SlideShare a Scribd company logo
Part III: Applications and analysis
Padmanabhan Krishnan
Viscoelastic response of hybrid polymeric
dental composites in sliding contacts and
applications
Abstract: The viscoelastic response of polymeric solids to sliding contact conditions
is observed and analyzed with respect to the sliding speed, material composition,
and geometry. It was discovered that polymeric solids produced their own distinct
viscoelastic signatures that cause resonance at certain sliding speeds which can be
explained with resonance conditions for electromagnetic waves. The observed vis-
colelastic phenomenon is characterized with respect to the relaxation and recovery
times for rigid polymeric solids. It is confirmatory as a demonstration of proof of
existence of viscoelasticity and self-organization in these materials under sliding con-
tact conditions. Viscoelastic observations are also made on the aged specimens in
sliding contact.
Keywords: Viscoelasticity, polymer, hybrid composites, surfaces, sliding contact,
ageing, stress waves
1 Introduction
Polymer-based composites with ceramic fillers are being increasingly used in dental
applications as they combine the requirements for strength, fatigue, toughness,
and bio-compatibility with enamel and wear resistance. The surface integrity and
long-term wear performance of these materials is a key issue in deciding their suit-
ability for dental applications. Pin on disc (POD) sliding wear testing of dental re-
storative materials (amalgam, ceramics, polymers, and composites) is a widely
accepted practice to generate data and evaluate the contact wear performance of
these materials prior to other wear test methods approved for use in dentistry. Dur-
ing the POD sliding wear of polymeric composites at loads ranging from a moderate
contact load of 5 N to a load of 15 N corresponding to the occlusal forces on the
molars, the choice of low sliding speeds of 2–5 mm/s was seen to produce some
interesting and periodic distortions in the friction force trace that can be mistaken
Padmanabhan Krishnan, School of Mechanical Engineering, Vellore Institute of Technology,
Vellore 632014, India, e-mail: padmanabhan.k@vit.ac.in
Acknowledgement: The author thanks VIT management and the School of Mechanical Engineering
colleagues for the wonderful support and encouragement.
https://doi.org/10.1515/9783110724684-003
for machine-related vibrations to begin with and considered undesirable in the
measurement of frictional force and estimation of the coefficient of friction. This
new disruptive discovery was later proven to be viscoelastic in nature as the ma-
chine vibrational frequencies were higher by an order or more. The discovery of
such a viscoelastic response would lead to many important applications later.
2 Viscoelastic models and the phenomena
In plastic materials, prolonged exposure to stress may cause noticeable and irre-
versible deformation which must be taken into consideration when designing parts
for structural and bio-medical applications. The susceptibility to permanently de-
form under load or a relaxation mechanism under stress can be measured in creep
and stress relaxation experiments, respectively [1–4]. In the simplest case, the re-
laxation mechanism under a constant strain can be described with the help of one-
dimensional Maxwell model which consists of a spring and dashpot in series.
According to the model shown in Figure 1, an instantaneous strain causes only the
elastic spring to initially deform, while the viscous dashpot slowly and gradually re-
laxes and allows the spring to slowly return to the original condition. Thus, for times
much shorter than the relaxation time, the Maxwell element behaves essentially like
a spring, whereas for times much longer than the relaxation time, it behaves like a
dashpot [5].
Figure 1: The Voigt and Maxwell viscoelastic models.
44 Padmanabhan Krishnan
An ideal linear elastic material does not experience any relaxation process. This
material can also be described with the Voigt model which consists of a spring paral-
lel to a dash pot. In this arrangement, no relaxation takes place because the visco-
elastic flow is restricted by the spring element. The viscoelastic behavior of real
polymeric materials is much more complicated, that is, these materials neither
fully relax nor are they ideally elastic. To accurately describe their relaxation be-
havior, Maxwell and Voigt elements have to be combined with more complex ar-
rangements. Zener arrangements and models are also exhibited by polymers that
show a linear viscoelastic behavior which explains the creep and stress relaxation
phenomena [6]. Zener models normally consist of Maxwell Kelvin–Voigt models
in series or parallel arrangements. Burger materials are examples of a set of poly-
mers obeying the viscoelastic models with the Maxwell material and Kelvin mate-
rial in series [6].
To study this strange phenomenon in sliding contacts further, parameters like
geometry (human enamel pin on polymeric disc or an alumina ball with a wider
contact area on disc) and material microstructure of the pin as well as the disc
{polymer-ceramic filler, ceramic filler-polymer-binder, and ceramic-(glassy)ceramic
composites} were considered, and combinations of geometry and material systems
were tried out to study the phenomenon further in a quantitative and methodical
manner. The wear behavior of these materials was also studied using a POD appara-
tus and the results, presented.
3 Experimental procedures
The two composites used in this study were
Hybrid Composite 1: A methacrylic ester matrix with silanated barium alumina sil-
ica glass and silicon dioxide microfillers by 70 wt% with an average particle size of
1 μm.
Hybrid Composite 2: A hybrid ceramic composite (enamel and dentin) with 92 wt%
of fine glass (0.1–10 μm, average 2 μm, and microfiller < 0.1 μm). The resin being
bis–glassy methacrylate (bis–GMA) and triethylene glycol methacrylate (TEGMA).
Composite restorative discs of approximately 15 mm diameter and 3 mm thickness
were prepared by light curing the samples between glass plates with inner Mylar™
film sheets (a thermoplastic-added polyester) and circular (polytetrafluoroethylene)
dams of 3 mm thickness in order to obtain uniformly cured discs. The curing was for
a time period between 60 and 120 s using a xenon light source with a strobe mode
(Dentacolor XS, Heraeus Kulzer) based on manufacturer’s recommendations for indi-
vidual pastes of raw materials in tubes. The fabricated discs were dry-polished using
grit 600 abrasive paper which is the normal grit size used for restorative finishes and
Viscoelastic response of hybrid polymeric dental composites 45
finished with “Texmet” cloth to a maximum surface roughness of Rmax ~ 2.5 to 3.5 μm
and an average roughness of Ra = 0.257 µm. Another set of discs were dry-polished to
a surface roughness of Rmax ~ 0.9–1.5 μm using grit 1200 and “velvet” cloth to obtain
a surface smoother than the average particle size down to about an Ra of 0.15 µm.
Acetone was used in minimum quantities to clean the surfaces that were dried and
then electric-blower-dried. Machined and polished human enamel pins from third
maxillary molars and pins of the polymeric materials that constitute the disc were
used, with a maximum possible tip roughness of 0.2 μm. Alumina balls (8.02 mm di-
ameter) with an average surface roughness Ra of 0.1 μm were also considered as pin
materials, but these were used as received. Needless to say, the contact area of the
balls with the disc can be expected to be higher than the pins but Hertzian likewise.
Thus, the counterfaces were defined. Sliding contact tests were conducted at 1–15
mm/s sliding speeds in a POD. A schematic sketch of the sinusoidal stress waves pro-
duced at different revolutions per minute (rpm) is presented in Figure 2.
This sketch also explains how viscoelastic signals lead to resonance when the wear
track perimeter and the wavelength of a single signal match under specific ratios. Fric-
tion force traces were obtained at various rpm. Some pins and discs were conditioned
Figure 2: A schematic sketch of the sinusoidal stress waves produced at different rpm.
46 Padmanabhan Krishnan
in distilled water at room temperature up to absorption saturation to obtain consistent
wear data on distilled water-conditioned specimens and compare them with dry wear
data. This process required that specimens be stored for any time between 3 days and
2 weeks until the sample weight was steady correct to 0.1 mg. Certain select specimens
were aged for longer durations of up to 8 months and then wear-tested to evaluate the
long-term effects on wear of these composites. This replicates the oral environment.
The current investigation is a step further that reports a discovery that can aid
in characterizing the mechanical properties of polymers and their composites by
sliding contact tests and explains the phenomenon with examples. Ageing of the
samples has also been investigated.
4 Results and discussion
During the POD sliding wear of polymer-based composites using a CSEM tribometer
(Geneva, Switzerland) at a load range of 5–15 N corresponding to moderate chewing
to occlusal forces in the mouth, in dry and distilled water conditioned environment,
the choice of the conventionally adopted low sliding speeds of 0–15 mm/s was seen
to produce some interesting and periodic but secondary distortions, rendering the
measurement of friction force and hence the determination of coefficient of friction
unreliable. Such an observation and analysis seems to have missed the attention of
others who have reported the mean coefficient of friction and related wear data on
such composites under similar conditions. As the sliding speed is increased to
15 mm/s for wear track radii in the range of 4–5 mm, i.e. from ~ 10 rpm to 40 rpm
for the disc dimensions in this study, low speed periodic, localized wave packets
were observed as in Figures 3–6, if the material is a polymer or its composite viz.
Composites 1 and 2.
This was observed for any pin/ball geometry or material like its own counter-
face, enamel, or alumina. To negate any influence of smoothening effects due to
“wearing in,” the experiment was conducted by decreasing the sliding speed from
40 rpm to 10 rpm. Low speed distortions were still observed with the same ampli-
tude. Here, Series 1 refers to Composite 1 and Series 2 refers to Composite 2. It was
also seen that the amplitude of the wave like distortion was proportional to the
polymer matrix content in the disc material. For example, Composite 1 which con-
tains 30 wt% of methacrylic ester, a polymer, exhibited a higher amplitude of wave
like signature than Composite 2 which contains only 8 wt% of polymer, a blend of
