Abstract: The viscoelastic response of polymeric solids to sliding contact conditions
is observed and analyzed with respect to the sliding speed, material composition,
and geometry. It was discovered that polymeric solids produced their own distinct
viscoelastic signatures that cause resonance at certain sliding speeds which can be
explained with resonance conditions for electromagnetic waves. The observed viscolelastic phenomenon is characterized with respect to the relaxation and recovery
times for rigid polymeric solids. It is confirmatory as a demonstration of proof of
existence of viscoelasticity and self-organization in these materials under sliding contact conditions. Viscoelastic observations are also made on the aged specimens in
sliding contact.
Viscoelastic response of polymeric solids to sliding contactsPadmanabhan Krishnan
A polymeric solid is seen to produce its own signatures in sliding contacts. This has immense applications. The viscoelastic phenomena and signatures are discussed with the relevant models.
Effect of fibers on Hybrid Matrix CompositesIJERA Editor
This document summarizes a study on the effect of fibers on hybrid matrix composites. The study examined the impact strength, frictional coefficient, dielectric strength, and chemical resistance of bamboo/glass fiber reinforced epoxy hybrid composites. It found that impact strength and frictional coefficient increased with higher glass fiber content. Properties were also higher when alkali-treated bamboo fibers were used. Dielectric strength was found to increase for all composites except those exposed to carbon tetrachloride. Scanning electron microscopy revealed improved bonding between fibers for alkali-treated composites compared to untreated ones. The removal of hemicellulose through alkali treatment led to higher fiber crystallinity and better fiber-matrix bonding.
This document summarizes an experimental investigation into the reinforcement of metal matrix composites with multiwalled carbon nanotubes to improve fatigue life. Glass fiber composites currently have high strength but poor fatigue performance due to matrix cracking. The study found that adding only 1% of carbon nanotubes by weight significantly increased the high-cycle fatigue life of glass fiber composites. Carbon nanotubes were found to inhibit crack formation and growth by nucleating many nano-scale damage zones. Energy absorption also increased through nanotube pullout and fracture. An energy-based model was proposed to explain the fatigue life improvement from additional strain energy absorption in the composite.
New Technique for Measuring and Controlling the Permeability of Polymeric Mem...Editor IJCATR
Membranes have wide uses in industry and medicine applications. Polymer membranes are important materials because of their high chemical resistance, but they are of weak mechanical resistance against high pressures. Therefore, it was essential to modify a permeability measuring technique free from high pressure application. The current work represented a modification for the permeability measuring technique of membranes, where ionic salt was added with known concentration to water as common solvent and the electrolyte current was measured behind the membrane. The electrolysis current was correlated to the flow rate of water across a polyvinyl alcohol (PVA) membrane. Some other problems were raised such that polarization on electrodes and changes in electrolyte contents during the long time of the slow process. Pulsed potential on electrodes resolved these problems and other associated problems like rush in current and the double layer capacitance effect. An empirical equation was suggested to evaluate the permeability of polymer membranes by this modified method. Easy and accurate measurement of permeability helped authors to change the permeability of PVA membranes by adding copper nano particles in membrane to reduce its permeability, and adding silicone dioxide micro particles to the PVA membranes to increase its permeability. Authors suggested a mechanism for these permeability changes. Scanning electron microscope images for the filled PVA membranes supported the suggested mechanism.
New Technique for Measuring and Controlling the Permeability of Polymeric Mem...Editor IJCATR
Membranes have wide uses in industry and medicine applications. Polymer membranes are important materials
because of their high chemical resistance, but they are of weak mechanical resistance against high pressures. Therefore, it was
essential to modify a permeability measuring technique free from high pressure application. The current work represented a
modification for the permeability measuring technique of membranes, where ionic salt was added with known concentration
to water as common solvent and the electrolyte current was measured behind the membrane. The electrolysis current was
correlated to the flow rate of water across a polyvinyl alcohol (PVA) membrane. Some other problems were raised such that
polarization on electrodes and changes in electrolyte contents during the long time of the slow process. Pulsed potential on
electrodes resolved these problems and other associated problems like rush in current and the double layer capacitance effect.
An empirical equation was suggested to evaluate the permeability of polymer membranes by this modified method. Easy and
accurate measurement of permeability helped authors to change the permeability of PVA membranes by adding copper nano
particles in membrane to reduce its permeability, and adding silicone dioxide micro particles to the PVA membranes to
increase its permeability. Authors suggested a mechanism for these permeability changes. Scanning electron microscope
images for the filled PVA membranes supported the suggested mechanism
Developments of nano clay particle reinforced plastics are of growing interest towards the
emergence of new materials which enhance optimal utilization of natural resources and particularly of
renewable resources. The effects of nano clay as filler in Basalt–epoxy composite systems on the
tribological properties have been discussed in this article. Basalt fiber reinforced epoxy (BE) composite
finds widespread application in erosive environment due to its several advantages like high wear
resistance, high strength-to-weight ratio and low cost. Experiments were carried out to study the effects
of impingement angle, particle velocity and filler material on the solid particle erosive wear behavior of
BE composite. The erosive wear is evaluated at different impingement angles from 30° to 90° at three
different velocities of 23, 42, & 60 m/s. The erodent used is silica sand with the size range (150 – 280 µm)
of irregular shape. The result shows semi-ductile behavior with maximum erosion rate at 60°
impingement angle. It is observed that wear rate increases with increasing particle velocity and
decreases with increases of filler percentage. The morphology of the eroded surfaces was examined by
using Scanning electron microscopy (SEM).
FRACTURE MECHANICS OF NANO-SILICA PARTICLES IN REINFORCED EPOXIES Jordan Suls
This document summarizes a study that used finite element modeling to examine how different levels of particle dispersion (evenly dispersed, moderately clumped, and severely clumped) affect the fracture mechanics of nanosilica particle reinforced epoxies. Three models were created in Abaqus with the different dispersion levels and subjected to tensile loading. The results found that the evenly dispersed model had the highest fracture toughness, as indicated by its ability to withstand a greater force at similar displacements. This was because the clumped models developed large stress regions around the clumps that caused earlier debonding of the particle-matrix interfaces and faster crack propagation.
Viscoelastic response of polymeric solids to sliding contactsPadmanabhan Krishnan
A polymeric solid is seen to produce its own signatures in sliding contacts. This has immense applications. The viscoelastic phenomena and signatures are discussed with the relevant models.
Effect of fibers on Hybrid Matrix CompositesIJERA Editor
This document summarizes a study on the effect of fibers on hybrid matrix composites. The study examined the impact strength, frictional coefficient, dielectric strength, and chemical resistance of bamboo/glass fiber reinforced epoxy hybrid composites. It found that impact strength and frictional coefficient increased with higher glass fiber content. Properties were also higher when alkali-treated bamboo fibers were used. Dielectric strength was found to increase for all composites except those exposed to carbon tetrachloride. Scanning electron microscopy revealed improved bonding between fibers for alkali-treated composites compared to untreated ones. The removal of hemicellulose through alkali treatment led to higher fiber crystallinity and better fiber-matrix bonding.
