TASK A3 
                   
    HAZARDOUS WASTE MANAGEMENT 
         CONCEPT FOR TURKEY 
 
 
IMPROVEMENT OF INDUSTRIAL HAZARDOUS WASTE MANAGEMENT
                      IN TURKEY

               LIFE “HAWAMAN” PROJECT



                 LIFE06/TCY/TR/000292




                       TASK A3



   HAZARDOUS WASTE MANAGEMENT CONCEPT FOR TURKEY
TABLE OF CONTENTS

1 INTRODUCTION ..................................................................................................... 1

2 LEGISLATIVE FRAMEWORK AND STAKEHOLDERS OF HAZARDOUS
    WASTE MANAGEMENT ...................................................................................... 9

   2.1     LEGISLATIVE FRAMEWORK ................................................................................. 9

   2.2     STAKEHOLDERS OF HAZARDOUS WASTE MANAGEMENT ..................... 17

3 DEVELOPMENT OF HAZARDOUS WASTE MANAGEMENT SYSTEM IN
    TURKEY ................................................................................................................. 19

4 CURRENT SITUATION OF HAZARDOUS WASTE MANAGEMENT IN
    TURKEY ................................................................................................................. 24

5 HAZARDOUS WASTE MANAGEMENT CONCEPT ....................................... 28

   5.1     HAZARDOUS WASTE QUANTITY ESTIMATION ........................................... 28

       5.1.1    Methodology ..................................................................................................................... 29

       5.1.2    Waste estimation .............................................................................................................. 34

       5.1.3    Comparison and validation of results .............................................................................. 45

   5.2     ASSIGMENT OF HAZARDOUS WASTE TYPES TO DISPOSAL OPTIONS . 48

       5.2.1    Methodology ..................................................................................................................... 48

       5.2.2    Allocation to Different Disposal Routes .......................................................................... 53

6 CONCLUSIONS...................................................................................................... 59

7 . RECOMMENDATONS........................................................................................ 62

APPENDIX ................................................................................................................. 65




                                                                                                                                                 ii
LIST OF TABLES

Table 1.1: Contribution of basic economic sectors to GDP (based on current prices) 2 .............................. 5
Table 2.1 List of Turkish legislation on hazardous wastes .................................................................................... 9
Table 4.1 Number of plants and recycle/recovery activities (June 2007)......................................................25
Table 4.2 Types of recyclable wastes admitted to licensed recycling facilities and their capacities... 25
Table 4.3 Wastes used as alternative fuels in cement factories .........................................................................26
Table 4.4 Current capacities of disposal facilities ...................................................................................................27
Table 4.5 Integrated Waste Disposal Facilities ........................................................................................................27
Table 5.1 Covered and omitted waste types and producers ................................................................................34
Table 5.2 List of industrial sector groups ...................................................................................................................37
Table 5.3 Sample waste sector sheet for metal working industry ....................................................................37
Table 5.4 Description and amount of hazardous waste groups in tons/yr ...................................................40
Table 5.5 Geographic distribution of hazardous wastes (1000 tons/yr) .......................................................42
Table 5.6 Comparison of Turkish and German hazardous waste generation ..............................................45



Table A. 1 List of NUTS codes for Turkey ....................................................................................................................65
Table A. 2 Turkish population (2007) ..........................................................................................................................66
Table A. 3 Number of employees in Turkish industry (2007) ..............................................................................69
Table A. 4 Additional information for provinces ......................................................................................................70
Table A. 5 Hazardous waste in Turkey, from industry and other sources in tons/yr ................................72
Table A. 6 Hazardous waste from main industrial sectors in tons/yr .............................................................74
Table A. 7 Hazardous waste from non-industrial sources in tons/yr ..............................................................76
Table A. 8 Hazardous waste from industrial branches in tons/yr ....................................................................78
Table A. 9 Hazardous waste groups in Turkish provinces in tons/yr ..............................................................88
Table A. 10 Range of disposal market prices (€/ton) - (Germany 2002 and Turkey 2007)................. 107
Table A. 11 Assignment of hazardous waste to disposal options .................................................................. 111
Table A. 12 Structure of the price list for hazardous waste incineration in Turkey (2007) ................ 108
Table A. 13 Structure of disposal prices for CPT treatment from Germany (HIM 2002) ...................... 110




                                                                                                                                                             iii
LIST OF FIGURES

Figure 1.1: Chronology of Population Growth, Turkey ............................................................................................ 2
Figure 1.2: Population Pyramid, Turkey (2006) ........................................................................................................ 2
Figure 1.3 Distribution of Population in Turkey ....................................................................................................... 3
Figure 1.4 Chronology of GNP of Turkey ....................................................................................................................... 4
Figure 1.5 Chronology of Inflation Rate of Turkey .................................................................................................... 4
Figure 1.6 Employees in Turkish Industry, total ........................................................................................................ 6
Figure 1.7 Employees in Turkish Metal Industry ....................................................................................................... 7
Figure 1.8 Employees in Turkish Chemical Industry ................................................................................................ 7
Figure 1.9 Employees in Turkish Other Industries .................................................................................................... 8
Figure 2.1 Steps to be followed to determine a hazardous waste according to RCHW ............................12
Figure 2.2 Main duties, responsibilities and jurisdiction in the hazardous waste management system
.....................................................................................................................................................................................................18
Figure 3.1 Hazardous waste management regions ................................................................................................20
Figure 5.1 Production in 1 or 3 facilities: material balance differs by factor three ...................................30
Figure 5.2 Hazardous waste generation in Turkey, total .....................................................................................43
Figure 5.3 Hazardous Waste Generation in Industry (81 %) .............................................................................43
Figure 5.4 Hazardous Waste Generation from separately collected waste (19 %) ...................................44
Figure 5.5 Hazardous waste amounts in several countries versus GNP “power parity” ..........................47
Figure 5.6 Recommended hazardous waste disposal routes for Turkey – overview .................................54
Figure 5.7 Recommended hazardous waste disposal routes to recycling/recovery ..................................54
Figure 5.8 Recommended hazardous waste disposal routes to CPT ................................................................55
Figure 5.9 Recommended hazardous waste disposal routes to thermal treatment ..................................55
Figure 5.10 Recommended hazardous waste disposal routes to controlled landfill .................................56
Figure 5.11 Scheme of a fully integrated hazardous waste treatment / disposal facility .......................58
Figure 6.1 Five recommended planning areas for integrated hazardous waste treatment facilities 61
Figure 6.2 Locations of 189 mostly private operating hazardous waste treatment facilities in Turkey
.....................................................................................................................................................................................................61
Figure 7.1 Locations and numbers of municipal sewage treatment plants in Turkey ..............................63



Figure A. 1 Number of employees in Turkish Industry (2007) ...........................................................................67
Figure A. 2 Provincial distribution of pesticides and agrochemical hazardous wastes (ID No:1) .......94
Figure A. 3 Provincial distribution of wood preservative wastes (ID No:2) ..................................................94
Figure A. 4 Provincial distribution of hazardous tannery wastes (ID No:3) .................................................95
Figure A. 5 Provincial distribution of hazardous petroleum refining wastes (ID No:4) ...........................95
Figure A. 6 Provincial distribution of acidic and alkaline wastes (ID No:5) .................................................96
Figure A. 7 Provincial distribution of hazardous inorganic chemistry wastes (ID No:6) ........................96
Figure A. 8 Provincial distribution of hazardous organic chemistry wastes (ID No:7) ............................97
Figure A. 9 Provincial distribution of hazardous paint and sealant production wastes (ID No:8) ......97
Figure A. 10 Provincial distribution of hazardous printing wastes (ID No:9)..............................................98
Figure A. 11 Provincial distribution of hazardous energy production wastes (ID No:10) ......................98
Figure A. 12 Provincial distribution of hazardous metal production wastes (ID No:11) ........................99
Figure A. 13 Provincial distribution of hazardous mineral and glass production wastes (ID No:12) 99
Figure A. 14 Provincial distribution of hazardous galvanizing wastes (ID No:13) ................................. 100
Figure A. 15 Provincial distribution of non-halogenated waste oil (ID No:14) ........................................ 100

