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Upstream Biomass Energy
Michael Weatherl
Background
 Shell is investigating several unproven
lignocellulosic biomass-derived fuel and
energy technologies
 These could provide sources of
Hydrogen, liquid fuels, and other
valuable chemicals
 The logistical and economic aspects of
the processes are not yet fully
understood
Advantages of Biomass
Energy
 Clean, renewable source of energy
 Does not release additional CO2 into the
atmosphere
 Utilizes waste material
 Creates local jobs and decreases
foreign imports
 Several areas of high biomass
availability near areas of high demand
for the end product
Project Description
 Identify key parameters governing bio-energy
economics, especially in the USA, Canada, and
Brazil
 Quantification of costs for upstream biomass
collection and handling
 Review several biomass conversion processes
to establish economic baselines for comparison
 Document the energy balance of the process
 Develop a simple economic model to help
guide decision making
The Bio-Energy Process
 Collection & Densification
 Handling/Storage
 Transportation
 Conversion
 Distribution of End-Product
‘upstream’
Feedstock Resources - USA
 Corn Stover (non-food portion): 100+ million
tons
 Forest Thinnings: 40+ million tons
 Primary Mill Residues: 40+ million tons
 Urban Wood Wastes: 35+ million tons
 Other Agricultural Waste: 50+ million tons
Estimated Sustainable Annual Supply
U.S. Biomass Resource Map
Feedstock Resources -
Canada
 Wheat Straw: 20+ million tons
 Forest Residues: 90+ million tons
 Mill Residues: 10+ million tons
Estimated Sustainable Annual Supply
Canadian Forestry Biomass
Canadian Agricultural
Biomass
Feedstock Resources - Brazil
 Bagasse: 60+ million tons annually
 Highly developed sugarcane-to-ethanol
program
Brazilian Agriculture
A Note on Feedstocks…
 These numbers are conservative, and
take into account the main parameters
of sustainable collection
 Less than 10% of all agricultural residue
is used
 Pre-collected residues (bagasse &
mills) tend to be used for inefficient
boiler firing, but are still very low cost
What if? ‘Efficient Energy
Crops of the Future’
 Technology will yield more and more
appealing products as time progresses.
Agriculture is no different.
 ORNL estimates that ‘Dedicated Energy
Crops’ could provide nearly 200 million
tons of biomass in the U.S. annually.
Feedstock Productivity
 Corn Stover: 1.5
 Wheat Straw: 1.2
 Forestry Waste: 5
 Energy Crops: >10
Annual tons of Biomass per acre:
The Bio-Energy Process
 Collection & Densification
 Handling/Storage
 Transportation
 Conversion
Biomass Collection: Case
Studies
Agricultural Residue: Harvest & Collection Costs
($/ton)
Approximate Farm-Gate Cost: $27/ton
Mowing Baling Stacking Total
Source 1: Rice Straw 6 14 7 27
Source 2: Wheat Straw 7 8 11 26
Source 3: Corn Stover 10 12 5 27
Biomass Collection: Case
Studies
Collect/Bundle Foreward/Load Chipping Total
Source 1 16 5 3 24
Source 2 7 8 11 26
Source 3 10 12 5 27
Forestry Waste: Collection Costs ($/ton)
Approximate Roadside Cost: $26/ton
Biomass Collection: Conclusions
 One-Pass harvest of both grain and
waste biomass would eliminate several
steps.
 Sustainable collection is important
 Agricultural Residue: $27/ton
 Forestry Residue: $26/ton
 For centrally located feedstocks,
purchase cost is $5-$15/ton (based on
LHV, alternate uses)
The Bio-Energy Process
 Collection & Densification
 Storage/Handling
 Transportation
 Conversion
Biomass Storage
 Agricultural waste that is only harvested once
or twice annually requires storage
 Large bales stored field side and covered by a
tarp will resist damage. This costs about
$5/ton.
 Forestry waste is generated year-round, and
does not require storage
 Mill residues and bagasse are stored at the
site where they are generated.
Biomass Handling
 Agricultural waste is transported to a
local pickup/storage point.
