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HIGH-TECH THERMOPLASTICS AND SUSTAINABLE SOLUTIONS
FOR EV CHARGING
Enabling Electrification with Celanese
Dr. Gulnaz Idiyatullina
EV Charging Infrastructure UK 2022
27 – 28 June 2022
CentrEd at ExCeL
London, UK
Celanese Corporation
Agenda
► Offering the broadest portfolio of thermoplastics and
sustainable solutions to the EVSE market
► EV charging infrastructure market and regulatory
information
► Engineered materials for EV charging applications
External 2
Celanese Corporation
Celanese Corporation Overview
► Global headquarters in Dallas, Texas, USA
► $8.5 billion in net sales in 2021
► Number 477 on the 2021 FORTUNE 500 list
► Approximately 8,500 employees globally
► 40+ manufacturing facilities; operations in 19 countries around the world
► Three leading businesses: Engineered Materials, Acetyls and Acetate Tow
► Innovation is at the core of our differentiated business model
External 3
We are a global chemical and specialty materials company that engineers and
manufactures a variety of products essential to everyday living.
Celanese Corporation
Serving a Broad Set of Industries
External 4
Other
11%
Construction
3%
Paints & Coatings
13%
Automotive
17%
Consumer &
Medical
Applications
11%
Filter Media
13%
Consumer &
Industrial
Adhesives
11%
Textiles
2%
Food &
Beverage
3%
Chemical Additives
2%
Paper &
Packaging
6%
Industrial Performance
Applications
9%
Celanese Corporation
Integrated Product Portfolio
External 5
Celanese Corporation
Edmonton, AB
Bay City, TX
Cangrejera, Mexico
Frankfurt,
Germany
Singapore
Al Jubail, SA
Nanjing, China
Narrows, VA
Clear Lake, TX
Boucherville, QC
Enoree, SC
Shelby, NC
Winona, MN
Suzano, Brazil
Nantong, China KEP, South Korea
Kunming, China
Geleen, Netherlands
Perstorp, Sweden
Spondon, UK
Zhuhai,China
Lanaken, Belgium
Joint Ventures
Dallas, TX
Auburn Hills, MI
Sulzbach, Germany
Budapest, Hungary
Oberhausen, Germany
Kaiserslautern, Germany
Wilmington, NC
Bishop, TX
Global Manufacturing Locations (including joint ventures)
Shanghai, China
Regional HQs
Amsterdam, Netherlands
Suzhou, China
Campo Bom, Brazil
Silao, Mexico
Florence, KY
Utzenfeld, Germany
Wehr, Germany
Forli, Italy
Ferrara, Italy
Evansville, IN
Silvassa,
India
Sales/Regional Offices
Sempach and
Moosleerau,
Switzerland Shanghai, China
Pensacola, FL
Newport, UK
External 6
Celanese Corporation
Celanese Portfolio
External 7
2021 Net Sales: $8.5 Billion
Automotive / E-Mobility
Electrical & Electronics
Industrial
Consumer
Medical
Food & Beverages
Other
Celanese has one of the broadest portfolios spanning all thermoplastic classes
Celanese Corporation
Engineered Materials Sustainable Solutions
8
external
Bio-mass balance
ECO-B
Products derived from
biological feedstock like
forestry and agricultural waste
materials or renewable
domestic waste using a mass
balance approach
Recycled content
ECO-R
Products that contain post-
industrial or post-consumer
recycled materials while still
maintaining consistency,
quality and performance
End-of-life
Products that are biodegradable
and compatible with waste
streams that go into composting
Carbon capture
ECO-CC
Products based on CO2
emissions converted into
methanol as building block for
downstream products
To learn more, view our sustainability website: www.celanese.com/corporate-sustainability-strategy
Celanese Corporation
Recycled Content – ECO-R
► Post-Industrial Recycle (PIR):
Derived from separated industrial waste streams
Generally higher quality due to more defined origin
► Post-Consumer Recycle (PCR):
Derived from separated consumer waste streams
Typically, higher variability and levels of contamination
► Internal scraps:
Derived from internal scraps incl compounded product
Generally, no longer recognized as recycling
Raw materials
Long-term suppliers with proven history and robust systems to
maximize quality, minimize variability and ensure traceability
Finished products
► Compensates performance drop from mechanical recycling step
► Product very close but not identical to prime (no drop in)
► Expanding offer beyond legacy unspecified recycled content to
ECO-R range with specified recycled content
Material Recycle Sources Available Product Brands
PA PIR carpet, textile, industrial fiber now Ecomid® PA ECO-R
PBT/PET PCR beverage bottles, packaging
scrap
now Impet® PET ECO-R, Celanex® PBT/PET ECO-R
PP PIR textile fiber, non-woven 2Q 22 Tecnoprene® PP ECO-R
TPV PCR PP now Santoprene® TPV ECO-R
9
external
Celanese Corporation
BioMass Balance – ECO-B
ECO-B concept
► Bio-based feedstock using a bio-mass balance approach
► Independent 3rd party audited mass balance certification (ISCC+, RedCert2)
► Significant increase in renewable content and reduction of CO2 footprint vs standard fossil equivalents
► End products in identical quality and properties enable drop-in replacement
10
external
Material Available CO2 footprint reduction Renewable content
Bio-Mass Balance
feedstock
POM ECO-B 1Q 2021 up to 50% up to 97% Bio Methanol
Celanex® PBT ECO-B 2Q 2022 up to 45% up to 40% Bio BDO
GUR® UHMWPE ECO-B 3Q 2022 under evaluation up to 99% Bio Ethylene
Celanese Corporation
EV Charging Infrastructure
External 11
Power Transformation, Meter and Panel
➢ Distribution lines, substations
➢ Transformer
➢ Switchgear​
➢ Meter
➢ Panel, conduit/circuit, outlet
Station and Supply Equipment
➢ Charging columns and
wall box​
➢ Structural parts
➢ E&E components inside
➢ Thermal management parts
➢ Sealants
Charging Plug and Cable
➢ Charging plug and
socket
➢ Charging wire and cable
Celanese Corporation
Overview of EV Charging Standards
External 12
► AC Charging station UL2594
► DC Charging station UL 2202
► Wireless Charger UL 2750
► Cord sets UL 2594
► Offboard cable UL 2263
► Personnel protection equipment
UL 2231-1, UL 2231-2, NEC625(a),
SAE J1772
► Bidirectional Charging station
UL 9741
Celanese offer a broad material portfolio covering application requirements
► Onboard
‒ Batteries UL 2580
‒ Cable UL 2733
‒ Inverters UL 458A
‒ Motors UL 1004-1
‒ Chargers UL 2202
‒ Connectors UL 2734
► EV Inlets UL 2251, SAE J1772
‒ Plugs, socket-outlets, vehicle
connectors and vehicle inlets
EV Onboard Equipment
EV Chargers
Celanese Corporation
Engineered Materials for E-Mobility
Requirements for the Electric Powertrain
external 13
► Crash Resistance
► Electrical Insulation
► Hydrolysis Resistance
► Flame Retardancy
Battery Systems
► Electrical Insulation
► Flame Retardancy V0
► Hydrolysis Resistance
► Dimension Stability
High Voltage Connectors
High Voltage
Connectors
► Electrical Insulation
► Hydrolysis Resistance
► Dimension Stability
► Temperature Resistance
Electric Motors
► Temperature range
(-40°C to + 80°C)
► Hydrolytic/chemical resistance
► Thermal Conductivity (Passive
cooling)
► Toughness
Thermo-Management ► Crash Resistance
► Electrical Insulation
► Chemical Resistance
► Hydrolysis