                                                                                                                                                                                                  iv
Figure A. 16 Provincial distribution of halogenated waste oil (ID No:15).................................................. 101
Figure A. 17 Provincial distribution of waste oil emulsions (ID No:16) ....................................................... 101
Figure A. 18 Provincial distribution of other oily wastes (ID No:17) ............................................................ 102
Figure A. 19 Provincial distribution of halogenated solvents (ID No:18) ................................................... 102
Figure A. 20 Provincial distribution of non-halogenated solvents (ID No:19) .......................................... 103
Figure A. 21 Provincial distribution of contaminated packagings (ID No:20) ......................................... 103
Figure A. 22 Provincial distribution of spent adsorbents and filter materials (ID No:21) ................... 104
Figure A. 23 Provincial distribution of spent oil filters (ID No:22) ................................................................ 104
Figure A. 24 Provincial distribution of spent brake fluids and antifreeze (ID No:23)............................ 105
Figure A. 25 Provincial distribution of spent batteries (ID No:24) ................................................................ 105
Figure A. 26 Provincial distribution of sludges from CPT (ID No:26) ........................................................... 106
Figure A. 27 Provincial distribution of mercury containing waste (ID No:27) ......................................... 106
Figure A. 28 Provincial distribution of contaminated wood (ID No:28)...................................................... 107
Figure A. 29 Recommended hazardous waste disposal routes to recycling/recovery – amount per
province ................................................................................................................................................................................. 119
Figure A. 30 Recommended hazardous waste disposal routes to CPT – amount per province .......... 121
Figure A. 31 Recommended hazardous waste disposal routes to thermal treatment – amount per
province ................................................................................................................................................................................. 123
Figure A. 32 Recommended hazardous waste disposal routes to controlled landfill – amount per
province ................................................................................................................................................................................. 125




                                                                                                                                                                                           v
1       INTRODUCTION

Fundamentals of hazardous waste management are laid down on various policy
and legislative documents. International principles on which hazardous waste
management concept is developed include “Precautionary Principle”, “Waste
Hierarchy” and “Polluter Pays”. These principles are embedded in legislative
documents according to which modern hazardous waste management systems
are developed and successfully established. Turkish Regulation on Control of
Hazardous           Wastes       (RCHW)1,     harmonized   with   Directive   of   European
Commission on hazardous wastes (91/689/EEC), being the core regulation on
hazardous waste management, also includes these principles of hazardous waste
management. Even though baseline of hazardous waste management is
presented, it is essential to develop an elaborate hazardous waste management
concept for Turkey in order for the waste management system to be realistic and
efficient. This concept should especially consider practical aspects unique to
Turkey.

Hazardous waste management concept presented in this report is developed
under Task A and Task C of LIFE HAWAMAN Project by German Experts,
Turkish Experts and Ministry of Environment and Forestry (MoEF). In the
context of this report, in Chapter 2, legislative framework concerning hazardous
wastes, in Chapter 3, current situation of hazardous waste management and
stakeholders of the system and in Chapter 4, hazardous waste management
concept as developed by LIFE Team are introduced.

Before presenting hazardous waste management concept, it is quite useful for the
reader to acquire some background information on Turkey. These include
demographic and economic information both of which influences hazardous
waste generation amounts and distribution.

Population of Turkey shows a rapid increase since the 1960s. As seen in Figure
1.1, population increased from about 30 Million in 1960s to about 71 Million in
2007 with a smooth turning range in the 1980s. Simple statistical analysis proves
that population growth of Turkey resembles arithmetic growth model with a nice
linear fit of r2= 0.997.




1   Official Gazette, 14/3/2005, No. 25755.

                                                                                          1
Figure 1.1: Chronology of Population Growth, Turkey

In Figure 1.2, population pyramid of Turkey is given. The shape of the population
pyramid looks sustainable at present with a high percentage of younger people
compared with a small percentage of older people. This shape of the pyramid
suggests high potential for productivity as result of high number of younger
people thus high number of work force.




Figure 1.2: Population Pyramid, Turkey (2006)




                                                                               2
Figure 1.3 below and Table A. 2 in Appendix present the countrywide
distribution of population. The major center of gravity of the Turkish population
by far is Đstanbul, with more than 12 Million people. Very low populated districts
are to be found in the eastern part of Turkey, like Tunceli or Bayburt (each much
less than 100 000 people).




Figure 1.3 Distribution of Population in Turkey 2

As mentioned before another important set of background information is the
economic figures. Gross National Product (GNP) is the total monetary value of all
final goods and services produced for consumption in society during a particular
time period and a very strong parameter indicating economic activity. Within the
last decade there is a remarkable increase in GNP (Figure 1.4), along with a
strong decrease of the inflation rate (consumer prices) (Figure 1.5).

Apparent from Figure 1.4 and Figure 1.5, Turkish economy between the years
2002-2007 has shown significant improvement. Average growth of economy
reached up to 7% and increase in export reached 23% 3.




2 List of NUTS codes used throughout the report is given in Table A. 1 in Appendix.
3 The Union of Chambers and Commodity Exchanges of Turkey (TOBB), Economy Report 2008, Available
from http://www.tobb.org.tr/yayinlar/64gk/ekonomik%20rapor.pdf , Data retrieved May 22, 2009

                                                                                              3
Figure 1.4 Chronology of GNP of Turkey




                                      Turkey - Inflation Rate in %
           70

            60

            50

            40

            30

            20

            10                                                         8.5%

                 Source: Index Mundi (2008)
             0
             2000                 2002           2004         2006   2008

Figure 1.5 Chronology of Inflation Rate of Turkey

This rapid development in economy has ceased in 2007 due to the effects of
global economic crisis. As a result, the average growth in the economy was 4.7%
in 2007, 3.6% in the first nine months of 2008, and 1.1% in whole year of 2008 3.

In Table 1.1, contribution of economic sectors to gross domestic product (GDP) is
given.



                                                                                    4
Table 1.1: Contribution of basic economic sectors to GDP (based on current prices) 3

                                                                        CONTRIBUTION TO GDP
                            SECTOR                                              (%)
                                                                         2006         2007         2008
Agriculture, hunting and forestry                                         8.0          7.4          7.6
Fishing                                                                   0.2          0.2          0.2
Mining and quarrying                                                      1.2          1.2          1.4
Manufacturing Industry                                                    17.2         16.8         16.1
Electricity, gas, steam and hot water generation and
                                                                          1.8          1.9          2.1
distribution
Construction                                                              4.7          4.9          4.7
Wholesale and retail commerce                                             12.5         12.2         12.2
Hotels and restaurants                                                    2.2          2.3          2.3
Transportation, storage and communication                                 13.7         13.9         14.2
Activities of financial factors                                           2.9          3.2          3.5
Residence ownership                                                       9.8          10.8         11.2
Real estate renting and other activities                                  3.7          4.1          4.3
Public administration, defense and mandatory social
                                                                          3.9          3.9          3.8
security
Education                                                                 2.8          2.9          2.9
Health and social services                                                1.6          1.6           1.6
Other social, public and individual services                              1.7          1.7          1.7
Domestic employment                                                       0.2          0.2          0.2
Indirect factoring and taxes                                              14.6         13.6         13.3
TOTAL                                                                     100          100          100



Among the manufacturing industry, food and beverage sector and textile sector
have the highest share in Turkey. According to Turkish Prime Ministry State
Planning Organization (SPO) food industry has a share of 18 – 20% in the overall
manufacturing industry in terms of production value4. Whereas the textile
industry occupies 10% of the GNP of Turkey that is 319 billions US $ 5.

