RADIOACTIVITY
and
RADIOACTIVE DECAY
REYNALDO S. JIMENEZ
Nuclear Training Center
Philippine Nuclear Research Institute
What is RADIATION ?
Has been around since the
earth was formed 4500
million years ago.
Can be detected, measured
and controlled.
87% of radiation dose
comes from natural sources,
e.g... cosmic, food we eat,
our homes
13% result of man’s activities..
- Medical Applications
(diagnosis and treatment of
disease)
- Industrial application
(inspection of welds, detection
of cracks in or cast metal)
- Research application (dating
of antiquities, food
preservation)
Radiation – any form energy that
travels and dissipates.
Ionizing Radiation – Its interaction with matter
may result to creation of charged particles.
Non-Ionizing Radiation – its interaction with
matter will not result to creation of charged
particles.
Everything in nature,
every creature
and every material
contains, and
always has contained,
radioactive
substances.
You are radioactive
yourself,
and so is your dog,
your coffee,
your seatmate,
and your mother-in-law.
Radiation is all around us.
Sunshine is one of the most familiar
forms of radiation.
IONIZING
RADIATION
Potentially harmful or beneficial to
Humans…depending on how it is used.
Short wavelength
= high energy
Long wavelength
= low energy
What is IONIZING RADIATION?
- the kind of radiation which is a result of the radioactive
process
- that which changes the physical state of atoms which it
strikes causing them to be electrically charged or
“ionized”
e-
Neutral atom
e-
e-
Ionized atom
SOURCES OF RADIOACTIVITY
Natural Sources
Artificial (Man-made)
accounts for 15% of the total
radiation burden
97% of man-made
radiation is due
to diagnostic medical exposures
Natural Sources
• Terrestrial
• Floors and
walls of our
homes,
schools or
offices
• Food, water
and air
• Muscles,
bones and
tissues
• Cosmic
radiation or
rays
Background Radiation
• Value of background
radiation is not stable, may
vary widely from place to place
and from time to time,
depending, for instance, on the
structure and wetness of the
soil, the seasons, changes in
weather, wind direction and
the level above sea
• Radiation emitted from
natural radioactive substances
in our environment and from
the cosmos
Artificial Sources
– Dental and other medical
x-rays
– Radiation used to
diagnose diseases and
for cancer therapy
– Industrial uses of nuclear
techniques
– Consumer products such
as luminous wrist
watches, ionization
smoke detectors
– Fallout from nuclear
weapons testing
– Small quantities of
radioactive materials
released to the
environment from coal
and nuclear power plants
What is RADIOACTIVITY ?
RADIOACTIVTY
is the process by
which certain atoms
spontaneously emit
high energy particles
or rays from their
nucleus.
Where does it come from?
How does it happen??
Radiation comes from the
nucleus of the atom.
. . . RADIATION . . . radiation . . .
•Everything in the world is composed of
different types of matter (chemical elements).
•Each element consists of very small parts
called the "Atoms".
ATOM
electron
NUCLEUS
ATOM
Typical diameter: ~ 10-10
m
Typical
diameter:
~ 10-15
m
NUCLEUS
neutron
proton
particle mass charge location
proton 1 amu + in nucleus
neutron 1 amu no
charge
in nucleus
electron 1/1850
amu
- around nucleus in
various energy
levels
Subatomic Particles
1 amu = 1.675 x 10-27
kg
Radioactivity depends on the structure of
the nucleus.
A nucleus should contain “appropriate” # of
neutrons to become stable  non-radioactive
C-12 C-13
C-10 C-11 C-14 C-15
Stable configuration (For Z ≤ 20) :
# of neutrons = or a bit higher than # of protons
An unstable nucleus has too much energy in it.
An atom cannot hold this energy forever.
Unstable nuclei make substances
radioactive.
Sooner or later, the atom must
get rid of the excess energy
. . . and return to its normal (stable) state.
radiation
WHY, again, do
certain ATOMS DECAY?
Atoms with too much energy in
their nuclei are called "radioactive".
Some nuclear arrangements
are less stable than others.
A radioactive isotope decays
to form a more stable nucleus.
… get rid of their
excess energy
(DECAY)
by emitting radiation.
Radioactive isotopes…
They decay by spitting
out:
- mass (alpha particles)
- charge (beta particles)
- energy (gamma rays)
PARENT and DAUGHTER
PARENT NUCLIDE – the original nuclide
which undergoes radioactive decay
DAUGHTER NUCLIDE (or progeny)
- the more stable nuclide which results
from radioactive decay
NUCLIDE - any atomic species characterized by
the number of protons and number of neutrons
notations: A
zXN X-A A
X
where X: symbol of element
Z: atomic number = no. of protons
N: number of neutrons
A: atomic mass = Z + N
Examples:
60
27Co33 Co-60 60
Co
32
P P-32 32
P
ALPHA, 
•A helium nucleus, 4
2He
- Consists of 2 protons and 2 neutrons
•heavy ( Mass : 4 units or 7340 times beta particle )
•Charge : +2
•High energy ( Energy range : 4 to 8 MeV )
•Slow moving ( Speed : 2 X 107
m/s)
•Emitted when the nucleus is too big
•Least penetrating but much damage where it penetrates
- Limited range : < 10 cm in air ; 60 microns in tissue
•Easily Shielded (e.g., paper, skin)
(1) alpha decay - emission of an alpha particle (a He
nucleus), resulting in a decrease in both mass and
atomic number.
Example: Alpha Decay of Americium-241 to Neptunium-237
α
Np
Am 4
2
237
93
241
95 

