The Roebling Steel Company site in New Jersey was contaminated by lead released over many years of steel production. Lead contamination spread through soil, groundwater, and air, affecting nearby residential areas that obtained drinking water from wells near the site. Epidemiological studies have linked lead exposure to developmental effects in children as well as neurological, reproductive, and other health impacts in humans and animals. The contamination degraded the local environment and ecosystem through pathways like biomagnification of lead in the food chain. The EPA conducted extensive cleanup and control efforts to reduce risks to public health from the contaminated Roebling Steel Company Superfund site.
Reduce microbial contamination with ready to use eco friendly silver hydrogen...Chemtex Speciality Limited
This document introduces two new ready-to-use formulations of silver hydrogen peroxide as safer alternatives to toxic disinfectants. Silver hydrogen peroxide is an eco-friendly disinfectant known for its antimicrobial efficacy, flexibility of use, non-toxicity, and biodegradability. The two new formulations - Alstasan Silvox 150 Fume and Alstasan Silvox 150 Mist - can be used for fumigation of indoor spaces and direct spraying of surfaces, respectively, without requiring preparation before use.
IRJET- Physical, Chemical, Analysis of Ground Water Around the Eletroplating ...IRJET Journal
This document discusses the removal of heavy metals from industrial wastewater using low-cost agricultural waste materials as adsorbents. It begins by introducing the problem of heavy metal pollution from industries like electroplating. It then provides background on adsorption as a method for wastewater treatment and removal of toxins like lead, chromium, and nickel. The document examines the use of inexpensive adsorbents derived from agricultural waste including maize cob, coffee husk, and cashewnut husk to purify industrial effluent in a cost-effective way. In summary, the document explores a natural approach for remediating heavy metal contamination through adsorption onto low-cost adsorbents from agricultural by
The document discusses heavy metals, which are defined as metallic elements that are relatively dense and toxic in low concentrations. Common heavy metals include aluminum, antimony, arsenic, barium, bismuth, cadmium, lead, mercury, nickel, uranium, and tin. Heavy metals enter the human body through food and water. While some heavy metals like iron and zinc are essential nutrients, others such as cadmium and lead are highly toxic even in small amounts. Sources of heavy metal exposure include mining, industrial waste, vehicle emissions, and food/water contamination. The document provides details on specific heavy metals like cadmium, chromium, arsenic, and lead, their sources, and health effects.
Study of corrosion control effect of H2S scavengers in drilling fluidsMutiu K. Amosa, Ph.D.
Selected environmentally benign iron compounds (synthetic magnetite and ferrous gluconate) have been evaluated as corrosion inhibitors for oil-well steel (N-80) in 50 mg/l sulphide concentration at various pH ranging from 5.5 to 11.5 and at High Temperature, High Pressure (HTHP) conditions by the weight loss method. The test temperatures were 150 °F, 275 °F and 350 °F respectively for pressures of 3 000 psi, 5 000 psi and 6 000 psi. The ferrous complex was found to be a better corrosion inhibitor compared to the synthetic magnetite. It exhibited up to 99.2% inhibition efficiency (IE) when the dose of the scavenger was doubled (i.e. when the sulphide to scavenger ratio was 1:2) irrespective of other factors such as pH, temperature and pressure. Whereas, the synthetic magnetite’s optimum inhibition efficiency (IE) was observed to be up to 75.1% only when the ratio of the sulphide to scavenger was 1:4 at the lowest pH of the experiment (pH 5.5) which is not desirable for a drilling mud. As the pH increases, the inhibition efficiency of the magnetite decreases and found to be lowest at the alkaline pH of 11.5.
Shalaby2021 article green_synthesis of recyclable iron nanoparticlesHalaYassinElKassas
This research article describes the green synthesis of iron oxide nanoparticles (SP-IONPs) using the microalgae Spirulina platensis for removing cationic and anionic dyes from aqueous solutions. The SP-IONPs were characterized using various techniques. Batch experiments were conducted to evaluate the sorption performance of the SP-IONPs for removing crystal violet and methyl orange dyes under different parameters. The SP-IONPs showed maximum sorption capacities of 256.4 mg/g and 270.2 mg/g for crystal violet and methyl orange, respectively, fitting well with the Langmuir model. The kinetics followed pseudo-second order kinetics and thermodynamics showed the process was endothermic. The
1) The study analyzed heavy metal concentrations in the tissues of 6 fish species from the Mediterranean Sea to understand the relationship between metal accumulation and fish size.
2) Metal concentrations were generally highest in the liver and varied between species, with cadmium levels highest in the liver of Trigla cuculus.
3) A negative relationship was found between metal levels and fish size for most species, though zinc and lead showed a positive relationship with size in Mugil cephalus.
4) The results provide insight into how species differences, tissue types, and size affect heavy metal accumulation in aquatic organisms.
Reduce microbial contamination with ready to use eco friendly silver hydrogen...Chemtex Speciality Limited
This document introduces two new ready-to-use formulations of silver hydrogen peroxide as safer alternatives to toxic disinfectants. Silver hydrogen peroxide is an eco-friendly disinfectant known for its antimicrobial efficacy, flexibility of use, non-toxicity, and biodegradability. The two new formulations - Alstasan Silvox 150 Fume and Alstasan Silvox 150 Mist - can be used for fumigation of indoor spaces and direct spraying of surfaces, respectively, without requiring preparation before use.
IRJET- Physical, Chemical, Analysis of Ground Water Around the Eletroplating ...IRJET Journal
This document discusses the removal of heavy metals from industrial wastewater using low-cost agricultural waste materials as adsorbents. It begins by introducing the problem of heavy metal pollution from industries like electroplating. It then provides background on adsorption as a method for wastewater treatment and removal of toxins like lead, chromium, and nickel. The document examines the use of inexpensive adsorbents derived from agricultural waste including maize cob, coffee husk, and cashewnut husk to purify industrial effluent in a cost-effective way. In summary, the document explores a natural approach for remediating heavy metal contamination through adsorption onto low-cost adsorbents from agricultural by
The document discusses heavy metals, which are defined as metallic elements that are relatively dense and toxic in low concentrations. Common heavy metals include aluminum, antimony, arsenic, barium, bismuth, cadmium, lead, mercury, nickel, uranium, and tin. Heavy metals enter the human body through food and water. While some heavy metals like iron and zinc are essential nutrients, others such as cadmium and lead are highly toxic even in small amounts. Sources of heavy metal exposure include mining, industrial waste, vehicle emissions, and food/water contamination. The document provides details on specific heavy metals like cadmium, chromium, arsenic, and lead, their sources, and health effects.