This document summarizes an experimental investigation into the reinforcement of metal matrix composites with multiwalled carbon nanotubes to improve fatigue life. Glass fiber composites currently have high strength but poor fatigue performance due to matrix cracking. The study found that adding only 1% of carbon nanotubes by weight significantly increased the high-cycle fatigue life of glass fiber composites. Carbon nanotubes were found to inhibit crack formation and growth by nucleating many nano-scale damage zones. Energy absorption also increased through nanotube pullout and fracture. An energy-based model was proposed to explain the fatigue life improvement from additional strain energy absorption in the composite.
New Technique for Measuring and Controlling the Permeability of Polymeric Mem...Editor IJCATR
Membranes have wide uses in industry and medicine applications. Polymer membranes are important materials because of their high chemical resistance, but they are of weak mechanical resistance against high pressures. Therefore, it was essential to modify a permeability measuring technique free from high pressure application. The current work represented a modification for the permeability measuring technique of membranes, where ionic salt was added with known concentration to water as common solvent and the electrolyte current was measured behind the membrane. The electrolysis current was correlated to the flow rate of water across a polyvinyl alcohol (PVA) membrane. Some other problems were raised such that polarization on electrodes and changes in electrolyte contents during the long time of the slow process. Pulsed potential on electrodes resolved these problems and other associated problems like rush in current and the double layer capacitance effect. An empirical equation was suggested to evaluate the permeability of polymer membranes by this modified method. Easy and accurate measurement of permeability helped authors to change the permeability of PVA membranes by adding copper nano particles in membrane to reduce its permeability, and adding silicone dioxide micro particles to the PVA membranes to increase its permeability. Authors suggested a mechanism for these permeability changes. Scanning electron microscope images for the filled PVA membranes supported the suggested mechanism.
New Technique for Measuring and Controlling the Permeability of Polymeric Mem...Editor IJCATR
Membranes have wide uses in industry and medicine applications. Polymer membranes are important materials
because of their high chemical resistance, but they are of weak mechanical resistance against high pressures. Therefore, it was
essential to modify a permeability measuring technique free from high pressure application. The current work represented a
modification for the permeability measuring technique of membranes, where ionic salt was added with known concentration
to water as common solvent and the electrolyte current was measured behind the membrane. The electrolysis current was
correlated to the flow rate of water across a polyvinyl alcohol (PVA) membrane. Some other problems were raised such that
polarization on electrodes and changes in electrolyte contents during the long time of the slow process. Pulsed potential on
electrodes resolved these problems and other associated problems like rush in current and the double layer capacitance effect.
An empirical equation was suggested to evaluate the permeability of polymer membranes by this modified method. Easy and
accurate measurement of permeability helped authors to change the permeability of PVA membranes by adding copper nano
particles in membrane to reduce its permeability, and adding silicone dioxide micro particles to the PVA membranes to
increase its permeability. Authors suggested a mechanism for these permeability changes. Scanning electron microscope
images for the filled PVA membranes supported the suggested mechanism
Developments of nano clay particle reinforced plastics are of growing interest towards the
emergence of new materials which enhance optimal utilization of natural resources and particularly of
renewable resources. The effects of nano clay as filler in Basalt–epoxy composite systems on the
tribological properties have been discussed in this article. Basalt fiber reinforced epoxy (BE) composite
finds widespread application in erosive environment due to its several advantages like high wear
resistance, high strength-to-weight ratio and low cost. Experiments were carried out to study the effects
of impingement angle, particle velocity and filler material on the solid particle erosive wear behavior of
BE composite. The erosive wear is evaluated at different impingement angles from 30° to 90° at three
different velocities of 23, 42, & 60 m/s. The erodent used is silica sand with the size range (150 – 280 µm)
of irregular shape. The result shows semi-ductile behavior with maximum erosion rate at 60°
impingement angle. It is observed that wear rate increases with increasing particle velocity and
decreases with increases of filler percentage. The morphology of the eroded surfaces was examined by
using Scanning electron microscopy (SEM).
FRACTURE MECHANICS OF NANO-SILICA PARTICLES IN REINFORCED EPOXIES Jordan Suls
This document summarizes a study that used finite element modeling to examine how different levels of particle dispersion (evenly dispersed, moderately clumped, and severely clumped) affect the fracture mechanics of nanosilica particle reinforced epoxies. Three models were created in Abaqus with the different dispersion levels and subjected to tensile loading. The results found that the evenly dispersed model had the highest fracture toughness, as indicated by its ability to withstand a greater force at similar displacements. This was because the clumped models developed large stress regions around the clumps that caused earlier debonding of the particle-matrix interfaces and faster crack propagation.
Investigation on the behaviour of alfa composite in pre and post heat treated...eSAT Journals
Abstract
Of the many types of particulate reinforcements fly ash is one type that is being used from the recent past to develop the composites. In the current research fly ash is reinforced in the aluminium alloy AA2024 to develop ALFA (ALuminium Fly Ash) composites. The stir casting technique is employed in the development of the said composite as this technique is economical and would produce a composite with fairly uniform distribution of the fly ash reinforcement in the alloy matrix. The fly ash was added in 2.5 and 5% by weight to the molten metal. Increase in the percentage weight of fly ash reinforcement resulted improvement in the mechanical properties. The composite is tested for hardness, tensile strength and wear performance under pre-heat treatment, as quenched and in peak hardened conditions. The peak hardened composite showed a superior hardness, tensile strength and wear resistance than the others.
Keywords: stir casting, fly ash composites, heat treatment, and characterization
Experimental Study of the Fatigue Strength of Glass fiber epoxy and Chapstan ...IJMER
1) The document describes an experimental study of the fatigue strength of two types of fiber-reinforced epoxy composite laminates: glass fiber epoxy and E-glass epoxy.
2) The study developed a fatigue testing rig to apply cyclic bending loads to composite beam specimens and measure the resulting stiffness degradation over cycles until failure.
3) The testing rig incorporated a load cell, data acquisition system, and software to automatically record measurements over millions of load cycles and analyze the failure behavior and fatigue life of the composite laminates.
To ensure good adhesion between a 200 nm thick silicon dioxide layer and a 4.5 μm thick hardcoat polymeric coating, a better understanding of mechanisms of adhesion at this interface is needed. To reach this purpose, focus is placed on two axes: characterizing mechanical properties of materials composing the system and in parallel, finding an applicable and effective method to quantify adhesion. Small dimension of SiO2 thin film makes it challenging to accurately characterize it. Hence the use of both nano-indentation and AFM to attempt assessment of SiO2 thin film elastic modulus Ef; taking into account limitations and uncertainty associated with each technique. Elastic modulus of SiO2 thin film determined by nano-indentation is roughly 50 GPa on a wafer substrate and 15 GPa on a lens substrate. As for AFM, modulus measured is approximately 56 GPa on a wafer substrate and 22 GPa on a lens substrate. This highlights significant influence of substrate for both techniques. Impact on mechanical properties between SiO2 thin films under different intrinsic stresses was also investigated. Results suggest that higher density of SiO2 thin film leads to higher elastic modulus.
To quantify adhesion, micro-tensile and micro-compression tests were performed. Micro-tensile experiments give ultimate shear strengths of hardcoat-substrate interface ranging from 9 to 14 MPa. Values of energy release rates of SiO2 / Hardcoat, range from 0.1 J/m² to 0.5 J/m², depending on moduli values found on wafer or lens substrate.
