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Transport Phenomena
Introduction
By
Dr Sourav Poddar
Department of Chemical Engineering
National Institute of Technology, Tiruchirappalli
• Vector and Tensor Analysis
• Momentum Transport
• Heat Transfer
• Mass Transport
Vector and Tensor Analysis
Introduction
Transport Phenomena is the subject which deals with the movement of different physical quantities in any chemical
or mechanical process and describes the basic principles and laws of transport. It also describes the relations and
similarities among different types of transport that may occur in any system. Transport in a chemical or mechanical
process can be classified into three types:
1. Momentum transport deals with the transport of momentum in fluids and is also known as fluid dynamics.
2. Energy transport deals with the transport of different forms of energy in a system and is also known as heat
transfer.
3.Mass transport deals with the transport of various chemical species themselves.
Three different types of physical quantities are used in transport phenomena: scalars
(e.g. temperature, pressure and concentration), vectors (e.g. velocity, momentum and
force) and second order tensors (e.g. stress or momentum flux and velocity gradient). It
is essential to have a primary knowledge of the mathematical operations of scalar,
vector and tensor quantities for solving the problems of transport phenomena. In fact,
the use of the indicial notation in cartesian coordinates will enable us to express the
long formulae encountered in transport phenomena in a concise and compact fashion.
In addition, any equation written in vector tensor form is equally valid in any
coordinate system.
In this course, we will be using the following notations for scalar, vector and tensor quantities:
notations:
a, b, c scalar quantities
vector quantities
2nd order tensor quantities
Cartesian coordinates and unit vectors
A xyz cartesian coordinate system may also be conventionally written as shown in Fig.1.1 below.
Fig. 1.1 3-dimensional cartesian coordinate system with unit vector
Here, and are the unit vectors in x, y and z direction respectively.
Tensor quantities
Most of us might have already encountered scalars and vectors in the study of high-school physics. It was pointed
out that the vectors also have a direction associated with them along with a magnitude, whereas scalars only have
a magnitude but no direction. Extending this definition, we can loosely define a 2nd order tensor as a physical
quantity which has a magnitude and two different directions associated with it. To better understand, why we
might need two different directions for specifying a particular physical quantity. Let us take the example of the
stresses which may arise in a solid body, or in a fluid. Clearly, the stresses are associated with magnitude of forces,
as well as with an area, whose direction is also need to be specified by the outward normal to the face of the area
on which a particular force acting. Hence, we will require 32, i.e., 9 components to specify a stress completely in a
3 dimensional cartesian coordinate system. In general, an nth order tensor will be specified by 3n components (in a
3-dimensional system). However, the number of components alone cannot determine whether a physical quantity
is a vector or a tensor. The additional requirement is that there should be some transformation rule for obtaining
the corresponding tensors when we rotate the coordinate system about the origin. Thus, the tensor quantities can
be defined by two essential conditions:
1. These quantities should have 3n components. According to this
definition, scalar quantities are zero order tensors and have 30=
1 component. Vector quantities are first order tensors and have 31 =
3 components. Second order tensors have 32 = 9 components and
third order tensors have 33 = 27 components. Third and higher order
tensors are not used in transport phenomena, and are not dealt here.
2. The second necessary requirement of any tensor quantity is that it
should follow some transformation rule.
Kronecker delta & Alternating Unit Tensor
There are two quantities which are quite useful in conveniently and concisely expressing several mathematical
operations on tensors. These are the Kronecker delta and the alternating unit tensor.
Kronecker delta
Kronecker delta or Kronecker’s delta is a function of two index variables, usually integer, which is 1 if they
are equal and 0 otherwise.
It is expressed as a symbol δij
δij=1, if i=j
δij=0, if i≠j
Thus, in three dimensions, we may also express the Kronecker delta in matrix form
Alternating unit tensor
The alternating unit tensor εijk is useful when expressing certain results in a compact form in index notation. It
may be noted that the alternating unit tensor has three index and therefore 27 possible combinations but it is a
scalar quantity
• εijk= 0 if any two of indices i, j, k are equal. For example ε113,ε131,ε111,ε222=0
• εijk= +1 when the indices i, j, k are different and are in cyclic order (123), For example ε123
 εijk=-1 when the indices i, j, k are different and are in anti-cyclic order. For example ε321
Free indices and Dummy indices
Free indices
Free indices are the indices which occur only once in each tensor term. For example, i is the free index in
following expression vij wj
In any tensorial equation, every term should have an equal number of free indices. For example, vij wj =cj dj is not
a valid tensorial expression since the number of free indices (index i) is not equal in both terms.
Any free indices in a tensorial expression can be replaced by any other indices as long as this symbol has not
already occurred in the expression. For example, Aij Bj= CiDjEj is equivalent to Akj Bj= CkDjEj
The number of free indices in an equation gives the actual number of mathematical equations that will arise from
it. For example, in equation Aij Bj= CiDjEj corresponds to 31 = 3 equations since there is only one free
indices i. It may be noted that each indices can take value i=1, 2 or 3.
Dummy indices
Dummy indices are the indices that occur twice in a tensor term. For example, j is the dummy
index in Aij Bj.
Any dummy index implies the summation of all components of that tensor term associated with
each coordinate axis. Thus, when we write Aiδi, we actually imply
Any dummy index in a tensor term can be replaced by any other symbol as long as this
symbol has not already occurred in previous terms. For example, Aijkδjδk= Aipqδpδq.
Note: The dummy indices can be renamed in each term separately in a equations but free indices should be
renamed for all terms in a tensor equations. For example, Aij Bj= CiDjEj can be replaced by Akp Bp= CkDjEj.
Here, i is the free index which has been replaced by k in both terms but j is a dummy index and can be replaced
either in one term or both.
Summation convention in vector and tensor analysis
According to the summation convention rule, if k is a dummy index
which repeats itself in a term then there should be a summation sign
associated with it. Therefore, we can eliminate the implied summation
sign and can write the expression in a more compact way. For example,
using the summation convention
can be simply written as εijkεljk . Since j and k are repeating, there is no need to
write summation sign over these indices
Relation between alternating unit tensor and Kronecker delta
When two indices are common between the two alternating unit tensors, that the following can be shown easily
.......................................................................(2.1)
When one index is common between the two alternating unit tensors, there product may be written as
.......................................................................(2.2)
16
Mathematics Review
A.1 Vectors
A.1.1 Definitions
A.1.2 Products
A.1.2.1 Scalar Products A.1.2.2 Vector Product
V.W = |v| |W|cos(V,W)
= vxwx + vywy + vzwz
V x W = |v||W|sin(V,W) nvw
V = vx ex + vyey + vzez
ex ey ez
vx vy vz
wx wy wz
=
(b) Divergence of vector field
Dot product of the del operator and a vector quantity is called the divergence
of vector field. It is a scalar quantity. If is a vector quantity then
divergence of a vector field is
24
A.2 Tensors
A.2.1 Definitions
A tensor (2nd order) has nine components, for example, a stress tensor
can be expressed in rectangular coordinates listed in the following:
A.2.2 Product
The tensor product of two vectors v and w, denoted as vw, is a tensor defined by
xx xy xz
yx yy yz
zx zy zz
  