- decay
•Heavy nuclei more massive than Pb decay by this method
•Atomic Number, Z, decreases by 2
•Atomic Mass Number, A, decreases by 4
•Products are a new element and an  particle
α
Y
X 4
2
4
A
2
Z
A
Z 
 

Beta, 
• A fast moving electron originating from the nucleus
• Emitted when the nucleus has too many neutrons
• Comes from a neutron which has changed into a p+
and an e-
• Very light ( Mass : 0.00055 amu )
• Charge : -1
• Energy dependent on radionuclide
- ( Energy range : several KeV to 5 MeV )
Range : ~ 12' / MeV in air ; few mm in tissue
• Shielding (aluminum and other light (Z<14) materials,
plastics)
(2) Beta decay - emission of a beta particle
(an electron from the nucleus), resulting in
an increase in atomic number.
- DECAY
•A radioactive nucleus that undergoes - decay has a
neutron in its nucleus convert into a p+
and an e-
•Atomic Number, Z, increases by 1
•Atomic Mass Number, A, remains the same
Example: Beta Decay of Hydrogen-3 to Helium-3.


 
He
H 3
2
3
1

 
 
Y
X A
1
Z
A
Z
Gamma, 
•Not a particle but a burst of very high energy as
electromagnetic radiations of very high frequency
•Results from the transition of nuclei from excited state
to their ground state
•No mass, 0 charge
•Have highest energy of all EM radiations
•Very dangerous (can do a lot of biological damage)
•Energies well defined and characteristics of the emitting
radionuclide (up to several MeV)
•Speed : speed of light
• Long range : km in air ; m in body
•Shielding : large amounts of lead or concrete
(3) Gamma decay - This is the photon that
carries the energy that is emitted. The
wavelength is in the order of 10-11
to 10-14
m
(higher energy than x-rays).
 DECAY
•Only energy is released
•Parent and daughter atoms are the same chem'l element
•Atomic Number, Z, remains the same
•Atomic Mass Number, A, remains the same


 X
X A
Z
A
Z
Example: Gamma Decay of Helium-3.


 He
He 3
2
3
2
POSITRON, +
• Similar to e- but opposite charge
• Comes from a proton which has changed
into a neutron and a positron
p+  n + +
• The neutron stays in the nucleus and the
positron ejected at high speed
• Charge : +1
POSITRON DECAY
•Occurs in nuclei which have an excess of protons
•Atomic Number, Z, reduces by 1
•Atomic Mass Number, A, remains the same


 
1
A
1
-
Z
A
Z Y
X
•Example: Positron Decay of Carbon-11 to Boron-11.


 
B
C 11
5
11
6
Comes from a proton which has
changed into a neutron and a
positron
p+  n + +
ELECTRON CAPTURE
•Occurs in atoms of excess protons
•e- in the innermost shell (K-shell) is captured by a p+
in the nucleus to form a neutron
• always accompanied by emission of x-rays
• x-rays emitted are characteristics of the progeny
nuclide
•Atomic Number, Z, reduces by 1
•Atomic Mass Number, A, remains the same
ray
-
x
Y
X A
1
-
Z
A
Z 

