SYNTHESIS OF
NEW ELEMENTS
IN THE
LABORATORY
OBJECTIVES:
• Explain how the concept of
atomic numbers led to the
synthesis of the new elements
in the laboratory
• Write the nuclear reactions
involved in the synthesis of
new elements
PERIODIC TABLE OF ELEMENTS
• Shows the tabular arrangement of tabular
elements
GROUP (FAMILY)
•Exhibit related
physical and chemical
properties
PERIOD
•Order elements in
increasing atomic number
ELEMENTS IN PERIODIC TABLE
• NUCLIDE
- atomic species characterized by the specific
constitution of its nucleus
ELEMENTS IN PERIODIC TABLE
• Discovered or synthesized
• 94 natural occurring elements
• 24 synthetic elements
SYNTHETIC ELEMENTS
• a chemical element that does not occur
naturally on Earth
• can only be created artificially
• radioactive and decay rapidly into lighter
elements
• only occur on Earth as the product of atomic
bombs or experiments
NUCLEAR
REACTOR
PARTICLE
ACCELERATOR
NUCLEAR REACTION
• Term implied that causes a
nuclide to change by
bombarding it with energetic
particle
• Involves a heavy target
nucleus and a light
bombarding particle
• Produces a heavier product
nucleus
• Emits a very high
electromagnetic energy
NUCLEAR REACTION INVOLVED IN
SYNTHESIS OF NEW ELEMENT IN
THE LABARATORY
1. Capture Reaction
2. Fission Reaction
3. Fusion reaction
THERMONUCLEAR FUSION
• Uses extremely
high temperature
• Temperature is a
measure of the
average kinetic
energy of a
particle
AMERICIUM
• analogy was named after
the Americas
• first produced in 1944 by
the group of Glenn T.
Seaborg
• uranium or plutonium
being bombarded
with neutrons in nuclear
reactors
CURIUM
• was named
after Marie and Pierre Curie –
both were known for their
research on radioactivity
• first intentionally produced and
identified in July 1944 by the
group of Glenn T. Seaborg
• produced by
bombarding uranium
or plutonium with neutrons in nu
clear reactors
BERKELIUM
• named after the city
of Berkeley, California where
it was discovered in
December 1949
• produced by bombarding
lighter
actinides uranium (238
U)
or plutonium (239
Pu)
with neutrons in a nuclea
reactor
CALIFORNIUM
• first synthesized on or
about February 9, 1950
• Most of these applications
exploit the property of
certain isotopes of
californium to emit neutrons
• made by bombarding
berkelium-249 with
neutrons
EINSTEINIUM
• discovered as a
component of the debris
of the first hydrogen
bomb explosion in 1952
• named after Albert
Einstein
• produced in minute
quantities by bombarding
lighter actinides with
neutrons
FERMIUM
• the heaviest element that can be
formed by neutron bombardment
of lighter elements
• discovered in the debris of
the first hydrogen
bomb explosion in 1952
• named after Enrico Fermi
• produced by the bombardment
of lighter actinides
with neutrons in a nuclear
reactor
MENDELEVIUM
• first element that currently
cannot be produced in
macroscopic quantities
through neutron bombardment
of lighter elements
• discovered by
bombarding einsteinium with al
pha particles in 1955
• bombarding plutonium and am
ericium targets with lighter ions
of carbon and nitrogen
NOBELIUM
• named in honor of Alfred Nobel,
the inventor of dynamite and
benefactor of science
• can only be produced in particle
accelerators by bombarding
lighter elements with charged
particles
• produced by bombarding
actinide targets to neutron
• 255
No, can be produced from
bombarding curium-248 or
californium-249 with carbon-12
LAWRENCIUM
• named in honor of Ernest
Lawrence, inventor of
the cyclotron
• 266
Lr isotopes are produced only
as alpha decay products
of dubnium
• 255
Lr to 262
Lr can all be produced
by bombarding actinide
(americium to einsteinium)
targets with light ions
(from boron to neon)
RUTHERFORDIUM
• Produced in the 1960s
• Synthesized the element
by bombarding
a californium-249 target
with carbon-12 ion
• correlated with the
daughter decay
of nobelium-253
DUBNIUM
• element was officially
named in 1997 after the
town of Dubna
• 243
Am was bombarded by
a beam of 22
Ne ions
• synthesized the element
by bombarding
a californium-249 target
with nitrogen-15 ions
SEABORGIUM
• named after the
American nuclear
chemist Glenn T. Seaborg
• produced in laboratories
in 1974
• targets of lead-208 and lead-
207 were bombarded with
accelerated ions
of chromium-54
Bohrium
• named after Danish physicist Niels
Bohr
• was first reported in 1976 by a
Russian research team led by
Yuri Oganessian
• targets of bismuth-209 and lead-
208 were bombarded with
accelerated nuclei of chromium-54
and manganese-55 respectively
HASSIUM
• named after the German
state of Hesse
• bombarded a target of
lead-208 with
accelerated nuclei of
iron-58 to produce
3 atoms of the isotope
hassium-265
• The most stable known
isotope, meitnerium-278, has
a half-life of 7.6 seconds
