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INTRODUCTION
     Since antiquity, pure gold has been a

metal of special intrinsic and practical

value. From the dawn of civilization until

the present time, man has utilized gold in

some form or other in the practice of

dentistry.
In its pure form, gold has the unusual
ability to cohere to it self at room
temperature. Gold is quite soft, and in a
compressible form, increments can be
welded by pressure into a solid metal
mass.
Another unique feature about gold is it

inertness. Under most conditions it does

not tarnish, corrode or stain.
   Its chief disadvantages are its color, high

    thermal conductivity(53.20), and technical

    difficulties in forming a dense restoration.

    It has one of the highest densities of all

    elements (19.3 g/cm3)
Indications;



 Incipient carious lesions
     Class I and pits
      Class V
      Class III
 Erosions
 Repair of defective cast margins
Advantages:       
   No tarnish and corrosion

   Insoluble in oral cavity

   Good adaptation to cavity walls

   High wear resistance
Disadvantages

Colour

Manipulation

Thermal conductivity
They are Classified into three categories:
II. Foil
   A. Sheet
       1. Cohesive
       2. Noncohesive
   B. Ropes
   C. Cylinders
   D. Laminated foil
   E. Platinized foil
I. Electrolytic precipitate

   A. Mat gold

   B. Mat foil (mat gold plus gold foil)

   C. Gold – calcium alloy
III Powdered gold (encapsulated gold
powder)
Gold Foil   (    Robert
Woffendale 1795)

Oldest of all products standard No. 4 Gold foil

4 x 4 inch sheets weight 4 grains (0.259g) and

0.51µm thick

No. 3 weight 3 grains – 3 µm thick.
Cohesive          -    Noncohesive

Gold:
     Gold attracts gases and any adsorbed gas

     film prevents intimate atomic contact

required for cold welding

-     Manufactures supply free of surface
NON COHESIVE FOIL:
Majority are provided with an adsorbed
protective gas   film like ammonia
-
Prevents premature cohesion of sheets
that may come into contact. Volatile film
is removed by heating to restore the
cohesive character of the foil.
Gold Foil Cylinders:
Formed by rolling cut segments of

No. 4 foils into a desired width

- 3.2mm, 4.8mm, 6.4mm using modified

No.22 tapestry needle.
Preformed Gold Foils:
      Cylinders and ropes are now
available in      preformed shapes made
from   No.4    foil    which    has   been
‘carbonised’ or corrugated
• Historical interest Great Chicago fire of
1871
Platinised Gold Foil:
 It is a laminated structure can be
  produced in
  one of the 2 ways.
4. 2 sheets of No.4 pure gold foil and a
  layer of pure platinum foil sandwiched
  between there can be hammered until
  the thickness of No.4 sheet is obtained.
2. Layers of platinum and gold can
  be bonded together by cladding
  process      during   the   rolling
  operation.

  Objective of adding platinum:

  Increases hardness and wear
  resistance
Electrolytic Precipitate:
    Crystalline gold powder formed by
     electrolytic precipitation.
     Powder is formed by sintering at an
elevated temp. well below the melting point of
gold, it causes self diffusion         between
particles where they are in contact.
Mat Gold (      Rule 1937)
     Is a crystalline, electrolytically
precipitated gold form that is formed
into strips .Preferred ease in building
up the internal bulk, more easily
compacted within and adapted to the
retentive portion    of the prepared
cavity.
Disadvantages:

    Because it is loosely packed it is

friable and contain numerous void

spaces.
    2- material technique mat is
covered with a veneer of foil.
Mat foil
Sandwich of electrolytic precipitated
gold powder between sheets of No.3
gold foil

Purpose – Try to eliminate the need
to veneer the restoration with a layer of
foil
No longer Marketed
Alloyed electrolytic
precipitate
The   newest    forms   of     electrolytic
precipitate electro alloy RV is alloyed
with calcium. Calcium content of the
finished product is about 1%
      Purpose is to produce stronger
restoration by dispersion strengthening
Powdered Gold:

1st used in early 1960’s

Gold powder was enclosed in No. 3

gold foil .maximum particle size is 74

µm Avg 15 µm
The     atomized      and      chemically
precipitated powders are

1st mixed with a soft wax to form pellets

These wax – gold pellets wrapped with
foil
Removal of Surface
Impurities:

With the exception of non cohesive
gold the DFGs are received by the
dentist in a cohesive condition.