Investigation on 3-body abrasive behaviour of glass fiber and ramie fiber rei...IRJET Journal
This document summarizes an investigation into the three-body abrasive wear behavior of glass fiber and ramie fiber reinforced epoxy hybrid composites. Hybrid composites with varying proportions of glass and ramie fibers were manufactured using hand layup and tested for three-body abrasive wear under different parameters. The optimal parameters that resulted in the lowest wear rate were found to be A3 (30% ramie), B1 (580g load), and C2 (2000m sliding distance). Sliding distance was the most significant influencing factor on wear, followed by load, while fiber proportion was the least influencing. SEM analysis showed micro-plucking, micro-cutting and micro-cracks on worn surfaces. The Ra10
International Journal of Computational Engineering Research(IJCER)ijceronline
International Journal of Computational Engineering Research(IJCER) is an intentional online Journal in English monthly publishing journal. This Journal publish original research work that contributes significantly to further the scientific knowledge in engineering and Technology.
MECHANICAL & THERMAL PROPERTIES OF NANO COMPOSITESArjun K Gopi
This document discusses the mechanical and thermal properties of polymer nanocomposites. It explains that polymer nanocomposites consist of a polymer matrix reinforced with nanoparticles, which have high surface area. This results in enhanced bonding between the polymer and nanoparticles. As a result, polymer nanocomposites often demonstrate improved mechanical properties over micro-composites, such as increased elastic modulus. A key factor influencing the mechanical properties is the interphase layer that forms between the polymer matrix and nanoparticles. The properties of this interphase region, which can differ from the bulk materials, largely determine how stress is transferred between phases. Several experimental techniques for characterizing the structure and properties of polymer nanocomposites are described, including tensile testing,
Preparation and characterisation of alumina nanocomposites with aramid fibre ...eSAT Journals
This document summarizes research on preparing and characterizing alumina nanocomposites with aramid fibre and hybrid fibre reinforcements. Alumina nanoparticles were dispersed in epoxy resin to create nanocomposites. Aramid fibre, carbon fibre, and hybrid carbon-aramid fibre laminates were produced from these epoxy-alumina nanocomposites. Mechanical testing showed improved tensile strength and flexural strength with the addition of alumina nanoparticles and with hybrid or aramid fibre reinforcement compared to plain epoxy composites. Impact strength did not significantly differ between materials with and without nanoparticles. The research demonstrated enhanced mechanical properties from adding alumina nanoparticles and different fibre reinforcements to epoxy resin composites
This document discusses the design and analysis of a composite bolt made of glass fiber and epoxy resin. It begins with an abstract that outlines the objectives of creating a low-cost composite bolt using glass fiber reinforcement in an epoxy matrix. It then reviews previous literature on composite materials and bolted joints, which found that addition of glass fibers increases strength and stiffness. The document describes the materials and methods used, including hand lay-up of epoxy resin reinforced with glass fibers. It presents results of testing the composite bolts and comparing the mechanical properties of unidirectional and bidirectional fiber orientations.
An Experimental Analysis to Determine Ultimate Tensile Strength of Jute Reinf...IJSRD
From past few decades, there is been substantial growth and development in field of Composites. Advanced materials and Composites are being used in almost every industry in some form or the other. Composites have found wider applicability and liking in designing industries. This has triggered researchers towards this emerging technology. Jute reinforced composites may be used in combination with biodegradable polymer or to replace conventional glass fibre reinforced composites. In this case, the main concern is their impact resistance. The production of hybrid laminates by coupling layers of glass fibre reinforced with jute reinforced laminates, proved also effective to improve the mechanical characteristics. In recent years, a number of studies have been carried out, aimed to compare properties of jute fibre reinforced laminates. This project studies Mechanical properties of Jute Reinforced Glass Fibre Composite by Acousto-Ultrasonic Technique. The specimens were tested for UTS on UTM and the correlation factors were determined by comparing SWF (Stress Wave Factors) and UTS. The comparative analyses are presented in results.
Comparison and Optimization of Wear Rates of Two Types of Dental Composites O...inventionjournals
International Journal of Engineering and Science Invention (IJESI) is an international journal intended for professionals and researchers in all fields of computer science and electronics. IJESI publishes research articles and reviews within the whole field Engineering Science and Technology, new teaching methods, assessment, validation and the impact of new technologies and it will continue to provide information on the latest trends and developments in this ever-expanding subject. The publications of papers are selected through double peer reviewed to ensure originality, relevance, and readability. The articles published in our journal can be accessed online.
This document summarizes research on incorporating polyamide 6 nanofibrous structures into glass fiber-reinforced epoxy composites to improve their mechanical properties. Experiments showed that the nanofibers had a catalytic effect on the curing of the epoxy resin, lowering its activation energy. Composites with nanofibers deposited on or between fiber layers showed increased stress at failure compared to a control without nanofibers. The deposited nanofibers in particular improved load transfer to the glass fibers. While nanofibers did not significantly increase modulus, their inclusion helped prevent delamination cracks in the composites. The research demonstrates that nanofibers can enhance some mechanical properties of glass fiber-ep
Nacre, found in mollusk shells, has ballistic resistant properties that make it suitable for coating wires. It has a layered structure of brittle aragonite plates separated by elastic biopolymer sheets. This gives it high strength and toughness.
Testing found that nacre has a bending strength of 4.3-5.8 MPa√m, tensile strength of 65 MPa, compressive strength over 370 MPa, and hardness ranging from 0.69-18.32 GPa depending on the applied load. Its fracture toughness is higher when hydrated. Shear testing measured an interfacial shear strength between plates of 36.9 MPa. Nacre's layered structure and interaction
1) The document investigates the effect of stacking sequence and hybridization on the tensile and flexural properties of composites made from basalt, jute, flax, and E-glass fibers reinforced with epoxy resin.
2) It was found that stacking sequence had little effect on tensile properties but a significant effect on flexural strength and modulus, with a sandwich-like sequence performing better.
3) Hybrid composites containing E-glass and basalt fibers had the highest specific tensile strength and modulus. E-glass/basalt performed better than E-glass/jute and E-glass/flax combinations in terms of strength to weight ratio.
1) The document investigates the effect of low-velocity impact and fatigue loading on woven glass fiber/epoxy composite laminates of different thicknesses (2mm and 4mm).
2) Specimens were subjected to low-velocity impact testing at different energy levels. Impacted specimens and non-impacted specimens were then subjected to tension-tension fatigue testing.
3) Results showed that impact velocity significantly influenced the fatigue life of composite laminates. The 2mm thick impacted laminates saw a drastic reduction in fatigue life compared to the 4mm laminates.
EFFECT OF NANO RUBBER ADDITIONS ON WEAR AND MECHANICAL PROPERTIES OF EPOXY GL...paperpublications3
Abstract: The use of polymer fiber reinforced composite materials is growing day by day in all types of engineering structures such as aerospace, automotive, aircraft, chemical, constructions etc. because of their tailorable properties. Through these materials are tailorable, improvement in tribological properties is demanded.Keywords:epoxy glass fiber composites, nano nitrile butadiene rubber particles.
A Study of Failure Criteria of Fibrous Composite Material...sudhakargeruganti
This research proposal aims to study the failure criteria of fibrous composite materials. The researcher will evaluate existing composite failure criteria in finite element analysis software and explore modifications to account for large deformations, progressive failure, and stress-strain interactions. Several composite failure theories will be presented and their advantages/limitations in modeling laminate failure will be discussed. Experimental testing will be conducted to validate the analysis results. The research intends to improve understanding and modeling of failure in fibrous composites.