  
  
 
 
  
 
 
τ
 
x x x x y x z
y x y z y x y y y z
z x z y z z
z
v v w v w v w
v w w w v w v w v w
v w v w v w
v
   
   
 
   
 
 
 
 
vw
[A.2-1]
[A.2-2]
Explanation (Borisenko, p64)
25
The vector product of a tensor  and a vector v, denoted by .v is a vector defined by
   
 
x
xx xy xz
yx yy yz y
zx zy zz z
x xx y xy z xz x yx y yy z yz
x zx y zy z zz
x y
z
v
v v
v
v v v v v v
v v v
  
  
  
     
  
 
 
 
 
   
 
   
   
     
  
τ
e e
e
[A.2-3]
   
 
  
 
x
x x x y x z
y x y y y z y
z x z y z z z
x x x x y y x z z y x x y y y y z z
z x x z y y z z z
x y z x x y y z z
x y
z
x y z
n
v v v v v v
v v v v v v n
v v v v v v n
v v n v v n v v n v v n v v n v v n
v v n v v n v v n
v v v v n v n v n
 
 
 
 
   
 
   
   
     
  
    
 
vv n
e e
e
e e e
v v n [A.2-5]
The product between a tensor vv and a vector n is a vector
26
The scalar product of two tensors s and , denoted as s:, is a scalar defined by
: :
xx xy xz xx xy xz
yx yy yz yx yy yz
zx zy zz zx zy zz
xx xx xy yx xz zx yx xy yy yy yz zy
zx xz zy yz zz zz
s s s   
s s s   
s s s   
s  s  s  s  s  s 
s  s  s 
   
   
    
   
   
     
  
σ τ
[A.2-6]
: :
x x x y x z xx xy xz
y x y y y z yx yy yz
z x z y z z zx zy zz
x x xx x y yx x z zx y x xy y y yy y z zy
z x xz z y yz z z zz
v w v w v w
v w v w v w
v w v w v w
v w v w v w v w v w v w
v w v w v w
  
   
  
     
  
   
   
    
   
   
     
  
vw [A.2-7]
The scalar product of two tensors vw and  is
Physical quantity Multiplication sign
Scalar Vector Tensor None X ‧ :
Order 0 1 2 0 -1 -2 -4
Table A.1-1 Orders of physical quantities and their multiplication signs
2
x y z
x y z
  
   
  
e e e
x y z
s s s
s
x y z
  
   
  
e e e
A.3 Differential Operators
A.3.1 Definitions
The vector differential operation , called “del”, has components similar to those
of a vector. However, unlike a vector, it cannot stand alone and must operate on
a scalar, vector, or tensor function. In rectangular coordinates it is defined by
The gradient of a scalar field s, denoted as ▽ s, is a vector defined by
[A.3-1]
[A.3-2]
A.3.2 Products
The divergence of a vector field v, denoted as ▽‧v is a scalar .
[A.3-5]
 
v x y z x x y y z z
x y z
v v v
x y z
v v v
x y z
 
  
      
 
  
 
  
  
  
e e e e e e
Flux is defined as the amount that flows through a unit area per unit time
Flow rate is the volume of fluid which passes through a given surface per unit time
28
   
     
x y z x x y y z z
x y z
x y z
x y z
a av av av
x y z
av av av
x y z
v v v a a a
a v v v
x y z x y z
 
  
      
 
  
 
  
  
  
   
     
     
   
     
   
v e e e e e e
Similarly
[A.3-5]
For the operation of [A.3-7]
   
a a a
    
v v v
For the operation of ▽‧▽s, we have
[A.3-8]
[A.3-9]
2
2
2
2
2
2
)
e
e
e
(
)
e
e
e
(
z
s
y
s
x
s
z
s
y
s
x
s
z
y
x
s z
y
x
z
y
x






























In other words s
s 2





Where the differential operator▽2, called Laplace operator, is defined as
2
2
2
2
2
2
2
z
y
x 








 [A.3-10]
For example: Streamline is defined as a line everywhere tangent to the velocity
vector at a given instant and can be described as a scale function of f.
Lines of constant f are streamlines of the flow for inviscid irrotational flow
in the xy plane ▽2f=0
29
x y z
x y z
e e e
x y z
v v v
  
 
  
v
 
x y z
x y z
x y z
x y z
v v v
x x x x
v v v
v v v
y y y y
v v v
z z z z
   
   
   
   
   
   
   
  
   
   
   
   
   
   
   
   
v
The curl of a vector field v, denoted by ▽ x v, is a vector like the vector product
of two vectors.
[A.3-11]
[A.3-12]
Like the tensor product of two vectors, ▽v is a tensor as shown:
x y x z y x
x y z
v v v v v v
e e e
y z z x x y
   
     
 
     
   
 
     
 
   
When the flow is irrotational, v = 0

30
[A.3-13]
Like the vector product of a vector and a tensor, ▽‧ is a vector.
xx xy xz
yx yy yz
zx zy zz
yx xy yy zy
xx zx
yz
xz zz
x y
z
x y z
x y z x y z
x y z
  
  
  
   
 

 
 
 
    
  
   
  
   
 
   
   
 
     
   
     
   

 
 
  
 
  
 
τ
e e
e
 
     
     
     
x x x y x z
y x y y y z
z x z y z z
x x x y x z x
y x y y y z y
z x z y z z z
v v v v v v
v v v v v v
x y z
v v v v v v
v v v v v v
x y z
v v v v v v
x y z
v v v v v v
x y z
  
   
  
  
  
  
 
 
    
