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Combustible Dust
National Emphasis Program
Combustible Dust Oxygen in Air
Ignition Source
Dispersion Confinement
Explosion
FIRE
Deflagration
Background
• History of Combustible Dust Incidents
• Overview of Combustible Dust NEP
• Hazard Mitigation Techniques
• Resources
Select Catastrophic Combustible Dust
Incidents since 1995
Malden Mills
Combustible Dust Explosions History
Malden Mills
• 12/11/1995
• Lawrence , MA
• 13 hospitalized
• No citations
• Made nylon fibers and suspected the
static electricity ignited the fibers that were
glues to make fibers stand on end in the
fleece making process.
Firefighting efforts following the explosion at
Malden Mills (Methuen, Massachusetts,
December 11, 1995).
Combustible Dust Explosions History
Jahn foundry
Jahn Foundry
• 2/25/1999
• Springfield, MA
• 3 fatalities, 9 hospitalized
• General duty, electrical and housekeeping.
$115k
• Secondary explosion ignited phenol
formaldehyde resin. Initial cause is not sure.
• Heavy deposits of resin dust were found in the
flexible exhaust ducts serving the ovens in the
shell molding stations
Ford River Rouge:
Combustible Dust Explosions History
Killed six workers
and injured 36
Ford River Rouge Power
Plant
• 2/1/1999
• Dearborn , MI
• General Duty egregious, 1.5M
• Natural gas boiler explosion triggered
secondary coal dust explosion that had
accumulated on building and equipment
surfaces
Combustible Dust Explosions History
Rouse Polymerics
Rouse Polymerics
• 5/16/2002
• Vicksburg, MS
• 5 fatalities, 7 injured
• 23 serious, 2 unclassified 210K to 187k
• Fire in the baghouse, then rubber dust
explosion
Combustible Dust Explosions History
• January 29, 2003 -
West
Pharmaceutical
Services, Kinston,
NC
– Six deaths, dozens of
injuries
– Facility produced
rubber stoppers and
other products for
medical use
West Pharmaceutical facility destroyed by polyethylene dust
West Pharmaceutical
Services
• Combustible dust was ignited by some ignition
source causing an initial explosion in the Milling
Room, which dislodged ceiling tiles, steel
beams, and wall panels, and also putting a large
quantity of combustible dust from these areas
into suspension, which was added fuel to the
blast wave from the first explosion, creating a
second and larger explosion.
CTA Acoustics
• 02/20/2003
• Corbin , KY
• 7 fatalities, 37 injured
• 4 serious including
1910.307b, 28k
• Fiberglass fibers and
excess phenolic resin
powder probably went to
the oven while workers
were using compressed
air and lance to break up
a cogged bag house filter.
Combustible Dust Explosions History
• October 29, 2003 -
Hayes Lemmerz
Manufacturing Plant
– Two severely burned
(one of the victims died)
– Accumulated aluminum
dust
– Facility manufactured
cast aluminum
automotive wheels
Hayes Lemmerz International
• 10/29/2003
• Huntington IN
• One fatality, one injured
• 6 serious, 42k
• General duty and 1910.307b cited
• A dust collector attached to the recycling
equipment exploded. The explosion propagated
through piping to a furnace where the burned
employees were working
Types of Dust Involved in incidents
Types of Industries Involved in Dust Incidents
Dust Incidents, Injuries, and Fatalities
What Combustible Dusts are explosible?
• Some Metal dust
• Wood dust
• Coal and other carbon dusts.
• Plastic dust
• Biosolids
• Organic dust such as sugar,
paper, soap, and dried blood.
• Certain textile materials
What metal dusts are explosive?
• B – 110 MEC g/m3
• Mg – 15.7
• AL – 80-120
• Si – 200
• S – 100
• Ti – 70
• Cr – undetermined
• Fe – 220-500
• Ni - NF
• Zn – 300 to NF
• Nb – 420 to
undetermined
• Mo – NF
• Sn – 450
• Hf – 180
• Ta – 400
• W – 700-undetermined
• Pb - NF
Which Industries have Potential Dust
Explosion Hazards?
• Agriculture
• Chemical
• Textile
• Forest and furniture products
• Metal Processing
• Paper products
• Pharmaceuticals
• Recycling operations (metal, paper, and plastic
recycling operations.)
• Coal Power plants and coal processing facilities
CSB Recommendations To OSHA
1) Issue a standard designed to prevent combustible dust fires and explosions
in general industry
2) Revise the Hazard Communication Standard (HCS) (1910.1200) to clarify that
the HCS covers combustible dusts
3) Communicate to the United Nations Economic Commission (UNECE) the
need to amend the Globally Harmonized System (GHS) to address
combustible dust hazards
4) Provide training through the OSHA Training Institute (OTI) on recognizing
and preventing combustible dust explosions.
5) While a standard is being developed, implement a National Special
Emphasis Program (SEP) on combustible dust hazards in general
industry
NFPA 654 (2006) Definitions
Combustible dust. A combustible particulate solid that presents a fire or
deflagration hazard when suspended in air or some other oxidizing medium
over a range of concentrations, regardless of particle size or shape.
Combustible Particulate Solid. Any combustible solid material composed of
distinct particles or pieces, regardless of size, shape, or chemical
composition.
Hybrid Mixture. A mixture of a flammable gas with either a combustible dust
or a combustible mist.
What is Combustible Dust?
Definitions and Terminology
Definitions and Terminology
NFPA 69 (2002), and 499 (2004) Definitions
 Combustible Dust. Any finely divided solid material 420
microns or less in diameter (i.e., material passing through a
U.S. No 40 Standard Sieve) that presents a fire or explosion
hazard when dispersed
1 micron (µ)
= 1.0 x 10-6
m = 1.0 x 10-4
cm = 1.0 x 10-3
mm
420 µ
= 420 x 10-4
cm = .042 cm
= 0.4mm
A typical paper thickness is approximately 0.1mm
What is Combustible Dust?
