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Engineering Relations from Second Law
P M V Subbarao
Professor
Mechanical Engineering Department
AnEquationtoRegulateManufacturingProcesses…..
Industrial Use of Entropy Generation
• Entropy is negative concept emerged from negative laws.
• Low quality devices lead to high entropy generation and
vice versa.
• Cost of any operation is proportional to energy transactions
involved in the operation.
• Quality of a device is characterized by amount of entropy
generation, which cannot be directly translated into energy
transactions.
• Another qualifying parameter, which is proportional to
energy transactions with a positive nature is essential.
Manufacturing System as a Rate Process
mat
mat
mat
h
m
H 
 

pro
pro
pro
h
m
H 
 

scrap
scrap
scrap
h
m
H 
 

loss
env
MF
Q 

in
MF
PP
W 

in
MF
HS
Q 

mat
mat
mat
s
m
S 
 

scrap
MF
scrap
MF
scrap
MF s
m
S 
 

pro
pro
pro
s
m
S 
 

Capability of Resources Utilization by a
Manufacturing Processes
Rate Equations for Manufacturing Systems
scrap
pro
mat
MF
m
m
m
dt
dM


 


Conservation of Mass:
First Law of Thermodynamics:
in
MF
PP
pro
pro
scrap
scrap
MF
mat
mat
loss
env
MF
in
MF
HS
W
h
m
h
m
dt
dE
h
m
Q
Q


















Entropy as A Rate Equation
• The second law of thermodynamics was used to write the
balance of entropy for a infinitesimal variation for a finite
change.
• Here the equation is needed in a rate form so that a given
process can be tracked in time.
• Take the incremental change and divide by dt.
• We get
t
S
t
Q
T
t
dS gen
cm
d
d
d
d
d


1
• For a given control mass we may have more than one source of
heat transfer, each at a certain surface temperature (semi-
distributed situation).
The rate of entropy change is due to the flux of entropy into
the control mass from heat transfer and an increase due to
irreversible processes inside the control mass.
t
S
T
Q
t
dS gen
i
i
cm
d
d
d

 

Entropy Rate Equation for CV
Rate of change in entropy of a CV = Entropy in flow rate –Entropy
out flow rate + the flux of entropy into the control mass from heat
transfer + Rate of Entropy generation
gen
e
e
i
i
CV
S
T
Q
s
m
s
m
dt
dS 


 


 


Analysis of SSSF Adiabatic Work Transfer CVs
0


 
 gen
e
e
i
i
S
s
m
s
m 


CV
out
out
in
in W
gz
V
h
m
gz
V
h
m


























 
 2
2
2
2
SSSF: Conservation of mass




 out
in m
m
First Law :
First Law :
gen
i
i
e
e
S
s
m
s
m 

 
 

irr
i
i
e
e
S
s
m
s
m 

 
 

Visualization of Irreversibilities in Turbine
(Power Generating Machine)
h
s
Ideal work ws = hin – herev
Actual work wa = hin – heirr
pinlet
pExit
Process Efficiency of A Thermodynamic Device
• A device following a Reversible process will produce
maximum benefits for a specified amount of resources.
• Irreversible or actual devices generate relatively lower
magnitude of benefits.
• The level of this process irreversibility is also defined as
efficiency of a process or machine.
• Conventional thermodynamics used various such
parameters.
• For example, a machine is expected to follow an Isentropic
process. However, due to friction it may be following an
irreversible adiabatic or irreversible and heat loss process.
• This irreversibility is defined as Isentropic Efficiency.
Isentropic Efficiency of a Device
• Isentropic efficiency is defined for a process.
• This is the ratio of actual performance to Isentropic
performance of a machine.
• For power generation machines:
• Isentropic efficiency = Actual power output/Isentropic
power output.
• For Power consuming machines:
• Isentropic efficiency = Isentropic power input/Actual
Power input.
erev
in
eirr
in
turbine
iso
h
h
h
h