Resistance
► EMI Shielding
Power Electronics
► Lightweight
► Chemical Resistance
► Dimensional Stability
► Low Warpage
Universal
Requirements
Celanese Corporation
Current Applications in EV Charging
External 14
LFRT PP - LCP - PCT - PA
PPA - TPC ET - POM
Charging Ports & Stations
• Electrical Isolation
• UV Stability
• Impact Resistance
• Flame Retardancy
Universal Requirements:
• Light-weighting
• Miniaturization
• Thermal Management
Circuit breaker
Frianyl® PA
Frianyl® XT PPA
Celanex® PBT
Vectra® LCP
Terminal blocks
Frianyl® PA
Electronics/
Controller
Frianyl® PA
Fusebox & holders
Frianyl® PA
Celanex® PBT
Power-Management
Frianyl® XT PPA
Vectra® LCP
Relays & Switches
Celanex® PBT
Frianyl® PA
Fortron® PPS
Power-Supply
Frianyl® PA
Frianyl® XT PPA
Thermal
Management
CoolPoly® TCP
Charger Plugs
& Sockets
Celanese Portfolio is used in most of the E-Mobility applications
Celanese Corporation
Charger Plugs Functional Requirements and Material Solutions
Celanese Portfolio offers a full range of plastics solutions
Image Source: Phoenix Contact
Relevant Material in Celanese Portfolio
Universal Requirements:
• Handling
• Safety
• Regulation conform UL & IEC • Impact resistance
• Electrical isolation
• Dimenstional stability
• Mechanical strength
• Flame retardant
• Temperature resistance
Socket & Mounting
Protection & Performance
PA - PBT
• Temperature resistance
• Electrical Isolation
• Dimensional Stability
• Durability
• Weatherability
• Aesthetics
Housing
Functionality & Protection
PA - PBT -TPV
PA - PBT -TPV
• Electrical isolation
• Flame Retardancy
• Heat Dissipation
• Media resistance to coolent
Thermal Management
Functionality & Performance
PPS - CoolPoly® TCP
External 15
Celanese Corporation
Elastic Components and Sealants Thermoplastic Elastomers
External 16
► High elastic recovery
► Chemical resistance
► Flex fatigue resistance
► High thermal and electric insulation, UL Listing
► Good abrasion resistance
► Good colorability (SEBS: translucent, transparent)
► Recyclability
► Soft touch and aesthetics
Santoprene™ TPV, Forprene® TPV; Laprene® SEBS
Technical Characteristics – Santoprene® TPV & Forprene® TPV
Hardness Range 20 ShA to 60 ShD
Operating Temperature Range -40 °C to 130 °C
Density Range <1.0 g/cm3
Technical Characteristics – Laprene® SEBS
Hardness Range 2 ShA to 60 ShD
Operating Temperature Range -50 °C to 120 °C
Density Range 0.90 g/cm3 to 1.20 g/cm3
grip
strain relief
cable
string
cap
Celanese Corporation
Leading Innovation in E-Mobility Lightweighting & EMI Shielding
HIGH
FLOW
Celanese’s high flow technology enables nominal
wall thickness of 1.0-1.5mm while meeting strict
mechanical, thermal, and emissions requirements.
First 60% long glass-filled polypropylene concentrate
for ultra-thin wall automotive applications. Celanese
offers a broad range of LFT products for EMI shielding
Reduce cycle time, costs, and weight.
Celanese is the only LFRT producer that can supply from 4
continents, and now we have added innovative high-flow
grades to help development of lightweight, thin wall
components.
Celanese materials enable thinner walls, lighter weight, parts consolidation, cost savings and design freedom
across E-mobility segments. An excellent example of weight reduction capability across a broad range of
applications occurs with the use of Celstran® long fiber reinforced thermoplastics (LFRT) for structural and
other larger parts of EV charging Infrastructure.
Short Fiber Granule
Fiber Length = 0.2 – 0.4 mm
Wire-Coated or
Co-Mingled Fibers
Short Fiber vs Long Fiber Reinforced Thermoplastics (LFRT)
Fully Impregnated
Long Fiber Granule
Fiber Length = 11mm
Celstran® LFRT: High Quality, Fully Impregnated Fiber
▪ Each fiber fully impregnated
▪ Constant fiber dispersion
▪ Unequalled quality in the industry
▪ Volume resistivity LFT SF-10 grades: <0.5 ohm-cm
SEM picture of pellet
crosssections
External 17
Celstran® LFRT Pellet (melt impregnated)
Celanese Corporation
CoolPoly® TCP E Electrically & Thermally Conductive Plastics
CoolPoly® E-Series:
Volume resistivity: <100 ohm-cm
Thermal conductivity: 17 – 34 W/m K
Celanese offers one of the broadest portfolios in the industry for thermal management + EMI shielding
► Generic curve for any application with conductive & convective components
► Axes values depends on power input, part size, convective cooling conditions
► Heat transfer is initially conduction limited and later convection limited
► Heat moves through part faster than it can be removed from its surface
CoolPoly® TCP value proposition vs. metals:
► Weight savings due to density difference
► More design freedom with 3D complex geometries
► Part consolidation opportunities
► Reduced fabrication costs & secondary process steps
► Equivalent heat transfer for wide range of designs
Infrared thermography of 3 x 3 inch injection molded
plaques with 5 watts heaters attached to the underside
Conventional plastic CoolPoly® TCP
23°C
33°C
29°C
47°C
ΔT = 24°C ΔT = 4°C
Heat
Transfer
Conduction
Convection
Radiation (small)
Total Heat Flow
Σ
Thermal Conductivity
External 18
Celanese Corporation 19
CoolPoly® TCP TPE
Metal replacement
✓ Weight Reduction
✓ Inherent Corrosion Resistance
Electrical Management
✓ Improve Safety
✓ Increase Reliability
✓ Reduce Amplification of Electrical
Interference
Thermal Management
✓ Extend Part and Component Life
(reduced device temperature)
✓ Enable Flexibility in Material Choice
✓ Efficient Heating and Cooling
✓ Eliminate Need for Active Cooling
Design Flexibility and Efficiency
✓ High Throughput Injection Molding
✓ Manufacture of Complex Shapes and
Geometries
✓ Rapid Prototyping and Evaluation
Hardness Range 40 ShA to 56 ShA
Operating Temperature Range -50 °C to 100°C
Thermal Conductivity 1 to 3 W/m·K
Electrical Resistivity >1014 ohm-m
Thermally Conductive Elastomers
PROCESSING TECHNOLOGY
TECHNICAL CHARACTERISTICS
TYPE AVAILABILITY
Injection Molding ✓
Extrusion ✓
Application opportunities include – Automotive, Computer IT, Consumer, E&E, Industrial.
✓ CoolPoly® TCP TPE D8102 injection molding
grade, thermally conductive/electrically
non-conductive, hardness 56ShA
External 19
Celanese Corporation
Improving Thermal Management in Electric Vehicles
External 20
Application Requirements
► Chemical resistance
► Hydrolysis resistance
► Heat dissipation
Celanese Materials to Consider
► Celstran® LFRT PP
► Fortron® PPS
► Tecnoprene® PP/GF
► Celanyl® PA
► Polifor® PP/GF
Effective cooling for improved system efficiency
► Chemical resistance
► Excellent dimensional stability
► High thermal resistance up to 220°C
► Hydrolysis resistant grades
Separating wall thickness of 0.5 mm in this real-world
example required the excellent dimensional stability
and flow properties of Celanese materials.
These materials also remain stable to antifreeze-water
mixtures at operating temperatures of up to 140 °C
even over extended periods.
