger Electron Emission
or
X-ray Fluorescence
• When an X-ray (with energy hv) ejects out an electron (by energy B.E). The
ejected electron is called photoelectron and this effect is called photoelectric
effect.
• The atom will release energy by the emission of an Auger Electron
5. The ejected photoelectron has kinetic energy:
K.E=hv-B.E- Ø
KE Kinetic Energy (which is measured by spectrometer of XPS)
hv Energy of photon emitted by X-rays
Ø Spectrometer work function. Few eV. calculated by calibration.
BE Binding Energy
6. • No emission of photon if h
ν< Ø
• No emission of photon from levels with BE + Ø > h
ν
• Increase in KE oh photoelectron cause decrease ki
BE.
• Photoemission intensity is represented by α
.
• Require monochromatic beam.
•
• Each element has different value of KE for core level
electrons.
E V
Kinetic
Energy
Binding
Energy
φ
Photoelectron
Valence
band
Core
levels
Photon
Ef
Core hole
7. Instrumentation
Components
A source of X-rays
An electron detector system
A set of stage manipulators
X-Ray Source
An ultra high vacuum (UHV)
Ion Source
An electron energy analyzer
CMA Analyzer
Magnetic field shielding
Sample introduction
Chamber
8. Schematic Diagram
5 4 . 7
X-ray
Source
Electron
Optics
Hemispherical Energy Analyzer
Position Sensitive
Detector (PSD)
Magnetic Shield
Outer Sphere
Inner Sphere
Sample
Computer
System
Analyzer Control
Multi-Channel Plate
Electron Multiplier
Lenses for Energy
Adjustment
(Retardation)
Lenses for Analysis
Area Definition
Resistive Anode
Encoder
Position Computer
Position Address
Converter
9. Instrumentation
X-ray Source
Monochromatic Al Kα: hv=1486.6 eV and Mg Kα: h
ν= 1253.6 eV
🠶An Ultra High Vacuum (UHV) chamber
(Pressure < 10-9 Torr)
🠶Hemispherical Analyzer
It contain positive charge on inner plate of hemisphere to attract electron and
negative charge on outer plate to repel electron which help to move electron in an
orbit.
Only electrons of certain voltage can allow to pass through plates due to potential
difference
🠶 Data Collection System
(Detector, Analyzer Control and Computer System)
http://www.seallabs.com/how-xps-works.html
cylindrical mirror analyzer
can also be use
10. Sample preparation
Sample preparation is not require usually. We just mount the sample and place it
for analysis
Removal of Volatile Material with the help of pumping or by washing with a
solvent like ethanol.
Removal of Nonvolatile Organic Contaminants by freshly distilled solvents.
Surface Etching (surface contaminants can remove by ion sputtering and other
erosion techniques).
Abrasion cause roughen the surface by grinding up to 600 grade paper. It
increase intensity of signal as compare to smooth surface.
11. XPS peak Elemental Shift
• XPS peak is plotted between No. of electrons (CPS) and B.E.
• Electron-nucleus attraction helps us identify the elements.
• Each element and orbital has different binding energy for each electron
present in it.
• The orbit which are closer to nucleus has high binding energy but low K.E
Elemental Shifts
Binding Energy (eV)
Element 2p3/2 3p
Fe 707 53 654
Co 778 60 718
Ni 853 67 786
Cu 933 75 858
Zn 1022 89 933
12. Chemical Shift
• It occur due to electronegativity difference and bonding of atoms.
• Higher positive oxidation state has high BE due to interaction between emitted
electrons and nucleus.
• Differentiate between different oxidation state and chemical environment is
major use of XPS.
Functional Binding Energy
Group (eV)
hydrocarbon C-H, C-C 285.0
amine C-N 286.0
alcohol, ether C-O-H, C-O-C 286.5
Cl bound to C C-Cl 286.5
F bound to C C-F 287.8
carbonyl C=O 288.0
Polyethylene Terephthalate (PET).
13. XPS Peak - Electronic effect
🠶 The binding energy of core electron not
only depends on the energy shell level
they occupy but also on
n principle quantum number
l orbital angular quantum number
s spin angular quantum number
j total angular quantum number
(j=l+s)
For orbital p
orbital angular quantum number l = 1
Spin angular quantum number s = ± 𝟏/𝟐
total angular quantum number j =𝟏/𝟐, 𝟑/𝟐
Electronic shift
effect also known as
multiplet splitting
14. Surface and bulk investigations of organ metal pipe degradation
Samples of degraded organ pipe are obtain from the Sicily island where aging of
metal alloys are influenced by environment.
These samples are investigated by XPS, EDX and XRD.
Tin and lead are cheap metals, shiny appearance and ductile in nature so use in
organ pipes.
Formation of tin oxide blisters, tin chloride phases and formation of lead nitrate
salts are the types of degradation observe during analysis.
XPS was recorded In order to determine the oxidation states of elements and
their surface atomic concentration were performed on PHI 5600 system using
Al Kα Source.
Binding energies were calculated with respect to C 1s which is ionize at 285 eV.
Because it is generally accepted to be independent of chemical state of the
sample which is under investigation.
15. a
b
The colour of tin is light grey but in several places circular white areas can be
observed. Because of the degradation on the edges of the mouth and it makes
metal brittle.
XPS analysis clearly shows the presence of nitrogen and chlorine in the samples
taken from zone completely degraded.
The XPS atomic concentration of sample a and b contain Sn 34,84%, Cl 35,11%
and O 30,05% respectively .
16. By Antonio Bovelaccia, Enrico Cilibertob, Enrico Grecob, Ezio Viscusob in 2012
www.sciencedirect.com
17. Advantages and Disadvantages
Advantages
Non-destructive technique.
Surface Sensitive (10-100 Å).
Detection unit: ppt and some
conditions ppm.
Quantitative measurements are
obtained.
Provides information about chemical
bonding.
Elemental mapping.
Limitations
Very expensive technique.
High vacuum is required.
Slow processing (1/2 to 8
hours/sample).
Large area analysis is required.
H and He can not be identified.
Data collection is slow 5 to 10 min.
Poor lateral resolution.
18. XPS is used to measure:
Elemental composition of the
surface (top 1–12 nm usually).
Empirical formula of pure materials.
Chemical or electronic state of each
element in the surface.
Uniformity of composition across
the top surface (line profiling).
Uniformity of elemental composition
as a function of ion beam etching
(depth profiling).
Applications in the industry:
Failure analysis
Polymer surface
Corrosion
Adhesion
Semiconductors
Dielectric materials
Thin film coatings
Uses
XPSPEAK 4.1, FitXPS, CasaXPS and
Spectral Data Processor (SDP) V3.0
are the softwares use for XPS analysis
19. References
• http://www.seallabs.com/how-xps-works.html
• http://www.chem.qmul.ac.uk/surfaces/scc/scat5_3.htm
• http://ssrl.slac.stanford.edu/nilssongroup/corelevel.html
• http://goliath.emt.inrs.ca/surfsci/arxps/fundamentalscss.html
• http://www.casaxps.com/help_manual/XPSInformation/XPSInstr.htm
• http://www.lanl.gov/orgs/nmt/nmtdo/AQarchive/04summer/XPS.html
• X-Ray Photoelectron Spectroscopy (XPS) by David Echevarría Torres
• X-RAY PHOTOELECTRON SPECTROSCOPY (XPS) by Yağmur Celasun,Görkem
Erdoğan.Fatma Sırkınti