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International Journal of Trend in Scientific Research and Development (IJTSRD)
Volume 3 Issue 5, August 2019 Available Online: www.ijtsrd.com e-ISSN: 2456 – 6470
@ IJTSRD | Unique Paper ID – IJTSRD27911 | Volume – 3 | Issue – 5 | July - August 2019 Page 1971
Production and Utilization of
Retarder from Hardwood Sawdust
Nay Myo Kyaw Thu1, Swe Swe Khaing2
1,2Civil Department, Technological University, Mawlamyine, Myanmar
How to cite this paper: Nay Myo Kyaw
Thu | Swe Swe Khaing "Production and
Utilization of Retarder from Hardwood
Sawdust" Published
in International
Journal of Trend in
Scientific Research
and Development
(ijtsrd), ISSN: 2456-
6470, Volume-3 |
Issue-5, August
2019, pp.1971-1978,
https://doi.org/10.31142/ijtsrd27911
Copyright © 2019 by author(s) and
International Journal ofTrend inScientific
Research and Development Journal. This
is an Open Access article distributed
under the terms of
the Creative
Commons Attribution
License (CC BY 4.0)
(http://creativecommons.org/licenses/by
/4.0)
ABSTRACT
In this study, production of retarding admixture (ASTM C494 Type-B) from
hardwood sawdust and utilization on concrete by using various dosage of
admixture was studied. In production of retarder as a local product
lignosulphonates based retarding admixture was produced to investigate
differences of test results by using admixtures. In this project, selected raw
material was Pyin-Ka-do sawdust and sodium sulphite(Na2SO3)was used as a
cooking aid chemical liquor by heating at 110°C based on pulp and paper
sulphite process. The mechanisms of action of lignosulphonate admixture in
cement-water systems are prescribed by five different types interaction
between retarder and cement grains : (i) Reductioninsurfacetensionofwater
(ii) Adsorption (iii) Electrical repulsion (iv)Dispersion and (v)Deflocculation.
These reactions cause delaying in setting time.
In utilization of retarder on concrete, setting time of hydraulic cement paste,
compressive strength of mortar and concrete were considered by using
produced admixture dosage of (0.5%, 1%, 1.5%) by weight of cement. The
setting time testing of cement paste was made by using vicat needle
penetration test, and compressive strength was tested with standard cubes.
The test results of produced admixture were compared with ASTM C494
(1993). Compressive strength of mortar was tested with 3 inches cube and
that of concrete was tested by 6 inches standard cube. For comparison of cost
and results of produced admixture, commercial admixture (0.5% byweight of
cement) was tested.
KEYWORDS: compressive strength, setting time, lignosulphonate, retarder,
admixture
I. INTRODUCTION
In Myanmar, chemical admixtures are widely used for
obtaining the desirable results of the job site requirements.
The specific quality of concrete depends on materials, mix
design, production, transporting, placing and curing. During
mixing of concrete, cement reacts with water and occurs
exothermic hydration reaction. The additionofadmixtureto
the concrete affects the hydration process of the cement. In
the fresh stage of mixing, the mix should be workable
enough to be compacted. In the hardened stage, satisfactory
compressive strength is needed. Thus the use of admixture
should not adversely affects to the properties of concrete.
In Myanmar, the organic chemical admixtures are imported
from other countries and they cannot be produced as a local
product. As a result, it causes to loss of foreign currency and
higher cost for applicators. Cement- admixture may occur
incompatible problem byusingwithlocalcement.This is due
to the specific effect of all types of admixtures are mainly
dependent on composition of cement. In this research,
lignosulphate, organic based retarding admixture was
produced and utilized on concrete by using locally available
cement.
II. LITERATURE REVIEW
A. General
An admixture can be defined as any materials other than
water, aggregate and hydraulic cement which is used as an
ingredient of a concrete or mortar mixture and is added to
the batch immediately before or during its mixing.
Admixture may be used to modify the properties ofconcrete
at fresh and hardened stage. The useful classes of admixture
for concrete are organic chemical materials and active
mineral powders such as pozzolan, Admixtures areavailable
as both liquid and powders. Water-soluble powders should
be dissolved in water prior to use so that they can be
dispensed as liquids. Powder admixtures that are not
completely soluble in water should be added to the fine
aggregate. In the application of liquid type admixtures, it is
important to avoid adding them directly to the dry and
absorptive aggregates.
B. Hydration of Cement
Admixture that modifies the properties of fresh concrete
may cause problems through early stiffening or undesirable
prolongation of setting times. The cause of abnormal setting
behaviour should be determined through studies of how
such admixtures affect the hydration of cement.
All main phases of Portland cement [tricalcium aluminate
(C3A), tricalcium silicate (C3S), dicalcium silicate (C2S) and
tetracalcium alumino ferrite (C4AF)] evolve heat when they
react with water [and calcium sulphate (gypsum)] and this
chemical reaction which leads to hardening and
development of strength is called hydration and the heat
generated during this reaction is called heat of hydration.
IJTSRD27911
International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD27911 | Volume – 3 | Issue – 5 | July - August 2019 Page 1972
1. Aluminate Phase
Immediate reaction with water and calcium sulphate
(gypsum) forms a compound called ettringite
[3CaO.Al2O3.3CaSO4.32 H2O]. In the absence of calcium
sulphate, C3A reacts directly with water to form
3CaO.Al2O3.6H2O (C3AH6). This is a very rapid and
exothermic reaction that leads to a quick hardening known
as ‘flash set’. The ettringite coating the underlying C3A then
reacts with it and additional water to form a low sulphate
ettringite. The approximate reaction being
C3A + 6H → C3AH6
[100] [40] [140]
2. Silicate Phase
The product of hydration of C3S is the microcrystalline
hydrate with some lime separating out as crystalline Ca
(OH2) [calcium hydroxide], C2S behaves similarly but clearly
contains less lime. The calcium silicate hydrate, 3CaO.2SiO2.
3H2O is described as C-S-H (tobermorite gel). The
approximate hydration reaction being written as follows:
For C3S; 2C3S+ 6H → C3S2H3 + 3Ca(OH)2
[100] [24] [75] [49]
For C2S; 2C2S + 4H → C3S2H3 + CaOH2
[100] [21] [99] [22]
The numbers in the square brackets are the corresponding
masses.
C. Active Ingredients used in Retarding Admixture
The materials those are generally available for use in
retarding admixtures can be divided into five groups.
