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Herbicide Classification by Mode of Action

•   Inhibit photosynthetic electron transport
•   Inhibit amino acid biosynthesis
•   Inhibit protoporphyrinogen oxidase
•   Inhibit lipid biosynthesis (ACCase inhibitors)
•   Act as growth regulators
•   Inhibit carotenoid biosynthesis
•   Inhibit seeding growth
Inhibit photosynthetic electron
                transport
Herbicide      Common                 Trade
Family         Name                   Name
Triazines      atrazine               AAtrex
               ametryn                Evik
               simazine               Princep
               cyanazine              Bladex
               metribuzin             Sencor,Lexone
               hexazinone             Velpar
               atrazine + cyanazine   Extrazine II
Triazines
• Stop photosynthesis: you see yellowing
• Mobile in plant and environment (move on
  soil off site)
• pH—low pH are soil bound (unavailable),
  high pH are available for plant uptake
• Low pH, lime increases pH, used high
  atrazine on corn, then plant small grains get
  injury
Inhibit photosynthetic electron
              transport
Herbicide     Common         Trade
Family        Name           Name
Phenylureas   linuron        Lorox
              tebuthiuron    Spike
              diuron         Karmex
              siduron        Tuperson
              fluormeturon   Cotoran
Phenylureas
• Mobile in plant
Inhibit photosynthetic electron
              transport
Herbicide    Common       Trade
Family       Name         Name
Uracils      bromacil     Hyvar
             terbacil     Sinbar
Uracils
• Mobil in plant
• Symptoms
  – Bleaching and yellowing
Inhibit photosynthetic electron
              transport
Herbicide    Common        Trade
Family       Name          Name
Diazinones   bentazon      Basagran
             pyridate      Tough
             chloridazon   Pyramin
Diazinones
• Do not move in plant—contact activity
Inhibit photosynthetic electron
              transport
Herbicide     Common      Trade
Family        Name        Name
Bipyridyliums paraquat    Gramoxone
                          Extra
              diquat      Diquat
Bipyridyliums
• Do not move in plant—contact activity
Inhibit photosynthetic electron
               transport
Herbicide       Common       Trade
Family          Name         Name
Benzonitriles   bromoxynil   Buctril
Benzonitriles
• Does not move in plant
Inhibit amino acid biosynthesis
            (ALS)—Imi’s
Herbicide      Common        Trade
Family         Name          Name
Imidazolinones imazethapyr   Pursuit
               imazaquin     Scepter
               imazapyr      Arsenal
               imazamethabenz Assert
               imazamox      Raptor
     imazapyr+ imazethapyr   Lightning
Imidazolinones (Imi’s)
• ALS: block an enzyme so the plant cannot make
  certain amino acids
• Scepter/Imi’s need rain to activate—in a dry year
  there is carryover to the next crop
• long lived in environment
• Symptoms:
   – prunes roots
   – purpling and stunted plant
   – bright yellow areas in whorl of plant
Inhibit amino acid biosynthesis
            (ALS)—SU’s
Herbicide       Common          Trade
Family          Name            Name
Sulfonylureas   bensulfuron     Londax
                chlorimuron     Classic
                chlorsulfuron   Glean, Telar
                metsulfuron     Ally
                nicosulfuron    Accent
                primisulfuron   Beacon
                sufometuron     Oust
Sulfonylureas (SU’s)
• ALS: block an enzyme so the plant cannot make
  certain amino acids
• Soilborne
• Symptoms:
   – Pruned roots
   – Short plant
   – Yellowing in whorl
• Permit—in very warm temperature, actively
  growing corn has a tough time growing = late
  season “buggy whipping”
Sulfonylureas (SU’s) cont.
• Lime amended slug = high pH = SU
  carryover
• Low to normal pH (<6.0-6.5) = microbes
  work to break down hericide = no carryover
  = good
• High pH (>6.5) slows microbial activity and
  hydrolysis stops = Bad!
Inhibit amino acid biosynthesis
             (ALS)—SU’s
Herbicide       Common           Trade
Family          Name             Name
Sulfonylureas   thifensulfuron   Harmony GT
                triasulfuron     Amber
                tribenuron       Express
                thifensulfuron   Harmony
                + tribenuron     Extra
                Halosulfuron     Permit,Battalion
                rimsulfuron      Matrix
                prosulfuron      Peak
Inhibit amino acid biosynthesis
             (ALS)—SU’s
Herbicide       Common           Trade
Family          Name             Name
Sulfonylureas   primisulfuron+
                prosulfuron      Exceed,Spirit
                rimsulfuron +
                thifensulfuron   Basis
                sulfosulfuron    Maverick
Inhibit amino acid biosynthesis
               (ALS)
Herbicide      Common        Trade
Family         Name          Name
Sulfonamides   flumetsulam   Python
Sulfonamides
• ALS: block an enzyme so the plant cannot
  make certain amino acids
• Cold, wet damage is worse because plant is
  not actively growing—does not metabolize
  herbicide
• Symptoms:
  – Purpling
  – stunting
Inhibit amino acid biosynthesis
Herbicide     Common       Trade
Family        Name         Name
Phosphono     glyphosate   Roundup,
Amino Acid                 Touchdown
Derivatives
Phosphono amino acid
            derivatives
• Roundup blocks an emzyme—not a
  photosynthesis inhibitor
• Symptoms:
  – Yellow band where spray droplet landed (stays
    yellow all season)
  – Will kill Non-Roundup Ready Corn
Inhibit protporphyringen oxidase
               (PPO’S)
Herbicide       Common          Trade
Family          Name            Name
Diphenyl ethers acifluorofen    Blazer
                lactofen        Cobra
                fomesafen       Reflex
                oxyfluorofen    Goal
Oxadiazoles     sulfentrazone   Authority
PPO’s
• Another enzyme system is blocked
• Symptoms:
  – Bronzing (contact burn)
Inhibit lipid biosynthesis (ACCase
               Inhibitors)
Herbicide           Common               Trade
Family              Name          Name
Aryloxyphenoxy-     diclofop             Hoelon
Propionates         fluazifop            Fusilade DX
(ACC-fop)           fenoxaprop           OptionII,Acclaim
                    quizalofop           Assure II
                    fluazifop +          Fusion
                    fenoxaprop
Cyclohexanediones   sethoxydim           Poast, Poast Plus
(Acc-dim)           clethodim            Select
ACCase Inhibitors
• Works on enzyem system—goes to
  meristem and kills it
• Post grass products in soybeans
Act as growth regulators
Herbicide       Common     Trade
Family          Name       Name
Phenoxys        2, 4-D     Many
                MCPP       Many
                MCPA       Many
                2, 4-D B   Butyrac,
                           Butoxone
Benzoic acids   dicamba    Banvel,
                           Clarity,
                           Distinct
Growth Regulators: Oldest compounds