Study of corrosion control effect of H2S scavengers in drilling fluidsMutiu K. Amosa, Ph.D.
Selected environmentally benign iron compounds (synthetic magnetite and ferrous gluconate) have been evaluated as corrosion inhibitors for oil-well steel (N-80) in 50 mg/l sulphide concentration at various pH ranging from 5.5 to 11.5 and at High Temperature, High Pressure (HTHP) conditions by the weight loss method. The test temperatures were 150 °F, 275 °F and 350 °F respectively for pressures of 3 000 psi, 5 000 psi and 6 000 psi. The ferrous complex was found to be a better corrosion inhibitor compared to the synthetic magnetite. It exhibited up to 99.2% inhibition efficiency (IE) when the dose of the scavenger was doubled (i.e. when the sulphide to scavenger ratio was 1:2) irrespective of other factors such as pH, temperature and pressure. Whereas, the synthetic magnetite’s optimum inhibition efficiency (IE) was observed to be up to 75.1% only when the ratio of the sulphide to scavenger was 1:4 at the lowest pH of the experiment (pH 5.5) which is not desirable for a drilling mud. As the pH increases, the inhibition efficiency of the magnetite decreases and found to be lowest at the alkaline pH of 11.5.
Shalaby2021 article green_synthesis of recyclable iron nanoparticlesHalaYassinElKassas
This research article describes the green synthesis of iron oxide nanoparticles (SP-IONPs) using the microalgae Spirulina platensis for removing cationic and anionic dyes from aqueous solutions. The SP-IONPs were characterized using various techniques. Batch experiments were conducted to evaluate the sorption performance of the SP-IONPs for removing crystal violet and methyl orange dyes under different parameters. The SP-IONPs showed maximum sorption capacities of 256.4 mg/g and 270.2 mg/g for crystal violet and methyl orange, respectively, fitting well with the Langmuir model. The kinetics followed pseudo-second order kinetics and thermodynamics showed the process was endothermic. The
1) The study analyzed heavy metal concentrations in the tissues of 6 fish species from the Mediterranean Sea to understand the relationship between metal accumulation and fish size.
2) Metal concentrations were generally highest in the liver and varied between species, with cadmium levels highest in the liver of Trigla cuculus.
3) A negative relationship was found between metal levels and fish size for most species, though zinc and lead showed a positive relationship with size in Mugil cephalus.
4) The results provide insight into how species differences, tissue types, and size affect heavy metal accumulation in aquatic organisms.
SCIENCE(SOLID WASTE) Power point-by SADIYA AKBAR SURVESADIYA1234
The document discusses the harmful effects of solid waste. It notes that solid waste can cause air, water, and soil pollution as well as bad odors and the production of toxic gases. It also discusses how solid waste can spread diseases. The key harmful effects mentioned are air pollution, water pollution, soil pollution, bad odors from waste, and the production of toxic gases from waste that can spread diseases.
Heavy metals like mercury, cadmium, and lead can contaminate drinking water. Mercury has no biological function and is toxic even at low levels. It enters water through industrial and agricultural pollution, sewage discharge, and the natural degassing of volcanoes. In water, mercury can transform into organic methyl mercury through bacteria, which bioaccumulates in fish and poses a health risk for humans. There are several processes to remove mercury from drinking water, including coagulation/filtration, granular activated carbon, lime softening, and reverse osmosis. Coagulation uses chemicals to precipitate mercury out of water, while granular carbon and reverse osmosis use filtration and semipermeable membranes.
Isolation and characterization of zinc resistant bacteria from a coil coating...Joshua Owolabi
This study isolated and characterized zinc-resistant bacteria from the wastewater treatment plant of a coil coating industrial facility in Nigeria. Ten zinc-resistant bacterial strains were isolated from treated wastewater samples on nutrient agar supplemented with zinc sulphate, and identified as species of Bacillus, Micrococcus, Serratia, Proteus, Aeromonas, and Citrobacter. Further testing showed that eight isolates were resistant to zinc concentrations of 6 mM and above. Four isolates also exhibited resistance to lead. Most isolates (70%) were resistant to multiple antibiotics. The zinc-resistant bacteria isolated could potentially be used to bioremediate zinc and lead contamination.
Corrosion is the process of metals returning to their natural state through a series of electrochemical reactions when in contact with water. It occurs due to the large difference in reduction potentials between oxygen and most metals. Common types of corrosion include uniform corrosion and galvanic corrosion. Corrosion can be prevented through methods like galvanizing, alloying, corrosion inhibitors, and cathodic protection. The proposed project aims to alter water parameters to deposit a CaCO3 barrier on metal surfaces to prevent corrosion without adding foreign elements or altering metal properties.
This document summarizes a study on using sodium diethyl dithiocarbamate to remove heavy metals from electroplating industry wastewater. It begins with background on heavy metal pollution from industrial sources and its effects. The document then reviews literature on electroplating wastewater composition and various treatment methods. The objectives of this study are to characterize wastewater from 5 electroplating sites, measure parameters like pH, BOD, COD and heavy metals, precipitate heavy metals from wastewater using sodium diethyl dithiocarbamate, and test using the precipitate as a plant disease management agent. The methodology describes analyzing wastewater samples for color, odor, turbidity, pH, total
This document discusses safety controversies regarding tooth bleaching. It describes how tooth bleaching uses peroxide compounds, mainly hydrogen peroxide and carbamide peroxide, as active ingredients. While tooth bleaching is generally safe, concerns have been raised about potential local adverse effects on enamel, gingiva, pulp, and restorative materials, as well as systemic effects and carcinogenicity. The document reviews the evidence regarding these safety issues and concludes that proper use of bleaching can maximize benefits while minimizing risks, though more research is still needed to fully understand some controversies like bleaching's potential carcinogenicity.