bis-GMA/TEGMA (see Figure 2). The low rpm coefficient of friction varies by ~ ±10%
at maxima in case of Composite 1 against alumina ball in dry conditions. The same
composite exhibited an amplitude variation of up to ±75% at maxima with the
human enamel as the pin material in the same conditions. Composite 1 disc with
Composite 1 pin yielded wave packets similar in amplitude to those with the enamel
Viscoelastic response of hybrid polymeric dental composites 47
pin for the same geometry, except for a different range of friction force values. It
was seen that the effect of damping due to pin geometry played a significant role in
the magnitude of the amplitude of the wave packet for similar type of materials.
The human molar pin, being functionally gradient with a softer dentin inside and a
layer of enamel outside, produced resonance patterns with amplitude variations of
up to ±75% at maxima. Further, the maximum amplitude of friction force traces was
directly proportional to the normal load used in sliding contacts. Lower ranges of
friction force values correspond to lower loads of 10 and 5 N, respectively, for the
Figure 3: Coefficient of friction of Alumina Ball versus Composite 1 for dry sliding speeds of 40 rpm
to 10 rpm.
Figure 4: Coefficient of friction of Alumina Ball versus Composites 1 and 2 for dry sliding speeds of
10 rpm to 1 rpm.
48 Padmanabhan Krishnan
set of materials used here. In general, the friction force trace for polymer compo-
sites is stable without oscillations only at ~ 35 rpm and above. This holds true in
dry as well as wet environments like distilled water. Needless to say, only 15 N tests
will be discussed henceforth for clarity and amplitude of signatures. When ceramic
discs like alumina or porcelain slide against a ceramic pin, there is no distortion at
any of the sliding speeds chosen as above. However, Composite 2 does show a wave
Figure 5: Friction force plots of Composites 1 and 2 versus Enamel Pin at 10–40 rpm in dry sliding
conditions.
Figure 6: A single wave train for the dry sliding of Alumina Ball versus Composite 1 at 10 rpm
indicating resonance.
Viscoelastic response of hybrid polymeric dental composites 49
packet like distortion with a much lesser amplitude than Composite 1 due to a
lower polymer binder content, for the same sliding speeds, thus confirming the vis-
coelastic influence of the polymer on the anomalous friction traces. This is evident
from Figures 4 and 5.
For composite 1 against alumina ball in dry conditions, when the speed of test-
ing was further lowered to 5 rpm, the wave train had an alternating strength of am-
plitude that resembled one with a carrier/modulator ratio of 5, what one exactly
comes across in wave transmission. When the rpm was reduced to 1, the wave train
pattern completely disappeared, and only a single waveform was seen to occur ex-
posing the linear viscoelastic response signal of the polymeric solid to the load ap-
plied (see Figure 7).
Schematically, this phenomenon is explained as shown in Figure 2, where the vibra-
tional resonance due to the sinusoidal viscoelastic stress wave propagation is shown
to arise from a 1:1 ratio between the viscoelastic wave length and the length of the
circumference of the wear track on the disc at 10 rpm. When the viscoelastic response
wavelength increases marginally at 5 and subsequently at 1 rpm, the resonance pat-
tern disappears completely as the single viscoelastic stress wave manifests out of the
packets due to a higher wavelength than the circumferential length. Since composites
with various surface roughness values at various stages of experimentation were em-
ployed in the study, it can be seen that the frictional force values are different along
the time axis due to “wearing in,” but the amplitude and wavelength are consistent
Figure 7: Coefficient of friction plots for dry sliding of Composite 1 vs. Alumina Ball showing a
single stress wave at 1 rpm.
50 Padmanabhan Krishnan
with the material properties, load, and speed of testing as conditions. A viscoelasti-
cally distorting second phase is sometimes incorporated forming a frictionally differ-
ent surface layer that is prone to wear, which can easily be inferred when the force
traces transit. It is envisaged that each polymeric material or its composite produces
its own characteristic signal that is a signature whose wavelength and amplitude de-
pend on the normal load. The nature and contact area of the pin/ball affect the am-
plitude of the 10 rpm resonance patterns due to the difference in vibration modes,
but it has very little influence at 1 rpm due to the absence of the same. The sinusoidal
waves resemble the stress waves which propagate in linear viscoelastic solids obey-
ing a Maxwell or Zener/Burger parameter model under stretching. Since sliding wear
gives rise to tensile forces at the surface due to contact stretching and shear forces
with a strong gradient at a sub-surface plane, the same is manifested in the present
case. A five-parameter model for hygrothermally degraded polymer, explaining every
aspect of the observed phenomena for certain type of polymeric materials, is envis-
aged for future work. The viscoelastic response of a polymeric material against a sur-
face that distributes load in sliding contacts is the cause for such waveforms. The
present viscoelastic behavior is seen to be (a) consisting of dilational and shear
waves (see Figure 8), (b) producing subsurface shear waves, (c) a spring and dashpot
model-based manipulation, (d) a secondary and segmental in polymer relaxation,
and (e) a viscoelastic version similar to the Tomlinson and Frenkel–Kontorova atomic
frictional models presented in Figure 9 [7].
Dilatational Shear
u
u
P-waves S-waves
z
z
Vp Vs
Rayleigh wave
E,V,P
(a) (b)
(c)
Surface
Figure 8: A schematic drawing of dilational, shear,
and Raleigh waves generated in sliding contacts.
Viscoelastic response of hybrid polymeric dental composites 51
Self-organization can be adapted for the polymer molecular structures here,
where the substrate is presented as a periodic energy profile created by the mole-
cules, using the “m” or mass in the Tomlinson–Frenkel–Kontoraova model as a vis-
cous dashpot and “k” the spring constant in series. This is similar to the Maxwell
model where the dashpot and the spring are in series. The stress relaxation implies
that the stress is time-dependent and varying as the pin moves around the disc sur-
face in circles, causing the stress to increase and decrease due to instantaneous
contact. Further, the strain that is developed is instantaneous in a POD experiment
right under the pin at the interface and is almost negligible at the incipient or far
behind locations. Hence, the strain in this case is localized, and the viscoelastic re-
sponse models are also localized like a surf-riding situation. The developed stress
waves behave like a fatigue wave train. Surface Raleigh waves are generated as shown
in Figure 9 which can be used for in situ NDT (nondestructive testing) inspection.
Though there is self-organization, over a longer time, thermal and hygrother-
mal effects can relax the stress further, causing hygrothermo-mechanical fatigue. In
short, the rpm speed at the given radius/radii and the resulting sliding velocity was
comparable to the relaxation time, τ, of the polymeric solid for the conditions that
allow such a viscoelastic reaction to take place. Normally, the mechanical relaxa-
tion time (not volume) for a glassy polymer below its glass transition temperature
ranges from seconds to minutes [8–10], and the evaluation of relaxation time, τ, for
a polymer filled with inorganic particles, based on the relationships for a linear vis-
coelastic solid [8, 9], gives us a static frequency range of ω = 0.1–1 for tan δ = 0.001
to 0.1 as a dynamic mechanical analysis (DMA) test would prove for polymers. The
relationship ωτ = 1 gets us an approximate value of 1–10 s for the relaxation time
for these two polymer composites. Since there is time (t ≫ τ) for viscous reaction to
take place at a low rpm value of 1 (for radius of 4–5 mm), the time-dependent stress,
σt, drops and rises depending on the relaxation and recovery times. It is observed
that this is not a stick-slip behavior which manifests as a saw-tooth waveform in
the wear of materials but a sinusoidal stress wave as a result of viscoelasticity of
the polymeric material. When the rpm increases, the material behaves elastically
since the time for such a viscous reaction to take place is not available, as t ≪ τ. At
an intermediate 10 rpm speed, the resonance occurring due to the viscoelastic re-
sponse of the material was not noticed in the 8 month distilled water aged Compos-
ite 1 samples as the wavelength of the friction force trace was obviously longer due
to time-dependent viscoelasticity, and the ratio for resonance was not met with. It
leads us to believe that the viscoelastic response curve of an non-aged specimen at
m m m m m
k k k k
Figure 9: A schematic drawing of the Tomlinson
and Frenkel–Kontorova atomic friction model.
52 Padmanabhan Krishnan
10 rpm is much shorter in order to obtain a wave train as shown in Figure 6, thereby
rendering support to the evidence that vibrational resonance due to viscoelastic re-
sponse of a polymer composite material to loading occurs when t = τ. The condition
for resonance, in order to obtain such a wave train, is very much similar to the Max-
well resonance condition for oscillation of fields as given in Feynman lectures [11]:
ω0 = 2.405 c=r
f g (1)
where ω0 is the resonant frequency, c the velocity, and r the radius of the wear track
that was discussed [9]. It is seen that the constant 2.405 can be interpreted as the
result of the path length of the wave train divided by the path length of the individual
viscoelastic signal, which is in fact the condition for resonance. The radius of the disc
can be substituted for r to obtain the condition for resonance. It is indeed interesting
to note the similarity between acousto-mechanical and electromagnetic resonance
conditions. The Maxwell resonant frequency in the present investigation, ω0, would
be less than 5 Hz in this case when we substitute for c and r. Here, the linear-
viscoelastic stress waves are in packets at certain speeds of sliding and represent the
viscoelastic and resonant stress wave propagation in the polymeric solid due to slid-
ing contact. As discussed earlier in Figure 2, the phenomenon of resonance originates
due to the coincidence of the viscoelastic signal wavelength with the perimeter of the
wear track, or in other words, one rpm.
The smooth attenuation of the friction force traces at rpm closer to 40 is a result
of an elastic behavior as discussed before. Further, dynamic damping can occur