This document summarizes an experimental study on the flexural fatigue behavior of carbon/epoxy angle ply laminates. Flexural fatigue tests were conducted on laminate composites with different fiber orientations: [00]4, [±450]4, [±550]4, and [00, 900]4. The tests measured the stiffness degradation of the laminates as a function of the number of load cycles applied. The results showed that stiffness reduced rapidly at first as the top and bottom layers were damaged, then the rate of reduction slowed as a "pivoting effect" limited further damage. Numerical models were able to describe the stiffness degradation curves.
International Journal of Engineering Research and DevelopmentIJERD Editor
Electrical, Electronics and Computer Engineering,
Information Engineering and Technology,
Mechanical, Industrial and Manufacturing Engineering,
Automation and Mechatronics Engineering,
Material and Chemical Engineering,
Civil and Architecture Engineering,
Biotechnology and Bio Engineering,
Environmental Engineering,
Petroleum and Mining Engineering,
Marine and Agriculture engineering,
Aerospace Engineering.
Stability Analysis of Journal Bearing Using Electro Rheological Fluid by Fini...ijsrd.com
in rotating machinery, the damping of structure which supports the rotating shaft has significant effect in machine vibration. Therefore by controlling the lubricant properties, the dynamic behavior of the system can be controlled. The objective of this paper is to study the dynamic behavior of a rotor supported by a journal bearing and fed with Electro-rheological (ER) fluid. ER fluids can be used to create ‘smart’ journal bearings & vibration controllers can be constructed to control the Stability of the ER fluid lubricated bearings. The ER fluid behaves like a Bingham fluid with a higher viscosity when electric field is applied, and restores its property when the field is removed. A reversible change in viscosity occurs in milliseconds with the electric field applied.
Using recycled concrete aggregates (RCA) for pavements is crucial to achieving sustainability. Implementing RCA for new pavement can minimize carbon footprint, conserve natural resources, reduce harmful emissions, and lower life cycle costs. Compared to natural aggregate (NA), RCA pavement has fewer comprehensive studies and sustainability assessments.
More Related Content
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Investigation on the behaviour of alfa composite in pre and post heat treated...eSAT Journals
Abstract
Of the many types of particulate reinforcements fly ash is one type that is being used from the recent past to develop the composites. In the current research fly ash is reinforced in the aluminium alloy AA2024 to develop ALFA (ALuminium Fly Ash) composites. The stir casting technique is employed in the development of the said composite as this technique is economical and would produce a composite with fairly uniform distribution of the fly ash reinforcement in the alloy matrix. The fly ash was added in 2.5 and 5% by weight to the molten metal. Increase in the percentage weight of fly ash reinforcement resulted improvement in the mechanical properties. The composite is tested for hardness, tensile strength and wear performance under pre-heat treatment, as quenched and in peak hardened conditions. The peak hardened composite showed a superior hardness, tensile strength and wear resistance than the others.
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Experimental Study of the Fatigue Strength of Glass fiber epoxy and Chapstan ...IJMER
1) The document describes an experimental study of the fatigue strength of two types of fiber-reinforced epoxy composite laminates: glass fiber epoxy and E-glass epoxy.
2) The study developed a fatigue testing rig to apply cyclic bending loads to composite beam specimens and measure the resulting stiffness degradation over cycles until failure.
3) The testing rig incorporated a load cell, data acquisition system, and software to automatically record measurements over millions of load cycles and analyze the failure behavior and fatigue life of the composite laminates.
To ensure good adhesion between a 200 nm thick silicon dioxide layer and a 4.5 μm thick hardcoat polymeric coating, a better understanding of mechanisms of adhesion at this interface is needed. To reach this purpose, focus is placed on two axes: characterizing mechanical properties of materials composing the system and in parallel, finding an applicable and effective method to quantify adhesion. Small dimension of SiO2 thin film makes it challenging to accurately characterize it. Hence the use of both nano-indentation and AFM to attempt assessment of SiO2 thin film elastic modulus Ef; taking into account limitations and uncertainty associated with each technique. Elastic modulus of SiO2 thin film determined by nano-indentation is roughly 50 GPa on a wafer substrate and 15 GPa on a lens substrate. As for AFM, modulus measured is approximately 56 GPa on a wafer substrate and 22 GPa on a lens substrate. This highlights significant influence of substrate for both techniques. Impact on mechanical properties between SiO2 thin films under different intrinsic stresses was also investigated. Results suggest that higher density of SiO2 thin film leads to higher elastic modulus.
To quantify adhesion, micro-tensile and micro-compression tests were performed. Micro-tensile experiments give ultimate shear strengths of hardcoat-substrate interface ranging from 9 to 14 MPa. Values of energy release rates of SiO2 / Hardcoat, range from 0.1 J/m² to 0.5 J/m², depending on moduli values found on wafer or lens substrate.
Investigation on 3-body abrasive behaviour of glass fiber and ramie fiber rei...IRJET Journal
This document summarizes an investigation into the three-body abrasive wear behavior of glass fiber and ramie fiber reinforced epoxy hybrid composites. Hybrid composites with varying proportions of glass and ramie fibers were manufactured using hand layup and tested for three-body abrasive wear under different parameters. The optimal parameters that resulted in the lowest wear rate were found to be A3 (30% ramie), B1 (580g load), and C2 (2000m sliding distance). Sliding distance was the most significant influencing factor on wear, followed by load, while fiber proportion was the least influencing. SEM analysis showed micro-plucking, micro-cutting and micro-cracks on worn surfaces. The Ra10
International Journal of Computational Engineering Research(IJCER)ijceronline
International Journal of Computational Engineering Research(IJCER) is an intentional online Journal in English monthly publishing journal. This Journal publish original research work that contributes significantly to further the scientific knowledge in engineering and Technology.
MECHANICAL & THERMAL PROPERTIES OF NANO COMPOSITESArjun K Gopi
This document discusses the mechanical and thermal properties of polymer nanocomposites. It explains that polymer nanocomposites consist of a polymer matrix reinforced with nanoparticles, which have high surface area. This results in enhanced bonding between the polymer and nanoparticles. As a result, polymer nanocomposites often demonstrate improved mechanical properties over micro-composites, such as increased elastic modulus. A key factor influencing the mechanical properties is the interphase layer that forms between the polymer matrix and nanoparticles. The properties of this interphase region, which can differ from the bulk materials, largely determine how stress is transferred between phases. Several experimental techniques for characterizing the structure and properties of polymer nanocomposites are described, including tensile testing,
Preparation and characterisation of alumina nanocomposites with aramid fibre ...eSAT Journals
This document summarizes research on preparing and characterizing alumina nanocomposites with aramid fibre and hybrid fibre reinforcements. Alumina nanoparticles were dispersed in epoxy resin to create nanocomposites. Aramid fibre, carbon fibre, and hybrid carbon-aramid fibre laminates were produced from these epoxy-alumina nanocomposites. Mechanical testing showed improved tensile strength and flexural strength with the addition of alumina nanoparticles and with hybrid or aramid fibre reinforcement compared to plain epoxy composites. Impact strength did not significantly differ between materials with and without nanoparticles. The research demonstrated enhanced mechanical properties from adding alumina nanoparticles and different fibre reinforcements to epoxy resin composites
This document discusses the design and analysis of a composite bolt made of glass fiber and epoxy resin. It begins with an abstract that outlines the objectives of creating a low-cost composite bolt using glass fiber reinforcement in an epoxy matrix. It then reviews previous literature on composite materials and bolted joints, which found that addition of glass fibers increases strength and stiffness. The document describes the materials and methods used, including hand lay-up of epoxy resin reinforced with glass fibers. It presents results of testing the composite bolts and comparing the mechanical properties of unidirectional and bidirectional fiber orientations.