This document analyzes the phytoremediation potential of Lemna minor (duckweed) for removing heavy metals from two types of effluents - sewage mixed industrial effluent (SMIE) and municipal effluent (ME). In a 31-day glasshouse experiment, L. minor was able to accumulate heavy metals like cadmium, copper, lead, and nickel from both effluents. Removal efficiency was over 80% for all metals, with maximum removal of nickel (99%) from SMIE. L. minor was a moderate accumulator, with bioconcentration factors under 1000. It was more effective at extracting lead than other metals. Overall, L. minor showed potential for phytore
Heavy metal pollution from sources like industrial effluents and vehicle emissions is a growing global problem. Some key heavy metals that are toxic to humans include cadmium, lead, and mercury. Cadmium toxicity can cause vomiting, diarrhea and bone deformities. Lead exposure is linked to anemia, kidney problems, and changes in bone marrow. Mercury poisoning results in issues like diarrhea, breathing difficulties, and abdominal pain. Heavy metals are a threat because unlike some other pollutants, they do not break down in the environment.
Suitability of leaching test methods for fly ash and slag a reviewManoj Kumar Tiwari
This document reviews different leaching test methods for assessing fly ash and slag. It discusses that leaching tests aim to simulate natural leaching in the laboratory but no single test can exactly replicate real-world conditions. The document outlines several commonly used leaching test methods and categorizes them as either static extraction tests with a single leaching fluid addition or dynamic tests where the fluid is renewed. It also discusses factors that must be considered in selecting a suitable test method, such as waste properties, disposal conditions, and climate. The review examines different leaching test standards and frameworks proposed by researchers for standardized testing of fly ash and slag.
Heavy metal pollution in soil and its mitigation aspect by Dr. Tarik MitranDr. Tarik Mitran
Heavy metal pollution in soil is a serious problem. Some key points:
- Heavy metals like lead, cadmium, arsenic, chromium, and mercury are toxic even in small amounts and can accumulate in the food chain.
- Sources of heavy metal pollution include industrial, agricultural, and mining activities which release these metals into the environment.
- Heavy metals can be taken up by plants and crops irrigated with contaminated water, accumulating in plant tissues and eventually entering the food chain. This poses risks to human and animal health.
- Remediating contaminated soils requires understanding the chemical processes by which heavy metals move and change form in the soil-water-air system over time. Mitigation strategies aim to reduce
This document discusses heavy metal soil contamination, its causes and health effects. Heavy metals can contaminate soil through mining, landfills and industrial activities. This leads to issues like the contamination of farmland near copper mines in Peru and the adverse health effects on residents living near a lead smelter in Boolaroo, Australia. The document also examines solutions to heavy metal contamination like bioremediation, phytoremediation and rhizoremediation, which use organisms or plants to clean up soils. More research is still needed to improve the success of remediation methods.
Heavy metals like chromium, copper, cadmium, lead, and nickel were found to contaminate drinking water in Agra City, India. Chromium levels were highest, likely due to chrome tanning used in many local leather industries. Concentrations of chromium, copper, and lead exceeded permissible limits, posing health risks. Removing heavy metals using biotechnology methods like microorganisms that absorb metals was suggested to improve water quality and protect public health.
This document summarizes concerns about applying sewage sludge to farmland. It notes that sewage sludge contains concentrated contaminants like heavy metals and organic pollutants. While the EPA regulates certain metals in sludge, there are no limits for many synthetic chemicals. Pathogens may not be fully eliminated in Class A sludge. Case studies show examples where sludge application resulted in environmental contamination and harm to livestock and human health. The complexity of sludge composition and lack of regulation for all contaminants mean the risks are difficult to assess and manage safely.
Acute Toxicity and Bioaccumulation Patterns of Lead and Zinc in Juveniles of ...iosrjce
Acute toxicity of lead and zinc salts (Pb(NO3)2 and ZnCl2) and their bioaccumulation patterns in
juveniles of Clarias gariepinus was investigated. ZnCl2 with a 96hr LC50 value of 15.301mg/l was found to be
more toxic than Pb(NO3)2 with a 96hr LC50 value of 51.516mg/l. ZnCl2 was bio-accumulated at a faster rate
in the gills and flesh of the fish than Pb(NO3)2 . The amount of ZnCl2 and Pb(NO3)2 bio-accumulated reduced
as the experiment proceeded. Higher levels of ZnCl2 were recorded in the gills than in the flesh of the juvenile
fishes. Essential heavy metals can be more toxic to aquatic organisms than non essential heavy metals when the
former is present in high enough concentrations. Water chemistry, speciation and bio-availability of heavy
metals in surrounding media are major factors that determine rate of accumulation in aquatic organisms.