when the material is both dissipative and dispersive [10] causing attenuation of the
friction force traces due to the dilational stress component reducing and the shear
stress component taking over. At higher loads and lower rpm, the attenuation
might be advanced. It is expected that the surface Raleigh waves generated due to
friction play a role in resonance at higher speeds and not in the viscoelastic re-
sponse at low rpm [12]. An acceptable level of treatise is presented on polymer tri-
bology by Sinha and Briscoe [13]. But this book does not deal with viscoelasticity or
the effect of aggressive environment on polymer tribology.
It is proposed to conduct monolithic unfilled polymer sliding contact tests in a lin-
ear reciprocating wear tester and confirm the precision and accuracy of the viscoelastic
signals, relaxation, and retardation times and resonance conditions which would lead
to the design and manufacture of viscoelastic testers that can correlate the viscoelastic
properties with the mechanical properties and predict the thermo-mechanical behavior
of polymers under controlled environment. At sub-zero temperatures, the threshold
transition from viscoelastic to elastic behavior can also be predicted in the presence of
a ductile to brittle transition. Viscoelastic response can also be appreciable when the
hygrothermal attack on restoratives and other polymer composites is appreciable. A
detailed account of the do’s and don’ts that involve the required specifications for
hygrothermal conditioning, postsaturation equilibration, and tribology of polymer
composites is presented in the investigations as done earlier [14, 15]. As viscoelasticity
Viscoelastic response of hybrid polymeric dental composites 53
is appreciable in the postsaturated and water-equilibrated polymers and restoratives,
these two references are considered significant. It is ascertained that it is not the ma-
chine natural frequency which falls between 50 and 1500 Hz as reported in literature
for similar machines [16], but a viscoelastic phenomenon whose relaxation times and
resonant frequencies with the POD geometry is much lower as evaluated here.
5 Erratum in existing literature and scope
Many publications have emerged in the last few decades that have either chosen to
ignore or just ignored the important aspect of viscoelastic interactions and mecha-
nisms in sliding contacts and wear of polymeric solids. Books, book chapters, and
research articles by tribology researchers have ended up measuring, assessing, and
evaluating wear, lubrication, and friction in polymeric solids without considering
the appreciable effects of viscoelasticity on these parameters [17–23]. As the friction
force traces in the low speed domain are significantly dependent on the viscoelastic
response of the material to sliding contact, any measurement of the friction force
traces that ignores these aspects without a regard for sensitivity is bound to be erro-
neous. Wear rates and wear volumes too depend on the material removed, and the
material just displaced out of the wear track due to viscoelasticity. Hence, their
measurement too is a suspect. Though viscoelasticity of polymers is a known phe-
nomenon, it has not been seriously considered by tribologists and machinists as a
significantly contributing subject in the evaluation of polymeric solids and their ap-
plications. The publications chosen here to highlight the issue are only an act of
serendipity and not choice. The real number is staggering and needs withdrawal or
revision of the data and the publications, if the conditions stated in this chapter are
encountered. The scope of viscoelasticity-based studies is very vast as polymeric
solids are known to be hygrothermally susceptible that renders them nonlinear – a
more complicated deviation from their linear viscoelasticity which is exhibited by
rigid polymers and their composites at normal pressures and room temperatures.
As nonlinear viscoelasticity demands the use of five-parameter models and similar
conformations in series or parallel, lot of scope exists in the study of these mecha-
nisms in the tribological modeling of such systems. The next section provides more
detail about the mechanisms and applications of this phenomena in tribology and
machining.
54 Padmanabhan Krishnan
6 Applications of the viscoelasticity phenomena
in sliding contact
The following are some of the salient features and applications of the discovery of
the phenomenon of viscoelasticity in sliding contact mechanisms;
1. It provides a quick test method to assess the viscoelastic response of polymeric
solids to sliding contact mechanisms.
2. A correlation of the viscoelastic properties with the mechanical properties is
possible that would help in evaluating the mechanical properties of a polymeric
solid from a knowledge of its viscoelastic response.
3. It is proposed as a single test that would evaluate the quasi-static mechanical prop-
erties and the tribological properties with an acceptable level of approximation.
4. A linear reciprocating wear test apparatus with an associated specific software
would suffice to achieve this phenomenally easy way of evaluating the mechan-
ical properties of a solid polymer.
5. This method serves as an easy to perform substitute dynamic mechanical ana-
lyzer as the relaxation and retardation times can be evaluated with an approxi-
mate assessment of the storage and loss modulus.
6. It helps in a quick materials selection process for ductile and ductile–brittle
solid polymers with viscoelastic properties.
7. A detailed study of viscoelastic fatigue is possible as an outcome of this investi-
gation. A viscoelastic thermal or hygro-thermal cut off can be evaluated in a
tribological test where thermal or hygorthermal frictional softening effects
could be quantified and the design limits, set to a required level.
7 Summary and conclusions
This investigation on sliding contact friction of polymeric solids illustrates and ex-
plains the existence of viscoelastic response through analysis of the friction force
traces that result from contact sliding under loads. The factors influencing the char-
acterization of the viscoelastic and elastic properties of polymeric solids in sliding
contacts viz. the relaxation time, the viscous reaction due to ageing and condition
for resonance, are discussed. The Maxwell and other relevant models that seek to
explain this phenomenon are highlighted and explained. It is proposed to use this
phenomenon to evaluate the elastic and viscoelastic properties of virgin polymers
and filled polymers with various processing, testing, and environmental conditions
to aid in their complete hygrothermo-mechanical characterization through an un-
derstanding of sliding contact mechanics. The salient applications of the discovery
of viscoelastic phenomena in sliding contacts are also predicted.
Viscoelastic response of hybrid polymeric dental composites 55
References
[1] Drozdov, A. D., Viscoelastic Structures, Academic Press, New York, 1998.
[2] Findley, W. N., Lai, J. S., and Onaran, K., Creep and Relaxation of Nonlinear Viscoelastic
Materials, Dover, New York, 1989.
[3] Torskaya, E. V. and Stepanov, F. I., Effect of surface layers in sliding contact of Viscoelastic
Solids ( 3D Model of Material), Frontiers in Mechanical Engineering, 09 May 2019, doi:
https://doi.org/10.3389/fmech2019.00026.
[4] Carbone, G. and Bottiglione, F., Editorial: Adhesion, friction and lubrication of viscoelastic
materials, Lubricants, 2021, 9, 23.
[5] Roylance, D., Engineering viscoelasticity, MIT's Department of Materials Science and
Engineering, 2001.
[6] Krishnan, P., Rheology of epoxy/rubber blends, In: The Handbook of Epoxy Blends,
Parameswaranpillai, J., Ed., et.al., Springer, Switzerland, 2017, 185–210.
[7] Weiss, M. and Elmer, F. J., Dry friction in the Tomlinson-Kontoraova-Frenkel model: Static
properties, Physical Review B, 1996, 53, 7539.
[8] Matsuoka, S., Relaxation Phenomena in Polymers, Chapter 3: Glassy State, Hanser
Publishers, Munich, 1992, 80.
[9] Kolsky, H., Viscoelastic Waves, International Symposium on Stress Wave Propagation in
Materials, In: Davids, N., Ed., Interscience Publishers Inc, New York, 1960, 59.
[10] Perepechko, I. I., An Introduction to Polymer Physics, Mir Publishers, Moscow, 1981, 209.
[11] Feynman, R. P., Leighton, R. B., and Sands, M., The Feynman Lectures on Physics Vol:2,
Mainly Electromagnetism and Matter, Narosa, New Delhi, 1995, 1049.
[12] Nosonovsky, M. and Mortazavi, V., Friction-Induced Vibrations and Self-Organization
Mechanics and Non-Equilibrium Thermodynamics of Sliding Contact, CRC Press, FL, USA,
2014.
[13] Sinha, S. K. and Briscoe, B. J., Polymer Tribology, Imperial college Press, London, 2009.
[14] Padmanabhan, K., Comments on standards on restoratives, Indian Journal of Dental
Research, 2009, 20(4), 514.
[15] Padmanabhan, K., The need to revise standards on dental restoratives – a commentary,
Current Science, 25 August 2006, 91(4), 418.
[16] Bergantin, R., Maru, M. M., Farias, M. C. M., and Padovese, L. R., Dynamic signal analyses in
dry sliding wear tests, Journal of the Brazilian Society of Mechanical Sciences and
Engineering, Sept 2003, 25(3), doi: https://doi.org/10.1590/S1678-58782003000300011.
[17] Menezes, P. L., Nosonovsky, M., Ingole, S. P., Kailas, S. V., and Lovell, M. R., Tribology for
Scientists and Engineers, Springer, 2013, 295–340.
[18] Nak-Ho, S. and Suh, N. P., Effect of fiber orientation on friction and wear of fiber reinforced
polymeric composites, Wear, 1979, 53(1), 129–141.
[19] Vižintin, J., Kalin, M., Jahanmir, S., and Dohda, K., Tribology of Mechanical Systems:
A Guide to Present and Future Technologies, American Society of Mechanical Engineers,
USA, 2004.
[20] Nagarajan, V. S., Hockey, B. J., Jahanmir, S., and Thompson, V. P., Contact wear mechanisms
of a dental composite with high filler content, Journal of Materials Science, 2000, 35(2),
487–496.
[21] Lee, J. H., Xu, G. H., and Liang, H., Experimental and numerical analysis of friction and wear
behavior of polycarbonate, Wear, 2001, 251(1–12), 1541–1556.
56 Padmanabhan Krishnan
[22] Moreau, J. L., Weir, M. D., Giuseppetti, A. A., Chow, L. C., Antonucci, J. M., and Xu, H. H. K.,
Long-term mechanical durability of dental nanocomposites containing amorphous calcium
phosphate nanoparticles, Journal of Biomedical Materials Research. Part B, Applied
Biomaterials, April 2012, doi: https://doi.org/10.1002/jbm.b.32691.
[23] Rutherford, K. L., Trezona, R. I., Ramamurthy, A. C., and Hutchings, I. M., The abrasive and
erosive wear of polymeric paint films, Wear, 1997, 203–204, 325–334.
Viscoelastic response of hybrid polymeric dental composites 57
Viscoelastic response of polymeric solids in sliding contacts

