This document discusses using spectroscopic ellipsometry to analyze molecular fractal surfaces through physical adsorption of water and other liquids. It provides background on existing surface adsorption theories and how they have been expanded to account for fractal surfaces. Experimental data is presented on water adsorption measured by ellipsometry on various surfaces like gold, silicon, and germanium. The data is analyzed using modified adsorption models that incorporate the fractal dimension of the surfaces to determine properties like monolayer coverage and surface dimensionality.
FIELD AND THEORETICAL ANALYSIS OF ACCELERATED CONSOLIDATION USING VERTICAL DR...P singh
Mumbai is the region consisting of soft compressible marine clay deposits. There are several construction problems on such soils and thus ground improvement is need to be carried out. Vertical drains is generally preferred technique as accelerated settlement is achieved during the construction phase itself if planned accordingly. The concept of vertical drains is based on the theory of three dimensional consolidation as described by Terzaghi (1943). Based on this concept, a consolidation programme is developed and an attempt is made to determine the field to laboratory coefficient of vertical consolidation ratio by Taylor’s Square Root of Time Method and Casagrande’s Logarithm of Time Fitting Method for this region by considering the case study of Bhandup Lagoon Works Embankment. Based on this ratio, the rate of consolidation and time required for consolidation in the field can be determined knowing the consolidation parameters. Equations are developed by using output of the programme and it is explained.
A Study of Anomalous Value of Free-Air Vertical Gradient for Density Determin...Premier Publishers
Underground Gravity Vertical Gradient is an important practice for prospecting underground densities, although in most cases it does not match the densities obtained directly in the laboratory from rock samples representative of the location. The densities of the laboratory samples were systematically lower when compared to the densities calculated by gravimetric determination suggesting some kind of systematic error. Several researchers propose different sources to explain these systematic errors including an anomalous value of the free-air vertical gradient. The anomalous value was admitted for the free-air vertical gradient in this paper to reinterpret the densities determination research made in a mine at Barberton, Ohio, in 1950, by gravimetric measurements and by laboratory rock samples. The results of both approaches reached similar densities agreeing with the free-air vertical gradient proposed.
2005 convective heat and solute transfer in partially porous cavitiesHassan S. Ghaleb
This paper deals with natural convection driven by combined thermal and solutal buoyancy forces in a binary fluid.
The configuration under study is a confined enclosure partially filled with a vertical porous layer. The mathematical
description of the problem is based on a one-domain formulation of the conservation equations. The set of numerical
results presented here quantitatively shows the influence of the porous layer on the flow structure and on heat and species transfer in the enclosure.
The paper is focused on the analysis of the influence of the characteristic parameters governing double diffusive convection, namely the ratios of solutal and thermal parameters: the diffusivities and the buoyancy forces. Heat and mass
transfer is analyzed as a function of the permeability of the porous layer. It is shown that the coupling of the flow penetration in the porous layer with the combined buoyancy forces induces a specific behavior of the flow structure and
average heat transfer in the enclosure.
MATHEMATICAL MODEL FOR HYDROTHERMAL CONVECTION AROUND A RADIOACTIVE WASTE DEP...Jean Belline
A mathematical model of thermally induced water movement in the vicinity of a hard rock
depository for radioactive waste is presented and discussed. For the low permeability rocks envisaged for
geological disposal the equations describing heat and mass transfer become uncoupled and linear.
Analytic solutions to these linearized equations are derived for an idealized spherical model of a
depository in a uniformly permeable rock mass. As the hydrogeological conditions to be expected at a
disposal site are uncertain, examples of flow paths are presented for a range of different permeabilities,
porosities, boundary conditions and regional cross-flows.
Seismic performance of a layered liquefiable site validation of numerical sim...Mahir Badanagki, Ph.D.
In this paper, the results of a centrifuge experiment modeling of a layered soil profile, including a liquefiable layer of Ottawa sand, are used to evaluate the predictive capabilities of two state ofthe-art constitutive models.
FIELD AND THEORETICAL ANALYSIS OF ACCELERATED CONSOLIDATION USING VERTICAL DR...P singh
Mumbai is the region consisting of soft compressible marine clay deposits. There are several construction problems on such soils and thus ground improvement is need to be carried out. Vertical drains is generally preferred technique as accelerated settlement is achieved during the construction phase itself if planned accordingly. The concept of vertical drains is based on the theory of three dimensional consolidation as described by Terzaghi (1943). Based on this concept, a consolidation programme is developed and an attempt is made to determine the field to laboratory coefficient of vertical consolidation ratio by Taylor’s Square Root of Time Method and Casagrande’s Logarithm of Time Fitting Method for this region by considering the case study of Bhandup Lagoon Works Embankment. Based on this ratio, the rate of consolidation and time required for consolidation in the field can be determined knowing the consolidation parameters. Equations are developed by using output of the programme and it is explained.