Benefits of Fortron® PPS
► High resistance to coolant chemicals
► Excellent tensile strength, impact resistance, flexibility
► Up to 70% weight savings vs. metal
► Simplified production requires no secondary operations
► Excellent dimensional stability
Commercialized Thin-Wall Pump – 0.5 mm
Celanese Corporation
Santoprene® TPV in EV cooling hoses
Commercial application examples
► Premium EV OEMs
Reasons for success
► Lightweight
► Recyclability
► Chemical resistance
► Increased durability
► Lower system costs vs EPDM, PA or PPS
External 21
Celanese Corporation
Celanese EMI Shielding Solutions
Broad portfolio of EMI shielding
solutions with ongoing innovation
External 22
Product Solutions Comments
❶ Celstran® LFT Steel fiber
(various base polymers)
► EMI shielding as high as 70 dB
► SF 10% by weight - 60 dB (higher possible with
higher loadings)
❷ CoolPoly® thermally
conductive products
(various base polymers)
► Available in LCP, PA6, PBT, and PPS
► EMI shielding of > 55 dB + thermal conductivity of
34 W/mK available
❸ Carbon fiber products
CoolPoly® TCP
Vectra® LCP A230/B230
Celanex® PBT ICF
Celanyl® PA CF
Celstran® LFT
► Available in various base polymers & product lines
► High strength and stiffness combined with EMI
shielding < 60 dB
► Good wear characteristics
EMI Shielding depends on:
► Shield thickness
► Gaps/leaks
Material
Part Design
Processing
► Polymer type
► Filler/fiber type, size,
shape, level
► Fiber orientation
► Filler/fiber dispersion
Hybrid Solutions (with partners)
❹ Metallization ► Plating (electroless, electrolytic)
► Conductive inkjet printing
❺ Over-molding inserts ► Metal film/foil with primer
► Conductive non-woven
Celanese Corporation
Lightening Inverter/Converter & Onboard Charging Systems
External 23
Application Requirements
► Electrical isolation
► Dimensional stability at high temperatures
► Low CLTE
► Resistance against oils and fluids up to 150°C
► Hydrolysis resistance
Celanese Materials to Consider
► Celstran® LFRT PP
► CoolPoly® TCP
► Celanex® & Pibiter® PBT
Gained efficiency throughout charging system component
development
► Decreased weight with design optimization
► Reduced mass with thin-wall technology enabled by high
flow, long fiber reinforced thermoplastics
► Reduced material costs through secondary process
elimination and 6x longer tool life
► Meets thermal performance needs previously requiring
aluminum
► Uses 1/3 energy in molding process and have the option
of recyclable grades
Die-Cast Alloy Typical Density
CoolPoly® TCP Density
+ thinner nominal wall, less “clunky” part design
1.6g/cc
2.8g/cc
45%
Design Optimization
Density Reduction
10%
55%
Weight Savings Achieved
Lightweighting Heat Sinks with CoolPoly® Thermally Conductive Plastics
Ford Mondeo
Headlamp Heat Sink
Case specificresults, will vary depending on previouslyspecifiedmaterial.
Considering that covers, trays and housings offer significant potential for
weight loss reduction throughout these systems, Celstran® LFRT offers the
ideal material to replace metal while providing EMI shielding.
Lightweighting Covers & Trays with Celstran® LFRT
Celanese Corporation
Supporting Safety in High Voltage Connectors
External 24
Application Requirements
► Non-halogenated
► Temperature stable up to 120°C for standard
(short-term up to 260°C for SMD soldering)
► Flame retardant
► High voltage up to 1.5KV DC
► Hydrolysis resistant
► High precision, low warpage
► Dimensional stability
Celanese Materials to Consider
► Celanex® PBT
► Thermx® PCT
► Frianyl® FR PA
► Fortron® PPS
► Vectra® LCP
Combined mechanical, electrical and flow properties to
support safer connectors
• Short-term temperature resistance up to 255°C for lead-free soldering
• Flame retardant (UL94 V-0)
• Chemical resistance to automotive fluids and printed circuit board
cleaning
• Low moisture absorption
• Low-flash processing, high CTI and arc resistance
• Mold-in color easily identified for safety requirement
• High dimensional stability
• Halogen-free flame retardant grades
• Hydrolysis resistant grades
• High heat
Suited for Demands
Celanese offers a broad portfolio of semi-crystalline thermoplastics
polyesters providing high strength, rigidity and toughness, with low
creep even at high temperatures.
Resistant to a wide range of
chemicals, solvents and oils.
+
Celanese Corporation
Specific engineering expertise necessary – beyond product offerings
25
Innovative Solution Development for Bus Bars
► Bus bar is a metal conductor overmolded with plastic for
insulation and protection purposes
► Complex requirements:
‒ Thermal shock resistance
‒ Good electrical properties
‒ High temperature resistance in case of thermal runaway
► Wide range of engineering plastics used: PBT, PA, PPA, LCP, PPS
► Celanese product offerings:
Celanex® PBT, Frianyl® PA and PPA, Fortron® PPS, Vectra® LCP
Battery System Power Electronics
Pictures courtesy of A2Mac1
external
Celanese Corporation
Electrical Insulations
external 26
Rotor
Axis with permanent magnets
(insulated and caged with plastics)
Stator
Ring of metal cores, insulated with
plastics and copper wired
► Performance-critical electrical insulations
of stator/rotor, end capping and guide rails
► Plastics in electrical insulation are exposed to
stringent requirements
(thin-wall-design, dimensional stability,
temperature /media resistance, el. insulation)
Celanese Corporation
Customer Value –
Impact of the Reduction of the Wall-Thickness
Reduction of wall thickness* at same power output
► Smaller size of the motor
(up to 8%, calculating with an avg. diameter of 40mm motor size)
► Weight reduction; material cost reduction
(up to 40%, depending on the design)
external
Reduction of wall thickness* at same motor** size
► More windings per square
(up to 3 more winding layers, depending on wire diameter)
► More power output; higher torque
(up to 10% higher power output, assuming 3 more layers per tooth)
27
*: wall thickness reductions up to 30%, due to excellent flow properties down to 0.5 /0.3mm;
final achievements strongly dependent on design, tooling, process conditions
**: servo motor with 12-16 teeth; ca. 4-6cm in diameter; length unchanged
Celanese Corporation
Battery-Cell Module
Setup & Requirements
external
► Dimensional stability
► Impact resistance
► Hydrolytic & chemical
resistance
► electric insulation
► Temp: -20°C to + 70°C
► UL94: V-0
► Thermal conduction
► EMS
Module Housing
Battery Cell Pack Housing
* Data (system, sub-system and component photos, weights and material details courtesy of A2Mac1 Automotive Benchmarking
*
28
Celanese Corporation
Battery – Cell Module Housing
Celanese Solution
Tecnoprene® PP HF GF 30 V0 Nero 900
• Low Density -> Weight Reduction – Increase Range
• Flame retardant grade
• Good mechanical properties
Tensile Modulus 23°C (Mpa) 8400
Tensile Strength 23°C (MPa): 80
Charpy Impact Toughness (kJ/m2): no data
Charpy Notched Impact
Toughness (kJ/m2): 7
HDT/A 1.8 MPa: 140
Density kg/m3: 1340
Cont. Use Temperature (°C): 80
Chemical resistance: ++
Flame Retardancy (UL94): V-0 (1.6 mm)
UL-certified: yes
► High impact resistance
(-40°C to + 80°C)
► Low warpage /flatness
► Stiffness
► Flame retardancy (halogen
free?)
(UL94 HB; V-0 (1.6 mm)
CTQs
external 29
* Data (system, sub-system and component photos, weights and material details courtesy of A2Mac1 Automotive Benchmarking
*
Celanese Corporation
Battery Module: Endplates (Metal / Plastic Hybrid Solution)
Requirements and Celanese Solutions
external 30
► Flowability/low warpage/
dimension-stability
► Hydrolytic stability
► Chemical resistance against
electrolyte
► Flame retardancy: V-0 (0.4 mm)
CTQs
Fortron® PPS 1140 L4
Glass-reinforced polyphenylene sulfide serves highest requirements regarding:
• Flowability
• Best dimension stability due to lowest warp and virtually no moisture up-take
• Polyphenylene sulfide is inherently flame-retardant and provides best chemical
& media resistance.