1. Lignosulphonic acid and their salts
2. Modification and derivatives of the first group
3. Hydroxylated carboxylic acids and their salts
4. Modification and derivatives of the above group
5. Other material which include (i) inorganic materials (ii)
Amines and their derivatives (iii) Carbohydrates,
polysaccharides and sugar acids (iv)certain polymeric
compounds.
In this research, produced lignosulphate admixture is
organic admixture.
D. Use of Retarder in Concrete
The desirable property of concrete in the fresh stateisthatit
should have adequate fluidity without segregation and
bleeding, place ability, compatibility and finish-ability
appropriate to the conditions ofplacement.Theseproperties
are collectively called (workability).
Retarding water-reducing admixtures are used to improve
the quality of concrete, to obtain specified strength at lower
cement content and to increase the slump of a given mixture
without increasing water content and delay in setting. So,
they may be used to offset the accelerating effect of high
ambient temperature, to eliminate the formation of cold
joints and discontinuities, to transport concrete over large
distances and so on.
E. Mechanisms of Action for Lignosulphonate Based
Retarder in Hydration of Cement
The surface-active properties oflignosulphonates incement-
water system are as follow.
A. Reduction in surface tension of water
B. Adsorption on C3A and C3S phase of cement
C. Electrical Repulsion (large negative zeta-potential)
D. Dispersion
E. Deflocculation
The surface activity of lignosulphonates is due to an
unbalanced charge of electricity carried by these. Due to
their ability to migrate to the water-air boundary,
plasticizing water-reducers reducethesurfacetensionatthe
boundary. Such lowering of surface tension aids better
wetting and hydration reaction.
In cement water dispersion, the tail end of the surfactant
gets adsorbed onto the cement particles.Thesefineparticles
of cement in water would tend to floc together because of
physical and chemical forces of attraction between them
would be dispersed. At the same time, the water trapped
inside such a floc of cement particles gets released.
Due to adsorption of lignosulphonate ions on them, the
cement particle develops similar charges and repels each
other. A film is formed around the cement grains which
prevents or reduces the hydration reactions with water.
F. Behavior of Materials used in Concrete
1. Cement
The various types of cement have the property that when
mixed with water, a chemical reaction (hydration) takes
place and produces a very strong binding medium for the
aggregate particles.
The physical properties of Portland cement are fineness,
setting time, consistency, specific gravity, compressive
strength.
A. Fineness Test
Fineness is expressed in percent retaining on a sieve of
ASTM No.200 or B.S. No. 170 after shaking for a period of 15
minutes. It shall not exceed 10%. In this study, fineness of
Myinegalay cement (Type I) is 8%.
B. Consistency Test
Consistency test is to determine the percentage of water
required for preparing cementpasteofstandardconsistency
is between 26 and 33%. Standard consistency ofMyinegalay
cement is 32%.
C. Setting Time Test
Setting is caused by hydration of cement compounds (C3A
and C3S). ASTM prescribes C191-92 the minimum initial
setting time of 60 minutes and final setting time as a
maximum of 10 hrs for Portland cement. In this test, initial
setting time and final setting time are 1:37 and 2:04
(hr:min).
D. Compressive Strength Test
Two British standard methods for testing compressive
strength of cement are mortar testing and concrete testing.
Compressive strength of Ordinary cement for (1:3) mortar
mix at 3-days and 7-days curing should notbelessthan1200
psi and 2000 psi [reference in ASTM (1975)].
International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD27911 | Volume – 3 | Issue – 5 | July - August 2019 Page 1973
TABLE I. Compressive Strength of Cement
Sample No 3-days (psi) 7-days (psi)
1.
2.
3.
4.
1421
1465
1450
1446
1653
1710
1697
1784
Average 1445 1711
2. Aggregate
Aggregates are generally classified as fine and coarse. Fine
aggregate or sand is any material that passes a No.4 ASTM
sieve and retain on No.200 sieve. Material coarser than this
is classified as coarse aggregate or gravel.
The physical properties of aggregates are specific gravity,
sieve analysis, absorption and moisture content.
Specific gravity is defined as the ratio of mass of a unit
volume of material to the mass of the same volume of water
at the stated temperature.Themajorityofnaturalaggregates
have an apparent specific gravity between 2.6 and 2.7.
The process of dividing a sample of aggregate into fractions
of same particle size is known as sieve analysis.It is madefor
the purpose of fineness modulus and its typical values range
from 2 to 3.5 for fine aggregate and for coarse aggregate
from 5.5 to 8.
The water absorption is determined by measuring the
decrease in mass of saturated and surface dry sample after
oven-drying for 24 hours. The ratio of the decrease in mass
to the mass of dry sample, expressed as percentage, is
termed absorption. Moisture content is defined as the water
in excess of saturated and surface dry condition.
TABLE.II Test Results for Ordinary Portland Cement (Rhinoceros Brand)
Specific Gravity Fineness Standard Consistency
Setting Time (hr:min) Compressive Strength (psi)
I.S F.S 3-days 7-days
3.08 * 32 1:37 2:04 1445 1711
Remark:
I.S = Initial Setting Time
F.S = Final Setting Time
* 92% passing BS sieve No.170
TABLE III. Test Results for Fine and Coarse Aggregates
Sample Name Fineness Modulus Specific Gravity Density (g/cc) Absorption Moisture Content
Yangon River Sand 2.65 2.5 2.5 2.05 5.13
Yangon River Shingle 7.5 2.63 2.63 0.715 Nil
III. Production of Retarding Admixture
A. Reaction of Lignin in Sulphite Process
Lignin is the most abundant constituent of the woody structure of higher plants. It comprises 20 to 40% of the mass of dry
wood. Lignin acts as a cementing medium to bind the matrix of cellulose fibres together in a rigid woody structure. Lignin
content of the plants is as follows: (i) softwoods (27~30%),(ii)hardwoods (16~24%),(iii) bamboo,othergrasses,cottonstalk,
wheat and rice straw (11~20%).
The successive steps in degree of acidity in sulphite cooking liquors,usingsodiumas thebase,have beendesignatedas follows:
A. Acid-bisulphite (NaHSO3 + SO2)
B. Bisulphite (NaHSO3)
C. Bisulphite- sulphite (NaHSO3+ Na2SO3)
D. Sulphite (Na2SO3)
E. Neutral sulphite (Na2SO3 + Na2CO3)
The primary reaction of the sulphite process occurs between the sulphite ions of the cooking liquor and theligninofthewood.
The reaction forms lignin sulphonic acids. The rate of sulphonation reaction is dependent on the temperatureandthesulphite
ion concentration.