A Study of Anomalous Value of Free-Air Vertical Gradient for Density Determin...Premier Publishers
Underground Gravity Vertical Gradient is an important practice for prospecting underground densities, although in most cases it does not match the densities obtained directly in the laboratory from rock samples representative of the location. The densities of the laboratory samples were systematically lower when compared to the densities calculated by gravimetric determination suggesting some kind of systematic error. Several researchers propose different sources to explain these systematic errors including an anomalous value of the free-air vertical gradient. The anomalous value was admitted for the free-air vertical gradient in this paper to reinterpret the densities determination research made in a mine at Barberton, Ohio, in 1950, by gravimetric measurements and by laboratory rock samples. The results of both approaches reached similar densities agreeing with the free-air vertical gradient proposed.
2005 convective heat and solute transfer in partially porous cavitiesHassan S. Ghaleb
This paper deals with natural convection driven by combined thermal and solutal buoyancy forces in a binary fluid.
The configuration under study is a confined enclosure partially filled with a vertical porous layer. The mathematical
description of the problem is based on a one-domain formulation of the conservation equations. The set of numerical
results presented here quantitatively shows the influence of the porous layer on the flow structure and on heat and species transfer in the enclosure.
The paper is focused on the analysis of the influence of the characteristic parameters governing double diffusive convection, namely the ratios of solutal and thermal parameters: the diffusivities and the buoyancy forces. Heat and mass
transfer is analyzed as a function of the permeability of the porous layer. It is shown that the coupling of the flow penetration in the porous layer with the combined buoyancy forces induces a specific behavior of the flow structure and
average heat transfer in the enclosure.
MATHEMATICAL MODEL FOR HYDROTHERMAL CONVECTION AROUND A RADIOACTIVE WASTE DEP...Jean Belline
A mathematical model of thermally induced water movement in the vicinity of a hard rock
depository for radioactive waste is presented and discussed. For the low permeability rocks envisaged for
geological disposal the equations describing heat and mass transfer become uncoupled and linear.
Analytic solutions to these linearized equations are derived for an idealized spherical model of a
depository in a uniformly permeable rock mass. As the hydrogeological conditions to be expected at a
disposal site are uncertain, examples of flow paths are presented for a range of different permeabilities,
porosities, boundary conditions and regional cross-flows.
Seismic performance of a layered liquefiable site validation of numerical sim...Mahir Badanagki, Ph.D.
In this paper, the results of a centrifuge experiment modeling of a layered soil profile, including a liquefiable layer of Ottawa sand, are used to evaluate the predictive capabilities of two state ofthe-art constitutive models.
Numerical Simulations of Residues Areas in different phases: Filling and Upst...IJERA Editor
Currently in Brazil, the deposition technique of bauxite residues provides an initial operation to discharge waste within artificial lakes, in a slurry form (wet disposal). After achieving the storage capacity of the reservoir and drying the waste, the embankment is raised by the upstream method. So, the slurry is discharged on top of a material which is undergoing a consolidation process. The prediction of bauxite wastes behavior is a challenge for geotechnical engineers, since these materials show a distinct response of the materials usually found in natural deposits. The present work aims at simulation of a bauxite residue area in different stages of operation: wet disposal and upstream, using a finite element program. The geotechnical parameters were defined according field and laboratory tests executed in the area. The numerical prediction was compared with the instrumentation field, located in different phases of operation. The results show the applicability of the numerical program in predicting the behavior of waste areas.
Asme2009 82287 - Porous Media - Forced Convection FlowHIIO
In this study the flow field and heat transfer properties of a
steady, two-dimensional flow field in a porous domain between
two parallel plates is investigated numerically by using a
discretized numeric code. Analysis has been carried for
Reynolds number based on particle sizes ranging from 60 to
1000. Numerical results are compared with different numerical
methods used for predicting this kind of flow. Results are
obtained for different regime, various p Re numbers and the
effect of Particles size is also investigated. Solutions indicate
that by increasing the
p Re , the flow in the porous media
remains laminar where the flow has turbulence characteristics
for p Re <50. Moreover, by increasing p Re , the value of
average Nusselt number increases. Also, reducing the particle
size affects the Nusselt number and it increases while the
porosity remains the same.
