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INSTITUTE OF AGRICULTURAL SCIENCES
SUBJECT: AGR-411 (0+10)
TOPIC- PROBLEM SOILS AND THEIR
MANAGEMENT
Presented to- Ardith Shankar
Presented by-
Ankita Das (16306)
Anna Alokita Hembrom (16309)
Deepanjali Srivastava (16310)
Anup kumar(16311)
CONTENT
• Introduction
• enlist of problematic soil
• Salt affected soil
• Characteristic of salt affected soil
• Comparison between salt affected soil
• Reclamation of Saline soils
• Reclamation of sodic soils
• Reclamation of saline-sodic soils
• Acidic soils
• Reclamation of acidic soil
• Acid Sulphate soils and its management
• Calcareous soil
INTRODUCTION
• Problem soils are the soils whose productivity is
lowered due to inherent unfavorable soil conditions
viz., salt content and soil reaction.
• In India, the extent of salt affected soils increased
enormously to 6.74M ha.
• Soil salinity is one of the major problems restricting
crop production in the arid and semi arid regions of
the world.
TYPES OF PROBLEMATIC SOIL
• Saline soil
• Sodic/alkaline soil
• Saline -sodic
• Acidic soils
• Other problematic soils-
a. acid sulphate soils
b. calcareous soils
SALT AFFECTED SOIL
• Geographical distribution in India- 4 major tract
a. Semi arid indo gangatic alluvial tract
b. Arid tract of Rajasthan and Gujarat
c. Arid and semi arid tract of central and southern states
d. Coastal-alluvial soil
• Area Distribution in India
 Saline soil- 2.96 Mha
1st Gujarat, 2nd Rajasthan
 Sodic soil- 3.78 Mha
1st UP , 2nd Gujarat
Source: agrigyaan site
CHARACTERISTIC
Characteristics of saline soils : Saline soils contain neutral
soluble salts of chlorides and sulfates of sodium, calcium and
magnesium.
• The electrical conductivity of saturated extract of the soil is
more than 4 dS m-1. ESP is less than 15 and pH is less than 8.5.
• Because of the presence of excess salts and low amount of
Na+, these soils are in a flocculated state and their
permeability is higher than alkali soils.
• Their physical condition is good and water can pass through
them. These soils have a white crust of salts on their surface.
• Salinisation refers to the accumulation of neutral soluble salts
in soils.
• Characteristics of alkali or sodic soils: Most of
the Na+ is in exchangeable form.
• EC of saturated extract is less than 4 dS m-1. ESP
is more than 15 and Ph more than 8.5.
• Such soils are not in a good physical condition
and the surface of these soils is sometimes black
due to dispersion of organic matter and humus.
• Such soils if ploughed when wet, turn into slick
furrow slice referred to as slick spots.
• Characteristics of saline - Alkali soils: These soils
have both soluble salts and exchangeable sodium.
The soil reaction becomes strongly alkaline because
of hydrolysis of exchangeable sodium. The physical
condition of the soil is deteriorated.
• The EC of saturated extract is more than 4 dS m-1,
ESP is more than 15 and pH is around 8.5.
• They are transitional soils that they may be
converted into saline or into sodic soils
Comparison of characteristics of salt
affected soils
Characteristic Saline soil Sodic soil or alkali
soil
Saline – sodic soil
Soil pH ~ 8.5 >8.5 <8.5
EC > 4 dS m-1 <4 dS m-1 > 4 dS m-1
ESP <15 >15 >15
Content in soil Excess soluble salts
of calcium,
magnesium and
sodium
Presence of excess
exchangeable
sodium on the
exchange complex
These are transition
soils. They contain
sodium saturation
and excess soluble
salts
Reclamation of Saline soils
Methods of reclamation of saline soils are:
• Cultural practices
• Tolerant and sensitive crops
• Biological reclamation
• Chemical method
• Irrigation water management
Saline soil
I. Cultural practices
• Scraping: Removing the salt that have accumulated on the soil surface by
mechanical means.
• Flushing: Washing away the surface accumulated salts by water over the
surface is sometimes used to desalinize soils having surface salt crust.