 Forestry waste is forwarded to the side of
the road to await transport
 Mill residues and bagasse are loaded
directly onto trucks and sent to the
conversion center
The Bio-Energy Process
 Collection & Densification
 Storage/Handling
 Transportation
 Conversion
Biomass Transport
 Truck
 Train
 Barge
 Pipeline?
Main Options:
North American Rail System
Transport Cost: Agricultural Waste
Fixed Cost ($/ton) Variable Cost ($/ton-mile)
Source 1: Rice Straw Bales 5.5 0.09
Source 2: Wheat Straw Bales 4.5 0.19
Assumed Trucking Cost 5 0.14
Source 3: Freight by Rail 11 0.03
Agricultural Waste Transport
0
5
10
15
20
25
30
35
0 50 100 150 200
Distance (miles)
TransportCost($)
Trucking
Rail
Delivered Cost: Agricultural Waste
Delivered Cost of Agricultural Feedstock
0
10
20
30
40
50
60
0 50 100 150 200
Distance
Cost($/ton)
Cost After Storage
Delivered Cost (Trucks)
Delivered Cost (Rail)
Transport Cost: Forestry Waste
Fixed Cost ($/ton) Variable Cost ($/ton-mile)
Truck Transport 4 0.2
Barge Transport (if possible) 15 0.02
Delivered Cost: Forestry Waste
Delivered Cost of Forestry Residue
0
10
20
30
40
50
60
70
0 50 100 150 200
Distance
Cost($/ton)
Flat Costs
Delivered Cost
Barge (w here available)
Pipeline Transport
Pipeline Transport?
 Short term: probably not
 Long term: more likely
 Allows for economies of scale and
integrated processes
Biomass Transport: Conclusions
 Agricultural Waste: <$50/ton
 Forestry Waste: <$42/ton
 Centralized Feedstocks: <$30/ton
Delivered Price:
The Bio-Energy Process
 Collection & Densification
 Storage/Handling
 Transportation
 Conversion
Conversion Technologies
 Combustion (gasification)
 Fermentation (MixAlco)
 Scale is everything!
Gasification into Hydrogen
Plant Scale (tons of bioimass/day) Cost of Hydrogen ($/GJ)
345 17.08
1150 15.39
1730 14.29
Gasification
0
2
4
6
8
10
12
14
16
18
0 500 1000 1500 2000
Plant Scale (tons of biomass/day)
CostofHydrogen($/GJ)
Predicted Plant-Gate
Hydrogen Selling Price
Current Wholesale
Hydrogen Price
MixAlco
 MixAlco is a fermentation process which
utilizes cellulosic feedstocks (non-food
sources such as waste from agriculture
and forests)
 Yields chemicals that can be made into
acids, alcohols, and hydrogen
 Developed by Dr. Mark Holtzapple of
Texas A&M University
Primary Alcohol Selling Price per Capacity, for
different Feedstock costs
0
0.2
0.4
0.6
0.8
1
1.2
1.4
0 1000 2000 3000 4000 5000
Tons of Biomass per Day
SellingPrice($/gal)
$11/ton
$22/ton
$33/ton
$44/ton
$55/ton
Today
MixAlco Costs
A healthy skepticism…
 15% ROI may not be high enough for
such a high-risk investment
 Feedstock quantity and quality are
inconsistent
 These numbers are educated guesses
and may overlook some unseen costs
Energy Balance
 Lignocellulosic-derived ethanol
has a higher NEV (Net Energy
Balance - an estimated 60,000
Btu) because of a less energy-
intensive conversion process,
when compared to traditional
ethanol sources like corn
 Hydrogen will have even higher
NEV because it does not require
a fuel-grade liquid
Conclusions:
 Centralized residues appear to be the
most viable option presently
 Forestry waste also appears feasible,
but not as cost-effective
 Agricultural waste appears to be the
least economical feedstock presently
 Transport costs have the greatest
impact on optimal scale
 Infrastructure is the only showstopper
Acknowledgements:
I’d like to thank the members of Shell Gamechanger
for giving me the opportunity to take part in this
project and learn so much this summer.
Special thanks to Jerry Morris, Jack Hirsch, Scott
Wellington, Brendan Murray, Ron Reinsfelder,
Jingyu Cui, Rebecca Hubbard, Russ Conser, Don
Maynard, Tim O’Gorman, Jochen Marwede, Lori
Glassgold, Jair Guarda, Jaison Thomas, and the rest
of the Gamechanger team.