Optimum replacement depth to control heave of swelling claysAhmed Ebid
The behavior of unsaturated swelling soils under changing of moisture content was intensively studied by many researchers since the 1950’s. Many proposed formulas and techniques were used to classify, describe and predict the swelling behavior and parameters of such type of soil. On the other hand, many techniques are used to allow structures to be founded on swelling soils without suffering any damages due to the soil heave. Replacing the swelling soil with granular mixture is one of the most famous and cheapest techniques especially in case of light structures on shallow layer of swelling soil. The aim of this research is to develop a simplified formula to estimate the heave of swelling soil considering the effect of replaced layer. The developed formula is used to estimate the required replacement depth to avoid damage due to excessive heave.
Nonclassical Properties of Even and Odd Semi-Coherent StatesIOSRJAP
Even and odd semi-coherent states have been introduced. Some of the nonclasscial properties of the states are studied in terms of the quadrature squeezing as well as sub-Poissonian photon statistics. The Husimi– Kano Q-function and the phase distribution in the framework of Pegg and Barnett formalism, are also discussed.
Numerical Simulations of Residues Areas in different phases: Filling and Upst...IJERA Editor
Currently in Brazil, the deposition technique of bauxite residues provides an initial operation to discharge waste within artificial lakes, in a slurry form (wet disposal). After achieving the storage capacity of the reservoir and drying the waste, the embankment is raised by the upstream method. So, the slurry is discharged on top of a material which is undergoing a consolidation process. The prediction of bauxite wastes behavior is a challenge for geotechnical engineers, since these materials show a distinct response of the materials usually found in natural deposits. The present work aims at simulation of a bauxite residue area in different stages of operation: wet disposal and upstream, using a finite element program. The geotechnical parameters were defined according field and laboratory tests executed in the area. The numerical prediction was compared with the instrumentation field, located in different phases of operation. The results show the applicability of the numerical program in predicting the behavior of waste areas.
Asme2009 82287 - Porous Media - Forced Convection FlowHIIO
In this study the flow field and heat transfer properties of a
steady, two-dimensional flow field in a porous domain between
two parallel plates is investigated numerically by using a
discretized numeric code. Analysis has been carried for
Reynolds number based on particle sizes ranging from 60 to
1000. Numerical results are compared with different numerical
methods used for predicting this kind of flow. Results are
obtained for different regime, various p Re numbers and the
effect of Particles size is also investigated. Solutions indicate
that by increasing the
p Re , the flow in the porous media
remains laminar where the flow has turbulence characteristics
for p Re <50. Moreover, by increasing p Re , the value of
average Nusselt number increases. Also, reducing the particle
size affects the Nusselt number and it increases while the
porosity remains the same.
Optimum replacement depth to control heave of swelling claysAhmed Ebid
The behavior of unsaturated swelling soils under changing of moisture content was intensively studied by many researchers since the 1950’s. Many proposed formulas and techniques were used to classify, describe and predict the swelling behavior and parameters of such type of soil. On the other hand, many techniques are used to allow structures to be founded on swelling soils without suffering any damages due to the soil heave. Replacing the swelling soil with granular mixture is one of the most famous and cheapest techniques especially in case of light structures on shallow layer of swelling soil. The aim of this research is to develop a simplified formula to estimate the heave of swelling soil considering the effect of replaced layer. The developed formula is used to estimate the required replacement depth to avoid damage due to excessive heave.
Nonclassical Properties of Even and Odd Semi-Coherent StatesIOSRJAP
Even and odd semi-coherent states have been introduced. Some of the nonclasscial properties of the states are studied in terms of the quadrature squeezing as well as sub-Poissonian photon statistics. The Husimi– Kano Q-function and the phase distribution in the framework of Pegg and Barnett formalism, are also discussed.
our make it better is..................................................................................................................................................................................................................................................................................................................................
3 Surface Tension and Its MeasurementSina Ebnesajjad3.1 In.docxlorainedeserre
3 Surface Tension and Its Measurement
Sina Ebnesajjad
3.1 Introduction
Surface science is an important branch of
physical organic chemistry that studies the
behavior and characteristics of molecules at or
near a surface or interface. The interface can form
between solids, liquids, gases, and combinations of
these states. Complex apparatus has been devel-
oped to identify and quantify surfaces and inter-
faces. Polymer surfaces are of special interest in
industrial and biological applications; examples of
the latter include dental implants and body part
prosthetic devices. Modification of surfaces of
these devices allows formation of controlled
interfaces to achieve characteristics such as
bondability and compatibility.