An Experimental Analysis to Determine Ultimate Tensile Strength of Jute Reinf...IJSRD
From past few decades, there is been substantial growth and development in field of Composites. Advanced materials and Composites are being used in almost every industry in some form or the other. Composites have found wider applicability and liking in designing industries. This has triggered researchers towards this emerging technology. Jute reinforced composites may be used in combination with biodegradable polymer or to replace conventional glass fibre reinforced composites. In this case, the main concern is their impact resistance. The production of hybrid laminates by coupling layers of glass fibre reinforced with jute reinforced laminates, proved also effective to improve the mechanical characteristics. In recent years, a number of studies have been carried out, aimed to compare properties of jute fibre reinforced laminates. This project studies Mechanical properties of Jute Reinforced Glass Fibre Composite by Acousto-Ultrasonic Technique. The specimens were tested for UTS on UTM and the correlation factors were determined by comparing SWF (Stress Wave Factors) and UTS. The comparative analyses are presented in results.
Comparison and Optimization of Wear Rates of Two Types of Dental Composites O...inventionjournals
International Journal of Engineering and Science Invention (IJESI) is an international journal intended for professionals and researchers in all fields of computer science and electronics. IJESI publishes research articles and reviews within the whole field Engineering Science and Technology, new teaching methods, assessment, validation and the impact of new technologies and it will continue to provide information on the latest trends and developments in this ever-expanding subject. The publications of papers are selected through double peer reviewed to ensure originality, relevance, and readability. The articles published in our journal can be accessed online.
This document summarizes research on incorporating polyamide 6 nanofibrous structures into glass fiber-reinforced epoxy composites to improve their mechanical properties. Experiments showed that the nanofibers had a catalytic effect on the curing of the epoxy resin, lowering its activation energy. Composites with nanofibers deposited on or between fiber layers showed increased stress at failure compared to a control without nanofibers. The deposited nanofibers in particular improved load transfer to the glass fibers. While nanofibers did not significantly increase modulus, their inclusion helped prevent delamination cracks in the composites. The research demonstrates that nanofibers can enhance some mechanical properties of glass fiber-ep
Nacre, found in mollusk shells, has ballistic resistant properties that make it suitable for coating wires. It has a layered structure of brittle aragonite plates separated by elastic biopolymer sheets. This gives it high strength and toughness.
Testing found that nacre has a bending strength of 4.3-5.8 MPa√m, tensile strength of 65 MPa, compressive strength over 370 MPa, and hardness ranging from 0.69-18.32 GPa depending on the applied load. Its fracture toughness is higher when hydrated. Shear testing measured an interfacial shear strength between plates of 36.9 MPa. Nacre's layered structure and interaction
1) The document investigates the effect of stacking sequence and hybridization on the tensile and flexural properties of composites made from basalt, jute, flax, and E-glass fibers reinforced with epoxy resin.
2) It was found that stacking sequence had little effect on tensile properties but a significant effect on flexural strength and modulus, with a sandwich-like sequence performing better.
3) Hybrid composites containing E-glass and basalt fibers had the highest specific tensile strength and modulus. E-glass/basalt performed better than E-glass/jute and E-glass/flax combinations in terms of strength to weight ratio.
1) The document investigates the effect of low-velocity impact and fatigue loading on woven glass fiber/epoxy composite laminates of different thicknesses (2mm and 4mm).
2) Specimens were subjected to low-velocity impact testing at different energy levels. Impacted specimens and non-impacted specimens were then subjected to tension-tension fatigue testing.
3) Results showed that impact velocity significantly influenced the fatigue life of composite laminates. The 2mm thick impacted laminates saw a drastic reduction in fatigue life compared to the 4mm laminates.
EFFECT OF NANO RUBBER ADDITIONS ON WEAR AND MECHANICAL PROPERTIES OF EPOXY GL...paperpublications3
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3. Padmanabhan Krishnan
Viscoelastic response of hybrid polymeric
dental composites in sliding contacts and
applications
Abstract: The viscoelastic response of polymeric solids to sliding contact conditions
is observed and analyzed with respect to the sliding speed, material composition,
and geometry. It was discovered that polymeric solids produced their own distinct
viscoelastic signatures that cause resonance at certain sliding speeds which can be
explained with resonance conditions for electromagnetic waves. The observed vis-
colelastic phenomenon is characterized with respect to the relaxation and recovery
times for rigid polymeric solids. It is confirmatory as a demonstration of proof of
existence of viscoelasticity and self-organization in these materials under sliding con-
tact conditions. Viscoelastic observations are also made on the aged specimens in
sliding contact.
Keywords: Viscoelasticity, polymer, hybrid composites, surfaces, sliding contact,
ageing, stress waves
1 Introduction
Polymer-based composites with ceramic fillers are being increasingly used in dental
applications as they combine the requirements for strength, fatigue, toughness,
and bio-compatibility with enamel and wear resistance. The surface integrity and
long-term wear performance of these materials is a key issue in deciding their suit-
ability for dental applications. Pin on disc (POD) sliding wear testing of dental re-
storative materials (amalgam, ceramics, polymers, and composites) is a widely
accepted practice to generate data and evaluate the contact wear performance of
these materials prior to other wear test methods approved for use in dentistry. Dur-
ing the POD sliding wear of polymeric composites at loads ranging from a moderate
contact load of 5 N to a load of 15 N corresponding to the occlusal forces on the
molars, the choice of low sliding speeds of 2–5 mm/s was seen to produce some
interesting and periodic distortions in the friction force trace that can be mistaken
Padmanabhan Krishnan, School of Mechanical Engineering, Vellore Institute of Technology,
Vellore 632014, India, e-mail: padmanabhan.k@vit.ac.in
Acknowledgement: The author thanks VIT management and the School of Mechanical Engineering
colleagues for the wonderful support and encouragement.
https://doi.org/10.1515/9783110724684-003
4. for machine-related vibrations to begin with and considered undesirable in the
measurement of frictional force and estimation of the coefficient of friction. This
new disruptive discovery was later proven to be viscoelastic in nature as the ma-
chine vibrational frequencies were higher by an order or more. The discovery of
such a viscoelastic response would lead to many important applications later.
2 Viscoelastic models and the phenomena
In plastic materials, prolonged exposure to stress may cause noticeable and irre-
versible deformation which must be taken into consideration when designing parts
for structural and bio-medical applications. The susceptibility to permanently de-
form under load or a relaxation mechanism under stress can be measured in creep
and stress relaxation experiments, respectively [1–4]. In the simplest case, the re-
laxation mechanism under a constant strain can be described with the help of one-
dimensional Maxwell model which consists of a spring and dashpot in series.
