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Prepared by: Miss. Shruti B. Chaudhari
A
Seminar
on
Study of Graphene As A
Lubricant
Contents
 Introduction
 Literature Review
 Graphene
 Case Study
 Conclusion
Introduction
 Lubrication
 Wear and Friction
 Necessity of Lubrication
 Advantages of Lubrication
 Applications of Lubrication
 Lubricants
 Types of Lubricants
Solid
Semi-solid
Liquid
Gaseous
 Functions of Lubricants
 Characteristics of ideal Lubricants
Literature Review
Sr.
No.
Name of
Author
Title of paper Year Methodology Conclusion
1 Jinshan Lin
Liwei Wang
Guohua Chen
Modification of Graphene
Platelets and their
Tribological
Properties as a Lubricant
Additive
2010 Experimental The overall lubricious
properties of
the lubricating oil were
notably improved, due to
the addition of MGP.
2 D. Berman,
A Erdemir,
A. V. Sumant
Graphene: a new
emerging lubricant
2014 Review Overview of the use of
graphene as lubricant for
nano scale as well as
macro scale.
3 Oleksiy
Penkov et al
Tribology of Graphene: A
Review
2014 Review Review of tribology of
graphene and factors
influencing its friction
and wear behaviour.
Sr.
No
.
Name of
Author
Title of paper Year Methodology Conclusion
4 E.D. Ramón-
Raygoza et al
Development of
nanolubricant based on
impregnated multilayer
graphene for automotive
applications: Analysis of
tribological properties
2016 Experimental Engine oil added with
MLG and MLG
impregnated with
nanomaterials showed the
ability to integrate a
friction modifier with
an anti-wear modifier in a
single lubricant
5 A.K. Rasheed
et al
Graphene based nanofluids
and nanolubricants –
Review of recent
developments
2016 Review Review of recent
developments in graphene
based lubricants.
GRAPHENE
 Two dimensional honeycomb lattice
 History
Andre Geim and Konstantin Novoselov (University of
Manchester)
Methods of Synthesis
Properties of Graphene
 High Mechanical strength
 High Thermal conductivity
 Chemical Inertness
 Automatically smooth surface
 High Flexibility
 Exhibit superlubricity on lattice
mismatch
Graphene : Solid Lubricant
 Graphene powder or flakes are used as
lubricant.
 High load carrying capacity
 Friction and wear reduction depends on
number of layers of graphene
 With a coating thickness of 0.001-0.002µm,
graphene gives a coefficient of friction of
0.15-0.2 in humid as well as dry conditions.
Graphene : Additive in base
oils
 Graphene flakes are dispersed in
base oils
 Graphene is modified for enhanced
lubrication
 Base oil along with graphene reduces
wear rate upto 4 orders of magnitude
 Also used as additive in greases
Parameters affecting friction and
wear
 Number of graphene layers
 Defects in graphene
 Magnitude of load
 Addition of Substrate
 Oxidation of graphene
 Concentration of graphene in additives
Case Study
I. Modification of graphene platelets and their
tribological properties as a lubricant.
Base oil used: SN350
Additives used: Modified Graphene Platelets(MGP),
Modified Natural Flake Graphite(MNFG).
Modifier used: Oleic Acid and Stearic Acid
Machine used: MS 10A Four Ball Machine
Results
 Stability Test  Load test
Fig. Suspension stability of lubricating
oils with MGP and GP
Fig. Effect of MGP and MNFG
concentration on maximum nonseizure
load
 Wear Rate  Friction Coefficient
Fig. Wear rate as a function of
friction time
Fig. Friction Coefficient as a function
of friction time
• Surface Analysis
a) For base oil b) For base oil with MNFG
c) For base oil with MGP
II. Oil impregnated with multi layer graphene for
automotive applications:
Base oil used: SAE 25 W-50
Additives used : Multilayered graphene(MLG),
MLG-Cu, MLG-PANI
Machine used: Tribometer -T05-block-on-ringwear
tester
Results
-10
-5
0
5
10
15
20
25
30
35
40
45
ReductioninFrictionCoefficient%
0
10
20
30
40
50
60
70
ReductioninWearCoefficient%
Conclusion
 Graphene has properties like high mechanical
strength, chemical inertness, smooth surface,
etc which makes it an ideal lubricant.
