‧ Can TEM waves be affected by the presence of electric charges?
‧ We’ve seen role of passive charges → dipoles → dielectrics
‧ Can EM waves/ lights be manipulated meaningfully by
active charges instead?
‧ Exact solution in the presence of still and moving charges
→ useful?
‧ E. T. Whittaker’s two potential general solution → useful?
‧ Feynman’s versatile formula → intuitive and useful?
‧ Scope reduction to steady-state → effect of interfacial & surface active charges
‧ Experiments & results
• Background and motivation – the success of pheophytin (pheo, 脫鎂葉綠素) catalyst
• Porphyrin-ring family and roles of their derivative morphologies
• Similar derivatives within DNA base pairs
• 1st-principle simulation of simplified H2 decomposition steps involving derivative DNA base pairs à energetically favorable?
• Wet DNA-catalyzed chemical battery experiment and result
• Dry DNA-catalyzed hydrogen fuel cell under room temperature
• Summary and conclusions
The document discusses how coherent control and photonic perspectives may change materials development and applications. It describes how manipulating nano or molecular dipoles can lead to new light behaviors and optical materials, such as asymmetric refraction. Applications involving interactions between light and bio-systems are also thriving, such as using subtle energy analyzers to probe plant wound currents treated with light and using low-level lasers for therapy. The document advocates developing technologies that integrate light and electronics at light frequencies.
A Suspected Derivative Morphology for pheophytin (脫鎂葉綠素) and the Enhanced H...cclarbl
The document discusses a conjectured derivative morphology of pheophytin that could facilitate proton conduction and hydrogen decomposition. Quantum simulations showed the derivative structure was energetically favorable. Spectral analyses of extracted pheophytin matched the simulated derivative structure more than the textbook structure. Battery experiments demonstrated pheophytin-catalyzed electrodes produced more discharge than non-catalyzed electrodes, providing evidence pheophytin can catalyze hydrogen decomposition. The findings suggest a derivative pheophytin form may exist that could better explain experimental observations than the accepted textbook structure.
Dr. Chungpin Liao is a Taiwanese inventor born in 1959. He received his PhD in plasma science and fusion technology from MIT in 1992. Since then, he has founded his own research lab focused on cross-disciplinary fields like nanotechnology and photonics. Some of his key inventions include the chlorophyll organic cell, which can generate electricity when wet and can power LED lights for a week. It is biodegradable and can be reused 3-4 times. He has received media coverage and recognition for his inventions in Taiwan.
This document discusses principles of ionization and ion dissociation in mass spectrometry. It covers topics like ionization energy, processes that occur during electron ionization like formation of molecular ions and fragment ions, and ionization by energetic electrons. It also discusses concepts like vertical transitions, where electronic transitions occur much faster than nuclear motions. The document provides background information on fundamental gas phase ion chemistry concepts in mass spectrometry.
Study of Substituent Effect on Properties of Platinum(II) Porphyrin Semicondu...UniversitasGadjahMada
Study of substituent effect on properties of platinum(II) porphyrin had been performed using the DFT method. The aim of the study is to investigate the effect of a substituent group on the electronic and optical properties of the platinum(II) porphyrin. Geometry optimization was conducted using DFT/B3LYP/LANL2DZ to obtain the molecular structure, electronic structure and energy profile. Band gap energy (Eg), the density of states (DOS), and UV-visible spectra are the semiconductor parameters to study. Computational results show that platinum(II) porphyrin and substituted platinum(II) porphyrin have properties of semiconductor based on Eg value, DOS, and UV-visible spectra. The results show that Mulliken partial charges of electron withdrawing substituents are higher than the electron donating substituents (CH3, OH, and NH2). Eg values of the complexes with respect to the substituents follow this order: NH2 < OH < NO2 < COOH < I < CH3 < Br < F < H, for DOSHOMO values, the order is CH3 < NO2 < I < OH < F < NH2 < COOH < Br < H and the maximum wavelength (λmax) for UV-visible adsorption spectra follows this order: NH2 > OH > COOH > NO2 > I > Br > CH3 > F > H. Molecules with smaller Eg and DOSHOMO values and higher λmax are considered as the most appropriate semiconductor materials. Our results show that Pt(II)P-NH2 has the smallest Eg and the highest λmax among other substituted platinum(II) porphyrin molecules. Therefore, Pt(II)P-NH2 are the most suitable semiconductor material based on the aforementioned criteria.
The document discusses the use of radioactive isotopes in geology and forensics. It describes the components of atoms, including protons, neutrons, and electrons. Isotopes are variants of the same element that differ in their number of neutrons. Unstable isotopes decay over time, while stable isotopes can be used for radiometric dating. Examples are given of carbon-14 dating of artifacts like the Dead Sea Scrolls and Stonehenge. Forensic cases show how carbon-14 has been used to date things like the Shroud of Turin and nuclear test fallout in teeth.
This document discusses isotopes and radioactive decay. It defines isotopes as forms of a chemical element with the same number of protons but different numbers of neutrons. It describes the history of discoveries in radioactivity by Henri Becquerel, Frederick Soddy, and Ernest Rutherford. It discusses the types of radioactive particles (alpha, beta, gamma rays), their properties, and how radioactive decay occurs. It also covers radioactive decay rates, units of radioactivity like curies, and the concept of half-life.
• Background and motivation – the success of pheophytin (pheo, 脫鎂葉綠素) catalyst
• Porphyrin-ring family and roles of their derivative morphologies
• Similar derivatives within DNA base pairs
• 1st-principle simulation of simplified H2 decomposition steps involving derivative DNA base pairs à energetically favorable?