It’s truly been a pleasure!

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Upstream Biomass Energy: MixAlco Fermentation of Lignocellulosic Feedstock

  • 2. Background  Shell is investigating several unproven lignocellulosic biomass-derived fuel and energy technologies  These could provide sources of Hydrogen, liquid fuels, and other valuable chemicals  The logistical and economic aspects of the processes are not yet fully understood
  • 3. Advantages of Biomass Energy  Clean, renewable source of energy  Does not release additional CO2 into the atmosphere  Utilizes waste material  Creates local jobs and decreases foreign imports  Several areas of high biomass availability near areas of high demand for the end product
  • 4. Project Description  Identify key parameters governing bio-energy economics, especially in the USA, Canada, and Brazil  Quantification of costs for upstream biomass collection and handling  Review several biomass conversion processes to establish economic baselines for comparison  Document the energy balance of the process  Develop a simple economic model to help guide decision making
  • 5. The Bio-Energy Process  Collection & Densification  Handling/Storage  Transportation  Conversion  Distribution of End-Product ‘upstream’
  • 6. Feedstock Resources - USA  Corn Stover (non-food portion): 100+ million tons  Forest Thinnings: 40+ million tons  Primary Mill Residues: 40+ million tons  Urban Wood Wastes: 35+ million tons  Other Agricultural Waste: 50+ million tons Estimated Sustainable Annual Supply
  • 8. Feedstock Resources - Canada  Wheat Straw: 20+ million tons  Forest Residues: 90+ million tons  Mill Residues: 10+ million tons Estimated Sustainable Annual Supply
  • 11. Feedstock Resources - Brazil  Bagasse: 60+ million tons annually  Highly developed sugarcane-to-ethanol program
  • 13. A Note on Feedstocks…  These numbers are conservative, and take into account the main parameters of sustainable collection  Less than 10% of all agricultural residue is used  Pre-collected residues (bagasse & mills) tend to be used for inefficient boiler firing, but are still very low cost
  • 14. What if? ‘Efficient Energy Crops of the Future’  Technology will yield more and more appealing products as time progresses. Agriculture is no different.  ORNL estimates that ‘Dedicated Energy Crops’ could provide nearly 200 million tons of biomass in the U.S. annually.
  • 15. Feedstock Productivity  Corn Stover: 1.5  Wheat Straw: 1.2  Forestry Waste: 5  Energy Crops: >10 Annual tons of Biomass per acre:
  • 16. The Bio-Energy Process  Collection & Densification  Handling/Storage  Transportation  Conversion
  • 17. Biomass Collection: Case Studies Agricultural Residue: Harvest & Collection Costs ($/ton) Approximate Farm-Gate Cost: $27/ton Mowing Baling Stacking Total Source 1: Rice Straw 6 14 7 27 Source 2: Wheat Straw 7 8 11 26 Source 3: Corn Stover 10 12 5 27
  • 18. Biomass Collection: Case Studies Collect/Bundle Foreward/Load Chipping Total Source 1 16 5 3 24 Source 2 7 8 11 26 Source 3 10 12 5 27 Forestry Waste: Collection Costs ($/ton) Approximate Roadside Cost: $26/ton
  • 19. Biomass Collection: Conclusions  One-Pass harvest of both grain and waste biomass would eliminate several steps.  Sustainable collection is important  Agricultural Residue: $27/ton  Forestry Residue: $26/ton  For centrally located feedstocks, purchase cost is $5-$15/ton (based on LHV, alternate uses)
  • 20. The Bio-Energy Process  Collection & Densification  Storage/Handling  Transportation  Conversion
  • 21. Biomass Storage  Agricultural waste that is only harvested once or twice annually requires storage  Large bales stored field side and covered by a tarp will resist damage. This costs about $5/ton.  Forestry waste is generated year-round, and does not require storage  Mill residues and bagasse are stored at the site where they are generated.
