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Influence of Windblown Dust on
              Snowmelt Timing in the Rocky
                     Mountains, USA
                Using Calcium as an indicator of dust



       David W. Clow1
       Mark Williams2
       George Ingersoll1



1. U.S. Geological Survey
2. University of Colorado, Boulder
Snowmelt is Occurring Earlier

                            Trend in Snowmelt Onset



 In Colorado, Snowmelt
 and Streamflow are
 Ocurring 2 Weeks Earlier
 than in the Late 1970s

 What are the Drivers?




                                Clow (2010), J. Climate
Dust is One Driver of Early Melt


 Dust changes snowpack albedo

 Other Drivers Include:

    Increasing Air Temperature

    Decreasing Snowfall



                                 Photo from Niwot Ridge, spring 2006
Key questions:
 What is the Spatial Pattern
 of Dust Deposition in the
 Rocky Mountains?

 Are there trends in Dust
 Deposition?

 What is the Relative
 Importance of Dust in
 Controlling Snowmelt
 Timing?
Problem: Data are Sparse



 Little dust data for Rocky
 Mountains

 Makes analysis of the
 influence of dust on
 snowmelt timing
 problematic
Can We Take Advantage of Existing Snow
Chemistry Data?
Hypothesis: Calcium can be Used as Indicator of Dust Deposition



  Dust contains Calcite

  Calcite dissolves readily,
  releasing Ca and HCO3
  (alkalinity)

  Reflected in precipitation
  Chemistry
Rocky Mountain Snowpack has Chemical
Signature of Calcite
  57 Sites Sampled Annually           Principal
  in Rockies during 1992-            Components
  2009                                1       2       3
                               Alk   0.77    0.16    0.33
  PCA identified the
                               Ca    0.82    -0.27   0.27
  following components:
                               Mg    0.79    -0.35   0.23

       Alk, Ca, Mg (dust)      Na    0.17    -0.15   0.92

                               K     0.69    -0.02   -0.04
       NH4, NO3, SO4 (acids)
                               NH4   -0.13   -0.69   0.13

       Na, Cl (salt)           Cl
                                     0.21    -0.05   0.90


  Explained 75% of             NO3   0.24    -0.85   0.08

  Variance in Chemistry        SO4   0.22    -0.88   -0.01
Dusty Snow Layers Contain Calcite

Major dust event in February 2006

Dust Layer was Sampled at 14 Sites in Colorado

Samples Analyzed for Ca, Alkalinity, Dust
Concentrations

Dust Layers had a Strong Calcite Signature




     Feb 2006 dust layer, Niwot Ridge
Dust often Originates in Desert Southwest



                                           Feb 14 - 15, 2006




            Typical Transport Trajectory
Spatial Patterns: Wet Deposition of Calcium

                          2007
Spatial Patterns: Snowpack Ca Increases
from North to South

   1992-2009                        Winter
   averages

   Alk and Mg
   show same
   pattern

   Ca can be
   used as
   surrogate for
   dust
Trends in Winter Ca during 1992 - 2009
 Trends were
 Analyzed using
 the Regional
                                    Winter
 Kendall Test
 (RKT)

 60% of groups
 had significant
 trends (all up)

 Trends were
 Strongest in
 South-Central
 Rockies
Trends in Springtime Ca in Wet Deposition




 Relatively few
 Significant trends

 A few Upward
 Trends in Northern
 Colorado
Climate and Dust Affect
       Snowmelt Timing
Snowmelt Onset   Snowmelt Center of Mass
Conclusions
Dust deposition increases from north to
south in the Rockies

Trends in Dust Deposition were variable

   Increasing trends in northern
   Colorado, but magnitude uncertain

Major Drivers of Snowmelt Timing in the
Rockies include:

   Increasing Springtime Air
   Temperatures

   Decreasing Snowfall

   Increasing Dust Concentrations
Acknowledgements

Funding Provided by
 USGS Office of Global Change
   Water, Energy, and
   Biogeochemical Budgets
   program