• Wet DNA-catalyzed chemical battery experiment and result
• Dry DNA-catalyzed hydrogen fuel cell under room temperature
• Summary and conclusions
The document discusses how coherent control and photonic perspectives may change materials development and applications. It describes how manipulating nano or molecular dipoles can lead to new light behaviors and optical materials, such as asymmetric refraction. Applications involving interactions between light and bio-systems are also thriving, such as using subtle energy analyzers to probe plant wound currents treated with light and using low-level lasers for therapy. The document advocates developing technologies that integrate light and electronics at light frequencies.
A Suspected Derivative Morphology for pheophytin (脫鎂葉綠素) and the Enhanced H...cclarbl
The document discusses a conjectured derivative morphology of pheophytin that could facilitate proton conduction and hydrogen decomposition. Quantum simulations showed the derivative structure was energetically favorable. Spectral analyses of extracted pheophytin matched the simulated derivative structure more than the textbook structure. Battery experiments demonstrated pheophytin-catalyzed electrodes produced more discharge than non-catalyzed electrodes, providing evidence pheophytin can catalyze hydrogen decomposition. The findings suggest a derivative pheophytin form may exist that could better explain experimental observations than the accepted textbook structure.
Dr. Chungpin Liao is a Taiwanese inventor born in 1959. He received his PhD in plasma science and fusion technology from MIT in 1992. Since then, he has founded his own research lab focused on cross-disciplinary fields like nanotechnology and photonics. Some of his key inventions include the chlorophyll organic cell, which can generate electricity when wet and can power LED lights for a week. It is biodegradable and can be reused 3-4 times. He has received media coverage and recognition for his inventions in Taiwan.
This document discusses principles of ionization and ion dissociation in mass spectrometry. It covers topics like ionization energy, processes that occur during electron ionization like formation of molecular ions and fragment ions, and ionization by energetic electrons. It also discusses concepts like vertical transitions, where electronic transitions occur much faster than nuclear motions. The document provides background information on fundamental gas phase ion chemistry concepts in mass spectrometry.
Study of Substituent Effect on Properties of Platinum(II) Porphyrin Semicondu...UniversitasGadjahMada
Study of substituent effect on properties of platinum(II) porphyrin had been performed using the DFT method. The aim of the study is to investigate the effect of a substituent group on the electronic and optical properties of the platinum(II) porphyrin. Geometry optimization was conducted using DFT/B3LYP/LANL2DZ to obtain the molecular structure, electronic structure and energy profile. Band gap energy (Eg), the density of states (DOS), and UV-visible spectra are the semiconductor parameters to study. Computational results show that platinum(II) porphyrin and substituted platinum(II) porphyrin have properties of semiconductor based on Eg value, DOS, and UV-visible spectra. The results show that Mulliken partial charges of electron withdrawing substituents are higher than the electron donating substituents (CH3, OH, and NH2). Eg values of the complexes with respect to the substituents follow this order: NH2 < OH < NO2 < COOH < I < CH3 < Br < F < H, for DOSHOMO values, the order is CH3 < NO2 < I < OH < F < NH2 < COOH < Br < H and the maximum wavelength (λmax) for UV-visible adsorption spectra follows this order: NH2 > OH > COOH > NO2 > I > Br > CH3 > F > H. Molecules with smaller Eg and DOSHOMO values and higher λmax are considered as the most appropriate semiconductor materials. Our results show that Pt(II)P-NH2 has the smallest Eg and the highest λmax among other substituted platinum(II) porphyrin molecules. Therefore, Pt(II)P-NH2 are the most suitable semiconductor material based on the aforementioned criteria.
The document discusses the use of radioactive isotopes in geology and forensics. It describes the components of atoms, including protons, neutrons, and electrons. Isotopes are variants of the same element that differ in their number of neutrons. Unstable isotopes decay over time, while stable isotopes can be used for radiometric dating. Examples are given of carbon-14 dating of artifacts like the Dead Sea Scrolls and Stonehenge. Forensic cases show how carbon-14 has been used to date things like the Shroud of Turin and nuclear test fallout in teeth.
This document discusses isotopes and radioactive decay. It defines isotopes as forms of a chemical element with the same number of protons but different numbers of neutrons. It describes the history of discoveries in radioactivity by Henri Becquerel, Frederick Soddy, and Ernest Rutherford. It discusses the types of radioactive particles (alpha, beta, gamma rays), their properties, and how radioactive decay occurs. It also covers radioactive decay rates, units of radioactivity like curies, and the concept of half-life.
The document discusses the structure of atoms including subatomic particles like protons, neutrons and electrons. It describes atomic number and mass number, isotopes, radioactive decay, and different types of radiation (alpha, beta, gamma). It explains how radiation can be detected and some uses and biological effects of radiation including cancer risks from ionizing radiation. The concept of half-life is introduced with examples of how radioactive materials decay over time in a predictable pattern.
Synthesis of low spin iron complex as potential redox mediator for DSCsdanielmorales91
This document discusses the synthesis of low spin iron complexes as potential redox mediators for dye sensitized solar cells. The complexes [Fe(bphen)3]2+/3+ are proposed as they may have a large redox potential and fast self-exchange electron rate due to a smaller reorganizational energy. Characterization techniques like NMR, ESR, and cyclic voltammetry will be used. The complexes will be tested in electrolytes with porphyrin dyes and device performance metrics like J/V and IPCE spectra will be analyzed. Modifying the ligands may tune the redox potential to optimize the open circuit voltage while allowing dye regeneration.
The document summarizes the development and validation of a photocalorimetry technique. It outlines the design of the photocalorimeter instrument and describes validation methods using chemical actinometers like 2-nitrobenzaldehyde and ferrioxalate in solution. Nifedipine degradation experiments were used to validate the technique for solids. Results showed 2-NB provided more stable calibration than ferrioxalate. Future work will apply the technique to study effects of wavelength, moisture and temperature on solid-state reactions.
