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New green chemical techniques in textile coloration processes   Dr. Richard S. Blackburn Senior Lecturer and Head of Green Chemistry Group Centre for Technical Textiles UNIVERSITY OF LEEDS, LS2 9JT, UK [email_address]
Where can Green Chemistry have an impact in Coloration? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Sustainable platform chemicals ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Sustainable platform chemicals ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Sustainable platform chemicals ,[object Object],[object Object],Table: The effect of pH on solubility and colour of alizarin and 1H2EA insoluble no colour v. sparingly soluble no colour 4 insoluble no colour soluble purple colour 10 insoluble no colour sparingly soluble orange/yellow colour 7 1H2EA Alizarin pH
Sustainable platform chemicals ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Table: Colour strength (K/S) values of dyed samples   20.9   19.2 4% omf at 130 °C 10.6   2.2   4% omf at 115 °C   8.7   6.5 1% omf at 130 °C 5.1 4.3 2.1 3.1 1% omf at 100 °C 4.3   1.5   1% omf at 90 °C PLA PET PLA PET 1H2EA Alizarin Conditions of application
 
Sustainable platform chemicals ,[object Object],[object Object],[object Object],[object Object],Table: Light fastness of dyed samples (1-8 scale)   6   5 4% omf at 130 °C 6   3/4 4% omf at 115 °C   6   4 1% omf at 130 °C 5/6 6 3 3 1% omf at 100 °C 5   3   1% omf at 90 °C PLA PET PLA PET 1H2EA Alizarin Conditions of application
Green Chemistry Sulphur Dyeing ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Mechanism of sulphur dyeing ,[object Object],[object Object],[object Object],[object Object]
Reducing agents in sulphur dyeing ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Alternative reducing agents ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Application of various reducing  D -sugars ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Blackburn, R. S.; Harvey, A.  Env. Sci. Technol.   2004 ,  38  (14), 4034.
D -arabinose D (-)-fructose D (+)-galactose α - D -glucose
D -maltose β - D -lactose
Environmental and economical considerations Relative theoretical COD and price of reducing agents per kg dyed cotton a  Based on 2.5 g dm -3  reducing agent (typical optimum concentration) at a liquor ratio of 25:1 4.30 70.1 D -maltose 2.08 70.1 β- D -lactose 0.58 66.6 α- D -glucose 4.14 66.6 D (+)-galactose 1.65 66.6 D (-)-fructose 28.06 66.6 D -arabinose 1.18 71.3 sodium hydrosulfide 1.60 51.3 sodium sulfide £ kg -1  dyed cotton a g O 2  kg -1  dyed cotton a Reducing agent
Greener reactive dyeing of cellulose ,[object Object],[object Object],[object Object],[object Object],[object Object]
Problems with high electrolyte concentration ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Mechanism of reactive dye fixation to cellulose (Nucleophilic substitution)
Mechanism of reactive dye fixation to cellulose (Michael Addition)
Colour (unfixed dye) in effluent ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
High water consumption ,[object Object],[object Object],[object Object],[object Object],[object Object]
Pre-treatment agents Copolymer of diallyldimethylammonium chloride and 3-aminoprop-1-ene (PT1) Copolymer of 4-vinylpyridine quaternised with 1-amino-2-chloroethane (PT2)
High substantivity of pre-treatments for cotton ,[object Object],[object Object],[object Object],[object Object],[object Object]
PT1 Conformational interaction between PT1 and cellulose
PT2 ,[object Object],[object Object]
Mechanism of operation (schematic)
Advantages of pre-treatment system ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
System comparison pre-treatment (10), detergent (20) 0 0 0 50 195 1 Pre-treatment acetic acid (60), detergent (20) 500 1500 0 125 295 5 Cibacron F detergent (20) 500 0 1625 105 365 4 Procion H-EXL acetic acid (60), detergent (20) 500 1250   0   145   355   6 Remazol RR Other Chemicals (g/kg fabric)   Na 2 CO 3 (g/kg fabric)   Na 2 SO 4 (g/kg fabric)   NaCl (g/kg fabric)   Water ( ℓ /kg fabric)   Time (mins)   Wash-off stages Procedure
Publications ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
DyeCat Ltd. ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],©DyeCat 2006
DyeCat Technology ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],©DyeCat 2006
Contacts ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],©DyeCat 2006
Acknowledgements ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]

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Wun Presentation

  • 1. New green chemical techniques in textile coloration processes Dr. Richard S. Blackburn Senior Lecturer and Head of Green Chemistry Group Centre for Technical Textiles UNIVERSITY OF LEEDS, LS2 9JT, UK [email_address]
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  • 14. D -arabinose D (-)-fructose D (+)-galactose α - D -glucose
  • 15. D -maltose β - D -lactose
  • 16. Environmental and economical considerations Relative theoretical COD and price of reducing agents per kg dyed cotton a Based on 2.5 g dm -3 reducing agent (typical optimum concentration) at a liquor ratio of 25:1 4.30 70.1 D -maltose 2.08 70.1 β- D -lactose 0.58 66.6 α- D -glucose 4.14 66.6 D (+)-galactose 1.65 66.6 D (-)-fructose 28.06 66.6 D -arabinose 1.18 71.3 sodium hydrosulfide 1.60 51.3 sodium sulfide £ kg -1 dyed cotton a g O 2 kg -1 dyed cotton a Reducing agent
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  • 19. Mechanism of reactive dye fixation to cellulose (Nucleophilic substitution)
  • 20. Mechanism of reactive dye fixation to cellulose (Michael Addition)
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  • 23. Pre-treatment agents Copolymer of diallyldimethylammonium chloride and 3-aminoprop-1-ene (PT1) Copolymer of 4-vinylpyridine quaternised with 1-amino-2-chloroethane (PT2)
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  • 25. PT1 Conformational interaction between PT1 and cellulose
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  • 27. Mechanism of operation (schematic)
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  • 29. System comparison pre-treatment (10), detergent (20) 0 0 0 50 195 1 Pre-treatment acetic acid (60), detergent (20) 500 1500 0 125 295 5 Cibacron F detergent (20) 500 0 1625 105 365 4 Procion H-EXL acetic acid (60), detergent (20) 500 1250 0 145 355 6 Remazol RR Other Chemicals (g/kg fabric) Na 2 CO 3 (g/kg fabric) Na 2 SO 4 (g/kg fabric) NaCl (g/kg fabric) Water ( ℓ /kg fabric) Time (mins) Wash-off stages Procedure
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