• Symptoms:
  – Distortion in plant growth
  – Bending of corn, twisting of leaves
  – Fusion of brace roots
  – If applied too late, kills ear—no kernals, can stop the
    development of seed head in small grains
  – Cupping in leaves upward (2, 4D)
  – Cupping in leaves downward (dicamba) = “Cobra
    Head”
Act as a growth regulator
Herbicide   Common       Trade
Family      Name         Name
Pyridines   picloram     Tordon
            clopyralid   Stinger
            triclopyr    Garlon
Inhibit carotenoid biosynthesis
        (Pigment inhibitors)
Herbicide       Common        Trade
Family          Name          Name
Isoxazolidinones clomazone    Command
Pyridazinones norflurazon     Zorial,
                              Solicam
Isoxazoles     isoxaflutole   Balance
Pigment inhibitors
• Symptoms:
  – Bleach leaves—turn white
  – Carryover in small grains with Command—
    white plants
Inhibit seedling growth (Shoot
               inhibitors)
Herbicide        Common         Trade
Family           Name           Name
Chloroacetamides metolachlor    Dual
                 alachlor       lasso,
                                Micro-Tech
                 propachlor     Ramrod
                 acetachlor     Harness,
                                Surpass
                 dimethenamid   Frontier
Shoot inhibitors (Chloroacetamides)

• Main group outside of permit
• Symptoms:
  – Typical “buggy whipping” early in season
  – Puckering on soybeans with Dual, Lasso,
    Frontier
     • V-shape at puckering at leaf tip
     • Favored by cold, wet conditions
Inhibit seedling growth (Shoot
              inhibitors)
Herbicide      Common          Trade
Family         Name            Name
Thiocarbamates EPTC            Eptam
               EPTC + safener Eradicane
               butylate+safener Sutan Plus
Shoot inhibitors (Thiocarbamates)