Removal of lead and oil hydrocarbon from oil refining contaminated wastewater...Alexander Decker
This document summarizes a study that investigated the potential of three Pseudomonas bacterial species (P. florescence, P. paucimobilis, and Pseudomonas sp.) to remove lead and crude oil from wastewater from an oil refinery in Alexandria, Egypt. The study tested different bacteria to wastewater ratios in batch experiments and measured the removal efficiency of lead, oil, biochemical oxygen demand (BOD), and chemical oxygen demand (COD). The results showed high removal efficiency of lead (over 90%) and oil (56.8-68.8%) and partial removal of COD and BOD. P. florescence was the most effective and a bacteria to wastewater ratio of
ABSTRACT- Aquatic organisms have been considered to concentrate metals several times greater than environmental levels. Fishes have been used for many decades to evaluate the pollution status of water and thus considered as excellent biological indicator of heavy metals in aquatic environments. Heavy metals are natural tress components of the aquatic environment, but their levels have increased due to domestic, industrial, mining and agricultural activities. These heavy metals when accumulated in the fish tissues, they damage and weaken the mechanisms concerned leading to physiological, pathological and biochemical changes. The lead is non essential element while cobalt is an essential element for living organisms but its presence in fresh water in higher concentration are toxic to organism’s brain, liver, ovary, kidney and gills of the fish. The present study was aimed to investigate the changes due to two heavy metals (lead & cobalt) on the activity of the antioxidant enzyme, Catalase (CAT), Reduced glutathione (GSH), and Lipid peroxidation (LPO) in the brain of Danio rerio during 5, 10, 15 and 20 days of exposure period. For this study adult fishes were exposed to four different concentrations viz., 20, 30, 40 and 50 mg/l of cobalt and 5, 9, 13, and 17 mg/l of lead. Key-words- Zebrafish, Lead, Cobalt, Catalase, LPO, Glutathione, Heavy metals
Biosorption kinetics of vetiveria zizanioides rhizobacter on heavy metals con...Alexander Decker
This study investigated the kinetics of biosorption of heavy metals in contaminated wastewater using two bacteria - Bacillus cereus and Bacillus subtilis - isolated from the rhizosphere of the Vetiveria zizanioides plant. The results showed that B. cereus accumulated the most lead (96.75%), cadmium (23%), and zinc (16.98%), while B. subtilis accumulated the most lead (95.2%), cadmium (41.3%), and zinc (32.2%). Kinetic studies revealed that the uptake of heavy metals followed pseudo-second order kinetics. The goal was to determine the potential of these microorganisms for bioremediating wast
Selenium is an essential element found naturally in the environment through weathering of rocks. It enters plants and air through dust and is released during combustion of coal and oil. Both too little and too much selenium can impact human health. It can accumulate in organisms and biomagnify up the food chain. Occupational exposure to high levels of selenium through air can cause respiratory effects. Measures are needed to reduce selenium levels to protect environmental and human health.
GIZOCORP is an office relocation and facility management company that has been in business for over 10 years, with a team that has over 35 years of combined experience. They specialize in office moves, including new and existing installations. GIZOCORP can assist with internal office relocations and facility maintenance needs. They have all necessary accreditations and their staff and vehicles are fully compliant with regulations. They provide references from reputable clients.
SCIENCE(SOLID WASTE) Power point-by SADIYA AKBAR SURVESADIYA1234
The document discusses the harmful effects of solid waste. It notes that solid waste can cause air, water, and soil pollution as well as bad odors and the production of toxic gases. It also discusses how solid waste can spread diseases. The key harmful effects mentioned are air pollution, water pollution, soil pollution, bad odors from waste, and the production of toxic gases from waste that can spread diseases.
Heavy metals like mercury, cadmium, and lead can contaminate drinking water. Mercury has no biological function and is toxic even at low levels. It enters water through industrial and agricultural pollution, sewage discharge, and the natural degassing of volcanoes. In water, mercury can transform into organic methyl mercury through bacteria, which bioaccumulates in fish and poses a health risk for humans. There are several processes to remove mercury from drinking water, including coagulation/filtration, granular activated carbon, lime softening, and reverse osmosis. Coagulation uses chemicals to precipitate mercury out of water, while granular carbon and reverse osmosis use filtration and semipermeable membranes.
Isolation and characterization of zinc resistant bacteria from a coil coating...Joshua Owolabi
This study isolated and characterized zinc-resistant bacteria from the wastewater treatment plant of a coil coating industrial facility in Nigeria. Ten zinc-resistant bacterial strains were isolated from treated wastewater samples on nutrient agar supplemented with zinc sulphate, and identified as species of Bacillus, Micrococcus, Serratia, Proteus, Aeromonas, and Citrobacter. Further testing showed that eight isolates were resistant to zinc concentrations of 6 mM and above. Four isolates also exhibited resistance to lead. Most isolates (70%) were resistant to multiple antibiotics. The zinc-resistant bacteria isolated could potentially be used to bioremediate zinc and lead contamination.
Corrosion is the process of metals returning to their natural state through a series of electrochemical reactions when in contact with water. It occurs due to the large difference in reduction potentials between oxygen and most metals. Common types of corrosion include uniform corrosion and galvanic corrosion. Corrosion can be prevented through methods like galvanizing, alloying, corrosion inhibitors, and cathodic protection. The proposed project aims to alter water parameters to deposit a CaCO3 barrier on metal surfaces to prevent corrosion without adding foreign elements or altering metal properties.
This document summarizes a study on using sodium diethyl dithiocarbamate to remove heavy metals from electroplating industry wastewater. It begins with background on heavy metal pollution from industrial sources and its effects. The document then reviews literature on electroplating wastewater composition and various treatment methods. The objectives of this study are to characterize wastewater from 5 electroplating sites, measure parameters like pH, BOD, COD and heavy metals, precipitate heavy metals from wastewater using sodium diethyl dithiocarbamate, and test using the precipitate as a plant disease management agent. The methodology describes analyzing wastewater samples for color, odor, turbidity, pH, total
This document discusses safety controversies regarding tooth bleaching. It describes how tooth bleaching uses peroxide compounds, mainly hydrogen peroxide and carbamide peroxide, as active ingredients. While tooth bleaching is generally safe, concerns have been raised about potential local adverse effects on enamel, gingiva, pulp, and restorative materials, as well as systemic effects and carcinogenicity. The document reviews the evidence regarding these safety issues and concludes that proper use of bleaching can maximize benefits while minimizing risks, though more research is still needed to fully understand some controversies like bleaching's potential carcinogenicity.
This document analyzes the phytoremediation potential of Lemna minor (duckweed) for removing heavy metals from two types of effluents - sewage mixed industrial effluent (SMIE) and municipal effluent (ME). In a 31-day glasshouse experiment, L. minor was able to accumulate heavy metals like cadmium, copper, lead, and nickel from both effluents. Removal efficiency was over 80% for all metals, with maximum removal of nickel (99%) from SMIE. L. minor was a moderate accumulator, with bioconcentration factors under 1000. It was more effective at extracting lead than other metals. Overall, L. minor showed potential for phytore
Heavy metal pollution from sources like industrial effluents and vehicle emissions is a growing global problem. Some key heavy metals that are toxic to humans include cadmium, lead, and mercury. Cadmium toxicity can cause vomiting, diarrhea and bone deformities. Lead exposure is linked to anemia, kidney problems, and changes in bone marrow. Mercury poisoning results in issues like diarrhea, breathing difficulties, and abdominal pain. Heavy metals are a threat because unlike some other pollutants, they do not break down in the environment.