With regard to population, the quota of employees in the Turkish industry is
overall about 3 % which is about 4.6 % in Đstanbul. Relating to the total number of
employees in Turkey, the biggest number of employees can be ascertained in


4 T.R. Prime Ministry State Planning Organization (SPO). IXth Development Plan Food Industry Special
Commission Report. Ankara: 2007
5 T.R. Prime Ministry State Planning Organization (SPO). IXth Development Plan Textile, Leather and Clothing

Industry Special Commission Report. Ankara: 2007

                                                                                                           5
Đstanbul - about 27 %, followed by Bursa (8.3 %), Đzmir (7.1 %), Kocaeli (5.1 %)
and Ankara (5.0 %). All other districts are below 5 %. From Figure 1.6 to Figure
1.9, the distribution of employees according to provinces (NUTS3 level) is given.
Moreover, in Table A. 3 and Figure A. 1 in Appendix exact numbers of employees
in every province and according to major industrial braches can be found. The
number of employees is a measure of industrial activity – and is therefore a rough
measure of hazardous waste generation. Hence it is most likely to find the
hazardous waste centers in the high-industrialized districts – especially in the
Metal Industry and the Chemical Industry.




Figure 1.6 Employees in Turkish Industry, total




                                                                                6
Figure 1.7 Employees in Turkish Metal Industry




Figure 1.8 Employees in Turkish Chemical Industry




                                                    7
Figure 1.9 Employees in Turkish Other Industries




                                                   8
2     LEGISLATIVE FRAMEWORK AND STAKEHOLDERS                                       OF
      HAZARDOUS WASTE MANAGEMENT

2.1   LEGISLATIVE FRAMEWORK

International framework for hazardous wastes is shaped by Basel Convention on
Control and Supervision of the Transboundary Shipment of Hazardous Waste
that has been ratified by Turkey. National legislative framework regarding
hazardous wastes is comprised of legislations regarding general rules for waste
management and hazardous wastes and legislations regarding management of
specific types of wastes. Legislations on specific types of wastes are in compliance
with the fundamental rules laid down in legislations handling general
management concepts. In Table 2.1, a list of legislations related to hazardous
wastes and their counterparts in European Union (EU) Acquis is provided

Table 2.1 List of Turkish legislation on hazardous wastes

        TURKISH LEGISLATION                              EU COUNTERPART
Regulation on General Principles of Waste
                                            Directive 2006/12/EC on waste
Management
Regulation on Control of Hazardous
                                            Directive 91/689/EEC on hazardous waste
Wastes
                                            Directive 75/439/EEC on the disposal of
Regulation on Control of Waste Oils
                                            waste oils
Regulation on Control of Waste Vegetable
Oils
                                            Directive 2006/66/EC on batteries and
Regulation on the Control of Used
                                            accumulators and waste batteries and
Batteries and Accumulators
                                            accumulators
Regulation on the Control of Packaging Directive 94/62/EC on packaging and
and Packaging Waste                         packaging waste
Regulation for Control of the Tyres Which
Have Completed Their Life-Cycles (TCL)
Regulation on the Restriction of the use of Directive 2002/95/EC on the restriction of the
Certain     Hazardous      Substances    in use of certain hazardous substances in
Electrical and Electronic Equipment         electrical and electronic equipment
Regulation for Control of Medical Waste
Regulation on Control of Polychlorinated Directive 96/59/EC on the disposal of
Biphenyls        and        Polychlorinated polychlorinated          biphenyls        and
Terphenyls                                  polychlorinated terphenyls (PCB/PCT)
Regulation on Control of End-Of-Life Directive 2000/53/EC on End-Of-Life
Vehicles (Draft)                            Vehicles
Regulation on Landfill of Waste (Draft)     Directive 1999/31/EC on the landfill of waste
Regulation on Incineration of Waste Directive 2000/76/EC on the incineration of
(Draft)                                     waste.

                                                                                      9
Among these regulations listed in Table 2.1, Regulation on General Principles of
Waste Management and RCHW are the core regulations covering main aspects of
waste management practices while the rest deals with specific types of waste.
Last two regulations that are on landfilling and incineration lays down general
measures for these two disposal activities. According to RCHW, main principles
of waste management is as follows:

 o Except for the cases in which hazardous wastes present an economic value
     to the importer and import of the hazardous waste is allowed by the edicts
     of MoEF, import of all types of hazardous wastes are forbidden.
 o In accordance with waste hierarchy, waste prevention and waste
     minimization is the most desired option. Reuse, recovery or recycling
     (especially waste oils, organic solvents, accumulators) and whenever prior
     options are not applicable, treatment options follow prevention and
     minimization respectively. The least desired option is final disposal.
     Whenever feasible, energy recovery during disposal should be evaluated
     and applied.
 o Waste generators, transporters and disposers are held responsible for the
     dangers created by hazardous wastes and “polluter pays” principle is
     adopted.
 o Companies that store, sell and dispose hazardous wastes are obliged to have
     a license from MoEF and companies without proper licenses are prohibited
     to operate and mix hazardous wastes with other fuels.
 o Segregation of hazardous wastes is mentioned and mixing of hazardous
     wastes with non-hazardous wastes is forbidden in all cases. This rule also
     holds for the commingled wastes arriving at disposal facilities.
 o In case of interim storage, priority should be given to storage at the point of
     generation.
Main components of the hazardous waste management system consists of
generation, storage, collection, transportation, treatment (whenever possible) and
disposal of hazardous wastes. Generation of hazardous wastes should involve the
waste prevention and waste minimization activities aside from the hazardous
waste generating processes. Storage involves temporary storage of hazardous
wastes either in the location of generation or specially designed temporary
storage facilities suitable for hazardous wastes. Storage should not be confused
with landfilling of hazardous wastes. Collection by definition means to gather
objects together which in the context of hazardous waste management refer to the


                                                                               10
step where hazardous wastes are accumulated before being sent to temporary
storage facilities, treatment or disposal sites. Transportation part of hazardous
waste management system is the one where the wastes are conveyed to
temporary storage, treatment or disposal facilities following collection of wastes.
Treatment also involves the recycling processes. It is important to note that not all
the hazardous wastes are suitable for treatment or recycle. Disposal is the
ultimate fate of most of the hazardous wastes.

Rules outlined by RCHW regarding the abovementioned components are as
follows:

Determination and classification of hazardous wastes

Steps that should be followed by waste generator in order to determine whether a
waste is hazardous or not is given in Figure 2.1.

Step 1: Is the substance described as waste in RCHW?

For a substance to be “waste” it should have waste properties given in RCHW
Annex 1. If the substance does not have those properties it cannot be described as
hazardous waste.

Step 2: Are there any specific provisions in RCHW for the waste in question?

Step 3: Does the waste listed in Annex 7?

RCHW Annex 7 is adopted from Commission Decision as regards the list of
wastes (2001/118/EC) and contains the marked entries as hazardous wastes.
Complete list of waste is presented in Regulation on General Principles of Waste
Management. Annex 7 contains 20 chapters that relate to the process that
generated the waste or to specific waste types. If the waste is listed in Annex 7,
Step 4a should be followed. If not Step 4b should be followed.

Step 4a: How is the waste coded and classified in Annex 7?

The chapters are given a two-digit number. Each Chapter contains sub-chapters
that are identified by four-digits. Within each sub-chapter is a list of unique six
digit codes for each waste.

Annex 7 contains two types of wastes:

    Absolute entries: hazardous regardless of their composition or concentration of
    any dangerous substance within the waste.

                                                                                  11
Mirror entries: wastes that have the potential to be either hazardous or not,
    depending on whether they contain “dangerous substances” at or above
    certain thresholds. For the mirror entries Annex 3b should be considered and
    Step 4b should be followed.