• Leaching: Leaching is effective when the salty drainage water is discharged
through subsurface drains that carry the leached salt out of the area
under reclamation.
• Improving irrigation
• Land leveling
• Subsoiling
• Sanding
• Safe disposal of saline water
Leaching requirement may
be defined as the fraction of
irrigation water that must
be leached through root
zone to control soil salinity
at any specific level.
II. Tolerant and sensitive crop
• Most of the major cereal crops exhibit high tolerance to soil salinity, it
include crops like sorghum, wheat , triticale, oats, barley etc.
• Vegetable crops tend to fall into more sensitive than to tolerant
categories, only notable exception are asparagus and red beet under
marginal condition of salinity.
• Most fruit trees are relatively sensitive to salinity. Stone fruit, citrus and
avocado have all shown specific sensitivity to foliar accumulation of Cl-
and Na+.
• Chrysanthemum, carnation are considered moderately tolerant to salt
stress. Aster, poinsettia, gladiolus are considered sensitive.
III. Biological Reclamation
The decomposition of cattle manures and plant residues, in the soil
liberates carbon dioxide and organic acids which help to dissolve any
insoluble calcium salts in the soil solution and also neutralize the alkali
present. Decomposing organic matter improves soil permeability and
increases stable aggregates.
The organic amendments or improvement of saline soil are:
• Green manuring and crop residues: decomposition acting as solubilizing
agent for Ca and neutralizing high pH of alkali soils. Sesbania aculeata has
been found most successful on saline soils.
• Afforestation: The forest growth exerts ameliorative effect on the soil by
loosening the subsoil and improving permeability through the action of
the root system.
• Bulky organic manures
IV.Chemical method
Amendments:
• Gypsum: When gypsum is applied to ameliorate salt affected soils,
the following reaction will take place and loss of exchangeable
sodium occurs and calcium will take place of sodium on the exchange
complex. Gypsum reacts with both Na2CO3 and the sodium adsorbed
sodium as follows:
Na2CO3 + CaSO4↔ CaCO3 +Na2CSO4↓
[Clay]Na + CaSO4↔ Ca[Clay + Na2SO4↓
• Sulphur:
2S +3O2 = 2SO3
SO3 + H2O = H2SO4
H2SO4 + Na2CO3↔ CO2 + H2O + Na2SO4↓
V. Irrigation water management
• irrigation frequency: Infrequent irrigation aggravates salinity
effects on growth, more frequent irrigations minimize the
adverse effects of salt in the soil.
• Irrigation method can play an important role in controlling salts
in the root zone. Sprinkler irrigation is an ideal method for
irrigation frequently and with small quantities of water at a
time. Leaching of soluble salts is also accomplished more
efficiently when the water application rates are lower than the
infiltration capacity of the soil and such a condition cannot be
achieved by flood irrigation method.
RECLAMATION OF SODIC SOIL :
Basically, reclamation or improvement of sodic soils
requires the removal of part or most of the
exchangeable sodium with more favourable calcium
ions in the root zone.
1) CHEMICAL METHOD :
Chemical amendments for sodic soil reclamation can be
broadly grouped into three categories :
• Water soluble calcium salts, e.g. Gypsum, Calcium
chloride.
• Acid or acid forming substances, e.g. Pyrites,
Sulphuric acid, iron sulphate, aluminium sulphate,
lime- sulphur , sulphur etc.
• Calcium salts of low solubility, e.g. ground limestone,
by product lime of sugar factory.
GYPSUM :
Gypsum is chemically 𝐶𝑎𝑆𝑂4. 2𝐻2 𝑂and is a white mineral that
occurs extensively in natural deposits. It must be ground before it
is applied to the soil. Gypsum is soluble in water to the extent of
about one-fourth of 1 percent and is, therefore, a direct source of
soluble calcium. Gypsum reacts with both the Na2CO3, and the
adsorbed sodium as follows:
Na2CO3 + CaSO4 ↔ CaSO3 + Na2SO4 (leachable).
CALCIUM CHLORIDE :
Calcium chloride is chemically CaCl2.2𝐻2 𝑂It is a highly soluble
salt which supplies soluble calcium directly. Its reactions in sodic
soil are similar to those of gypsum:
Na2CO3 + CaCl2 ↔CaCO3 + 2NaCl (leachable).
