ORGANIC CHEMISTRY
PREPARED BY:
FARHAN AHMAD
What are elimination reactions? Discuss in
detail.
Elimination reactions:
 The elimination reaction is an organic reaction in which two
substituents are removed from a molecule to form a new product.
 This process takes place in the presence of acid, base, metal and
sometimes through heating.
 Through this process it is possible to synthesize unsaturated organic
compounds from saturated ones.
 The elimination is mechanically the reverse of the addition reaction.
Steps involves in elimination reactions:
The elimination reaction involves three fundamental steps:
 Removal of proton
 Formation of C=C pi bond
 Breaking of the bond to leaving group.2
Nomenclatures used in elimination reaction:
 When a hydrogen atom is removed from the compound as a proton,
the process is called deprotonation.
 If a halogen is removed then it is called dehalogenation.
 If both hydrogen and halogen are removed, then it is called
dehydrohalogenation.
 If hydrogen and oxygen are removed together, as in the case of
alcohols, then it is a dehydration or β-Elimination.
Types of Elimination Reaction:
There are two types of elimination reaction:
E1 type
E2 type
E1 Type:
Two step removal mechanism process.
Also known as unimolecular elimination.
Formation of an intermediate.
The reaction rate is proportional to the cocentration of the
compound to be transformed( First order Kinetics)
E2 Types:
One step Mechanism
Also known as Bimolecular reaction
Carbon leaving group and carbon hydrogen bonds break
off simultaneously
Stereo selective and regioselective

Elimination Reactions ppt..pptx

  • 1.
  • 2.
    What are eliminationreactions? Discuss in detail.
  • 3.
    Elimination reactions:  Theelimination reaction is an organic reaction in which two substituents are removed from a molecule to form a new product.  This process takes place in the presence of acid, base, metal and sometimes through heating.  Through this process it is possible to synthesize unsaturated organic compounds from saturated ones.  The elimination is mechanically the reverse of the addition reaction.
  • 4.
    Steps involves inelimination reactions: The elimination reaction involves three fundamental steps:  Removal of proton  Formation of C=C pi bond  Breaking of the bond to leaving group.2
  • 5.
    Nomenclatures used inelimination reaction:  When a hydrogen atom is removed from the compound as a proton, the process is called deprotonation.  If a halogen is removed then it is called dehalogenation.  If both hydrogen and halogen are removed, then it is called dehydrohalogenation.  If hydrogen and oxygen are removed together, as in the case of alcohols, then it is a dehydration or β-Elimination.
  • 6.
    Types of EliminationReaction: There are two types of elimination reaction: E1 type E2 type
  • 7.
    E1 Type: Two stepremoval mechanism process. Also known as unimolecular elimination. Formation of an intermediate. The reaction rate is proportional to the cocentration of the compound to be transformed( First order Kinetics)
  • 8.
    E2 Types: One stepMechanism Also known as Bimolecular reaction Carbon leaving group and carbon hydrogen bonds break off simultaneously Stereo selective and regioselective