During storage and packaging they are
exposed to the atmosphere
It is necessary to heat the foil or pellet
before it is carried into the prepared
cavity. It is called

Annealing, heat treatment, degassing a
more appropriate term is desorption. It
is essential to achieve a cohesive mass.
Chamois finger tips should be worn by the

dentist   to   protect   the   gold   from

contamination.
Proper desorption is a matter of heating
long enough at a temperature that removes
gases and in case of powdered gold burns
away the wax.
Temperatures in the range of 600-13000F
must be produced
Under heating should be avoided because it
does not adequately remove the impurities
Overheating should be avoided because
excessive sintering causes the material to
become more stiffer less ductile and
difficult to condense.
-     Too Long time
-    Too high temperature
Temperatures below 3150C are inadequate
The Gold can be heated in
two ways
1.Flame Heating




Flame annealing, held       The alcohol flame
near the top of the         is transparent; the
flame,                      flame from the
                            pellets is visible
2.Electric Annealing



           Pellets are being heated on

           a tray
When heating in bulk on a tray, excessive
amounts should be avoided, since the
difficulties   arising   from   prolonged
heating can arise, from repeated heating
as well.
Handle the pieces with stain less steel wire

points that will not contaminate the gold.

Flame desorption occurs when the gold

segment has exhibited a dull red glow.
The fuel may be alcohol or gas but
alcohol is preferred because there is less
danger of contamination.


Alcohol must be pure methanol or
ethanol without colorants or additives.
Advantages of flame desorption


3. Ability to select a piece of
   appropriate size.
4. Desorption of only these pieces used.
5. Less exposure to contamination.
6. Less danger of over sintering
DISADVANTAGES OF ELECTRIC ANNEALING

-   Pellets may stick together, if the tray is
    moved.
-   Air currents may effect the uniformity of
    heating
-   Difficult to anneal appropriate amounts of
    gold.
-   Oversintering.

-   Greater exposure to contamination.

-   Size selection among the pieces of

    desorbed gold is limited.
COMPACTION OF DIRECT FILLING
  GOLD

Condensation is the procedure used to

condense and harden gold inside the cavity

preparation

2 main process

6. Welding

7. Wedging
Welding:

Forming atomic bonds between pellets or

layer as result of condensation.
Wedging refers to the pressurized

adaptation of the gold form within the

space between the tooth structure walls

that   have    been   slightly   deformed

elastically.
Straight points are cut in the prepared

cavity and the 1st pieces of foil are

wedged into these areas
COMPACTION:

           Can be done by:

3. Hand mallet.

4. Pneumatic vibratory condensers.

5. Electrically driven condensers.
a. Nichrome wire used for carrying gold;
b. Pneumatic condenser
c. Detachable condensing tins
PHYSICAL PROPERTIES OF COMPACTED GOLD



1. Strength and Hardness:

BHN of pure gold is 25. During
condensation its hardness rises to 75.
Tensile strength rises from 19000 psi to
32000 psi.

Yield strength rises from 0 to 30,000 psi
3) Density:

Density of pure gold is 19.3. Density of

well compacted direct gold is 16.5 cm3

The difference is due to the presence of

porosity and voids

4. Melting point of Gold-1063O C
5.Tarnish and Corrosion Resistance:
Is good, there is very little marginal
leakage between the filling and cavity
walls, if the compaction is good.
6. It dissolves in aqua regia
7. high thermal conductivity (.710cal /sec
6 Biocompatibility:

            It is biocompatible. Produces
only   a   minimal    pulpal    response,   if
compacted     properly.   The      technique,
however, does involve a certain amount of
trauma to the tooth and its supporting
tissues.
Gold in Dentistry: A History of Direct Gold Restorations
Gold in Dentistry: A History of Direct Gold Restorations

