Proper dental care for infants begins with the appearance of the first tooth, and it is important to clean gums even before teeth emerge. Care guidelines include using a clean washcloth, a fluoride toothpaste the size of a grain of rice, and supervising brushing to prevent swallowing toothpaste. Additionally, avoiding prolonged bottle feeding can prevent tooth decay known as 'bottle mouth' and promoting the use of sippy cups around six months can help protect the teeth.