Sodic
soil
2) CULTURAL METHOD :
Following methods are used for
cultural reclamation :
• Deep ploughing
• Subsoiling
• Sanding and profile inversion
• Land levelling
• Improving planting techniques
• Scraping
• Flushing
• Leaching
• Improving irrigation/ drainage
3) BIOLOGICAL METHOD :
• Bulky organic manure, green manure, crop
residues application and other biological materials
which produce weak organic acids that helps in
creating temporarily acidic condition and help in
reclamation .
• Crop rotation is good for sodicity problem. E.g. Rice-
Dhaincha, Dhaincha- Rice -Berseem.
• Frequent irrigation with small quantities of water is
successful irrigation management practices.
• Tree plantation is very useful .
4) TOLERANT AND SENSITIVE CROPS :
• Choice of crops :Growing crops tolerant to excess
exchangeable sodium can ensure reasonable returns during
the initial phases of reclamation.
• Rice and Dhaincha appear to be tolerant to sodic conditions ,
wheat and bajra are only moderately tolerant and legume
crops like mash and lentil are relatively sensitive to excess
exchangeable sodium.
• Crops like wheat, cotton, barley, tomatoes, etc. were rated as
tolerant.
• Crops that are able to withstand excess moisture conditions
resulting in short-term oxygen deficiencies are also more
tolerant of sodic conditions.
5) IRRIGATION WATER MANAGEMENT :
• Leaching with water of good quality
• Continued use of quality irrigation water, good irrigation
methods, and cropping practices further displaces adsorbed
sodium.
• In some cases, it may be necessary to restore the soil to
greater depths to obtain adequate drainage and root
penetration.
Reclaiming saline-sodic soil
• this type of soil can be reclaimed by replacing
the exchangeable Na with Calcium.
• This is commonly accomplished by adding
gypsum, since it is relatively soluble and
inexpensive.
• However if the soil is naturally high in Calcium
carbonate(lime), then elemental S or sulphuric
acid can be applied.
• Saline sodic soil should be leached with a good
quality (low-sodium)water treatment with
calcium bearing amendment or sulfur.
Acidic soils
•The soil having pH less than 7 is called acidic soil.
• They contains excessive amounts of dissolved
ions of Al,Fe, Mn and Cu.
• Acid soils are deficient in Ca and Mg .
• Acid sulphate soils are rich in pyrite which on
oxidation form sulphuric acid .These soils have pH <3.5.
• Crops on these soils suffer mainly due to Al toxicity and
nutrient deficiency
Distribution of acid soils in India
• Total area – 92 million ha.
• Among states M.P. is 1st and
Maharashtra is 2nd
• Acid soils comprise about
28% of total geographical
area
• 9.3% area has pH < 5.5 ,
18.9% area has pH range
5.5-6.5
Formation of Acid soils
1) Parent materials (Granite- acidic)
2) Acid rain (High pollution area, US-CANADA)
3) Acid forming fertilizers – (NH4)2SO4
4) High rainfall area ( basic salts leach down –
remain Al3+)
5) Highly weathered soil ( Laterite soil- it has Fe
and Al)
Kinds of soil acidity
1) Active acidity / Solution acidity- It is due to
dissolved H+ and Al3+ ions in solution . It
measured by pH.
2) Exchangeable acidity - It is due to adsorbed Al3+,
H+ at clay surface , replaced by neutral salts.
3) Reserve acidity / residual acidity – Acidity
remaining after liming .
Total acidity= (active acidity + exchangeable
acidity + reserve acidity)
RECLAMATION OF ACID SOILS
A) Liming
• Application of lime is recommended for
reclaming acid soils.
• Burnt lime -CaO, Hydrated lime- Ca(OH)2, Basic
slag –CaSiO3, Dolomite- CaCO3.MgCO3, Calcite.
• It improves the base saturation,inactivates iron
,manganese and aluminium in soil solution
• Lime should be applied once in five years
depending on soil pH.
• B) Choice of crops
• Rice is relatively tolerant to soil acidity,since flooding
the field raise soil pH to near neutrality.