More Related Content

Similar to Viscoelastic response of polymeric solids in sliding contacts

Investigation on the behaviour of alfa composite in pre and post heat treated...
Investigation on the behaviour of alfa composite in pre and post heat treated...Investigation on the behaviour of alfa composite in pre and post heat treated...
Investigation on the behaviour of alfa composite in pre and post heat treated...
eSAT Journals
 
Experimental Study of the Fatigue Strength of Glass fiber epoxy and Chapstan ...
Experimental Study of the Fatigue Strength of Glass fiber epoxy and Chapstan ...Experimental Study of the Fatigue Strength of Glass fiber epoxy and Chapstan ...
Experimental Study of the Fatigue Strength of Glass fiber epoxy and Chapstan ...
IJMER
 
Adhesion characterization of SiO2 thin films evaporated onto a polymeric subs...
Adhesion characterization of SiO2 thin films evaporated onto a polymeric subs...Adhesion characterization of SiO2 thin films evaporated onto a polymeric subs...
Adhesion characterization of SiO2 thin films evaporated onto a polymeric subs...
IJOEAR Agriculture Research Journal
 
Investigation on 3-body abrasive behaviour of glass fiber and ramie fiber rei...
Investigation on 3-body abrasive behaviour of glass fiber and ramie fiber rei...Investigation on 3-body abrasive behaviour of glass fiber and ramie fiber rei...
Investigation on 3-body abrasive behaviour of glass fiber and ramie fiber rei...
IRJET Journal
 
International Journal of Computational Engineering Research(IJCER)
International Journal of Computational Engineering Research(IJCER)International Journal of Computational Engineering Research(IJCER)
International Journal of Computational Engineering Research(IJCER)
ijceronline
 
MECHANICAL & THERMAL PROPERTIES OF NANO COMPOSITES
MECHANICAL & THERMAL PROPERTIES OF NANO COMPOSITESMECHANICAL & THERMAL PROPERTIES OF NANO COMPOSITES
MECHANICAL & THERMAL PROPERTIES OF NANO COMPOSITES
Arjun K Gopi
 
Preparation and characterisation of alumina nanocomposites with aramid fibre ...
Preparation and characterisation of alumina nanocomposites with aramid fibre ...Preparation and characterisation of alumina nanocomposites with aramid fibre ...
Preparation and characterisation of alumina nanocomposites with aramid fibre ...
eSAT Journals
 
Design and Analysis of Composite Bolt
Design and Analysis of Composite BoltDesign and Analysis of Composite Bolt
Design and Analysis of Composite Bolt
IRJET Journal
 
An Experimental Analysis to Determine Ultimate Tensile Strength of Jute Reinf...
An Experimental Analysis to Determine Ultimate Tensile Strength of Jute Reinf...An Experimental Analysis to Determine Ultimate Tensile Strength of Jute Reinf...
An Experimental Analysis to Determine Ultimate Tensile Strength of Jute Reinf...
IJSRD
 
Comparison and Optimization of Wear Rates of Two Types of Dental Composites O...
Comparison and Optimization of Wear Rates of Two Types of Dental Composites O...Comparison and Optimization of Wear Rates of Two Types of Dental Composites O...
Comparison and Optimization of Wear Rates of Two Types of Dental Composites O...
inventionjournals
 
Summary
SummarySummary
Electrospn 3 clerck-full
Electrospn 3 clerck-fullElectrospn 3 clerck-full
Electrospn 3 clerck-full
miroli
 
Research Paper on Nacre
Research Paper on NacreResearch Paper on Nacre
Research Paper on Nacre
Chinweike Osubor
 
Effect of stacking sequence and hybridization on the tensile and flexural pro...
Effect of stacking sequence and hybridization on the tensile and flexural pro...Effect of stacking sequence and hybridization on the tensile and flexural pro...
Effect of stacking sequence and hybridization on the tensile and flexural pro...
International journal of scientific and technical research in engineering (IJSTRE)
 
Paper2
Paper2Paper2
EFFECT OF NANO RUBBER ADDITIONS ON WEAR AND MECHANICAL PROPERTIES OF EPOXY GL...
EFFECT OF NANO RUBBER ADDITIONS ON WEAR AND MECHANICAL PROPERTIES OF EPOXY GL...EFFECT OF NANO RUBBER ADDITIONS ON WEAR AND MECHANICAL PROPERTIES OF EPOXY GL...
EFFECT OF NANO RUBBER ADDITIONS ON WEAR AND MECHANICAL PROPERTIES OF EPOXY GL...
paperpublications3
 
A Study of Failure Criteria of Fibrous Composite Material...
A Study of Failure Criteria of Fibrous                     Composite Material...A Study of Failure Criteria of Fibrous                     Composite Material...
A Study of Failure Criteria of Fibrous Composite Material...
sudhakargeruganti
 
H1075262
H1075262H1075262
H1075262
IJERD Editor
 
International Journal of Engineering Research and Development
International Journal of Engineering Research and DevelopmentInternational Journal of Engineering Research and Development
International Journal of Engineering Research and Development
IJERD Editor
 
Stability Analysis of Journal Bearing Using Electro Rheological Fluid by Fini...
Stability Analysis of Journal Bearing Using Electro Rheological Fluid by Fini...Stability Analysis of Journal Bearing Using Electro Rheological Fluid by Fini...
Stability Analysis of Journal Bearing Using Electro Rheological Fluid by Fini...
ijsrd.com
 

Similar to Viscoelastic response of polymeric solids in sliding contacts (20)

Investigation on the behaviour of alfa composite in pre and post heat treated...
Investigation on the behaviour of alfa composite in pre and post heat treated...Investigation on the behaviour of alfa composite in pre and post heat treated...
Investigation on the behaviour of alfa composite in pre and post heat treated...
 
Experimental Study of the Fatigue Strength of Glass fiber epoxy and Chapstan ...
Experimental Study of the Fatigue Strength of Glass fiber epoxy and Chapstan ...Experimental Study of the Fatigue Strength of Glass fiber epoxy and Chapstan ...
Experimental Study of the Fatigue Strength of Glass fiber epoxy and Chapstan ...
 
Adhesion characterization of SiO2 thin films evaporated onto a polymeric subs...
Adhesion characterization of SiO2 thin films evaporated onto a polymeric subs...Adhesion characterization of SiO2 thin films evaporated onto a polymeric subs...
Adhesion characterization of SiO2 thin films evaporated onto a polymeric subs...
 
Investigation on 3-body abrasive behaviour of glass fiber and ramie fiber rei...
Investigation on 3-body abrasive behaviour of glass fiber and ramie fiber rei...Investigation on 3-body abrasive behaviour of glass fiber and ramie fiber rei...
Investigation on 3-body abrasive behaviour of glass fiber and ramie fiber rei...
 
International Journal of Computational Engineering Research(IJCER)
International Journal of Computational Engineering Research(IJCER)International Journal of Computational Engineering Research(IJCER)
International Journal of Computational Engineering Research(IJCER)
 
MECHANICAL & THERMAL PROPERTIES OF NANO COMPOSITES
MECHANICAL & THERMAL PROPERTIES OF NANO COMPOSITESMECHANICAL & THERMAL PROPERTIES OF NANO COMPOSITES
MECHANICAL & THERMAL PROPERTIES OF NANO COMPOSITES
 
Preparation and characterisation of alumina nanocomposites with aramid fibre ...
Preparation and characterisation of alumina nanocomposites with aramid fibre ...Preparation and characterisation of alumina nanocomposites with aramid fibre ...
Preparation and characterisation of alumina nanocomposites with aramid fibre ...
 
Design and Analysis of Composite Bolt
Design and Analysis of Composite BoltDesign and Analysis of Composite Bolt
Design and Analysis of Composite Bolt
 
An Experimental Analysis to Determine Ultimate Tensile Strength of Jute Reinf...
An Experimental Analysis to Determine Ultimate Tensile Strength of Jute Reinf...An Experimental Analysis to Determine Ultimate Tensile Strength of Jute Reinf...
An Experimental Analysis to Determine Ultimate Tensile Strength of Jute Reinf...
 
Comparison and Optimization of Wear Rates of Two Types of Dental Composites O...
Comparison and Optimization of Wear Rates of Two Types of Dental Composites O...Comparison and Optimization of Wear Rates of Two Types of Dental Composites O...
Comparison and Optimization of Wear Rates of Two Types of Dental Composites O...
 
Summary
SummarySummary
Summary
 
Electrospn 3 clerck-full
Electrospn 3 clerck-fullElectrospn 3 clerck-full
Electrospn 3 clerck-full
 
Research Paper on Nacre
Research Paper on NacreResearch Paper on Nacre
Research Paper on Nacre
 
Effect of stacking sequence and hybridization on the tensile and flexural pro...
Effect of stacking sequence and hybridization on the tensile and flexural pro...Effect of stacking sequence and hybridization on the tensile and flexural pro...
Effect of stacking sequence and hybridization on the tensile and flexural pro...
 
Paper2
Paper2Paper2
Paper2
 
EFFECT OF NANO RUBBER ADDITIONS ON WEAR AND MECHANICAL PROPERTIES OF EPOXY GL...
EFFECT OF NANO RUBBER ADDITIONS ON WEAR AND MECHANICAL PROPERTIES OF EPOXY GL...EFFECT OF NANO RUBBER ADDITIONS ON WEAR AND MECHANICAL PROPERTIES OF EPOXY GL...
EFFECT OF NANO RUBBER ADDITIONS ON WEAR AND MECHANICAL PROPERTIES OF EPOXY GL...
 
A Study of Failure Criteria of Fibrous Composite Material...
A Study of Failure Criteria of Fibrous                     Composite Material...A Study of Failure Criteria of Fibrous                     Composite Material...
A Study of Failure Criteria of Fibrous Composite Material...
 
H1075262
H1075262H1075262
H1075262
 
International Journal of Engineering Research and Development
International Journal of Engineering Research and DevelopmentInternational Journal of Engineering Research and Development
International Journal of Engineering Research and Development
 
Stability Analysis of Journal Bearing Using Electro Rheological Fluid by Fini...
Stability Analysis of Journal Bearing Using Electro Rheological Fluid by Fini...Stability Analysis of Journal Bearing Using Electro Rheological Fluid by Fini...
Stability Analysis of Journal Bearing Using Electro Rheological Fluid by Fini...
 