Adhesion is an interfacial phenomenon that
occurs at the interfaces of adherends and adhe-
sives. This is the fact underlying the macroscopic
process of joining parts using adhesives. An
understanding of the forces that develop the
interfaces is helpful to the selection of the right
adhesive, proper surface treatment of adherends,
and effective and economical processes to form
bonds. This chapter is devoted to the discussion of
the thermodynamic principles and work of adhe-
sion that quantitatively characterize surfaces of
materials.
Figure 3.1 Liquideliquid interface and balance of
forces on molecules of liquids.
3.2 What is an Interface?
Two solid or liquid phases in contact have atoms/
molecules on both sides of an imaginary plane called
the interface. The interfacial particles differ ener-
getically from those in the bulk of each phase due to
being on the boundary of the respective phase and
interacting with the particles of the other phase. The
composition and energy vary continuously from one
phase to the other through the interface. This region
has a finite thickness, usually less than 0.1 mm.1,2
Handbook of Adhesives and Surface Preparation, ed. Sina Ebnesajjad. DOI:
� 2011 Elsevier Inc. All rights reserved.
This chapter has been adapted from ‘Surface Tension and Its Measurement’ in
S. Ebnesajjad & C.F. Ebnesajjad � 2006 Elsevier Inc.
3.3 Surface Tension
The molecules of a liquid are held together by
attraction forces. The sum of all attractive forces on
any molecule present in the bulk of a liquid averages
zero. The net force (also known as cohesion force) on
a surface molecule is a nonzero quantity in the
direction toward the bulk (Fig. 3.1). This is the force
that must be counteracted to increase the surface
area; the energy consumed by this process is called
surface energy. The unbalanced forces on the inter-
face cause it to contract to the minimum. Water
droplets are spherical because a sphere has minimum
surface area for a given volume among all geometric
shapes. Although surface tension and surface free
energy of a liquid are equal, the same is not true for
a solid surface.
Surface tension is defined as the work required to
increase the area of a surface isothermally and
reversibly by unit amount. Surface ...
Adhesion is linked with surface forces like capillary pressure and is thus detrimental at the
nanoscale where body forces are negligible. It can lead to instant failure during fabrication and
operation but it can also lead to overtime failure because of induced friction and wear. However,
when it is possible, coating a device with hydrophobic materials reduces drastically that mechanism.
Understanding how adhesion works is crucial to design new systems and to enable new
technologies. Two models (JKR and DMT) are studied in this paper and model adhesion in different
cases. Photolithography and particularly the release step must be carefully designed to prevent
contamination and stiction. Materials must be chosen and designed wisely to prevent adhesion
failure during operation but lubricants can be used to reduce its impact as well as the impact of
friction and wear.
Impact of Gouy-Chapman-Stern model on conventional ISFET sensitivity and stab...TELKOMNIKA JOURNAL
Utilizing Gouy-Chapman-Stern model can improve ISFET sensitivity and stability using Stern layer in direct contact with electrolyte in ISFET sensing window. However, this model remains a challenge in mathematical way, unless it’s re-applied using accurate simulation approaches. Here, we developed an approach using a commercial Silvaco TCAD to re-apply Gouy-Chapman-Stern model as ISFET sensing membrane to investigate its impact on sensitivity and stability of conventional ISFET. Sio2 material and high-k Ta2O5 material have been examined based on Gouy-Chapman and Gouy-Chapman-Stern models. Results shows that the ISFET sensitivity of SiO2 sensing membrane is improved from ~38 mV/pH to ~51 mV/pH and the VTH shift stability is also improved. Additionally, the results indicate that the sensitivity of Ta2O5 is 59.03 mV/pH that hit the Nearnst Limit 59.3 mV/pH and achieves good agreements with mathematical model and previous experimental results. In conclusion, this investigation introduces a real validation of previous mathematical models using commercial TCAD approach rather than expensive fabrication that paves the way for further analysis and optimization.
Finding the Spontaneous/Self Potential of the SurfaceIRJESJOURNAL
Abstract:- Measuring the spontaneous/self potential of the ground at different points in a line to now the subsurface structure.This helps us to show the high potential and low potential points of the ground,actually these are the elevation and steep areas of the subsurface structure.basically,these points together forms in the shape of the countor map of the area which shows the characteristics of the subsurface. This experiment is carried out by the voltmeter.
