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Think Small
20 April 2010


Nanomaterials for Green Energy

Tim Mays ( t.j.mays@bath.ac.uk )
Department of Chemical Engineering
A core element of energy policy
must be to ensure the provision of
sustainable, secure and safe heat
     and power for everyone
Scope
Some examples of nanomaterials
for green energy:

• batteries
• energy efficient lighting
• hydrogen storage
Li Batteries: Portable Revolution




• Energy density    small & light
• Over 2 billion cells per year
• Fundamental science (1980s)
   SONY cell (1991)
Low Carbon Transport:
      HEVs & Li Batteries?




     “Materials Challenge”
New or improved materials are key
       to major advances:
        performance, cost
Energy Storage: lithium battery
                        Charge


                          Li+

                        Discharge
                   Li+ - conducting
LixCoO2 cathode    electrolyte               Graphite anode

                           Hybrid

  TRANSPORT
  ~30%+ CO2 emissions
                                      87% cleaner
New or Improved Materials:
     Key to major advances
    “Spinel”        “Layered”              “Olivine”
    LiMn2O4        Li(Mn,Ni)O2             LiFePO4




Structure-property relationships: atomic-scale insight
into Li transport, defects, dopants & surfaces
New LiFePO4 Cathode

Scale-up
                          Defect chem?
                          Li+ transport ?
                          Doping: Zr,Nb?




           Blue: PO4
           Yellow: FeO6
LiFePO4: Li Diffusion Path?
        [010] channel (0.55eV) & curved path




[010]


         [100]                                          Li
                      FeO6 octahedra   PO4 tetrahedra
                                                Chem. Mater (2005)
M Saiful Islam
Department of Chemistry
Nanoparticle Factory-on-a-Chip
Vision: ‘Large scale production of nanoparticles with controllable and reproducible
characteristics will lead to a radical shift in all manufacturing sectors …’ (RAEng/Royal Soc., 2004)

Methodology: Forcing water through a nanoporous membrane into an immiscible solvent produces
nanodroplets, which are then converted into nanoparticles, with control over particle shape, size and properties:

           organic
           solvent     water




                                                                                             10 nm
                                                                     nanoporous alumina membranes
                  nanoparticles                                      have billions of pores per cm2.



             organic
                 L2
             solvent
                                                              Large scale manufacturing of
              water
                L1                                            nanoparticles with controllable
                                                              and reproducible properties.
Nanoparticles are currently used in many applications (fuel cells, sun-blocking creams, solar
panels, fuel additives…) but transformative developments are hindered by the lack of methods
to produce large quantities of nanoparticles with controllable and reproducible properties.
One example of what will be possible to achieve with better nanoparticle property control:




                                                                                           © Benoit Dubertret, 2004
                                                  Diameter (nm)
Lighting fixtures based on quantum dot nanoparticles are 20-30 % more efficient that
fluorescent bulbs and do not contain harmful chemicals. Prototype quantum dot-based
displays are already more efficient than conventional LCD displays.
Today they are made in batches of a few milligrams at a time, against projected market
demand of three tonnes per year by 2012!
(The Economist, 04/03/2010; data from Coe-Sullivan, Nature Photonics, 3, 315-316, 2009 )
Davide Mattia
Department of Chemical Engineering
Hydrogen energy

         hydrogen + oxygen → water + energy

                            2H2 + O2 → 2H2O

         energy = 120 - 142 MJ/kg heat (combustion)


                = 1.23 V electrical potential + 24 MJ/kg heat (fuel cell)     +
  TE
NO




       Only material product of above reaction is water
       Compare: hydrocarbon + oxygen → water + carbon dioxide + …

       A lot of energy per unit mass of hydrogen
       Compare: 40-55 MJ/kg for combustion of hydrocarbons




                                                                              TE
                                                                            NO
Basic principles of hydrogen energy systems

      Ein                     time / location
                                                                  Eout


     energy           produce                store /              energy
       in            hydrogen               distribute              out



    electricity                          liquid hydrogen        combustion
                       water
       heat                             high-pressure gas         fuel cell
                     biomass
       light                            chemical storage
                    fossil fuels
    radiation                              porous solids       2H2+O2 → 2H2O




  many available   many available         H2 easier to store
                                                                 no CO2 at
    sources of      sources of           than many energy
                                                                point of use
     energy             H2                     forms
Hydrogen storage
  technologies
Nanopores