In the lignin sulphonation reaction with sulphite cooking liquor,thetimeconsumedin thepenetrationperiodofa sulphitecook,
which may be as long three hours at 110°C has for economic reasons. The chemical reaction of lignin sulphonation reaction
with sulphite cooking liquor can be written as
HSO + lignin-OH → lignin- SO + H2O
B. Production of Sodium Lignosulphonate based Set Retarding Admixture
In this study, wood and chemical reagent are used as raw materials to produce lignosulphonate based on sulphite process.
Hardwood (Pyin-Ka-Do) sawdust and sodium sulphite (Na2SO3) powder which is used as cooking aid chemical are selected as
raw materials.
Quantity of applied materials : sawdust 454 gm
Na2SO3 300gm
Temperature : 110°C
Duration of cooking : 3hours
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For the production of Lignosulphonate, step-by-step procedure is as follows:
1. Cooking liquor is prepared by mixing 300gm of sodium sulphite and 2 liter of ordinary tap water in the steel pot. pH value
of fresh liquor is 10. Then 454gm of sawdust which is removed from undesirable materials is added to the cooking liquor.
And then the pot is marked at the point where the mixture reached.
2. Mixture of sawdust and cooking liquor is heated by hot plate joining with voltage regulator. The duration of cooking is as
long as 3 hours at 110° C .At the early stage of cooking, sulphur dioxide gas is released. It has an undesirable pungent
smell.
3. The boiling water is added to cover the loss of water from the cooking liquor due to evaporation. It is added to reach the
marking point of the pot whenever the water loses. At the end of cooking stage, cooking liquoremits sweet smell andithas
dark brown colour.
4. After that dark brown colour liquid is separated from the solid portion by filtration and squeezing.
5. In this step, liquid lignosulphonate is heated to form dry powder lignosulphonate by evaporation and drying. Dry powder
form of lignosulphonate is important for constant solid concentration of liquid admixture and storage life. In this study,
liquid type admixture is prepared by adding produced dry powder lignosulphonate with water to get the constant solid
concentration of 23 gm of powder per 100 ml of liquid.
C. Quality of Product
Colour : dark brown
Solid Content : 23 gm of powder per 100 ml of liquid
Density : 1.18 kg/li
pH : 10
D. Unit Price of Produced Admixture
Sodium sulphite : 462 ks for 300gm
Sawdust : 10 ks for 454 gm
Temperature : 160 ks for 6.4kwh
Total Cost for an Experiment : 632ks
Yield : 49% powder form (based on sawdust) (approximately)
:820ml liquid type (approximately)
Unit price of produced admixture is 770 kyats per liter.
IV. Effect of Produced Admixture on the Initial Setting Time and Compressive Strength
TABLE.IV Initial Setting Time of Neat Cement Paste with and without Retarding Admixture
Mix
Admixture Dosage %by
Weight of Cement
Number of
Sample
Average Initial
Set (min)
Estimated
Final Set (min)
Control - 10 94 203
Produced Admixture 0.5 10 134 250
Produced Admixture 1 9 162 284
Produced Admixture 1.5 5 194 323
Commercial Admixture 0.5 4 137 254
Remark: Final setting time (min) = 91+1.2 [Initial setting time (min)]
TABLE.V Average Compressive Strength of (1:3) Mortar Specimens
Mix
Admixture
Dosage % by
Weight of Cement
Water-
cement
Ratio
No. of Cube
Specimen
Average Compressive
Strength (psi)
3-days 7-days 28-days
Control - 0.5 12 1445 1711 2137
Produced Admixture 0.5 0.5 12 1457 1769 2130
Produced Admixture 1 0.5 12 1350 2133 2900
Produced Admixture 1.5 0.5 12 1300 1850 2100
Commercial Admixture 0.5 0.5 12 1606 2045 2500
TABLE.VI Mix Proportions and Slump Value of Concrete Mixes
Mix
Admixture
Dosage % by
Weight of Cement
Mix proportion for a cubic meter (kg)
Effective
w/c Ratio
Slump
(in)Cement
Aggregate
Water
Fine Coarse
Control - 308 569 1357 169 0.6 2
Produced Admixture 0.5 308 569 1357 169 0.6 2 ¼
Produced Admixture 1 308 569 1357 169 0.6 2
Produced Admixture 1.5 308 569 1357 169 0.6 2 ½
Commercial Admixture 0.5 308 569 1357 169 0.6 2 ½
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TABLE.VII Test Results for Average Compressive Strength of Concrete Specimens
Mix
Admixture Dosage, %
by weight of cement
Compressive Strength of Standard Cubes
3-days 7-days 28-days
Control
-
1867
1929
1878
2177
2163
2239
2823
2823
2853
Average 1891 2193 2833
Produced Admixture 0.5
2488
2624
2503
2860
2653
2868
3364
3509
3197
Average 2538 2794 3357
Produced Admixture 1.0
2892
2923
2933
3102
3316
3194
3129
3283
3168
Average 2916 3204 3193
Produced Admixture 1.5
1181
1193
1185
1706
1911
1728
3379
3201
3568
Average 1186 1782 3383
Commercial Admixture 0.5
2425
2498
2488
2742
2965
2742
4166
3940
4203
Average 2470 2816 4103
V. Comparison of Results
Fig.1. Comparison of Initial Setting Time of Cement Paste with and without Produced Admixture
Fig.2. Comparison of Initial Setting Time of Cement Paste with Different Types of Admixture
0
50
100
150
200
250
Control Produced
Admixture 0.5%
Produced Admixture 1% Produced Admixture 1.5%
InitialSettingTime(min)
94
0
20
40
60
80
100
120
140
160
Control Produced Admixture 0.5% bwc Commercial Admixture 0.5% bwc
InitialSettingTime(min)
94
137134
134
162
194
International Journal of Trend in Scientific Research and Development (IJTSRD)
@ IJTSRD | Unique Paper ID – IJTSRD27
TABLE.VIII Comparison of Test Results with the Standard Requirement for ASTM C494 Type B and D Admixtures
Mix
Admixture
Dosage
%bwc
Produced Admixture
Produced Admixture
Produced Admixture
TABLE.IX Comparison of Test Results with Standard Requirement for
Mix
Admixture
Produced Admixture
Produced Admixture
Produced Admixture
Fig.3. Comparison of Compressive Strength of Mortar with and without Produced Admixture
Fig.4. Comparison of Compressive
of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com
27911 | Volume – 3 | Issue – 5 | July - August 2019
Comparison of Test Results with the Standard Requirement for ASTM C494 Type B and D Admixtures
Admixture
Dosage
%bwc
Actual Initial Set
Deviation from
Control Mix