,

These definitions are case dependent and a separate definition is
to be developed for each application.
Power Consuming Device
A Generalized Model Of A Manufacturing System
Material Processing
System
Creation of Energy
Sources for Material
Processing System
Creation of Energy
Sources for
Manufacturing System
Manufacturing System
Material Processing
System Manufacturing System
Manufacturing System as a Rate Process
mat
MF
mat
MF
mat
MF h
m
H 
 

pro
MF
pro
MF
pro
MF h
m
H 
 

scrap
MF
scrap
MF
scrap
MF h
m
H 
 

loss
env
MF
Q 

in
MF
PP
W 

in
MF
HS
Q 

mat
MF
mat
MF
mat
MF s
m
S 
 

scrap
MF
scrap
MF
scrap
MF s
m
S 
 

pro
MF
pro
MF
pro
MF s
m
S 
 

Auxiliaries (to Manufacturing System) as a Thermodynamic
CV
raw
Mp
raw
MP
raw
MP h
m
H 
 

mat
MP
mat
MP
mat
MP h
m
H 
 

scrap
MP
scrap
MP
scrap
MP h
m
H 
 

loss
env
MP
Q 

in
MP
PP
W 

in
MP
HS
Q 

raw
Mp
raw
MP
raw
MP s
m
S 
 

scrap
MP
scrap
MP
scrap
MP s
m
S 
 

mat
MP
mat
MP
mat
MP s
m
S 
 

Power Plant for A Manufacturing System & Material
Processing System
Power Plant for
Manufacturing System &
Material Processing System
in
MP
PP
W 

in
MF
PP
W 

fuel
PP
fuel
PP
fuel
PP h
m
H 
 

air
PP
air
PP
air
PP h
m
H 
 

exhaust
PP
exhaust
PP
exhaust
PP h
m
H 
 

loss
env
PP
Q 

air
PP
air
PP
air
PP s
m
S 
 

fuel
PP
fuel
PP
fuel
PP s
m
S 
 

exhaust
PP
exhaust
PP
exhaust
PP h
m
S 
 

Heat Source for A Manufacturing System & Material
Processing System
Heat Generation Unit for
Manufacturing System &
Material Processing System
fuel
HS
fuel
HS
fuel
HS h
m
H 
 