                          Mays, Stud Surf Sci Catal
                          160 (2006) 57




Familiar nanoporous materials
A core element of energy policy
must be to ensure the provision of
sustainable, secure and safe heat
     and power for everyone

    Nanomaterials will have an
   important role in future low
   carbon energy technologies

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T Mays Presentation - Think Small Event

  • 1. Think Small 20 April 2010 Nanomaterials for Green Energy Tim Mays ( t.j.mays@bath.ac.uk ) Department of Chemical Engineering
  • 2. A core element of energy policy must be to ensure the provision of sustainable, secure and safe heat and power for everyone
  • 3. Scope Some examples of nanomaterials for green energy: • batteries • energy efficient lighting • hydrogen storage
  • 4.
  • 5.
  • 6.
  • 7. Li Batteries: Portable Revolution • Energy density small & light • Over 2 billion cells per year • Fundamental science (1980s) SONY cell (1991)
  • 8. Low Carbon Transport: HEVs & Li Batteries? “Materials Challenge” New or improved materials are key to major advances: performance, cost
  • 9. Energy Storage: lithium battery Charge Li+ Discharge Li+ - conducting LixCoO2 cathode electrolyte Graphite anode Hybrid TRANSPORT ~30%+ CO2 emissions 87% cleaner
  • 10. New or Improved Materials: Key to major advances “Spinel” “Layered” “Olivine” LiMn2O4 Li(Mn,Ni)O2 LiFePO4 Structure-property relationships: atomic-scale insight into Li transport, defects, dopants & surfaces
  • 11. New LiFePO4 Cathode Scale-up Defect chem? Li+ transport ? Doping: Zr,Nb? Blue: PO4 Yellow: FeO6
  • 12. LiFePO4: Li Diffusion Path? [010] channel (0.55eV) & curved path [010] [100] Li FeO6 octahedra PO4 tetrahedra Chem. Mater (2005)
  • 14. Nanoparticle Factory-on-a-Chip Vision: ‘Large scale production of nanoparticles with controllable and reproducible characteristics will lead to a radical shift in all manufacturing sectors …’ (RAEng/Royal Soc., 2004) Methodology: Forcing water through a nanoporous membrane into an immiscible solvent produces nanodroplets, which are then converted into nanoparticles, with control over particle shape, size and properties: organic solvent water 10 nm nanoporous alumina membranes nanoparticles have billions of pores per cm2. organic L2 solvent Large scale manufacturing of water L1 nanoparticles with controllable and reproducible properties.
  • 15. Nanoparticles are currently used in many applications (fuel cells, sun-blocking creams, solar panels, fuel additives…) but transformative developments are hindered by the lack of methods to produce large quantities of nanoparticles with controllable and reproducible properties. One example of what will be possible to achieve with better nanoparticle property control: © Benoit Dubertret, 2004 Diameter (nm) Lighting fixtures based on quantum dot nanoparticles are 20-30 % more efficient that fluorescent bulbs and do not contain harmful chemicals. Prototype quantum dot-based displays are already more efficient than conventional LCD displays. Today they are made in batches of a few milligrams at a time, against projected market demand of three tonnes per year by 2012! (The Economist, 04/03/2010; data from Coe-Sullivan, Nature Photonics, 3, 315-316, 2009 )
  • 16.
  • 17. Davide Mattia Department of Chemical Engineering
  • 18.
  • 19. Hydrogen energy hydrogen + oxygen → water + energy 2H2 + O2 → 2H2O energy = 120 - 142 MJ/kg heat (combustion) = 1.23 V electrical potential + 24 MJ/kg heat (fuel cell) + TE NO Only material product of above reaction is water Compare: hydrocarbon + oxygen → water + carbon dioxide + … A lot of energy per unit mass of hydrogen Compare: 40-55 MJ/kg for combustion of hydrocarbons TE NO
  • 20. Basic principles of hydrogen energy systems Ein time / location Eout energy produce store / energy in hydrogen distribute out electricity liquid hydrogen combustion water heat high-pressure gas fuel cell biomass light chemical storage fossil fuels radiation porous solids 2H2+O2 → 2H2O many available many available H2 easier to store no CO2 at sources of sources of than many energy point of use energy H2 forms
  • 21.
  • 22. Hydrogen storage technologies
  • 23. Nanopores Mays, Stud Surf Sci Catal 160 (2006) 57 Familiar nanoporous materials
  • 24.
  • 25. A core element of energy policy must be to ensure the provision of sustainable, secure and safe heat and power for everyone Nanomaterials will have an important role in future low carbon energy technologies