Particle Size of Common Materials
Class II locations are those that are hazardous because of the presence of
combustible dust. The following are Class II locations where the combustible
dust atmospheres are present:
Group E. Atmospheres containing combustible metal dusts,
including aluminum, magnesium, and their commercial alloys, and
other combustible dusts whose particle size, abrasiveness, and
conductivity present similar hazards in the use of electrical equipment.
Group F. Atmospheres containing combustible carbonaceous
dusts that have more than 8 percent total entrapped volatiles (see
ASTM D 3175, Standard Test Method for Volatile Matter in the Analysis Sample
of Coal and Coke, for coal and coke dusts) or that have been
sensitized by other materials so that they present an explosion
hazard. Coal, carbon black, charcoal, and coke dusts are examples of
carbonaceous dusts.
Group G. Atmospheres containing other combustible
dusts, including flour, grain, wood flour, plastic and chemicals.
Class II Locations
Definitions and Terminology
Deflagration Vs. Explosion
Deflagration. Propagation of a combustion zone at a speed that
is less than the speed of sound in the unreacted medium.
Detonation. Propagation of a combustion zone at a velocity
that is greater than the speed of sound in the unreacted
medium.
Explosion. The bursting or rupture of an enclosure or a
container due to the development of internal pressure from
deflagration.
Explosion
Deflagration
Detonation
Definitions and Terminology
How are MEC and LFL Different?
Minimum Explosible Concentration (MEC)
The minimum concentration of combustible dust suspended in
air, measured in mass per unit volume that will support a
deflagration.
The lower flammable limit is the lowest concentration of a combustible
substance in an oxidizing medium
Lower Flammable Limit (LFL)
Upper Flammable Limit (UFL)
The upper flammable limits is the highest concentration of a combustible
substance in an oxidizing medium that will propagate a flame.
Definitions and Terminology
Source: Dust Explosions in the Process Industries, Second Edition, Rolf K Eckhoff
Explosible Range
Definitions and Terminology
 Minimum Ignition Temperature (MIT). The lowest
temperature at which ignition occurs.
 Lower the particle size – Lower the MIT
 Lower the moisture content - Lower the MIT
 Minimum Ignition Energy (MIE). The lowest electrostatic
spark energy that is capable of igniting a dust cloud.
 Energy Units (millijoules)
 Decrease in particle size and moisture content – decreases MIE
 An increase in temperature in dust cloud atmosphere - decreases MIE
 Deflagration Index, Kst – Maximum dp/dt normalized to 1.0 m3
volume.
 Pmax – The maximum pressure reached during the course of a
deflagration.
Dust explosion class Kst (bar.m/s) Characteristic
St 0 0 No explosion
St 1 >0 and <=200 Weak explosion
St 2 >200 and <=300 Strong explosion
St 3 >300 Very strong explosion
Deflagration Index - Kst
Kst = (dP/dt)max V1/3
(bar m/s)
where:
(dP/dt) max = the maximum rate of pressure rise
(bar/s)
V = the volume of the testing chamber (m3
)
The “Typical” Explosion
Event
Process
Equipment
Initial
Internal
Deflagration
Time, msec.
0 25 50 75 100 125 150 175 200 225 250 300 325
The “Typical” Explosion
Event
Process
Equipment
Initial
Internal
Deflagration
Shock Wave
Time, msec.
0 25 50 75 100 125 150 175 200 225 250 300 325
The “Typical” Explosion
Event
Process
Equipment
Initial
Internal
Deflagration
Elastic Rebound
Shock Waves
Time, msec.
0 25 50 75 100 125 150 175 200 225 250 300 325
The “Typical” Explosion
Event
Time, msec.
0 25 50 75 100 125 150 175 200 225 250 300 325
Process
Equipment
Initial
Internal
Deflagration
Dust clouds caused
by Elastic Rebound
The “Typical” Explosion
Event
Process
Equipment
Containment
Failure from Initial
Deflagration
Dust Clouds Caused
by Elastic Rebound
Time, msec.
0 25 50 75 100 125 150 175 200 225 250 300 325
The “Typical” Explosion
Event
Process
Equipment
Secondary Deflagration
Initiated
Dust Clouds Caused
by Elastic Rebound
Time, msec.
0 25 50 75 100 125 150 175 200 225 250 300 325
The “Typical” Explosion
Event
Process
Equipment
Secondary Deflagration
Propagates through Interior
Time, msec.
0 25 50 75 100 125 150 175 200 225 250 300 325
The “Typical” Explosion
Event
Process
Equipment
Secondary Deflagration
Vents from Structure
Time, msec.
0 25 50 75 100 125 150 175 200 225 250 300 325
The “Typical” Explosion
Event
Secondary Deflagration
Causes Collapse and Residual Fires
Time, msec.
0 25 50 75 100 125 150 175 200 225 250 300 325
Diagrams Courtesy of John M. Cholin, P.E., FSFPE, J.M. Cholin Consultants, Inc.
Dust Handling
Equipment
Types of Equipment Used in Dust
Handling
• Bag Openers (Slitters)
• Blenders/Mixers
• Dryers
• Dust Collectors
• Pneumatic Conveyors
• Size Reduction Equipment
(Grinders)
• Silos and Hoppers
• Hoses, Loading Spouts,
Flexible Boots
U.S (1985 -1995) U.K ( 1979-1988) Germany (1965 – 1980)
Material
Number of
Incidents
% Number of
Incidents
% Number of
Incidents
%
Dust Collectors
Grinders
Silos/Bunkers
Conveying System
Dryer/Oven
Mixers/Blenders
Other or Unknown
156
35
27
32
22
>12
84
42
9
7
9
6
>3
23
55
51
19
33
43
7
95
18
17
6
11
14
2
31
73
56
86
43
34
20
114
17
13
13
10
8
5
27
Total 372 100 303 100 426 100
Equipment Involved in Dust Explosions
Source: Guidelines for Safe Handling of Powders and Bulk Solids, CCPS, AICHE
Blenders/Mixers
• Heat Generation due
to
– Rubbing of Solids
– Rubbing of internal
parts
• Electrostatic Charging
of the Solids
• Dust Formation inside
of the equipment
Source: http://www.fedequip.com/abstract.asp?