Example: Electron Capture of Beryllium-7.
It decays to Lithium-7.
Li
Be 7
3
7
4

(4) positron emission - emission of a positively charged
electron (positron) from the nucleus, resulting in a decrease in
the atomic number. A positron has the same mass as an
electron, but opposite in charge. In other words, inside the
nucleus, a proton is being converted into a neutron.
(5) electron capture - This happens in heavy atoms in which an
inner shell (1s) electron is captured by the nucleus, resulting in a
decrease in atomic number. This process has the same effect as
positron emission.
Summary of Radioactive Decay Modes
Decay Mode Symbol Common
Source
Change
in Z
Change
in N
Change
in A
Alpha  Heavy Nuclei - 2 - 2 - 4
Beta -
Excess
Neutrons
+ 1 - 1 0
Gamma  Excited
Nuclei
0 0 0
Positron +
Excess
Protons
- 1 + 1 0
Electron
Capture
 Excess
Protons
- 1 + 1 0
Decay Chains / Decay Series
A radionuclide may decay to a
nuclide which is also radioactive.
This radionuclide may in turn give
rise to another radionuclide…
… and this will be repeated until
the atom finally reaches a stable
form.
This path to stability is called a
DECAY CHAIN or a DECAY SERIES.
CHART OF NUCLIDES
• a plot of Z vs. N of all known nuclides
• provides several important data
concerning the isotopes
• may be used to determine
how a particular nuclide will decay
• may be used to determine the progeny of a parent nuclide
• decay modes are given in order of abundance
• From the chart it is possible to find nuclides which are stable.
• Stable nuclides form a rough band running diagonally up and to the
right on the chart.
• General Rule : The closer a nuclide is to the line of stability, the
more stable it is.
238 234 230 226 222 218 214 210 206
U-92
Pa-91
Th-90
Ac-89
Ra-88
Fr-87
Rn-86
At-85
Po-84
Bi-83
Pb-82
Tl-81
U
Th Th
Ra
Rn
Po
Pb
Bi
Po
Tl
Pb
Bi
Po
Pb
U
Pa
Atomic Mass Number
Atomic
element
and
number
Uranium-238 Series
Alpha
in
Beta-
out
n
out
Original
nucleus
n
in
Beta+
out
Alpha
out
Atomic
Mass
Number
Atomic element and number
NUCLEAR EQUATIONS
•Nuclear equations show how atoms decay.
•Similar to chemical equations
- must still balance mass and charge
NUCLEAR EQUATIONS
Example:
A patient is injected with radioactive
phosphorus. What happens to the phosphorus?
Is this equation balanced?
You must see if the mass and charge
are the same on both sides.
Charge
+15 (protons) + 16 (protons)
- 1 ()
--------------------------------------
+15 total charge +15 total charge
Yes, it is balanced.
Mass
15 protons 16 protons
17 neutrons 16 neutrons
-------------------------------------
32 total mass 32 total mass
32
15P17  32
16S16 + 
DECAY PARAMETERS:
characteristics of specific radionuclide
•ACTIVITY, A
- number of disintegrations of a nucleus occurring per
second
•DECAY CONSTANT, 
- the fractions of atoms which undergo decay per unit
time
•HALF-LIFE, T1/2
- time taken for half the atoms of a radionuclide to
undergo radioactive decay
RADIOACTIVE DECAY LAW
N = No e - T
where :
No : original number of nuclei
present
T : time which passed
 : radioactive decay constant
N : remaining nuclei after time T
UNITS
ACTIVITY
- described by the number of nuclear
disintegrations per unit time.
1 Becquerel (Bq) = 1 disintegration per second
- named after Henri Becquerel,
discoverer of radioactivity
1 Curie (Ci) = 37 billion disintegrations per second
- named after Marie Curie who discovered and
named radium and polonium
1 Ci = 3.7 x 1010
Bq
Activity: how much is present?
Activity – tells how many unstable nuclei decay in
a second and emit radiation
Activity of an object need not be in any proportion
to its size.
High activity Low activity
Radiography
isotope
Low level
waste
ACTIVITY, A
Proportional to the number of unstable nuclei
A = N
Can be written in the form:
A = Ao e - T
where:
Ao: original activity of radionuclide
T : time which passed
 : radioactive decay constant
A : remaining activity after decay
time
Half-Life
Each radioisotope has its own half-life.
Half-life values can range from
milliseconds to billions of years.
Half-life examples:
•Molybdenum-99 67 hours
• Iodine-131 8 days
• Phosphorus-32 14.3 days
• Iron-59 45 days
• Cobalt-60 5.3 years
• Carbon-14 5760 years
• Uranium-235 710 million years
HALF-LIFE, T1/2 - time taken for half the atoms of a
radionuclide to undergo radioactive decay
To determine relationship between  and T1/2 :
at T=T1/2 , N = No / 2
substituting to N = No e -T
taking ln of both sides:
2
1
T
e
2
1 


2
1
T
693
.
0


2
1
T
o
o
e
N
2
N 


ln (1/2) = ln e(-T1/2)
- 0.693 = - T
CALCULATING ACTIVITY
Activity is also defined as:
Where A : activity at time T
Ao : initial activity
n : number of half-lives which
have elapsed, i.e.
n
o
2
A
A 
2
1
T
T
n 
EXAMPLE OF ACTIVITY CALCULATION
PROBLEM:
P-32 has a half-life of 14.3 days. On Jan. 10, 2006, the
activity of the P-32 sample was 10 mCi. What will the
activity be on February 6, 2006?
n
o
2
A
A 
METHOD 1: USE Eqn. 1
SOLUTIONS:
Given:
T = 27 days : Time interval bet Jan. 10, Feb. 6, 2006
T1/2 = 14.3 days : Half-life of P-32
Ao = 10 Ci : Activity of source on Jan. 10, 2006
Activity of P-32 on Feb. 6, 2006 is 2.698 mCi.
substituting to Eqn. 1 :
n
o
A
A
2