Recently uploaded

Computational Engineering IITH Presentation
Computational Engineering IITH PresentationComputational Engineering IITH Presentation
Computational Engineering IITH Presentation
co23btech11018
 
Recycled Concrete Aggregate in Construction Part III
Recycled Concrete Aggregate in Construction Part IIIRecycled Concrete Aggregate in Construction Part III
Recycled Concrete Aggregate in Construction Part III
Aditya Rajan Patra
 
Question paper of renewable energy sources
Question paper of renewable energy sourcesQuestion paper of renewable energy sources
Question paper of renewable energy sources
mahammadsalmanmech
 
Unit-III-ELECTROCHEMICAL STORAGE DEVICES.ppt
Unit-III-ELECTROCHEMICAL STORAGE DEVICES.pptUnit-III-ELECTROCHEMICAL STORAGE DEVICES.ppt
Unit-III-ELECTROCHEMICAL STORAGE DEVICES.ppt
KrishnaveniKrishnara1
 
2008 BUILDING CONSTRUCTION Illustrated - Ching Chapter 02 The Building.pdf
2008 BUILDING CONSTRUCTION Illustrated - Ching Chapter 02 The Building.pdf2008 BUILDING CONSTRUCTION Illustrated - Ching Chapter 02 The Building.pdf
2008 BUILDING CONSTRUCTION Illustrated - Ching Chapter 02 The Building.pdf
Yasser Mahgoub
 
Comparative analysis between traditional aquaponics and reconstructed aquapon...
Comparative analysis between traditional aquaponics and reconstructed aquapon...Comparative analysis between traditional aquaponics and reconstructed aquapon...
Comparative analysis between traditional aquaponics and reconstructed aquapon...
bijceesjournal
 
学校原版美国波士顿大学毕业证学历学位证书原版一模一样
学校原版美国波士顿大学毕业证学历学位证书原版一模一样学校原版美国波士顿大学毕业证学历学位证书原版一模一样
学校原版美国波士顿大学毕业证学历学位证书原版一模一样
171ticu
 
Iron and Steel Technology Roadmap - Towards more sustainable steelmaking.pdf
Iron and Steel Technology Roadmap - Towards more sustainable steelmaking.pdfIron and Steel Technology Roadmap - Towards more sustainable steelmaking.pdf
Iron and Steel Technology Roadmap - Towards more sustainable steelmaking.pdf
RadiNasr
 
A review on techniques and modelling methodologies used for checking electrom...
A review on techniques and modelling methodologies used for checking electrom...A review on techniques and modelling methodologies used for checking electrom...
A review on techniques and modelling methodologies used for checking electrom...
nooriasukmaningtyas
 
Generative AI leverages algorithms to create various forms of content
Generative AI leverages algorithms to create various forms of contentGenerative AI leverages algorithms to create various forms of content
Generative AI leverages algorithms to create various forms of content
Hitesh Mohapatra
 
Harnessing WebAssembly for Real-time Stateless Streaming Pipelines
Harnessing WebAssembly for Real-time Stateless Streaming PipelinesHarnessing WebAssembly for Real-time Stateless Streaming Pipelines
Harnessing WebAssembly for Real-time Stateless Streaming Pipelines
Christina Lin
 
Properties Railway Sleepers and Test.pptx
Properties Railway Sleepers and Test.pptxProperties Railway Sleepers and Test.pptx
Properties Railway Sleepers and Test.pptx
MDSABBIROJJAMANPAYEL
 
Recycled Concrete Aggregate in Construction Part II
Recycled Concrete Aggregate in Construction Part IIRecycled Concrete Aggregate in Construction Part II
Recycled Concrete Aggregate in Construction Part II
Aditya Rajan Patra
 
Eric Nizeyimana's document 2006 from gicumbi to ttc nyamata handball play
Eric Nizeyimana's document 2006 from gicumbi to ttc nyamata handball playEric Nizeyimana's document 2006 from gicumbi to ttc nyamata handball play
Eric Nizeyimana's document 2006 from gicumbi to ttc nyamata handball play
enizeyimana36
 
132/33KV substation case study Presentation
132/33KV substation case study Presentation132/33KV substation case study Presentation
132/33KV substation case study Presentation
kandramariana6
 
官方认证美国密歇根州立大学毕业证学位证书原版一模一样
官方认证美国密歇根州立大学毕业证学位证书原版一模一样官方认证美国密歇根州立大学毕业证学位证书原版一模一样
官方认证美国密歇根州立大学毕业证学位证书原版一模一样
171ticu
 
DEEP LEARNING FOR SMART GRID INTRUSION DETECTION: A HYBRID CNN-LSTM-BASED MODEL
DEEP LEARNING FOR SMART GRID INTRUSION DETECTION: A HYBRID CNN-LSTM-BASED MODELDEEP LEARNING FOR SMART GRID INTRUSION DETECTION: A HYBRID CNN-LSTM-BASED MODEL
DEEP LEARNING FOR SMART GRID INTRUSION DETECTION: A HYBRID CNN-LSTM-BASED MODEL
gerogepatton
 
哪里办理(csu毕业证书)查尔斯特大学毕业证硕士学历原版一模一样
哪里办理(csu毕业证书)查尔斯特大学毕业证硕士学历原版一模一样哪里办理(csu毕业证书)查尔斯特大学毕业证硕士学历原版一模一样
哪里办理(csu毕业证书)查尔斯特大学毕业证硕士学历原版一模一样
insn4465
 
ISPM 15 Heat Treated Wood Stamps and why your shipping must have one
ISPM 15 Heat Treated Wood Stamps and why your shipping must have oneISPM 15 Heat Treated Wood Stamps and why your shipping must have one
ISPM 15 Heat Treated Wood Stamps and why your shipping must have one
Las Vegas Warehouse
 
The Python for beginners. This is an advance computer language.
The Python for beginners. This is an advance computer language.The Python for beginners. This is an advance computer language.
The Python for beginners. This is an advance computer language.
sachin chaurasia
 

Recently uploaded (20)

Computational Engineering IITH Presentation
Computational Engineering IITH PresentationComputational Engineering IITH Presentation
Computational Engineering IITH Presentation
 
Recycled Concrete Aggregate in Construction Part III
Recycled Concrete Aggregate in Construction Part IIIRecycled Concrete Aggregate in Construction Part III
Recycled Concrete Aggregate in Construction Part III
 
Question paper of renewable energy sources
Question paper of renewable energy sourcesQuestion paper of renewable energy sources
Question paper of renewable energy sources
 
Unit-III-ELECTROCHEMICAL STORAGE DEVICES.ppt
Unit-III-ELECTROCHEMICAL STORAGE DEVICES.pptUnit-III-ELECTROCHEMICAL STORAGE DEVICES.ppt
Unit-III-ELECTROCHEMICAL STORAGE DEVICES.ppt
 
2008 BUILDING CONSTRUCTION Illustrated - Ching Chapter 02 The Building.pdf
2008 BUILDING CONSTRUCTION Illustrated - Ching Chapter 02 The Building.pdf2008 BUILDING CONSTRUCTION Illustrated - Ching Chapter 02 The Building.pdf
2008 BUILDING CONSTRUCTION Illustrated - Ching Chapter 02 The Building.pdf
 
Comparative analysis between traditional aquaponics and reconstructed aquapon...
Comparative analysis between traditional aquaponics and reconstructed aquapon...Comparative analysis between traditional aquaponics and reconstructed aquapon...
Comparative analysis between traditional aquaponics and reconstructed aquapon...
 
学校原版美国波士顿大学毕业证学历学位证书原版一模一样
学校原版美国波士顿大学毕业证学历学位证书原版一模一样学校原版美国波士顿大学毕业证学历学位证书原版一模一样
学校原版美国波士顿大学毕业证学历学位证书原版一模一样
 
Iron and Steel Technology Roadmap - Towards more sustainable steelmaking.pdf
Iron and Steel Technology Roadmap - Towards more sustainable steelmaking.pdfIron and Steel Technology Roadmap - Towards more sustainable steelmaking.pdf
Iron and Steel Technology Roadmap - Towards more sustainable steelmaking.pdf
 
A review on techniques and modelling methodologies used for checking electrom...
A review on techniques and modelling methodologies used for checking electrom...A review on techniques and modelling methodologies used for checking electrom...
A review on techniques and modelling methodologies used for checking electrom...
 
Generative AI leverages algorithms to create various forms of content
Generative AI leverages algorithms to create various forms of contentGenerative AI leverages algorithms to create various forms of content
Generative AI leverages algorithms to create various forms of content
 
Harnessing WebAssembly for Real-time Stateless Streaming Pipelines
Harnessing WebAssembly for Real-time Stateless Streaming PipelinesHarnessing WebAssembly for Real-time Stateless Streaming Pipelines
Harnessing WebAssembly for Real-time Stateless Streaming Pipelines
 
Properties Railway Sleepers and Test.pptx
Properties Railway Sleepers and Test.pptxProperties Railway Sleepers and Test.pptx
Properties Railway Sleepers and Test.pptx
 
Recycled Concrete Aggregate in Construction Part II
Recycled Concrete Aggregate in Construction Part IIRecycled Concrete Aggregate in Construction Part II
Recycled Concrete Aggregate in Construction Part II
 
Eric Nizeyimana's document 2006 from gicumbi to ttc nyamata handball play
Eric Nizeyimana's document 2006 from gicumbi to ttc nyamata handball playEric Nizeyimana's document 2006 from gicumbi to ttc nyamata handball play
Eric Nizeyimana's document 2006 from gicumbi to ttc nyamata handball play
 
132/33KV substation case study Presentation
132/33KV substation case study Presentation132/33KV substation case study Presentation
132/33KV substation case study Presentation
 
官方认证美国密歇根州立大学毕业证学位证书原版一模一样
官方认证美国密歇根州立大学毕业证学位证书原版一模一样官方认证美国密歇根州立大学毕业证学位证书原版一模一样
官方认证美国密歇根州立大学毕业证学位证书原版一模一样
 
DEEP LEARNING FOR SMART GRID INTRUSION DETECTION: A HYBRID CNN-LSTM-BASED MODEL
DEEP LEARNING FOR SMART GRID INTRUSION DETECTION: A HYBRID CNN-LSTM-BASED MODELDEEP LEARNING FOR SMART GRID INTRUSION DETECTION: A HYBRID CNN-LSTM-BASED MODEL
DEEP LEARNING FOR SMART GRID INTRUSION DETECTION: A HYBRID CNN-LSTM-BASED MODEL
 
哪里办理(csu毕业证书)查尔斯特大学毕业证硕士学历原版一模一样
哪里办理(csu毕业证书)查尔斯特大学毕业证硕士学历原版一模一样哪里办理(csu毕业证书)查尔斯特大学毕业证硕士学历原版一模一样
哪里办理(csu毕业证书)查尔斯特大学毕业证硕士学历原版一模一样
 
ISPM 15 Heat Treated Wood Stamps and why your shipping must have one
ISPM 15 Heat Treated Wood Stamps and why your shipping must have oneISPM 15 Heat Treated Wood Stamps and why your shipping must have one
ISPM 15 Heat Treated Wood Stamps and why your shipping must have one
 
The Python for beginners. This is an advance computer language.
The Python for beginners. This is an advance computer language.The Python for beginners. This is an advance computer language.
The Python for beginners. This is an advance computer language.
 