Fortron 1140 L4 Competitive PA6 Competitive
PA66
Shrinkage
(%)
Mold Shrinkage of
Fortron® PPS 1140L4
vs. competitive PA
Tensile Modulus 23°C (MPa): 14700
Tensile Strength 23°C: 190
Charpy Impact Toughness (kJ/m2): 53
Charpy Notched Impact Toughness (kJ/m2): 10
HDT/A 1.8 MPa: 270
Density kg/m3: 1650
Cont. Use Temperature (°C): 220
Chemical resistance: +++
Flame Retardant (UL94): V-0 (0.4 mm)
CTI (Volt): 125
UL-certified: yes
Celanese Corporation
Battery Pack – Housing & Tray
Requirements and Celanese Solutions
external 31
• 50 % Weight Saving (vs. Steel) → Increased range
• Reduced production costs for large quantities
Celstran® LFT PP-GF30 Plus Celstran® CFR-TP -Tapes (PPGF60)
Celstran® LFT PP-GF50-0403
Celstran®
CFR-TP PP GF60
Celstran®
LFT
PP-GF30-04
Competitive
PA6 composite
Competitive
PP composite
Density 1490 kg/m3
1120 kg/m3
1800 kg/m3
1680 kg/m3
Tensile modulus 25,7 GPa 7000 MPa 18 GPa 20 GPa
Tensile stress 732 MPa 110 MPa 380 MPa 430 MPa
Charpy impact
strength
55 kJ/m²
Charpy notched
impact strength
24 kJ/m²
DTUL at 1.8 MPa 158 °C
Celstran® CFR-TP
Benchmarking
Stiffness & Strength
Source: Volkswagen
* Source: Volkswagen
*
Celanese Corporation
Enabling Wireless Connectivity
External 32
Application Requirements
► Dimensional stability
► Thin wall for miniaturization
► Good dielectric properties
► Flame retardant
► High temperature resistant
Celanese Materials to Consider
► Vectra® LCP
► Fortron® PPS
► Celanyl® PA66
► Frianyl® FR PA
► Celanyl® XT PPA
► Frianyl® XT FR PPA
Enabling wireless electronics via miniaturization
and part consolidation.
► Laser Direct Structuring (LDS) compatible materials for
complex circuits and smaller antennae
► High flow materials for thin walls and complex geometry
► High temperature resistance for Surface Mount Technology
(SMT)
Vectra® LCP for LDS is very high flow, high HDT, dimensionally stable, chemically resistant, low
moisture absorbing, fast molding, non flashing and inherently non-flammable.
• Molding resin containing laser
activatable complex
• Laser induces physio-chemical
reaction to release metal seeds
• Activated surface is metallized
Laser Direct Structuring
Celanese Corporation
Engineered Materials
ODMs & Molders ask for material and part reliability. End users demand fast and safe performance.
We support new projects through the whole process, from material development to tool and part design.
Global Customer Enabling Capabilities Locations
Specialty Processing
Specialty Processing
Specialty Processing
• Microscopy
• Spectroscopy
• Chromatography
• Elemental Analysis
• Wet Chemistry
CAE/Part Design
• Mold Flow Simulation
• Structural Modeling
• Part & Tool Optimization
• Data Support
Material Characterization
• Thermal
• Mechanical
• Electrical
• Flammability
• Conductivity
• Rheology
Custom Application Testing
Custom Application Testing
Custom Application Testing
Prototyping Support
• Prototype Tool Design
• Part Machining
• Customer Consulting
Processing
Optimization
• Injection Molding
• Extrusion
• Profile Extrusion
• Blow Molding
• Welding & Joining
• Laser Marking
• Color/Appearance
• Environmental/Media Aging
• Buckle, Hinge, Heat Sink Testing
• Custom Pharma Development Support
• Connector, CCM Testing
• 2K Molding
• Foaming
• Ram/Gel Extrusion
• Porous Sintering
• Tribology (Friction, Wear)
• High Speed Impact Testing
• Filtration Device Testing
• Connector, CCM Testing
• Dynamic Warpage, Reflow
• Membrane Characterization
• Fatigue & Creep Testing
• Odor / Emission, VOC,
Formaldehyde
• High Precision Molding
• Membrane Processing
Analytical Testing
Americas
Europe
Asia
External 33
Celanese Corporation
Why Celanese Engineered Materials for EV Charging Infrastructure
► The Infrastructure is always as good as their individual components
► Proven solutions for plugs & sockets
► Well established polymer families & FR technologies inside the charging columns
► CoolPoly® Technology for most efficient thermal management and EMI shielding
► Celstran® LFRT Technology for housings and mounting parts, EMI shielding
► Broad range of TPVs and TPEs for sealings, grip, strain relief and caps, auxiliary
equipment
► Custom coloration for most grades
Celanese – Broad Range of Material Solutions and Expert Support for your Charging Technology Projects
34
External
Celanese Corporation
Thank you for your attention! Stay Charged!
Dr. Gulnaz Idiyatullina
Global Program Manager – EV Charging
Infrastructure
Celanese Sales Germany GmbH
Am Unisys-Park 1; 65843 Sulzbach (Taunus)
e-mail: Gulnaz.Idiyatullina@Celanese.com
35
External
Celanese Corporation
Disclaimer & Notice to Users
Disclaimer
This publication was printed based on Celanese’s present state of knowledge, and Celanese undertakes no obligation to update it. Because
conditions of product use are outside Celanese’s control, Celanese makes no warranties, express or implied, and assumes no liability in connection
with any use of this information. Nothing herein is intended as a license to operate under or a recommendation to infringe any patents.
Notice to Users
Values shown are based on testing of laboratory test specimens and represent data that fall within the standard range of properties for natural
material. These values alone do not represent a sufficient basis for any part design and are not intended for use in establishing maximum,
minimum, or ranges of values for specification purposes. Colorants or other additives may cause significant variations in data values. Properties of
molded parts can be influenced by a wide variety of factors including, but not limited to, material selection, additives, part design, processing
conditions and environmental exposure. Any determination of the suitability of a particular material and part design for any use contemplated by
the users and the manner of such use is the sole responsibility of the users, who must assure themselves that the material as subsequently
processed meets the needs of their particular product or use.
To the best of our knowledge, the information contained in this publication is accurate; however, we do not assume any liability whatsoever for
the accuracy and completeness of such information. The information contained in this publication should not be construed as a promise or
guarantee of specific properties of our products. It is the sole responsibility of the users to investigate whether any existing patents are infringed
by the use of the materials mentioned in this publication. Moreover, there is a need to reduce human exposure to many materials to the lowest
practical limits in view of possible adverse effects. To the extent that any hazards may have been mentioned in this publication, we neither suggest
nor guarantee that such hazards are the only ones that exist. We recommend that persons intending to rely on any recommendation or to use any
equipment, processing technique or material mentioned in this publication should satisfy themselves that they can meet all applicable safety and
health standards. We strongly recommend that users seek and adhere to the manufacturer’s current instructions for handling each material they
use, and entrust the handling of such material to adequately trained personnel only.
The products mentioned herein are not intended for use in medical or dental implants.
Hostaform® is a registered trademark of Hoechst GmbH, used by Celanese Corporation under license.
Fortron® is a registered trademark of Fortron Industries LLC, used by Celanese Corporation under license.
Celanese®, registered C-ball design and all other trademarks identified herein with ®, TM, SM, unless otherwise noted, are trademarks of Celanese
or its affiliates.
© 2022 Celanese or its affiliates. All rights reserved. Published June 2022.