Figure 2.1 Steps to be followed to determine a hazardous waste according to RCHW




                                                                                   12
Step 4b: Is the waste produced as a result of processes listed in RCHW Annex 3?

RCHW Annex 3 lists activities that can generate hazardous wastes. Annex 3 is
comprised of two sections; Annexes 3a and 3b. If no specific entry could be found
in Annex 7 regarding the waste or if the waste is a mirror entry, Annexes should
be checked whether Annex 3a or Annex 3b applies based on the process from
which the waste is generated. For the wastes that are in context of Annex 3a, Step
5 should be followed. If the waste generating process is not listed in Annex 3a,
Annex 3b should be checked. This section lists the waste that can be hazardous
only if certain components are present within the waste.

Step 4c: Is the waste listed in Annex 3b contains the constituents listed in Annex 4?

The constituents that can render a waste hazardous are listed in Annex 4 and if
the waste listed in Annex 3b contains any of the constituents given in Annex 4;
Step 5 should be applied. If the waste listed in Annex 3b does not contain any of
the constituents of Annex 4, it cannot be classified as hazardous waste.

Step 5: Does the waste have the properties listed in Annex 5?

For the following classes of wastes to be hazardous, they must have at least one
property given in Annex 5:
     o Wastes classified as mirror waste in Annex 7
     o Wastes generated as a result of processes given in Annex 3a
     o Wastes listed in Annex 3b and contain at least one component of Annex 4.

For these types of wastes there are two methods to determine whether they are
hazardous or not:
     o Estimation of presence of hazardous properties by checking threshold
           concentrations associated with certain risk phrases
     o Testing for hazardous properties

For mirror entries, as long as the composition of the waste is known, presence of
“dangerous materials” can be confirmed.

If none of the constituents of the waste are “dangerous” and if the waste itself
does not show any hazardous properties from H1 to H14, this waste cannot be
classified as hazardous. If a mirror waste possess a property from H1 to H14 due
to   its     “dangerous”    constituent   concentrations    exceeding     the   threshold
concentrations specified for any hazardous property, this waste should be
classified as hazardous and should be given code accordingly.

                                                                                        13
Step 6a: Does the waste possess hazardous properties of H1,2,9,12-14?

When a waste posses hazardous properties of H1,2,9,12-14, this waste must be
classified as hazardous For these properties no threshold concentrations are
specified.

Step 6b: Does the waste possess hazardous properties of H3-8, H10,11?

For some hazardous properties listed in RCHW Annex 5, threshold
concentrations are specified. If any of the constituents of the waste show
hazardous properties of H3-8, H10, 11 Step 7 should be followed.

Step 7: Does the constituents or waste itself above the threshold concentrations specified
in Annex 6?

The hazardous properties for which threshold concentrations are specified are
H3-8, H10, 11. For this reason, concentrations of constituents that render a waste
hazardous should be checked whether they are above these threshold
concentrations. If a waste contains dangerous constituents below these threshold
concentrations, this waste cannot be classified as hazardous and waste codes
should be given accordingly.

Waste Generation

As mentioned before, priority should be given to prevention and minimization of
wastes at the location of generation. Hazardous waste generators should prepare
a waste management plan and have this plan approved by governorship.
Moreover, if the wastes are going to be stored temporarily within the facility
premises, a permit is required to be taken from governorship. The most
important aspect of temporary storage is to achieve proper and safe conditions
for storage.

Waste generator is obliged to take records of the amounts and types of wastes
generated within the facility and to report these records annually to MoEF
through waste declaration forms. If the generated waste is a mirror entry
according to the abovementioned procedures hazardous nature of wastes should
be confirmed by generator.

Another important responsibility of the waste generator is to ensure that
hazardous wastes generated are transported by licensed companies and disposed

                                                                                       14
of in licensed facilities. Throughout these processes, waste generator shall
provide labeling and packaging in a proper and safe manner.

Waste generator is held responsible for submitting a detailed report (on types,
amounts etc.) to governorship in case of an accidental or deliberate illegal spill
and remediation of the contaminated site no later than one month based on the
type of the waste. Moreover, all the expenses related to remediation must be paid
by the waste generator.

Transportation of the wastes

Transportation companies are obliged to obtain a license from MoEF for
transportation of the wastes to recycling, recovery and disposal facilities.
Licensed waste transporters must use vehicles suitable for the types of wastes
they are carrying. Another important aspect is that the wastes that are being
carried in a vehicle must have the same waste codes. Waste transportation is
followed up via various transportation forms. These forms are categorized as
national and international transportation forms and the required ones need to be
present in the vehicle during transportation.

Interim storage

Main objective of interim storage is to collect wastes so that the amount of wastes
reaches sufficient capacity for transportation before they are sent to recovery or
disposal facilities. Such interim storage facilities are again subject to a license
obtained from MoEF. However, for all types of wastes temporary storage
duration cannot exceed one year that means interim storage facilities cannot act
as final disposal sites. In order to get a license, interim storage facilities need to
show presence of contingency equipments and necessary systems to control
hazardous wastes in case of an accident.

Waste recovery

In order to obtain economic income and to decrease the amount of waste destined
for final disposal, recovery of wastes is promoted. Possible recovery processes are
listed in RCHW (Annex 2b). The most important aspect of recovery is that an
accredited laboratory must confirm that waste becomes a product as a result of
recovery processes. In the same manner, when chemical, physical and biological
treatment is applied on a waste; there is a necessity to confirm that waste is no
longer hazardous according to Annex 11a.


                                                                                   15
Waste Disposal

Liquid wastes suitable for pumping can be disposed of by injection into
geologically and hydrogeologically suitable wells, salt rocks and natural cavities.
Moreover, in abandoned mining sites wastes can be disposed of inside
containers. For these two methods to be applied a feasibility report should be
prepared and a permit should be obtained from MoEF. In Annex 2a of RCHW,
some other possible final disposal methods are listed.

When incineration is used as a disposal method, complete combustion should be
achieved as much as possible. RCHW lists operation requirements for
incinerators. Incineration plants should be designed, equipped and operated so
that the flue gas composition does not violate the emission limits specified in
RCHW. Combustion gases are discharged to atmosphere via the stack in a
controlled manner. Stack height should be designed and applied according to
Industrial Air Pollution Control Regulation. Incineration facilities perform trial
burns before they acquire their permits from MoEF and take license according to
the results of these trial burns.

Second mostly used final disposal method after combustion is landfilling. Proven
that there exist enough precautions or there are no negative impacts on
environment due to the nature of the waste, hazardous wastes can be landfilled
and permit can be taken from MoEF for establishment of landfills. Criteria for
landfilling are presented in Annex 11a of RCHW. Aside from this Annex, the
most important criterion for landfilling is that the water content of the waste to be
landfilled should not exceed 65%. Site selection for landfills is also very
important. According to RCHW, possible sites for establishment of landfills are
listed. In RCHW, there are specifications about landfill liners, drainage systems,
embankments and top cover that will be applied when the landfill site can no
longer accept waste. Hazardous waste landfill must have an operational plan and
submit it to MoEF.

Transboundary movement of wastes

Transboundary movement of wastes into the country is allowed if and only if the
imported wastes have an economically significant value and this is subject to a
permit taken from MoEF. Export of wastes is allowed if and only if there is no
established facility that has sufficient technical waste disposal capacity in Turkey
and the     responsible    authority of the importing country permits the


                                                                                  16
transboundary movement of waste into that country. Neither transit passages nor
transshipments and transfer of wastes are allowed within the area of national
jurisdiction without the consent of MoEF.