air
HS
air
HS
air
HS h
m
H 
 

exhaust
HS
exhaust
HS
exhaust
HS h
m
H 
 

loss
env
HS
Q 

in
MP
HS
Q 

in
MF
HS
Q 

air
HS
air
HS
air
HS s
m
S 
 

fuel
HS
fuel
HS
fuel
HS s
m
S 
 

exhaust
HS
exhaust
HS
exhaust
HS s
m
S 
 


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mcl141-36.ppt

  • 1. Engineering Relations from Second Law P M V Subbarao Professor Mechanical Engineering Department AnEquationtoRegulateManufacturingProcesses…..
  • 2. Industrial Use of Entropy Generation • Entropy is negative concept emerged from negative laws. • Low quality devices lead to high entropy generation and vice versa. • Cost of any operation is proportional to energy transactions involved in the operation. • Quality of a device is characterized by amount of entropy generation, which cannot be directly translated into energy transactions. • Another qualifying parameter, which is proportional to energy transactions with a positive nature is essential.
  • 3. Manufacturing System as a Rate Process mat mat mat h m H     pro pro pro h m H     scrap scrap scrap h m H     loss env MF Q   in MF PP W   in MF HS Q   mat mat mat s m S     scrap MF scrap MF scrap MF s m S     pro pro pro s m S     Capability of Resources Utilization by a Manufacturing Processes
  • 4. Rate Equations for Manufacturing Systems scrap pro mat MF m m m dt dM       Conservation of Mass: First Law of Thermodynamics: in MF PP pro pro scrap scrap MF mat mat loss env MF in MF HS W h m h m dt dE h m Q Q                  
  • 5. Entropy as A Rate Equation • The second law of thermodynamics was used to write the balance of entropy for a infinitesimal variation for a finite change. • Here the equation is needed in a rate form so that a given process can be tracked in time. • Take the incremental change and divide by dt. • We get t S t Q T t dS gen cm d d d d d   1
  • 6. • For a given control mass we may have more than one source of heat transfer, each at a certain surface temperature (semi- distributed situation). The rate of entropy change is due to the flux of entropy into the control mass from heat transfer and an increase due to irreversible processes inside the control mass. t S T Q t dS gen i i cm d d d    
  • 7. Entropy Rate Equation for CV Rate of change in entropy of a CV = Entropy in flow rate –Entropy out flow rate + the flux of entropy into the control mass from heat transfer + Rate of Entropy generation gen e e i i CV S T Q s m s m dt dS           
  • 8. Analysis of SSSF Adiabatic Work Transfer CVs 0      gen e e i i S s m s m    CV out out in in W gz V h m gz V h m                              2 2 2 2 SSSF: Conservation of mass      out in m m First Law : First Law : gen i i e e S s m s m        irr i i e e S s m s m       
  • 9. Visualization of Irreversibilities in Turbine (Power Generating Machine) h s Ideal work ws = hin – herev Actual work wa = hin – heirr pinlet pExit
  • 10. Process Efficiency of A Thermodynamic Device • A device following a Reversible process will produce maximum benefits for a specified amount of resources. • Irreversible or actual devices generate relatively lower magnitude of benefits. • The level of this process irreversibility is also defined as efficiency of a process or machine. • Conventional thermodynamics used various such parameters. • For example, a machine is expected to follow an Isentropic process. However, due to friction it may be following an irreversible adiabatic or irreversible and heat loss process. • This irreversibility is defined as Isentropic Efficiency.
  • 11. Isentropic Efficiency of a Device • Isentropic efficiency is defined for a process. • This is the ratio of actual performance to Isentropic performance of a machine. • For power generation machines: • Isentropic efficiency = Actual power output/Isentropic power output. • For Power consuming machines: • Isentropic efficiency = Isentropic power input/Actual Power input. erev in eirr in turbine iso h h h h    ,  These definitions are case dependent and a separate definition is to be developed for each application.
  • 13. A Generalized Model Of A Manufacturing System Material Processing System Creation of Energy Sources for Material Processing System Creation of Energy Sources for Manufacturing System Manufacturing System
  • 15. Manufacturing System as a Rate Process mat MF mat MF mat MF h m H     pro MF pro MF pro MF h m H     scrap MF scrap MF scrap MF h m H     loss env MF Q   in MF PP W   in MF HS Q   mat MF mat MF mat MF s m S     scrap MF scrap MF scrap MF s m S     pro MF pro MF pro MF s m S    
  • 16. Auxiliaries (to Manufacturing System) as a Thermodynamic CV raw Mp raw MP raw MP h m H     mat MP mat MP mat MP h m H     scrap MP scrap MP scrap MP h m H     loss env MP Q   in MP PP W   in MP HS Q   raw Mp raw MP raw MP s m S     scrap MP scrap MP scrap MP s m S     mat MP mat MP mat MP s m S    
  • 17. Power Plant for A Manufacturing System & Material Processing System Power Plant for Manufacturing System & Material Processing System in MP PP W   in MF PP W   fuel PP fuel PP fuel PP h m H     air PP air PP air PP h m H     exhaust PP exhaust PP exhaust PP h m H     loss env PP Q   air PP air PP air PP s m S     fuel PP fuel PP fuel PP s m S     exhaust PP exhaust PP exhaust PP h m S    
  • 18. Heat Source for A Manufacturing System & Material Processing System Heat Generation Unit for Manufacturing System & Material Processing System fuel HS fuel HS fuel HS h m H     air HS air HS air HS h m H     exhaust HS exhaust HS exhaust HS h m H     loss env HS Q   in MP HS Q   in MF HS Q   air HS air HS air HS s m S     fuel HS fuel HS fuel HS s m S     exhaust HS exhaust HS exhaust HS s m S    