Americas
8040 Dixie Highway, Florence, KY 41042 USA
Product Information Service
t: +1-800-833-4882 t: +1-859-372-3244
Customer Service
t: +1-800-526-4960 t: +1-859-372-3214
e: info-engineeredmaterials-am@celanese.com
Europe
Am Unisys-Park 1, 65843 Sulzbach, Germany
Product Information Service
t: +(00)-800-86427-531 t: +49-(0)-69-45009-1011
e: info-engineeredmaterials-eu@celanese.com
Asia
4560 Jinke Road, Zhang Jiang Hi Tech Park
Shanghai 201203 PRC
Customer Service
t: +86 21 3861 9266 f: +86 21 3861 9599
e: info-engineeredmaterials-asia@celanese.com
Contact Information
External 36

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HIGH-TECH THERMOPLASTICS AND SUSTAINABLE SOLUTIONS FOR EV CHARGING

  • 1. HIGH-TECH THERMOPLASTICS AND SUSTAINABLE SOLUTIONS FOR EV CHARGING Enabling Electrification with Celanese Dr. Gulnaz Idiyatullina EV Charging Infrastructure UK 2022 27 – 28 June 2022 CentrEd at ExCeL London, UK
  • 2. Celanese Corporation Agenda ► Offering the broadest portfolio of thermoplastics and sustainable solutions to the EVSE market ► EV charging infrastructure market and regulatory information ► Engineered materials for EV charging applications External 2
  • 3. Celanese Corporation Celanese Corporation Overview ► Global headquarters in Dallas, Texas, USA ► $8.5 billion in net sales in 2021 ► Number 477 on the 2021 FORTUNE 500 list ► Approximately 8,500 employees globally ► 40+ manufacturing facilities; operations in 19 countries around the world ► Three leading businesses: Engineered Materials, Acetyls and Acetate Tow ► Innovation is at the core of our differentiated business model External 3 We are a global chemical and specialty materials company that engineers and manufactures a variety of products essential to everyday living.
  • 4. Celanese Corporation Serving a Broad Set of Industries External 4 Other 11% Construction 3% Paints & Coatings 13% Automotive 17% Consumer & Medical Applications 11% Filter Media 13% Consumer & Industrial Adhesives 11% Textiles 2% Food & Beverage 3% Chemical Additives 2% Paper & Packaging 6% Industrial Performance Applications 9%
  • 6. Celanese Corporation Edmonton, AB Bay City, TX Cangrejera, Mexico Frankfurt, Germany Singapore Al Jubail, SA Nanjing, China Narrows, VA Clear Lake, TX Boucherville, QC Enoree, SC Shelby, NC Winona, MN Suzano, Brazil Nantong, China KEP, South Korea Kunming, China Geleen, Netherlands Perstorp, Sweden Spondon, UK Zhuhai,China Lanaken, Belgium Joint Ventures Dallas, TX Auburn Hills, MI Sulzbach, Germany Budapest, Hungary Oberhausen, Germany Kaiserslautern, Germany Wilmington, NC Bishop, TX Global Manufacturing Locations (including joint ventures) Shanghai, China Regional HQs Amsterdam, Netherlands Suzhou, China Campo Bom, Brazil Silao, Mexico Florence, KY Utzenfeld, Germany Wehr, Germany Forli, Italy Ferrara, Italy Evansville, IN Silvassa, India Sales/Regional Offices Sempach and Moosleerau, Switzerland Shanghai, China Pensacola, FL Newport, UK External 6
  • 7. Celanese Corporation Celanese Portfolio External 7 2021 Net Sales: $8.5 Billion Automotive / E-Mobility Electrical & Electronics Industrial Consumer Medical Food & Beverages Other Celanese has one of the broadest portfolios spanning all thermoplastic classes
  • 8. Celanese Corporation Engineered Materials Sustainable Solutions 8 external Bio-mass balance ECO-B Products derived from biological feedstock like forestry and agricultural waste materials or renewable domestic waste using a mass balance approach Recycled content ECO-R Products that contain post- industrial or post-consumer recycled materials while still maintaining consistency, quality and performance End-of-life Products that are biodegradable and compatible with waste streams that go into composting Carbon capture ECO-CC Products based on CO2 emissions converted into methanol as building block for downstream products To learn more, view our sustainability website: www.celanese.com/corporate-sustainability-strategy
  • 9. Celanese Corporation Recycled Content – ECO-R ► Post-Industrial Recycle (PIR): Derived from separated industrial waste streams Generally higher quality due to more defined origin ► Post-Consumer Recycle (PCR): Derived from separated consumer waste streams Typically, higher variability and levels of contamination ► Internal scraps: Derived from internal scraps incl compounded product Generally, no longer recognized as recycling Raw materials Long-term suppliers with proven history and robust systems to maximize quality, minimize variability and ensure traceability Finished products ► Compensates performance drop from mechanical recycling step ► Product very close but not identical to prime (no drop in) ► Expanding offer beyond legacy unspecified recycled content to ECO-R range with specified recycled content Material Recycle Sources Available Product Brands PA PIR carpet, textile, industrial fiber now Ecomid® PA ECO-R PBT/PET PCR beverage bottles, packaging scrap now Impet® PET ECO-R, Celanex® PBT/PET ECO-R PP PIR textile fiber, non-woven 2Q 22 Tecnoprene® PP ECO-R TPV PCR PP now Santoprene® TPV ECO-R 9 external
  • 10. Celanese Corporation BioMass Balance – ECO-B ECO-B concept ► Bio-based feedstock using a bio-mass balance approach ► Independent 3rd party audited mass balance certification (ISCC+, RedCert2) ► Significant increase in renewable content and reduction of CO2 footprint vs standard fossil equivalents ► End products in identical quality and properties enable drop-in replacement 10 external Material Available CO2 footprint reduction Renewable content Bio-Mass Balance feedstock POM ECO-B 1Q 2021 up to 50% up to 97% Bio Methanol Celanex® PBT ECO-B 2Q 2022 up to 45% up to 40% Bio BDO GUR® UHMWPE ECO-B 3Q 2022 under evaluation up to 99% Bio Ethylene
  • 11. Celanese Corporation EV Charging Infrastructure External 11 Power Transformation, Meter and Panel ➢ Distribution lines, substations ➢ Transformer ➢ Switchgear​ ➢ Meter ➢ Panel, conduit/circuit, outlet Station and Supply Equipment ➢ Charging columns and wall box​ ➢ Structural parts ➢ E&E components inside ➢ Thermal management parts ➢ Sealants Charging Plug and Cable ➢ Charging plug and socket ➢ Charging wire and cable
  • 12. Celanese Corporation Overview of EV Charging Standards External 12 ► AC Charging station UL2594 ► DC Charging station UL 2202 ► Wireless Charger UL 2750 ► Cord sets UL 2594 ► Offboard cable UL 2263 ► Personnel protection equipment UL 2231-1, UL 2231-2, NEC625(a), SAE J1772 ► Bidirectional Charging station UL 9741 Celanese offer a broad material portfolio covering application requirements ► Onboard ‒ Batteries UL 2580 ‒ Cable UL 2733 ‒ Inverters UL 458A ‒ Motors UL 1004-1 ‒ Chargers UL 2202 ‒ Connectors UL 2734 ► EV Inlets UL 2251, SAE J1772 ‒ Plugs, socket-outlets, vehicle connectors and vehicle inlets EV Onboard Equipment EV Chargers
  • 13. Celanese Corporation Engineered Materials for E-Mobility Requirements for the Electric Powertrain external 13 ► Crash Resistance ► Electrical Insulation ► Hydrolysis Resistance ► Flame Retardancy Battery Systems ► Electrical Insulation ► Flame Retardancy V0 ► Hydrolysis Resistance ► Dimension Stability High Voltage Connectors High Voltage Connectors ► Electrical Insulation ► Hydrolysis Resistance ► Dimension Stability ► Temperature Resistance Electric Motors ► Temperature range (-40°C to + 80°C) ► Hydrolytic/chemical resistance ► Thermal Conductivity (Passive cooling) ► Toughness Thermo-Management ► Crash Resistance ► Electrical Insulation ► Chemical Resistance ► Hydrolysis Resistance ► EMI Shielding Power Electronics ► Lightweight ► Chemical Resistance ► Dimensional Stability ► Low Warpage Universal Requirements