  
   
  
   
 
 
  
  
 
  
 
 
  
  
 
  
 
 
  
  
 
  
 
vv
e
e
e
[A.3-14]
From Eq. [A.2-2]
[A.3-15]
It can be shown that    
  
    
vv v v v v
Second order tensor
Analogous to a vector, second order tensor must also follow some transformation rules. Firstly,
they should contain 32
= 9 components and secondly, they should also follow the following
transformation rule as follows.
if m=1 and n=1 then, and from Equation (4.1), we have
,
For a second order tensor, are the normal components of the tensor and this
second order tensor is symmetric, if
2nd order tensor as dyadic product of two vectors
As we have discussed earlier, the dyadic product of two vectors is a 2nd
order tensor quantity.
For example, if and are two vectors, then
From Equation 4.6, we can see that on the right hand side nine terms have been added together
and if we omit the product of unit vectors, the nine components may written as shown below
Thus,
Mathematical operations for 2nd order tensors
The following mathematical operations are possible for 2nd order tensor quantities
Addition of 2nd order tensors
Tensors of the same order can be added or subtracted as follows
Similarly,
Multiplication of tensors
Various multiplication operations are possible between two different order tensors. Some of
these are shown below
Multiplication of a 2nd order tensor by a scalar
A scalar and a 2nd
order tensor quantity can be multiplied as follows
Multiplication of a 2nd order tensor by a vector
A vector and a 2nd
order tensor can be multiplied in various ways:
1. Dyadic product of a vector and 2nd order tensor
Dyadic product of vector and tensor is a third order tensor. Though, it is not required in
transport phenomena, may still be computed as shown below
2. Dot product of a vector and a 2nd order tensor
Dot operation reduces the order of resulting quantity by two. Hence, the dot product of a vector
and a tensor is a vector quantity. For example, if is a 2nd tensor and is a vector
quantity, then
Next, we perform the dot operation between two the nearest unit vectors as shown below
replace j by k or k by j
thus
For example, if i = 1, then
Dyadic Product of two tensors Dyadic product of two second order tensors is a fourth order
tensor quantity. It is not discussed here as this is not required in transport phenomena. Cross
product of two tensors Cross product of two second order tensors is a third order tensor
quantity and is not discussed here for the same reason as above.
Dot product of tensors (tensor product) Dot reduces the order of resultant quantity by two.
Thus, the dot product of two second order tensors is a second order tensor quantity.
If and are two second order tensors, then
While performing the dot product between two-unit vectors, the order in which indices
appear above, should not be changed and the dot product should be performed between the
two nearest unit vectors. Replace k by j (or you may also replace j by k) (compaction
operation)
Double dot product or Scalar product of two second order tensors Double dot operation
reduces the order of resultant quantity by four. Thus, the double dot product of two second
order tensors is a scalar quantity. If and are two second order tensors, then. First
dot operation should take place between the two nearer vectors and the next dot operation
should take place between two remaining unit vectors.
Hence, (Replace k by j)
(Replace l by i)
which is a scalar quantity.
73
A.4 Divergence Theorem
A.4.1 Vectors
Let Ω be a closed region in space surrounded by a surface A and n the outward-
directed unit vector normal to the surface. For a vector v
A
d dA

   
 
v v n [A.4-1]
This equation , called the gauss divergence theorem, is useful for converting from a
surface integral to a volume integral.
A.4.2 Scalars
A.4.3 Tensors
For a scale s
For a tensor  or vv
A
sd s dA

  
  n
   
A
d dA
 

   
  n
   
A
d dA

   
 
vv vv n
[A.4-2]
[A.4-3]
[A.4-4]
Time derivatives in transport phenomena Many times, we are interested to know how fast any
physical quantity or property is changing with time. However, the property might be also the
function of space coordinates, makes more complicated to measure. In this section, three
different types of time derivatives are discussed.
1. Partial derivative, denoted as
2. Total derivative, denoted as
3. Substantial derivative, denoted as
To understand the differences between these time derivatives, let us consider a hypothetical
case. A chimney produces flue gases containing SO2 and we want to study the change in
SO2 concentration with time.
Fig 6.1 Partial derivative with constant observer at point C
Partial derivative If the observer remains fixed at a particular position and determines the
change in the concentration of SO2. It is being the partial derivative that is measured. At
time t=t, let the concentration of SO2 be C1 and at time t+Δt, let it be C1+ΔC1. Thus, the time
derivative, which is the measure of change in SO2 concentration is given by
While calculating the partial derivative it is assumed other space coordinates remain
constant. Total derivative If, however, the observer also changes his position with time. It is
the total derivative which is measured. Suppose at any time t = t, the observer is situated at
the point A and measures concentration of SO2 as C1. At time t= t+Δt, the observer has move
and reaches a different location at point B. Let this measured concentration of of SO2 be C2 .
In this case, the time derivative
is
This may be called a total derivative as the change in concentration with respect to both time
and space is being considered. Therefore, it should also include the effects of the velocity of
observer. Mathematically this time derivative may be expressed
as,
Here, ux, uy and uz are the components of the velocity of the observer in
the x, y and z directions respectively. Substantial derivative It is a special case of the total
derivative where the observer floats in a balloon with the speed of the air around it. Thus, the
velocity of fluid is same as the velocity of the observer. In this
case,
where vx, vy and vz are the components of the velocity of the fluid. To understand the
differences between partial and substantial derivatives, let us take a simple one dimensional
problem. Let the point A be at the position ‘x’, and point B be at the position ‘x+ Δx’. The
concentration of SO2 is a function of both time t as well as spatial coordinate x. As shown in
Figure 6.2, the concentration profile (plot of C vs. x) changes with time. Let the concentration
of SO2 at the point A be recorded at time t=t as C1 and at time t+Δt as C2. In the same way,
the concentration of SO2 is recorded at point B at time t=t as C3 and at time t=t+Δt as C4 as
shown in Fig. 6.2
Fig 6.2 Position of observer A ( C1 & C2 ) and B ( C3 and C4 )
The observer, starting from point A, reaches the point B in time Δt . If the velocity of the
observer is ux , the distance traversed in time Δt will be Δx=ux Δt The partial derivatives can
thus be computed
as
The substantial derivative, is however computed
as
Equation (6.7) shows the difference between the partial and the substantial derivative. In
order to relate the two mathematically, we may proceed as follows. From the Fig. 6.2, C3 may
be written
as
Furthermore, C4 can be written in terms of C3 as
Therefore,
Dividing the equation by Δt and taking the limit as Δt → 0, we have
Generalizing the Equation (6.4) and making it independent of the coordinate system, we may
write it in vector and tensor form
as
The above definition of substantial derivative may also apply to a quantity which is vector or
second order tensor,
i.e.,
87
A.5 Curvilinear Coordinates
For many problems in transport phenomena, the curvilinear coordinates such as
cylindrical and spherical coordinates are more natural than rectangular coordinates.
A point P in space, as shown in Fig. A.5.1, can be represented by P(x,y,z) in
rectangular coordinates, P(r, θ,z) in cylindrical coordinates, or P(r, θ,ψ) in
spherical coordinates.
Fig. A.5-1(a)
A.5.1 Cartesian Coordinates
For Cartesian coordinates, as shown
in A.5-1(a), the differential increments
of a control unit in x, y and z axis are
dx, dy , and dz, respectively.
x
y
z
dx
dy
dz
P(x,y,z) ex
ey
ez
88
Fig. A.5-1(b)
A.5.1 Cylindrical Coordinates
For cylindrical coordinates, as shown in A.5-1(b), the variables r, θ, and z are
related to x, y, and z.
x = r cosθ [A.5-1] y = r sinθ [A.5-2] z = z [A.5-3]
Fig. A.5-1(b)*
v = er vr + eθvθ + ezvz
rr r rz
r z
zr z zz