According to the model shown in Figure 1, an instantaneous strain causes only the
elastic spring to initially deform, while the viscous dashpot slowly and gradually re-
laxes and allows the spring to slowly return to the original condition. Thus, for times
much shorter than the relaxation time, the Maxwell element behaves essentially like
a spring, whereas for times much longer than the relaxation time, it behaves like a
dashpot [5].
Figure 1: The Voigt and Maxwell viscoelastic models.
44 Padmanabhan Krishnan
5. An ideal linear elastic material does not experience any relaxation process. This
material can also be described with the Voigt model which consists of a spring paral-
lel to a dash pot. In this arrangement, no relaxation takes place because the visco-
elastic flow is restricted by the spring element. The viscoelastic behavior of real
polymeric materials is much more complicated, that is, these materials neither
fully relax nor are they ideally elastic. To accurately describe their relaxation be-
havior, Maxwell and Voigt elements have to be combined with more complex ar-
rangements. Zener arrangements and models are also exhibited by polymers that
show a linear viscoelastic behavior which explains the creep and stress relaxation
phenomena [6]. Zener models normally consist of Maxwell Kelvin–Voigt models
in series or parallel arrangements. Burger materials are examples of a set of poly-
mers obeying the viscoelastic models with the Maxwell material and Kelvin mate-
rial in series [6].
To study this strange phenomenon in sliding contacts further, parameters like
geometry (human enamel pin on polymeric disc or an alumina ball with a wider
contact area on disc) and material microstructure of the pin as well as the disc
{polymer-ceramic filler, ceramic filler-polymer-binder, and ceramic-(glassy)ceramic
composites} were considered, and combinations of geometry and material systems
were tried out to study the phenomenon further in a quantitative and methodical
manner. The wear behavior of these materials was also studied using a POD appara-
tus and the results, presented.
3 Experimental procedures
The two composites used in this study were
Hybrid Composite 1: A methacrylic ester matrix with silanated barium alumina sil-
ica glass and silicon dioxide microfillers by 70 wt% with an average particle size of
1 μm.
Hybrid Composite 2: A hybrid ceramic composite (enamel and dentin) with 92 wt%
of fine glass (0.1–10 μm, average 2 μm, and microfiller < 0.1 μm). The resin being
bis–glassy methacrylate (bis–GMA) and triethylene glycol methacrylate (TEGMA).
Composite restorative discs of approximately 15 mm diameter and 3 mm thickness
were prepared by light curing the samples between glass plates with inner Mylar™
film sheets (a thermoplastic-added polyester) and circular (polytetrafluoroethylene)
dams of 3 mm thickness in order to obtain uniformly cured discs. The curing was for
a time period between 60 and 120 s using a xenon light source with a strobe mode
(Dentacolor XS, Heraeus Kulzer) based on manufacturer’s recommendations for indi-
vidual pastes of raw materials in tubes. The fabricated discs were dry-polished using
grit 600 abrasive paper which is the normal grit size used for restorative finishes and
Viscoelastic response of hybrid polymeric dental composites 45
6. finished with “Texmet” cloth to a maximum surface roughness of Rmax ~ 2.5 to 3.5 μm
and an average roughness of Ra = 0.257 µm. Another set of discs were dry-polished to
a surface roughness of Rmax ~ 0.9–1.5 μm using grit 1200 and “velvet” cloth to obtain
a surface smoother than the average particle size down to about an Ra of 0.15 µm.
Acetone was used in minimum quantities to clean the surfaces that were dried and
then electric-blower-dried. Machined and polished human enamel pins from third
maxillary molars and pins of the polymeric materials that constitute the disc were
used, with a maximum possible tip roughness of 0.2 μm. Alumina balls (8.02 mm di-
ameter) with an average surface roughness Ra of 0.1 μm were also considered as pin
materials, but these were used as received. Needless to say, the contact area of the
balls with the disc can be expected to be higher than the pins but Hertzian likewise.
Thus, the counterfaces were defined. Sliding contact tests were conducted at 1–15
mm/s sliding speeds in a POD. A schematic sketch of the sinusoidal stress waves pro-
duced at different revolutions per minute (rpm) is presented in Figure 2.
This sketch also explains how viscoelastic signals lead to resonance when the wear
track perimeter and the wavelength of a single signal match under specific ratios. Fric-
tion force traces were obtained at various rpm. Some pins and discs were conditioned
Figure 2: A schematic sketch of the sinusoidal stress waves produced at different rpm.
46 Padmanabhan Krishnan
7. in distilled water at room temperature up to absorption saturation to obtain consistent
wear data on distilled water-conditioned specimens and compare them with dry wear
data. This process required that specimens be stored for any time between 3 days and
2 weeks until the sample weight was steady correct to 0.1 mg. Certain select specimens
were aged for longer durations of up to 8 months and then wear-tested to evaluate the
long-term effects on wear of these composites. This replicates the oral environment.
The current investigation is a step further that reports a discovery that can aid
in characterizing the mechanical properties of polymers and their composites by
sliding contact tests and explains the phenomenon with examples. Ageing of the
samples has also been investigated.
4 Results and discussion
During the POD sliding wear of polymer-based composites using a CSEM tribometer
(Geneva, Switzerland) at a load range of 5–15 N corresponding to moderate chewing
to occlusal forces in the mouth, in dry and distilled water conditioned environment,
the choice of the conventionally adopted low sliding speeds of 0–15 mm/s was seen
to produce some interesting and periodic but secondary distortions, rendering the
measurement of friction force and hence the determination of coefficient of friction
unreliable. Such an observation and analysis seems to have missed the attention of
others who have reported the mean coefficient of friction and related wear data on
such composites under similar conditions. As the sliding speed is increased to
15 mm/s for wear track radii in the range of 4–5 mm, i.e. from ~ 10 rpm to 40 rpm
for the disc dimensions in this study, low speed periodic, localized wave packets
were observed as in Figures 3–6, if the material is a polymer or its composite viz.
Composites 1 and 2.
This was observed for any pin/ball geometry or material like its own counter-
face, enamel, or alumina. To negate any influence of smoothening effects due to
“wearing in,” the experiment was conducted by decreasing the sliding speed from
40 rpm to 10 rpm. Low speed distortions were still observed with the same ampli-
tude. Here, Series 1 refers to Composite 1 and Series 2 refers to Composite 2. It was
also seen that the amplitude of the wave like distortion was proportional to the
polymer matrix content in the disc material. For example, Composite 1 which con-
tains 30 wt% of methacrylic ester, a polymer, exhibited a higher amplitude of wave
like signature than Composite 2 which contains only 8 wt% of polymer, a blend of
bis-GMA/TEGMA (see Figure 2). The low rpm coefficient of friction varies by ~ ±10%
at maxima in case of Composite 1 against alumina ball in dry conditions. The same
composite exhibited an amplitude variation of up to ±75% at maxima with the
human enamel as the pin material in the same conditions. Composite 1 disc with
Composite 1 pin yielded wave packets similar in amplitude to those with the enamel
Viscoelastic response of hybrid polymeric dental composites 47
8. pin for the same geometry, except for a different range of friction force values. It
was seen that the effect of damping due to pin geometry played a significant role in
the magnitude of the amplitude of the wave packet for similar type of materials.
