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Martensitic transformation
Habit plane
This shape to reduce the strain energy
Habit planes are irrational therefore approximated
A homogeneous deformation of the lattice of the austenite occurs to change it to
the lattice of the martensite
A diffusion less transformation occurs due to either too quick transformation
(steel) or due to too slow transformation (iron nickel alloy at 5 K)
A homogeneous deformation of the lattice of
the austenite occurs to change it to the lattice
of the martensite
No compositional change during transformation therefore Aust. And martensite
compositions are same which can be confirmed by EDS analysis
NW vs KS OR
KS relation
KS OR is 5.26 more rotation in NW so that (111) α matches with the (011) γ
In both cases, (011)α || (111) γ
Importance of glissile disl. In martensite
transformation
As glissile dislocations moves, it diffuses one part of the crystal into other
hence shape change occur
As glissile dislocations are necessary requirements for the martensitic
transformation
Do not require diffusion to
move
Require diffusion to move
Sessile Jogs
Sets cuts each other
The other part pin both
dislocations to move
This phen. Is imp. In work
hardening
As glissile dislocations can not contain more than one set of the
Dislocations
The only set of dislocations line must lie along the invariant line
Thefore interfacial energy per unit area is very small
Shear deformation
γ α’
Martensitic transformation
Martensitic transformation is both
volume change as well as shear
deformation
Invariant plane
Shear strain is high
Volume change is low
Strain energy for martensite transformation
C – thickness of the plate
Therefore to minimise the energy
thickness is very small
s; shear strain
Reason for thin plate shape in martensite
and mechanical twins
Although overall shear strain
is uniform but since invariant
plane is unchanged and to
minimise the strain energy,
at the corner it takes the
shape of thin plate
• Due to a similar reason, the mechanical twin forms plate like structure,
1. since invariant plane is unchanged at corner displacement is minimum
for same shear strain, 2. To minimises the strain energy
• while the annealing twins forms the slab like structure because they
don’t have to accommodate the deformation
γ-α or α’ Deformation (Bain strain)
Same Lattice but refined the structure as BCT
FCC
Compression
Expansion
But we can not get invariant plane from this loading
Therefore a slight rigid body rotation is
required to match oa and oa’ to get
invariant plane
Slipped and twinned martensite
Twins and martensite
HKDH Bhadesia
Twin involves the shearing
of close pack plane
Twin involves the shearing
of close pack plane
Crystal structure of the
twin is same as the crystal
str. Of the matrix/ Only
orientation changes
Mod-01 order-disorder transformation
Ms depends upon the carbon
content, alloying elemnt and
grain size
Smaller the gap b/w T0 and
TMs, smaller the shear is
requires

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MARTENSITIC_TRANSFORMATION

  • 1.
  • 2. Martensitic transformation Habit plane This shape to reduce the strain energy Habit planes are irrational therefore approximated A homogeneous deformation of the lattice of the austenite occurs to change it to the lattice of the martensite A diffusion less transformation occurs due to either too quick transformation (steel) or due to too slow transformation (iron nickel alloy at 5 K) A homogeneous deformation of the lattice of the austenite occurs to change it to the lattice of the martensite No compositional change during transformation therefore Aust. And martensite compositions are same which can be confirmed by EDS analysis
  • 3. NW vs KS OR KS relation KS OR is 5.26 more rotation in NW so that (111) α matches with the (011) γ In both cases, (011)α || (111) γ
  • 4. Importance of glissile disl. In martensite transformation As glissile dislocations moves, it diffuses one part of the crystal into other hence shape change occur As glissile dislocations are necessary requirements for the martensitic transformation Do not require diffusion to move Require diffusion to move Sessile Jogs Sets cuts each other The other part pin both dislocations to move This phen. Is imp. In work hardening As glissile dislocations can not contain more than one set of the Dislocations
  • 5.
  • 6. The only set of dislocations line must lie along the invariant line Thefore interfacial energy per unit area is very small Shear deformation γ α’
  • 7. Martensitic transformation Martensitic transformation is both volume change as well as shear deformation Invariant plane Shear strain is high Volume change is low Strain energy for martensite transformation C – thickness of the plate Therefore to minimise the energy thickness is very small s; shear strain
  • 8. Reason for thin plate shape in martensite and mechanical twins Although overall shear strain is uniform but since invariant plane is unchanged and to minimise the strain energy, at the corner it takes the shape of thin plate • Due to a similar reason, the mechanical twin forms plate like structure, 1. since invariant plane is unchanged at corner displacement is minimum for same shear strain, 2. To minimises the strain energy • while the annealing twins forms the slab like structure because they don’t have to accommodate the deformation
  • 9. γ-α or α’ Deformation (Bain strain) Same Lattice but refined the structure as BCT FCC
  • 10. Compression Expansion But we can not get invariant plane from this loading Therefore a slight rigid body rotation is required to match oa and oa’ to get invariant plane
  • 11. Slipped and twinned martensite
  • 13. Twin involves the shearing of close pack plane Twin involves the shearing of close pack plane Crystal structure of the twin is same as the crystal str. Of the matrix/ Only orientation changes
  • 14. Mod-01 order-disorder transformation Ms depends upon the carbon content, alloying elemnt and grain size Smaller the gap b/w T0 and TMs, smaller the shear is requires