Viscoelastic response of polymeric solids in sliding contacts

  • 1. Part III: Applications and analysis
  • 2.
  • 3. Padmanabhan Krishnan Viscoelastic response of hybrid polymeric dental composites in sliding contacts and applications Abstract: The viscoelastic response of polymeric solids to sliding contact conditions is observed and analyzed with respect to the sliding speed, material composition, and geometry. It was discovered that polymeric solids produced their own distinct viscoelastic signatures that cause resonance at certain sliding speeds which can be explained with resonance conditions for electromagnetic waves. The observed vis- colelastic phenomenon is characterized with respect to the relaxation and recovery times for rigid polymeric solids. It is confirmatory as a demonstration of proof of existence of viscoelasticity and self-organization in these materials under sliding con- tact conditions. Viscoelastic observations are also made on the aged specimens in sliding contact. Keywords: Viscoelasticity, polymer, hybrid composites, surfaces, sliding contact, ageing, stress waves 1 Introduction Polymer-based composites with ceramic fillers are being increasingly used in dental applications as they combine the requirements for strength, fatigue, toughness, and bio-compatibility with enamel and wear resistance. The surface integrity and long-term wear performance of these materials is a key issue in deciding their suit- ability for dental applications. Pin on disc (POD) sliding wear testing of dental re- storative materials (amalgam, ceramics, polymers, and composites) is a widely accepted practice to generate data and evaluate the contact wear performance of these materials prior to other wear test methods approved for use in dentistry. Dur- ing the POD sliding wear of polymeric composites at loads ranging from a moderate contact load of 5 N to a load of 15 N corresponding to the occlusal forces on the molars, the choice of low sliding speeds of 2–5 mm/s was seen to produce some interesting and periodic distortions in the friction force trace that can be mistaken Padmanabhan Krishnan, School of Mechanical Engineering, Vellore Institute of Technology, Vellore 632014, India, e-mail: padmanabhan.k@vit.ac.in Acknowledgement: The author thanks VIT management and the School of Mechanical Engineering colleagues for the wonderful support and encouragement. https://doi.org/10.1515/9783110724684-003
  • 4. for machine-related vibrations to begin with and considered undesirable in the measurement of frictional force and estimation of the coefficient of friction. This new disruptive discovery was later proven to be viscoelastic in nature as the ma- chine vibrational frequencies were higher by an order or more. The discovery of such a viscoelastic response would lead to many important applications later. 2 Viscoelastic models and the phenomena In plastic materials, prolonged exposure to stress may cause noticeable and irre- versible deformation which must be taken into consideration when designing parts for structural and bio-medical applications. The susceptibility to permanently de- form under load or a relaxation mechanism under stress can be measured in creep and stress relaxation experiments, respectively [1–4]. In the simplest case, the re- laxation mechanism under a constant strain can be described with the help of one- dimensional Maxwell model which consists of a spring and dashpot in series. According to the model shown in Figure 1, an instantaneous strain causes only the elastic spring to initially deform, while the viscous dashpot slowly and gradually re- laxes and allows the spring to slowly return to the original condition. Thus, for times much shorter than the relaxation time, the Maxwell element behaves essentially like a spring, whereas for times much longer than the relaxation time, it behaves like a dashpot [5]. Figure 1: The Voigt and Maxwell viscoelastic models. 44 Padmanabhan Krishnan
  • 5. An ideal linear elastic material does not experience any relaxation process. This material can also be described with the Voigt model which consists of a spring paral- lel to a dash pot. In this arrangement, no relaxation takes place because the visco- elastic flow is restricted by the spring element. The viscoelastic behavior of real polymeric materials is much more complicated, that is, these materials neither fully relax nor are they ideally elastic. To accurately describe their relaxation be- havior, Maxwell and Voigt elements have to be combined with more complex ar- rangements. Zener arrangements and models are also exhibited by polymers that show a linear viscoelastic behavior which explains the creep and stress relaxation phenomena [6]. Zener models normally consist of Maxwell Kelvin–Voigt models in series or parallel arrangements. Burger materials are examples of a set of poly- mers obeying the viscoelastic models with the Maxwell material and Kelvin mate- rial in series [6]. To study this strange phenomenon in sliding contacts further, parameters like geometry (human enamel pin on polymeric disc or an alumina ball with a wider contact area on disc) and material microstructure of the pin as well as the disc {polymer-ceramic filler, ceramic filler-polymer-binder, and ceramic-(glassy)ceramic composites} were considered, and combinations of geometry and material systems were tried out to study the phenomenon further in a quantitative and methodical manner. The wear behavior of these materials was also studied using a POD appara- tus and the results, presented. 3 Experimental procedures The two composites used in this study were Hybrid Composite 1: A methacrylic ester matrix with silanated barium alumina sil- ica glass and silicon dioxide microfillers by 70 wt% with an average particle size of 1 μm. Hybrid Composite 2: A hybrid ceramic composite (enamel and dentin) with 92 wt% of fine glass (0.1–10 μm, average 2 μm, and microfiller < 0.1 μm). The resin being bis–glassy methacrylate (bis–GMA) and triethylene glycol methacrylate (TEGMA). Composite restorative discs of approximately 15 mm diameter and 3 mm thickness were prepared by light curing the samples between glass plates with inner Mylar™ film sheets (a thermoplastic-added polyester) and circular (polytetrafluoroethylene) dams of 3 mm thickness in order to obtain uniformly cured discs. The curing was for a time period between 60 and 120 s using a xenon light source with a strobe mode (Dentacolor XS, Heraeus Kulzer) based on manufacturer’s recommendations for indi- vidual pastes of raw materials in tubes. The fabricated discs were dry-polished using grit 600 abrasive paper which is the normal grit size used for restorative finishes and Viscoelastic response of hybrid polymeric dental composites 45
  • 6. finished with “Texmet” cloth to a maximum surface roughness of Rmax ~ 2.5 to 3.5 μm and an average roughness of Ra = 0.257 µm. Another set of discs were dry-polished to a surface roughness of Rmax ~ 0.9–1.5 μm using grit 1200 and “velvet” cloth to obtain a surface smoother than the average particle size down to about an Ra of 0.15 µm. Acetone was used in minimum quantities to clean the surfaces that were dried and then electric-blower-dried. Machined and polished human enamel pins from third maxillary molars and pins of the polymeric materials that constitute the disc were used, with a maximum possible tip roughness of 0.2 μm. Alumina balls (8.02 mm di- ameter) with an average surface roughness Ra of 0.1 μm were also considered as pin materials, but these were used as received. Needless to say, the contact area of the balls with the disc can be expected to be higher than the pins but Hertzian likewise. Thus, the counterfaces were defined. Sliding contact tests were conducted at 1–15 mm/s sliding speeds in a POD. A schematic sketch of the sinusoidal stress waves pro- duced at different revolutions per minute (rpm) is presented in Figure 2. This sketch also explains how viscoelastic signals lead to resonance when the wear track perimeter and the wavelength of a single signal match under specific ratios. Fric- tion force traces were obtained at various rpm. Some pins and discs were conditioned Figure 2: A schematic sketch of the sinusoidal stress waves produced at different rpm. 46 Padmanabhan Krishnan
  • 7. in distilled water at room temperature up to absorption saturation to obtain consistent wear data on distilled water-conditioned specimens and compare them with dry wear data. This process required that specimens be stored for any time between 3 days and 2 weeks until the sample weight was steady correct to 0.1 mg. Certain select specimens were aged for longer durations of up to 8 months and then wear-tested to evaluate the long-term effects on wear of these composites. This replicates the oral environment. The current investigation is a step further that reports a discovery that can aid in characterizing the mechanical properties of polymers and their composites by sliding contact tests and explains the phenomenon with examples. Ageing of the samples has also been investigated. 4 Results and discussion During the POD sliding wear of polymer-based composites using a CSEM tribometer (Geneva, Switzerland) at a load range of 5–15 N corresponding to moderate chewing to occlusal forces in the mouth, in dry and distilled water conditioned environment, the choice of the conventionally adopted low sliding speeds of 0–15 mm/s was seen to produce some interesting and periodic but secondary distortions, rendering the measurement of friction force and hence the determination of coefficient of friction unreliable. Such an observation and analysis seems to have missed the attention of others who have reported the mean coefficient of friction and related wear data on such composites under similar conditions. As the sliding speed is increased to 15 mm/s for wear track radii in the range of 4–5 mm, i.e. from ~ 10 rpm to 40 rpm for the disc dimensions in this study, low speed periodic, localized wave packets were observed as in Figures 3–6, if the material is a polymer or its composite viz. Composites 1 and 2. This was observed for any pin/ball geometry or material like its own counter- face, enamel, or alumina. To negate any influence of smoothening effects due to “wearing in,” the experiment was conducted by decreasing the sliding speed from 40 rpm to 10 rpm. Low speed distortions were still observed with the same ampli- tude. Here, Series 1 refers to Composite 1 and Series 2 refers to Composite 2. It was also seen that the amplitude of the wave like distortion was proportional to the polymer matrix content in the disc material. For example, Composite 1 which con- tains 30 wt% of methacrylic ester, a polymer, exhibited a higher amplitude of wave like signature than Composite 2 which contains only 8 wt% of polymer, a blend of bis-GMA/TEGMA (see Figure 2). The low rpm coefficient of friction varies by ~ ±10% at maxima in case of Composite 1 against alumina ball in dry conditions. The same composite exhibited an amplitude variation of up to ±75% at maxima with the human enamel as the pin material in the same conditions. Composite 1 disc with Composite 1 pin yielded wave packets similar in amplitude to those with the enamel Viscoelastic response of hybrid polymeric dental composites 47