Suitability of leaching test methods for fly ash and slag a reviewManoj Kumar Tiwari
This document reviews different leaching test methods for assessing fly ash and slag. It discusses that leaching tests aim to simulate natural leaching in the laboratory but no single test can exactly replicate real-world conditions. The document outlines several commonly used leaching test methods and categorizes them as either static extraction tests with a single leaching fluid addition or dynamic tests where the fluid is renewed. It also discusses factors that must be considered in selecting a suitable test method, such as waste properties, disposal conditions, and climate. The review examines different leaching test standards and frameworks proposed by researchers for standardized testing of fly ash and slag.
Heavy metal pollution in soil and its mitigation aspect by Dr. Tarik MitranDr. Tarik Mitran
Heavy metal pollution in soil is a serious problem. Some key points:
- Heavy metals like lead, cadmium, arsenic, chromium, and mercury are toxic even in small amounts and can accumulate in the food chain.
- Sources of heavy metal pollution include industrial, agricultural, and mining activities which release these metals into the environment.
- Heavy metals can be taken up by plants and crops irrigated with contaminated water, accumulating in plant tissues and eventually entering the food chain. This poses risks to human and animal health.
- Remediating contaminated soils requires understanding the chemical processes by which heavy metals move and change form in the soil-water-air system over time. Mitigation strategies aim to reduce
This document discusses heavy metal soil contamination, its causes and health effects. Heavy metals can contaminate soil through mining, landfills and industrial activities. This leads to issues like the contamination of farmland near copper mines in Peru and the adverse health effects on residents living near a lead smelter in Boolaroo, Australia. The document also examines solutions to heavy metal contamination like bioremediation, phytoremediation and rhizoremediation, which use organisms or plants to clean up soils. More research is still needed to improve the success of remediation methods.
Heavy metals like chromium, copper, cadmium, lead, and nickel were found to contaminate drinking water in Agra City, India. Chromium levels were highest, likely due to chrome tanning used in many local leather industries. Concentrations of chromium, copper, and lead exceeded permissible limits, posing health risks. Removing heavy metals using biotechnology methods like microorganisms that absorb metals was suggested to improve water quality and protect public health.
This document summarizes concerns about applying sewage sludge to farmland. It notes that sewage sludge contains concentrated contaminants like heavy metals and organic pollutants. While the EPA regulates certain metals in sludge, there are no limits for many synthetic chemicals. Pathogens may not be fully eliminated in Class A sludge. Case studies show examples where sludge application resulted in environmental contamination and harm to livestock and human health. The complexity of sludge composition and lack of regulation for all contaminants mean the risks are difficult to assess and manage safely.
Acute Toxicity and Bioaccumulation Patterns of Lead and Zinc in Juveniles of ...iosrjce
Acute toxicity of lead and zinc salts (Pb(NO3)2 and ZnCl2) and their bioaccumulation patterns in
juveniles of Clarias gariepinus was investigated. ZnCl2 with a 96hr LC50 value of 15.301mg/l was found to be
more toxic than Pb(NO3)2 with a 96hr LC50 value of 51.516mg/l. ZnCl2 was bio-accumulated at a faster rate
in the gills and flesh of the fish than Pb(NO3)2 . The amount of ZnCl2 and Pb(NO3)2 bio-accumulated reduced
as the experiment proceeded. Higher levels of ZnCl2 were recorded in the gills than in the flesh of the juvenile
fishes. Essential heavy metals can be more toxic to aquatic organisms than non essential heavy metals when the
former is present in high enough concentrations. Water chemistry, speciation and bio-availability of heavy
metals in surrounding media are major factors that determine rate of accumulation in aquatic organisms.
Removal of lead and oil hydrocarbon from oil refining contaminated wastewater...Alexander Decker
This document summarizes a study that investigated the potential of three Pseudomonas bacterial species (P. florescence, P. paucimobilis, and Pseudomonas sp.) to remove lead and crude oil from wastewater from an oil refinery in Alexandria, Egypt. The study tested different bacteria to wastewater ratios in batch experiments and measured the removal efficiency of lead, oil, biochemical oxygen demand (BOD), and chemical oxygen demand (COD). The results showed high removal efficiency of lead (over 90%) and oil (56.8-68.8%) and partial removal of COD and BOD. P. florescence was the most effective and a bacteria to wastewater ratio of
ABSTRACT- Aquatic organisms have been considered to concentrate metals several times greater than environmental levels. Fishes have been used for many decades to evaluate the pollution status of water and thus considered as excellent biological indicator of heavy metals in aquatic environments. Heavy metals are natural tress components of the aquatic environment, but their levels have increased due to domestic, industrial, mining and agricultural activities. These heavy metals when accumulated in the fish tissues, they damage and weaken the mechanisms concerned leading to physiological, pathological and biochemical changes. The lead is non essential element while cobalt is an essential element for living organisms but its presence in fresh water in higher concentration are toxic to organism’s brain, liver, ovary, kidney and gills of the fish. The present study was aimed to investigate the changes due to two heavy metals (lead & cobalt) on the activity of the antioxidant enzyme, Catalase (CAT), Reduced glutathione (GSH), and Lipid peroxidation (LPO) in the brain of Danio rerio during 5, 10, 15 and 20 days of exposure period. For this study adult fishes were exposed to four different concentrations viz., 20, 30, 40 and 50 mg/l of cobalt and 5, 9, 13, and 17 mg/l of lead. Key-words- Zebrafish, Lead, Cobalt, Catalase, LPO, Glutathione, Heavy metals
Biosorption kinetics of vetiveria zizanioides rhizobacter on heavy metals con...Alexander Decker
This study investigated the kinetics of biosorption of heavy metals in contaminated wastewater using two bacteria - Bacillus cereus and Bacillus subtilis - isolated from the rhizosphere of the Vetiveria zizanioides plant. The results showed that B. cereus accumulated the most lead (96.75%), cadmium (23%), and zinc (16.98%), while B. subtilis accumulated the most lead (95.2%), cadmium (41.3%), and zinc (32.2%). Kinetic studies revealed that the uptake of heavy metals followed pseudo-second order kinetics. The goal was to determine the potential of these microorganisms for bioremediating wast
Selenium is an essential element found naturally in the environment through weathering of rocks. It enters plants and air through dust and is released during combustion of coal and oil. Both too little and too much selenium can impact human health. It can accumulate in organisms and biomagnify up the food chain. Occupational exposure to high levels of selenium through air can cause respiratory effects. Measures are needed to reduce selenium levels to protect environmental and human health.