Artigo mostra resultados obtidos com o OSIRIS que mostra manchas brilhantes na superfície do cometa 67P/Churyumov-Gerasimenko, interpretadas como sendo gelo de água e provadas via experimentos de laboratório.
A Method For Evaluating the Sorption Capacity of The SorbentsIJMERJOURNAL
ABSTRACT: A new method for evaluating the sorption capacity of the sorbents is offered. The proposed model is based on the adsorption data of the sorbent depending on the sorption duration in static mode. The new model allows to quickly and easily evaluate the duration of sorbent saturation. The formula of this relationship is determined by means of plotting of sorbent saturation curve on the base of experimental data, and using of Exel Trendline program. After the appropriate calculations and plotting q from time the sorption capacity of the sorbent is estimated. The model, as a primary parameter, includes time. The experimental data were obtained on the base of peat-containing sorbent for sorption of copper and cobalt. Sorption processes were evaluated by ICP-MS.
1. 1
Molecular Fractal Surfaces Analysis by Spectroscopic
Ellipsometry
F. Ferrieu*
1
, J. P. Piel**
2
, J. L. Stehlé
2
, A. Danel
3
.
1
STMicroelectronics, 850, rue Jean Monnet, F38926 CROLLES Cédex France.
2
SOPRA-SA 26, rue Pierre Joigneaux, 92270 BOIS-COLOMBES France
3
CEA/LETI Minatec 17 rue des Martyrs 38054 GRENOBLE cedex 9 France.
Received zzz,revised zzz,accepted zzz
Published online zzz
PACS 06.20.-f, 07.60.Fs, 85.40.-e, 67.70.+n,68.03.Fg,
*
Corresponding author:e-mail: frederic.ferrieu@cea.fr , Phone +33 438784056Fax +33438785273
**
e-mail jean-phlippe.piel@sopra-sa.com Phone+33146496700Fax +33 142422934
This paper reports on recent highlights in the application of fractals to surface science. The use of Spectroscopic Ellipsometry
(SE) for emphasizing the surface properties of thin films is simply described. The physical adsorption of water by non-porous
materials, which gives rise to a Type II isotherm and only few studies exists [1], is reported. Our aim is to demonstrate the
application of the surface adsorption optical technique for surface analysis. Some examples are presented and discussed.
1 Introduction During these last years the
Ellipsometry-Porosimetry, (EP), investigation field
has been extensively prospected, [2], leading to
commercial equipments able to analyze the pore size
distribution and density of porous materials such as
for example low k dielectrics. However, in the past
high sensitivity ellipsometry was also used to study
the adsorption of liquids vapors onto solids surface.
The earlier papers from D. Beaglehole, [3], and J.G.
Dash [4] stated most of the physics of the interactive
forces present in the adsorption phenomena between
an adsorbate species and a surface. This important
field of surface science is closely related to similar
phenomena such as wetting, spreading and surface
melting. The extent of adsorption depends on the
strength and range of the potential between substrate
and the adsorbing molecules. Similar effects have
been studied first in the adsorption of gases
phenomena such as clustering and even percolation
transition in He (helium) (wetting) and other thin
films [4]. However in most of these works the surface
morphology has not been specifically considered
assuming that clustering and wetting phenomena are
only driven from the interacting forces between the
substrate and the adsorbing molecule. In the
semiconductor field, the study of surface states is
mandatory in most of the epitaxial or deposition
growth process. One could be aware of the possible
applications which could be developed with this
method in the surface state of thin deposited films,
e.g., in the case of the atomic layer deposition (ALD).
If one considers a silicon wafer substrate with its
native oxide, its surface state can be altered after
specific etching process and following various
treatments, plasma deposition sputtering or ion bias
plasma which yield various intrinsic surface
properties. Furthermore a “composite” surface can be
seen of a patchwork of regions and the control of the
active surface area (ASA) ratio certainly turns a key
parameter. The paper discuss of the level of
understanding of the information which can be
obtained through this technique. As a counterpart of
the other surfaces analysis methods, the optical
technique is non destructive, fast and easy to
implement even on line or in situ. Several parameters
have mainly to be considered, rather often, one only is
retained: i.e., the surface roughness value. It can be:
either mechanical or optical [5]). None of these
approaches fills other surface information requests
such as the Gaussian nature of a random surface or in
a hemispherical or conical quasi periodically
distribution. Here come additional correlation effects,
since the phenomenon is repetitive and self affine, it
has to be described with a fractal dimension. From
AFM data, the surface peak-peak autocorrelation
function H(r) can be seen as:
(1)
2. 2
ω is the roughness and ξ , a lateral correlation
length. The fractal surface dimension D appears in α,
since α=3-D .
