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Stoichiometry
What is
Stoichiometry?
Stoichiometry
Stoicheion [Gr. “element” or “part”]
Metron [Gr. “measure”]
Study of quantitative aspects of
chemical formulas and reactions
Cooking/Baking
Recipes
+
Recipes
+
Meat + Boiling Water =
Stock
Recipes
+
Water + Sugar = Soft
Candy
Recipes
+
Flour + Eggs + Milk + Sugar =
Cake
Similarly…
• Chemical reactions have
ingredients (reactants) and
finished products.
• Some are simple while
others are complex.
• Both obey the Law of
Conservation of Mass.
(What you put in is what you
get)
ChemicalReactions
In chemical reactions, we use moles and
molar mass as our measurement.
Moles to measure amount of substance.
Molar mass to measure the ratio of mass
and amount of substance
Chemical reactions are expressed as
chemical equations
ChemicalReactions
Chemical reactions are expressed in
chemical equations (our “recipe”)
2 Mg(s)
+
O2(g
)
--- 2
MgO(s)
Indicates the state of matter;
solid (s), liquid (l), aqueous
solution (aq), gas (g)
ChemicalReactions
Chemical reactions are expressed in
chemical equations (our “recipe”)
2 Mg(s)
+
O2(g
)
--- 2
MgO(s)
coefficient
Both sides of the equation must have
equal
amounts of atoms.
Mg: 2
atoms
O: 2 atoms
Mg: 2
atoms
O: 2 atoms
Measurement
in Chemical
Reactions
Measurement
In baking, we measure ingredients
using measuring cups
Instead, in chemistry, we measure reactants
and products in moles
TheMole(mol)
SI unit for amount of substance
Defined as the amount of a substance that
contains the same number of entities as there
are atoms in exactly 12 grams of carbon-12.
That is
6.022 x1023 [called Avogrado’s number]
∴1 mol of carbon-12 contains 6.022
x1023 carbon-12 atoms
1 mol of H2O contains 6.022 x1023 H2O
molecules
MolarMass(M)
Ratio of amount of substance (mol) and
mass (g)
Expressed in grams per mol (g/mol)
Molar mass (M)of element: listed in
the Periodic Table
Of compound: sum of the molar masses of
the atoms of the elements in the
compound
MolarMass(M)
MM of O2 = 32
g/mol O = 16 g/mol
16x2 = 32
MM of CO2 =
44.01 g/mol
Problems
Related
toChemical
Reactions
ProblemsRelatedtoChemReactions
Balancing reactions
Converting moles to
grams
Finding the limiting (and excess)
reactant
Balancing
N2O5 --- NO2 +
O2
Balancing
2
N2O5
--- 4 NO2
+
1
O2
Balancing
C8H1
8
+ O2 --- CO2 +
H2O
Balancing
2
C8H18
+ 25
O2
---16CO2 +18
H2O
Balancing
Cu
(s)
+ S8(
s)
---

Cu2S(
s)
Balancing
16 Cu (s) + 1
S8(s)
--- 8
Cu2S(s)
Conversio
n
How many moles are there in 7.00 grams of
Cu?
7 g Cu x mol Cu/63.55 g Cu = 0.110 moles
Conversio
n
How many grams are there in of 1 mol
O2?
32 grams
ReactionsInvolvingaLimiting
Reactant
+
ReactionsInvolvingaLimiting
Reactant
+
Sample
Problem
A fuel mixture is composed of two liquids,
hydrazine (N2H4) and dinitrogen tetraoxide
(N2O4), which ignite on contact to form
nitrogen gas and water vapour. How many
grams form when 1.00 x102 g of N2H4 and
2.00 x102 g of N2O4 are mixed?
MM of N = 14.01
g/mol MM of H =
1.01 g/mol MM of O
= 16 g/mol
Sample
Problem
• Plan:
– Write the balanced
equation
– 2 N2H4 (l) +
N2O4(l)
--- 3 N2(g) + 4
H2O(g)
– To determine the limiting reagent/reactant, we
calculate the mass of N2 from each reactant
assuming an excess of the other. Whichever
yields less N2 is the limiting reactant.
Sample
Problem
• 2 N2H4 (l) +
N2O4(l)
--- 3 N2(g) + 4
H2O(g)
• Assuming N2H4 is limiting, 4.68 mol
N2 is produced
• Assuming N2O4 is limiting, 6.51 mol
N2 is produced
• ∴N2H4 is the limiting reactant
Sample
Problem
• If N2H4 is the limiting reactant, 131 g
N2 is produced
Sample
Problem
Nuclear engineers use chlorine trifluoride in
the processing of uranium fuel for power
plants. This extremely reactive substance is
formed as a gas in special metal containers
by the reaction of elemental chlorine and
fluorine.
With 0.750 mol of Cl2 and 3.00 mol of F2,
what mass of chlorine trifluoride will be
prepared?
MM Cl = 35.45
g/mol MM F =
Sample
Problem
Cl2(g) + 3F2(g) --> 2
ClF3(g)
Cl2 is limiting
Mass (g) of ClF3 =
139 g
Sources
• Dragon Cave Holiday Cooking 2012. [Photos]
• Silberberg, Martin S. “Stoichiometry of Formulas and
Equations”. Principles of General Chemistry.
McGraw-Hill, 2010.

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