2.2   STAKEHOLDERS OF HAZARDOUS WASTE MANAGEMENT

Parties involved in hazardous waste          management      system are     MoEF,
administrative chiefs (governors), local administrations (municipalities in smaller
provinces and greater municipalities in bigger provinces), hazardous waste
generators, and companies that are responsible for transportation, treatment,
recovery and disposal of hazardous wastes. Among these parties, rules valid for
companies responsible for transportation, treatment, recovery and disposal of
hazardous wastes are given in RCHW. Duties, responsibilities and jurisdiction of
MoEF, administrative chiefs, local administrations and waste generators are
shown in Figure 2.2. In the hazardous waste management system, main duties of
MoEF are policy setting, giving permits to disposal, transportation, recovery
companies that have the obligation to have license and inspect them. Application
of hazardous waste management system according to the plans and programs of
MoEF on province-scale is achieved by administrative chiefs and local
administrations. However, the biggest responsibilities on hazardous waste
management systems lie upon hazardous waste generators. From classification
to disposal of hazardous wastes in the context of “polluter pays” principle, the
generator is held financially responsible. Proper transportation, recovery and
disposal of the hazardous waste generated through licensed companies are also
the responsibilities of waste generator. Waste declaration, that has great
importance in inspection mechanisms of MoEF should be carried out by waste
generator with accuracy. It can be seen that for the hazardous waste management
system to function properly waste generators have great responsibility.




                                                                                17
Figure 2.2 Main duties, responsibilities and jurisdiction in the hazardous waste management
system

                                                                                        18
3   DEVELOPMENT OF HAZARDOUS WASTE MANAGEMENT
    SYSTEM IN TURKEY

MoEF has participated in and completed a number of projects towards
development of hazardous waste management practices in Turkey. First one of
these major projects is the In Hazardous Waste Management Project 6 carried out
by TÇT-Zinerji Consortium in 2001. In this project, hazardous waste generation
and disposal practices, institutional structure and legal framework are covered
and possible sources of problems are investigated. Suggestions were made on
legal framework related to management of hazardous wastes and harmonization
with EU directives. In Hazardous Waste Management Project, the hazardous
waste generation in Turkey was evaluated based on the total number of
employees working in hazardous waste generating industries adopting a method
from Germany.

MoEF’s approach for locating new hazardous waste facilities is towards
concerning with both cost and effectiveness of the system shaped as a result of
the “Technical Assistance for Environmental Heavy-Cost Investment Planning”
Project 7. According to “economy of scale” principle, building large scale and
regional hazardous waste processing and disposal facilities reduce disposal costs
(per ton). On the other hand, establishing fewer but large-scale plants increases
transportation distances and hence transportation costs. However, transportation
costs can be reduced by establishing interim storage network where hazardous
wastes originating from small sized companies will be stored safely until
reaching necessary amount for transportation by larger vehicles or railway.

In this EU project carried out by an international consortium in coordination with
MoEF, three scenarios were evaluated. First scenario includes establishment of a
number of large scale incineration and disposal facilities along with collection
network and transfer stations at the locations where industrial activity is high.
According to this scenario transfer stations should be able to perform basic
physical and chemical treatment processes in order to decrease the volume of




6 Management o Hazardous Wastes, Ministry of Environment and Forestry General Directorate of Waste
Management, Department of Waste Management, 2001, Ankara
7 Technical Assistance for Environmental Heavy-Cost Investment Planning, Turkey Directive-Specific
Investment Plan for Council Directive on Hazardous Waste (91/689/EEC), Ministry of Environment and
Forestry, 2005, Ankara

                                                                                               19
waste. The regions for which the hazardous waste incineration and disposal
facilities will serve are shown in Figure 3.1.




Figure 3.1 Hazardous waste management regions

Second scenario is similar to the first one however, in this one instead of low
number of large scale facilities to serve for regions, high number of smaller scale
facilities serving for smaller areas is considered. This scenario also includes the
network and transfer station but again in smaller number and scale. Third
scenario involves implementation of first or second scenario along with co-
incineration practices in cement kilns.

Among these three scenarios first one was chosen by technical working group
involved in the project, which will be referred as regional hazardous waste
management plan from now on. In the first phase, regional hazardous waste
management systems will be realized in highly industrialized regions;
   o Thrace Region
   o Eastern Marmara Region
   o Aegean Region
   o Central Anatolia Region
   o Mediterranean Region
Number and capacities of facilities planned to be constructed according to
regional planning may increase as a result of rate of industrialization. In addition
to that, it should be kept in mind that as the awareness of waste producers
increase; technological developments will be installed for waste minimization
purposes at the source. Construction, installation and operation of hazardous
waste disposal facilities require special technology and training. Moreover, these


                                                                                 20
facilities need to be inspected by Ministry of Environment and Forest thoroughly.
In this context, these facilities are obliged to use BAT (Best available Techniques)
specified in Reference documents on BAT (BREFs). These facilities are expected to
be constructed by private sector on “built-operate” basis.

In the second phase, interim storage facilities including physical-chemical
pretreatment units are planned to be installed at less industrialized regions. Also,
transfer network to integrated facilities will be developed.

There is already an incineration plant in Marmara Region, which is Đzaydaş
having 35.000 t/yr of waste incineration capacity. A capacity increase of 70.000
t/yr was foreseen for Đzaydaş. Other newly established facilities is planned to be
as given below:

      o Thrace Region: an incinerator (60.000 t/yr) and a landfill (90.000 t/yr) to be
          installed in 2013 – for the orange region shown in Figure 3.1.
      o Đzmir: an incinerator (40.000 + 30.000 t/yr) to be installed at 2015 and 2020
          in two phase and a landfill (120.000 t/yr) to be installed in 2014 – for the
          blue region shown in Figure 3.1.
      o Adana/Mersin: an incinerator (45.000 + 40.000 t/yr) to be installed at 2016
          and 2021 in two phase and a landfill (140.000 t/yr) to be installed in 2015 –
          for the purple region shown in Figure 3.1.

“Technical Assistance for Environmental Heavy-Cost Investment Planning”
Project was followed by two Twinning Projects namely Waste Management
Twinning Project, (TR/2003/EN/01)8 and Special Waste Twinning Project
(TR/2004/IB/EN/01) 9. In Waste Management Twinning Project, hazardous
waste management concept was developed aiming to determine mid-term and
long-term measures and ways to establish a sufficient hazardous waste
management structure all over Turkey. Emphasis was given to waste
minimization and recovery operations. Requirement for self-sufficiency of
disposal and recovery operations in terms of capacity was underlined. Moreover,
waste specific handling of hazardous wastes was covered under establishment of
dedicated waste recovery and disposal facilities towards handling of specific
wastes. In addition, branch-specific measures were listed management of wastes
originating from selected sectors.



8   Waste Management Twinning Project, (TR/2003/EN/01
9   Special Waste Twinning Project (TR/2004/IB/EN/01)

                                                                                    21
Measures for waste avoidance recommended by Waste Management Twinning
Project were listed as:

   o Cooperation between production plants and research institutions for
       development of new equipments
   o Construction of a network to spread the relevant technical information
       between good’s producers, chambers and associations, responsible
       environmental authorities as well as institutions
   o Promotion of public relations on hazardous waste management as well as
       education and training programs
   o Establishment of a special working unit (task force) subordinated the
       governmental level or subordinated the level of the environmental
       agencies which is responsible as an advisory board to give advices for
       suited measures to the private enterprises in terms of waste avoidance and
       waste recycling/recovery
Highlights for waste recovery and recycling are:

   o Supporting establishment of waste recycling exchange to manage and
       broke with valuable goods and secondary raw material
   o Promotion of recycling-friendly designs
   o Promotion of high-level and emission-free recovery by
          o Immediate reuse of waste, devices and parts out of waste for the
              further production without any treatment
          o Recycling of the immanent raw materials and material use of
              hazardous components out of waste immediately or after treatment
              as secondary raw material for the same or for other production
              purposes
          o Recycling of the immanent raw material and material use (for the
              same or for other production purposes) of all non-hazardous waste
              parts after separation, elimination and disposal of hazardous
              components and compartments



                                                                              22
o Recycling of the immanent raw materials of waste and material use
                 for other purposes than production
          o Energy recovery of hazardous waste in production plants
In order to realize abovementioned measures creation of a special tax /fee /levy
for waste generation and tax privileges given to the enterprises for investments in
waste minimized production processes are suggested.