• Millets and oats among cereals, groundnut among the
legumes, tea and potato among others can be grown
on acid soils.
C) Soil fertility management
• Leaching losses of nitrogen fertilisers can be reduced
by split by split applications.
• Use of completely water soluble sources like SSP
,TSP,DAP should be avoided.
• Potassium sulphate is preferred over murate of potash
Problems associated with over liming
1) Deficiency of Fe, Cu,Mn,Zn
2) Phosphorus availability reduce
3) Incidence of diseases like Scab in root crops
increases.
4) Boron deficiency is seen , it adsorbed on
Al(OH)3
5) Root tip swelling due to high cons. of OH-
ion
Other problematic soils-
Acid Sulphate soils ( Kari soils)
Area-
• Kottayam & Alleppey of kerala,Coastal Odisha,
Sundarbans of West Bengal
Characteristics-
• Acid sulphate soils are rich in pyrites(FeS2 ) which on
oxidation form sulphuric acid These soils have pH <3.5.
• Occur in humid region where frequent tides comes
• Sulphide(FeS2)→ oxidation → Sulphates(H2SO4)
Management of Acid sulphate soils-
1) Crops- Paddy ( Pokkali variety)
2) Keeping the area flooded , so frequent
oxidation- reduction avoided.
3) Liming & leaching
4) Controlling water table
5) Allowing soil to dry for a long time the
leaching with water , so that sulphide
minerals are oxidized to sulfates and washed
off.
Calcareous Soils
• Found in arid or semi arid area , when high
amount of CaCO3 dominates .
• Characterised by the presence of CaCO3 in the
parent material and by a Calcic horizon
• pH- 7-8.5
• CaCO3 precipitates at pH-8.5
• Calcareous soils to be low in O.M. and available
N.
• Deficient in P and Mo.
Degraded alkali soils
Charecteristics-
1) Formed in highly irrigated /areas with
extensive leaching.
2) Top soil – Acidic, Sub-surface soil- Sodic(
black in colour)
Formation-
Clay]Na+ + H2O = Clay]H+ + NaOH (acidic)
NaOH + CO2 =Na2CO3 + H2O (basic)
PROBLEM SOILS AND THEIR MANAGEMENT

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PROBLEM SOILS AND THEIR MANAGEMENT

  • 1. INSTITUTE OF AGRICULTURAL SCIENCES SUBJECT: AGR-411 (0+10) TOPIC- PROBLEM SOILS AND THEIR MANAGEMENT Presented to- Ardith Shankar Presented by- Ankita Das (16306) Anna Alokita Hembrom (16309) Deepanjali Srivastava (16310) Anup kumar(16311)
  • 2. CONTENT • Introduction • enlist of problematic soil • Salt affected soil • Characteristic of salt affected soil • Comparison between salt affected soil • Reclamation of Saline soils • Reclamation of sodic soils • Reclamation of saline-sodic soils • Acidic soils • Reclamation of acidic soil • Acid Sulphate soils and its management • Calcareous soil
  • 3. INTRODUCTION • Problem soils are the soils whose productivity is lowered due to inherent unfavorable soil conditions viz., salt content and soil reaction. • In India, the extent of salt affected soils increased enormously to 6.74M ha. • Soil salinity is one of the major problems restricting crop production in the arid and semi arid regions of the world.
  • 4. TYPES OF PROBLEMATIC SOIL • Saline soil • Sodic/alkaline soil • Saline -sodic • Acidic soils • Other problematic soils- a. acid sulphate soils b. calcareous soils
  • 5. SALT AFFECTED SOIL • Geographical distribution in India- 4 major tract a. Semi arid indo gangatic alluvial tract b. Arid tract of Rajasthan and Gujarat c. Arid and semi arid tract of central and southern states d. Coastal-alluvial soil • Area Distribution in India  Saline soil- 2.96 Mha 1st Gujarat, 2nd Rajasthan  Sodic soil- 3.78 Mha 1st UP , 2nd Gujarat Source: agrigyaan site
  • 6. CHARACTERISTIC Characteristics of saline soils : Saline soils contain neutral soluble salts of chlorides and sulfates of sodium, calcium and magnesium. • The electrical conductivity of saturated extract of the soil is more than 4 dS m-1. ESP is less than 15 and pH is less than 8.5. • Because of the presence of excess salts and low amount of Na+, these soils are in a flocculated state and their permeability is higher than alkali soils. • Their physical condition is good and water can pass through them. These soils have a white crust of salts on their surface. • Salinisation refers to the accumulation of neutral soluble salts in soils.