GIZOCORP is an office relocation and facility management company that has been in business for over 10 years, with a team that has over 35 years of combined experience. They specialize in office moves, including new and existing installations. GIZOCORP can assist with internal office relocations and facility maintenance needs. They have all necessary accreditations and their staff and vehicles are fully compliant with regulations. They provide references from reputable clients.
Sixth Circuit Court of Appeals Decision in Harper v Muskingum Watershed Conse...Marcellus Drilling News
Anti-drilling landowners (backed by Food & Water Watch) claimed the Muskingum Watershed Conservancy District had violated the deed to the land it owns by leasing that land for Utica Shale drilling. The Sixth Circuit dismissed the case. The anti-drillers lost.
Schedule 13D - Stone Energy Corporation - Largest Shareholder Opposes Bankrup...Marcellus Drilling News
Stone Energy's largest investor, Thomas Satterfield, owns 9.9% of the company's stock. He doesn't want to see that stock turned into toilet paper by handing the keys over to debtholders under the current bankruptcy plan. He filed this report with the SEC opposing Stone's existing plan.
This document provides an overview of DevOps with containers in VPC and hybrid cloud environments. It discusses problems with traditional development and operations workflows, and how DevOps addresses these through automation, integration, measurement, communication and collaboration. It then covers Docker containers, microservices architectures, DevOps pipelines, container orchestration, automatic scaling, high availability, and deploying workloads across public and private clouds or regions for redundancy.
Dinsdag 19 februari 2016 kwamen zo’n 60 installatiebedrijven uit Friesland naar Leeuwarden voor de bijeenkomst Zonnestroom voor de installatiebranche. Friesland wil 25% duurzame energie opwekken in 2025. ‘Dit stimuleren we met financieel voordeel voor MKB bedrijven die de keuze maken voor zonnestroom’, aldus Henk Schrier, gedeputeerde van de Provinsje Fryslan. ‘Daarvoor zijn professionele adviespartners zonnestroom voor het MKB nodig’, is de aanvulling van Paul Molenaar van ROC Friese Poort Bedrijfsopleidingen.
Klik door voor meer informatie:
http://www.centrumduurzaamfriesland.nl/nieuws/zonnestroom-met-financieel-voordeel-voor-mkb-bedrijven-in-friesland/
Columbia Gas of Ohio Agreement to Ship Gas on NEXUS Gas Transmission PipelineMarcellus Drilling News
Columbia Gas of Ohio has signed a long-term contract to ship 50,000 decatherms per day (50 million cubic feet per day) of natural gas along the NEXUS from two points in Ohio and Pennsylvania to a point in Sandusky County, OH. This document provides the details.
FERC Order Denying Stay of Kinder Morgan's Broad Run Expansion ProjectMarcellus Drilling News
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1. 1
Evan Gross
IssuesinEnvironmental&Occupational Health
Roebling Steel Co. Superfund Site
Event & Contaminant Properties
In one shortparagraph, please introduce the eventandthe contaminantresponsible.
The RoeblingSteel Companywasaformerwire productsand steel manufacturerplant,
operatedbyseveral differentcompaniesandtenantsoverthe years, whichwasinvolvedwith
famousprojectssuchas the GoldenGate Bridge andthe George WashingtonBridge.Itwas
closedinthe 1970’s, and declaredafederal Superfundsite in1982. It is a 200-acre site,located
inFlorence TownshipinBurlingtonCounty,NJalongthe Delaware River.Althoughithelped
produce beautiful bridgesandotherusesforsociety withsteel,the landitoccupied became
contaminatedfromthe productionthatwasdone on the landfor years. Althoughthisisa
complicatedsite withseveral contaminantsandmethodsof cleanupandcontrol of hazardous
issues, Iwill focusonthe effectsof leadandhow itcontaminated soil,groundwater,andairof
RoeblingSteelCo.(http://www.epa.gov/Region2/superfund/npl/0200439c.pdf).
Was thissubstance the cause of a contaminationpriortothisevent?If so,how and where?
There wasnot a specificeventof contamination,butacumulatingof yearsof unsafe practices
on the RoeblingSteelSuperfundsite, whichledtoliquidwastes,solidwastes,andgasesof
containingleadbeingreleasesintothe atmosphere contaminatingair,soil,andwaterways in
and aroundthe RoeblingSteel Co.site (“RECORDOFDECISION” 848590013-14). The
contaminatedmediumswere soil(includingslagarea),sediment,andgroundwater
(848590007).
What isthe currentresidentialpopulationinthe townwhere thisreleaseoccurred?
The current populationaccordingtothe 2010 US Censusinthe townof Roebling,NJ,the
locationof RoeblingSteelCo.is3,715 (“Your GeographySelections”).
Were the residentsof thisareasuppliedbypublicwater,ordidtheyhave private wells?
Residentsof the areaare suppliedbypublicsuppliedwells2mileswestof the site. (“RECORDOF
DECISION”848590011). The cityof Burlington,whichisapproximately6milesdownstreamfrom
Roebling,obtainswaterfromthe Delaware River,alongwithshallowgroundwaterwells.The
groundwaterfrom the Roeblingsite flowssouthwestfromthe site directlyintothe Delaware
River.
How isthiscontaminantgenerallyused(industrial,commercial and/orsocietal uses)?
Lead isa heavysoftmetal that has beenusedin waterpipes,pottery,ammunition,radiation
shielding, instained-glasswindows, additiveingasoline, lead-acidstorage batteries, building
material, andmore!(“LeadStatisticsandInformation”).
Was thiscontaminantreleasedinagaseous,liquidorsolidform?