  

  
  
  
 
 
  
 
 
τ
and
The differential increments of a control unit, as shown in Fig. A.5-1(b)*, in r, ,
and z axis are dr, rd , and dz, respectively. A vector v and a tensor τcan be
expressed as follows:
89
Fig. A.5-1(c)
A.5.2 Spherical Coordinates
For spherical coordinates, as shown in A.5-1(c), the variables r, θ, and ψ are
related to x, y, and z as follows
x= r sin cosf A.5-6
y = r sin sinf [A.5-7]
z = r cos A.5-8
[A.5-9]
rr r rz
r z
zr z zz

  

  
  
  
 
 
  
 
 
τ [A.5-10]
The differential increments of a control
unit, as shown in Fig. A.5-1(c)*, in r, θ,
and φ axis are dr, rdθ , and rsinθdφ ,
respectively. A vector v and a tensor τ
can be expressed as follows:
f
f

 v
v
vr
r e
e
e
v 


Fig. A.5-1(c)*
θ
φ φ
θ
θ φ
θ
θ
90
A.5.3 Differential Operators
1
0
0
rz
r z
zr z zz
r zr
rr r
r
r rr z
  




  
  
  
  
   
   
  
   
   
   
  
τ e
e e e
1
0
0
r
r
r
r r
rr r
r
r rr

  
  
 

 
  
  
  
  
   
   
  
   
 
 
 
 
  
τ e
e e e
1
r z
s s s
s
r r z


  
   
  
e e e
1 1
sin
r
s s s
s
r r r
 f
  f
  
   
  
e e e
Vectors, tensors, and their products in curvilinear coordinates are similar in form
to those in curvilinear coordinates. For example, if v = er in cylindrical coordinates,
the operation of τ.er can be expressed in [A.5-11], and it can be expressed in
[A.5-12] when in spherical coordinates
[A.5-11] [A.5-12]
In curvilinear coordinates, ▽ assumes different forms depending on the orders of
the physical quantities and the multiplication sign involved. For example, in cylindrical
coordinates
Whereas in spherical coordinates,
[A.5-13]
[A.5-14]
OR
Transfer processes
Transfer processes
Transfer processes
Transfer processes
Summary of transfer processes
Ratios of transport diffusivities
Ratios of transport diffusivities
Rapid and brief introduction to mass transfer
Turbulent mass diffusivities
Convective mass transfer
Convective mass transfer
Convective mass transfer correlations
Interphase mass transfer: Two film theory
Two-film theory: Overall mass transfer coefficient
Diffusion coefficient or mass diffusivity
Ranges of mass diffusivities
Diffusion coefficient or mass diffusivity
Experimental diffusion coefficients
Diffusion coefficient for gases at low pressure
Diffusion coefficient for gases at low pressure:
Estimation
Diffusion coefficient for gases at low pressure:
Estimation
Diffusion coefficient for gases at low pressure: Estimation
Lennard-Jones potential
Diffusion coefficient for gases at low pressure:
Estimation
Diffusion coefficient for gases at low
pressure: Estimation
Fuller’s equation
Diffusion volumes to be used with Fuller’s equation
Diffusion coefficient for gases at high density
Diffusion coefficient for gases at high density:
Takahashi method
Diffusion coefficient for gas mixtures
Diffusion coefficient for gas mixtures
Diffusion coefficient for gas mixtures
Diffusion coefficient for liquid mixtures
Diffusion coefficient for liquid mixtures
Selected molar volumes at normal boiling points
Atomic volumes for calculating molar volumes and corrections
Diffusion coefficient for liquid mixtures
Why do we need shell (small
control element ) mass
balance?
We need, because, we desire to know what
is happening inside. In other words, we
want to know the differential or point to
point molar flux and concentration
distributions with in a system, i.e., we will
represent the system in terms of
differential equations. Macro or bulk
balances such as that applied in material
balance calculations only give input and
output information and do not tell what
happens inside the system.
Coordinate systems
Diffusion through a
stagnant gas film
Diffusion through a stagnant gas film
Diffusion through a stagnant gas film
Diffusion through a stagnant gas film:
Concentration profile
Diffusion through a stagnant gas film:
Molar flux
Diffusion through a stagnant gas film
Pseudosteady state diffusion through a stagnant
gas film
Diffusion through a stagnant gas film:
Applications
Diffusion through a stagnant gas film: Defects
Diffusion of A through stagnant gas film in spherical
coordinates
Diffusion of A through stagnant gas film in
spherical coordinates
Diffusion of A through stagnant gas film in cylindrical
coordinates
Diffusion of A through Pyrex glass tube
Diffusion with a heterogeneous chemical reaction
Significance of dimensionless numbers
It is convenient to write the above mentioned differential
equations and their boundary conditions in terms of
dimensionless groups. Dimensionless groups may have smaller
numerical values which may facilitate a numerical solution. Also
analysis of the system may be described in a more convenient
manner.
The above equations are usually written in terms of Peclet
number
Solution of partial differential equations
Liquid pulsed extraction column
Mathematical modeling of a differential
extraction column
Mathematical modeling of a differential
extraction column
Differential equation for mass transfer
Differential equations for mass transfer in terms of NA
(molar units)
Differential equation for mass transfer in rectangular
coordinates (mass units)
Differential equations for mass transfer in terms of jAz
Differential equations for mass transfer in terms of ωA
THANK YOU

