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FIBER
TYPES
• Glass Fiber
• Carbon Fiber
• Graphite Fiber
• Aramid Fiber
• Boron Fiber
• Ceramic Fiber
Glass Fiber
• Common for Polymeric Matrix
• Advantages
• Low Cost
• High tensile strength
• High chemical resistance
• Excellent insulating property
• Disadvantages
• Low Modulus
• High specific gravity (relatively)
• Sensitive to abrasion( due to handling)
• Low fatigue resistance and high hardness leads to wear
TYPES OF GLASS FIBER
• E-Glass – E stands for electrical
• S-Glass – S stands for high silica content
» High thermal expansion coefficient
» High fatigue strength
• C-Glass – C stands for Corrosion
» Used in Chemical applications
» Storage tanks
• R-Glass – R stands for Rigid
» Structural applications
• D-Glass – D stands for Dielectric
» Low dielectric constants
• A-Glass – A Stands for appearance
» To improve surface appearance
» For ornamental works
• E-CR Glass – E-CR stands for Electrical and corrosion
resistance
• AR Glass – AR stands for Alkali resistance
PROPERTIES OF GLASS FIBER
Property E – Glass S – Glass
Specific Gravity 2.54 2.49
Young’s Modulus
(GPa)
72.4 85.5
Tensile Strength
(MPa)
3447 4585
Thermal Expansion
Coefficient
5.04 5.58
COMPOSITION OF GLASS FIBER
Material % by Weight
E – Glass S – Glass
Sio2 54 64
Al2O3 15 25
Ca2O3 17 0.01
MgO 4.5 10
B2O3 8 0.01
Others 1.5 0.8
Glass fiber Manufacturing
• Raw Material –
Sand, Alumina &
Lime Stone
Processing
Temperature:
1400 Degree C
for 45 Minutes
Pulled Through
Platinum Nozzles
CARBON FIBER
• Advantages
– High tensile strength to weight ratio
– High tensile modulus to weight ratio (due to graphitic
form of carbon)
– Low cost
– Low specific gravity
– Low thermal coefficient of expansion (Dimensionally
stable)
• Disadvantages
– Low impact resistance
– High electrical conductivity
• Carbon Fiber – 93 to 95 % of Carbon
• Graphite Fiber - > 99 % of Carbon
• Precursor Material
» Rayon
» PolyAcryloNitrile (PAN)
» Pitch
Spinnaret
Carbon fiber Manufacturing
PROPERTIES OF GRAPHITE
FIBER
Property Pitch PAN
Specific Gravity 1.99 1.78
Youngs Modulus
(GPa)
379.2 241.3
Tensile Strength
(MPa)
1723 3447
Thermal Expansion
Coefficient
-0.54 -1.26
ARAMID FIBERS
• Principle Constituents are
» C, H2, O2 & Nitrogen
• Advantages
» Low Density
» High Tensile Strength
» Low Cost
» High Impact Resistance
• Disadvantages
» Low Compressive properties
» Degrades under Sunlight
• Two Types
» Kevlar 29
» Kevlar 49
• Specific Stiffness of Kevlar 49 is high
when compared with Kevlar 29
• Kevlar 29 – Used in Bullet Proof vests,
Ropes and Cables
• Kevlar 49 – Aircraft Industry
PROPERTIES OF ARAMID FIBER
Property Kevlar 29 Kevlar 49
Specific Gravity 1.44 1.48
Youngs Modulus
(GPa)
62.05 131
Tensile Strength
(MPa)
3620 3620
Thermal Expansion
Coefficient
-2 -2
Characteristics of KEVLAR 49 Fiber
• Though tensile stress strain curve is linear fiber fracture is preceded
by fragmentation, splintering and even localized drawing.
• In bending Kevlar 49 fiber exhibit yielding on compression side. This
non-catastrophic failure leads to damage tolerance against impact or
dynamic loading.
• Use temperature recommended is 160 c
• Chemical resistance is good.
• Sensitive to ultra violet (add fillers to reduce)
• Prolong direct exposure to sunlight causes to dis- coloration and
loss in tensile strength ( problem is less in laminates)
• Hygroscopic and can absorb 6% moisture, however has less effect
• Low thermal conductivity and high damping coefficient
BORON FIBER
• High tensile Modulus
• Resistance to buckling
• High cost therefore restricted application.
Manufacturing
• By chemical vapor deposition of Boron on heated
substrate [Tungsten or carbon filament]
• Tungsten wire(0.0127 in dia) is pulled through a reaction
chamber[ 2Bcl3+3H2=2B+6Hcl] in which boron is
deposited on its surface at 1100-1300c
• Fiber diameter is controlled by pulling speed or
deposition temperature.
