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UNIT-V
ALTERNATIVE FUELS
Introduction to alternative fuels
 Improve both environment and reduce
india dependence on imported petroleum
Fuels identified include two alcohols
1. Ethanol 2. methanol
Fuel gases at normal temp and pressures,
liquefied petroleum gas, natural gas and
hydrogen
Reason for alternative fuels
• Crude oil and petroleum products will become
scarce and costly to find and produce.
• Motivating the development of alternate fuels
for IC engine Is the concern over emission
problems of gasoline engines
1. LPG – consists mainly of propane, propylene,
butance and butylene in various mixtures
2. Biodiesel is a clean burning alternative fuel
produced from domestic, renewable
resources such as soybeam oil or recycled
grease.
3. Ethanol-
Properties of alternative fuels
• Energy density: Petrol and diesel which liquids have
higher energy density
• Ethanol and methanol are liquids at atmospheric
pressure and ambient temp
• LPG gas at normal temp and pressure is stored in a
liquid form under the pressure
• Both propane and butane have lower energy content
• Natural gas is stored in the vehicle fuel tanks under
pressure as a compressed gas. Both high pressure and
energy density is less
• Hydrogen is less dense than natural gas
• Volatility : Controlled for both engine performance and
emissions.
• Octane number : is a measure a fuel’s tendency to knock in
a SI engine. Knocking occur when the gasoline air vapour
mixture prematurely self ignites as the mixture is
compressed during the upward movement of the piston.
• Cetane number: Ignition characteristics of CI engine fuels.
High octane number means a low cetane number.
• Heat of vapourization: Affects both engine power and
efficiency. High heat of vaporization leads to improved
cooling ability.
• Flame speed:
• Flame temp and luminosity
• Flash point
• Flammability
• Natural Gas in Automobiles:
• Natural gas is a fossil fuel such as petroleum and
coal. The main ingredient is methane.
• Cars, vans, buses and small trucks are use natural
gas which has been compressed called compressed
natural gas stored at high pressure cylinders.
• Properties:
• Colourless, odourless, tasteless, shapeless and
lighter than air.
• It is not possible to see and smell natural gas.
• Natural gas is mixture of light hydrocarbons
including methane, ethane, propane, butanes and
pentanes.
• It is neither corrosive not toxic
• Methane(CH4):
• As a hydrocarbon is considered non-reactive
• Do not react with sunlight to create smong
• It is used engine fuel & SAE
• Advantages
• It has very low emissions, toxies and carbon
monoxide
• It can be made from a variety of feed stocks including
renewable
• It is excellent fuel
• Disadvantages
• Vehicle cost is higher
• Vehicle range is lower
• It has less convenient refueling
• Ethanol: Ethanol called grain alcohol. It si used many
year in US
• Pure ethanol fuel offers the excellent performance
and low hydrocarbon and toxic emissions
• It can produced domestically from corn and cellulose
materials such as wood or paper wastes .
• Advantages:
• It is excellent automotive fuel
• Very low emission of ozone forming hydrocarbon and
toxics
• It made from renewable soures
• It can be domestically produced.
• Disadvantages:
• Fuel cost is high
• Vehicle range is somewhat lower
• Methanol:
• High performance liquid fuel which emits low level
toxic and ozone forming compounds.
• It is excellent automotive fuel
• It is very low emissions
• It can be made from a variety of feedstock including
renewable
• Disadvantages
• Vehicle cost is high
• Propane:
• It is cheaper than gasoline today
• It is widely available clean fuel today
• Emissions are less
• Excellent fuel especially for fleet vehicle.
• LPG
• LPG is mixture of propane and hydrocarbon gases
• LPG is stored in special tanks which keep it under
pressure. It stays as liquid
• Very low sulphur level
• Low cold start emissions due to its gaseous state
at ambient pressure and temp
• Relatively high octane number with propane
having the best antiknock properties relative ot
other component.