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vector and tensor.pptx

  • 1. Transport Phenomena Introduction By Dr Sourav Poddar Department of Chemical Engineering National Institute of Technology, Tiruchirappalli
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  • 4. • Vector and Tensor Analysis • Momentum Transport • Heat Transfer • Mass Transport
  • 5. Vector and Tensor Analysis Introduction Transport Phenomena is the subject which deals with the movement of different physical quantities in any chemical or mechanical process and describes the basic principles and laws of transport. It also describes the relations and similarities among different types of transport that may occur in any system. Transport in a chemical or mechanical process can be classified into three types: 1. Momentum transport deals with the transport of momentum in fluids and is also known as fluid dynamics. 2. Energy transport deals with the transport of different forms of energy in a system and is also known as heat transfer. 3.Mass transport deals with the transport of various chemical species themselves.
  • 6. Three different types of physical quantities are used in transport phenomena: scalars (e.g. temperature, pressure and concentration), vectors (e.g. velocity, momentum and force) and second order tensors (e.g. stress or momentum flux and velocity gradient). It is essential to have a primary knowledge of the mathematical operations of scalar, vector and tensor quantities for solving the problems of transport phenomena. In fact, the use of the indicial notation in cartesian coordinates will enable us to express the long formulae encountered in transport phenomena in a concise and compact fashion. In addition, any equation written in vector tensor form is equally valid in any coordinate system.
  • 7. In this course, we will be using the following notations for scalar, vector and tensor quantities: notations: a, b, c scalar quantities vector quantities 2nd order tensor quantities Cartesian coordinates and unit vectors A xyz cartesian coordinate system may also be conventionally written as shown in Fig.1.1 below. Fig. 1.1 3-dimensional cartesian coordinate system with unit vector Here, and are the unit vectors in x, y and z direction respectively.
  • 8. Tensor quantities Most of us might have already encountered scalars and vectors in the study of high-school physics. It was pointed out that the vectors also have a direction associated with them along with a magnitude, whereas scalars only have a magnitude but no direction. Extending this definition, we can loosely define a 2nd order tensor as a physical quantity which has a magnitude and two different directions associated with it. To better understand, why we might need two different directions for specifying a particular physical quantity. Let us take the example of the stresses which may arise in a solid body, or in a fluid. Clearly, the stresses are associated with magnitude of forces, as well as with an area, whose direction is also need to be specified by the outward normal to the face of the area on which a particular force acting. Hence, we will require 32, i.e., 9 components to specify a stress completely in a 3 dimensional cartesian coordinate system. In general, an nth order tensor will be specified by 3n components (in a 3-dimensional system). However, the number of components alone cannot determine whether a physical quantity is a vector or a tensor. The additional requirement is that there should be some transformation rule for obtaining the corresponding tensors when we rotate the coordinate system about the origin. Thus, the tensor quantities can be defined by two essential conditions:
  • 9. 1. These quantities should have 3n components. According to this definition, scalar quantities are zero order tensors and have 30= 1 component. Vector quantities are first order tensors and have 31 = 3 components. Second order tensors have 32 = 9 components and third order tensors have 33 = 27 components. Third and higher order tensors are not used in transport phenomena, and are not dealt here. 2. The second necessary requirement of any tensor quantity is that it should follow some transformation rule.
  • 10. Kronecker delta & Alternating Unit Tensor There are two quantities which are quite useful in conveniently and concisely expressing several mathematical operations on tensors. These are the Kronecker delta and the alternating unit tensor. Kronecker delta Kronecker delta or Kronecker’s delta is a function of two index variables, usually integer, which is 1 if they are equal and 0 otherwise. It is expressed as a symbol δij δij=1, if i=j δij=0, if i≠j Thus, in three dimensions, we may also express the Kronecker delta in matrix form
  • 11. Alternating unit tensor The alternating unit tensor εijk is useful when expressing certain results in a compact form in index notation. It may be noted that the alternating unit tensor has three index and therefore 27 possible combinations but it is a scalar quantity • εijk= 0 if any two of indices i, j, k are equal. For example ε113,ε131,ε111,ε222=0 • εijk= +1 when the indices i, j, k are different and are in cyclic order (123), For example ε123  εijk=-1 when the indices i, j, k are different and are in anti-cyclic order. For example ε321
  • 12. Free indices and Dummy indices Free indices Free indices are the indices which occur only once in each tensor term. For example, i is the free index in following expression vij wj In any tensorial equation, every term should have an equal number of free indices. For example, vij wj =cj dj is not a valid tensorial expression since the number of free indices (index i) is not equal in both terms. Any free indices in a tensorial expression can be replaced by any other indices as long as this symbol has not already occurred in the expression. For example, Aij Bj= CiDjEj is equivalent to Akj Bj= CkDjEj The number of free indices in an equation gives the actual number of mathematical equations that will arise from it. For example, in equation Aij Bj= CiDjEj corresponds to 31 = 3 equations since there is only one free indices i. It may be noted that each indices can take value i=1, 2 or 3.
  • 13. Dummy indices Dummy indices are the indices that occur twice in a tensor term. For example, j is the dummy index in Aij Bj. Any dummy index implies the summation of all components of that tensor term associated with each coordinate axis. Thus, when we write Aiδi, we actually imply Any dummy index in a tensor term can be replaced by any other symbol as long as this symbol has not already occurred in previous terms. For example, Aijkδjδk= Aipqδpδq. Note: The dummy indices can be renamed in each term separately in a equations but free indices should be renamed for all terms in a tensor equations. For example, Aij Bj= CiDjEj can be replaced by Akp Bp= CkDjEj. Here, i is the free index which has been replaced by k in both terms but j is a dummy index and can be replaced either in one term or both.