CERAMIC FIBER
• Silicon carbide and aluminum oxide fibers
are examples of ceramic fibers
• Best suited for Metal and Ceramic matrix
• High temperature application
• Monofilaments that are produced by Sic
on a 25 μm dia carbon filament substrate
( coated with pyrolitic graphite for
smoothening the surface
CLASSIFICATION OF
POLYMERIC RESINS
• Thermoplastics
» Weak bond – Vander Wall’s type
» Formable at high temperature
» Can be reprocessed
» Short cure cycle
» Excellent solvent resistance
» Polyethylene, polystyrene, polyether-ether-ketone
(PEEK), polyphenylene sulfide (PPS)
• Thermosets
POLYMERIC MATRIX
• Epoxy
• Polyester
• Phenolic
• Acrylic
• Urethane
• Polyamide
• Polyester
» Low cost
» Translucent in nature
» Operating temperature should be < 70 degree
» Brittleness
» High shrinkage rate
• Phenolic
» Low cost
» High mechanical strength
» High void content
• Epoxy
» High mechanical strength
» Good adhesive nature
» Low viscosity
» Low volatility
» Low shrinkage rate
» High cost
PROPERTY COMPARISON OF
RESINS
PROPERTIES OF EPOXY RESIN
Property Epoxy
Resin
Specific Gravity 1.28
Youngs Modulus
(GPa)
3.792
Tensile Strength
(MPa)
82.74
Incorporation of fiber into matrix
• Finished Structure
• Ready to mold sheets
Ready to mold fiber reinforced polymer
sheets are available in two forms
• Prepregs
• Sheet Molding Compounds
PREPREG
• Prepregs – Thin sheets of fibers impregnated
with predetermined amounts of uniformly
distributed polymeric matrix
• Width of prepregs sheets vary between 25 mm
to 457mm
• Sheets wider than 47 mm are Broad goods
• Thickness range from 0.13 – 0.25 mm
• Resin content is between 30 – 45 % by weight
• Normal Shelf life 6 – 8 days at 23 deg c
• When stored at – 18 deg C it can prolong upto 6
months
Prepreg Manufacturing
Sheet Molding Compound
(SMC)
– Chopped glass fiber added to polyester resin
mixture
Types of SMC
• SMC – R SMC – CR XMC
Material Forms
• Textile forms
–Braiding or weaving
• Tubular braided form
– can be flattened and cut for non-tubular
products
Fabric effects on material
properties

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FIBER AND MATRIX.ppt

  • 2. TYPES • Glass Fiber • Carbon Fiber • Graphite Fiber • Aramid Fiber • Boron Fiber • Ceramic Fiber
  • 3. Glass Fiber • Common for Polymeric Matrix • Advantages • Low Cost • High tensile strength • High chemical resistance • Excellent insulating property • Disadvantages • Low Modulus • High specific gravity (relatively) • Sensitive to abrasion( due to handling) • Low fatigue resistance and high hardness leads to wear
  • 4. TYPES OF GLASS FIBER • E-Glass – E stands for electrical • S-Glass – S stands for high silica content » High thermal expansion coefficient » High fatigue strength • C-Glass – C stands for Corrosion » Used in Chemical applications » Storage tanks • R-Glass – R stands for Rigid » Structural applications • D-Glass – D stands for Dielectric » Low dielectric constants • A-Glass – A Stands for appearance » To improve surface appearance » For ornamental works • E-CR Glass – E-CR stands for Electrical and corrosion resistance • AR Glass – AR stands for Alkali resistance
  • 5. PROPERTIES OF GLASS FIBER Property E – Glass S – Glass Specific Gravity 2.54 2.49 Young’s Modulus (GPa) 72.4 85.5 Tensile Strength (MPa) 3447 4585 Thermal Expansion Coefficient 5.04 5.58
  • 6. COMPOSITION OF GLASS FIBER Material % by Weight E – Glass S – Glass Sio2 54 64 Al2O3 15 25 Ca2O3 17 0.01 MgO 4.5 10 B2O3 8 0.01 Others 1.5 0.8
  • 7. Glass fiber Manufacturing • Raw Material – Sand, Alumina & Lime Stone Processing Temperature: 1400 Degree C for 45 Minutes Pulled Through Platinum Nozzles
  • 8. CARBON FIBER • Advantages – High tensile strength to weight ratio – High tensile modulus to weight ratio (due to graphitic form of carbon) – Low cost – Low specific gravity – Low thermal coefficient of expansion (Dimensionally stable) • Disadvantages – Low impact resistance – High electrical conductivity
  • 9. • Carbon Fiber – 93 to 95 % of Carbon • Graphite Fiber - > 99 % of Carbon • Precursor Material » Rayon » PolyAcryloNitrile (PAN) » Pitch
  • 10.