• Lower peak pressure during combustion and
reduce noise and improves durabilty
Unitv

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Unitv

  • 2. Introduction to alternative fuels  Improve both environment and reduce india dependence on imported petroleum Fuels identified include two alcohols 1. Ethanol 2. methanol Fuel gases at normal temp and pressures, liquefied petroleum gas, natural gas and hydrogen
  • 3. Reason for alternative fuels • Crude oil and petroleum products will become scarce and costly to find and produce. • Motivating the development of alternate fuels for IC engine Is the concern over emission problems of gasoline engines
  • 4. 1. LPG – consists mainly of propane, propylene, butance and butylene in various mixtures 2. Biodiesel is a clean burning alternative fuel produced from domestic, renewable resources such as soybeam oil or recycled grease. 3. Ethanol-
  • 5. Properties of alternative fuels • Energy density: Petrol and diesel which liquids have higher energy density • Ethanol and methanol are liquids at atmospheric pressure and ambient temp • LPG gas at normal temp and pressure is stored in a liquid form under the pressure • Both propane and butane have lower energy content • Natural gas is stored in the vehicle fuel tanks under pressure as a compressed gas. Both high pressure and energy density is less • Hydrogen is less dense than natural gas
  • 6. • Volatility : Controlled for both engine performance and emissions. • Octane number : is a measure a fuel’s tendency to knock in a SI engine. Knocking occur when the gasoline air vapour mixture prematurely self ignites as the mixture is compressed during the upward movement of the piston. • Cetane number: Ignition characteristics of CI engine fuels. High octane number means a low cetane number. • Heat of vapourization: Affects both engine power and efficiency. High heat of vaporization leads to improved cooling ability. • Flame speed: • Flame temp and luminosity • Flash point • Flammability
  • 7. • Natural Gas in Automobiles: • Natural gas is a fossil fuel such as petroleum and coal. The main ingredient is methane. • Cars, vans, buses and small trucks are use natural gas which has been compressed called compressed natural gas stored at high pressure cylinders. • Properties: • Colourless, odourless, tasteless, shapeless and lighter than air. • It is not possible to see and smell natural gas. • Natural gas is mixture of light hydrocarbons including methane, ethane, propane, butanes and pentanes. • It is neither corrosive not toxic
  • 8. • Methane(CH4): • As a hydrocarbon is considered non-reactive • Do not react with sunlight to create smong • It is used engine fuel & SAE • Advantages • It has very low emissions, toxies and carbon monoxide • It can be made from a variety of feed stocks including renewable • It is excellent fuel • Disadvantages • Vehicle cost is higher • Vehicle range is lower • It has less convenient refueling
  • 9. • Ethanol: Ethanol called grain alcohol. It si used many year in US • Pure ethanol fuel offers the excellent performance and low hydrocarbon and toxic emissions • It can produced domestically from corn and cellulose materials such as wood or paper wastes . • Advantages: • It is excellent automotive fuel • Very low emission of ozone forming hydrocarbon and toxics • It made from renewable soures • It can be domestically produced. • Disadvantages: • Fuel cost is high • Vehicle range is somewhat lower
  • 10. • Methanol: • High performance liquid fuel which emits low level toxic and ozone forming compounds. • It is excellent automotive fuel • It is very low emissions • It can be made from a variety of feedstock including renewable • Disadvantages • Vehicle cost is high • Propane: • It is cheaper than gasoline today • It is widely available clean fuel today • Emissions are less • Excellent fuel especially for fleet vehicle.
  • 11. • LPG • LPG is mixture of propane and hydrocarbon gases • LPG is stored in special tanks which keep it under pressure. It stays as liquid • Very low sulphur level • Low cold start emissions due to its gaseous state at ambient pressure and temp • Relatively high octane number with propane having the best antiknock properties relative ot other component. • Lower peak pressure during combustion and reduce noise and improves durabilty