In the light of outcomes of these projects and following the rules laid down by
legislative framework, current hazardous waste management system in Turkey is
shaped. However, in terms of practical aspects, hazardous waste management
system should be further studied and improved. Following this motivation LIFE
HAWAMAN            Project   on   Improvement   of    Industrial   Hazardous   Waste
Management in Turkey (LIFE06/TCY/TR/000292) was started. The project’s
objective is to improve the management of industrial hazardous waste in Turkey
and to tackle the increase in hazardous waste generation and environmental risks
that such waste may cause. In order to reach this goal, the following items were
worked out:

    1. Estimation of the amount of industrial hazardous waste in Turkey
    2. Allocation of hazardous waste to disposal routes according to the state of
       the art
    3. Recommendations concerning a hazardous waste management concept for
       Turkey



.




                                                                                  23
4   CURRENT  SITUATION                     OF       HAZARDOUS              WASTE
    MANAGEMENT IN TURKEY

Rising environmental awareness, legislative obligations, increasing costs because
of capacity constraints of waste disposal operations and increasing importance of
environmental protection measures especially in foreign trade lead to an increase
in implementation of pollution prevention technologies and waste minimization
activities.

In implementation of recycle/recovery and reuse activities the priority is given to
the wastes easy to collect, manage and require simpler technologies. Wastes of
packing materials such as IBC, barrels and other packing wastes is a good
example for easy to handle type of wastes as those wastes pose lower risk for the
environment. Another example can be recovery of silver, which is simple in terms
of technology to be used. Furthermore, waste exchange system implemented
within the scope of chamber of industries by Turkish Union of Chambers and
Commodity Exchanges supported by Ministry of Environment and Forestry
(MoEF). Waste exchange is an intermediary system aiming recovery and reuse of
production wastes from the industries to be used as a secondary raw material in
other industries. With the implementation of waste exchange, amount of wastes
to be ultimately disposed of is reduced. However, effective implementation and
operation of this system is predicted to take some time.

According to the data of November 2007, number of recycle plants with ad-hoc
working permit and license reached up to 89. Currently, 52 of those plants are
operating with the license. The classification of those plants according to
recycling methods indicated in Annex 2 of Turkish RCHW can be seen in Table
4.1. As can be seen, metals are recycled as priority in 33% of recycling plants.
Metals are of priority as installed capacity for recycling of metals consists half of
the overall recycling capacity in Turkey. Waste oils follow metals in terms of
number of plants (21%) and installed capacity (35%).

The distribution and amount of recovered materials can be seen in Table 4.2.




                                                                                  24
Table 4.1 Number of plants and recycle/recovery activities (June 2007)

         CODE OF                        NUMBER OF PLANTS                 TOTAL CAPACITY
     RECYCLE/RECOVERY                     WITH LICENSE                     (TON/YEAR)
R2 (Recovery of solvents)                              3                       9,350
R3 (Reclaim of organics other than
                                                       7                      17,477
solvents)
R4 (Reclaim of metals and metal
                                                      17                      113,442
compounds)
R5(Reclaim of inorganic materials)                    4                       1,955
R9 (Refinement of waste oils)                         11                      82,452
R11 (Use of wastes from R1-R10
                                                       3                      14,570
operations)
R12 (Change of one of R1-R11
                                                       7                      24,415
operations)
TOTAL                                                 52                      263,661


Table 4.2 Types of recyclable wastes admitted to licensed recycling facilities and their
capacities

                                 ANNUAL CONSUMPTION                      SHARE IN OVERALL
      WASTE TYPE
                                 CAPACITY (TONE/YEAR)                      CAPACITY (%)
Dye sludge                                    4,503                            1.01
Oily waste (wastes
                                              86,618                           19.48
including heavy metals)
Chemical wastes                               21,106                           4.75
Contaminated cloth and
                                              7,978                            1.80
cotton waste
Waste solvent                                 1,990                             0.44
Waste barrel                                656,400                              --
Battery accumulator                         192,439                            43.30
Industrial sludge                             7,360                             1.65
Waste tyres                                  51,979                            11.70
Waste oil (1st Category)                     33,762                            7.60
Waste oil (2nd Category)                     36,735                             8.27
TOTAL                              445,000 (+656,400 barrels)                   100



Recently, a pilot scale hazardous waste recovery plant with gasification has come
into operation in Istanbul Kemerburgaz with 29,000 tons/year capacity. The
facility was established by Ecological Energy Limited Company (Ekolojik Enerji
Ltd. Şti.). Energy recovery indicated in Annex 2 of RCHW is another method for
waste recovery. This type of recovery can be implemented in cement industry.
Wastes from cement industry are utilized as alternative fuels for energy recovery
                                                                                        25
in factories. Waste tyres, 1st and 2nd type of waste oils, dye sludge, solvents and
plastic wastes can be disposed in cement factories. Additionally, two cement
factories got permission for utilization of grit and domestic sludge as alternative
raw material. Currently, 22 cement plants have license in R1 category. In Table
4.3, amount of waste types used as fuel in licensed cement factories are given.

Table 4.3 Wastes used as alternative fuels in cement factories

                 WASTE TYPES               AMOUNT LICENSED (TONE/YEAR)
           1st and 2nd type Waste oils                      214,226
           Waste tyres                                      106,458
           Contaminated waste                                61,884
           Waste plastic                                     51,866
           Petroleum refinery waste                         24,120
           Petroleum bottom mud                              18,902
           Dye sludge                                        16,964
           Liquid fuel sludge                                 4,020
           Total                                            498,440



Currently, there are three landfills and three incinerators licensed by MoEF for
disposal of industrial wastes in Turkey. TÜPRAŞ has established a rotary kiln for
their own wastes while Erdemir and Đsken have build disposal facilities for their
own wastes. Information related to current waste disposal facilities is provided in
Table 4.4. Capacities given in Table 4.4 are the installed capacities and almost 80%
of the total capacity is utilized currently.

Following the regional waste management plan developed in “Technical
Assistance for Environmental Heavy-Cost Investment Planning” Project,
establishment of certain hazardous waste facilities are underway. List of these
facilities along with their location and capacities are given in Table 4.5.




                                                                                  26
Table 4.4 Waste incineration capacity of PETKĐM is 17.500 tones/year. Less than
half of the capacity (7500 tones/year) is utilized by PETKĐM, while the rest is for
other industries.

Following the regional waste management plan developed in “Technical
Assistance for Environmental Heavy-Cost Investment Planning” Project,
establishment of certain hazardous waste facilities are underway. List of these
facilities along with their location and capacities are given in Table 4.5.




