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WATER INNOVATION: BRIDGING GAPS,
CREATING OPPORTUNITIES
27 AND 28 SEPTEMBER 2017
ALFÂNDEGA PORTO CONGRESS CENTRE
WATER AND THE CIRCULAR ECONOMY, PART 1 -
INDUSTRY
MINING WATER: POLLUTANT OR RESOURCE?
MONA ARNOLD
VTT TECHNICAL RESEARCH
CENTRE OF FINLAND
Mine water - a pollutant or a
resource?
Mona Arnold
VTT Technical Research Centre of Finland
312/10/2017 3
Discharges from mines – major worldwide problem
 50,000 km of rivers contaminated by these
discharges worldwide
 at least 8,000 km are in Europe
 Discharge from mines has been recognised
as the main cause of 7% of failures to
achieve the goals of the Water Framework
Directive
412/10/2017 4
What’s in there?
Anything (= everything) that the ore contains
and
process chemicals
Cu2+
Fe2+
Al3+
Zn2+
Mg2+
Ni2+
H2AsO4
Fe3+ PO4
2-
Cl-
As
Sb
Se
AsO4
2-
SO4
2-
REE
512/10/2017 5
Remove by precipitation
612/10/2017 6
Valorize the precipitate
End of waste?
Magnesium oxide Processing costs vs revenues?
Building boards Fulfil quality criteria set for virgin
materials
Application Precondition
Soil amendment/
fertiliser production
Max. concentration of hazardous
elements
712/10/2017 7
REE Recovery
SRBSulphate Sulphide
Y Sc Nd….
MeS
SO4
2-
H2S
812/10/2017 8
Pollutant or a resource?
TECHNOLOGY IS THERE√
 PROCESS ECONOMY IS THERE?
 LOCAL MARKET IS THERE?
Cu2+
Fe2+
Al3+
Zn2+
Mg2+
Ni2+
H2AsO4
Fe3+ PO4
2-
Cl-
As
Sb
Se
AsO4
2-
SO4
2-
• Price of virgin material?
• Avoid waste management costs
• Concentrations?
REE
TECHNOLOGY FOR BUSINESS

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Mining water: pollutant or resource?

  • 1. WATER INNOVATION: BRIDGING GAPS, CREATING OPPORTUNITIES 27 AND 28 SEPTEMBER 2017 ALFÂNDEGA PORTO CONGRESS CENTRE WATER AND THE CIRCULAR ECONOMY, PART 1 - INDUSTRY MINING WATER: POLLUTANT OR RESOURCE? MONA ARNOLD VTT TECHNICAL RESEARCH CENTRE OF FINLAND
  • 2. Mine water - a pollutant or a resource? Mona Arnold VTT Technical Research Centre of Finland
  • 3. 312/10/2017 3 Discharges from mines – major worldwide problem  50,000 km of rivers contaminated by these discharges worldwide  at least 8,000 km are in Europe  Discharge from mines has been recognised as the main cause of 7% of failures to achieve the goals of the Water Framework Directive
  • 4. 412/10/2017 4 What’s in there? Anything (= everything) that the ore contains and process chemicals Cu2+ Fe2+ Al3+ Zn2+ Mg2+ Ni2+ H2AsO4 Fe3+ PO4 2- Cl- As Sb Se AsO4 2- SO4 2- REE
  • 5. 512/10/2017 5 Remove by precipitation
  • 6. 612/10/2017 6 Valorize the precipitate End of waste? Magnesium oxide Processing costs vs revenues? Building boards Fulfil quality criteria set for virgin materials Application Precondition Soil amendment/ fertiliser production Max. concentration of hazardous elements
  • 7. 712/10/2017 7 REE Recovery SRBSulphate Sulphide Y Sc Nd…. MeS SO4 2- H2S
  • 8. 812/10/2017 8 Pollutant or a resource? TECHNOLOGY IS THERE√  PROCESS ECONOMY IS THERE?  LOCAL MARKET IS THERE? Cu2+ Fe2+ Al3+ Zn2+ Mg2+ Ni2+ H2AsO4 Fe3+ PO4 2- Cl- As Sb Se AsO4 2- SO4 2- • Price of virgin material? • Avoid waste management costs • Concentrations? REE