  • 22. Biomass Handling  Agricultural waste is transported to a local pickup/storage point.  Forestry waste is forwarded to the side of the road to await transport  Mill residues and bagasse are loaded directly onto trucks and sent to the conversion center
  • 23. The Bio-Energy Process  Collection & Densification  Storage/Handling  Transportation  Conversion
  • 24. Biomass Transport  Truck  Train  Barge  Pipeline? Main Options:
  • 26. Transport Cost: Agricultural Waste Fixed Cost ($/ton) Variable Cost ($/ton-mile) Source 1: Rice Straw Bales 5.5 0.09 Source 2: Wheat Straw Bales 4.5 0.19 Assumed Trucking Cost 5 0.14 Source 3: Freight by Rail 11 0.03 Agricultural Waste Transport 0 5 10 15 20 25 30 35 0 50 100 150 200 Distance (miles) TransportCost($) Trucking Rail
  • 27. Delivered Cost: Agricultural Waste Delivered Cost of Agricultural Feedstock 0 10 20 30 40 50 60 0 50 100 150 200 Distance Cost($/ton) Cost After Storage Delivered Cost (Trucks) Delivered Cost (Rail)
  • 28. Transport Cost: Forestry Waste Fixed Cost ($/ton) Variable Cost ($/ton-mile) Truck Transport 4 0.2 Barge Transport (if possible) 15 0.02
  • 29. Delivered Cost: Forestry Waste Delivered Cost of Forestry Residue 0 10 20 30 40 50 60 70 0 50 100 150 200 Distance Cost($/ton) Flat Costs Delivered Cost Barge (w here available)
  • 31. Pipeline Transport?  Short term: probably not  Long term: more likely  Allows for economies of scale and integrated processes
  • 32. Biomass Transport: Conclusions  Agricultural Waste: <$50/ton  Forestry Waste: <$42/ton  Centralized Feedstocks: <$30/ton Delivered Price:
  • 33. The Bio-Energy Process  Collection & Densification  Storage/Handling  Transportation  Conversion
  • 34. Conversion Technologies  Combustion (gasification)  Fermentation (MixAlco)  Scale is everything!
  • 35. Gasification into Hydrogen Plant Scale (tons of bioimass/day) Cost of Hydrogen ($/GJ) 345 17.08 1150 15.39 1730 14.29 Gasification 0 2 4 6 8 10 12 14 16 18 0 500 1000 1500 2000 Plant Scale (tons of biomass/day) CostofHydrogen($/GJ) Predicted Plant-Gate Hydrogen Selling Price Current Wholesale Hydrogen Price
  • 36. MixAlco  MixAlco is a fermentation process which utilizes cellulosic feedstocks (non-food sources such as waste from agriculture and forests)  Yields chemicals that can be made into acids, alcohols, and hydrogen  Developed by Dr. Mark Holtzapple of Texas A&M University
  • 37. Primary Alcohol Selling Price per Capacity, for different Feedstock costs 0 0.2 0.4 0.6 0.8 1 1.2 1.4 0 1000 2000 3000 4000 5000 Tons of Biomass per Day SellingPrice($/gal) $11/ton $22/ton $33/ton $44/ton $55/ton Today MixAlco Costs
  • 38. A healthy skepticism…  15% ROI may not be high enough for such a high-risk investment  Feedstock quantity and quality are inconsistent  These numbers are educated guesses and may overlook some unseen costs
  • 39. Energy Balance  Lignocellulosic-derived ethanol has a higher NEV (Net Energy Balance - an estimated 60,000 Btu) because of a less energy- intensive conversion process, when compared to traditional ethanol sources like corn  Hydrogen will have even higher NEV because it does not require a fuel-grade liquid
  • 40. Conclusions:  Centralized residues appear to be the most viable option presently  Forestry waste also appears feasible, but not as cost-effective  Agricultural waste appears to be the least economical feedstock presently  Transport costs have the greatest impact on optimal scale  Infrastructure is the only showstopper
  • 41. Acknowledgements: I’d like to thank the members of Shell Gamechanger for giving me the opportunity to take part in this project and learn so much this summer. Special thanks to Jerry Morris, Jack Hirsch, Scott Wellington, Brendan Murray, Ron Reinsfelder, Jingyu Cui, Rebecca Hubbard, Russ Conser, Don Maynard, Tim O’Gorman, Jochen Marwede, Lori Glassgold, Jair Guarda, Jaison Thomas, and the rest of the Gamechanger team. It’s truly been a pleasure!