Chapter 5 of 'The Monk Who Sold His Ferrari' discusses the 'performance gap' where knowledge fails to convert into action due to distractions and lack of motivation. It emphasizes the importance of linking purpose to paychecks to inspire and engage employees, fostering a sense of connection to a higher cause. Leaders are urged to refine their vision, align it with their team's values, and empower their people to reach their full potential for organizational success.