91
.
1
17
.
30
5
.
57
2
1



y
y
T
T
n
27 days
14.3 days
1.89
mCi
mCi
mCi
A 698
.
2
706
.
3
10
2
10
89
.
1



METHOD 2 : USE
T
oe
A
A 

 Eqn. 2
Substituting to Eqn. 2 :
A = 10 e – (0.048 / day) x (27 days)
= 10 e - 1.308
= 10 x 0.27
= 2.7023 Ci
Activity of P-32 on Feb. 6, 2006 is 2.7023 Ci.
Note: Difference is due to rounding adjustments.
1
2
2
1
10
3
.
2
17
.
30
693
.
0
693
.
0 



 y
x
y
T

Where
0.048 / day
14.3 days
EXAMPLE OF ACTIVITY CALCULATION
PROBLEM:
A Cs-137 source had an activity of 800 MBq on
Jan. 1, 1973. What will its activity be on July 1, 2030?
n
o
2
A
A 
METHOD 1: USE Eqn. 1
SOLUTIONS:
Given:
T = 57.5 y : Time interval bet Jan. 1, 1973 and July 1, 2030
T1/2 = 30.17 y : Half-life of Cs-137 (from Table of Nuclide)
Ao = 800 MBq : Activity of source on Jan. 1, 1973
Computation for T
year , mo. , day
Tf = July 1, 2030  2030 , 7 , 1
Ti = Jan 1, 1973  1973 , 1 , 1
----------------------------------
57 yrs , 6 mo. , 0 days
 57 yrs + 6 mo / 12 mo/yr + 0 days
 57 yrs + 0.5 yrs
-------------------------------------
T = Tf - Ti = 57.5 yrs
91
.
1
17
.
30
5
.
57
2
1



y
y
T
T
n
MBq
MBq
MBq
A 213
76
.
3
800
2
800
91
.
1



Activity of Cs-137 on July 1, 2030 is 213 MBq.
subsituting to Eqn. 1 :
n
o
A
A
2

METHOD 2 : USE
T
oe
A
A 

 Eqn. 2
Substituting to Eqn. 2 :
A = 800 e – (0.023 / y) x (57.5 y)
= 800 e - 1.32
= 800 x 0.267
= 214 MBq
Activity of Cs-137 on July 1, 2030 is 214 MBq.
Note: Difference of 1 MBq is due to rounding adjustments.
1
2
2
1
10
3
.
2
17
.
30
693
.
0
693
.
0 



 y
x
y
T

Where
0.023 / y
Sample computation for T
Given: Tf = 3:20 pm
Ti = 10:00 am
---------------------------------
5 hrs + 20 mins
Convert hrs to mins:
(5 hrs) X (60 mins/hr) = 300 mins
Add the 20 mins:
300 mins + 20 mins = 320 mins = T
 3 + 12 = 15 hrs , 20 mins
 = 10 hrs, 0 mins
Seatwork: Sample computation for T
Given:
Tf = Sept. 12, 1997
Ti = Jan. 1, 1966
---------------------------------
T = Tf – Ti  31 yrs + 8mos. + 11 days
Convert 8 mos. to yrs:
(8 mos.) X (1 yr/12 mos.) = 0.6666 yr
Convert 11 days to yrs:
(11 days) X (1 yr / 365 days) = 0.0301 yr
Add all the numbers converted to yrs:
(31 + 0.6666 + 0.0301) yrs = 31.6967 yrs or 31.70 yrs = T
 1997 , 9 , 12
 1966 , 1 , 1
Seatwork:
32
P has a half life of 14.3 days. At 0 day it
has an activity of 1mCi. Compute for the
activity of 32
P after the:
1) 1st
half life :
2) 2nd
half life:
3) 3rd
half life:
4) 4th
half life:
EXAMPLE OF HALF-LIFE CALCULATION
PROBLEM : A sample is counted and found to have
952 counts per minute. Seven minutes
later it is measured again and has a count
of 148 counts per minute. A background
measurement gave 6 counts per minute.
What is the half-life of the sample?
SOLUTIONS :
GIVEN:
Initial Activity : Ao
= 952 - 6 = 946 cpm
Activity 7 minutes after : A = 148 - 6 = 142 cpm
This means that the number of half-lives (n) in 7
minutes is 2.74.
METHOD 1 : Use n
o
A
A
2

66
.
6
142
946
2 


A
Ao
n
n log 2 = log 6.66
74
.
2
3010
.
0
8235
.
0
2
log
66
.
6
log



n
74
.
2
7
2
1 
T
Using
2
1
T
T
n 
n
T
T 
2
1
Therefore, the half-life of the sample is 2.55 mins.
T1/2 = 2.55 minutes
Use
T
o
e
A
A 



T
A
A
ln
o









T
A
A
ln o








T
A
A
ln o








METHOD 2 :
A = Ao e -T
7
142
946
ln 







 
7
66
.
6
ln


7
89
.
1


271
.
0


Then use:
2
1
693
.
0
T



693
.
0
2
1 
 T
271
.
0
693
.
0
2
1 
T
T1/2 = 2.55 minutes
THANK YOU for your attention.

