The NFPA 70E standard is established to ensure safety for workers interacting with electricity by outlining safe work practices related to electrical hazards. Employers are responsible for providing training on safety procedures, risk assessments, and the use of protective equipment, while also implementing lockout/tagout systems to prevent accidents. Although NFPA 70E does not cover electrical system design, it emphasizes the importance of awareness, organization, and proper training to maintain a safe working environment.