• named for Lise Meitner
• bombarded a target
of bismuth-209 with
accelerated nuclei of iron-58
and detected a single atom
of the isotope meitnerium-
266
MEITNERIUM
DARMSTADTIUM
• An extremely radioactive synthetic
element
• has a half-life of approximately
10 seconds
• bombarded a lead-208 target with
accelerated nuclei of nickel-62 in a
heavy ion accelerator and
detected a single atom of the
isotope darmstadtium-269
ROENTGENIUM
• named after the
physicist Wilhelm Röntgen
• bombarded a target
of bismuth-209 with
accelerated nuclei of nickel-64
and detected a single atom of
the isotope roentgenium-272
COPERNICIUM
• was created by firing
accelerated zinc-70
nuclei at a target made
of lead-208 nuclei in a
heavy ion accelerator
NIHONIUM
• name comes from the common Japanese
name for Japan
• half-life of about 8 seconds
• was identified as an alpha decay product of
element 115, moscovium in August 2003
• Synthesized via cold fusion reactions
(bombarding closed-
shell lead and bismuth targets with
3d transition metal ions, creating fused
nuclei with low excitation energies due to
the magic shells of the targets)
FLEROVIUM
• bombarded a target
of plutonium-244 with
accelerated nuclei
of calcium-48
MOSCOVIUM
• bombarded americium-
243 with calcium-48 ions
to produce four atoms of
moscovium. These atoms
decayed by emission of
alpha-particles
to nihonium in about
100 milliseconds
LIVERMORIUM
• bombarded a curium-248 target
with accelerated calcium-48
ions. A single atom was
detected, decaying by alpha
emission with decay
energy 10.54 MeV to an
isotope of flerovium. The
results were published in
December 2000.
TENNESSINE
• involved fusing
a berkelium (element 97)
target and
a calcium (element 20)
beam, conducted via
bombardment of the
berkelium target with
calcium nuclei
OGANESSON
• synthesized in 2002 by a
joint team of Russian and
American scientists
headed by Russian
nuclear physicist Yuri
Oganessian
• produced via collisions
of californium-249 atoms
and calcium-48 ions
EXTENDED PERIODIC TABLE
• theorizes about elements
beyond oganesson (beyond period 7, or row 7)
• An eight-period table containing this block was
suggested by Glenn T. Seaborg in 1969
• elements with atomic number 119(Ununennium)-
127(Unbiseptium)
“The science of
today is technology
of tomorrow”
-Edward Teller
THANK YOU!

synthesisofnewelementsinthelaboratory-.ppt

  • 1.
  • 2.
    OBJECTIVES: • Explain howthe concept of atomic numbers led to the synthesis of the new elements in the laboratory • Write the nuclear reactions involved in the synthesis of new elements
  • 3.
    PERIODIC TABLE OFELEMENTS • Shows the tabular arrangement of tabular elements
  • 4.
    GROUP (FAMILY) •Exhibit related physicaland chemical properties PERIOD •Order elements in increasing atomic number
  • 5.
    ELEMENTS IN PERIODICTABLE • NUCLIDE - atomic species characterized by the specific constitution of its nucleus
  • 6.
    ELEMENTS IN PERIODICTABLE • Discovered or synthesized • 94 natural occurring elements • 24 synthetic elements
  • 7.
    SYNTHETIC ELEMENTS • achemical element that does not occur naturally on Earth • can only be created artificially • radioactive and decay rapidly into lighter elements • only occur on Earth as the product of atomic bombs or experiments
  • 11.
  • 12.
    NUCLEAR REACTION • Termimplied that causes a nuclide to change by bombarding it with energetic particle • Involves a heavy target nucleus and a light bombarding particle • Produces a heavier product nucleus • Emits a very high electromagnetic energy
  • 13.
    NUCLEAR REACTION INVOLVEDIN SYNTHESIS OF NEW ELEMENT IN THE LABARATORY 1. Capture Reaction 2. Fission Reaction 3. Fusion reaction
  • 14.
    THERMONUCLEAR FUSION • Usesextremely high temperature • Temperature is a measure of the average kinetic energy of a particle
  • 15.
    AMERICIUM • analogy wasnamed after the Americas • first produced in 1944 by the group of Glenn T. Seaborg • uranium or plutonium being bombarded with neutrons in nuclear reactors
  • 16.
    CURIUM • was named afterMarie and Pierre Curie – both were known for their research on radioactivity • first intentionally produced and identified in July 1944 by the group of Glenn T. Seaborg • produced by bombarding uranium or plutonium with neutrons in nu clear reactors
  • 17.
    BERKELIUM • named afterthe city of Berkeley, California where it was discovered in December 1949 • produced by bombarding lighter actinides uranium (238 U) or plutonium (239 Pu) with neutrons in a nuclea reactor
  • 18.
    CALIFORNIUM • first synthesizedon or about February 9, 1950 • Most of these applications exploit the property of certain isotopes of californium to emit neutrons • made by bombarding berkelium-249 with neutrons
  • 19.