Radioactivity and radyoactive decay Jimenez.ppt

  • 1.
    RADIOACTIVITY and RADIOACTIVE DECAY REYNALDO S.JIMENEZ Nuclear Training Center Philippine Nuclear Research Institute
  • 2.
    What is RADIATION? Has been around since the earth was formed 4500 million years ago. Can be detected, measured and controlled. 87% of radiation dose comes from natural sources, e.g... cosmic, food we eat, our homes 13% result of man’s activities.. - Medical Applications (diagnosis and treatment of disease) - Industrial application (inspection of welds, detection of cracks in or cast metal) - Research application (dating of antiquities, food preservation)
  • 3.
    Radiation – anyform energy that travels and dissipates. Ionizing Radiation – Its interaction with matter may result to creation of charged particles. Non-Ionizing Radiation – its interaction with matter will not result to creation of charged particles.
  • 4.
    Everything in nature, everycreature and every material contains, and always has contained, radioactive substances. You are radioactive yourself, and so is your dog, your coffee, your seatmate, and your mother-in-law. Radiation is all around us.
  • 5.
    Sunshine is oneof the most familiar forms of radiation. IONIZING RADIATION Potentially harmful or beneficial to Humans…depending on how it is used. Short wavelength = high energy Long wavelength = low energy
  • 6.
    What is IONIZINGRADIATION? - the kind of radiation which is a result of the radioactive process - that which changes the physical state of atoms which it strikes causing them to be electrically charged or “ionized” e- Neutral atom e- e- Ionized atom
  • 7.
    SOURCES OF RADIOACTIVITY NaturalSources Artificial (Man-made) accounts for 15% of the total radiation burden 97% of man-made radiation is due to diagnostic medical exposures
  • 8.
    Natural Sources • Terrestrial •Floors and walls of our homes, schools or offices • Food, water and air • Muscles, bones and tissues • Cosmic radiation or rays
  • 9.
    Background Radiation • Valueof background radiation is not stable, may vary widely from place to place and from time to time, depending, for instance, on the structure and wetness of the soil, the seasons, changes in weather, wind direction and the level above sea • Radiation emitted from natural radioactive substances in our environment and from the cosmos
  • 10.
    Artificial Sources – Dentaland other medical x-rays – Radiation used to diagnose diseases and for cancer therapy – Industrial uses of nuclear techniques – Consumer products such as luminous wrist watches, ionization smoke detectors – Fallout from nuclear weapons testing – Small quantities of radioactive materials released to the environment from coal and nuclear power plants
  • 11.
    What is RADIOACTIVITY? RADIOACTIVTY is the process by which certain atoms spontaneously emit high energy particles or rays from their nucleus.
  • 12.
    Where does itcome from? How does it happen?? Radiation comes from the nucleus of the atom. . . . RADIATION . . . radiation . . .
  • 13.
    •Everything in theworld is composed of different types of matter (chemical elements). •Each element consists of very small parts called the "Atoms". ATOM electron NUCLEUS ATOM Typical diameter: ~ 10-10 m Typical diameter: ~ 10-15 m
  • 14.
    NUCLEUS neutron proton particle mass chargelocation proton 1 amu + in nucleus neutron 1 amu no charge in nucleus electron 1/1850 amu - around nucleus in various energy levels Subatomic Particles 1 amu = 1.675 x 10-27 kg
  • 15.
    Radioactivity depends onthe structure of the nucleus. A nucleus should contain “appropriate” # of neutrons to become stable  non-radioactive C-12 C-13 C-10 C-11 C-14 C-15 Stable configuration (For Z ≤ 20) : # of neutrons = or a bit higher than # of protons
  • 16.
    An unstable nucleushas too much energy in it. An atom cannot hold this energy forever. Unstable nuclei make substances radioactive. Sooner or later, the atom must get rid of the excess energy . . . and return to its normal (stable) state. radiation
  • 17.
    WHY, again, do certainATOMS DECAY? Atoms with too much energy in their nuclei are called "radioactive". Some nuclear arrangements are less stable than others. A radioactive isotope decays to form a more stable nucleus.