The contaminantleadisa solid.It was mixedintoliquids,due todifferentprocessesinthe mills,
intoan effluentthatwasreleasedintothe groundwater. The millsusedlarge amountsof water
inproduction,andleadwouldcontaminate groundandsurface areas,alongwiththe effluent
flowingintothe Delaware River.Leadwasalsoreleasedintothe atmosphereasa gas. (“RECORD
OF DECISION” 848590013-14).
Is thissubstance typicallyfoundcombinedwithotherharmful and/orbenignchemicals?
Lead isan element,butisrarelyfoundinthatstate.Instead,itisusuallyfoundinitsoxidative
state,inoresthroughoutthe world(Sanders).These orescancontaincopper,zinc,andsilver
2. 2
and leadisusuallyextractedwiththese metals.Itisfoundinthe environmentnaturally,but
areas withhigherconcentrationare due tohumansusinglead,whichcausesthe environmentto
become contaminated.Leadalsowasfoundmixedwithtoxicchemicalsingasoline,andwould
evaporate intothe skythencome back to contaminate waterwhenitrains("WaterTreatment
Solutions"). Inthe case of Roebling,leadwasinprocessedwater,alongwithiron,zinc,oil,
chloride,phosphate,sulfate,soap,andspentpickleacid.Itwasalsofoundinsoil waste and was
releasedasvolatilizedgasintoenvironmental,andresidueswerefoundonprocessequipment
inthe factories(“RECORDOFDECISION” 848590014).
Human & Animal Health
What humanroutesof exposure are associatedwiththiscontaminant?
Most humanroutesof exposure toleadare ingestionandinhalation.Absorptionisapossible
but notlikelywayof beingexposedtoleadbecause leadedgasoline use hasceased.However,
organicleadworkershave a higherchance than the general populationatbeingexposedtolead
viainhalation. Ingestionisthe mostcommonroute of exposure forchildrendue tomanytoys
and paintscontaininglead,along withthe sweettaste leadhas ("LeadToxicity"16-20).
What acute and/orchronichealtheffectshave beenassociatedwiththiscontaminant?
Lead can be absorbed,ingested,orinhaled.Accordingtothe CDC,there isno thresholdfor
developmental effectsinchildren.The CDC alsostatedthatlead couldalsoaffecteveryorgan
systeminthe body,withthe nervoussystembeingthe mostsensitive due toleadbeinga
neurotoxicagentandcan leadtomany differentneurological effects("LeadToxicity" 30-7).
Reproductive functionscanalsobe affected,suchasdecreasedspermcountsinmen,andas we
watchedinclassabout the womanand herdisabledson,exposure toleadwhilepregnantcan
leadto disabledchildren. AccordingtoMoeller, generallyspeaking, whenleadisinhaled, itcan
accumulate inbone,softtissues,andblood.Since leadisnoteasilyexcreted,itcanleadto
affectsof the kidneys,nervoussystem, liver,andotherorgansthat produce bloodinthe body,
and withincreasedexposure comes neurological problems,forexample seizures,mental
retardation,and/orbehavioral problems (Moeller98).
Is thiscontaminanta knownorsuspectedcarcinogen,teratogen,mutagen,neurotoxin,
immunotoxinorreproductive risk?
Lead isa knownas a developmentalneurotoxicantthatcan affectthe brainand itsdevelopment
and function.Researchhasshownithaseffectsonthe central nervoussystem(CNS) and
exposuresasayouthcan leadto problemslaterinlife.Leadexposure cancause memory,vision,
cognitive,andbehavioral problems,alongwithmental retardation.Allthese effectsare
associatedwiththe brain(Sanders).AccordingtoDictionary.com, neurotoxicis“poisonousto
nerve tissue,astothe brain or spinal cord,”and neurotoxinis“aneurotoxicsubstance,as
rattlesnake venomorthe poisonof ablack widow spider.” Leadisalsoa neurotoxicsubstance,
and isfoundnaturallyinthe environmentinsoil underground.
Have any epidemiological studiesbeenconducted,linkingthiscontaminantwithillness?
There are several epidemiological studiesthathave beenconductedthathave linkedleadwith
illness,especiallyoneslinkedtoproblemsduringpregnancyandreproduction,alongwithmany
showingleadtohave effects onneurobiological development.These includedcohort,case-
control study,ecological andcross-sectional studies.Anyof these studiescanbe searched
online,usinggooglescholarorotherscholarlyresearch-findingsources. There isnospecific
epidemiological studyfoundregardingleadexposure onthe RoeblingSteel site. Forexample,
there wasan epidemiological studycompletedwithagroupof 434 womenthatshowedthat
earlymenopause wasrelatedtohigherexposureof lead.Itshowedthatthe highestlead
3. 3
exposedgrouphadmenopause 1.21yearsearlierthan didwomeninthe lowestleadexposed
group.Thisstudy concludedthatlevelsof exposure tolead couldbringonmenopause for
womenat a fasterrate (Eum).
Are there human/animal/cell toxicologicalstudiescitingthe specificriskstothiscontaminant?
There wasa studydone in rats that showedthatexposure tolead isa riskfactor for
osteoporosisbecauseleadwasshowntodecrease bone densityinratsalongwithalso
decreasingthe abilityforrats toheal fromfractures(Sharifi 225). Part of the reasonof thisis
because leadisstoredinbone marrow,andcan be transferredtootherparts of the body,
includingthe blood,whichshowsinhighlevelsof leadinaperson’sblood(Riedt90).
What otherhealthriskshasthiscontaminantbeenshowntopose tohumansand animals?
Some healthriskswere noticedinthe assessmentof Rochester,NYpopulation,whichcontained
childrenwithanaverage rate overthe safe limitsof leaddue tomany oldhousesbuiltwithlead
paint.Impactsfromthis exposure inMonroe County,inwhichRochesterislocated,included
over1,000 childrenwhowere 6x as likelytohave learningdisabilities, more than1,000 children
7x as likelythantheirpeerstodropoutof highschool,andover1000 childrenwhowere lost
earningpotential bynothavingIQ’s10 pointshigher (Stoss290).