 National Science Foundation
   Long-Term Ecological Research
   program
Future Directions
 Prepare Manuscript

 Incorporate Dust Effect in
 Hydrological Models
 (PRMS)

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Influence of Windblown Dust on Snowmelt Timing in the Rocky Mountains

  • 1. Influence of Windblown Dust on Snowmelt Timing in the Rocky Mountains, USA Using Calcium as an indicator of dust David W. Clow1 Mark Williams2 George Ingersoll1 1. U.S. Geological Survey 2. University of Colorado, Boulder
  • 2. Snowmelt is Occurring Earlier Trend in Snowmelt Onset In Colorado, Snowmelt and Streamflow are Ocurring 2 Weeks Earlier than in the Late 1970s What are the Drivers? Clow (2010), J. Climate
  • 3. Dust is One Driver of Early Melt Dust changes snowpack albedo Other Drivers Include: Increasing Air Temperature Decreasing Snowfall Photo from Niwot Ridge, spring 2006
  • 4. Key questions: What is the Spatial Pattern of Dust Deposition in the Rocky Mountains? Are there trends in Dust Deposition? What is the Relative Importance of Dust in Controlling Snowmelt Timing?
  • 5. Problem: Data are Sparse Little dust data for Rocky Mountains Makes analysis of the influence of dust on snowmelt timing problematic
  • 6. Can We Take Advantage of Existing Snow Chemistry Data? Hypothesis: Calcium can be Used as Indicator of Dust Deposition Dust contains Calcite Calcite dissolves readily, releasing Ca and HCO3 (alkalinity) Reflected in precipitation Chemistry
  • 7. Rocky Mountain Snowpack has Chemical Signature of Calcite 57 Sites Sampled Annually Principal in Rockies during 1992- Components 2009 1 2 3 Alk 0.77 0.16 0.33 PCA identified the Ca 0.82 -0.27 0.27 following components: Mg 0.79 -0.35 0.23 Alk, Ca, Mg (dust) Na 0.17 -0.15 0.92 K 0.69 -0.02 -0.04 NH4, NO3, SO4 (acids) NH4 -0.13 -0.69 0.13 Na, Cl (salt) Cl 0.21 -0.05 0.90 Explained 75% of NO3 0.24 -0.85 0.08 Variance in Chemistry SO4 0.22 -0.88 -0.01
  • 8. Dusty Snow Layers Contain Calcite Major dust event in February 2006 Dust Layer was Sampled at 14 Sites in Colorado Samples Analyzed for Ca, Alkalinity, Dust Concentrations Dust Layers had a Strong Calcite Signature Feb 2006 dust layer, Niwot Ridge
  • 9. Dust often Originates in Desert Southwest Feb 14 - 15, 2006 Typical Transport Trajectory
  • 10. Spatial Patterns: Wet Deposition of Calcium 2007
  • 11. Spatial Patterns: Snowpack Ca Increases from North to South 1992-2009 Winter averages Alk and Mg show same pattern Ca can be used as surrogate for dust
  • 12. Trends in Winter Ca during 1992 - 2009 Trends were Analyzed using the Regional Winter Kendall Test (RKT) 60% of groups had significant trends (all up) Trends were Strongest in South-Central Rockies
  • 13. Trends in Springtime Ca in Wet Deposition Relatively few Significant trends A few Upward Trends in Northern Colorado
  • 14. Climate and Dust Affect Snowmelt Timing Snowmelt Onset Snowmelt Center of Mass
  • 15. Conclusions Dust deposition increases from north to south in the Rockies Trends in Dust Deposition were variable Increasing trends in northern Colorado, but magnitude uncertain Major Drivers of Snowmelt Timing in the Rockies include: Increasing Springtime Air Temperatures Decreasing Snowfall Increasing Dust Concentrations
  • 16. Acknowledgements Funding Provided by USGS Office of Global Change Water, Energy, and Biogeochemical Budgets program National Science Foundation Long-Term Ecological Research program
  • 17. Future Directions Prepare Manuscript Incorporate Dust Effect in Hydrological Models (PRMS)