  • 14. Summation convention in vector and tensor analysis According to the summation convention rule, if k is a dummy index which repeats itself in a term then there should be a summation sign associated with it. Therefore, we can eliminate the implied summation sign and can write the expression in a more compact way. For example, using the summation convention can be simply written as εijkεljk . Since j and k are repeating, there is no need to write summation sign over these indices
  • 15. Relation between alternating unit tensor and Kronecker delta When two indices are common between the two alternating unit tensors, that the following can be shown easily .......................................................................(2.1) When one index is common between the two alternating unit tensors, there product may be written as .......................................................................(2.2)
  • 16. 16 Mathematics Review A.1 Vectors A.1.1 Definitions A.1.2 Products A.1.2.1 Scalar Products A.1.2.2 Vector Product V.W = |v| |W|cos(V,W) = vxwx + vywy + vzwz V x W = |v||W|sin(V,W) nvw V = vx ex + vyey + vzez ex ey ez vx vy vz wx wy wz =
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  • 19. (b) Divergence of vector field Dot product of the del operator and a vector quantity is called the divergence of vector field. It is a scalar quantity. If is a vector quantity then divergence of a vector field is
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  • 24. 24 A.2 Tensors A.2.1 Definitions A tensor (2nd order) has nine components, for example, a stress tensor can be expressed in rectangular coordinates listed in the following: A.2.2 Product The tensor product of two vectors v and w, denoted as vw, is a tensor defined by xx xy xz yx yy yz zx zy zz                     τ   x x x x y x z y x y z y x y y y z z x z y z z z v v w v w v w v w w w v w v w v w v w v w v w v                       vw [A.2-1] [A.2-2] Explanation (Borisenko, p64)
  • 25. 25 The vector product of a tensor  and a vector v, denoted by .v is a vector defined by       x xx xy xz yx yy yz y zx zy zz z x xx y xy z xz x yx y yy z yz x zx y zy z zz x y z v v v v v v v v v v v v v                                                  τ e e e [A.2-3]            x x x x y x z y x y y y z y z x z y z z z x x x x y y x z z y x x y y y y z z z x x z y y z z z x y z x x y y z z x y z x y z n v v v v v v v v v v v v n v v v v v v n v v n v v n v v n v v n v v n v v n v v n v v n v v n v v v v n v n v n                                       vv n e e e e e e v v n [A.2-5] The product between a tensor vv and a vector n is a vector
  • 26. 26 The scalar product of two tensors s and , denoted as s:, is a scalar defined by : : xx xy xz xx xy xz yx yy yz yx yy yz zx zy zz zx zy zz xx xx xy yx xz zx yx xy yy yy yz zy zx xz zy yz zz zz s s s    s s s    s s s    s  s  s  s  s  s  s  s  s                                σ τ [A.2-6] : : x x x y x z xx xy xz y x y y y z yx yy yz z x z y z z zx zy zz x x xx x y yx x z zx y x xy y y yy y z zy z x xz z y yz z z zz v w v w v w v w v w v w v w v w v w v w v w v w v w v w v w v w v w v w                                                  vw [A.2-7] The scalar product of two tensors vw and  is Physical quantity Multiplication sign Scalar Vector Tensor None X ‧ : Order 0 1 2 0 -1 -2 -4 Table A.1-1 Orders of physical quantities and their multiplication signs
  • 27. 2 x y z x y z           e e e x y z s s s s x y z           e e e A.3 Differential Operators A.3.1 Definitions The vector differential operation , called “del”, has components similar to those of a vector. However, unlike a vector, it cannot stand alone and must operate on a scalar, vector, or tensor function. In rectangular coordinates it is defined by The gradient of a scalar field s, denoted as ▽ s, is a vector defined by [A.3-1] [A.3-2] A.3.2 Products The divergence of a vector field v, denoted as ▽‧v is a scalar . [A.3-5]   v x y z x x y y z z x y z v v v x y z v v v x y z                             e e e e e e Flux is defined as the amount that flows through a unit area per unit time Flow rate is the volume of fluid which passes through a given surface per unit time
  • 28. 28           x y z x x y y z z x y z x y z x y z a av av av x y z av av av x y z v v v a a a a v v v x y z x y z                                                           v e e e e e e Similarly [A.3-5] For the operation of [A.3-7]     a a a      v v v For the operation of ▽‧▽s, we have [A.3-8] [A.3-9] 2 2 2 2 2 2 ) e e e ( ) e e e ( z s y s x s z s y s x s z y x s z y x z y x                               In other words s s 2      Where the differential operator▽2, called Laplace operator, is defined as 2 2 2 2 2 2 2 z y x           [A.3-10] For example: Streamline is defined as a line everywhere tangent to the velocity vector at a given instant and can be described as a scale function of f. Lines of constant f are streamlines of the flow for inviscid irrotational flow in the xy plane ▽2f=0
  • 29. 29 x y z x y z e e e x y z v v v         v   x y z x y z x y z x y z v v v x x x x v v v v v v y y y y v v v z z z z                                                                v The curl of a vector field v, denoted by ▽ x v, is a vector like the vector product of two vectors. [A.3-11] [A.3-12] Like the tensor product of two vectors, ▽v is a tensor as shown: x y x z y x x y z v v v v v v e e e y z z x x y                                     When the flow is irrotational, v = 0 
  • 30. 30 [A.3-13] Like the vector product of a vector and a tensor, ▽‧ is a vector. xx xy xz yx yy yz zx zy zz yx xy yy zy xx zx yz xz zz x y z x y z x y z x y z x y z                                                                                         τ e e e                     x x x y x z y x y y y z z x z y z z x x x y x z x y x y y y z y z x z y z z z v v v v v v v v v v v v x y z v v v v v v v v v v v v x y z v v v v v v x y z v v v v v v x y z                                                                                          vv e e e [A.3-14] From Eq. [A.2-2] [A.3-15] It can be shown that             vv v v v v
  • 31.
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  • 63. Second order tensor Analogous to a vector, second order tensor must also follow some transformation rules. Firstly, they should contain 32 = 9 components and secondly, they should also follow the following transformation rule as follows. if m=1 and n=1 then, and from Equation (4.1), we have , For a second order tensor, are the normal components of the tensor and this second order tensor is symmetric, if