  • 18.
    … get ridof their excess energy (DECAY) by emitting radiation. Radioactive isotopes… They decay by spitting out: - mass (alpha particles) - charge (beta particles) - energy (gamma rays)
  • 19.
    PARENT and DAUGHTER PARENTNUCLIDE – the original nuclide which undergoes radioactive decay DAUGHTER NUCLIDE (or progeny) - the more stable nuclide which results from radioactive decay
  • 20.
    NUCLIDE - anyatomic species characterized by the number of protons and number of neutrons notations: A zXN X-A A X where X: symbol of element Z: atomic number = no. of protons N: number of neutrons A: atomic mass = Z + N Examples: 60 27Co33 Co-60 60 Co 32 P P-32 32 P
  • 21.
    ALPHA,  •A heliumnucleus, 4 2He - Consists of 2 protons and 2 neutrons •heavy ( Mass : 4 units or 7340 times beta particle ) •Charge : +2 •High energy ( Energy range : 4 to 8 MeV ) •Slow moving ( Speed : 2 X 107 m/s) •Emitted when the nucleus is too big •Least penetrating but much damage where it penetrates - Limited range : < 10 cm in air ; 60 microns in tissue •Easily Shielded (e.g., paper, skin)
  • 22.
    (1) alpha decay- emission of an alpha particle (a He nucleus), resulting in a decrease in both mass and atomic number.
  • 23.
    Example: Alpha Decayof Americium-241 to Neptunium-237 α Np Am 4 2 237 93 241 95   - decay •Heavy nuclei more massive than Pb decay by this method •Atomic Number, Z, decreases by 2 •Atomic Mass Number, A, decreases by 4 •Products are a new element and an  particle α Y X 4 2 4 A 2 Z A Z    
  • 24.
    Beta,  • Afast moving electron originating from the nucleus • Emitted when the nucleus has too many neutrons • Comes from a neutron which has changed into a p+ and an e- • Very light ( Mass : 0.00055 amu ) • Charge : -1 • Energy dependent on radionuclide - ( Energy range : several KeV to 5 MeV ) Range : ~ 12' / MeV in air ; few mm in tissue • Shielding (aluminum and other light (Z<14) materials, plastics)
  • 25.
    (2) Beta decay- emission of a beta particle (an electron from the nucleus), resulting in an increase in atomic number.
  • 26.
    - DECAY •A radioactivenucleus that undergoes - decay has a neutron in its nucleus convert into a p+ and an e- •Atomic Number, Z, increases by 1 •Atomic Mass Number, A, remains the same Example: Beta Decay of Hydrogen-3 to Helium-3.     He H 3 2 3 1      Y X A 1 Z A Z
  • 28.
    Gamma,  •Not aparticle but a burst of very high energy as electromagnetic radiations of very high frequency •Results from the transition of nuclei from excited state to their ground state •No mass, 0 charge •Have highest energy of all EM radiations •Very dangerous (can do a lot of biological damage) •Energies well defined and characteristics of the emitting radionuclide (up to several MeV) •Speed : speed of light • Long range : km in air ; m in body •Shielding : large amounts of lead or concrete
  • 29.
    (3) Gamma decay- This is the photon that carries the energy that is emitted. The wavelength is in the order of 10-11 to 10-14 m (higher energy than x-rays).
  • 30.
     DECAY •Only energyis released •Parent and daughter atoms are the same chem'l element •Atomic Number, Z, remains the same •Atomic Mass Number, A, remains the same    X X A Z A Z Example: Gamma Decay of Helium-3.    He He 3 2 3 2
  • 32.
    POSITRON, + • Similarto e- but opposite charge • Comes from a proton which has changed into a neutron and a positron p+  n + + • The neutron stays in the nucleus and the positron ejected at high speed • Charge : +1
  • 33.
    POSITRON DECAY •Occurs innuclei which have an excess of protons •Atomic Number, Z, reduces by 1 •Atomic Mass Number, A, remains the same     1 A 1 - Z A Z Y X •Example: Positron Decay of Carbon-11 to Boron-11.     B C 11 5 11 6 Comes from a proton which has changed into a neutron and a positron p+  n + +
  • 34.
    ELECTRON CAPTURE •Occurs inatoms of excess protons •e- in the innermost shell (K-shell) is captured by a p+ in the nucleus to form a neutron • always accompanied by emission of x-rays • x-rays emitted are characteristics of the progeny nuclide •Atomic Number, Z, reduces by 1 •Atomic Mass Number, A, remains the same ray - x Y X A 1 - Z A Z   Example: Electron Capture of Beryllium-7. It decays to Lithium-7. Li Be 7 3 7 4 