The XRR and small angle Neutron Scattering,
(SANS) techniques also yields the H(r) surface
correlation function. The AFM also correlates the
scanned surfaces with the Power Spectral density
(PSD) of the diffracted haze light. In none of these
methods, the ratio of ASA, (active surface area),
which is the ratio of possible partially cluster-patched
surface areas, can be given. By studying surface
states, means to observe how a specific molecular
species (the adsorbate) will probe the surface itself
(the adsorber). As a counterpart the adsorber surface
information is deduced. The weak inlet of adsorbate
molecule in the low pressure chamber is controlled
within a rate varying between zero (p ~ mTorr)) until
reaching the saturation pressure p=ps., i.e., the vapor-
liquid condensation limit The bonding characters
between adsorbate molecules or atoms with the
adsorber substrate are mainly due to dipole-dipole
interactions often modeled with van der Waals force.
Main studies with gases were performed at low
temperature since the temperature of the surface
Tsurface must yield an energy U ( kb Tsurface < +/-10 U)
less than the binding energy U of the dipole and its
image in the plane of the substrate.,(kb is the
Boltzmann constant). Adsorbate molecules can exist
in a number of different phases. Phase transition to 2-
D multi layer fluid where there are no bondings to
particular substrate site form a “registered” or
commensurate structure that could be observed. The
signature of this effect should be expected and be
seen as small “bumps” in the isotherm curve [4].
From the experimental point of view, with a gas ,
samples have to be chosen with a large adsorptive
area capacity. As a contrary, several monolayers films
of small organic molecules like methanol, ethanol,
(Eth), benzene, Iso Propyl Alcool, (IPA) and
therefore H2O, can be detected with in situ
ellipsometry. The technique is in fact one of the most
sensitive instruments to this purpose. Previous
measurements were already reported [6]. The attempt
here is to summarize them first and to show the
potential issues of this technique. This paper refers
also to new measurements since the availability of the
(EPA) Ellipsometer Porosimeter Atmospheric system
from SOPRA.SA [7], depicted in the following
scheme (fig. 1). The EPA system has been designed
in order to realize easy porosimetry measurement in
the case of water H2O in N2 diluted in an atmospheric
pressure cell at room temperature.
2The BET, FHH Surfaces Adsorption Theories.
Two former theories exists the so-called BET
(Brunauer, Emmet et Teller) equations for a flat
surface (1938). From the equilibrium between the
two rates of evaporation and condensation on the
surface of the adsorber, Brunauer, Emmet and Teller
built the following equation
(2)
Here, the V, Vm are volumes corresponding
respectively to the surface volume on the adsorber
and the monolayer volume Vm also called the
monolayer coverage capacity. The pressure p is a
partial pressure ps The BET coefficient Cm, is
related to the surface energies, (interaction between
adsorbate and adsorber and also between adsorbate
molecules themselves), is obviously thermally
activated with a monolayer capacity coefficient Cm~
exp-∆E/kBT . The BET equations were established
considering only a plane surface. Beside these
classical BET equations, other theories of surface
energy interactions emerged later in 1948, referred as
the FHH theory. The multi layers build up by water
adsorption on a clean surface at low partial pressure
comes from the interface intensity (and the nature) of
long, (London (LD) forces)), or short (Debye and
Keesom interactions) range forces between the water
molecule and the analyzed surface. The answer to
their intensity could be extracted from the isotherm
data. When the water film thickens beyond two or
three monomolecular layers, previous theories should
fail since one has to analyze the isotherm by reference
to all present surface forces including adsorbate
interactions. The physical H2O vapors adsorption on
chemically cleaned Si surfaces at constant
temperature (25°C), was studied by Archer [8] as
function of the relative humidity, by ellipsometry.
With hydration these surfaces become hydrophilic
whereas etched, polished, they turn to a more
hydrophobic behavior. Other measurements were also
reported on quartz surfaces showing the high
sensitivity of the method to very low
contaminations.[9]. More recently, H.Arwin et al, [1]
considered the Halsey general form when the t-curve
on oxidized planar silicon is measured and recognized
the London dispersion force as the main mechanism
involved in the adsorption of water on silicon.