ItemNumber=17478&txtSearchType=0&txtPageNo=1
&txtSearchCriteria=ribbon_mixer
Dust Collectors
• Presence of easily ignitable
fine dust atmosphere and high
turbulence
• Experienced many fires over
the years due to broken bags.
• Ignition source is electrostatic
spark discharges
• Another ignition source is
entrance of hot, glowing
particles into the baghouse
from upstream equipment
Fabric Filters (Baghouses)
Aluminum Dry Dust Collector
• Dry Type collectors located
outside
• Explosive Dust Warning sign
on collector
• Collectors or cyclone have
temperature alarms
• No recycling of air from
powder collectors
• Collector ductwork blanked
before repairs
• Filter cannot be synthetic
• Dust removed AT LEAST once
a day
• Dust put in sealed tight metal
containers
Pneumatic conveying system
• Downstream equipment have high
rate of risk for fires and explosion
– Static electricity is generated from
particle to particle contact or from
particle to duct wall contact.
– Heated particles which are created
during grinding or drying may be
carried into the pneumatic
conveying system and fanned to a
glow by high gas velocity.
– Tramp metal in the pneumatic
system may also cause frictional
heating.
– Charged powder may leak from
joints to the atmosphere and
electrostatic sparking can occur
resulting in an explosion.
Figure source:www.flexicon.com/us/products/PneumaticConveyingSystems/index.asp?gclid=COa2kKWK4o8CFQGzGgodikc9Dg
Aluminum
• Bonding between
containers
transferring powder
aluminum
• Explosive vents (if
provided) vent to the
outside
• Conveyor velocity
4500 ft/min for
pneumatic conveyor
Duct Velocity?
• Significant dust and
chip accumulation.
Pneumatic conveying systems
(Cont.)
• Prevention and Protection systems
– Venting
– Suppression
– Pressure Containment
– Deflagration Isolation
– Spark detection and extinguishing system
– Use of inert conveying gas
Silos and Hoppers
• No inter-silo Venting
• Silos and hoppers shall be located outside the
buildings with some exceptions
• Air cannons not to be used to break bridges in silos
• Detection of smoldering fires in silos and hoppers
can be achieved with methane and carbon monoxide
detectors
• Pressure containment, inerting, and suppression
systems to protect against explosions
• Venting is the most widely used protection against
explosions
Hazard Mitigation
Hazard Mitigation
Dust control
Ignition source control
Damage control
Dust Control
Design of facility & process
equipment
Contain combustible dust
Clean fugitive dust
Regular program
Access to hidden areas
Safe cleaning methods
Maintenance
Aluminum
• Machining operations provided
with dust collection
• Daily removal of turnings and
chips
• Grinding operation dust
collection separate from
buffing/polishing operations
• Vacuum Cleaners only used
that are approved for
aluminum dust
• No compressed air cleaning
unless no other method
available.
Dust Layer Thickness
Guidelines
1/8” in grain standard
Rule of thumb in NFPA 654
1/32” over 5% of area
Bar joist surface area ~ 5%
Max 20,000 SF
Idealized
Consider point in cleaning cycle
Housekeeping
• Maintain dust free as possible
• No blow down unless All electrical power
and processes have been shutdown.
• No welding, cutting or grinding unless
under hot-work permit
• Comfort heating equipment shall obtain
combustion air from clean outside source.
Aluminum
• Building
noncombustible
• Surfaces where dust
can collect have 55
degrees sloping
design
• Explosion venting for
aluminum powder
processing building
Note: For example, a 1/8 inch thick
layer of dust, once disturbed, can
easily form a dangerous cloud that
could explode.
Ignition Source Control
Electrical equipment
Static electricity control
Mechanical sparks & friction
Open flame control
Design of heating systems & heated surfaces
Use of tools, & vehicles
Maintenance
Damage Control Construction
Detachment (outside or other bldg.)
Separation (distance with in same room)
Segregation (barrier)
Pressure resistant construction
Pressure relieving construction
Pressure Venting
Relief valves
Maintenance
Explosion Venting
• The vent opening must be
sized to allow the expanding
gases to be vented at a rapid
rate so that the internal
pressures developed by the
explosion do not compromise
the structural integrity of the
protected equipment
• The volume of the equipment
to be protected
• The maximum pressure during
venting (Pred)
• The KSt of the dust (or
fundamental burning velocity
of a gas)
• The burst pressure of the
explosion
Explosion Venting
• NFPA 68
• It is the discharge of heat
and flame that make
indoor application of
explosion venting
undesirable
• Vented flame igniting
dusts or vapors indoors
creates a secondary
explosion hazard.
Damage Control Systems
Specialized detection systems
Specialized suppression systems
Explosion prevention systems
Maintenance
NEP/ Industry Application
– Agriculture
– Chemicals
– Textiles
– Forest and furniture products
– Metal processing
– Tire and rubber manufacturing plants
– Paper products
– Pharmaceuticals
– Wastewater treatment
– Recycling operations (metal, paper, and plastic.)
– Coal dust in coal handling and processing facilities.
Employee Training
• Extensive Employee
training required
• Hazards of the process
• Emergency Procedures
• Location of Electrical
switches and alarms
• Fire fighting for incipient
fires
• Evacuation
• Equipment operation,
start up and shutdown,
and response to upset
conditions.