What kindsof workersmightbe at riskin handlingthiscontaminant?
Workerswhoworkedonlandsof the RoeblingSteelCo. andpeople whocleaned upthe site
possiblycouldbe atriskbecause the abilitytobe exposedtoleadwaspresent.Inaddition,
anglersinthe Delaware Riverorpeople whouseditforrecreationcouldhave beenincontact
withleadcontaminationinthe water. The goal of the EPA’scause was “to protectpublichealth
or welfare orthe environmentfromactual or threatenedreleasesof hazardoussubstancesfrom
the site intothe environment”(“RECORDOFDECISION”848590002).
Environmental Health
Throughwhichenvironmental medium/mediawasthiscontaminantreleased?
The contaminantwasreleasedinthe water,soil,andsedimentation. Itwasalsoreleasesinto
atmosphere asvolatilizedgas(“RECORDOFDECISION” 848590014).
Didthe contaminationremaininimmediate proximityto the source,ordidit become more
widespreadanddiffuse?If so,how?
Acidiceffluentcontainingleadandotherheavymetalswasreleasedfrompartof the factory
ownedbyCF & I (ColoradoFuel andIron) intothe Delaware River,causingthe water
environmenttobecome messedupdue tothe low pH of the water.Whereverthiswater
traveled,dependingonthe currentof the river,iswhere itdiffused.Thiswasdiscoveredwhen
the NJDOH wenttoinvestigate the plant,anddiscovered15-milliongallonsof untreatedeffluent
was beingreleasedonadailybasis(“RECORDOF DECISION” 848590015).
Was the particularincident/eventinyourarticle(s) responsible fordegradationtothe environment
or personal property?
As the EPA investigated,there wereresponsible partiesthatcontributedtothe degradationof
the environmentonthe settingof the RoeblingSteel Co(848590020-21).
Were there anyfar-reachingeffectsonthe ecosystematlarge,like biomagnificationof the
contaminantthroughthe foodchain?
Lead usuallyaccumulatesinsurface groundwater andaccumulates inplantsinanimalswhich
thenhumanseat,so biomagnificationdoesoccurthroughthe foodchain (Ong1549).
Summary
4. 4
Whichfederal,state and/orlocal governmental agencieshadastake inthiscontamination?
The EPA was the leadagencyinthe cleanupof the site.The NJDEP isa supportagencyinvolved
withthe site. The site wasput onthe National Prioritieslistbythe EPA (“RECORDOF DECISION”
848590011).
Is there,orwas there,anongoinginvestigationandcleanupinvolvingthisevent/site?(i.e.,wasthe
site declaredafederal Superfundsite withrequisiteabatement?).
RoeblingSteelCo. wasputon the National PrioritieslistinDecember1982, and wasdeclareda
federal Superfundsite in September1983. In 1985, a remedial investigationandfeasibilitystudy
was completedbythe EPA anddecidedtohandle the manydifferentcontaminationspresentin
differentphases(848590017). From priorknowledge,the formersedimentareahasbeen
cleanedoutandis nowa part for the communitytoenjoy.
Were any finesoradministrative penaltiesimposedonthe generator,distributororstorage facility
involvedwiththiscontaminant?
In 1985 and 1987, general notice lettersweresenttopotential responsible parties(PRP)
following the Comprehensive EnvironmentalResponse,CompensationandLiabilityActof 1980
(CERCLA),whichwasamended,toinformpastandpresentownersof theirinvolvementin
environmental contamination.NoPRPrespondedatthat time.Eventually,throughsearching
theyfoundthatCF & I,a formersite operator,hadreleasedorpotentiallyreleased
environmental contaminantssuchasleadthroughtheirunsafe handlingpractices. CF& I was
undergoingbankruptcy.Eventuallyitwasall sorted out,andin August1995, CF & I paid the EPA
$2.2 milliondollars(“RECORDOFDECISION” 848590020-21).
What didlocal officialsdotocommunicate the risktothe publicorinvolve theminasolution?
AftertownofficialsandresidentsfoundoutaboutRoeblingasaSuperfundsite in1983 on the
news,townofficialstookmeasurestokeepthe communityinvolvedinthe followingyears.
However,townofficialscontendtheywere notbriefedpriortorelease of the information,and
communicationbetweenstate andfederal officialswaspoor.Concerninthe townwasveryhigh
and so wasresidentinvolvement.The EPA became involvedwithinformingthe publicbyhaving
several informationsessions,attendingtownmeetings,andprovidingfactsheetsonthe
RoeblingSteelEPA website. Publicinterestinthe cleanupof the site remainedhighthroughthe
cleanupprocess (848590259-60).
In youropinion,couldthiscontaminationhave beeneasily prevented?How?
In myopinion,Ithinkthiscontaminationcouldhave beenpreventedif the knowledgewe have
nowwas applied whenthe RoeblingSteelCo.wasestablished. If today’srulesandregulations
were ineffect whenthe factorywasbeingbuilt,manyof the chemicalsusedinproduction
wouldnothave beenused. One tool thatcouldbe appliedinthe contaminationof leadin
Roeblingisthe Hierarchyof Controls,aslearnedinDr.Cohen’slessononOccupational Healthat
the RutgersSchool of PublicHealthonJuly 30, 2015. Thissystemisusedto reduce and/or
eliminatehazardousexposure inthe workplace. The toptwostepsof the Hierarchyof Controls
are EliminationandSubstitution,respectively,andthese are usedtoavoidthe hazard being
presentaltogether,whichinthe topicof thispaper, wouldbe avoidingthe use of leadin
operationsatthe RoeblingSteel Factory.Eliminationisphysicallyremovingthe hazard,and
substitutionisreplacingthe hazards.Byavoidingleadinthe workplace,italsopreventsthe
environmentfrom beinginfectedwiththe hazard,causingdamage toplants,animals,and
residentsinthe local area. Anotherstepthatcould have beenusedwaslearnedinthe Resource
ConservationandRecoveryAct,andthatconceptis cradle to grave.If RoeblingSteel Co. were
more responsibleinhandlingtheirownwastes,theywouldhave beenmore thoughtful intheir
abilitytouse and recycle theirownwastes.