2.1The BET Modified Multilayer Adsorption
Model on a Fractal Surface. The fractal theories
from the mathematician B. Mandelbrot [10] were then
extensively developed since the 1980 years
particularly most of the surface physical sciences
topics. The fractal theory for a self affine surface is an
extent of the basic relation where n is the
number of time the use of the metric r is
accomplished to get, (and therefore to measure), the
area of a fractal object with dimension D, but here the
metric correspond to one molecule size here.
Developments proposed and applied only with gases
adsorbate. [13-15], give a more clear view of the
3. 3
adsorption by considering fractals surfaces and
reviewing the previous BET formalism [16]
The FHH equations were analysed following
the surface dimensionality D introduced when
considering the surface fractal character [13]. In the
case of the two theories (BET and FHH), the number
of the molecules needed to cover entirely the surface
is correlated with the surface fractal dimension itself.
The attractive van der Waals force potential, (mostly
from long range order London (LD) interaction for a
non polar adsorbate), wants to make the film-vapor
interface to follow up and down the surface as closely
as possible whereas, the surface free potential energy
of the film (surface tension capillary forces) wants to
make the film vapour interface as flat as possible.
Early fractal analyses emphasize the fact that when a
surface is scale invariant, (self affine), the number of
molecules of same size a in the range required to
cover the surface with a monolayer is
where D is the surface fractal dimension with
(2<D<3) and C, the Hausdorf metric of the surface.
Data can then be analyzed through the fractal
generalization of the FHH isotherm. The measure of
the film thickness, probes the geometry of the surface
over this range of scales. In the FHH case, the number
of adsorbed molecules N and the monolayer coverage
Nm turns to be related to the fractal dimension through
the Minkowski dimension factor
in this equation with The ξp is a metric
according to the partial pressure . In the
second BET fractal theory, [13], the model takes into
account the multilayer filling along a Koch curve
[10]. One get the fractal dimension D from α, but also
the other corrected BET parameters, i.e., Cm (BET
constant), a function of both adsorbate and adsorber, a
function of temperature T, as well and with Vm the
monolayer coverage and the partial pressure
one has:
(3)
Finally, very recent works [16], have shown that
surface adsorption could be also described adding
several contributions of composites n aggregates with
respective density θι, i=1,.n seen as a weighting
distribution of the different active surface areas.
3.Nanotechnology materials As a test from these
theories, several preliminary measurements were
carried out with a low pressure Ellipsometer
Porosimeter (EP). These are only for demonstrative
purposes since, many recommendation, as given here
previously have not been thoroughly fulfilled. The
data have been acquired with both systems:i)the
ambient Water (H2O) adsorption technique and ii)a
low pressure analysis ellipsometric cell with inlet of
organic solvents like ethanol alcohol (Eth) and Iso-
Propyl Alcohol,(IPA). The temperature is somewhat
lower maintained at 15°C, instead of the room
temperature with the EPA experiments with a higher
temperature in the range 24-25°C. With EP,
measurements were from few milliTorr, (mTorr)
reaching to the saturation pressure Ps (10-30Torr).
The water adsorption system (EPA patented) is
commercially available. [7], it is much easier to
mount on the attachment of a spectroscopic
ellipsometer. A schematic is shown in the figure 1
Figure 1. Scheme of the experimental ellipso-porosimeter
Several examples will follow hereafter to demonstrate
the use of equation (3) and then the interest of the
technique. Let us remind as general rule for fitting in
equation (3), that the C parameter takes effect only in
the low partial pressure region (or low R.H.), whereas
the behavior is dominated by )1log( p−α as p
approaches unity (or 100%R.H.).A first comparison
can be done as shown in Figure 2.
Figure 2 Comparison between adsorption and desorption
process with their respective t-curves (nm),
(adsorbed/desorbed) layer H2O thickness versus %R.H.
The Figure 2 shows the t-curve, (adsorbate multilayer
thickness t, during an adsorption and desorption
cycle, layer thickness versus x the partial pressure
x=p/ps, i.e., for H2O, R.H(% percent relative
humidity in a dry N2 ), in the case of an air-
contaminated gold surface covered a silicon wafer
(Au), film 50nm-thick film).It reveals a very
4. 4
contaminated surface state with D~2.6.