  • 13.
  • 14. PROPERTIES OF GRAPHITE FIBER Property Pitch PAN Specific Gravity 1.99 1.78 Youngs Modulus (GPa) 379.2 241.3 Tensile Strength (MPa) 1723 3447 Thermal Expansion Coefficient -0.54 -1.26
  • 15. ARAMID FIBERS • Principle Constituents are » C, H2, O2 & Nitrogen • Advantages » Low Density » High Tensile Strength » Low Cost » High Impact Resistance • Disadvantages » Low Compressive properties » Degrades under Sunlight • Two Types » Kevlar 29 » Kevlar 49
  • 16. • Specific Stiffness of Kevlar 49 is high when compared with Kevlar 29 • Kevlar 29 – Used in Bullet Proof vests, Ropes and Cables • Kevlar 49 – Aircraft Industry
  • 17. PROPERTIES OF ARAMID FIBER Property Kevlar 29 Kevlar 49 Specific Gravity 1.44 1.48 Youngs Modulus (GPa) 62.05 131 Tensile Strength (MPa) 3620 3620 Thermal Expansion Coefficient -2 -2
  • 18. Characteristics of KEVLAR 49 Fiber • Though tensile stress strain curve is linear fiber fracture is preceded by fragmentation, splintering and even localized drawing. • In bending Kevlar 49 fiber exhibit yielding on compression side. This non-catastrophic failure leads to damage tolerance against impact or dynamic loading. • Use temperature recommended is 160 c • Chemical resistance is good. • Sensitive to ultra violet (add fillers to reduce) • Prolong direct exposure to sunlight causes to dis- coloration and loss in tensile strength ( problem is less in laminates) • Hygroscopic and can absorb 6% moisture, however has less effect • Low thermal conductivity and high damping coefficient
  • 19. BORON FIBER • High tensile Modulus • Resistance to buckling • High cost therefore restricted application. Manufacturing • By chemical vapor deposition of Boron on heated substrate [Tungsten or carbon filament] • Tungsten wire(0.0127 in dia) is pulled through a reaction chamber[ 2Bcl3+3H2=2B+6Hcl] in which boron is deposited on its surface at 1100-1300c • Fiber diameter is controlled by pulling speed or deposition temperature.
  • 20. CERAMIC FIBER • Silicon carbide and aluminum oxide fibers are examples of ceramic fibers • Best suited for Metal and Ceramic matrix • High temperature application • Monofilaments that are produced by Sic on a 25 μm dia carbon filament substrate ( coated with pyrolitic graphite for smoothening the surface
  • 21.
  • 22. CLASSIFICATION OF POLYMERIC RESINS • Thermoplastics » Weak bond – Vander Wall’s type » Formable at high temperature » Can be reprocessed » Short cure cycle » Excellent solvent resistance » Polyethylene, polystyrene, polyether-ether-ketone (PEEK), polyphenylene sulfide (PPS) • Thermosets
  • 23. POLYMERIC MATRIX • Epoxy • Polyester • Phenolic • Acrylic • Urethane • Polyamide
  • 24. • Polyester » Low cost » Translucent in nature » Operating temperature should be < 70 degree » Brittleness » High shrinkage rate • Phenolic » Low cost » High mechanical strength » High void content • Epoxy » High mechanical strength » Good adhesive nature » Low viscosity » Low volatility » Low shrinkage rate » High cost
  • 26. PROPERTIES OF EPOXY RESIN Property Epoxy Resin Specific Gravity 1.28 Youngs Modulus (GPa) 3.792 Tensile Strength (MPa) 82.74
  • 27. Incorporation of fiber into matrix • Finished Structure • Ready to mold sheets Ready to mold fiber reinforced polymer sheets are available in two forms • Prepregs • Sheet Molding Compounds
  • 28. PREPREG • Prepregs – Thin sheets of fibers impregnated with predetermined amounts of uniformly distributed polymeric matrix • Width of prepregs sheets vary between 25 mm to 457mm • Sheets wider than 47 mm are Broad goods • Thickness range from 0.13 – 0.25 mm • Resin content is between 30 – 45 % by weight • Normal Shelf life 6 – 8 days at 23 deg c • When stored at – 18 deg C it can prolong upto 6 months
  • 30. Sheet Molding Compound (SMC) – Chopped glass fiber added to polyester resin mixture
  • 31. Types of SMC • SMC – R SMC – CR XMC
  • 32. Material Forms • Textile forms –Braiding or weaving • Tubular braided form – can be flattened and cut for non-tubular products
  • 33. Fabric effects on material properties