  • 8. pin for the same geometry, except for a different range of friction force values. It was seen that the effect of damping due to pin geometry played a significant role in the magnitude of the amplitude of the wave packet for similar type of materials. The human molar pin, being functionally gradient with a softer dentin inside and a layer of enamel outside, produced resonance patterns with amplitude variations of up to ±75% at maxima. Further, the maximum amplitude of friction force traces was directly proportional to the normal load used in sliding contacts. Lower ranges of friction force values correspond to lower loads of 10 and 5 N, respectively, for the Figure 3: Coefficient of friction of Alumina Ball versus Composite 1 for dry sliding speeds of 40 rpm to 10 rpm. Figure 4: Coefficient of friction of Alumina Ball versus Composites 1 and 2 for dry sliding speeds of 10 rpm to 1 rpm. 48 Padmanabhan Krishnan
  • 9. set of materials used here. In general, the friction force trace for polymer compo- sites is stable without oscillations only at ~ 35 rpm and above. This holds true in dry as well as wet environments like distilled water. Needless to say, only 15 N tests will be discussed henceforth for clarity and amplitude of signatures. When ceramic discs like alumina or porcelain slide against a ceramic pin, there is no distortion at any of the sliding speeds chosen as above. However, Composite 2 does show a wave Figure 5: Friction force plots of Composites 1 and 2 versus Enamel Pin at 10–40 rpm in dry sliding conditions. Figure 6: A single wave train for the dry sliding of Alumina Ball versus Composite 1 at 10 rpm indicating resonance. Viscoelastic response of hybrid polymeric dental composites 49
  • 10. packet like distortion with a much lesser amplitude than Composite 1 due to a lower polymer binder content, for the same sliding speeds, thus confirming the vis- coelastic influence of the polymer on the anomalous friction traces. This is evident from Figures 4 and 5. For composite 1 against alumina ball in dry conditions, when the speed of test- ing was further lowered to 5 rpm, the wave train had an alternating strength of am- plitude that resembled one with a carrier/modulator ratio of 5, what one exactly comes across in wave transmission. When the rpm was reduced to 1, the wave train pattern completely disappeared, and only a single waveform was seen to occur ex- posing the linear viscoelastic response signal of the polymeric solid to the load ap- plied (see Figure 7). Schematically, this phenomenon is explained as shown in Figure 2, where the vibra- tional resonance due to the sinusoidal viscoelastic stress wave propagation is shown to arise from a 1:1 ratio between the viscoelastic wave length and the length of the circumference of the wear track on the disc at 10 rpm. When the viscoelastic response wavelength increases marginally at 5 and subsequently at 1 rpm, the resonance pat- tern disappears completely as the single viscoelastic stress wave manifests out of the packets due to a higher wavelength than the circumferential length. Since composites with various surface roughness values at various stages of experimentation were em- ployed in the study, it can be seen that the frictional force values are different along the time axis due to “wearing in,” but the amplitude and wavelength are consistent Figure 7: Coefficient of friction plots for dry sliding of Composite 1 vs. Alumina Ball showing a single stress wave at 1 rpm. 50 Padmanabhan Krishnan
  • 11. with the material properties, load, and speed of testing as conditions. A viscoelasti- cally distorting second phase is sometimes incorporated forming a frictionally differ- ent surface layer that is prone to wear, which can easily be inferred when the force traces transit. It is envisaged that each polymeric material or its composite produces its own characteristic signal that is a signature whose wavelength and amplitude de- pend on the normal load. The nature and contact area of the pin/ball affect the am- plitude of the 10 rpm resonance patterns due to the difference in vibration modes, but it has very little influence at 1 rpm due to the absence of the same. The sinusoidal waves resemble the stress waves which propagate in linear viscoelastic solids obey- ing a Maxwell or Zener/Burger parameter model under stretching. Since sliding wear gives rise to tensile forces at the surface due to contact stretching and shear forces with a strong gradient at a sub-surface plane, the same is manifested in the present case. A five-parameter model for hygrothermally degraded polymer, explaining every aspect of the observed phenomena for certain type of polymeric materials, is envis- aged for future work. The viscoelastic response of a polymeric material against a sur- face that distributes load in sliding contacts is the cause for such waveforms. The present viscoelastic behavior is seen to be (a) consisting of dilational and shear waves (see Figure 8), (b) producing subsurface shear waves, (c) a spring and dashpot model-based manipulation, (d) a secondary and segmental in polymer relaxation, and (e) a viscoelastic version similar to the Tomlinson and Frenkel–Kontorova atomic frictional models presented in Figure 9 [7]. Dilatational Shear u u P-waves S-waves z z Vp Vs Rayleigh wave E,V,P (a) (b) (c) Surface Figure 8: A schematic drawing of dilational, shear, and Raleigh waves generated in sliding contacts. Viscoelastic response of hybrid polymeric dental composites 51
  • 12. Self-organization can be adapted for the polymer molecular structures here, where the substrate is presented as a periodic energy profile created by the mole- cules, using the “m” or mass in the Tomlinson–Frenkel–Kontoraova model as a vis- cous dashpot and “k” the spring constant in series. This is similar to the Maxwell model where the dashpot and the spring are in series. The stress relaxation implies that the stress is time-dependent and varying as the pin moves around the disc sur- face in circles, causing the stress to increase and decrease due to instantaneous contact. Further, the strain that is developed is instantaneous in a POD experiment right under the pin at the interface and is almost negligible at the incipient or far behind locations. Hence, the strain in this case is localized, and the viscoelastic re- sponse models are also localized like a surf-riding situation. The developed stress waves behave like a fatigue wave train. Surface Raleigh waves are generated as shown in Figure 9 which can be used for in situ NDT (nondestructive testing) inspection. Though there is self-organization, over a longer time, thermal and hygrother- mal effects can relax the stress further, causing hygrothermo-mechanical fatigue. In short, the rpm speed at the given radius/radii and the resulting sliding velocity was comparable to the relaxation time, τ, of the polymeric solid for the conditions that allow such a viscoelastic reaction to take place. Normally, the mechanical relaxa- tion time (not volume) for a glassy polymer below its glass transition temperature ranges from seconds to minutes [8–10], and the evaluation of relaxation time, τ, for a polymer filled with inorganic particles, based on the relationships for a linear vis- coelastic solid [8, 9], gives us a static frequency range of ω = 0.1–1 for tan δ = 0.001 to 0.1 as a dynamic mechanical analysis (DMA) test would prove for polymers. The relationship ωτ = 1 gets us an approximate value of 1–10 s for the relaxation time for these two polymer composites. Since there is time (t ≫ τ) for viscous reaction to take place at a low rpm value of 1 (for radius of 4–5 mm), the time-dependent stress, σt, drops and rises depending on the relaxation and recovery times. It is observed that this is not a stick-slip behavior which manifests as a saw-tooth waveform in the wear of materials but a sinusoidal stress wave as a result of viscoelasticity of the polymeric material. When the rpm increases, the material behaves elastically since the time for such a viscous reaction to take place is not available, as t ≪ τ. At an intermediate 10 rpm speed, the resonance occurring due to the viscoelastic re- sponse of the material was not noticed in the 8 month distilled water aged Compos- ite 1 samples as the wavelength of the friction force trace was obviously longer due to time-dependent viscoelasticity, and the ratio for resonance was not met with. It leads us to believe that the viscoelastic response curve of an non-aged specimen at m m m m m k k k k Figure 9: A schematic drawing of the Tomlinson and Frenkel–Kontorova atomic friction model. 52 Padmanabhan Krishnan