  • 14. Celanese Corporation Current Applications in EV Charging External 14 LFRT PP - LCP - PCT - PA PPA - TPC ET - POM Charging Ports & Stations • Electrical Isolation • UV Stability • Impact Resistance • Flame Retardancy Universal Requirements: • Light-weighting • Miniaturization • Thermal Management Circuit breaker Frianyl® PA Frianyl® XT PPA Celanex® PBT Vectra® LCP Terminal blocks Frianyl® PA Electronics/ Controller Frianyl® PA Fusebox & holders Frianyl® PA Celanex® PBT Power-Management Frianyl® XT PPA Vectra® LCP Relays & Switches Celanex® PBT Frianyl® PA Fortron® PPS Power-Supply Frianyl® PA Frianyl® XT PPA Thermal Management CoolPoly® TCP Charger Plugs & Sockets Celanese Portfolio is used in most of the E-Mobility applications
  • 15. Celanese Corporation Charger Plugs Functional Requirements and Material Solutions Celanese Portfolio offers a full range of plastics solutions Image Source: Phoenix Contact Relevant Material in Celanese Portfolio Universal Requirements: • Handling • Safety • Regulation conform UL & IEC • Impact resistance • Electrical isolation • Dimenstional stability • Mechanical strength • Flame retardant • Temperature resistance Socket & Mounting Protection & Performance PA - PBT • Temperature resistance • Electrical Isolation • Dimensional Stability • Durability • Weatherability • Aesthetics Housing Functionality & Protection PA - PBT -TPV PA - PBT -TPV • Electrical isolation • Flame Retardancy • Heat Dissipation • Media resistance to coolent Thermal Management Functionality & Performance PPS - CoolPoly® TCP External 15
  • 16. Celanese Corporation Elastic Components and Sealants Thermoplastic Elastomers External 16 ► High elastic recovery ► Chemical resistance ► Flex fatigue resistance ► High thermal and electric insulation, UL Listing ► Good abrasion resistance ► Good colorability (SEBS: translucent, transparent) ► Recyclability ► Soft touch and aesthetics Santoprene™ TPV, Forprene® TPV; Laprene® SEBS Technical Characteristics – Santoprene® TPV & Forprene® TPV Hardness Range 20 ShA to 60 ShD Operating Temperature Range -40 °C to 130 °C Density Range <1.0 g/cm3 Technical Characteristics – Laprene® SEBS Hardness Range 2 ShA to 60 ShD Operating Temperature Range -50 °C to 120 °C Density Range 0.90 g/cm3 to 1.20 g/cm3 grip strain relief cable string cap
  • 17. Celanese Corporation Leading Innovation in E-Mobility Lightweighting & EMI Shielding HIGH FLOW Celanese’s high flow technology enables nominal wall thickness of 1.0-1.5mm while meeting strict mechanical, thermal, and emissions requirements. First 60% long glass-filled polypropylene concentrate for ultra-thin wall automotive applications. Celanese offers a broad range of LFT products for EMI shielding Reduce cycle time, costs, and weight. Celanese is the only LFRT producer that can supply from 4 continents, and now we have added innovative high-flow grades to help development of lightweight, thin wall components. Celanese materials enable thinner walls, lighter weight, parts consolidation, cost savings and design freedom across E-mobility segments. An excellent example of weight reduction capability across a broad range of applications occurs with the use of Celstran® long fiber reinforced thermoplastics (LFRT) for structural and other larger parts of EV charging Infrastructure. Short Fiber Granule Fiber Length = 0.2 – 0.4 mm Wire-Coated or Co-Mingled Fibers Short Fiber vs Long Fiber Reinforced Thermoplastics (LFRT) Fully Impregnated Long Fiber Granule Fiber Length = 11mm Celstran® LFRT: High Quality, Fully Impregnated Fiber ▪ Each fiber fully impregnated ▪ Constant fiber dispersion ▪ Unequalled quality in the industry ▪ Volume resistivity LFT SF-10 grades: <0.5 ohm-cm SEM picture of pellet crosssections External 17 Celstran® LFRT Pellet (melt impregnated)
  • 18. Celanese Corporation CoolPoly® TCP E Electrically & Thermally Conductive Plastics CoolPoly® E-Series: Volume resistivity: <100 ohm-cm Thermal conductivity: 17 – 34 W/m K Celanese offers one of the broadest portfolios in the industry for thermal management + EMI shielding ► Generic curve for any application with conductive & convective components ► Axes values depends on power input, part size, convective cooling conditions ► Heat transfer is initially conduction limited and later convection limited ► Heat moves through part faster than it can be removed from its surface CoolPoly® TCP value proposition vs. metals: ► Weight savings due to density difference ► More design freedom with 3D complex geometries ► Part consolidation opportunities ► Reduced fabrication costs & secondary process steps ► Equivalent heat transfer for wide range of designs Infrared thermography of 3 x 3 inch injection molded plaques with 5 watts heaters attached to the underside Conventional plastic CoolPoly® TCP 23°C 33°C 29°C 47°C ΔT = 24°C ΔT = 4°C Heat Transfer Conduction Convection Radiation (small) Total Heat Flow Σ Thermal Conductivity External 18
  • 19. Celanese Corporation 19 CoolPoly® TCP TPE Metal replacement ✓ Weight Reduction ✓ Inherent Corrosion Resistance Electrical Management ✓ Improve Safety ✓ Increase Reliability ✓ Reduce Amplification of Electrical Interference Thermal Management ✓ Extend Part and Component Life (reduced device temperature) ✓ Enable Flexibility in Material Choice ✓ Efficient Heating and Cooling ✓ Eliminate Need for Active Cooling Design Flexibility and Efficiency ✓ High Throughput Injection Molding ✓ Manufacture of Complex Shapes and Geometries ✓ Rapid Prototyping and Evaluation Hardness Range 40 ShA to 56 ShA Operating Temperature Range -50 °C to 100°C Thermal Conductivity 1 to 3 W/m·K Electrical Resistivity >1014 ohm-m Thermally Conductive Elastomers PROCESSING TECHNOLOGY TECHNICAL CHARACTERISTICS TYPE AVAILABILITY Injection Molding ✓ Extrusion ✓ Application opportunities include – Automotive, Computer IT, Consumer, E&E, Industrial. ✓ CoolPoly® TCP TPE D8102 injection molding grade, thermally conductive/electrically non-conductive, hardness 56ShA External 19
  • 20. Celanese Corporation Improving Thermal Management in Electric Vehicles External 20 Application Requirements ► Chemical resistance ► Hydrolysis resistance ► Heat dissipation Celanese Materials to Consider ► Celstran® LFRT PP ► Fortron® PPS ► Tecnoprene® PP/GF ► Celanyl® PA ► Polifor® PP/GF Effective cooling for improved system efficiency ► Chemical resistance ► Excellent dimensional stability ► High thermal resistance up to 220°C ► Hydrolysis resistant grades Separating wall thickness of 0.5 mm in this real-world example required the excellent dimensional stability and flow properties of Celanese materials. These materials also remain stable to antifreeze-water mixtures at operating temperatures of up to 140 °C even over extended periods. Benefits of Fortron® PPS ► High resistance to coolant chemicals ► Excellent tensile strength, impact resistance, flexibility ► Up to 70% weight savings vs. metal ► Simplified production requires no secondary operations ► Excellent dimensional stability Commercialized Thin-Wall Pump – 0.5 mm
  • 21. Celanese Corporation Santoprene® TPV in EV cooling hoses Commercial application examples ► Premium EV OEMs Reasons for success ► Lightweight ► Recyclability ► Chemical resistance ► Increased durability ► Lower system costs vs EPDM, PA or PPS External 21