  • 35.
    (4) positron emission- emission of a positively charged electron (positron) from the nucleus, resulting in a decrease in the atomic number. A positron has the same mass as an electron, but opposite in charge. In other words, inside the nucleus, a proton is being converted into a neutron. (5) electron capture - This happens in heavy atoms in which an inner shell (1s) electron is captured by the nucleus, resulting in a decrease in atomic number. This process has the same effect as positron emission.
  • 36.
    Summary of RadioactiveDecay Modes Decay Mode Symbol Common Source Change in Z Change in N Change in A Alpha  Heavy Nuclei - 2 - 2 - 4 Beta - Excess Neutrons + 1 - 1 0 Gamma  Excited Nuclei 0 0 0 Positron + Excess Protons - 1 + 1 0 Electron Capture  Excess Protons - 1 + 1 0
  • 37.
    Decay Chains /Decay Series A radionuclide may decay to a nuclide which is also radioactive. This radionuclide may in turn give rise to another radionuclide… … and this will be repeated until the atom finally reaches a stable form. This path to stability is called a DECAY CHAIN or a DECAY SERIES.
  • 38.
    CHART OF NUCLIDES •a plot of Z vs. N of all known nuclides • provides several important data concerning the isotopes • may be used to determine how a particular nuclide will decay • may be used to determine the progeny of a parent nuclide • decay modes are given in order of abundance • From the chart it is possible to find nuclides which are stable. • Stable nuclides form a rough band running diagonally up and to the right on the chart. • General Rule : The closer a nuclide is to the line of stability, the more stable it is.
  • 40.
    238 234 230226 222 218 214 210 206 U-92 Pa-91 Th-90 Ac-89 Ra-88 Fr-87 Rn-86 At-85 Po-84 Bi-83 Pb-82 Tl-81 U Th Th Ra Rn Po Pb Bi Po Tl Pb Bi Po Pb U Pa Atomic Mass Number Atomic element and number Uranium-238 Series
  • 41.
  • 42.
    NUCLEAR EQUATIONS •Nuclear equationsshow how atoms decay. •Similar to chemical equations - must still balance mass and charge
  • 43.
    NUCLEAR EQUATIONS Example: A patientis injected with radioactive phosphorus. What happens to the phosphorus? Is this equation balanced? You must see if the mass and charge are the same on both sides. Charge +15 (protons) + 16 (protons) - 1 () -------------------------------------- +15 total charge +15 total charge Yes, it is balanced. Mass 15 protons 16 protons 17 neutrons 16 neutrons ------------------------------------- 32 total mass 32 total mass 32 15P17  32 16S16 + 
  • 44.
    DECAY PARAMETERS: characteristics ofspecific radionuclide •ACTIVITY, A - number of disintegrations of a nucleus occurring per second •DECAY CONSTANT,  - the fractions of atoms which undergo decay per unit time •HALF-LIFE, T1/2 - time taken for half the atoms of a radionuclide to undergo radioactive decay
  • 45.
    RADIOACTIVE DECAY LAW N= No e - T where : No : original number of nuclei present T : time which passed  : radioactive decay constant N : remaining nuclei after time T
  • 46.
    UNITS ACTIVITY - described bythe number of nuclear disintegrations per unit time. 1 Becquerel (Bq) = 1 disintegration per second - named after Henri Becquerel, discoverer of radioactivity 1 Curie (Ci) = 37 billion disintegrations per second - named after Marie Curie who discovered and named radium and polonium 1 Ci = 3.7 x 1010 Bq
  • 47.
    Activity: how muchis present? Activity – tells how many unstable nuclei decay in a second and emit radiation Activity of an object need not be in any proportion to its size. High activity Low activity Radiography isotope Low level waste
  • 48.
    ACTIVITY, A Proportional tothe number of unstable nuclei A = N Can be written in the form: A = Ao e - T where: Ao: original activity of radionuclide T : time which passed  : radioactive decay constant A : remaining activity after decay time
  • 49.
  • 50.
    Each radioisotope hasits own half-life. Half-life values can range from milliseconds to billions of years. Half-life examples: •Molybdenum-99 67 hours • Iodine-131 8 days • Phosphorus-32 14.3 days • Iron-59 45 days • Cobalt-60 5.3 years • Carbon-14 5760 years • Uranium-235 710 million years