Table 4.4 Current capacities of disposal facilities

                     COMPANY NAME                                       CAPACITY
                      ∗
ĐZAYDAS(storage)                                           790.000 m3 (occupancy ratio %20)
ĐZAYDAS (incineration)                                     35.000 tons/year
PETKĐM (incineration)                                      17.500 tons/year
TÜPRAŞ (incineration) (for the facilities own wastes)      7.750 tons/year
ERDEMĐR (storage) (for the facilities own wastes)          6.084 tons/year
ISKEN (storage)∗ (for the facilities own wastes)           115.000 m3



Table 4.5 Integrated Waste Disposal Facilities

                                                                               PRESENT
NAME OF THE PROJECT AND LOCATION                           CAPACITY
                                                                              SITUATION
Kiplasma Sanayi ve Ticaret A.Ş. – Integrated
Industrial Waste Disposal Facility
                                                      Incineration:
                                                                              EIA Phase
                                                      48.000 tons/yr
Gebze Organized Industry Zone
Kocaeli
Aegean Region Industrial Waste Disposal Landfilling:                          Landfill
                                                                              brought in line
Complex                                 3.230.000 m3
                                                                              on March 2009.
                                        Incineration:



∗
    Total capacity

                                                                                          27
Kırtıllı Tepe Mevkii Sandal Beldesi     20.000 tons/yr       Incinerator   in
Kula - Manisa                                                planning
                                                             stage.
ITC Invest Trading & Consulting AG – Gasification:
                                                           Feasibility
Integrated Waste Disposal Facility   20-30 thousand ton/yr
                                                           study
Çadırtepe Mevkii                     (100 thousand ton/yr
                                                           completed
Sincan - Ankara                      with expansion)
Türkiye Metal Sanayiciler Sendikası                        Planning
Bursa                                                      phase




                                                                           28
5     HAZARDOUS WASTE MANAGEMENT CONCEPT

5.1    HAZARDOUS WASTE QUANTITY ESTIMATION

The Twinning project "TR03/EN/IB-01 Waste" activities on hazardous waste
regarded the lack of reliable data as one obstacle to base any kind of concept on.
Due to this the estimation of quantities and types of waste for certain industrial
activities was a basic task of the HAWAMAN-Project to base the hazardous
waste management concept on. This section gives the outline of hazardous waste
generation estimation methodology and its basic findings.

The realistic estimation of kind, amount and geographic origin of the currently
produced hazardous waste is the most important basis for the introduction of a
waste management system that includes the implementation of waste
transportation, interim storage and treatment facilities and the optimal
organization of waste transportation – where appropriate via interim storage
facilities - to treatment facilities. A too imprecise evaluation of the amount of
waste could either lead to expensive bad investments in oversized waste
treatment plants or to insufficient capacities for a proper and environmental
sound waste treatment.

The following work steps for the estimation of quantities and types of waste were
planned:
      o Definition of industry sectors generating hazardous waste
      o Compilation of basic data for estimation of hazardous waste amounts
            o Population per province
            o GNP per province
            o Industry structure with list of enterprises with employees, sector
               and province
            o Number of motor vehicles etc.
      o Estimation of amount of hazardous industrial waste for selected industry
         sectors based on international experiences and the above mentioned basic
         data from Turkey
      o Report on the methodology, used experiences/data, results and
         compilation/development of maps
The estimation is using a heuristic method based on long year international
experiences. It does not include any prognosis for future hazardous waste


                                                                               29
quantities and qualities, which will change due economic development or
structural changes in industry etc. Moreover, it does not cover all waste streams.

The hazardous waste generation estimation outlined in this section with its data
amount per type of waste per province gives the basis for the following project
tasks on waste logistics and waste management treatment concept.

5.1.1 Methodology

There are several methods in order to estimate the types, amounts and regional
distribution of the hazardous waste in a country in which exists no working
hazardous waste management system so far.

Data from waste generators

a) Direct information from waste generators: This approach will lead to no
reliable data with very high aberration from real situation, because waste types
and waste amounts often are unknown, especially in countries with no hazardous
waste management system; participation << 100 %; this method is labor and time
intensive. Even in countries with long-time existing hazardous waste
management system the data given by the companies are not very reliable; they
just can give a qualitative, but not quantitative statement, if the waste amounts
will in- or decrease.

b) Material balances from companies: Input/output balances from companies or
processes are not existing normally, this method is not practicable and very labor
and time intensive.

c) Internal notification / waste declaration forms: Because waste types and waste
amounts often are unknown in the companies at present, the waste types and
amounts given in the Internal Notification often are wrong resp. consciously
bigger or smaller than in reality. Even with a long-time existing hazardous waste
management system Internal Notification will not give reliable data.

Data from waste transportation

Because a hazardous waste management system is not covering the whole
country the current situation needs to be improved, only partial data about waste
transportation exist. An extrapolation of this data is not possible, because only a
part of the waste types are transported to treatment facilities, for the other part no
treatment facilities exist.


                                                                                   30
But even with a long time existing hazardous waste management system the
Waste Transportation Forms will not give 100% reliable data: There is always a
gap between the waste mounts from waste generators to waste transportation
service and from waste transportation service to waste facilities. Possible reasons
for the situation are thought as mistakes in m³ to ton conversion, partly filled
transportation units and loss of some part of water evaporation of water.

Data based on material and product amounts

Material input and product output data and the associated waste ratios are not
available for all industrial sectors, so only a part of the waste amounts can be
estimated by this approach.

Even if these data were known; the following points will remain as possible
problems:

    o    the material efficiency = waste ratios can differ by magnitudes
    o    statistical problems can falsify the data:
            o       production of product in one or more companies (Figure 5.1)?
            o       waste per produced item, e.g. vehicle: truck or compact car?
            o       complete production at facility or import of parts?


            Production in 1 facility                 Production in 3 facilities


                                                            input               output




            input                           output          input               output




                                                            input               output

                              1       Material/Product   3
                              1       Employees/Sales 3*1/3=1
Figure 5.1 Production in 1 or 3 facilities: material balance differs by factor three




Data based on inhabitants/employees and GNP/sales per region

                                                                                         31
This method gives a rough estimation about hazardous waste generation in a
country or in a region. Large amount of such data is available from many
different countries with long-time existing hazardous waste management
systems. This is a very cheap and simple method. Problem of this approach is that
some of the industrial sectors are waste intensive, others not. Without
considering the employees per sector, the aberration from the real data may be
high. For instance, the main industry in Turkey are the textile and food industry
(with only small amounts of hazardous waste) plus metal industry; in Germany
are the metal and chemical sector, which are very waste relevant, are the two
main industrial sectors.

Data based on employees/sales per sector and region

Data based on employees/sales per industrial sector and per region gives a good
estimation about waste situation per region, not very labor and time intensive,
but the waste ratios are not available in studies/literature up to now and have to
be developed with experience from a lot of waste management projects in a lot of
countries knowing the situation in the waste generating industries.


The development of waste amounts in regions without a long time existing
hazardous waste management system depends on:

    o the presence of waste facilities
    o the possibility of waste recycling
    o the costs for waste treatment (disposal and recycling)
    o the authorities (surveillance, penalties)
    o the laws and regulations, judgement
    o the limits for gas emissions (filter dust and sludges from flue gas cleaning)
        and sewage (waste water sludges) and their implementation
    o achievements in waste minimisation / material efficiency
    o development of industry
However, the „Delinking“ between GNP/employees and waste amounts should
be considered in a way that a higher production will not lead to similar higher
waste amounts. Therefore, every hazardous waste management system has to be
built up in a manner, that it can react flexible on changes in waste types and
amounts.



                                                                                32
While comparing waste factors from other countries following items should be
kept in mind:
   o big waste ratios are mainly caused by mineral wastes (e.g. Luxemburg >
       50% contaminated soils!)
   o hazardous waste, which is recycled, sometimes is included and sometimes
       excluded
   o sometimes hazardous waste, which is treated by the waste generator, is
       in/excluded
   o some regional waste balances are worked out by consultants, who are
       interested in big waste amounts, so there is more work for planning more
       and bigger treatment facilities
   o waste factors for countries with no (long time) existing hazardous waste
       management system are often copied one by one without being proofed
       and are based on inhabitants/employee and GNP/sales.
As a conclusion; waste balances based on
   o regional data (employees/GNP per province) and
   o employees or sales per industrial sector
will give as a kind of best available technique not exceeding cost (BATNEC)-
method the best estimation for a hazardous waste investment planning. It is
based on long time and multi-region experience.

Following the discussion presented above; for the HAWAMAN-Project a method
should be used that gives a waste quantities estimation with low effort that is
sufficiently accurate to plan kinds, capacities and locations of waste treatment
facilities. Heuristic method used for HAWAMAN Project is based upon waste
ratios per employee and sector.