Photochemical study of micelles in photogalvanic cell for solar energy converIAEME Publication
- The document describes a study of a photogalvanic cell containing Rhodamine 6G, EDTA, and sodium lauryl sulfate (NaLS) for solar energy conversion and storage.
- Key results include a maximum photopotential of 905.0 mV, photocurrent of 450.0 μA, conversion efficiency of 1.26%, fill factor of 0.2516, and storage capacity of 170 minutes under illumination for 140 minutes.
- The effects of varying the concentrations of dye, reductant, and micelles were investigated, finding optimal values that produced the highest electrical outputs from the cell. Other parameters such as pH, diffusion length, and electrode area were also examined.
Impact of electronic correlation on the electron-phonon couplingClaudio Attaccalite
1) Electronic correlation effects are not fully captured by DFT calculations of electron-phonon coupling (EPC). GW and hybrid functional methods can provide corrections.
2) GW calculations have shown that EPC values can be underestimated or overestimated by DFT. Correlation effects can also lead to new physics in EPC.
3) Simplified approaches have been developed to approximate GW corrections to EPC in order to reduce computational cost, such as using static screening or thermal averaging. These approaches have been shown to improve predictions of properties like phonon dispersions and superconducting transition temperatures.
This document discusses the absorption of light by particles in a 1D box. It explains that the energy of the particle is associated with its wavelength based on requiring the particle's wavefunction to be zero at the ends of the box. For a conjugated hydrocarbon like butadiene, the length of the box is estimated to be 578 pm. The wavelength where absorption will occur can be calculated using Planck's relation and equating the energy gap to hν. A longer conjugated molecule like beta-carotene, which appears orange, absorbs visible light with a maximum wavelength of 455 nm due to its extended conjugated system acting as a longer 1D box.
(1) The document discusses doping of semiconductors and transition metal oxides, including n-type and p-type doping of silicon. It also covers band structure diagrams and density of states plots.
(2) Preparation methods for metal oxides include molecular synthesis and solid state synthesis. Modification of solids can occur through ion exchange or intercalation. Lithium ion batteries operate through lithium intercalation into graphite.
(3) Characterization techniques covered are XRD for crystal structure analysis and electron microscopy. Magnetic properties depend on temperature; ferromagnets become paramagnetic above the Curie temperature. Spinels can exhibit ferrimagnetism from opposing sublattice
NANO281 is the University of California San Diego NanoEngineering Department's first course on the application of data science in materials science. It is taught by Professor Shyue Ping Ong of the Materials Virtual Lab (http://www.materialsvirtuallab.org).
This document describes a new tissue-equivalent plastic called A-181 that accurately simulates the photon and neutron absorption properties of brain tissue. A-181 was formulated to match the recommended hydrogen and nitrogen content of brain tissue for applications using low-energy neutrons like boron neutron capture therapy (BNCT). Measurements using A-181 and the standard muscle tissue equivalent plastic A-150 in a BNCT beam show good agreement with Monte Carlo calculations and demonstrate A-181's suitability for neutron dosimetry in brain tissue.
Direct/indirect band gap and exciton dispersion: Monolayer and bulk hexagonal...Claudio Attaccalite
1) A tight-binding model for excitons in 2D and layered hexagonal boron nitride provides insight into its optical properties in the bulk and different polymorphs.
2) Ab initio calculations show the flattening of the exciton dispersion in bulk hBN leads to a mixing of direct and indirect transitions, consistently explaining conflicting data on band structure and optical spectra.
3) The model predicts an even stronger direct gap behavior for Bernal stacked hBN, despite it having an indirect fundamental gap.
Computational chemistry methods can be used to predict the photophysical properties of BODIPY dyes. The author performed preliminary work validating their computational approach by comparing excited state calculations on 26 BODIPY dyes to experimental data. Molecular dynamics simulations were carried out to sample potential energy surfaces and check for non-parallelity between time-dependent density functional theory and restricted open-shell Kohn-Sham methods. Interactions between BODIPY dyes and oxygen were modeled to study singlet oxygen generation pathways.
Spectroscopic methods in Inorganic ChemistryChris Sonntag
This document provides an overview of spectroscopic methods in inorganic chemistry, focusing on infrared (IR) spectroscopy. It discusses key concepts like dipole moments, factors that influence bond vibrational frequencies, and using symmetry to determine vibration modes. Specific applications covered include identifying functional groups, distinguishing between cis and trans transition metal carbonyl complexes using IR spectra, and analyzing metal-ligand vibrations in complexes. The document also lists several online resources for IR spectral simulation, prediction, and reference databases.
Fluoride Recognition of Amide- and Pyrrole-Based Receptors: A Theoretical Study drboon
The novel amide-based receptors, N-(anthracen-1-yl)-1H-pyrrole-2-carboxamide (1) and N-(8-(1H-pyrrole-2-carboxamido) anthracen-1-yl)-1H-pyrrole-2-carboxamide (2) have been designed and investigated for their halide ion recognition using the density functional theory calculations in gas and solvent phases. Electronic and thermodynamic properties of halide ion binding complexes of receptors were investigated. Intermolecular interactions in all the studied complexes occurring via hydrogen bonding are found. The designed receptors 1 and 2 are found to be excellent selectivity for fluoride ion in both gas and solvent phases.
The document contains questions regarding topics in nuclear physics and radiation protection including:
1) The wavelength of an electron as a function of its properties and constants
2) Common materials used in photoneutron sources
3) The least significant type of radiation emitted from Iodine-126
4) The fraction of atoms decayed after a given time period based on the disintegration constant
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
Plenary lecture given by Prof. Katsuhiko Ariga (WPI-MANA, NIMS and University of Tokyo, Japan) on September 12, 2017 in Gramado (Brazil) during the XVI B-MRS Meeting.