    EINSTEINIUM • discovered asa component of the debris of the first hydrogen bomb explosion in 1952 • named after Albert Einstein • produced in minute quantities by bombarding lighter actinides with neutrons
  • 20.
    FERMIUM • the heaviestelement that can be formed by neutron bombardment of lighter elements • discovered in the debris of the first hydrogen bomb explosion in 1952 • named after Enrico Fermi • produced by the bombardment of lighter actinides with neutrons in a nuclear reactor
  • 21.
    MENDELEVIUM • first elementthat currently cannot be produced in macroscopic quantities through neutron bombardment of lighter elements • discovered by bombarding einsteinium with al pha particles in 1955 • bombarding plutonium and am ericium targets with lighter ions of carbon and nitrogen
  • 22.
    NOBELIUM • named inhonor of Alfred Nobel, the inventor of dynamite and benefactor of science • can only be produced in particle accelerators by bombarding lighter elements with charged particles • produced by bombarding actinide targets to neutron • 255 No, can be produced from bombarding curium-248 or californium-249 with carbon-12
  • 23.
    LAWRENCIUM • named inhonor of Ernest Lawrence, inventor of the cyclotron • 266 Lr isotopes are produced only as alpha decay products of dubnium • 255 Lr to 262 Lr can all be produced by bombarding actinide (americium to einsteinium) targets with light ions (from boron to neon)
  • 24.
    RUTHERFORDIUM • Produced inthe 1960s • Synthesized the element by bombarding a californium-249 target with carbon-12 ion • correlated with the daughter decay of nobelium-253
  • 25.
    DUBNIUM • element wasofficially named in 1997 after the town of Dubna • 243 Am was bombarded by a beam of 22 Ne ions • synthesized the element by bombarding a californium-249 target with nitrogen-15 ions
  • 26.
    SEABORGIUM • named afterthe American nuclear chemist Glenn T. Seaborg • produced in laboratories in 1974 • targets of lead-208 and lead- 207 were bombarded with accelerated ions of chromium-54
  • 27.
    Bohrium • named afterDanish physicist Niels Bohr • was first reported in 1976 by a Russian research team led by Yuri Oganessian • targets of bismuth-209 and lead- 208 were bombarded with accelerated nuclei of chromium-54 and manganese-55 respectively
  • 28.
    HASSIUM • named afterthe German state of Hesse • bombarded a target of lead-208 with accelerated nuclei of iron-58 to produce 3 atoms of the isotope hassium-265
  • 29.
    • The moststable known isotope, meitnerium-278, has a half-life of 7.6 seconds • named for Lise Meitner • bombarded a target of bismuth-209 with accelerated nuclei of iron-58 and detected a single atom of the isotope meitnerium- 266 MEITNERIUM
  • 30.
    DARMSTADTIUM • An extremelyradioactive synthetic element • has a half-life of approximately 10 seconds • bombarded a lead-208 target with accelerated nuclei of nickel-62 in a heavy ion accelerator and detected a single atom of the isotope darmstadtium-269
  • 31.
    ROENTGENIUM • named afterthe physicist Wilhelm Röntgen • bombarded a target of bismuth-209 with accelerated nuclei of nickel-64 and detected a single atom of the isotope roentgenium-272
  • 32.
    COPERNICIUM • was createdby firing accelerated zinc-70 nuclei at a target made of lead-208 nuclei in a heavy ion accelerator
  • 33.
    NIHONIUM • name comesfrom the common Japanese name for Japan • half-life of about 8 seconds • was identified as an alpha decay product of element 115, moscovium in August 2003 • Synthesized via cold fusion reactions (bombarding closed- shell lead and bismuth targets with 3d transition metal ions, creating fused nuclei with low excitation energies due to the magic shells of the targets)
  • 34.
    FLEROVIUM • bombarded atarget of plutonium-244 with accelerated nuclei of calcium-48
  • 35.
    MOSCOVIUM • bombarded americium- 243with calcium-48 ions to produce four atoms of moscovium. These atoms decayed by emission of alpha-particles to nihonium in about 100 milliseconds
  • 36.
    LIVERMORIUM • bombarded acurium-248 target with accelerated calcium-48 ions. A single atom was detected, decaying by alpha emission with decay energy 10.54 MeV to an isotope of flerovium. The results were published in December 2000.
  • 37.
    TENNESSINE • involved fusing aberkelium (element 97) target and a calcium (element 20) beam, conducted via bombardment of the berkelium target with calcium nuclei
  • 38.
    OGANESSON • synthesized in2002 by a joint team of Russian and American scientists headed by Russian nuclear physicist Yuri Oganessian • produced via collisions of californium-249 atoms and calcium-48 ions
  • 39.
    EXTENDED PERIODIC TABLE •theorizes about elements beyond oganesson (beyond period 7, or row 7) • An eight-period table containing this block was suggested by Glenn T. Seaborg in 1969 • elements with atomic number 119(Ununennium)- 127(Unbiseptium)
  • 40.
    “The science of todayis technology of tomorrow” -Edward Teller
  • 41.