  • 51.
    HALF-LIFE, T1/2 -time taken for half the atoms of a radionuclide to undergo radioactive decay To determine relationship between  and T1/2 : at T=T1/2 , N = No / 2 substituting to N = No e -T taking ln of both sides: 2 1 T e 2 1    2 1 T 693 . 0   2 1 T o o e N 2 N    ln (1/2) = ln e(-T1/2) - 0.693 = - T
  • 52.
    CALCULATING ACTIVITY Activity isalso defined as: Where A : activity at time T Ao : initial activity n : number of half-lives which have elapsed, i.e. n o 2 A A  2 1 T T n 
  • 53.
    EXAMPLE OF ACTIVITYCALCULATION PROBLEM: P-32 has a half-life of 14.3 days. On Jan. 10, 2006, the activity of the P-32 sample was 10 mCi. What will the activity be on February 6, 2006? n o 2 A A  METHOD 1: USE Eqn. 1 SOLUTIONS: Given: T = 27 days : Time interval bet Jan. 10, Feb. 6, 2006 T1/2 = 14.3 days : Half-life of P-32 Ao = 10 Ci : Activity of source on Jan. 10, 2006
  • 54.
    Activity of P-32on Feb. 6, 2006 is 2.698 mCi. substituting to Eqn. 1 : n o A A 2  91 . 1 17 . 30 5 . 57 2 1    y y T T n 27 days 14.3 days 1.89 mCi mCi mCi A 698 . 2 706 . 3 10 2 10 89 . 1   
  • 55.
    METHOD 2 :USE T oe A A    Eqn. 2 Substituting to Eqn. 2 : A = 10 e – (0.048 / day) x (27 days) = 10 e - 1.308 = 10 x 0.27 = 2.7023 Ci Activity of P-32 on Feb. 6, 2006 is 2.7023 Ci. Note: Difference is due to rounding adjustments. 1 2 2 1 10 3 . 2 17 . 30 693 . 0 693 . 0      y x y T  Where 0.048 / day 14.3 days
  • 56.
    EXAMPLE OF ACTIVITYCALCULATION PROBLEM: A Cs-137 source had an activity of 800 MBq on Jan. 1, 1973. What will its activity be on July 1, 2030? n o 2 A A  METHOD 1: USE Eqn. 1 SOLUTIONS: Given: T = 57.5 y : Time interval bet Jan. 1, 1973 and July 1, 2030 T1/2 = 30.17 y : Half-life of Cs-137 (from Table of Nuclide) Ao = 800 MBq : Activity of source on Jan. 1, 1973
  • 57.
    Computation for T year, mo. , day Tf = July 1, 2030  2030 , 7 , 1 Ti = Jan 1, 1973  1973 , 1 , 1 ---------------------------------- 57 yrs , 6 mo. , 0 days  57 yrs + 6 mo / 12 mo/yr + 0 days  57 yrs + 0.5 yrs ------------------------------------- T = Tf - Ti = 57.5 yrs
  • 58.
  • 59.
    METHOD 2 :USE T oe A A    Eqn. 2 Substituting to Eqn. 2 : A = 800 e – (0.023 / y) x (57.5 y) = 800 e - 1.32 = 800 x 0.267 = 214 MBq Activity of Cs-137 on July 1, 2030 is 214 MBq. Note: Difference of 1 MBq is due to rounding adjustments. 1 2 2 1 10 3 . 2 17 . 30 693 . 0 693 . 0      y x y T  Where 0.023 / y
  • 60.
    Sample computation forT Given: Tf = 3:20 pm Ti = 10:00 am --------------------------------- 5 hrs + 20 mins Convert hrs to mins: (5 hrs) X (60 mins/hr) = 300 mins Add the 20 mins: 300 mins + 20 mins = 320 mins = T  3 + 12 = 15 hrs , 20 mins  = 10 hrs, 0 mins
  • 61.
    Seatwork: Sample computationfor T Given: Tf = Sept. 12, 1997 Ti = Jan. 1, 1966 --------------------------------- T = Tf – Ti  31 yrs + 8mos. + 11 days Convert 8 mos. to yrs: (8 mos.) X (1 yr/12 mos.) = 0.6666 yr Convert 11 days to yrs: (11 days) X (1 yr / 365 days) = 0.0301 yr Add all the numbers converted to yrs: (31 + 0.6666 + 0.0301) yrs = 31.6967 yrs or 31.70 yrs = T  1997 , 9 , 12  1966 , 1 , 1
  • 62.
    Seatwork: 32 P has ahalf life of 14.3 days. At 0 day it has an activity of 1mCi. Compute for the activity of 32 P after the: 1) 1st half life : 2) 2nd half life: 3) 3rd half life: 4) 4th half life:
  • 63.
    EXAMPLE OF HALF-LIFECALCULATION PROBLEM : A sample is counted and found to have 952 counts per minute. Seven minutes later it is measured again and has a count of 148 counts per minute. A background measurement gave 6 counts per minute. What is the half-life of the sample? SOLUTIONS : GIVEN: Initial Activity : Ao = 952 - 6 = 946 cpm Activity 7 minutes after : A = 148 - 6 = 142 cpm
  • 64.
    This means thatthe number of half-lives (n) in 7 minutes is 2.74. METHOD 1 : Use n o A A 2  66 . 6 142 946 2    A Ao n n log 2 = log 6.66 74 . 2 3010 . 0 8235 . 0 2 log 66 . 6 log    n
  • 65.
    74 . 2 7 2 1  T Using 2 1 T T n  n T T 2 1 Therefore, the half-life of the sample is 2.55 mins. T1/2 = 2.55 minutes
  • 66.
  • 67.
    7 142 946 ln           7 66 . 6 ln   7 89 . 1   271 . 0   Thenuse: 2 1 693 . 0 T    693 . 0 2 1   T 271 . 0 693 . 0 2 1  T T1/2 = 2.55 minutes
  • 68.
    THANK YOU foryour attention.