  • 64. 2nd order tensor as dyadic product of two vectors As we have discussed earlier, the dyadic product of two vectors is a 2nd order tensor quantity. For example, if and are two vectors, then From Equation 4.6, we can see that on the right hand side nine terms have been added together and if we omit the product of unit vectors, the nine components may written as shown below Thus,
  • 65. Mathematical operations for 2nd order tensors The following mathematical operations are possible for 2nd order tensor quantities Addition of 2nd order tensors Tensors of the same order can be added or subtracted as follows Similarly,
  • 66. Multiplication of tensors Various multiplication operations are possible between two different order tensors. Some of these are shown below Multiplication of a 2nd order tensor by a scalar A scalar and a 2nd order tensor quantity can be multiplied as follows Multiplication of a 2nd order tensor by a vector A vector and a 2nd order tensor can be multiplied in various ways:
  • 67. 1. Dyadic product of a vector and 2nd order tensor Dyadic product of vector and tensor is a third order tensor. Though, it is not required in transport phenomena, may still be computed as shown below 2. Dot product of a vector and a 2nd order tensor Dot operation reduces the order of resulting quantity by two. Hence, the dot product of a vector and a tensor is a vector quantity. For example, if is a 2nd tensor and is a vector quantity, then
  • 68. Next, we perform the dot operation between two the nearest unit vectors as shown below replace j by k or k by j thus For example, if i = 1, then
  • 69.
  • 70. Dyadic Product of two tensors Dyadic product of two second order tensors is a fourth order tensor quantity. It is not discussed here as this is not required in transport phenomena. Cross product of two tensors Cross product of two second order tensors is a third order tensor quantity and is not discussed here for the same reason as above.
  • 71. Dot product of tensors (tensor product) Dot reduces the order of resultant quantity by two. Thus, the dot product of two second order tensors is a second order tensor quantity. If and are two second order tensors, then While performing the dot product between two-unit vectors, the order in which indices appear above, should not be changed and the dot product should be performed between the two nearest unit vectors. Replace k by j (or you may also replace j by k) (compaction operation)
  • 72. Double dot product or Scalar product of two second order tensors Double dot operation reduces the order of resultant quantity by four. Thus, the double dot product of two second order tensors is a scalar quantity. If and are two second order tensors, then. First dot operation should take place between the two nearer vectors and the next dot operation should take place between two remaining unit vectors. Hence, (Replace k by j) (Replace l by i) which is a scalar quantity.
  • 73. 73 A.4 Divergence Theorem A.4.1 Vectors Let Ω be a closed region in space surrounded by a surface A and n the outward- directed unit vector normal to the surface. For a vector v A d dA        v v n [A.4-1] This equation , called the gauss divergence theorem, is useful for converting from a surface integral to a volume integral. A.4.2 Scalars A.4.3 Tensors For a scale s For a tensor  or vv A sd s dA       n     A d dA          n     A d dA        vv vv n [A.4-2] [A.4-3] [A.4-4]
  • 74.
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  • 80. Time derivatives in transport phenomena Many times, we are interested to know how fast any physical quantity or property is changing with time. However, the property might be also the function of space coordinates, makes more complicated to measure. In this section, three different types of time derivatives are discussed. 1. Partial derivative, denoted as 2. Total derivative, denoted as 3. Substantial derivative, denoted as
  • 81. To understand the differences between these time derivatives, let us consider a hypothetical case. A chimney produces flue gases containing SO2 and we want to study the change in SO2 concentration with time. Fig 6.1 Partial derivative with constant observer at point C
  • 82. Partial derivative If the observer remains fixed at a particular position and determines the change in the concentration of SO2. It is being the partial derivative that is measured. At time t=t, let the concentration of SO2 be C1 and at time t+Δt, let it be C1+ΔC1. Thus, the time derivative, which is the measure of change in SO2 concentration is given by While calculating the partial derivative it is assumed other space coordinates remain constant. Total derivative If, however, the observer also changes his position with time. It is the total derivative which is measured. Suppose at any time t = t, the observer is situated at the point A and measures concentration of SO2 as C1. At time t= t+Δt, the observer has move and reaches a different location at point B. Let this measured concentration of of SO2 be C2 . In this case, the time derivative is This may be called a total derivative as the change in concentration with respect to both time and space is being considered. Therefore, it should also include the effects of the velocity of observer. Mathematically this time derivative may be expressed as,
  • 83. Here, ux, uy and uz are the components of the velocity of the observer in the x, y and z directions respectively. Substantial derivative It is a special case of the total derivative where the observer floats in a balloon with the speed of the air around it. Thus, the velocity of fluid is same as the velocity of the observer. In this case, where vx, vy and vz are the components of the velocity of the fluid. To understand the differences between partial and substantial derivatives, let us take a simple one dimensional problem. Let the point A be at the position ‘x’, and point B be at the position ‘x+ Δx’. The concentration of SO2 is a function of both time t as well as spatial coordinate x. As shown in Figure 6.2, the concentration profile (plot of C vs. x) changes with time. Let the concentration of SO2 at the point A be recorded at time t=t as C1 and at time t+Δt as C2. In the same way, the concentration of SO2 is recorded at point B at time t=t as C3 and at time t=t+Δt as C4 as shown in Fig. 6.2
  • 84. Fig 6.2 Position of observer A ( C1 & C2 ) and B ( C3 and C4 ) The observer, starting from point A, reaches the point B in time Δt . If the velocity of the observer is ux , the distance traversed in time Δt will be Δx=ux Δt The partial derivatives can thus be computed as The substantial derivative, is however computed as
  • 85. Equation (6.7) shows the difference between the partial and the substantial derivative. In order to relate the two mathematically, we may proceed as follows. From the Fig. 6.2, C3 may be written as Furthermore, C4 can be written in terms of C3 as Therefore, Dividing the equation by Δt and taking the limit as Δt → 0, we have
