Complex carbohydrates are polysaccharides made of long chains of monosaccharides that take longer to digest. Humans need to get most of their energy from complex carbs like glycogen, fiber, and starch. Simple carbs are sugars made of single or double monosaccharides and include natural sugars from fruits as well as refined sugars. Carbs are digested through enzymes in saliva and the small intestine that break them down into monosaccharides, which are then absorbed and used for energy or storage.