 Compared to most other solid lubricants, gives
low coefficient of friction
 Gives brilliant results when used as an
additive.
 Graphene is a relatively unexplored area and
has a good future scope.

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Study of Graphene as lubricant

  • 1. Prepared by: Miss. Shruti B. Chaudhari A Seminar on Study of Graphene As A Lubricant
  • 2. Contents  Introduction  Literature Review  Graphene  Case Study  Conclusion
  • 3. Introduction  Lubrication  Wear and Friction  Necessity of Lubrication  Advantages of Lubrication  Applications of Lubrication
  • 4.  Lubricants  Types of Lubricants Solid Semi-solid Liquid Gaseous  Functions of Lubricants  Characteristics of ideal Lubricants
  • 5. Literature Review Sr. No. Name of Author Title of paper Year Methodology Conclusion 1 Jinshan Lin Liwei Wang Guohua Chen Modification of Graphene Platelets and their Tribological Properties as a Lubricant Additive 2010 Experimental The overall lubricious properties of the lubricating oil were notably improved, due to the addition of MGP. 2 D. Berman, A Erdemir, A. V. Sumant Graphene: a new emerging lubricant 2014 Review Overview of the use of graphene as lubricant for nano scale as well as macro scale. 3 Oleksiy Penkov et al Tribology of Graphene: A Review 2014 Review Review of tribology of graphene and factors influencing its friction and wear behaviour.
  • 6. Sr. No . Name of Author Title of paper Year Methodology Conclusion 4 E.D. Ramón- Raygoza et al Development of nanolubricant based on impregnated multilayer graphene for automotive applications: Analysis of tribological properties 2016 Experimental Engine oil added with MLG and MLG impregnated with nanomaterials showed the ability to integrate a friction modifier with an anti-wear modifier in a single lubricant 5 A.K. Rasheed et al Graphene based nanofluids and nanolubricants – Review of recent developments 2016 Review Review of recent developments in graphene based lubricants.
  • 7. GRAPHENE  Two dimensional honeycomb lattice  History Andre Geim and Konstantin Novoselov (University of Manchester)
  • 9. Properties of Graphene  High Mechanical strength  High Thermal conductivity  Chemical Inertness  Automatically smooth surface  High Flexibility  Exhibit superlubricity on lattice mismatch
  • 10. Graphene : Solid Lubricant  Graphene powder or flakes are used as lubricant.  High load carrying capacity  Friction and wear reduction depends on number of layers of graphene  With a coating thickness of 0.001-0.002µm, graphene gives a coefficient of friction of 0.15-0.2 in humid as well as dry conditions.
  • 11. Graphene : Additive in base oils  Graphene flakes are dispersed in base oils  Graphene is modified for enhanced lubrication  Base oil along with graphene reduces wear rate upto 4 orders of magnitude  Also used as additive in greases
  • 12. Parameters affecting friction and wear  Number of graphene layers  Defects in graphene  Magnitude of load  Addition of Substrate  Oxidation of graphene  Concentration of graphene in additives
  • 13. Case Study I. Modification of graphene platelets and their tribological properties as a lubricant. Base oil used: SN350 Additives used: Modified Graphene Platelets(MGP), Modified Natural Flake Graphite(MNFG). Modifier used: Oleic Acid and Stearic Acid Machine used: MS 10A Four Ball Machine
  • 14. Results  Stability Test  Load test Fig. Suspension stability of lubricating oils with MGP and GP Fig. Effect of MGP and MNFG concentration on maximum nonseizure load
  • 15.  Wear Rate  Friction Coefficient Fig. Wear rate as a function of friction time Fig. Friction Coefficient as a function of friction time
  • 16. • Surface Analysis a) For base oil b) For base oil with MNFG c) For base oil with MGP
  • 17. II. Oil impregnated with multi layer graphene for automotive applications: Base oil used: SAE 25 W-50 Additives used : Multilayered graphene(MLG), MLG-Cu, MLG-PANI Machine used: Tribometer -T05-block-on-ringwear tester
  • 19. Conclusion  Graphene has properties like high mechanical strength, chemical inertness, smooth surface, etc which makes it an ideal lubricant.  Compared to most other solid lubricants, gives low coefficient of friction  Gives brilliant results when used as an additive.  Graphene is a relatively unexplored area and has a good future scope.