The human molar pin, being functionally gradient with a softer dentin inside and a
layer of enamel outside, produced resonance patterns with amplitude variations of
up to ±75% at maxima. Further, the maximum amplitude of friction force traces was
directly proportional to the normal load used in sliding contacts. Lower ranges of
friction force values correspond to lower loads of 10 and 5 N, respectively, for the
Figure 3: Coefficient of friction of Alumina Ball versus Composite 1 for dry sliding speeds of 40 rpm
to 10 rpm.
Figure 4: Coefficient of friction of Alumina Ball versus Composites 1 and 2 for dry sliding speeds of
10 rpm to 1 rpm.
48 Padmanabhan Krishnan
9. set of materials used here. In general, the friction force trace for polymer compo-
sites is stable without oscillations only at ~ 35 rpm and above. This holds true in
dry as well as wet environments like distilled water. Needless to say, only 15 N tests
will be discussed henceforth for clarity and amplitude of signatures. When ceramic
discs like alumina or porcelain slide against a ceramic pin, there is no distortion at
any of the sliding speeds chosen as above. However, Composite 2 does show a wave
Figure 5: Friction force plots of Composites 1 and 2 versus Enamel Pin at 10–40 rpm in dry sliding
conditions.
Figure 6: A single wave train for the dry sliding of Alumina Ball versus Composite 1 at 10 rpm
indicating resonance.
Viscoelastic response of hybrid polymeric dental composites 49
10. packet like distortion with a much lesser amplitude than Composite 1 due to a
lower polymer binder content, for the same sliding speeds, thus confirming the vis-
coelastic influence of the polymer on the anomalous friction traces. This is evident
from Figures 4 and 5.
For composite 1 against alumina ball in dry conditions, when the speed of test-
ing was further lowered to 5 rpm, the wave train had an alternating strength of am-
plitude that resembled one with a carrier/modulator ratio of 5, what one exactly
comes across in wave transmission. When the rpm was reduced to 1, the wave train
pattern completely disappeared, and only a single waveform was seen to occur ex-
posing the linear viscoelastic response signal of the polymeric solid to the load ap-
plied (see Figure 7).
Schematically, this phenomenon is explained as shown in Figure 2, where the vibra-
tional resonance due to the sinusoidal viscoelastic stress wave propagation is shown
to arise from a 1:1 ratio between the viscoelastic wave length and the length of the
circumference of the wear track on the disc at 10 rpm. When the viscoelastic response
wavelength increases marginally at 5 and subsequently at 1 rpm, the resonance pat-
tern disappears completely as the single viscoelastic stress wave manifests out of the
packets due to a higher wavelength than the circumferential length. Since composites
with various surface roughness values at various stages of experimentation were em-
ployed in the study, it can be seen that the frictional force values are different along
the time axis due to “wearing in,” but the amplitude and wavelength are consistent
Figure 7: Coefficient of friction plots for dry sliding of Composite 1 vs. Alumina Ball showing a
single stress wave at 1 rpm.
50 Padmanabhan Krishnan
11. with the material properties, load, and speed of testing as conditions. A viscoelasti-
cally distorting second phase is sometimes incorporated forming a frictionally differ-
ent surface layer that is prone to wear, which can easily be inferred when the force
traces transit. It is envisaged that each polymeric material or its composite produces
its own characteristic signal that is a signature whose wavelength and amplitude de-
pend on the normal load. The nature and contact area of the pin/ball affect the am-
plitude of the 10 rpm resonance patterns due to the difference in vibration modes,
but it has very little influence at 1 rpm due to the absence of the same. The sinusoidal
waves resemble the stress waves which propagate in linear viscoelastic solids obey-
ing a Maxwell or Zener/Burger parameter model under stretching. Since sliding wear
gives rise to tensile forces at the surface due to contact stretching and shear forces
with a strong gradient at a sub-surface plane, the same is manifested in the present
case. A five-parameter model for hygrothermally degraded polymer, explaining every
aspect of the observed phenomena for certain type of polymeric materials, is envis-
aged for future work. The viscoelastic response of a polymeric material against a sur-
face that distributes load in sliding contacts is the cause for such waveforms. The
present viscoelastic behavior is seen to be (a) consisting of dilational and shear
waves (see Figure 8), (b) producing subsurface shear waves, (c) a spring and dashpot
model-based manipulation, (d) a secondary and segmental in polymer relaxation,
and (e) a viscoelastic version similar to the Tomlinson and Frenkel–Kontorova atomic
frictional models presented in Figure 9 [7].
Dilatational Shear
u
u
P-waves S-waves
z
z
Vp Vs
Rayleigh wave
E,V,P
(a) (b)
(c)
Surface
Figure 8: A schematic drawing of dilational, shear,
and Raleigh waves generated in sliding contacts.
Viscoelastic response of hybrid polymeric dental composites 51
12. Self-organization can be adapted for the polymer molecular structures here,
where the substrate is presented as a periodic energy profile created by the mole-
cules, using the “m” or mass in the Tomlinson–Frenkel–Kontoraova model as a vis-
cous dashpot and “k” the spring constant in series. This is similar to the Maxwell
model where the dashpot and the spring are in series. The stress relaxation implies
that the stress is time-dependent and varying as the pin moves around the disc sur-
face in circles, causing the stress to increase and decrease due to instantaneous
contact. Further, the strain that is developed is instantaneous in a POD experiment
right under the pin at the interface and is almost negligible at the incipient or far
behind locations. Hence, the strain in this case is localized, and the viscoelastic re-
sponse models are also localized like a surf-riding situation. The developed stress
waves behave like a fatigue wave train. Surface Raleigh waves are generated as shown
in Figure 9 which can be used for in situ NDT (nondestructive testing) inspection.
Though there is self-organization, over a longer time, thermal and hygrother-
mal effects can relax the stress further, causing hygrothermo-mechanical fatigue. In
short, the rpm speed at the given radius/radii and the resulting sliding velocity was
comparable to the relaxation time, τ, of the polymeric solid for the conditions that
allow such a viscoelastic reaction to take place. Normally, the mechanical relaxa-
tion time (not volume) for a glassy polymer below its glass transition temperature
ranges from seconds to minutes [8–10], and the evaluation of relaxation time, τ, for
a polymer filled with inorganic particles, based on the relationships for a linear vis-
coelastic solid [8, 9], gives us a static frequency range of ω = 0.1–1 for tan δ = 0.001
to 0.1 as a dynamic mechanical analysis (DMA) test would prove for polymers. The
relationship ωτ = 1 gets us an approximate value of 1–10 s for the relaxation time
for these two polymer composites. Since there is time (t ≫ τ) for viscous reaction to
take place at a low rpm value of 1 (for radius of 4–5 mm), the time-dependent stress,
σt, drops and rises depending on the relaxation and recovery times. It is observed
that this is not a stick-slip behavior which manifests as a saw-tooth waveform in
the wear of materials but a sinusoidal stress wave as a result of viscoelasticity of
the polymeric material. When the rpm increases, the material behaves elastically
since the time for such a viscous reaction to take place is not available, as t ≪ τ. At
an intermediate 10 rpm speed, the resonance occurring due to the viscoelastic re-
sponse of the material was not noticed in the 8 month distilled water aged Compos-
ite 1 samples as the wavelength of the friction force trace was obviously longer due
to time-dependent viscoelasticity, and the ratio for resonance was not met with. It
leads us to believe that the viscoelastic response curve of an non-aged specimen at
m m m m m
k k k k
Figure 9: A schematic drawing of the Tomlinson
and Frenkel–Kontorova atomic friction model.