  • 13. 10 rpm is much shorter in order to obtain a wave train as shown in Figure 6, thereby rendering support to the evidence that vibrational resonance due to viscoelastic re- sponse of a polymer composite material to loading occurs when t = τ. The condition for resonance, in order to obtain such a wave train, is very much similar to the Max- well resonance condition for oscillation of fields as given in Feynman lectures [11]: ω0 = 2.405 c=r f g (1) where ω0 is the resonant frequency, c the velocity, and r the radius of the wear track that was discussed [9]. It is seen that the constant 2.405 can be interpreted as the result of the path length of the wave train divided by the path length of the individual viscoelastic signal, which is in fact the condition for resonance. The radius of the disc can be substituted for r to obtain the condition for resonance. It is indeed interesting to note the similarity between acousto-mechanical and electromagnetic resonance conditions. The Maxwell resonant frequency in the present investigation, ω0, would be less than 5 Hz in this case when we substitute for c and r. Here, the linear- viscoelastic stress waves are in packets at certain speeds of sliding and represent the viscoelastic and resonant stress wave propagation in the polymeric solid due to slid- ing contact. As discussed earlier in Figure 2, the phenomenon of resonance originates due to the coincidence of the viscoelastic signal wavelength with the perimeter of the wear track, or in other words, one rpm. The smooth attenuation of the friction force traces at rpm closer to 40 is a result of an elastic behavior as discussed before. Further, dynamic damping can occur when the material is both dissipative and dispersive [10] causing attenuation of the friction force traces due to the dilational stress component reducing and the shear stress component taking over. At higher loads and lower rpm, the attenuation might be advanced. It is expected that the surface Raleigh waves generated due to friction play a role in resonance at higher speeds and not in the viscoelastic re- sponse at low rpm [12]. An acceptable level of treatise is presented on polymer tri- bology by Sinha and Briscoe [13]. But this book does not deal with viscoelasticity or the effect of aggressive environment on polymer tribology. It is proposed to conduct monolithic unfilled polymer sliding contact tests in a lin- ear reciprocating wear tester and confirm the precision and accuracy of the viscoelastic signals, relaxation, and retardation times and resonance conditions which would lead to the design and manufacture of viscoelastic testers that can correlate the viscoelastic properties with the mechanical properties and predict the thermo-mechanical behavior of polymers under controlled environment. At sub-zero temperatures, the threshold transition from viscoelastic to elastic behavior can also be predicted in the presence of a ductile to brittle transition. Viscoelastic response can also be appreciable when the hygrothermal attack on restoratives and other polymer composites is appreciable. A detailed account of the do’s and don’ts that involve the required specifications for hygrothermal conditioning, postsaturation equilibration, and tribology of polymer composites is presented in the investigations as done earlier [14, 15]. As viscoelasticity Viscoelastic response of hybrid polymeric dental composites 53
  • 14. is appreciable in the postsaturated and water-equilibrated polymers and restoratives, these two references are considered significant. It is ascertained that it is not the ma- chine natural frequency which falls between 50 and 1500 Hz as reported in literature for similar machines [16], but a viscoelastic phenomenon whose relaxation times and resonant frequencies with the POD geometry is much lower as evaluated here. 5 Erratum in existing literature and scope Many publications have emerged in the last few decades that have either chosen to ignore or just ignored the important aspect of viscoelastic interactions and mecha- nisms in sliding contacts and wear of polymeric solids. Books, book chapters, and research articles by tribology researchers have ended up measuring, assessing, and evaluating wear, lubrication, and friction in polymeric solids without considering the appreciable effects of viscoelasticity on these parameters [17–23]. As the friction force traces in the low speed domain are significantly dependent on the viscoelastic response of the material to sliding contact, any measurement of the friction force traces that ignores these aspects without a regard for sensitivity is bound to be erro- neous. Wear rates and wear volumes too depend on the material removed, and the material just displaced out of the wear track due to viscoelasticity. Hence, their measurement too is a suspect. Though viscoelasticity of polymers is a known phe- nomenon, it has not been seriously considered by tribologists and machinists as a significantly contributing subject in the evaluation of polymeric solids and their ap- plications. The publications chosen here to highlight the issue are only an act of serendipity and not choice. The real number is staggering and needs withdrawal or revision of the data and the publications, if the conditions stated in this chapter are encountered. The scope of viscoelasticity-based studies is very vast as polymeric solids are known to be hygrothermally susceptible that renders them nonlinear – a more complicated deviation from their linear viscoelasticity which is exhibited by rigid polymers and their composites at normal pressures and room temperatures. As nonlinear viscoelasticity demands the use of five-parameter models and similar conformations in series or parallel, lot of scope exists in the study of these mecha- nisms in the tribological modeling of such systems. The next section provides more detail about the mechanisms and applications of this phenomena in tribology and machining. 54 Padmanabhan Krishnan
  • 15. 6 Applications of the viscoelasticity phenomena in sliding contact The following are some of the salient features and applications of the discovery of the phenomenon of viscoelasticity in sliding contact mechanisms; 1. It provides a quick test method to assess the viscoelastic response of polymeric solids to sliding contact mechanisms. 2. A correlation of the viscoelastic properties with the mechanical properties is possible that would help in evaluating the mechanical properties of a polymeric solid from a knowledge of its viscoelastic response. 3. It is proposed as a single test that would evaluate the quasi-static mechanical prop- erties and the tribological properties with an acceptable level of approximation. 4. A linear reciprocating wear test apparatus with an associated specific software would suffice to achieve this phenomenally easy way of evaluating the mechan- ical properties of a solid polymer. 5. This method serves as an easy to perform substitute dynamic mechanical ana- lyzer as the relaxation and retardation times can be evaluated with an approxi- mate assessment of the storage and loss modulus. 6. It helps in a quick materials selection process for ductile and ductile–brittle solid polymers with viscoelastic properties. 7. A detailed study of viscoelastic fatigue is possible as an outcome of this investi- gation. A viscoelastic thermal or hygro-thermal cut off can be evaluated in a tribological test where thermal or hygorthermal frictional softening effects could be quantified and the design limits, set to a required level. 7 Summary and conclusions This investigation on sliding contact friction of polymeric solids illustrates and ex- plains the existence of viscoelastic response through analysis of the friction force traces that result from contact sliding under loads. The factors influencing the char- acterization of the viscoelastic and elastic properties of polymeric solids in sliding contacts viz. the relaxation time, the viscous reaction due to ageing and condition for resonance, are discussed. The Maxwell and other relevant models that seek to explain this phenomenon are highlighted and explained. It is proposed to use this phenomenon to evaluate the elastic and viscoelastic properties of virgin polymers and filled polymers with various processing, testing, and environmental conditions to aid in their complete hygrothermo-mechanical characterization through an un- derstanding of sliding contact mechanics. The salient applications of the discovery of viscoelastic phenomena in sliding contacts are also predicted. Viscoelastic response of hybrid polymeric dental composites 55
  • 16. References [1] Drozdov, A. D., Viscoelastic Structures, Academic Press, New York, 1998. [2] Findley, W. N., Lai, J. S., and Onaran, K., Creep and Relaxation of Nonlinear Viscoelastic Materials, Dover, New York, 1989. [3] Torskaya, E. V. and Stepanov, F. I., Effect of surface layers in sliding contact of Viscoelastic Solids ( 3D Model of Material), Frontiers in Mechanical Engineering, 09 May 2019, doi: https://doi.org/10.3389/fmech2019.00026. [4] Carbone, G. and Bottiglione, F., Editorial: Adhesion, friction and lubrication of viscoelastic materials, Lubricants, 2021, 9, 23. [5] Roylance, D., Engineering viscoelasticity, MIT's Department of Materials Science and Engineering, 2001. [6] Krishnan, P., Rheology of epoxy/rubber blends, In: The Handbook of Epoxy Blends, Parameswaranpillai, J., Ed., et.al., Springer, Switzerland, 2017, 185–210. [7] Weiss, M. and Elmer, F. J., Dry friction in the Tomlinson-Kontoraova-Frenkel model: Static properties, Physical Review B, 1996, 53, 7539. [8] Matsuoka, S., Relaxation Phenomena in Polymers, Chapter 3: Glassy State, Hanser Publishers, Munich, 1992, 80. [9] Kolsky, H., Viscoelastic Waves, International Symposium on Stress Wave Propagation in Materials, In: Davids, N., Ed., Interscience Publishers Inc, New York, 1960, 59. [10] Perepechko, I. I., An Introduction to Polymer Physics, Mir Publishers, Moscow, 1981, 209. [11] Feynman, R. P., Leighton, R. B., and Sands, M., The Feynman Lectures on Physics Vol:2, Mainly Electromagnetism and Matter, Narosa, New Delhi, 1995, 1049. [12] Nosonovsky, M. and Mortazavi, V., Friction-Induced Vibrations and Self-Organization Mechanics and Non-Equilibrium Thermodynamics of Sliding Contact, CRC Press, FL, USA, 2014. [13] Sinha, S. K. and Briscoe, B. J., Polymer Tribology, Imperial college Press, London, 2009. [14] Padmanabhan, K., Comments on standards on restoratives, Indian Journal of Dental Research, 2009, 20(4), 514. [15] Padmanabhan, K., The need to revise standards on dental restoratives – a commentary, Current Science, 25 August 2006, 91(4), 418. [16] Bergantin, R., Maru, M. M., Farias, M. C. M., and Padovese, L. R., Dynamic signal analyses in dry sliding wear tests, Journal of the Brazilian Society of Mechanical Sciences and Engineering, Sept 2003, 25(3), doi: https://doi.org/10.1590/S1678-58782003000300011. [17] Menezes, P. L., Nosonovsky, M., Ingole, S. P., Kailas, S. V., and Lovell, M. R., Tribology for Scientists and Engineers, Springer, 2013, 295–340. [18] Nak-Ho, S. and Suh, N. P., Effect of fiber orientation on friction and wear of fiber reinforced polymeric composites, Wear, 1979, 53(1), 129–141. [19] Vižintin, J., Kalin, M., Jahanmir, S., and Dohda, K., Tribology of Mechanical Systems: A Guide to Present and Future Technologies, American Society of Mechanical Engineers, USA, 2004. [20] Nagarajan, V. S., Hockey, B. J., Jahanmir, S., and Thompson, V. P., Contact wear mechanisms of a dental composite with high filler content, Journal of Materials Science, 2000, 35(2), 487–496. [21] Lee, J. H., Xu, G. H., and Liang, H., Experimental and numerical analysis of friction and wear behavior of polycarbonate, Wear, 2001, 251(1–12), 1541–1556. 56 Padmanabhan Krishnan
  • 17. [22] Moreau, J. L., Weir, M. D., Giuseppetti, A. A., Chow, L. C., Antonucci, J. M., and Xu, H. H. K., Long-term mechanical durability of dental nanocomposites containing amorphous calcium phosphate nanoparticles, Journal of Biomedical Materials Research. Part B, Applied Biomaterials, April 2012, doi: https://doi.org/10.1002/jbm.b.32691. [23] Rutherford, K. L., Trezona, R. I., Ramamurthy, A. C., and Hutchings, I. M., The abrasive and erosive wear of polymeric paint films, Wear, 1997, 203–204, 325–334. Viscoelastic response of hybrid polymeric dental composites 57