Fan housing is eroded, which is
typically caused by dust leaking
through or past the filters.
Other Programs
 State plan participation in this national emphasis effort is strongly
encouraged but is not required.
 does not replace the grain handling facility directive, OSHA Instruction
CPL 02-01-004, Inspection of Grain Handling Facilities, 29 CFR
1910.272.
 not intended for inspections of explosives and pyrotechnics
manufacturing facilities covered by the Process Safety Management
(PSM) standard (1910.119)
 does not exclude facilities that manufacture or handle other types of
combustible dusts (such as ammonium perchlorate) covered under
the PSM standard.
CSHOs Safety and Health
• PPE and Nonspark Producing Clothing
• Use of Cameras
• Use of Safe Practices when collecting dust
samples
Primary Applicable OSHA Standards
1910.22 General – Housekeeping
1910.307 Hazardous (Classified)
Locations
1910.178 Powered Industrial Trucks
1910. 263 Bakery Equipment
1910.265 Sawmills
1910.272 Grain Handling
General Duty Clause
Resources
Safety and Health Information
Bulletin
Purpose
Background
Elements of a Dust Explosion
Facility Dust Hazard Assessment
Dust Control
Ignition Control
Damage Control
Training
References
NFPA Standards – Dust Hazards
654 General
664 Wood
61 Agriculture
484 Metal
480 Magnesium
481 Titanium
482 Zirconium
485 Lithium
NFPA Standards – Electrical & Systems
70 National Electric Code
499 Classification of Combustible
Dust
68 Deflagration Venting Systems
69 Explosion Prevention Systems
91 Exhaust Systems
Combustible Dust NEP
• Any Questions?
Combustible Dust Hazards and Deflagration

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Combustible Dust Hazards and Deflagration

  • 1. Combustible Dust National Emphasis Program Combustible Dust Oxygen in Air Ignition Source Dispersion Confinement Explosion FIRE Deflagration
  • 2. Background • History of Combustible Dust Incidents • Overview of Combustible Dust NEP • Hazard Mitigation Techniques • Resources
  • 3. Select Catastrophic Combustible Dust Incidents since 1995
  • 4. Malden Mills Combustible Dust Explosions History
  • 5. Malden Mills • 12/11/1995 • Lawrence , MA • 13 hospitalized • No citations • Made nylon fibers and suspected the static electricity ignited the fibers that were glues to make fibers stand on end in the fleece making process.
  • 6. Firefighting efforts following the explosion at Malden Mills (Methuen, Massachusetts, December 11, 1995).
  • 7. Combustible Dust Explosions History Jahn foundry
  • 8. Jahn Foundry • 2/25/1999 • Springfield, MA • 3 fatalities, 9 hospitalized • General duty, electrical and housekeeping. $115k • Secondary explosion ignited phenol formaldehyde resin. Initial cause is not sure. • Heavy deposits of resin dust were found in the flexible exhaust ducts serving the ovens in the shell molding stations
  • 9. Ford River Rouge: Combustible Dust Explosions History Killed six workers and injured 36
  • 10. Ford River Rouge Power Plant • 2/1/1999 • Dearborn , MI • General Duty egregious, 1.5M • Natural gas boiler explosion triggered secondary coal dust explosion that had accumulated on building and equipment surfaces
  • 11. Combustible Dust Explosions History Rouse Polymerics
  • 12. Rouse Polymerics • 5/16/2002 • Vicksburg, MS • 5 fatalities, 7 injured • 23 serious, 2 unclassified 210K to 187k • Fire in the baghouse, then rubber dust explosion
  • 13. Combustible Dust Explosions History • January 29, 2003 - West Pharmaceutical Services, Kinston, NC – Six deaths, dozens of injuries – Facility produced rubber stoppers and other products for medical use
  • 14. West Pharmaceutical facility destroyed by polyethylene dust
  • 15. West Pharmaceutical Services • Combustible dust was ignited by some ignition source causing an initial explosion in the Milling Room, which dislodged ceiling tiles, steel beams, and wall panels, and also putting a large quantity of combustible dust from these areas into suspension, which was added fuel to the blast wave from the first explosion, creating a second and larger explosion.
  • 16. CTA Acoustics • 02/20/2003 • Corbin , KY • 7 fatalities, 37 injured • 4 serious including 1910.307b, 28k • Fiberglass fibers and excess phenolic resin powder probably went to the oven while workers were using compressed air and lance to break up a cogged bag house filter.