  • 7. • Characteristics of alkali or sodic soils: Most of the Na+ is in exchangeable form. • EC of saturated extract is less than 4 dS m-1. ESP is more than 15 and Ph more than 8.5. • Such soils are not in a good physical condition and the surface of these soils is sometimes black due to dispersion of organic matter and humus. • Such soils if ploughed when wet, turn into slick furrow slice referred to as slick spots.
  • 8. • Characteristics of saline - Alkali soils: These soils have both soluble salts and exchangeable sodium. The soil reaction becomes strongly alkaline because of hydrolysis of exchangeable sodium. The physical condition of the soil is deteriorated. • The EC of saturated extract is more than 4 dS m-1, ESP is more than 15 and pH is around 8.5. • They are transitional soils that they may be converted into saline or into sodic soils
  • 9. Comparison of characteristics of salt affected soils Characteristic Saline soil Sodic soil or alkali soil Saline – sodic soil Soil pH ~ 8.5 >8.5 <8.5 EC > 4 dS m-1 <4 dS m-1 > 4 dS m-1 ESP <15 >15 >15 Content in soil Excess soluble salts of calcium, magnesium and sodium Presence of excess exchangeable sodium on the exchange complex These are transition soils. They contain sodium saturation and excess soluble salts
  • 10. Reclamation of Saline soils Methods of reclamation of saline soils are: • Cultural practices • Tolerant and sensitive crops • Biological reclamation • Chemical method • Irrigation water management
  • 12. I. Cultural practices • Scraping: Removing the salt that have accumulated on the soil surface by mechanical means. • Flushing: Washing away the surface accumulated salts by water over the surface is sometimes used to desalinize soils having surface salt crust. • Leaching: Leaching is effective when the salty drainage water is discharged through subsurface drains that carry the leached salt out of the area under reclamation. • Improving irrigation • Land leveling • Subsoiling • Sanding • Safe disposal of saline water Leaching requirement may be defined as the fraction of irrigation water that must be leached through root zone to control soil salinity at any specific level.
  • 13. II. Tolerant and sensitive crop • Most of the major cereal crops exhibit high tolerance to soil salinity, it include crops like sorghum, wheat , triticale, oats, barley etc. • Vegetable crops tend to fall into more sensitive than to tolerant categories, only notable exception are asparagus and red beet under marginal condition of salinity. • Most fruit trees are relatively sensitive to salinity. Stone fruit, citrus and avocado have all shown specific sensitivity to foliar accumulation of Cl- and Na+. • Chrysanthemum, carnation are considered moderately tolerant to salt stress. Aster, poinsettia, gladiolus are considered sensitive.
  • 14. III. Biological Reclamation The decomposition of cattle manures and plant residues, in the soil liberates carbon dioxide and organic acids which help to dissolve any insoluble calcium salts in the soil solution and also neutralize the alkali present. Decomposing organic matter improves soil permeability and increases stable aggregates. The organic amendments or improvement of saline soil are: • Green manuring and crop residues: decomposition acting as solubilizing agent for Ca and neutralizing high pH of alkali soils. Sesbania aculeata has been found most successful on saline soils. • Afforestation: The forest growth exerts ameliorative effect on the soil by loosening the subsoil and improving permeability through the action of the root system. • Bulky organic manures
  • 15. IV.Chemical method Amendments: • Gypsum: When gypsum is applied to ameliorate salt affected soils, the following reaction will take place and loss of exchangeable sodium occurs and calcium will take place of sodium on the exchange complex. Gypsum reacts with both Na2CO3 and the sodium adsorbed sodium as follows: Na2CO3 + CaSO4↔ CaCO3 +Na2CSO4↓ [Clay]Na + CaSO4↔ Ca[Clay + Na2SO4↓ • Sulphur: 2S +3O2 = 2SO3 SO3 + H2O = H2SO4 H2SO4 + Na2CO3↔ CO2 + H2O + Na2SO4↓
  • 16. V. Irrigation water management • irrigation frequency: Infrequent irrigation aggravates salinity effects on growth, more frequent irrigations minimize the adverse effects of salt in the soil. • Irrigation method can play an important role in controlling salts in the root zone. Sprinkler irrigation is an ideal method for irrigation frequently and with small quantities of water at a time. Leaching of soluble salts is also accomplished more efficiently when the water application rates are lower than the infiltration capacity of the soil and such a condition cannot be achieved by flood irrigation method.