1. The document discusses the basic dielectric theory of materials, focusing on polarization at the molecular level in response to an applied electric field.
2. There are several mechanisms that can contribute to polarization, including electronic, ionic, dipolar, and space charge polarization.
3. The dielectric properties of a material, including polarization, permittivity, and loss, are studied as a function of frequency and temperature, and related to the material's molecular structure.
The document discusses the structure of atoms including subatomic particles like protons, neutrons and electrons. It describes atomic number and mass number, isotopes, radioactive decay, and different types of radiation (alpha, beta, gamma). It explains how radiation can be detected and some uses and biological effects of radiation including cancer risks from ionizing radiation. The concept of half-life is introduced with examples of how radioactive materials decay over time in a predictable pattern.
Synthesis of low spin iron complex as potential redox mediator for DSCsdanielmorales91
This document discusses the synthesis of low spin iron complexes as potential redox mediators for dye sensitized solar cells. The complexes [Fe(bphen)3]2+/3+ are proposed as they may have a large redox potential and fast self-exchange electron rate due to a smaller reorganizational energy. Characterization techniques like NMR, ESR, and cyclic voltammetry will be used. The complexes will be tested in electrolytes with porphyrin dyes and device performance metrics like J/V and IPCE spectra will be analyzed. Modifying the ligands may tune the redox potential to optimize the open circuit voltage while allowing dye regeneration.
The document summarizes the development and validation of a photocalorimetry technique. It outlines the design of the photocalorimeter instrument and describes validation methods using chemical actinometers like 2-nitrobenzaldehyde and ferrioxalate in solution. Nifedipine degradation experiments were used to validate the technique for solids. Results showed 2-NB provided more stable calibration than ferrioxalate. Future work will apply the technique to study effects of wavelength, moisture and temperature on solid-state reactions.
Photochemical study of micelles in photogalvanic cell for solar energy converIAEME Publication
- The document describes a study of a photogalvanic cell containing Rhodamine 6G, EDTA, and sodium lauryl sulfate (NaLS) for solar energy conversion and storage.
- Key results include a maximum photopotential of 905.0 mV, photocurrent of 450.0 μA, conversion efficiency of 1.26%, fill factor of 0.2516, and storage capacity of 170 minutes under illumination for 140 minutes.
- The effects of varying the concentrations of dye, reductant, and micelles were investigated, finding optimal values that produced the highest electrical outputs from the cell. Other parameters such as pH, diffusion length, and electrode area were also examined.
Impact of electronic correlation on the electron-phonon couplingClaudio Attaccalite
1) Electronic correlation effects are not fully captured by DFT calculations of electron-phonon coupling (EPC). GW and hybrid functional methods can provide corrections.
2) GW calculations have shown that EPC values can be underestimated or overestimated by DFT. Correlation effects can also lead to new physics in EPC.
3) Simplified approaches have been developed to approximate GW corrections to EPC in order to reduce computational cost, such as using static screening or thermal averaging. These approaches have been shown to improve predictions of properties like phonon dispersions and superconducting transition temperatures.
This document discusses the absorption of light by particles in a 1D box. It explains that the energy of the particle is associated with its wavelength based on requiring the particle's wavefunction to be zero at the ends of the box. For a conjugated hydrocarbon like butadiene, the length of the box is estimated to be 578 pm. The wavelength where absorption will occur can be calculated using Planck's relation and equating the energy gap to hν. A longer conjugated molecule like beta-carotene, which appears orange, absorbs visible light with a maximum wavelength of 455 nm due to its extended conjugated system acting as a longer 1D box.
(1) The document discusses doping of semiconductors and transition metal oxides, including n-type and p-type doping of silicon. It also covers band structure diagrams and density of states plots.
(2) Preparation methods for metal oxides include molecular synthesis and solid state synthesis. Modification of solids can occur through ion exchange or intercalation. Lithium ion batteries operate through lithium intercalation into graphite.
(3) Characterization techniques covered are XRD for crystal structure analysis and electron microscopy. Magnetic properties depend on temperature; ferromagnets become paramagnetic above the Curie temperature. Spinels can exhibit ferrimagnetism from opposing sublattice
NANO281 is the University of California San Diego NanoEngineering Department's first course on the application of data science in materials science. It is taught by Professor Shyue Ping Ong of the Materials Virtual Lab (http://www.materialsvirtuallab.org).
This document describes a new tissue-equivalent plastic called A-181 that accurately simulates the photon and neutron absorption properties of brain tissue. A-181 was formulated to match the recommended hydrogen and nitrogen content of brain tissue for applications using low-energy neutrons like boron neutron capture therapy (BNCT). Measurements using A-181 and the standard muscle tissue equivalent plastic A-150 in a BNCT beam show good agreement with Monte Carlo calculations and demonstrate A-181's suitability for neutron dosimetry in brain tissue.
Direct/indirect band gap and exciton dispersion: Monolayer and bulk hexagonal...Claudio Attaccalite
1) A tight-binding model for excitons in 2D and layered hexagonal boron nitride provides insight into its optical properties in the bulk and different polymorphs.
2) Ab initio calculations show the flattening of the exciton dispersion in bulk hBN leads to a mixing of direct and indirect transitions, consistently explaining conflicting data on band structure and optical spectra.
3) The model predicts an even stronger direct gap behavior for Bernal stacked hBN, despite it having an indirect fundamental gap.