52 Padmanabhan Krishnan
13. 10 rpm is much shorter in order to obtain a wave train as shown in Figure 6, thereby
rendering support to the evidence that vibrational resonance due to viscoelastic re-
sponse of a polymer composite material to loading occurs when t = τ. The condition
for resonance, in order to obtain such a wave train, is very much similar to the Max-
well resonance condition for oscillation of fields as given in Feynman lectures [11]:
ω0 = 2.405 c=r
f g (1)
where ω0 is the resonant frequency, c the velocity, and r the radius of the wear track
that was discussed [9]. It is seen that the constant 2.405 can be interpreted as the
result of the path length of the wave train divided by the path length of the individual
viscoelastic signal, which is in fact the condition for resonance. The radius of the disc
can be substituted for r to obtain the condition for resonance. It is indeed interesting
to note the similarity between acousto-mechanical and electromagnetic resonance
conditions. The Maxwell resonant frequency in the present investigation, ω0, would
be less than 5 Hz in this case when we substitute for c and r. Here, the linear-
viscoelastic stress waves are in packets at certain speeds of sliding and represent the
viscoelastic and resonant stress wave propagation in the polymeric solid due to slid-
ing contact. As discussed earlier in Figure 2, the phenomenon of resonance originates
due to the coincidence of the viscoelastic signal wavelength with the perimeter of the
wear track, or in other words, one rpm.
The smooth attenuation of the friction force traces at rpm closer to 40 is a result
of an elastic behavior as discussed before. Further, dynamic damping can occur
when the material is both dissipative and dispersive [10] causing attenuation of the
friction force traces due to the dilational stress component reducing and the shear
stress component taking over. At higher loads and lower rpm, the attenuation
might be advanced. It is expected that the surface Raleigh waves generated due to
friction play a role in resonance at higher speeds and not in the viscoelastic re-
sponse at low rpm [12]. An acceptable level of treatise is presented on polymer tri-
bology by Sinha and Briscoe [13]. But this book does not deal with viscoelasticity or
the effect of aggressive environment on polymer tribology.
It is proposed to conduct monolithic unfilled polymer sliding contact tests in a lin-
ear reciprocating wear tester and confirm the precision and accuracy of the viscoelastic
signals, relaxation, and retardation times and resonance conditions which would lead
to the design and manufacture of viscoelastic testers that can correlate the viscoelastic
properties with the mechanical properties and predict the thermo-mechanical behavior
of polymers under controlled environment. At sub-zero temperatures, the threshold
transition from viscoelastic to elastic behavior can also be predicted in the presence of
a ductile to brittle transition. Viscoelastic response can also be appreciable when the
hygrothermal attack on restoratives and other polymer composites is appreciable. A
detailed account of the do’s and don’ts that involve the required specifications for
hygrothermal conditioning, postsaturation equilibration, and tribology of polymer
composites is presented in the investigations as done earlier [14, 15]. As viscoelasticity
Viscoelastic response of hybrid polymeric dental composites 53
14. is appreciable in the postsaturated and water-equilibrated polymers and restoratives,
these two references are considered significant. It is ascertained that it is not the ma-
chine natural frequency which falls between 50 and 1500 Hz as reported in literature
for similar machines [16], but a viscoelastic phenomenon whose relaxation times and
resonant frequencies with the POD geometry is much lower as evaluated here.
5 Erratum in existing literature and scope
Many publications have emerged in the last few decades that have either chosen to
ignore or just ignored the important aspect of viscoelastic interactions and mecha-
nisms in sliding contacts and wear of polymeric solids. Books, book chapters, and
research articles by tribology researchers have ended up measuring, assessing, and
evaluating wear, lubrication, and friction in polymeric solids without considering
the appreciable effects of viscoelasticity on these parameters [17–23]. As the friction
force traces in the low speed domain are significantly dependent on the viscoelastic
response of the material to sliding contact, any measurement of the friction force
traces that ignores these aspects without a regard for sensitivity is bound to be erro-
neous. Wear rates and wear volumes too depend on the material removed, and the
material just displaced out of the wear track due to viscoelasticity. Hence, their
measurement too is a suspect. Though viscoelasticity of polymers is a known phe-
nomenon, it has not been seriously considered by tribologists and machinists as a
significantly contributing subject in the evaluation of polymeric solids and their ap-
plications. The publications chosen here to highlight the issue are only an act of
serendipity and not choice. The real number is staggering and needs withdrawal or
revision of the data and the publications, if the conditions stated in this chapter are
encountered. The scope of viscoelasticity-based studies is very vast as polymeric
solids are known to be hygrothermally susceptible that renders them nonlinear – a
more complicated deviation from their linear viscoelasticity which is exhibited by
rigid polymers and their composites at normal pressures and room temperatures.
As nonlinear viscoelasticity demands the use of five-parameter models and similar
conformations in series or parallel, lot of scope exists in the study of these mecha-
nisms in the tribological modeling of such systems. The next section provides more
detail about the mechanisms and applications of this phenomena in tribology and
machining.
54 Padmanabhan Krishnan
15. 6 Applications of the viscoelasticity phenomena
in sliding contact
The following are some of the salient features and applications of the discovery of
the phenomenon of viscoelasticity in sliding contact mechanisms;
1. It provides a quick test method to assess the viscoelastic response of polymeric
solids to sliding contact mechanisms.
2. A correlation of the viscoelastic properties with the mechanical properties is
possible that would help in evaluating the mechanical properties of a polymeric
solid from a knowledge of its viscoelastic response.
3. It is proposed as a single test that would evaluate the quasi-static mechanical prop-
erties and the tribological properties with an acceptable level of approximation.
4. A linear reciprocating wear test apparatus with an associated specific software
would suffice to achieve this phenomenally easy way of evaluating the mechan-
ical properties of a solid polymer.
5. This method serves as an easy to perform substitute dynamic mechanical ana-
lyzer as the relaxation and retardation times can be evaluated with an approxi-
mate assessment of the storage and loss modulus.
6. It helps in a quick materials selection process for ductile and ductile–brittle
solid polymers with viscoelastic properties.
7. A detailed study of viscoelastic fatigue is possible as an outcome of this investi-
gation. A viscoelastic thermal or hygro-thermal cut off can be evaluated in a
tribological test where thermal or hygorthermal frictional softening effects
could be quantified and the design limits, set to a required level.
7 Summary and conclusions
This investigation on sliding contact friction of polymeric solids illustrates and ex-
plains the existence of viscoelastic response through analysis of the friction force
traces that result from contact sliding under loads. The factors influencing the char-
acterization of the viscoelastic and elastic properties of polymeric solids in sliding
contacts viz. the relaxation time, the viscous reaction due to ageing and condition
for resonance, are discussed. The Maxwell and other relevant models that seek to
explain this phenomenon are highlighted and explained. It is proposed to use this
phenomenon to evaluate the elastic and viscoelastic properties of virgin polymers
and filled polymers with various processing, testing, and environmental conditions
to aid in their complete hygrothermo-mechanical characterization through an un-
derstanding of sliding contact mechanics. The salient applications of the discovery
of viscoelastic phenomena in sliding contacts are also predicted.
Viscoelastic response of hybrid polymeric dental composites 55
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