  • 17. Combustible Dust Explosions History • October 29, 2003 - Hayes Lemmerz Manufacturing Plant – Two severely burned (one of the victims died) – Accumulated aluminum dust – Facility manufactured cast aluminum automotive wheels
  • 18. Hayes Lemmerz International • 10/29/2003 • Huntington IN • One fatality, one injured • 6 serious, 42k • General duty and 1910.307b cited • A dust collector attached to the recycling equipment exploded. The explosion propagated through piping to a furnace where the burned employees were working
  • 19. Types of Dust Involved in incidents
  • 20. Types of Industries Involved in Dust Incidents
  • 21. Dust Incidents, Injuries, and Fatalities
  • 22. What Combustible Dusts are explosible? • Some Metal dust • Wood dust • Coal and other carbon dusts. • Plastic dust • Biosolids • Organic dust such as sugar, paper, soap, and dried blood. • Certain textile materials
  • 23. What metal dusts are explosive? • B – 110 MEC g/m3 • Mg – 15.7 • AL – 80-120 • Si – 200 • S – 100 • Ti – 70 • Cr – undetermined • Fe – 220-500 • Ni - NF • Zn – 300 to NF • Nb – 420 to undetermined • Mo – NF • Sn – 450 • Hf – 180 • Ta – 400 • W – 700-undetermined • Pb - NF
  • 24. Which Industries have Potential Dust Explosion Hazards? • Agriculture • Chemical • Textile • Forest and furniture products • Metal Processing • Paper products • Pharmaceuticals • Recycling operations (metal, paper, and plastic recycling operations.) • Coal Power plants and coal processing facilities
  • 25. CSB Recommendations To OSHA 1) Issue a standard designed to prevent combustible dust fires and explosions in general industry 2) Revise the Hazard Communication Standard (HCS) (1910.1200) to clarify that the HCS covers combustible dusts 3) Communicate to the United Nations Economic Commission (UNECE) the need to amend the Globally Harmonized System (GHS) to address combustible dust hazards 4) Provide training through the OSHA Training Institute (OTI) on recognizing and preventing combustible dust explosions. 5) While a standard is being developed, implement a National Special Emphasis Program (SEP) on combustible dust hazards in general industry
  • 26. NFPA 654 (2006) Definitions Combustible dust. A combustible particulate solid that presents a fire or deflagration hazard when suspended in air or some other oxidizing medium over a range of concentrations, regardless of particle size or shape. Combustible Particulate Solid. Any combustible solid material composed of distinct particles or pieces, regardless of size, shape, or chemical composition. Hybrid Mixture. A mixture of a flammable gas with either a combustible dust or a combustible mist. What is Combustible Dust? Definitions and Terminology
  • 27. Definitions and Terminology NFPA 69 (2002), and 499 (2004) Definitions  Combustible Dust. Any finely divided solid material 420 microns or less in diameter (i.e., material passing through a U.S. No 40 Standard Sieve) that presents a fire or explosion hazard when dispersed 1 micron (µ) = 1.0 x 10-6 m = 1.0 x 10-4 cm = 1.0 x 10-3 mm 420 µ = 420 x 10-4 cm = .042 cm = 0.4mm A typical paper thickness is approximately 0.1mm What is Combustible Dust?
  • 28. Particle Size of Common Materials
  • 29. Class II locations are those that are hazardous because of the presence of combustible dust. The following are Class II locations where the combustible dust atmospheres are present: Group E. Atmospheres containing combustible metal dusts, including aluminum, magnesium, and their commercial alloys, and other combustible dusts whose particle size, abrasiveness, and conductivity present similar hazards in the use of electrical equipment. Group F. Atmospheres containing combustible carbonaceous dusts that have more than 8 percent total entrapped volatiles (see ASTM D 3175, Standard Test Method for Volatile Matter in the Analysis Sample of Coal and Coke, for coal and coke dusts) or that have been sensitized by other materials so that they present an explosion hazard. Coal, carbon black, charcoal, and coke dusts are examples of carbonaceous dusts. Group G. Atmospheres containing other combustible dusts, including flour, grain, wood flour, plastic and chemicals. Class II Locations Definitions and Terminology
  • 30. Deflagration Vs. Explosion Deflagration. Propagation of a combustion zone at a speed that is less than the speed of sound in the unreacted medium. Detonation. Propagation of a combustion zone at a velocity that is greater than the speed of sound in the unreacted medium. Explosion. The bursting or rupture of an enclosure or a container due to the development of internal pressure from deflagration. Explosion Deflagration Detonation Definitions and Terminology
  • 31. How are MEC and LFL Different? Minimum Explosible Concentration (MEC) The minimum concentration of combustible dust suspended in air, measured in mass per unit volume that will support a deflagration. The lower flammable limit is the lowest concentration of a combustible substance in an oxidizing medium Lower Flammable Limit (LFL) Upper Flammable Limit (UFL) The upper flammable limits is the highest concentration of a combustible substance in an oxidizing medium that will propagate a flame. Definitions and Terminology
  • 32. Source: Dust Explosions in the Process Industries, Second Edition, Rolf K Eckhoff Explosible Range
  • 33. Definitions and Terminology  Minimum Ignition Temperature (MIT). The lowest temperature at which ignition occurs.  Lower the particle size – Lower the MIT  Lower the moisture content - Lower the MIT  Minimum Ignition Energy (MIE). The lowest electrostatic spark energy that is capable of igniting a dust cloud.  Energy Units (millijoules)  Decrease in particle size and moisture content – decreases MIE  An increase in temperature in dust cloud atmosphere - decreases MIE  Deflagration Index, Kst – Maximum dp/dt normalized to 1.0 m3 volume.  Pmax – The maximum pressure reached during the course of a deflagration.
  • 34. Dust explosion class Kst (bar.m/s) Characteristic St 0 0 No explosion St 1 >0 and <=200 Weak explosion St 2 >200 and <=300 Strong explosion St 3 >300 Very strong explosion Deflagration Index - Kst Kst = (dP/dt)max V1/3 (bar m/s) where: (dP/dt) max = the maximum rate of pressure rise (bar/s) V = the volume of the testing chamber (m3 )
  • 36. The “Typical” Explosion Event Process Equipment Initial Internal Deflagration Shock Wave Time, msec. 0 25 50 75 100 125 150 175 200 225 250 300 325
  • 37. The “Typical” Explosion Event Process Equipment Initial Internal Deflagration Elastic Rebound Shock Waves Time, msec. 0 25 50 75 100 125 150 175 200 225 250 300 325
  • 38. The “Typical” Explosion Event Time, msec. 0 25 50 75 100 125 150 175 200 225 250 300 325 Process Equipment Initial Internal Deflagration Dust clouds caused by Elastic Rebound
  • 39. The “Typical” Explosion Event Process Equipment Containment Failure from Initial Deflagration Dust Clouds Caused by Elastic Rebound Time, msec. 0 25 50 75 100 125 150 175 200 225 250 300 325
  • 40. The “Typical” Explosion Event Process Equipment Secondary Deflagration Initiated Dust Clouds Caused by Elastic Rebound Time, msec. 0 25 50 75 100 125 150 175 200 225 250 300 325
  • 41. The “Typical” Explosion Event Process Equipment Secondary Deflagration Propagates through Interior Time, msec. 0 25 50 75 100 125 150 175 200 225 250 300 325
  • 42. The “Typical” Explosion Event Process Equipment Secondary Deflagration Vents from Structure Time, msec. 0 25 50 75 100 125 150 175 200 225 250 300 325
  • 43. The “Typical” Explosion Event Secondary Deflagration Causes Collapse and Residual Fires Time, msec. 0 25 50 75 100 125 150 175 200 225 250 300 325 Diagrams Courtesy of John M. Cholin, P.E., FSFPE, J.M. Cholin Consultants, Inc.