• Incorporated products
• Thio=sulfur
• Symptoms:
  – “buggy whipping” early in season
  – Puckering on soybeans
Inhibit seedling growth (Root
         inhibitors – DNA’s)
Herbicide       Common          Trade
Family          Name            Name
Dinitroanalines trifluralin     Treflan, etc
                ethafluralin    Sonalan
                penimethanlin   Prowl
                benefin         Balan
                oryzalin        Surflan
Root inhibitors (Dinitroanalines)
• Important group
• Proves brittle bean syndrome
• Symptoms:
  – Pruned roots, stubby

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Herbicide classification by mode of action

  • 1. Herbicide Classification by Mode of Action • Inhibit photosynthetic electron transport • Inhibit amino acid biosynthesis • Inhibit protoporphyrinogen oxidase • Inhibit lipid biosynthesis (ACCase inhibitors) • Act as growth regulators • Inhibit carotenoid biosynthesis • Inhibit seeding growth
  • 2. Inhibit photosynthetic electron transport Herbicide Common Trade Family Name Name Triazines atrazine AAtrex ametryn Evik simazine Princep cyanazine Bladex metribuzin Sencor,Lexone hexazinone Velpar atrazine + cyanazine Extrazine II
  • 3. Triazines • Stop photosynthesis: you see yellowing • Mobile in plant and environment (move on soil off site) • pH—low pH are soil bound (unavailable), high pH are available for plant uptake • Low pH, lime increases pH, used high atrazine on corn, then plant small grains get injury
  • 4. Inhibit photosynthetic electron transport Herbicide Common Trade Family Name Name Phenylureas linuron Lorox tebuthiuron Spike diuron Karmex siduron Tuperson fluormeturon Cotoran
  • 6. Inhibit photosynthetic electron transport Herbicide Common Trade Family Name Name Uracils bromacil Hyvar terbacil Sinbar
  • 7. Uracils • Mobil in plant • Symptoms – Bleaching and yellowing
  • 8. Inhibit photosynthetic electron transport Herbicide Common Trade Family Name Name Diazinones bentazon Basagran pyridate Tough chloridazon Pyramin
  • 9. Diazinones • Do not move in plant—contact activity
  • 10. Inhibit photosynthetic electron transport Herbicide Common Trade Family Name Name Bipyridyliums paraquat Gramoxone Extra diquat Diquat
  • 11. Bipyridyliums • Do not move in plant—contact activity
  • 12. Inhibit photosynthetic electron transport Herbicide Common Trade Family Name Name Benzonitriles bromoxynil Buctril
  • 13. Benzonitriles • Does not move in plant
  • 14. Inhibit amino acid biosynthesis (ALS)—Imi’s Herbicide Common Trade Family Name Name Imidazolinones imazethapyr Pursuit imazaquin Scepter imazapyr Arsenal imazamethabenz Assert imazamox Raptor imazapyr+ imazethapyr Lightning
  • 15. Imidazolinones (Imi’s) • ALS: block an enzyme so the plant cannot make certain amino acids • Scepter/Imi’s need rain to activate—in a dry year there is carryover to the next crop • long lived in environment • Symptoms: – prunes roots – purpling and stunted plant – bright yellow areas in whorl of plant
  • 16. Inhibit amino acid biosynthesis (ALS)—SU’s Herbicide Common Trade Family Name Name Sulfonylureas bensulfuron Londax chlorimuron Classic chlorsulfuron Glean, Telar metsulfuron Ally nicosulfuron Accent primisulfuron Beacon sufometuron Oust
  • 17. Sulfonylureas (SU’s) • ALS: block an enzyme so the plant cannot make certain amino acids • Soilborne • Symptoms: – Pruned roots – Short plant – Yellowing in whorl • Permit—in very warm temperature, actively growing corn has a tough time growing = late season “buggy whipping”
  • 18. Sulfonylureas (SU’s) cont. • Lime amended slug = high pH = SU carryover • Low to normal pH (<6.0-6.5) = microbes work to break down hericide = no carryover = good • High pH (>6.5) slows microbial activity and hydrolysis stops = Bad!
  • 19. Inhibit amino acid biosynthesis (ALS)—SU’s Herbicide Common Trade Family Name Name Sulfonylureas thifensulfuron Harmony GT triasulfuron Amber tribenuron Express thifensulfuron Harmony + tribenuron Extra Halosulfuron Permit,Battalion rimsulfuron Matrix prosulfuron Peak