ASTM C494 Type (B) and (D)
Initial Setting Time
Deviation from Control
0.5 40 minutes later
At least 1:00 later
not more than 3:30 later
1 1:08 hour later
1.5 1:40 hour later
IX Comparison of Test Results with Standard Requirement for ASTM C494 Type (A) Admixtures
Admixture
Dosage
%bwc
Actual Initial Set
Deviation from
Control Mix
ASTM C494 Type (A)
Setting Time
Deviation from Control
0.5 40 minutes later
Not more than 1:00 earlier
Nor 1:30
1 1:08 hour later
1.5 1:40 hour later
Fig.3. Comparison of Compressive Strength of Mortar with and without Produced Admixture
Fig.4. Comparison of Compressive Strength of Mortar with Different Types of Admixture
2114
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August 2019 Page 1976
Comparison of Test Results with the Standard Requirement for ASTM C494 Type B and D Admixtures
ASTM C494 Type (B) and (D)
Initial Setting Time Allowable
from Control
At least 1:00 later
not more than 3:30 later
ASTM C494 Type (A) Admixtures
ASTM C494 Type (A) Initial
Allowable
Deviation from Control
Not more than 1:00 earlier
Nor 1:30 later
Fig.3. Comparison of Compressive Strength of Mortar with and without Produced Admixture
Strength of Mortar with Different Types of Admixture
28
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TABLE.X Comparison of Relative Compressive Strength of Concretes with the Standard Requirement for ASTM C
494 Type (A and D) Admixture
Mix
Admixture
Dosage %
bwc
Actual Relative Compressive
Strength, (%) of Control
ASTM Type (A and D)
Minimum % of Control
3-days 7-days 28-days 3-days 7-days 28-days
Produced Admixture 0.5 134.2 127.4 118.5
110 110 110
Produced Admixture 1 154.2 146.1 112.7
Produced Admixture 1.5 62.7 81.2 119.4
Commercial Admixture 0.5 130.6 128.4 142.32
Fig.5. Comparison of Compressive Strength of Concrete with and without Produced Admixture for 3-days
Fig.6. Comparison of Compressive Strength of Concrete with Different Types of Admixture for 3-days
Fig.7. Comparison of Compressive Strength of Concrete with and without Produced Admixture for 7-days
0
500
1000
1500
2000
2500
3000
3500
Control Produced Admixture 0.5
%
Produced Admixture 1 % Produced Admixture 1.5
%
CompressiveStrength(psi)
1891
2538
2916
1186
0
500
1000
1500
2000
2500
3000
Control Produced Admixture 0.5 % Commercial Admixture 0.5 %
CompressiveStrength(psi)
1891
2538 2470
0
500
1000
1500
2000
2500
3000
3500
Control Produced Admixture 0.5
%
Produced Admixture 1 % Produced Admixture 1.5
%
CompressiveStrength(psi)
2193
2794
3204
1782
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Fig.8. Comparison of Compressive Strength of Concrete with Different Types of Admixture for 7-days
TABLE.XI Comparison of Cost for Admixtures
Particular Type, according to ASTM C 494 Unit Price
Produced Admixture
Commercial Admixture
Type D
Type B and D
770 kyats per liter
1000 kyats per liter
VI. DISSCUSSIONS AND Conclusions
The efficiency of produced admixture is considerably varied
with the composition of raw materials (wood and cooking
aid chemical). The highest product efficiency and product
yield greatly depend on the rate of reaction of lignin
sulphonation. The degree of lignin sulphonationmaybehigh
by using high acidity of cooking liquor and the wood
containing highest lignin content.
In this study, hardwood sawdust (Pyin-Ka-Do) and sodium
sulphite (Na2SO3) are used in the production of
lignosulphonate. In this case, the variation of physical and
chemical properties of lignosulphonate may be less because
of lower lignin content of wood and low acidity of cooking
aid chemical.
The unit price of produced admixture is 25% less than that
of commercial admixture. For more economical and
commercial use, sulphurous acid and bisulphite should be
used as cooking liquor because of unnecessary of high
temperature, long duration time of cooking and improving
the rate of dissolving lignin components which improve the
quantity of product.
From the discussions in this paper,thefollowingconclusions
can be drawn:
1. The production procedurebyusinghardwood(Pyin-Ka-
Do) sawdust and sodium sulphite (Na2SO3) as a cooking
aid chemical liquor can be successfully used for the
production of lignosulphonate based set-retarding and
water-reducing admixture.
2. Produced admixture can be effectively used as Type A,
water-reducing admixture or Type D, water-reducing
and retarding admixture depend on the amount of
dosage.
3. Produced admixturedosage 0.5%and1% byweight
of cement can be used as Type A and Type D. Produced
admixture dosage 1% gives the highest compressive
strength on concrete according to 3 and 7 days strength.
Produced admixture dosage 1.5% cannot be used as
admixture because it gives very small amount of
compressive strength in spite ofdelayinginsettingtime.
4. In making mortar mixes and testing initial setting time,
produced admixture can be beneficially utilized.
5. In order to produce more economically and
commercially, it should be used pressure digester and
high acidity of cooking aid chemical in the production
product.
6. To obtain uniform lignin content of wood, the same
source of wood is important to be used.
ACKNOWLEDGEMENT
The author is also grateful to Dr. Min Zaw Aung, Principal of
Technological University (Mawlamyine), for his valuable
guidance, correction and advice. Finally, the author deeply
grateful to his parents for their supports, encouragement
and the author would like to expressheartfelt gratitudeto all
of his teachers who taught his everything from childhoodtill
now.
REFERENCES
[1] Neville, A. M. and Brooks, J. J., 1994, “Concrete
Technology”, Printed in Singapore.
[2] Neville, A.M, “Properties of Concrete”, Second (metric)
Edition, 1973.
[3] Shetty, M. S., “Concrete Technology”, new Delhi: Tata
MC Graw Hill. 1995.
[4] Shetty, M. S., “Concrete Technology”, (Theory and
Practice), Second Edition.
[5] Kenneth, W. Brith., “Handbook of Pulp and Paper
Technology”., Second Edition.
[6] Rixom, M.R., “Chemical Admixtures for Concrete”.
[7] Chanda, Satish., “Waste Materials Used in Concrete
Manufacturing”.