  • 45. Types of Equipment Used in Dust Handling • Bag Openers (Slitters) • Blenders/Mixers • Dryers • Dust Collectors • Pneumatic Conveyors • Size Reduction Equipment (Grinders) • Silos and Hoppers • Hoses, Loading Spouts, Flexible Boots
  • 46. U.S (1985 -1995) U.K ( 1979-1988) Germany (1965 – 1980) Material Number of Incidents % Number of Incidents % Number of Incidents % Dust Collectors Grinders Silos/Bunkers Conveying System Dryer/Oven Mixers/Blenders Other or Unknown 156 35 27 32 22 >12 84 42 9 7 9 6 >3 23 55 51 19 33 43 7 95 18 17 6 11 14 2 31 73 56 86 43 34 20 114 17 13 13 10 8 5 27 Total 372 100 303 100 426 100 Equipment Involved in Dust Explosions Source: Guidelines for Safe Handling of Powders and Bulk Solids, CCPS, AICHE
  • 47. Blenders/Mixers • Heat Generation due to – Rubbing of Solids – Rubbing of internal parts • Electrostatic Charging of the Solids • Dust Formation inside of the equipment Source: http://www.fedequip.com/abstract.asp? ItemNumber=17478&txtSearchType=0&txtPageNo=1 &txtSearchCriteria=ribbon_mixer
  • 48. Dust Collectors • Presence of easily ignitable fine dust atmosphere and high turbulence • Experienced many fires over the years due to broken bags. • Ignition source is electrostatic spark discharges • Another ignition source is entrance of hot, glowing particles into the baghouse from upstream equipment Fabric Filters (Baghouses)
  • 49. Aluminum Dry Dust Collector • Dry Type collectors located outside • Explosive Dust Warning sign on collector • Collectors or cyclone have temperature alarms • No recycling of air from powder collectors • Collector ductwork blanked before repairs • Filter cannot be synthetic • Dust removed AT LEAST once a day • Dust put in sealed tight metal containers
  • 50. Pneumatic conveying system • Downstream equipment have high rate of risk for fires and explosion – Static electricity is generated from particle to particle contact or from particle to duct wall contact. – Heated particles which are created during grinding or drying may be carried into the pneumatic conveying system and fanned to a glow by high gas velocity. – Tramp metal in the pneumatic system may also cause frictional heating. – Charged powder may leak from joints to the atmosphere and electrostatic sparking can occur resulting in an explosion. Figure source:www.flexicon.com/us/products/PneumaticConveyingSystems/index.asp?gclid=COa2kKWK4o8CFQGzGgodikc9Dg
  • 51. Aluminum • Bonding between containers transferring powder aluminum • Explosive vents (if provided) vent to the outside • Conveyor velocity 4500 ft/min for pneumatic conveyor
  • 52. Duct Velocity? • Significant dust and chip accumulation.
  • 53. Pneumatic conveying systems (Cont.) • Prevention and Protection systems – Venting – Suppression – Pressure Containment – Deflagration Isolation – Spark detection and extinguishing system – Use of inert conveying gas
  • 54. Silos and Hoppers • No inter-silo Venting • Silos and hoppers shall be located outside the buildings with some exceptions • Air cannons not to be used to break bridges in silos • Detection of smoldering fires in silos and hoppers can be achieved with methane and carbon monoxide detectors • Pressure containment, inerting, and suppression systems to protect against explosions • Venting is the most widely used protection against explosions
  • 56. Hazard Mitigation Dust control Ignition source control Damage control
  • 57. Dust Control Design of facility & process equipment Contain combustible dust Clean fugitive dust Regular program Access to hidden areas Safe cleaning methods Maintenance
  • 58. Aluminum • Machining operations provided with dust collection • Daily removal of turnings and chips • Grinding operation dust collection separate from buffing/polishing operations • Vacuum Cleaners only used that are approved for aluminum dust • No compressed air cleaning unless no other method available.
  • 59. Dust Layer Thickness Guidelines 1/8” in grain standard Rule of thumb in NFPA 654 1/32” over 5% of area Bar joist surface area ~ 5% Max 20,000 SF Idealized Consider point in cleaning cycle
  • 60. Housekeeping • Maintain dust free as possible • No blow down unless All electrical power and processes have been shutdown. • No welding, cutting or grinding unless under hot-work permit • Comfort heating equipment shall obtain combustion air from clean outside source.
  • 61. Aluminum • Building noncombustible • Surfaces where dust can collect have 55 degrees sloping design • Explosion venting for aluminum powder processing building Note: For example, a 1/8 inch thick layer of dust, once disturbed, can easily form a dangerous cloud that could explode.