  • 20. Inhibit amino acid biosynthesis (ALS)—SU’s Herbicide Common Trade Family Name Name Sulfonylureas primisulfuron+ prosulfuron Exceed,Spirit rimsulfuron + thifensulfuron Basis sulfosulfuron Maverick
  • 21. Inhibit amino acid biosynthesis (ALS) Herbicide Common Trade Family Name Name Sulfonamides flumetsulam Python
  • 22. Sulfonamides • ALS: block an enzyme so the plant cannot make certain amino acids • Cold, wet damage is worse because plant is not actively growing—does not metabolize herbicide • Symptoms: – Purpling – stunting
  • 23. Inhibit amino acid biosynthesis Herbicide Common Trade Family Name Name Phosphono glyphosate Roundup, Amino Acid Touchdown Derivatives
  • 24. Phosphono amino acid derivatives • Roundup blocks an emzyme—not a photosynthesis inhibitor • Symptoms: – Yellow band where spray droplet landed (stays yellow all season) – Will kill Non-Roundup Ready Corn
  • 25. Inhibit protporphyringen oxidase (PPO’S) Herbicide Common Trade Family Name Name Diphenyl ethers acifluorofen Blazer lactofen Cobra fomesafen Reflex oxyfluorofen Goal Oxadiazoles sulfentrazone Authority
  • 26. PPO’s • Another enzyme system is blocked • Symptoms: – Bronzing (contact burn)
  • 27. Inhibit lipid biosynthesis (ACCase Inhibitors) Herbicide Common Trade Family Name Name Aryloxyphenoxy- diclofop Hoelon Propionates fluazifop Fusilade DX (ACC-fop) fenoxaprop OptionII,Acclaim quizalofop Assure II fluazifop + Fusion fenoxaprop Cyclohexanediones sethoxydim Poast, Poast Plus (Acc-dim) clethodim Select
  • 28. ACCase Inhibitors • Works on enzyem system—goes to meristem and kills it • Post grass products in soybeans
  • 29. Act as growth regulators Herbicide Common Trade Family Name Name Phenoxys 2, 4-D Many MCPP Many MCPA Many 2, 4-D B Butyrac, Butoxone Benzoic acids dicamba Banvel, Clarity, Distinct
  • 30. Growth Regulators: Oldest compounds • Symptoms: – Distortion in plant growth – Bending of corn, twisting of leaves – Fusion of brace roots – If applied too late, kills ear—no kernals, can stop the development of seed head in small grains – Cupping in leaves upward (2, 4D) – Cupping in leaves downward (dicamba) = “Cobra Head”
  • 31. Act as a growth regulator Herbicide Common Trade Family Name Name Pyridines picloram Tordon clopyralid Stinger triclopyr Garlon
  • 32. Inhibit carotenoid biosynthesis (Pigment inhibitors) Herbicide Common Trade Family Name Name Isoxazolidinones clomazone Command Pyridazinones norflurazon Zorial, Solicam Isoxazoles isoxaflutole Balance
  • 33. Pigment inhibitors • Symptoms: – Bleach leaves—turn white – Carryover in small grains with Command— white plants
  • 34. Inhibit seedling growth (Shoot inhibitors) Herbicide Common Trade Family Name Name Chloroacetamides metolachlor Dual alachlor lasso, Micro-Tech propachlor Ramrod acetachlor Harness, Surpass dimethenamid Frontier
  • 35. Shoot inhibitors (Chloroacetamides) • Main group outside of permit • Symptoms: – Typical “buggy whipping” early in season – Puckering on soybeans with Dual, Lasso, Frontier • V-shape at puckering at leaf tip • Favored by cold, wet conditions
  • 36. Inhibit seedling growth (Shoot inhibitors) Herbicide Common Trade Family Name Name Thiocarbamates EPTC Eptam EPTC + safener Eradicane butylate+safener Sutan Plus
  • 37. Shoot inhibitors (Thiocarbamates) • Incorporated products • Thio=sulfur • Symptoms: – “buggy whipping” early in season – Puckering on soybeans
  • 38. Inhibit seedling growth (Root inhibitors – DNA’s) Herbicide Common Trade Family Name Name Dinitroanalines trifluralin Treflan, etc ethafluralin Sonalan penimethanlin Prowl benefin Balan oryzalin Surflan
  • 39. Root inhibitors (Dinitroanalines) • Important group • Proves brittle bean syndrome • Symptoms: – Pruned roots, stubby

Editor's Notes

  1. Diphenyl ethers are all post emergence—contact, and the oxadiazole is a soil applied