  • 22. Celanese Corporation Celanese EMI Shielding Solutions Broad portfolio of EMI shielding solutions with ongoing innovation External 22 Product Solutions Comments ❶ Celstran® LFT Steel fiber (various base polymers) ► EMI shielding as high as 70 dB ► SF 10% by weight - 60 dB (higher possible with higher loadings) ❷ CoolPoly® thermally conductive products (various base polymers) ► Available in LCP, PA6, PBT, and PPS ► EMI shielding of > 55 dB + thermal conductivity of 34 W/mK available ❸ Carbon fiber products CoolPoly® TCP Vectra® LCP A230/B230 Celanex® PBT ICF Celanyl® PA CF Celstran® LFT ► Available in various base polymers & product lines ► High strength and stiffness combined with EMI shielding < 60 dB ► Good wear characteristics EMI Shielding depends on: ► Shield thickness ► Gaps/leaks Material Part Design Processing ► Polymer type ► Filler/fiber type, size, shape, level ► Fiber orientation ► Filler/fiber dispersion Hybrid Solutions (with partners) ❹ Metallization ► Plating (electroless, electrolytic) ► Conductive inkjet printing ❺ Over-molding inserts ► Metal film/foil with primer ► Conductive non-woven
  • 23. Celanese Corporation Lightening Inverter/Converter & Onboard Charging Systems External 23 Application Requirements ► Electrical isolation ► Dimensional stability at high temperatures ► Low CLTE ► Resistance against oils and fluids up to 150°C ► Hydrolysis resistance Celanese Materials to Consider ► Celstran® LFRT PP ► CoolPoly® TCP ► Celanex® & Pibiter® PBT Gained efficiency throughout charging system component development ► Decreased weight with design optimization ► Reduced mass with thin-wall technology enabled by high flow, long fiber reinforced thermoplastics ► Reduced material costs through secondary process elimination and 6x longer tool life ► Meets thermal performance needs previously requiring aluminum ► Uses 1/3 energy in molding process and have the option of recyclable grades Die-Cast Alloy Typical Density CoolPoly® TCP Density + thinner nominal wall, less “clunky” part design 1.6g/cc 2.8g/cc 45% Design Optimization Density Reduction 10% 55% Weight Savings Achieved Lightweighting Heat Sinks with CoolPoly® Thermally Conductive Plastics Ford Mondeo Headlamp Heat Sink Case specificresults, will vary depending on previouslyspecifiedmaterial. Considering that covers, trays and housings offer significant potential for weight loss reduction throughout these systems, Celstran® LFRT offers the ideal material to replace metal while providing EMI shielding. Lightweighting Covers & Trays with Celstran® LFRT
  • 24. Celanese Corporation Supporting Safety in High Voltage Connectors External 24 Application Requirements ► Non-halogenated ► Temperature stable up to 120°C for standard (short-term up to 260°C for SMD soldering) ► Flame retardant ► High voltage up to 1.5KV DC ► Hydrolysis resistant ► High precision, low warpage ► Dimensional stability Celanese Materials to Consider ► Celanex® PBT ► Thermx® PCT ► Frianyl® FR PA ► Fortron® PPS ► Vectra® LCP Combined mechanical, electrical and flow properties to support safer connectors • Short-term temperature resistance up to 255°C for lead-free soldering • Flame retardant (UL94 V-0) • Chemical resistance to automotive fluids and printed circuit board cleaning • Low moisture absorption • Low-flash processing, high CTI and arc resistance • Mold-in color easily identified for safety requirement • High dimensional stability • Halogen-free flame retardant grades • Hydrolysis resistant grades • High heat Suited for Demands Celanese offers a broad portfolio of semi-crystalline thermoplastics polyesters providing high strength, rigidity and toughness, with low creep even at high temperatures. Resistant to a wide range of chemicals, solvents and oils. +
  • 25. Celanese Corporation Specific engineering expertise necessary – beyond product offerings 25 Innovative Solution Development for Bus Bars ► Bus bar is a metal conductor overmolded with plastic for insulation and protection purposes ► Complex requirements: ‒ Thermal shock resistance ‒ Good electrical properties ‒ High temperature resistance in case of thermal runaway ► Wide range of engineering plastics used: PBT, PA, PPA, LCP, PPS ► Celanese product offerings: Celanex® PBT, Frianyl® PA and PPA, Fortron® PPS, Vectra® LCP Battery System Power Electronics Pictures courtesy of A2Mac1 external
  • 26. Celanese Corporation Electrical Insulations external 26 Rotor Axis with permanent magnets (insulated and caged with plastics) Stator Ring of metal cores, insulated with plastics and copper wired ► Performance-critical electrical insulations of stator/rotor, end capping and guide rails ► Plastics in electrical insulation are exposed to stringent requirements (thin-wall-design, dimensional stability, temperature /media resistance, el. insulation)
  • 27. Celanese Corporation Customer Value – Impact of the Reduction of the Wall-Thickness Reduction of wall thickness* at same power output ► Smaller size of the motor (up to 8%, calculating with an avg. diameter of 40mm motor size) ► Weight reduction; material cost reduction (up to 40%, depending on the design) external Reduction of wall thickness* at same motor** size ► More windings per square (up to 3 more winding layers, depending on wire diameter) ► More power output; higher torque (up to 10% higher power output, assuming 3 more layers per tooth) 27 *: wall thickness reductions up to 30%, due to excellent flow properties down to 0.5 /0.3mm; final achievements strongly dependent on design, tooling, process conditions **: servo motor with 12-16 teeth; ca. 4-6cm in diameter; length unchanged
  • 28. Celanese Corporation Battery-Cell Module Setup & Requirements external ► Dimensional stability ► Impact resistance ► Hydrolytic & chemical resistance ► electric insulation ► Temp: -20°C to + 70°C ► UL94: V-0 ► Thermal conduction ► EMS Module Housing Battery Cell Pack Housing * Data (system, sub-system and component photos, weights and material details courtesy of A2Mac1 Automotive Benchmarking * 28
  • 29. Celanese Corporation Battery – Cell Module Housing Celanese Solution Tecnoprene® PP HF GF 30 V0 Nero 900 • Low Density -> Weight Reduction – Increase Range • Flame retardant grade • Good mechanical properties Tensile Modulus 23°C (Mpa) 8400 Tensile Strength 23°C (MPa): 80 Charpy Impact Toughness (kJ/m2): no data Charpy Notched Impact Toughness (kJ/m2): 7 HDT/A 1.8 MPa: 140 Density kg/m3: 1340 Cont. Use Temperature (°C): 80 Chemical resistance: ++ Flame Retardancy (UL94): V-0 (1.6 mm) UL-certified: yes ► High impact resistance (-40°C to + 80°C) ► Low warpage /flatness ► Stiffness ► Flame retardancy (halogen free?) (UL94 HB; V-0 (1.6 mm) CTQs external 29 * Data (system, sub-system and component photos, weights and material details courtesy of A2Mac1 Automotive Benchmarking *
  • 30. Celanese Corporation Battery Module: Endplates (Metal / Plastic Hybrid Solution) Requirements and Celanese Solutions external 30 ► Flowability/low warpage/ dimension-stability ► Hydrolytic stability ► Chemical resistance against electrolyte ► Flame retardancy: V-0 (0.4 mm) CTQs Fortron® PPS 1140 L4 Glass-reinforced polyphenylene sulfide serves highest requirements regarding: • Flowability • Best dimension stability due to lowest warp and virtually no moisture up-take • Polyphenylene sulfide is inherently flame-retardant and provides best chemical & media resistance. Fortron 1140 L4 Competitive PA6 Competitive PA66 Shrinkage (%) Mold Shrinkage of Fortron® PPS 1140L4 vs. competitive PA Tensile Modulus 23°C (MPa): 14700 Tensile Strength 23°C: 190 Charpy Impact Toughness (kJ/m2): 53 Charpy Notched Impact Toughness (kJ/m2): 10 HDT/A 1.8 MPa: 270 Density kg/m3: 1650 Cont. Use Temperature (°C): 220 Chemical resistance: +++ Flame Retardant (UL94): V-0 (0.4 mm) CTI (Volt): 125 UL-certified: yes