  • 86. Generalizing the Equation (6.4) and making it independent of the coordinate system, we may write it in vector and tensor form as The above definition of substantial derivative may also apply to a quantity which is vector or second order tensor, i.e.,
  • 87. 87 A.5 Curvilinear Coordinates For many problems in transport phenomena, the curvilinear coordinates such as cylindrical and spherical coordinates are more natural than rectangular coordinates. A point P in space, as shown in Fig. A.5.1, can be represented by P(x,y,z) in rectangular coordinates, P(r, θ,z) in cylindrical coordinates, or P(r, θ,ψ) in spherical coordinates. Fig. A.5-1(a) A.5.1 Cartesian Coordinates For Cartesian coordinates, as shown in A.5-1(a), the differential increments of a control unit in x, y and z axis are dx, dy , and dz, respectively. x y z dx dy dz P(x,y,z) ex ey ez
  • 88. 88 Fig. A.5-1(b) A.5.1 Cylindrical Coordinates For cylindrical coordinates, as shown in A.5-1(b), the variables r, θ, and z are related to x, y, and z. x = r cosθ [A.5-1] y = r sinθ [A.5-2] z = z [A.5-3] Fig. A.5-1(b)* v = er vr + eθvθ + ezvz rr r rz r z zr z zz                          τ and The differential increments of a control unit, as shown in Fig. A.5-1(b)*, in r, , and z axis are dr, rd , and dz, respectively. A vector v and a tensor τcan be expressed as follows:
  • 89. 89 Fig. A.5-1(c) A.5.2 Spherical Coordinates For spherical coordinates, as shown in A.5-1(c), the variables r, θ, and ψ are related to x, y, and z as follows x= r sin cosf A.5-6 y = r sin sinf [A.5-7] z = r cos A.5-8 [A.5-9] rr r rz r z zr z zz                          τ [A.5-10] The differential increments of a control unit, as shown in Fig. A.5-1(c)*, in r, θ, and φ axis are dr, rdθ , and rsinθdφ , respectively. A vector v and a tensor τ can be expressed as follows: f f   v v vr r e e e v    Fig. A.5-1(c)* θ φ φ θ θ φ θ θ
  • 90. 90 A.5.3 Differential Operators 1 0 0 rz r z zr z zz r zr rr r r r rr z                                              τ e e e e 1 0 0 r r r r r rr r r r rr                                                   τ e e e e 1 r z s s s s r r z             e e e 1 1 sin r s s s s r r r  f   f           e e e Vectors, tensors, and their products in curvilinear coordinates are similar in form to those in curvilinear coordinates. For example, if v = er in cylindrical coordinates, the operation of τ.er can be expressed in [A.5-11], and it can be expressed in [A.5-12] when in spherical coordinates [A.5-11] [A.5-12] In curvilinear coordinates, ▽ assumes different forms depending on the orders of the physical quantities and the multiplication sign involved. For example, in cylindrical coordinates Whereas in spherical coordinates, [A.5-13] [A.5-14]
  • 91.
  • 92.
  • 93.
  • 94.
  • 95. OR
  • 96.
  • 101. Summary of transfer processes
  • 102.
  • 103.
  • 104. Ratios of transport diffusivities
  • 105. Ratios of transport diffusivities
  • 106. Rapid and brief introduction to mass transfer
  • 107.
  • 108.
  • 109.
  • 110.
  • 111.
  • 112.
  • 115.
  • 117.
  • 118. Convective mass transfer correlations
  • 119. Interphase mass transfer: Two film theory
  • 120. Two-film theory: Overall mass transfer coefficient
  • 121. Diffusion coefficient or mass diffusivity
  • 122. Ranges of mass diffusivities
  • 123. Diffusion coefficient or mass diffusivity
  • 125. Diffusion coefficient for gases at low pressure
  • 126. Diffusion coefficient for gases at low pressure: Estimation
  • 127.
  • 128.
  • 129. Diffusion coefficient for gases at low pressure: Estimation
  • 130.
  • 131. Diffusion coefficient for gases at low pressure: Estimation
  • 133. Diffusion coefficient for gases at low pressure: Estimation
  • 134. Diffusion coefficient for gases at low pressure: Estimation
  • 135.
  • 136.
  • 138. Diffusion volumes to be used with Fuller’s equation
  • 139.
  • 140. Diffusion coefficient for gases at high density
  • 141. Diffusion coefficient for gases at high density: Takahashi method
  • 142.
  • 143. Diffusion coefficient for gas mixtures
  • 144. Diffusion coefficient for gas mixtures
  • 145. Diffusion coefficient for gas mixtures
  • 146. Diffusion coefficient for liquid mixtures
  • 147. Diffusion coefficient for liquid mixtures
  • 148. Selected molar volumes at normal boiling points
  • 149. Atomic volumes for calculating molar volumes and corrections
  • 150. Diffusion coefficient for liquid mixtures
  • 151. Why do we need shell (small control element ) mass balance?
  • 152. We need, because, we desire to know what is happening inside. In other words, we want to know the differential or point to point molar flux and concentration distributions with in a system, i.e., we will represent the system in terms of differential equations. Macro or bulk balances such as that applied in material balance calculations only give input and output information and do not tell what happens inside the system.
  • 153.
  • 154.
  • 156.
  • 158. Diffusion through a stagnant gas film
  • 159. Diffusion through a stagnant gas film
  • 160.
  • 161.
  • 162.
  • 163. Diffusion through a stagnant gas film: Concentration profile
  • 164. Diffusion through a stagnant gas film: Molar flux
  • 165. Diffusion through a stagnant gas film
  • 166. Pseudosteady state diffusion through a stagnant gas film
  • 167. Diffusion through a stagnant gas film: Applications
  • 168. Diffusion through a stagnant gas film: Defects
  • 169. Diffusion of A through stagnant gas film in spherical coordinates
  • 170. Diffusion of A through stagnant gas film in spherical coordinates
  • 171.
  • 172. Diffusion of A through stagnant gas film in cylindrical coordinates
  • 173.
  • 174. Diffusion of A through Pyrex glass tube
  • 175.
  • 176. Diffusion with a heterogeneous chemical reaction
  • 177.
  • 178.
  • 179.
  • 180.
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  • 189.
  • 190.
  • 191.
  • 192.
  • 193. Significance of dimensionless numbers It is convenient to write the above mentioned differential equations and their boundary conditions in terms of dimensionless groups. Dimensionless groups may have smaller numerical values which may facilitate a numerical solution. Also analysis of the system may be described in a more convenient manner. The above equations are usually written in terms of Peclet number
  • 194.
  • 195. Solution of partial differential equations
  • 196.
  • 197.
  • 198.
  • 200. Mathematical modeling of a differential extraction column
  • 201. Mathematical modeling of a differential extraction column
  • 202. Differential equation for mass transfer
  • 203.
  • 204. Differential equations for mass transfer in terms of NA (molar units)
  • 205. Differential equation for mass transfer in rectangular coordinates (mass units)
  • 206. Differential equations for mass transfer in terms of jAz
  • 207. Differential equations for mass transfer in terms of ωA
  • 208.
  • 209.
  • 210.