[8] Aung Moe Khaing, Mg., 2005, “Production and
Utilization of retarding Admixture by Using Locally
Available Materials”, M.E (Thesis) Department of Civil
Engineering, YTU.
0
500
1000
1500
2000
2500
3000
Control Produced Admixture 0.5 % Commercial Admixture 0.5 %
CompressiveStrength(psi)
2193
2794
2816

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Production and Utilization of Retarder from Hardwood Sawdust

  • 1. International Journal of Trend in Scientific Research and Development (IJTSRD) Volume 3 Issue 5, August 2019 Available Online: www.ijtsrd.com e-ISSN: 2456 – 6470 @ IJTSRD | Unique Paper ID – IJTSRD27911 | Volume – 3 | Issue – 5 | July - August 2019 Page 1971 Production and Utilization of Retarder from Hardwood Sawdust Nay Myo Kyaw Thu1, Swe Swe Khaing2 1,2Civil Department, Technological University, Mawlamyine, Myanmar How to cite this paper: Nay Myo Kyaw Thu | Swe Swe Khaing "Production and Utilization of Retarder from Hardwood Sawdust" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456- 6470, Volume-3 | Issue-5, August 2019, pp.1971-1978, https://doi.org/10.31142/ijtsrd27911 Copyright © 2019 by author(s) and International Journal ofTrend inScientific Research and Development Journal. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0) (http://creativecommons.org/licenses/by /4.0) ABSTRACT In this study, production of retarding admixture (ASTM C494 Type-B) from hardwood sawdust and utilization on concrete by using various dosage of admixture was studied. In production of retarder as a local product lignosulphonates based retarding admixture was produced to investigate differences of test results by using admixtures. In this project, selected raw material was Pyin-Ka-do sawdust and sodium sulphite(Na2SO3)was used as a cooking aid chemical liquor by heating at 110°C based on pulp and paper sulphite process. The mechanisms of action of lignosulphonate admixture in cement-water systems are prescribed by five different types interaction between retarder and cement grains : (i) Reductioninsurfacetensionofwater (ii) Adsorption (iii) Electrical repulsion (iv)Dispersion and (v)Deflocculation. These reactions cause delaying in setting time. In utilization of retarder on concrete, setting time of hydraulic cement paste, compressive strength of mortar and concrete were considered by using produced admixture dosage of (0.5%, 1%, 1.5%) by weight of cement. The setting time testing of cement paste was made by using vicat needle penetration test, and compressive strength was tested with standard cubes. The test results of produced admixture were compared with ASTM C494 (1993). Compressive strength of mortar was tested with 3 inches cube and that of concrete was tested by 6 inches standard cube. For comparison of cost and results of produced admixture, commercial admixture (0.5% byweight of cement) was tested. KEYWORDS: compressive strength, setting time, lignosulphonate, retarder, admixture I. INTRODUCTION In Myanmar, chemical admixtures are widely used for obtaining the desirable results of the job site requirements. The specific quality of concrete depends on materials, mix design, production, transporting, placing and curing. During mixing of concrete, cement reacts with water and occurs exothermic hydration reaction. The additionofadmixtureto the concrete affects the hydration process of the cement. In the fresh stage of mixing, the mix should be workable enough to be compacted. In the hardened stage, satisfactory compressive strength is needed. Thus the use of admixture should not adversely affects to the properties of concrete. In Myanmar, the organic chemical admixtures are imported from other countries and they cannot be produced as a local product. As a result, it causes to loss of foreign currency and higher cost for applicators. Cement- admixture may occur incompatible problem byusingwithlocalcement.This is due to the specific effect of all types of admixtures are mainly dependent on composition of cement. In this research, lignosulphate, organic based retarding admixture was produced and utilized on concrete by using locally available cement. II. LITERATURE REVIEW A. General An admixture can be defined as any materials other than water, aggregate and hydraulic cement which is used as an ingredient of a concrete or mortar mixture and is added to the batch immediately before or during its mixing. Admixture may be used to modify the properties ofconcrete at fresh and hardened stage. The useful classes of admixture for concrete are organic chemical materials and active mineral powders such as pozzolan, Admixtures areavailable as both liquid and powders. Water-soluble powders should be dissolved in water prior to use so that they can be dispensed as liquids. Powder admixtures that are not completely soluble in water should be added to the fine aggregate. In the application of liquid type admixtures, it is important to avoid adding them directly to the dry and absorptive aggregates. B. Hydration of Cement Admixture that modifies the properties of fresh concrete may cause problems through early stiffening or undesirable prolongation of setting times. The cause of abnormal setting behaviour should be determined through studies of how such admixtures affect the hydration of cement. All main phases of Portland cement [tricalcium aluminate (C3A), tricalcium silicate (C3S), dicalcium silicate (C2S) and tetracalcium alumino ferrite (C4AF)] evolve heat when they react with water [and calcium sulphate (gypsum)] and this chemical reaction which leads to hardening and development of strength is called hydration and the heat generated during this reaction is called heat of hydration. IJTSRD27911