Computational chemistry methods can be used to predict the photophysical properties of BODIPY dyes. The author performed preliminary work validating their computational approach by comparing excited state calculations on 26 BODIPY dyes to experimental data. Molecular dynamics simulations were carried out to sample potential energy surfaces and check for non-parallelity between time-dependent density functional theory and restricted open-shell Kohn-Sham methods. Interactions between BODIPY dyes and oxygen were modeled to study singlet oxygen generation pathways.
Spectroscopic methods in Inorganic ChemistryChris Sonntag
This document provides an overview of spectroscopic methods in inorganic chemistry, focusing on infrared (IR) spectroscopy. It discusses key concepts like dipole moments, factors that influence bond vibrational frequencies, and using symmetry to determine vibration modes. Specific applications covered include identifying functional groups, distinguishing between cis and trans transition metal carbonyl complexes using IR spectra, and analyzing metal-ligand vibrations in complexes. The document also lists several online resources for IR spectral simulation, prediction, and reference databases.
Fluoride Recognition of Amide- and Pyrrole-Based Receptors: A Theoretical Study drboon
The novel amide-based receptors, N-(anthracen-1-yl)-1H-pyrrole-2-carboxamide (1) and N-(8-(1H-pyrrole-2-carboxamido) anthracen-1-yl)-1H-pyrrole-2-carboxamide (2) have been designed and investigated for their halide ion recognition using the density functional theory calculations in gas and solvent phases. Electronic and thermodynamic properties of halide ion binding complexes of receptors were investigated. Intermolecular interactions in all the studied complexes occurring via hydrogen bonding are found. The designed receptors 1 and 2 are found to be excellent selectivity for fluoride ion in both gas and solvent phases.
The document contains questions regarding topics in nuclear physics and radiation protection including:
1) The wavelength of an electron as a function of its properties and constants
2) Common materials used in photoneutron sources
3) The least significant type of radiation emitted from Iodine-126
4) The fraction of atoms decayed after a given time period based on the disintegration constant
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
Plenary lecture given by Prof. Katsuhiko Ariga (WPI-MANA, NIMS and University of Tokyo, Japan) on September 12, 2017 in Gramado (Brazil) during the XVI B-MRS Meeting.
1. The document discusses the basic dielectric theory of materials, focusing on polarization at the molecular level in response to an applied electric field.
2. There are several mechanisms that can contribute to polarization, including electronic, ionic, dipolar, and space charge polarization.
3. The dielectric properties of a material, including polarization, permittivity, and loss, are studied as a function of frequency and temperature, and related to the material's molecular structure.
1. Hartree-Fock theory describes molecules using a linear combination of atomic orbitals to approximate molecular orbitals. It treats electrons as independent particles moving in the average field of other electrons.
2. The Hartree-Fock method involves iteratively solving the Fock equations until self-consistency is reached between the input and output orbitals. This approximates electron correlation by including an average electron-electron repulsion term.
3. The Hartree-Fock approach satisfies the Pauli exclusion principle through the use of Slater determinants, which are antisymmetric wavefunctions that go to zero when the spatial or spin coordinates of any two electrons are identical.
1. Hartree-Fock theory describes molecules using a linear combination of atomic orbitals to approximate molecular orbitals. It treats electrons as independent particles moving in the average field of other electrons.
2. The Hartree-Fock method involves iteratively solving the Fock equations until self-consistency is reached between the input and output orbitals. This approximates electron correlation by including an average electron-electron repulsion term.
3. The Hartree-Fock method satisfies the Pauli exclusion principle through the use of Slater determinants, which are antisymmetric wavefunctions that go to zero when the spatial or spin coordinates of any two electrons are identical.
Optical spectroscopy allows the study of light-matter interactions and provides information about electronic structures. It is a key technique used to probe various states of matter. Spectroscopy gives direct information about electronic structures through the absorption and emission of radiation. Measurement of absorption and photoluminescence emission spectra provides information about electronic band structures and transition rates in semiconductors.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
1. The document outlines research on organic spintronics conducted by Zeev Valy Vardeny and collaborators at the University of Utah.
2. A key finding was the first demonstration of an organic spin valve using ferromagnetic La0.7Sr0.3MnO3 and Co electrodes separated by the organic semiconductor Alq3, which showed a giant magnetoresistance of over 12%.
3. The research aims to exploit unique properties of organic semiconductors like weak spin-orbit coupling and long spin relaxation times for applications in spin injection and detection.
The document summarizes the research of Zeev Valy Vardeny and his collaborators on organic spintronics at the University of Utah. Some of their key findings include:
1) Demonstrating the first organic spin-valve device using LSMO/Alq3/Co layers, which showed a giant magnetoresistance of over 12%.
2) Studying spin dynamics and relaxation processes in organic semiconductors using spin-valve and Hanle effect measurements.
3) Exploring new device concepts like organic spin light-emitting diodes by injecting spin-polarized carriers into organic layers.
electron positron production of dark sector particlesFlip Tanedo
This document discusses potential studies of dark sector particles that could be performed at a future linear collider, such as the International Linear Collider. It begins by noting some advantages of a linear collider compared to the LHC for such searches, including cleaner events and control of beam polarization. It then discusses various portals through which dark sectors could couple to visible matter and characteristics of interest to measure. Examples of specific studies proposed include searches for light mediators, long-lived low-mass particles, distinguishing spin and mass scales of dark particles, and probing axion-like particles and displaced lepton jets from dark sector bound states.
Talk device approach to biology march 29 1 2015Bob Eisenberg
Device Approach to Biology (and Engineering)
The goal of biological research is often more to control than to understand. Devices in biology (like ion channels) control individual functions just as they do in our technology. Study of control requires a multiscale approach because a handful of atoms, moving in 10-15 sec, control biological functions extending meters and taking seconds. Structural biology and molecular dynamics are essential (and beautiful!) parts of this hierarchy, but so are the functions themselves, and the electric field equations that link structure and function on all scales from atoms to nerve cells. Analyzing biological systems as devices is usually successful, and almost always productive.