  • 31. Celanese Corporation Battery Pack – Housing & Tray Requirements and Celanese Solutions external 31 • 50 % Weight Saving (vs. Steel) → Increased range • Reduced production costs for large quantities Celstran® LFT PP-GF30 Plus Celstran® CFR-TP -Tapes (PPGF60) Celstran® LFT PP-GF50-0403 Celstran® CFR-TP PP GF60 Celstran® LFT PP-GF30-04 Competitive PA6 composite Competitive PP composite Density 1490 kg/m3 1120 kg/m3 1800 kg/m3 1680 kg/m3 Tensile modulus 25,7 GPa 7000 MPa 18 GPa 20 GPa Tensile stress 732 MPa 110 MPa 380 MPa 430 MPa Charpy impact strength 55 kJ/m² Charpy notched impact strength 24 kJ/m² DTUL at 1.8 MPa 158 °C Celstran® CFR-TP Benchmarking Stiffness & Strength Source: Volkswagen * Source: Volkswagen *
  • 32. Celanese Corporation Enabling Wireless Connectivity External 32 Application Requirements ► Dimensional stability ► Thin wall for miniaturization ► Good dielectric properties ► Flame retardant ► High temperature resistant Celanese Materials to Consider ► Vectra® LCP ► Fortron® PPS ► Celanyl® PA66 ► Frianyl® FR PA ► Celanyl® XT PPA ► Frianyl® XT FR PPA Enabling wireless electronics via miniaturization and part consolidation. ► Laser Direct Structuring (LDS) compatible materials for complex circuits and smaller antennae ► High flow materials for thin walls and complex geometry ► High temperature resistance for Surface Mount Technology (SMT) Vectra® LCP for LDS is very high flow, high HDT, dimensionally stable, chemically resistant, low moisture absorbing, fast molding, non flashing and inherently non-flammable. • Molding resin containing laser activatable complex • Laser induces physio-chemical reaction to release metal seeds • Activated surface is metallized Laser Direct Structuring
  • 33. Celanese Corporation Engineered Materials ODMs & Molders ask for material and part reliability. End users demand fast and safe performance. We support new projects through the whole process, from material development to tool and part design. Global Customer Enabling Capabilities Locations Specialty Processing Specialty Processing Specialty Processing • Microscopy • Spectroscopy • Chromatography • Elemental Analysis • Wet Chemistry CAE/Part Design • Mold Flow Simulation • Structural Modeling • Part & Tool Optimization • Data Support Material Characterization • Thermal • Mechanical • Electrical • Flammability • Conductivity • Rheology Custom Application Testing Custom Application Testing Custom Application Testing Prototyping Support • Prototype Tool Design • Part Machining • Customer Consulting Processing Optimization • Injection Molding • Extrusion • Profile Extrusion • Blow Molding • Welding & Joining • Laser Marking • Color/Appearance • Environmental/Media Aging • Buckle, Hinge, Heat Sink Testing • Custom Pharma Development Support • Connector, CCM Testing • 2K Molding • Foaming • Ram/Gel Extrusion • Porous Sintering • Tribology (Friction, Wear) • High Speed Impact Testing • Filtration Device Testing • Connector, CCM Testing • Dynamic Warpage, Reflow • Membrane Characterization • Fatigue & Creep Testing • Odor / Emission, VOC, Formaldehyde • High Precision Molding • Membrane Processing Analytical Testing Americas Europe Asia External 33
  • 34. Celanese Corporation Why Celanese Engineered Materials for EV Charging Infrastructure ► The Infrastructure is always as good as their individual components ► Proven solutions for plugs & sockets ► Well established polymer families & FR technologies inside the charging columns ► CoolPoly® Technology for most efficient thermal management and EMI shielding ► Celstran® LFRT Technology for housings and mounting parts, EMI shielding ► Broad range of TPVs and TPEs for sealings, grip, strain relief and caps, auxiliary equipment ► Custom coloration for most grades Celanese – Broad Range of Material Solutions and Expert Support for your Charging Technology Projects 34 External
  • 35. Celanese Corporation Thank you for your attention! Stay Charged! Dr. Gulnaz Idiyatullina Global Program Manager – EV Charging Infrastructure Celanese Sales Germany GmbH Am Unisys-Park 1; 65843 Sulzbach (Taunus) e-mail: Gulnaz.Idiyatullina@Celanese.com 35 External
  • 36. Celanese Corporation Disclaimer & Notice to Users Disclaimer This publication was printed based on Celanese’s present state of knowledge, and Celanese undertakes no obligation to update it. Because conditions of product use are outside Celanese’s control, Celanese makes no warranties, express or implied, and assumes no liability in connection with any use of this information. Nothing herein is intended as a license to operate under or a recommendation to infringe any patents. Notice to Users Values shown are based on testing of laboratory test specimens and represent data that fall within the standard range of properties for natural material. These values alone do not represent a sufficient basis for any part design and are not intended for use in establishing maximum, minimum, or ranges of values for specification purposes. Colorants or other additives may cause significant variations in data values. Properties of molded parts can be influenced by a wide variety of factors including, but not limited to, material selection, additives, part design, processing conditions and environmental exposure. Any determination of the suitability of a particular material and part design for any use contemplated by the users and the manner of such use is the sole responsibility of the users, who must assure themselves that the material as subsequently processed meets the needs of their particular product or use. To the best of our knowledge, the information contained in this publication is accurate; however, we do not assume any liability whatsoever for the accuracy and completeness of such information. The information contained in this publication should not be construed as a promise or guarantee of specific properties of our products. It is the sole responsibility of the users to investigate whether any existing patents are infringed by the use of the materials mentioned in this publication. Moreover, there is a need to reduce human exposure to many materials to the lowest practical limits in view of possible adverse effects. To the extent that any hazards may have been mentioned in this publication, we neither suggest nor guarantee that such hazards are the only ones that exist. We recommend that persons intending to rely on any recommendation or to use any equipment, processing technique or material mentioned in this publication should satisfy themselves that they can meet all applicable safety and health standards. We strongly recommend that users seek and adhere to the manufacturer’s current instructions for handling each material they use, and entrust the handling of such material to adequately trained personnel only. The products mentioned herein are not intended for use in medical or dental implants. Hostaform® is a registered trademark of Hoechst GmbH, used by Celanese Corporation under license. Fortron® is a registered trademark of Fortron Industries LLC, used by Celanese Corporation under license. Celanese®, registered C-ball design and all other trademarks identified herein with ®, TM, SM, unless otherwise noted, are trademarks of Celanese or its affiliates. © 2022 Celanese or its affiliates. All rights reserved. Published June 2022. Americas 8040 Dixie Highway, Florence, KY 41042 USA Product Information Service t: +1-800-833-4882 t: +1-859-372-3244 Customer Service t: +1-800-526-4960 t: +1-859-372-3214 e: info-engineeredmaterials-am@celanese.com Europe Am Unisys-Park 1, 65843 Sulzbach, Germany Product Information Service t: +(00)-800-86427-531 t: +49-(0)-69-45009-1011 e: info-engineeredmaterials-eu@celanese.com Asia 4560 Jinke Road, Zhang Jiang Hi Tech Park Shanghai 201203 PRC Customer Service t: +86 21 3861 9266 f: +86 21 3861 9599 e: info-engineeredmaterials-asia@celanese.com Contact Information External 36