  • 17. RECLAMATION OF SODIC SOIL : Basically, reclamation or improvement of sodic soils requires the removal of part or most of the exchangeable sodium with more favourable calcium ions in the root zone. 1) CHEMICAL METHOD : Chemical amendments for sodic soil reclamation can be broadly grouped into three categories : • Water soluble calcium salts, e.g. Gypsum, Calcium chloride. • Acid or acid forming substances, e.g. Pyrites, Sulphuric acid, iron sulphate, aluminium sulphate, lime- sulphur , sulphur etc. • Calcium salts of low solubility, e.g. ground limestone, by product lime of sugar factory.
  • 18. GYPSUM : Gypsum is chemically 𝐶𝑎𝑆𝑂4. 2𝐻2 𝑂and is a white mineral that occurs extensively in natural deposits. It must be ground before it is applied to the soil. Gypsum is soluble in water to the extent of about one-fourth of 1 percent and is, therefore, a direct source of soluble calcium. Gypsum reacts with both the Na2CO3, and the adsorbed sodium as follows: Na2CO3 + CaSO4 ↔ CaSO3 + Na2SO4 (leachable). CALCIUM CHLORIDE : Calcium chloride is chemically CaCl2.2𝐻2 𝑂It is a highly soluble salt which supplies soluble calcium directly. Its reactions in sodic soil are similar to those of gypsum: Na2CO3 + CaCl2 ↔CaCO3 + 2NaCl (leachable).
  • 20. 2) CULTURAL METHOD : Following methods are used for cultural reclamation : • Deep ploughing • Subsoiling • Sanding and profile inversion • Land levelling • Improving planting techniques • Scraping • Flushing • Leaching • Improving irrigation/ drainage
  • 21. 3) BIOLOGICAL METHOD : • Bulky organic manure, green manure, crop residues application and other biological materials which produce weak organic acids that helps in creating temporarily acidic condition and help in reclamation . • Crop rotation is good for sodicity problem. E.g. Rice- Dhaincha, Dhaincha- Rice -Berseem. • Frequent irrigation with small quantities of water is successful irrigation management practices. • Tree plantation is very useful .
  • 22. 4) TOLERANT AND SENSITIVE CROPS : • Choice of crops :Growing crops tolerant to excess exchangeable sodium can ensure reasonable returns during the initial phases of reclamation. • Rice and Dhaincha appear to be tolerant to sodic conditions , wheat and bajra are only moderately tolerant and legume crops like mash and lentil are relatively sensitive to excess exchangeable sodium. • Crops like wheat, cotton, barley, tomatoes, etc. were rated as tolerant. • Crops that are able to withstand excess moisture conditions resulting in short-term oxygen deficiencies are also more tolerant of sodic conditions.
  • 23. 5) IRRIGATION WATER MANAGEMENT : • Leaching with water of good quality • Continued use of quality irrigation water, good irrigation methods, and cropping practices further displaces adsorbed sodium. • In some cases, it may be necessary to restore the soil to greater depths to obtain adequate drainage and root penetration.
  • 24. Reclaiming saline-sodic soil • this type of soil can be reclaimed by replacing the exchangeable Na with Calcium. • This is commonly accomplished by adding gypsum, since it is relatively soluble and inexpensive. • However if the soil is naturally high in Calcium carbonate(lime), then elemental S or sulphuric acid can be applied. • Saline sodic soil should be leached with a good quality (low-sodium)water treatment with calcium bearing amendment or sulfur.
