Google hacking involves using Google search operators and modifiers to identify vulnerabilities on websites. The document provides examples of common operators like cache:, link:, related:, and site: and shows how they can be combined with keywords and modifiers like intitle:, inurl:, and filetype: to search for specific types of sensitive information like default login pages, backup files, and documents containing PII data. It encourages experimenting with different operator combinations to uncover interesting search results.