  • 62. Ignition Source Control Electrical equipment Static electricity control Mechanical sparks & friction Open flame control Design of heating systems & heated surfaces Use of tools, & vehicles Maintenance
  • 63. Damage Control Construction Detachment (outside or other bldg.) Separation (distance with in same room) Segregation (barrier) Pressure resistant construction Pressure relieving construction Pressure Venting Relief valves Maintenance
  • 64. Explosion Venting • The vent opening must be sized to allow the expanding gases to be vented at a rapid rate so that the internal pressures developed by the explosion do not compromise the structural integrity of the protected equipment • The volume of the equipment to be protected • The maximum pressure during venting (Pred) • The KSt of the dust (or fundamental burning velocity of a gas) • The burst pressure of the explosion
  • 65. Explosion Venting • NFPA 68 • It is the discharge of heat and flame that make indoor application of explosion venting undesirable • Vented flame igniting dusts or vapors indoors creates a secondary explosion hazard.
  • 66. Damage Control Systems Specialized detection systems Specialized suppression systems Explosion prevention systems Maintenance
  • 67. NEP/ Industry Application – Agriculture – Chemicals – Textiles – Forest and furniture products – Metal processing – Tire and rubber manufacturing plants – Paper products – Pharmaceuticals – Wastewater treatment – Recycling operations (metal, paper, and plastic.) – Coal dust in coal handling and processing facilities.
  • 68. Employee Training • Extensive Employee training required • Hazards of the process • Emergency Procedures • Location of Electrical switches and alarms • Fire fighting for incipient fires • Evacuation • Equipment operation, start up and shutdown, and response to upset conditions. Fan housing is eroded, which is typically caused by dust leaking through or past the filters.
  • 69. Other Programs  State plan participation in this national emphasis effort is strongly encouraged but is not required.  does not replace the grain handling facility directive, OSHA Instruction CPL 02-01-004, Inspection of Grain Handling Facilities, 29 CFR 1910.272.  not intended for inspections of explosives and pyrotechnics manufacturing facilities covered by the Process Safety Management (PSM) standard (1910.119)  does not exclude facilities that manufacture or handle other types of combustible dusts (such as ammonium perchlorate) covered under the PSM standard.
  • 70. CSHOs Safety and Health • PPE and Nonspark Producing Clothing • Use of Cameras • Use of Safe Practices when collecting dust samples
  • 71. Primary Applicable OSHA Standards 1910.22 General – Housekeeping 1910.307 Hazardous (Classified) Locations 1910.178 Powered Industrial Trucks 1910. 263 Bakery Equipment 1910.265 Sawmills 1910.272 Grain Handling General Duty Clause
  • 73. Safety and Health Information Bulletin Purpose Background Elements of a Dust Explosion Facility Dust Hazard Assessment Dust Control Ignition Control Damage Control Training References
  • 74. NFPA Standards – Dust Hazards 654 General 664 Wood 61 Agriculture 484 Metal 480 Magnesium 481 Titanium 482 Zirconium 485 Lithium
  • 75. NFPA Standards – Electrical & Systems 70 National Electric Code 499 Classification of Combustible Dust 68 Deflagration Venting Systems 69 Explosion Prevention Systems 91 Exhaust Systems
  • 76. Combustible Dust NEP • Any Questions?

Editor's Notes

  1. The employer manufacturers various types of textile products for upholstery and clothing. One production process for an upholstery product is known as flocking. During this process, small chemically-treated nylon fibers are applied to a fabric backing using an electrical field. Three of the company&amp;apos;s five flock lines are located on the first through third floors and were in operation. A sudden explosion/deflagration occurred on the first floor, originating at the beginning of the production lines where some employees were cleaning. The explosion/deflagration moved throughout the entire first floor of the building with great force, leaving only small incidental fires. Employees #1 through #13 were injured. Employees located closest to the explosion suffered multiple burns. Employees further away sustained less severe burns. Some injured employees were located on the second floor directly above the explosion point. They sustained minor injuries, smoke inhalation, bruise and contusions. Some of the employees who helped with a search and rescue were treated for smoke inhalation. The explosion was caused by an electrical spark which ignited a combustible nylon fiber dust cloud in the hopper room at the beginning of a production line. The hopper room is where the nylon fibers are applied to the cloth backing. 37 people were injured in an explosion of nylon fibers. Even though the facility was completely destroyed, the owner of the company kept the employees on the payroll long after the explosion. The Malden Mills explosion was likely ignited by the static electricity used to make the fibers stand on end, where they could be glued to fabric to make fleece.
  2. A
  3. Employees #1 through #12 were in the shell mold department when there was a large explosion. All twelve sustained burns, from which Employees #6, #8, and #12 died. Employees #1 through #5, #7, and #9 through #11 were hospitalized. OSHA and fire investigators determined that the damage was caused by secondary explosions of accumulated resin within exhaust ductwork throughout the building. He noted that the investigation determined that an initiating fire event in one of the Shell Mold stations in the Shell Mold Building was pulled into the exhaust ventilation system. The interior of the ductwork of that system was heavily loaded with deposits of phenol formaldehyde resin, an explosive organic dust. The ignition of this dust caused a turbulent fire and explosion(s) which traveled through the interior ductwork and in turn shook down explosive concentrations of combustible resin dust that had collected on surfaces throughout the Shell Mold Building. When the fire exploded out from the ductwork, it ignited these airborne concentrations of combustible dust, causing a catastrophic dust explosion which lifted the building&amp;apos;s roof and blew out its walls. The report notes that, although it was not possible to conclusively determine the initiating event which caused the resultant dust explosion, a number of plausible scenarios were developed from the physical and testimonial evidence. Of these, the following two were determined to be the most probable: Dust Scenario: Heavy deposits of resin dust were found in the flexible exhaust ducts serving the ovens in the shell molding stations. The open ends of the ducts were placed adjacent to the ovens, at approximately head level, and in an area where employees must present themselves to deal with the ovens. Jarring of the duct readily dislodged the deposits of dust. In this scenario, jarring of the duct caused dust to fall down onto the oven and be ignited. The resulting fireball was then pulled back into the flexible duct where it started the turbulent fire and explosions in the exhaust ventilation system. Gas Scenario: The fuel trains to the ovens in the shell molding stations were found to be in very bad condition. The internal mechanisms of the valves controlling the flow of combustion air and natural gas to the ovens were found to be massively contaminated with resin and sand. The proper functioning of these valves was critical for providing air and gas to the ovens in the correct ratio to support combustion. Oven flameouts were a recurrent problem. The ovens were not provided with a flame-sensing device to prevent the flow of gas to the oven in the absence of main flame. Although a switch and thermocouple prevented the flow of gas to the oven in the absence of a pilot flame, the pilot flame was not able to light the burners. Thus, in the absence of a main flame, gas could continue to flow to the oven. In this scenario, gas was flowing to an oven that was not lit. The unburned gas collected in sufficient quantities to finally be ignited by the pilot or other ignition source, and the resulting fireball was pulled into the flexible duct where it started the turbulent fire and explosions in the exhaust ventilation system. The report found that inadequate housekeeping, ventilation, maintenance practices and equipment were all causal factors for the initiating and catastrophic events.