  • 25. Acidic soils •The soil having pH less than 7 is called acidic soil. • They contains excessive amounts of dissolved ions of Al,Fe, Mn and Cu. • Acid soils are deficient in Ca and Mg . • Acid sulphate soils are rich in pyrite which on oxidation form sulphuric acid .These soils have pH <3.5. • Crops on these soils suffer mainly due to Al toxicity and nutrient deficiency
  • 26. Distribution of acid soils in India • Total area – 92 million ha. • Among states M.P. is 1st and Maharashtra is 2nd • Acid soils comprise about 28% of total geographical area • 9.3% area has pH < 5.5 , 18.9% area has pH range 5.5-6.5
  • 27. Formation of Acid soils 1) Parent materials (Granite- acidic) 2) Acid rain (High pollution area, US-CANADA) 3) Acid forming fertilizers – (NH4)2SO4 4) High rainfall area ( basic salts leach down – remain Al3+) 5) Highly weathered soil ( Laterite soil- it has Fe and Al)
  • 28. Kinds of soil acidity 1) Active acidity / Solution acidity- It is due to dissolved H+ and Al3+ ions in solution . It measured by pH. 2) Exchangeable acidity - It is due to adsorbed Al3+, H+ at clay surface , replaced by neutral salts. 3) Reserve acidity / residual acidity – Acidity remaining after liming . Total acidity= (active acidity + exchangeable acidity + reserve acidity)
  • 29. RECLAMATION OF ACID SOILS A) Liming • Application of lime is recommended for reclaming acid soils. • Burnt lime -CaO, Hydrated lime- Ca(OH)2, Basic slag –CaSiO3, Dolomite- CaCO3.MgCO3, Calcite. • It improves the base saturation,inactivates iron ,manganese and aluminium in soil solution • Lime should be applied once in five years depending on soil pH.
  • 30. • B) Choice of crops • Rice is relatively tolerant to soil acidity,since flooding the field raise soil pH to near neutrality. • Millets and oats among cereals, groundnut among the legumes, tea and potato among others can be grown on acid soils. C) Soil fertility management • Leaching losses of nitrogen fertilisers can be reduced by split by split applications. • Use of completely water soluble sources like SSP ,TSP,DAP should be avoided. • Potassium sulphate is preferred over murate of potash
  • 31. Problems associated with over liming 1) Deficiency of Fe, Cu,Mn,Zn 2) Phosphorus availability reduce 3) Incidence of diseases like Scab in root crops increases. 4) Boron deficiency is seen , it adsorbed on Al(OH)3 5) Root tip swelling due to high cons. of OH- ion
  • 32. Other problematic soils- Acid Sulphate soils ( Kari soils) Area- • Kottayam & Alleppey of kerala,Coastal Odisha, Sundarbans of West Bengal Characteristics- • Acid sulphate soils are rich in pyrites(FeS2 ) which on oxidation form sulphuric acid These soils have pH <3.5. • Occur in humid region where frequent tides comes • Sulphide(FeS2)→ oxidation → Sulphates(H2SO4)
  • 33. Management of Acid sulphate soils- 1) Crops- Paddy ( Pokkali variety) 2) Keeping the area flooded , so frequent oxidation- reduction avoided. 3) Liming & leaching 4) Controlling water table 5) Allowing soil to dry for a long time the leaching with water , so that sulphide minerals are oxidized to sulfates and washed off.
  • 34. Calcareous Soils • Found in arid or semi arid area , when high amount of CaCO3 dominates . • Characterised by the presence of CaCO3 in the parent material and by a Calcic horizon • pH- 7-8.5 • CaCO3 precipitates at pH-8.5 • Calcareous soils to be low in O.M. and available N. • Deficient in P and Mo.
  • 35. Degraded alkali soils Charecteristics- 1) Formed in highly irrigated /areas with extensive leaching. 2) Top soil – Acidic, Sub-surface soil- Sodic( black in colour) Formation- Clay]Na+ + H2O = Clay]H+ + NaOH (acidic) NaOH + CO2 =Na2CO3 + H2O (basic)