  • 2. International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD27911 | Volume – 3 | Issue – 5 | July - August 2019 Page 1972 1. Aluminate Phase Immediate reaction with water and calcium sulphate (gypsum) forms a compound called ettringite [3CaO.Al2O3.3CaSO4.32 H2O]. In the absence of calcium sulphate, C3A reacts directly with water to form 3CaO.Al2O3.6H2O (C3AH6). This is a very rapid and exothermic reaction that leads to a quick hardening known as ‘flash set’. The ettringite coating the underlying C3A then reacts with it and additional water to form a low sulphate ettringite. The approximate reaction being C3A + 6H → C3AH6 [100] [40] [140] 2. Silicate Phase The product of hydration of C3S is the microcrystalline hydrate with some lime separating out as crystalline Ca (OH2) [calcium hydroxide], C2S behaves similarly but clearly contains less lime. The calcium silicate hydrate, 3CaO.2SiO2. 3H2O is described as C-S-H (tobermorite gel). The approximate hydration reaction being written as follows: For C3S; 2C3S+ 6H → C3S2H3 + 3Ca(OH)2 [100] [24] [75] [49] For C2S; 2C2S + 4H → C3S2H3 + CaOH2 [100] [21] [99] [22] The numbers in the square brackets are the corresponding masses. C. Active Ingredients used in Retarding Admixture The materials those are generally available for use in retarding admixtures can be divided into five groups. 1. Lignosulphonic acid and their salts 2. Modification and derivatives of the first group 3. Hydroxylated carboxylic acids and their salts 4. Modification and derivatives of the above group 5. Other material which include (i) inorganic materials (ii) Amines and their derivatives (iii) Carbohydrates, polysaccharides and sugar acids (iv)certain polymeric compounds. In this research, produced lignosulphate admixture is organic admixture. D. Use of Retarder in Concrete The desirable property of concrete in the fresh stateisthatit should have adequate fluidity without segregation and bleeding, place ability, compatibility and finish-ability appropriate to the conditions ofplacement.Theseproperties are collectively called (workability). Retarding water-reducing admixtures are used to improve the quality of concrete, to obtain specified strength at lower cement content and to increase the slump of a given mixture without increasing water content and delay in setting. So, they may be used to offset the accelerating effect of high ambient temperature, to eliminate the formation of cold joints and discontinuities, to transport concrete over large distances and so on. E. Mechanisms of Action for Lignosulphonate Based Retarder in Hydration of Cement The surface-active properties oflignosulphonates incement- water system are as follow. A. Reduction in surface tension of water B. Adsorption on C3A and C3S phase of cement C. Electrical Repulsion (large negative zeta-potential) D. Dispersion E. Deflocculation The surface activity of lignosulphonates is due to an unbalanced charge of electricity carried by these. Due to their ability to migrate to the water-air boundary, plasticizing water-reducers reducethesurfacetensionatthe boundary. Such lowering of surface tension aids better wetting and hydration reaction. In cement water dispersion, the tail end of the surfactant gets adsorbed onto the cement particles.Thesefineparticles of cement in water would tend to floc together because of physical and chemical forces of attraction between them would be dispersed. At the same time, the water trapped inside such a floc of cement particles gets released. Due to adsorption of lignosulphonate ions on them, the cement particle develops similar charges and repels each other. A film is formed around the cement grains which prevents or reduces the hydration reactions with water. F. Behavior of Materials used in Concrete 1. Cement The various types of cement have the property that when mixed with water, a chemical reaction (hydration) takes place and produces a very strong binding medium for the aggregate particles. The physical properties of Portland cement are fineness, setting time, consistency, specific gravity, compressive strength. A. Fineness Test Fineness is expressed in percent retaining on a sieve of ASTM No.200 or B.S. No. 170 after shaking for a period of 15 minutes. It shall not exceed 10%. In this study, fineness of Myinegalay cement (Type I) is 8%. B. Consistency Test Consistency test is to determine the percentage of water required for preparing cementpasteofstandardconsistency is between 26 and 33%. Standard consistency ofMyinegalay cement is 32%. C. Setting Time Test Setting is caused by hydration of cement compounds (C3A and C3S). ASTM prescribes C191-92 the minimum initial setting time of 60 minutes and final setting time as a maximum of 10 hrs for Portland cement. In this test, initial setting time and final setting time are 1:37 and 2:04 (hr:min). D. Compressive Strength Test Two British standard methods for testing compressive strength of cement are mortar testing and concrete testing. Compressive strength of Ordinary cement for (1:3) mortar mix at 3-days and 7-days curing should notbelessthan1200 psi and 2000 psi [reference in ASTM (1975)].
  • 3. International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD27911 | Volume – 3 | Issue – 5 | July - August 2019 Page 1973 TABLE I. Compressive Strength of Cement Sample No 3-days (psi) 7-days (psi) 1. 2. 3. 4. 1421 1465 1450 1446 1653 1710 1697 1784 Average 1445 1711 2. Aggregate Aggregates are generally classified as fine and coarse. Fine aggregate or sand is any material that passes a No.4 ASTM sieve and retain on No.200 sieve. Material coarser than this is classified as coarse aggregate or gravel. The physical properties of aggregates are specific gravity, sieve analysis, absorption and moisture content. Specific gravity is defined as the ratio of mass of a unit volume of material to the mass of the same volume of water at the stated temperature.Themajorityofnaturalaggregates have an apparent specific gravity between 2.6 and 2.7. The process of dividing a sample of aggregate into fractions of same particle size is known as sieve analysis.It is madefor the purpose of fineness modulus and its typical values range from 2 to 3.5 for fine aggregate and for coarse aggregate from 5.5 to 8. The water absorption is determined by measuring the decrease in mass of saturated and surface dry sample after oven-drying for 24 hours. The ratio of the decrease in mass to the mass of dry sample, expressed as percentage, is termed absorption. Moisture content is defined as the water in excess of saturated and surface dry condition. TABLE.II Test Results for Ordinary Portland Cement (Rhinoceros Brand) Specific Gravity Fineness Standard Consistency Setting Time (hr:min) Compressive Strength (psi) I.S F.S 3-days 7-days 3.08 * 32 1:37 2:04 1445 1711 Remark: I.S = Initial Setting Time F.S = Final Setting Time * 92% passing BS sieve No.170 TABLE III. Test Results for Fine and Coarse Aggregates Sample Name Fineness Modulus Specific Gravity Density (g/cc) Absorption Moisture Content Yangon River Sand 2.65 2.5 2.5 2.05 5.13 Yangon River Shingle 7.5 2.63 2.63 0.715 Nil III. Production of Retarding Admixture A. Reaction of Lignin in Sulphite Process Lignin is the most abundant constituent of the woody structure of higher plants. It comprises 20 to 40% of the mass of dry wood. Lignin acts as a cementing medium to bind the matrix of cellulose fibres together in a rigid woody structure. Lignin content of the plants is as follows: (i) softwoods (27~30%),(ii)hardwoods (16~24%),(iii) bamboo,othergrasses,cottonstalk, wheat