Optical spectroscopy techniques such as transmission, reflection, absorption, and photoluminescence measurements are important tools for characterizing the optical properties of semiconductor materials for photovoltaic applications. These techniques can determine the band gap type and energy, which are crucial for a material's suitability as a solar cell absorber. A direct band gap is preferable to an indirect band gap. Temperature-dependent absorption measurements provide insight into the temperature dependence of the band gap and allow comparison to density functional theory calculations. Characterizing defects through photoluminescence is also useful. Together, optical measurements provide essential information for understanding and improving photovoltaic materials.
Electromagnetically induced transparency (EIT) is a quantum interference effect that can eliminate absorption of light in a medium. The effect was first observed in 1991 by Steve Harris. EIT occurs when a weak probe beam experiences reduced absorption due to destructive interference from a coupling beam. This creates a "window" of transparency. The physics of EIT involves coherent population trapping in a three-level atomic system using a probe and coupling laser. When the two-photon resonance condition is met, both the real and imaginary parts of the linear susceptibility vanish, resulting in EIT. EIT enables phenomena like slow light and light storage by significantly reducing the group velocity of light pulses.
This document provides an overview of the history of atomic structure models. It begins with early Greek philosophers' concept of atoms. In the 19th century, Dalton proposed that elements are made of unique atom types that can combine. Experiments by Thomson, Rutherford and Bohr led to discoveries about the electron and nuclear structure of atoms. Bohr's 1913 model improved on Rutherford's by proposing discrete electron orbits. Later, the developments of quantum mechanics by Heisenberg, Schrodinger, de Broglie and others explained atomic structure and spectra through wave functions and quantum numbers. This allowed visualization of electron orbitals in atoms.
Ion channels poisson fermi for ima july 23 1 2015Bob Eisenberg
This document summarizes Bob Eisenberg's Poisson Fermi approach to modeling ion channels. It describes how ion channels control important biological functions through the movement of ions like potassium and sodium. The approach uses a Fermi distribution and crowded sphere model to describe the saturation of ion concentration in biological systems, which can reach concentrations over 10M. This allows dimensional reduction to a device equation that describes how ion channels work at the macroscale, controlled by interactions at the atomic scale. The approach has been implemented in a 3D Poisson-Nernst-Planck Fermi code that considers protein structure and couples electrostatics to ion flow, providing a quantitative model of charge-space competition in ion channels and other biological systems.
Ultracold atoms in superlattices as quantum simulators for a spin ordering mo...Alexander Decker
This document discusses using ultracold fermionic atoms in optical lattices to simulate spin ordering models. It begins by describing how atoms can be trapped in optical lattices using laser light. It then proposes how a spin ordering Hamiltonian could be used to achieve superexchange interaction in a double well system. Finally, it suggests going beyond double wells to study resonating valence bond states in a kagome lattice, which could provide insights into phenomena like high-temperature superconductivity.
This document provides an introduction to direct methods for solving the phase problem in crystallography. It discusses several important phase relationships that are used in direct methods, including:
1) The E1 relationship, which estimates the phase of reflection 2H based on the magnitudes of EH and E2H. It shows that for large EH and E2H, it is likely the phase of 2H is 0.
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On the Possibility of Manipulating Lightwaves via Active Electric Charges
1. On the Possibility of Manipulating Lightwaves
via Active Electric Charges
Chungpin Liao1,2,* Li-Shen Yeh,2 Wen-Bing Lai,1,2 Jyun-Lin Huang,1,2
(廖重賓) (葉立紳) (賴玟柄) (黃均霖)
1Graduate School of Electro-Optic and Materials Science,
National Formosa University (NFU), Huwei, Taiwan 632, ROC.
2Advanced Research & Business Laboratory (ARBL),
Taichung, Taiwan 407, ROC.
*Corresponding Author: cpliao@alum.mit.edu
2015/8/13 1Chungpin Liao et al.
2. 2015/8/13 2Chungpin Liao et al.
Outline
• Can TEM waves be affected by the presence of electric charges?
• We’ve seen role of passive charges dipoles dielectrics
• Exact solution in the presence of still and moving charges
useful?
• Feynman’s versatile formula intuitive and useful?
• Scope reduction to steady-state effect of interfacial & surface
active charges
• Can EM waves/ lights be manipulated meaningfully by
active charges instead?
• Experiments & results
• E. T. Whittaker’s two potential general solution useful?
3. 2015/8/13 Chungpin Liao et al. 3
• Can TEM waves be affected by the presence of electric charges?
The TEM solution is from the source-free wave equation:
Hence, the answer should be YES, especially when
the charges are responsive to the EM wave/ light frequency.
But …
2
2
2
0
E
E
t
02
2
2
t
B
B
4. 2015/8/13 Chungpin Liao et al. 4
Q: How come in fully-ionized dense plasmas, which is full of
positive and negative charges, TEM waves are normal modes?
A: Would the quasi-neutrality property of plasma convince us?
i.e., net charge ~ 0
Q: What about the situations where
charge number density ne falls between
those of vacuum and dense plasma?
?
1. Self-consistent in terms of charges and fields?
2. Even motionless charges, any clue to wave-guiding?
5. 2015/8/13 Chungpin Liao et al. 5
• We’ve seen role of passive charges dipoles dielectrics
Matters respond to impinging lights via passively induced charges,
i.e., induced dipoles, in ways against the incoming EM fields.
Cluster of induced electric dipoles dielectrics
However, there is essentially NO magnetic dipoles responsive to
light frequency.
