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(A) Colour of Substances

The several possibilities for a particular colour are given below:

  Colour of Unknown                                   Chemicals/Ions
     Substances




                             Copper(II) oxide, CuO




                             Iron(II) oxide, FeO
        Black




                             Manganese(IV) oxide, MnO2




                             Iodine crystals, I2
Colour of Unknown                         Chemicals/Ions
   Substances
                                               Examples:

                                                                Hydrated copper(II)
                                                                sulfate crystals,
                                                                CuSO4.5H2O




                                                                Aqueous copper(II)
                                                                sulfate solution,
                                                                CuSO4(aq)
     Blue
                    Copper(II), Cu2+




                                                               Hydrated copper(II)
                                                               nitrate crystals,
                                                               Cu(NO3)2.3H2O




                                                                Aqueous copper(II)
                                                                nitrate solution,
                                                                Cu(NO3)2(aq)




                                 Anhydrous cobalt(II) chloride, CoCl2
Colour of Unknown                     Chemicals/Ions
    Substances

                     I2 (solution)




    Brown

                     Lead(IV) oxide,
                     PbO2




                                       Examples:

                                                        Hydrated iron(III)
                                                        nitrate crystals,
                                                        Fe(NO3)3.9H2O
                     Iron(III), Fe3+



                                                         Aqueous iron(III)
                                                         nitrate solution,
Reddish-brown                                            Fe(NO3)3(aq)




                                                         Iron(III) oxide,
                                                         Fe2O3




                     Copper metal
Colour of Unknown                       Chemicals/Ions
   Substances

                                       Examples:

                                                         Hydrated iron(II)
                                                         sulfate crystals,
                                                         FeSO4.7H2O
                    Iron(II), Fe2+
Green / Light
   Green                                                 Aqueous iron(II)
                                                         sulfate solution,
                                                         FeSO4(aq)




                                       Examples:

                                                            Copper(II)
                                                            carbonate, CuCO3



                    Copper(II), Cu2+

                                                              Hydrated
                                                              copper(II) chloride
                                                              crystals,
                                                              CuCl2.2H2O




                    Potassium
   Purple           manganate(VII),
                    KMnO4




                    Potassium
   Orange           dichromate(VI),
                    K2Cr2O7
Colour of Unknown                             Chemicals/Ions
   Substances

                    Lead(II)
   Yellow           oxide,
                    PbO




                    Lead(II)
                    iodide,
                    PbI2,




                                  See the web site below for the test for iodide
                                  http://www.youtube.com/watch?v=tQ_sJTQAnRM
                    Silver
                    bromide,
                    AgBr
                    (Pale
                    yellow)



                    Silver
                    iodide, AgI
Colour of Unknown                        Chemicals/Ions
   Substances
                                   Examples:



                                                               Zinc powder




                    Metals (in
     Grey           powder form)                            Aluminium powder




                                                          Iron powder




                    Co2+                                    Hydrated cobalt(II)

    Pink            (hydrated)                              chloride crystals,
                                                            CoCl2.6H2O




                                                      Aqueous cobalt(II)
                                                      chloride solution,
                                                      CoCl2(aq)
Colour of Unknown                                     Chemicals/Ions
        Substances

                                 Na+, K+, NH4+, Ca2+, Zn2+, Pb2+, Al3+
              White
                                 (Absence of salts like iron(II), iron(III), copper(II) and other
                                 transition elements)

            Colourless           Dilute acids, alkalis, hydrogen peroxide(H2O2)
             Solution


(B) Action of Heat on Carbonates

    Cation            Observations/Gas                                  Equation
                          evolved

Na+             White residue;                   Na2CO3.10H2O(s) → Na2CO3(s) + 10H2O(g)
                Water vapour evolved               white crystals           white powder
 +
K               White residue                    Not decomposed
Ca   2+
                White residue; carbon            CaCO3(s) → CaO(s) + CO2(g)
                dioxide evolved
                                                 white              white
Zn2+            Residue is yellow when hot       ZnCO3(s)     →        ZnO(s)           +   CO2(g)
                and white when cold;
                                                 white               yellow –hot
                carbon dioxide evolved
                                                                     white - cold
Pb   2+
                Yellow (orange) residue;         PbCO3(s) → PbO(s) + CO2(g)
                carbon dioxide evolved
                                                 white          yellow