and rice straw (11~20%). The successive steps in degree of acidity in sulphite cooking liquors,usingsodiumas thebase,have beendesignatedas follows: A. Acid-bisulphite (NaHSO3 + SO2) B. Bisulphite (NaHSO3) C. Bisulphite- sulphite (NaHSO3+ Na2SO3) D. Sulphite (Na2SO3) E. Neutral sulphite (Na2SO3 + Na2CO3) The primary reaction of the sulphite process occurs between the sulphite ions of the cooking liquor and theligninofthewood. The reaction forms lignin sulphonic acids. The rate of sulphonation reaction is dependent on the temperatureandthesulphite ion concentration. In the lignin sulphonation reaction with sulphite cooking liquor,thetimeconsumedin thepenetrationperiodofa sulphitecook, which may be as long three hours at 110°C has for economic reasons. The chemical reaction of lignin sulphonation reaction with sulphite cooking liquor can be written as HSO + lignin-OH → lignin- SO + H2O B. Production of Sodium Lignosulphonate based Set Retarding Admixture In this study, wood and chemical reagent are used as raw materials to produce lignosulphonate based on sulphite process. Hardwood (Pyin-Ka-Do) sawdust and sodium sulphite (Na2SO3) powder which is used as cooking aid chemical are selected as raw materials. Quantity of applied materials : sawdust 454 gm Na2SO3 300gm Temperature : 110°C Duration of cooking : 3hours
  • 4. International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD27911 | Volume – 3 | Issue – 5 | July - August 2019 Page 1974 For the production of Lignosulphonate, step-by-step procedure is as follows: 1. Cooking liquor is prepared by mixing 300gm of sodium sulphite and 2 liter of ordinary tap water in the steel pot. pH value of fresh liquor is 10. Then 454gm of sawdust which is removed from undesirable materials is added to the cooking liquor. And then the pot is marked at the point where the mixture reached. 2. Mixture of sawdust and cooking liquor is heated by hot plate joining with voltage regulator. The duration of cooking is as long as 3 hours at 110° C .At the early stage of cooking, sulphur dioxide gas is released. It has an undesirable pungent smell. 3. The boiling water is added to cover the loss of water from the cooking liquor due to evaporation. It is added to reach the marking point of the pot whenever the water loses. At the end of cooking stage, cooking liquoremits sweet smell andithas dark brown colour. 4. After that dark brown colour liquid is separated from the solid portion by filtration and squeezing. 5. In this step, liquid lignosulphonate is heated to form dry powder lignosulphonate by evaporation and drying. Dry powder form of lignosulphonate is important for constant solid concentration of liquid admixture and storage life. In this study, liquid type admixture is prepared by adding produced dry powder lignosulphonate with water to get the constant solid concentration of 23 gm of powder per 100 ml of liquid. C. Quality of Product Colour : dark brown Solid Content : 23 gm of powder per 100 ml of liquid Density : 1.18 kg/li pH : 10 D. Unit Price of Produced Admixture Sodium sulphite : 462 ks for 300gm Sawdust : 10 ks for 454 gm Temperature : 160 ks for 6.4kwh Total Cost for an Experiment : 632ks Yield : 49% powder form (based on sawdust) (approximately) :820ml liquid type (approximately) Unit price of produced admixture is 770 kyats per liter. IV. Effect of Produced Admixture on the Initial Setting Time and Compressive Strength TABLE.IV Initial Setting Time of Neat Cement Paste with and without Retarding Admixture Mix Admixture Dosage %by Weight of Cement Number of Sample Average Initial Set (min) Estimated Final Set (min) Control - 10 94 203 Produced Admixture 0.5 10 134 250 Produced Admixture 1 9 162 284 Produced Admixture 1.5 5 194 323 Commercial Admixture 0.5 4 137 254 Remark: Final setting time (min) = 91+1.2 [Initial setting time (min)] TABLE.V Average Compressive Strength of (1:3) Mortar Specimens Mix Admixture Dosage % by Weight of Cement Water- cement Ratio No. of Cube Specimen Average Compressive Strength (psi) 3-days 7-days 28-days Control - 0.5 12 1445 1711 2137 Produced Admixture 0.5 0.5 12 1457 1769 2130 Produced Admixture 1 0.5 12 1350 2133 2900 Produced Admixture 1.5 0.5 12 1300 1850 2100 Commercial Admixture 0.5 0.5 12 1606 2045 2500 TABLE.VI Mix Proportions and Slump Value of Concrete Mixes Mix Admixture Dosage % by Weight of Cement Mix proportion for a cubic meter (kg) Effective w/c Ratio Slump (in)Cement Aggregate Water Fine Coarse Control - 308 569 1357 169 0.6 2 Produced Admixture 0.5 308 569 1357 169 0.6 2 ¼ Produced Admixture 1 308 569 1357 169 0.6 2 Produced Admixture 1.5 308 569 1357 169 0.6 2 ½ Commercial Admixture 0.5 308 569 1357 169 0.6 2 ½
  • 5. International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD27911 | Volume – 3 | Issue – 5 | July - August 2019 Page 1975 TABLE.VII Test Results for Average Compressive Strength of Concrete Specimens Mix Admixture Dosage, % by weight of cement Compressive Strength of Standard Cubes 3-days 7-days 28-days Control - 1867 1929 1878 2177 2163 2239 2823 2823 2853 Average 1891 2193 2833 Produced Admixture 0.5 2488 2624 2503 2860 2653 2868 3364 3509 3197 Average 2538 2794 3357 Produced Admixture 1.0 2892 2923 2933 3102 3316 3194 3129 3283 3168 Average 2916 3204 3193 Produced Admixture 1.5 1181 1193 1185 1706 1911 1728 3379 3201 3568 Average 1186 1782 3383 Commercial Admixture 0.5 2425 2498 2488 2742 2965 2742 4166 3940 4203 Average 2470 2816 4103 V. Comparison of Results Fig.1. Comparison of Initial Setting Time of Cement Paste with and without Produced Admixture Fig.2. Comparison of Initial Setting Time of Cement Paste with Different Types of Admixture 0 50 100 150 200 250 Control Produced Admixture 0.5% Produced Admixture 1% Produced Admixture 1.5% InitialSettingTime(min) 94 0 20 40 60 80 100 120 140 160 Control Produced Admixture 0.5% bwc Commercial Admixture 0.5% bwc InitialSettingTime(min) 94 137134 134 162 194