6. Chungpin Liao et al. 6
• Due to Doyle [1985],* the whole set of Fresnel equations
could be written in its “scattering form”, i.e., D S:
(D – single dipole, S – collective dipoles oscillation pattern)
t
iti
itrrrr
r
p
i
p
t
E
E
sin
sincos2
cos11
(a)
it
it
itrrrr
itrrrr
p
i
p
r
E
E
sin
sin
cos11
cos11
(b)
t
iti
itrrrr
r
s
i
s
t
E
E
sin
sincos2
cos11
(c)
it
it
itrrrr
itrrrr
s
i
s
r
E
E
sin
sin
cos11
cos11
(d)
• S 0, D = 0 for (b), (d) Brewster’s angle, e.g.
1
tan2
rr
rrrp
B
1
tan2
rr
rrrs
B
2015/8/13
rrti nn ,1
* W. T. Doyle, “Scattering approach to Fresnel’s equations and Brewster’s law,” Am. J. Phys. 53 (5), 463-468 (1985).
7. Chungpin Liao et al. 7
iti
t
it
p
ip
P
E
sincos2
sin
cos
0
iti
t
it
p
rp
P
E
sincos2
sin
cos
0
electric dipole
p-wave
iti
tp
im
M
E
sincos2
sin
0
0
iti
tp
rm
M
E
sincos2
sin
0
0
p-wave
magnetic dipole
Total:
iti
t
it
p
i
MP
E
sincos2
sin
cos
0
0
0
iti
t
it
p
r
MP
E
sincos2
sin
cos
0
0
0
• Induced dipole sources revealed mNMpNP
2015/8/13
p
im
p
ip
p
i EEE
p
rm
p
rp
p
r EEE
8. Chungpin Liao et al. 8
iti
t
it
p
i
MP
E
sincos2
sin
cos
0
0
0
iti
t
it
p
r
MP
E
sincos2
sin
cos
0
0
0
Putting p
tr EP
10 and p
t
r
r
r EM
0
0
1 into:
we obtain:
it
it
itrrrr
itrrrr
p
i
p
r
E
E
sin
sin
)cos(11
)cos(11
(b)
i.e., Scattering form of one of the Fresnel equations
• Checking: p-wave as an example
Source equations
2015/8/13
9. Chungpin Liao et al. 9
• Similarly, for s-wave, with total P and M contributions:
iti
t
it
s
i
MP
E
sincos2
sin
cos
0
0
0
Putting p
tr EP
10 and p
t
r
r
r EM
0
0
1 in, to obtain:
iti
t
it
s
r
MP
E
sincos2
sin
cos
0
0
0
it
it
itrrrr
itrrrr
s
i
s
r
E
E
sin
sin
)cos(11
)cos(11
(d)
i.e., Scattering form of one of the Fresnel equations
Source equations
2015/8/13
10. Chungpin Liao et al. 10
E.g., adding permanent dipoles for novel applications
• By generalization of the types of involved dipoles in
source equations
• Namely, in general, optically-responsive permanent dipoles
(P0 and M0) embedded in the original material can vary
optical properties, such as the Brewster angle.
• This is, now P = P0 + Pind, M = M0 + Mind
(with Pind and Mind as induced dipoles)
• However, still, how exactly do the dipoles affect the
optical properties, physically?
• See e.g., p-wave, unmagnetized case (i.e., P 0, but M = 0)
2015/8/13
11. Chungpin Liao et al. 11
iti
t
it
p
ip
P
E
sincos2
sin
cos
0
iti
t
it
p
rp
P
E
sincos2
sin
cos
0
So, the P (of whatever origin) contributes only its component
along the relevant E.
|| P
All induced P (so || Et)
2015/8/13
itit PP coscos
12. Chungpin Liao et al. 12
• Adding P0 into an unmagnetized host and look at the p-wave case:
2015/8/13
iti
t
iti
p
tr
p
ip
P
EE
sincos2
sin
coscos1 0
0
0
ti
p
tr E cos1~
iti
t
iti
p
ip
PP
E
sincos2
sin
coscos 0
0
0
0
ti
p
tr E cos1
13. 2015/8/13 Chungpin Liao et al. 13
• Can EM waves/ lights be manipulated meaningfully by
active charges instead?
H
E
t
( curl on Faraday’s )
u
=
=
=
=
uniform ε
Ampere’s
Gauss’E
uniform μ
H
E
t
E)E( 2
H
t
u
E
J
t
2
2
2
u uJE
E
tt
The answer should be YES, even though it is nontrivial.
14. 2015/8/13 14Chungpin Liao et al.
• Exact solution in the presence of still and moving charges
useful?
The formal approach is as follows:
A
tt
B
E
AHB
(Faraday’s law)
0
t
A
E
t
A
E
t
J
E
t
E u
2
2
2
15. 2015/8/13 Chungpin Liao et al. 15
Now, according to Ampere’s law: E
t
JH u
t
A
t
u
AA
A
B
E
t
JH
2
uJ
t
A
A
t
A
2
2
2
Now, let
t
A
(Lorentz gauge)
So, we have: uJ
t
A
A
2
2
2
16. 2015/8/13 Chungpin Liao et al. 16
On the other hand, we work on Gauss’ E law: uE
u
t
u A
tt
A
2
We reach:
u
t
2
2
2
So, we have: AHB
t
A
E
uJ
t
A
A
2
2
2
u
t
2
2
2
t
A
Using
(Lorentz gauge)
17. 2015/8/13 17Chungpin Liao et al.
The formal general solution: (see, e.g., Feynman Lecture Notes –II)
2
12
12
4
,2
,1 dV
r
c
r
t
t
u
2
12
2
12
4
,2
,1 dV
rc
c
r
tJ
tA
u
Q: Is it helpful in regard to the purpose of guiding lightwaves?
TEM Light in vacuum
, J 0
?