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Gold in Dentistry: A History of Direct Gold Restorations

  • 1.
  • 3. Since antiquity, pure gold has been a metal of special intrinsic and practical value. From the dawn of civilization until the present time, man has utilized gold in some form or other in the practice of dentistry.
  • 4. In its pure form, gold has the unusual ability to cohere to it self at room temperature. Gold is quite soft, and in a compressible form, increments can be welded by pressure into a solid metal mass.
  • 5. Another unique feature about gold is it inertness. Under most conditions it does not tarnish, corrode or stain.
  • 6. Its chief disadvantages are its color, high thermal conductivity(53.20), and technical difficulties in forming a dense restoration. It has one of the highest densities of all elements (19.3 g/cm3)
  • 7. Indications;  Incipient carious lesions Class I and pits Class V Class III  Erosions  Repair of defective cast margins
  • 8. Advantages:   No tarnish and corrosion  Insoluble in oral cavity  Good adaptation to cavity walls  High wear resistance
  • 10.
  • 11. They are Classified into three categories: II. Foil A. Sheet 1. Cohesive 2. Noncohesive B. Ropes C. Cylinders D. Laminated foil E. Platinized foil
  • 12. I. Electrolytic precipitate A. Mat gold B. Mat foil (mat gold plus gold foil) C. Gold – calcium alloy
  • 13. III Powdered gold (encapsulated gold powder)
  • 14. Gold Foil ( Robert Woffendale 1795) Oldest of all products standard No. 4 Gold foil 4 x 4 inch sheets weight 4 grains (0.259g) and 0.51µm thick No. 3 weight 3 grains – 3 µm thick.
  • 15. Cohesive - Noncohesive Gold: Gold attracts gases and any adsorbed gas film prevents intimate atomic contact required for cold welding - Manufactures supply free of surface
  • 16. NON COHESIVE FOIL: Majority are provided with an adsorbed protective gas film like ammonia - Prevents premature cohesion of sheets that may come into contact. Volatile film is removed by heating to restore the cohesive character of the foil.
  • 17. Gold Foil Cylinders: Formed by rolling cut segments of No. 4 foils into a desired width - 3.2mm, 4.8mm, 6.4mm using modified No.22 tapestry needle.
  • 18. Preformed Gold Foils:  Cylinders and ropes are now available in preformed shapes made from No.4 foil which has been ‘carbonised’ or corrugated • Historical interest Great Chicago fire of 1871
  • 19. Platinised Gold Foil:  It is a laminated structure can be produced in one of the 2 ways. 4. 2 sheets of No.4 pure gold foil and a layer of pure platinum foil sandwiched between there can be hammered until the thickness of No.4 sheet is obtained.
  • 20. 2. Layers of platinum and gold can be bonded together by cladding process during the rolling operation. Objective of adding platinum: Increases hardness and wear resistance
  • 21. Electrolytic Precipitate:  Crystalline gold powder formed by electrolytic precipitation.  Powder is formed by sintering at an elevated temp. well below the melting point of gold, it causes self diffusion between particles where they are in contact.
  • 22. Mat Gold ( Rule 1937) Is a crystalline, electrolytically precipitated gold form that is formed into strips .Preferred ease in building up the internal bulk, more easily compacted within and adapted to the retentive portion of the prepared cavity.
  • 23. Disadvantages:  Because it is loosely packed it is friable and contain numerous void spaces.  2- material technique mat is covered with a veneer of foil.
  • 24. Mat foil Sandwich of electrolytic precipitated gold powder between sheets of No.3 gold foil Purpose – Try to eliminate the need to veneer the restoration with a layer of foil No longer Marketed
  • 25. Alloyed electrolytic precipitate The newest forms of electrolytic precipitate electro alloy RV is alloyed with calcium. Calcium content of the finished product is about 1% Purpose is to produce stronger restoration by dispersion strengthening
  • 26. Powdered Gold: 1st used in early 1960’s Gold powder was enclosed in No. 3 gold foil .maximum particle size is 74 µm Avg 15 µm
