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GROUP 7
        ARINA IRMAN
NIK NURUL FATIHAH MOHD NOOR
 MUHAMMAD SYAMSUL MAARIF
   Was developed in 1953 by Bayer in Germany,
    and General Electric in US independently.

   one of the high performance heterochain
    polymeric material that comprises the family
    of engineering thermoplastic
•PC molecule composed by a bisphenol A part and carbonate
group
•Bisphenol A contain two aromatic ring which are responsible for
PC stiff backbone
•Bisphenol also contribute to PC inability to crystallize
•It contribute to be amorphous and give the polymer transparency
•High glass transition temperature (Tg=145°C)
1) Bisphenol A
group reactted
with proton
acceptor such
as NaOH to
obtained the
polyemrization
functional
group
2) The
deprotonataed
Bisphenol A
reacts with
Phosgene and a
catalyst at
temperature
beteween 25-35
degree
PROPERTIES         DESCRIPTION
Temperature        •Glass transition : 145ᵒC
                   •Melting point : 225ᵒC
Amorphous          1.20 g/cm3
density
Molecular weight   254.3 g/mol
Resistance         •Excellent : dilute acids and mineral oils
                   •Good : Alcohols and vegetable oils
                   •Limited : Aldehydes
                   •Poor : Concentrated Acids, Bases, Esters, Aliphatic
                   Hydrocarbons, Aromatic Hydrocarbons, Halogenated
                   Hydrocarbons, Ketones and Oxidizing Agents.
ADVANTAGES                         DISADVANTAGES
Strength                            Production
•High & lightweight                 •High processing temperature
•Tough & stable
•Resist temperature to 120ᵒC
UV protection                       Resistant
•‘bloom’ when exposed to sunlight   •Poor resistant to alkalies

Easy to modify                      Needs UV stabilization
•Safe to machine
   Combination of diisocyanate
   Thermoplastic
   Common comercial polymer, and can process
    amazingly diverse properties depending on
    how they are manufactured
   The present of both amide and carbamide
    give the characteristic of plastic in this
    polymer
   General component
   synthesis
PROPERTIES    DESCRIPTION

Mechanical    •Resistance to further tearing
              •Resistance to abrasion

Electrical    Surface resistance

Fabrication   •High : strength (impact, tensile, shear, and flexural),
              modulus of elasticity
              •Excellent : strength retention at elevated
              temperatures, flow resistance (creep and cold)
              •Low : deformation under load, coefficient of thermal
              expansion
              •good electrical insulation properties
              •easy to fabricate
Others        •Microbial resistance of PUR
              •Resistance to media
              •Resistance to atmospheric corrosion
              •Fire resistance
ADVANTAGES                      DISADVANTAGES
Abrasion resistant               Durability
•outwear other materials         •hydroscopic tendencies

Load bearing capacity            Odour
•High, ideal material for load   •petroleum-based chemical,flame
wheels, heavy duty couplings     retardant fumes cause physical
                                 problems; this becomes irritating.
Weather resistant                Health Problems
•resistance to oxygen, ozone,    •releases toxic fumes (symptom :
sunlight and general weather     allergic reactions, rashes, difficulty
conditions                       breathing, loss of consciousness,
                                 blindness)
Excellent noise abatement        Environmental Issues
properties                       •blowing agents produce
•used to replace rubbers for     greenhouse gases
improved sound/vibration
dampening
POLYCARBONATE                POLYURETHRANE
•Electronic components       •Belts
•Construction materials      •Prototype machined parts
•Data storage                •Wood finishing
•Automotive, aircraft, and   •Furniture
security components          •Automobile seats
•Niche applications          •Houses, sculptures, and
•Medical applications        decorations

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Group 7 edited 2

  • 1. GROUP 7 ARINA IRMAN NIK NURUL FATIHAH MOHD NOOR MUHAMMAD SYAMSUL MAARIF
  • 2. Was developed in 1953 by Bayer in Germany, and General Electric in US independently.  one of the high performance heterochain polymeric material that comprises the family of engineering thermoplastic
  • 3. •PC molecule composed by a bisphenol A part and carbonate group •Bisphenol A contain two aromatic ring which are responsible for PC stiff backbone •Bisphenol also contribute to PC inability to crystallize •It contribute to be amorphous and give the polymer transparency •High glass transition temperature (Tg=145°C)
  • 4. 1) Bisphenol A group reactted with proton acceptor such as NaOH to obtained the polyemrization functional group
  • 5. 2) The deprotonataed Bisphenol A reacts with Phosgene and a catalyst at temperature beteween 25-35 degree
  • 6. PROPERTIES DESCRIPTION Temperature •Glass transition : 145ᵒC •Melting point : 225ᵒC Amorphous 1.20 g/cm3 density Molecular weight 254.3 g/mol Resistance •Excellent : dilute acids and mineral oils •Good : Alcohols and vegetable oils •Limited : Aldehydes •Poor : Concentrated Acids, Bases, Esters, Aliphatic Hydrocarbons, Aromatic Hydrocarbons, Halogenated Hydrocarbons, Ketones and Oxidizing Agents.
  • 7. ADVANTAGES DISADVANTAGES Strength Production •High & lightweight •High processing temperature •Tough & stable •Resist temperature to 120ᵒC UV protection Resistant •‘bloom’ when exposed to sunlight •Poor resistant to alkalies Easy to modify Needs UV stabilization •Safe to machine
  • 8. Combination of diisocyanate  Thermoplastic  Common comercial polymer, and can process amazingly diverse properties depending on how they are manufactured  The present of both amide and carbamide give the characteristic of plastic in this polymer
  • 9. General component
  • 10. synthesis
  • 11. PROPERTIES DESCRIPTION Mechanical •Resistance to further tearing •Resistance to abrasion Electrical Surface resistance Fabrication •High : strength (impact, tensile, shear, and flexural), modulus of elasticity •Excellent : strength retention at elevated temperatures, flow resistance (creep and cold) •Low : deformation under load, coefficient of thermal expansion •good electrical insulation properties •easy to fabricate Others •Microbial resistance of PUR •Resistance to media •Resistance to atmospheric corrosion •Fire resistance
  • 12. ADVANTAGES DISADVANTAGES Abrasion resistant Durability •outwear other materials •hydroscopic tendencies Load bearing capacity Odour •High, ideal material for load •petroleum-based chemical,flame wheels, heavy duty couplings retardant fumes cause physical problems; this becomes irritating. Weather resistant Health Problems •resistance to oxygen, ozone, •releases toxic fumes (symptom : sunlight and general weather allergic reactions, rashes, difficulty conditions breathing, loss of consciousness, blindness) Excellent noise abatement Environmental Issues properties •blowing agents produce •used to replace rubbers for greenhouse gases improved sound/vibration dampening
  • 13. POLYCARBONATE POLYURETHRANE •Electronic components •Belts •Construction materials •Prototype machined parts •Data storage •Wood finishing •Automotive, aircraft, and •Furniture security components •Automobile seats •Niche applications •Houses, sculptures, and •Medical applications decorations