2’
2
1r’
r12
Position at
t -r’/c
Position at t
q
q
v
Again, self-consistency problem here, unless for motionless charges. Secondly, any practical clue provided for EM wave guiding?
18. 2015/8/13 Chungpin Liao et al. 18
• E. T. Whittaker’s# two potential general solution useful?
2
2
22
22222
1
,
1
,
1
t
F
cz
F
D
tx
G
czy
F
D
ty
G
czx
F
ED zyxx
2
2
2
22222
,
1
,
1
y
G
x
G
H
zy
G
tx
F
c
H
zx
G
ty
F
c
H zyx
),,(
cos,sinsin,cossinˆ
ˆ
,,,
,,,
2
0 0
2
0 0
zyxr
k
rkct
gddtzyxG
fddtzyxF
F & G are:
arbitrary functional of
Nontrivial to put to use
# Whittaker, E. T., "ON AN EXPRESSION OF THE ELECTROMAGNETIC
FIELD DUE TO ELECTRONS BY MEANS OF TWO SCALAR POTENTIAL
FUNCTIONS," Proceedings of the London Mathematical Society, Vol.
1, p. 367-372 (1904).
19. 2015/8/13 19Chungpin Liao et al.
• Feynman’s+ versatile formula intuitive and useful?
'ˆ
1
'
'ˆ'
'
'ˆ
4 2
2
222
r
dt
d
cr
r
dt
d
c
r
r
rq
E
For a charge q in whatever motion
ErBc
'ˆ
Q: How to arrange so many q’s in motion such that the desired
E & B fields are secured for light-guiding purposes?
+ Feynman R., Leighton R. B., Sands M., The Feynman lectures on physics, Vol. II, Sec. 21, Addison-Wesley, Boston, MA, USA (1971).
20. 2015/8/13 Chungpin Liao et al. 20
• Scope reduction to steady-state effect of interfacial
active charges Experiment 1
0
J
t
Charge conservation law:
Steady state: .vv0 ee constEEenJJ eee
At interface between two
conducting media:
0
t
tEtEtE sb
n
a
nn
21. 21
2
0 0 02
0u p uE J
.const
0 0
0
spsu
Pu
no source of E
2
0
Note that the distrib. of ε plays no part in shaping the E lines, but σ can.
Conduction and EQS Charge Relaxation
ba
terminates or originates on it
)1(ˆ 0
b
aa
spsu
En
0 spsu
En
ˆ&
ab
< 0
E excluded from high σ
0 0 up
E
&
terminates or originates on them (it)
20
uup
J
increasing)r(
E attenuates
< 0
2015/8/13 Chungpin Liao et al.
22. V
0
ITO
ZnO
DC current
glass
s < 0
2015/8/13 22Chungpin Liao et al.
• Experiments & results
+
-+
-
Laser beam spot more focused
E direction
23. 2015/8/13 23Chungpin Liao et al.
56.0
58.0
60.0
62.0
64.0
66.0
0.0 5.0 10.0
光功率(µW)
Time (minute)
2015.07.24_measured intensity at edge
DC power supply turned off
Spot bottom edge,
ITO(+)/ZnO(-) 4V
Spot bottom edge,
ZnO(+)/ITO(-) 4V
Residual charges
- undesirable
24. 2015/8/13 24Chungpin Liao et al.
417.5
420.0
422.5
425.0
427.5
430.0
0.0 1.0 2.0 3.0 4.0 5.0
light intensity (µW)
Time (minute)
2015.07.31_Face to face_Top Edge_ITO (+)/ZnO(-)_1.0V to 4.0V
Unbiased reference
4 V
1 V
2 V
3 V
The repeatability was poor so far, possibly due to varying interfacial states.
25. 2015/8/13 Chungpin Liao et al. 25
405.0
410.0
415.0
420.0
425.0
430.0
0.0 1.0 2.0 3.0 4.0 5.0
light intensity (µW)
Time (minute)
2015.07.31_Face to face_Top Edge_ITO(+)/ZnO(-)_4.0 V to 1.0V
reference
1 V
2 V
3 V
4 V
There were likely hysteresis effect due to residual charges.
26. Experiment 2: charge-influenced light reflection
2015/8/13 Chungpin Liao et al. 26
Dielectric: paper
Solid-state
Argon laser,
with E
vertical to the
laser beam
Light power
measurement
per 300 ms
Smooth and shiny
stainless steel
E
Biased
Capacitor
28. 2015/8/13 Chungpin Liao et al. 28
Summary & conclusions
• Active electric charges were found to be responsive to incident
lightwaves and to affect the propagation/reflection of lightwaves.
• Guiding of lightwaves by active charges is valid in principle, but
putting it to work practically would need more creativity and
efforts.
• In the future, such active ingredients may assist the
traditional passive dielectric approach for more meaningful
optical and photonic purposes.
Editor's Notes
Mainly to ask two questions: 1. Will active charges be responsive to incident lightwaves? 2. If so, how to use active charges for the manipulation of lightwaves?
TEM mode is picked up for ease of elaboration only.
The important thing in the light diffraction: E_in, E_ref, and E_tran can all be viewed as results of the induced E and M dipoles, as envisioned from the latter.
We will be talking about nearly vacuum or nearly uniform cases, where the medium is isotropic, linear, and memoryless.
An inhomogeneous wave equation for the vector potential
An inhomogeneous wave equation for the scalar potential
One scalar potential, one vector potential to suffice the full solution; The bottom part: what about self-consistency?
Mathematically easier, but practically harder for our purposes
Again, what about the self-consistency?
To create steady-state interface charges, unpaired and paired.
Residual charge effect might be due to the interface traps.
The results were varying from time to time, but the charge influence on light was obvious.