Figure 3 After cleaning, the Au surface becomes
hydrophobic and Vm (monolayer coverage) is10 times
lower, i.e., quite no adsorption occurs at 25°C
The situation becomes very different after a standard
surface clean. The adsorption curve reveals a very
low adsorption as shown in Figure 2, the monolayer
coverage Vm, turns 10 times lower. The surface
become hydrophobic (contact angle Θ=80°), such as
no adsorption phenomena occurs at 25°C.Only low
temperature data could reveal the fractal character of
this surface. The registered monolayer coverage
remains of the same order of magnitude as the size of
the H2O molecule such as the fitted parameter is
clearly without physical meaning
Table 1 The continuous curves are calculated from equation
(3) with α=3-D and parameters used in Figure 1.
Vm Cm D sigma
adsorption 3.19474 0.11395 2.6777 0.0460014
desorption 3.00895 0.16779 2.6748 0.0072466
aft.Clean 0.32 7.65 2.91 0.00029
3.1The effects of surface contamination and also
the dimensionality character (D value) Surface data
from three different sample are reported (in Figure 4
together with Table 2 for comparison:
i) A standard silicon wafer Si with its native oxide
(2.5nm thick) gives the most important adsorption t-
curve amplitude (filled circle in Figure 4) but
measured in fact by ethanol adsorption at 15°C.This
explains the large value of the monolayer capacity
Cm.(T). This is why experiments should be at lower
temperature because p/ps low partial pressure scale
and the t-curve magnitude are enhanced. A native
oxide exposed to ambient atmosphere, reveals a
surface very hydrophilic and a very low contact angle
θ~12 °, with no roughness( D~1.96), ii) A
germanium, Ge, wafer (2mm thick Ge slab from
foundry mechanically polished, ) measured only by
EPA at 25°C, (the filled squares in Figure 4). Here the
dimension: D~2.4. This type of wafer has a higher
roughness than epitaxial the Ge pseudo-substrate
(epitaxied Ge/SiO2/Si sample).as seen with the next
case:iii)an epitaxied layer on oxide SiO2 (100nm
thick) on a Si substrate,( filled triangles in Figure 4, ,
provides the lowest adsorption rate Cm~40, with
values for D ~ 2, (1.9 which is within the order of
these parameters determination accuracy.)
Figure 4 t-curves for .a native oxide Si (filled circles),a
Ge (filled squares), with an epitaxial Ge (filled ∆).
Table 2.The parameters extracted from equation (3) from a
nonlinear curve fit
Material sample Vm Cm D σ θ
0.445 88.48 2 0.0022 12
GeSiO2 clean 0.043 60.58 1.9 0.0002
Ge/SiO2 0.055 45.69 1.8 0.0019 28
Ge 0.392 16.71 2.2 0.0004 (?)
SiO2eth 15°C
The comparison , finally between two hafnia (HfO2),
MOCVD deposited, thin oxides as deposited at low
temperature 400-550°C very promising since the
comparison of the t-curve leaves a quite unexpected
behavior. The results are reproduced in Figure5
together with the Table 3
Figure 5 The comparison, between two hafnia films,2 and
6nm thick oxide on silicon wafer repectively deposited at
temperature 400 and 550°C.
5. 5
Table 3 fitted parameters in the case of HfO2 high k
materials ,σ is a fit mean square error (mse) and θ is the
measured contact angle
ID Vm Cm D σ θ
HfO2 2nm 0.772 0.128 2.402 0.003 q < 20
HfO2 6nm 0.924 2.62 2.999 0.001 66
These isotherms are clearly different demonstrate that
a drastic change in the surface properties occurred. If
the thinner sample (2nm-thick), has a quite classical
behavior, the 6nm-thick HfO2 film shows a definite
tri dimensional character possibly more seen as a
volume than as a surface adsorption. This indicates
the presence of open micro porosity in the film. To
our knowledge, this assumption has not been yet
verified. Both the contact angle, the monolayer
coverage and monolayer capacity increase,( Table 3).
4Conclusions. With the high sensitivity of today’s
SE instruments, the fractal surface analysis appears as
a new potential development orientation to
characterize in a near future, a surface, modification
during a process,( etching, plasma, epitaxial films,..).
The basic system remains an adsorbate versatile, low
pressure, temperature controlled in situ SE
ellipsometer. However, to another extent, the use of
water molecule as adsorbate with an refined version
of the actual atmospheric water adsorption system
EPA is an easy method in the case of many inert
hydrophilic surfaces of the nanotechnology
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