  4. On February 1, 1999 a natural gas explosion at the power plant for the Ford River Rouge facility near Dearborn, Michigan, triggered subsequent secondary explosions of coal dust that had accumulated on surfaces in the plant. Six people died and another 30 were injured. The power plant had to be completely rebuilt. Six employees were taking a boiler off-line for maintenance. A natural gas valve was inadvertently left open. When a secondary butterfly valve was opened for purging, gas entered the unfired boiler which was still hot. This resulted in an explosion in the boiler and that explosion caused secondary explosions from coal dust that had accumulated on building and equipment surfaces. All six employees were killed in the explosion.
  5. Combustible dust was ignited by some ignition source causing an initial explosion in the Milling Room, which dislodged ceiling tiles, steel beams, and wall panels, and also putting a large quantity of combustible dust from these areas into suspension, which was added fuel to the blast wave from the first explosion, creating a second and larger explosion, that exited through the roof of the Northeast tower section of the building, in the ACS area. Three workers were killed from this explosion on 1/29/03 and three other workers died later (1/31/03 to 3/03/03), in the UNC Burn Center in Chapel Hill, NC. 85/86 Citations were deleted. $602K to $100k was the final serious penalty for a single general duty violation.
  6. Another photo of the virtual destruction of the plant
  7. Only three weeks after the explosion in North Carolina, another deadly blast occurred in Corbin, Kentucky, at the CTA Acoustics facility. Thirty-seven people were injured, and seven workers died, some weeks after the explosion from severe burn injuries. This photo shows one of the many production areas where workers were caught in secondary dust explosions that traveled from one production line to the next. On February 20, 2003, at approximately 7:30am an explosion occurred at CTA Acoustics, Inc. in Corbin, KY. The explosion and subsequent fires resulted in the injury of 45 employees, 18 of which were hospitalized. Of the 18 employees hospitalized, six later succumbed to their injuries. Most injuries consisted of 1st, 2nd and 3rd degree burns. Other injuries included lacerations, smoke inhalation, and one knee fracture. The explosion occurred in the area of the facility&amp;apos;s production lines known as Lines 405, 403, 402 and 401, which produce a fiberglass/resin blend automotive insulation. The explosion damaged all lines with the most significant damage on Lines 405 and 403. Damage to the facility included blown out roof decking, fire and blast damage to the dust collection system on the equipment. At the time of the explosion, employees were beginning their shift and the four lines were being prepared to run product. All of the seriously injured were working on or near the four lines when the explosion occurred as supervisors, machine or oven operators, or product inspectors. two of the injured line employees were working on the roof performing maintenance duties on the dust collection system for line 405.
  8. Hayes Lemmerz aluminum foundry in Huntington, Indiana. Two workers were engulfed in flames from an aluminum dust explosion. One of those workers died later that evening; another spent weeks in the burn unit. Hayes remelted scrap aluminum in their automotive wheel casting plant. A dust collector attached to the recycling equipment exploded. The explosion propagated through piping to a furnace where the burned employees were working. On 10-29-2003 at about 8:25 PM the facility experienced a major explosion and fire in the number 5 furnace area that killed one employee and severely burned another. 5 others were transported to emergency care facilities and released after treatment, these included 3 Hayes Lemmerz employees and two contract employees doing foundry stack testing. The day of the explosion at about 3:00 P M a fire was reported in the number 5 furnace chip melt side well exhaust duct. The maintenance department was sent to evaluated the fire and shut the exhaust ventilation system down to allow the fire in the pipe to self extinguish as this was the plant policy for aluminum dust fires in the pipe. About 8:10 or 8:15 the employees started the system up after the pipe had cooled and been cleaned out by the employees. An employee who was working in the area that evening states in his statement in part the night of the event we had to wait for a smoldering in the multi clone pipe to go out then we cleaned the ash out of the pipe started multiclone blower checked for proper operation turned on the dry chip blower #3 then the auger checked multiclone for proper operation we were starting to leave when a big flash came out of the well where the chips feed in this moved the dust off of the ceiling &amp; ignited it causing a ball of fire to move through the room it also destroyed equipment outside the building &amp; started many small fires inside the building in that area.
  9. http://www.cdc.gov/niosh/mining/pubs/pdfs/etoma.pdf
  10. I
  11. General and industry-specific
  12. Purpose: hazard information &amp; mitigation
  13. CSB advocated specifically for NFPA 654 &amp; 484 General Duty Clause
  14. The draft directive has been reviewed by both National and Regional Offices. Comments received during the review process have been addressed. Additionally, OSHA received extensive input from the Office of the Solicitors , along with their final concurrence. The directive was reviewed by the PPB and we received Secretarial approval in the last week of September and It was approved on October 18th.