Al3+            White residue; carbon            Al2(CO3)3(s) → Al2O3(s) + 3CO2(g)
                dioxide evolved
                                                  white              white
 Cu    2+
                Black residue; carbon            CuCO3(s) → CuO(s) + CO2(g)
                dioxide evolved
                                                  green             black
Fe2+            Black residue turning            FeCO3(s) → FeO(s) + CO2(g)
                reddish brown on contact
                                                 green          black
                with air (oxidation); carbon
                dioxide evolved
                                                 4FeO(s) + O2(g) → 2Fe2O3(s)
                                                              air           reddish-brown
Fe3+            Reddish-brown residue;           Fe2(CO3)3(s) → Fe2O3(s)            +       3CO2(g)
                carbon dioxide evolve
                                                  brown             reddish-brown

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Colour Of Substances

  • 1. (A) Colour of Substances The several possibilities for a particular colour are given below: Colour of Unknown Chemicals/Ions Substances Copper(II) oxide, CuO Iron(II) oxide, FeO Black Manganese(IV) oxide, MnO2 Iodine crystals, I2
  • 2. Colour of Unknown Chemicals/Ions Substances Examples: Hydrated copper(II) sulfate crystals, CuSO4.5H2O Aqueous copper(II) sulfate solution, CuSO4(aq) Blue Copper(II), Cu2+ Hydrated copper(II) nitrate crystals, Cu(NO3)2.3H2O Aqueous copper(II) nitrate solution, Cu(NO3)2(aq) Anhydrous cobalt(II) chloride, CoCl2
  • 3. Colour of Unknown Chemicals/Ions Substances I2 (solution) Brown Lead(IV) oxide, PbO2 Examples: Hydrated iron(III) nitrate crystals, Fe(NO3)3.9H2O Iron(III), Fe3+ Aqueous iron(III) nitrate solution, Reddish-brown Fe(NO3)3(aq) Iron(III) oxide, Fe2O3 Copper metal
  • 4. Colour of Unknown Chemicals/Ions Substances Examples: Hydrated iron(II) sulfate crystals, FeSO4.7H2O Iron(II), Fe2+ Green / Light Green Aqueous iron(II) sulfate solution, FeSO4(aq) Examples: Copper(II) carbonate, CuCO3 Copper(II), Cu2+ Hydrated copper(II) chloride crystals, CuCl2.2H2O Potassium Purple manganate(VII), KMnO4 Potassium Orange dichromate(VI), K2Cr2O7
  • 5. Colour of Unknown Chemicals/Ions Substances Lead(II) Yellow oxide, PbO Lead(II) iodide, PbI2, See the web site below for the test for iodide http://www.youtube.com/watch?v=tQ_sJTQAnRM Silver bromide, AgBr (Pale yellow) Silver iodide, AgI
  • 6. Colour of Unknown Chemicals/Ions Substances Examples: Zinc powder Metals (in Grey powder form) Aluminium powder Iron powder Co2+ Hydrated cobalt(II) Pink (hydrated) chloride crystals, CoCl2.6H2O Aqueous cobalt(II) chloride solution, CoCl2(aq)
  • 7. Colour of Unknown Chemicals/Ions Substances Na+, K+, NH4+, Ca2+, Zn2+, Pb2+, Al3+ White (Absence of salts like iron(II), iron(III), copper(II) and other transition elements) Colourless Dilute acids, alkalis, hydrogen peroxide(H2O2) Solution (B) Action of Heat on Carbonates Cation Observations/Gas Equation evolved Na+ White residue; Na2CO3.10H2O(s) → Na2CO3(s) + 10H2O(g) Water vapour evolved white crystals white powder + K White residue Not decomposed Ca 2+ White residue; carbon CaCO3(s) → CaO(s) + CO2(g) dioxide evolved white white Zn2+ Residue is yellow when hot ZnCO3(s) → ZnO(s) + CO2(g) and white when cold; white yellow –hot carbon dioxide evolved white - cold Pb 2+ Yellow (orange) residue; PbCO3(s) → PbO(s) + CO2(g) carbon dioxide evolved white yellow Al3+ White residue; carbon Al2(CO3)3(s) → Al2O3(s) + 3CO2(g) dioxide evolved white white Cu 2+ Black residue; carbon CuCO3(s) → CuO(s) + CO2(g) dioxide evolved green black Fe2+ Black residue turning FeCO3(s) → FeO(s) + CO2(g) reddish brown on contact green black with air (oxidation); carbon dioxide evolved 4FeO(s) + O2(g) → 2Fe2O3(s) air reddish-brown Fe3+ Reddish-brown residue; Fe2(CO3)3(s) → Fe2O3(s) + 3CO2(g) carbon dioxide evolve brown reddish-brown