  • 27. The atomized and chemically precipitated powders are 1st mixed with a soft wax to form pellets These wax – gold pellets wrapped with foil
  • 28. Removal of Surface Impurities: With the exception of non cohesive gold the DFGs are received by the dentist in a cohesive condition. During storage and packaging they are exposed to the atmosphere
  • 29. It is necessary to heat the foil or pellet before it is carried into the prepared cavity. It is called Annealing, heat treatment, degassing a more appropriate term is desorption. It is essential to achieve a cohesive mass.
  • 30. Chamois finger tips should be worn by the dentist to protect the gold from contamination.
  • 31. Proper desorption is a matter of heating long enough at a temperature that removes gases and in case of powdered gold burns away the wax. Temperatures in the range of 600-13000F must be produced Under heating should be avoided because it does not adequately remove the impurities
  • 32. Overheating should be avoided because excessive sintering causes the material to become more stiffer less ductile and difficult to condense. - Too Long time - Too high temperature Temperatures below 3150C are inadequate
  • 33. The Gold can be heated in two ways 1.Flame Heating Flame annealing, held The alcohol flame near the top of the is transparent; the flame, flame from the pellets is visible
  • 34. 2.Electric Annealing Pellets are being heated on a tray
  • 35. When heating in bulk on a tray, excessive amounts should be avoided, since the difficulties arising from prolonged heating can arise, from repeated heating as well.
  • 36. Handle the pieces with stain less steel wire points that will not contaminate the gold. Flame desorption occurs when the gold segment has exhibited a dull red glow.
  • 37. The fuel may be alcohol or gas but alcohol is preferred because there is less danger of contamination. Alcohol must be pure methanol or ethanol without colorants or additives.
  • 38. Advantages of flame desorption 3. Ability to select a piece of appropriate size. 4. Desorption of only these pieces used. 5. Less exposure to contamination. 6. Less danger of over sintering
  • 39. DISADVANTAGES OF ELECTRIC ANNEALING - Pellets may stick together, if the tray is moved. - Air currents may effect the uniformity of heating - Difficult to anneal appropriate amounts of gold.
  • 40. - Oversintering. - Greater exposure to contamination. - Size selection among the pieces of desorbed gold is limited.
  • 41. COMPACTION OF DIRECT FILLING GOLD Condensation is the procedure used to condense and harden gold inside the cavity preparation 2 main process 6. Welding 7. Wedging
  • 42. Welding: Forming atomic bonds between pellets or layer as result of condensation.
  • 43. Wedging refers to the pressurized adaptation of the gold form within the space between the tooth structure walls that have been slightly deformed elastically.
  • 44. Straight points are cut in the prepared cavity and the 1st pieces of foil are wedged into these areas
  • 45. COMPACTION: Can be done by: 3. Hand mallet. 4. Pneumatic vibratory condensers. 5. Electrically driven condensers.
  • 46. a. Nichrome wire used for carrying gold; b. Pneumatic condenser c. Detachable condensing tins
  • 47. PHYSICAL PROPERTIES OF COMPACTED GOLD 1. Strength and Hardness: BHN of pure gold is 25. During condensation its hardness rises to 75. Tensile strength rises from 19000 psi to 32000 psi. Yield strength rises from 0 to 30,000 psi
  • 48. 3) Density: Density of pure gold is 19.3. Density of well compacted direct gold is 16.5 cm3 The difference is due to the presence of porosity and voids 4. Melting point of Gold-1063O C
  • 49. 5.Tarnish and Corrosion Resistance: Is good, there is very little marginal leakage between the filling and cavity walls, if the compaction is good. 6. It dissolves in aqua regia 7. high thermal conductivity (.710cal /sec
  • 50. 6 Biocompatibility: It is biocompatible. Produces only a minimal pulpal response, if compacted properly. The technique, however, does involve a certain amount of trauma to the tooth and its supporting tissues.