  • 6. International Journal of Trend in Scientific Research and Development (IJTSRD) @ IJTSRD | Unique Paper ID – IJTSRD27 TABLE.VIII Comparison of Test Results with the Standard Requirement for ASTM C494 Type B and D Admixtures Mix Admixture Dosage %bwc Produced Admixture Produced Admixture Produced Admixture TABLE.IX Comparison of Test Results with Standard Requirement for Mix Admixture Produced Admixture Produced Admixture Produced Admixture Fig.3. Comparison of Compressive Strength of Mortar with and without Produced Admixture Fig.4. Comparison of Compressive of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com 27911 | Volume – 3 | Issue – 5 | July - August 2019 Comparison of Test Results with the Standard Requirement for ASTM C494 Type B and D Admixtures Admixture Dosage %bwc Actual Initial Set Deviation from Control Mix ASTM C494 Type (B) and (D) Initial Setting Time Deviation from Control 0.5 40 minutes later At least 1:00 later not more than 3:30 later 1 1:08 hour later 1.5 1:40 hour later IX Comparison of Test Results with Standard Requirement for ASTM C494 Type (A) Admixtures Admixture Dosage %bwc Actual Initial Set Deviation from Control Mix ASTM C494 Type (A) Setting Time Deviation from Control 0.5 40 minutes later Not more than 1:00 earlier Nor 1:30 1 1:08 hour later 1.5 1:40 hour later Fig.3. Comparison of Compressive Strength of Mortar with and without Produced Admixture Fig.4. Comparison of Compressive Strength of Mortar with Different Types of Admixture 2114 www.ijtsrd.com eISSN: 2456-6470 August 2019 Page 1976 Comparison of Test Results with the Standard Requirement for ASTM C494 Type B and D Admixtures ASTM C494 Type (B) and (D) Initial Setting Time Allowable from Control At least 1:00 later not more than 3:30 later ASTM C494 Type (A) Admixtures ASTM C494 Type (A) Initial Allowable Deviation from Control Not more than 1:00 earlier Nor 1:30 later Fig.3. Comparison of Compressive Strength of Mortar with and without Produced Admixture Strength of Mortar with Different Types of Admixture 28
  • 7. International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD27911 | Volume – 3 | Issue – 5 | July - August 2019 Page 1977 TABLE.X Comparison of Relative Compressive Strength of Concretes with the Standard Requirement for ASTM C 494 Type (A and D) Admixture Mix Admixture Dosage % bwc Actual Relative Compressive Strength, (%) of Control ASTM Type (A and D) Minimum % of Control 3-days 7-days 28-days 3-days 7-days 28-days Produced Admixture 0.5 134.2 127.4 118.5 110 110 110 Produced Admixture 1 154.2 146.1 112.7 Produced Admixture 1.5 62.7 81.2 119.4 Commercial Admixture 0.5 130.6 128.4 142.32 Fig.5. Comparison of Compressive Strength of Concrete with and without Produced Admixture for 3-days Fig.6. Comparison of Compressive Strength of Concrete with Different Types of Admixture for 3-days Fig.7. Comparison of Compressive Strength of Concrete with and without Produced Admixture for 7-days 0 500 1000 1500 2000 2500 3000 3500 Control Produced Admixture 0.5 % Produced Admixture 1 % Produced Admixture 1.5 % CompressiveStrength(psi) 1891 2538 2916 1186 0 500 1000 1500 2000 2500 3000 Control Produced Admixture 0.5 % Commercial Admixture 0.5 % CompressiveStrength(psi) 1891 2538 2470 0 500 1000 1500 2000 2500 3000 3500 Control Produced Admixture 0.5 % Produced Admixture 1 % Produced Admixture 1.5 % CompressiveStrength(psi) 2193 2794 3204 1782
  • 8. International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD27911 | Volume – 3 | Issue – 5 | July - August 2019 Page 1978 Fig.8. Comparison of Compressive Strength of Concrete with Different Types of Admixture for 7-days TABLE.XI Comparison of Cost for Admixtures Particular Type, according to ASTM C 494 Unit Price Produced Admixture Commercial Admixture Type D Type B and D 770 kyats per liter 1000 kyats per liter VI. DISSCUSSIONS AND Conclusions The efficiency of produced admixture is considerably varied with the composition of raw materials (wood and cooking aid chemical). The highest product efficiency and product yield greatly depend on the rate of reaction of lignin sulphonation. The degree of lignin sulphonationmaybehigh by using high acidity of cooking liquor and the wood containing highest lignin content. In this study, hardwood sawdust (Pyin-Ka-Do) and sodium sulphite (Na2SO3) are used in the production of lignosulphonate. In this case, the variation of physical and chemical properties of lignosulphonate may be less because of lower lignin content of wood and low acidity of cooking aid chemical. The unit price of produced admixture is 25% less than that of commercial admixture. For more economical and commercial use, sulphurous acid and bisulphite should be used as cooking liquor because of unnecessary of high temperature, long duration time of cooking and improving the rate of dissolving lignin components which improve the quantity of product. From the discussions in this paper,thefollowingconclusions can be drawn: 1. The production procedurebyusinghardwood(Pyin-Ka- Do) sawdust and sodium sulphite (Na2SO3) as a cooking aid chemical liquor can be successfully used for the production of lignosulphonate based set-retarding and water-reducing admixture. 2. Produced admixture can be effectively used as Type A, water-reducing admixture or Type D, water-reducing and retarding admixture depend on the amount of dosage. 3. Produced admixturedosage 0.5%and1% byweight of cement can be used as Type A and Type D. Produced admixture dosage 1% gives the highest compressive strength on concrete according to 3 and 7 days strength. Produced admixture dosage 1.5% cannot be used as admixture because it gives very small amount of compressive strength in spite ofdelayinginsettingtime. 4. In making mortar mixes and testing initial setting time, produced admixture can be beneficially utilized. 5. In order to produce more economically and commercially, it should be used pressure digester and high acidity of cooking aid chemical in the production product. 6. To obtain uniform lignin content of wood, the same source of wood is important to be used. ACKNOWLEDGEMENT The author is also grateful to Dr. Min Zaw Aung, Principal of Technological University (Mawlamyine), for his valuable guidance, correction and advice. Finally, the author deeply grateful to his parents for their supports, encouragement and the author would like to expressheartfelt gratitudeto all of his teachers who taught his everything from childhoodtill now. REFERENCES [1] Neville, A. M. and Brooks, J. J., 1994, “Concrete Technology”, Printed in Singapore. [2] Neville, A.M, “Properties of Concrete”, Second (metric) Edition, 1973. [3] Shetty, M. S., “Concrete Technology”, new Delhi: Tata MC Graw Hill. 1995. [4] Shetty, M. S., “Concrete Technology”, (Theory and Practice), Second Edition. [5] Kenneth, W. Brith., “Handbook of Pulp and Paper Technology”., Second Edition. [6] Rixom, M.R., “Chemical Admixtures for Concrete”. [7] Chanda, Satish., “Waste Materials Used in Concrete Manufacturing”. [8] Aung Moe Khaing, Mg., 2005, “Production and Utilization of retarding Admixture by Using Locally Available Materials”, M.E (Thesis) Department of Civil Engineering, YTU. 0 500 1000 1500 2000 2500 3000 Control Produced Admixture 0.5 % Commercial Admixture 0.5 % CompressiveStrength(psi) 2193 2794 2816