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Temporal and spatial variability in  δ (D,H 2 ) :   measurement time series from six EUROHYDROS stations   Batenburg, A.M. , G. Pieterse, M. Krol, S. Walter, I. Levin, M. Schmidt, A. Jordan, S. Hammer, C. Yver, and T. Röckmann
Presentation overview ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
The atmospheric H 2  budget
Effects of a Hydrogen Economy
Isotope  δ -notation The  δ (D,H 2 ) value represents the deuterium-to-hydrogen ratio in the H 2  relative to a standard (Vienna Standard Mean Ocean Water (VSMOW))
Isotopic source signatures Isotopes can be used to gain information about different sources and sinks.
The EUROHYDROS network
Presentation overview ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Alert ,[object Object],[object Object],[object Object],[object Object]
Overview of the time series
Latitudinal gradient ,[object Object],[object Object],[object Object]
Sink processes Rayleigh fractionation formula: where  m (H 2 , max ) is the maximum mixing ratio,  c  a constant and  α  the fractionation factor: with  k  the removal rate of the species
NH sink processes: an estimate ,[object Object],[object Object]
Presentation overview ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Conclusions ,[object Object],[object Object],[object Object],[object Object]
Questions? ,[object Object],[object Object],[object Object],[object Object]

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Temporal and spatial variability in δ(D,H2) measurement time series

  • 1. Temporal and spatial variability in δ (D,H 2 ) : measurement time series from six EUROHYDROS stations Batenburg, A.M. , G. Pieterse, M. Krol, S. Walter, I. Levin, M. Schmidt, A. Jordan, S. Hammer, C. Yver, and T. Röckmann
  • 2.
  • 3. The atmospheric H 2 budget
  • 4. Effects of a Hydrogen Economy
  • 5. Isotope δ -notation The δ (D,H 2 ) value represents the deuterium-to-hydrogen ratio in the H 2 relative to a standard (Vienna Standard Mean Ocean Water (VSMOW))
  • 6. Isotopic source signatures Isotopes can be used to gain information about different sources and sinks.
  • 8.
  • 9.
  • 10. Overview of the time series
  • 11.
  • 12. Sink processes Rayleigh fractionation formula: where m (H 2 , max ) is the maximum mixing ratio, c a constant and α the fractionation factor: with k the removal rate of the species
  • 13.
  • 14.
  • 15.
  • 16.

Editor's Notes

  1. - Linked to methane cycle - Large uncertainties exist in the global H 2 budget - Expected `Hydrogen economy ’ Expected leakage assumptions from Tromp: All current technologies based on oil or gasoline combustion replaced by H2 fuel cells 10 to 20% leakage
  2. Explain delta notation. BB signature is likely more depleted. Hydrogen has large isotope effects (large relative mass difference) -> Isotopic analysis is a useful tool to constrain sources and sinks