This document discusses nickel-catalyzed organic reactions for synthesis, including the Suzuki-Miyaura cross-coupling, enantioselective reductive carbo-acylation of alkenes, and carbonylative Sonogashira reaction. It also mentions nickel-catalyzed Kumada-Tamao-Corriu cross coupling and redox-neutral carbo-acylation. These reactions allow for difunctionalization of alkenes and asymmetric dicarbofunctionalization of tethered alkenes using nickel catalysis.

1. Transition-metal and Organocatalysis in
Organic Synthesis
Nickel
UNIT-IV

2. Nickel catalysed suzuki miyaura
cross coupling
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3. Nickel-catalyzed enantioselective reductive carbo-
acylation of alkenes
Transition-metal-catalyzed difunctionalization of alkenes.
a Asymmetric dicarbofunctionalization of tethered alkenes involving arylmetalation.
2

4. B. Redox-neutral carbo-acylation

5. C. Ni-catalyzed reductive asymmetric carbo-acylation of tethered alkenes

6. Nickel catalysed carbonylative Sonogashira reaction for the
synthesis of diarylalkynones and 2-substituted flavones
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7. Kumada-Tamao-Corriu
Cross Coupling
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