For this purpose the industrial sectors were merged to 21 sector groups whose
companies have a similar spectrum of waste types. For each of those 21 sector
groups a waste sector sheet was created that contains the typical waste types of
this sector group and their waste ratios per employee.

The waste ratios used in the waste sector sheets have not yet been published.
They mainly base on data from countries with long-time existing hazardous
waste management systems. The result of calculations gives an estimation of the
waste situation in Turkey how it would be if there were already waste
surveillance institutions and waste treatment facilities existing for several years.

                                                                                   33
This result with the distribution of the amounts of the different types of
hazardous waste is exactly the result that is required in order to plan kinds,
capacities and locations of the needed waste treatment facilities. This approach
covers some of the factors of influence on the waste amounts listed previously. It
is obvious, that in the years of the launch phase of a hazardous waste
management system significant fluctuations and variations from the estimated
values will occur.

Waste ratios were developed based upon our long-year experiences in various
institutions and countries and also from consideration of studies and balances
like
   o numerous waste inventories of EU-countries and regions
   o data from world-bank and other institutions
   o BREF-documents (Sevilla process)
Due to this information and experience it is possible to create waste sector sheets
and to calculate the amount of waste per industrial sector and per province with
the waste sector sheets and the basic data (employees per sector and province).
By summating these results the waste amounts for Turkey can be calculated.

This heuristic method has already been utilized successfully in other countries
and verified with data from regions with long-time existing hazardous waste
management systems. The accuracy of the approach is estimated as the final
result to plus/minus 25%. This is sufficiently exact in order to base a hazardous
waste management system on. It is believed that this uncertainty will be
incorporated into design of hazardous waste management system since the
system itself should be flexible in order to cover deviations due to unpredictable
developments.

It should be noted that on analysing and discussing the data it has to be
considered that this method is a statistic approach that is only able to achieve
realistic results for a great number of companies. The smaller the number of the
regarded companies is, the greater the differences from reality can be. This
applies for example to the consideration on the level of provinces with few
employees or even single or few companies per group.

The waste situation in single companies can deviate significantly from the used
statistic waste ratios. Thus it can be reasonable to analyse the waste situation of
individual exceptionally waste relevant companies respectively of companies


                                                                                34
with very big amounts of hazardous waste and to integrate these values in results
obtained from current approach. It's essential to make sure that these additional
data are real data, that means data from wastes, which are occurring and are
treated in reality, and not estimated data.

5.1.2   Waste estimation

According to the assignment only certain sources and types of waste were to be
considered at our waste quantity estimation. The focus is on the hazardous waste
produced in the industry. List of considered and disregarded waste producers
and waste types are given in Table 5.1. Disregarded waste producers are the ones
either covered by special directives or the ones that produce “mirror” type
hazardous wastes.

Table 5.1 Covered and omitted waste types and producers

                COVERED
                                                              OMITTED
         (TOBB-Codes 3000 to 4101)
Food, beverage and tobacco                    Mining
Textile and leather                           Construction
Wood products and furniture                   Contaminated soils / sites
Paper production and paper products           End-of-live-vehicles
Printing                                      Service sector like hotels, commerce and
Chemistry, chemical products                     offices (partly included in sep. collected
Petroleum refineries                             fractions)
Rubber and plastic products                   Logistics/Transportation (but car repair
Mineral products (e.g. cement, glass)            service as a.m.)
Metal production                              Health care
Metal working                                 PCBs and PCTs
Electrical machines and equipment             Waste electrical and electronic equipment
Electricity                                   Public services (e.g. sewage sludge or
and in addition:                                 wastes from waste management
    o Separately collected fractions             facilities, but power-plants)
    o Car repair service
    o Agriculture


That means the wastes and waste groups
   o EWC 01 Mining
   o EWC 17 Construction / Demolition
   o EWC 18 Health Care
   o EWC 19 Waste + Waste Water Treatment
   o EWC 160104 End-of-live-vehicles


                                                                                        35
o EWC 200123/135 Electrical Equipment
are excluded in our waste quantity estimation.

In order to estimate the waste quantities per province on the basis of statistic
ratios certain basic data from a as current as possible year are needed:
       o For the waste quantity estimation from the considered TOBB industrial
            sectors the number of employees per industrial sector per province is
            required as basic data.
       o For the waste quantity estimation of the separately collected fractions the
            capita per province are required as basic data.
       o For the waste quantity estimation of the car repair services the quantity of
            vehicles per province is required as basic data.
       o For the waste quantity estimation of the agricultural sector the agricultural
            employees per province are required as basic data.
       o For a comparison with general waste ratios on basis of the GNP
            information about the GNP of Turkey is required.
Basic data for employee number was received from TOBB industrial sectors from
TOBB via the Turkish MoEF. The data have been surveyed in 2007 and thus are
very up-to-date. The TOBB database contains information of about approximately
66,000 companies, 38,000 of which have 10 or more employees. 35,800 of those
companies are among the industrial sectors covered in this study and contain
altogether 2.17 million employees. The other basic data like capita, vehicles,
agricultural employees and GNP are taken from current publications of TurkStat
10.   They were surveyed in years 2004 and 2005. As the basic data was obtained
following procedure was followed:

Step one: Deletion of all data sets with companies that come from other TOBB-
sectors than No. 3000-4101.

Step two: Deletion of all data sets with companies with less than 10 employees.

Step three: Approximately 13,000 companies had assignments to more than one
TOBB-code. Their employees were prorated on the different sectors.

Step four: Addition of the numbers of employees per province of those TOBB-
codes that are assigned to a waste sector sheet for every waste sector sheet.



10   Turkish Statistical Institute (TurkStat), statistics available from www.turkstat.gov.tr .

                                                                                                 36
Step five: Creation of Table A. 3 given in Appendix.

The basic data for capita, vehicles, agricultural employees and GNP per province
were available at TurkStat in the required form. They were summarized in Table
A. 4 in Appendix.

Waste sector sheets

As mentioned before 21 industrial sector groups, whose allocated companies each
have a similar waste situation and differ relevantly from other groups, were
selected (Table 5.2). For these sectors waste sector sheets were generated.

The sector 39 “not otherwise specified products” is split to plastics, metalworking
and wood.

These 21 sector groups were supplemented by the following three non-industrial
groups:
   o Agriculture
   o Separately collected fractions
   o Car repair services

For each of these sector groups, a list of hazardous waste that can occur in this
sector group has been created according to European Waste Catalogue (EWC).
Because it's not always possible to give the waste ratios in every sector for each
single waste type, some waste types were partly united to groups with similar
waste composition: acids, waste oil, halogenated solvents, non-halogenated
solvents etc.

The waste sector sheets contain from a few to over 30 different waste types and
waste type groups depending on the waste situation of this sector group. The
waste sector sheets cover 200 hazardous waste types of the EWC. The other
missing about 200 hazardous waste types originate from the disregarded sectors
like mining, construction/demolition, health care and waste water/waste
treatment or are related to waste types that only occur in a few companies or just
in small amounts.

For each of these waste types and for each sector group specific waste amounts in
tons per 1.000 employees and year are given. Depending on the stage of
development of the industry and the foci within a sector group the ratios of the
situation in the country were adjusted specifically. Thereto data for the Turkish


                                                                                37
economy as given in Introduction section of this report were considered. In Table
5.3, a sample waste sector sheet is presented for metal working industry.

Table 5.2 List of industrial sector groups

                 WASTE SECTOR SHEET                      TOBB-CODES
            Batteries production                 383902
            Cement                               3692
            Inorganic chemistry                  351112-351131
            Fertilizer manufacture               3512
            Organic chemistry.                   351101-11, 351140-50, 3513
            Other chemical industries            351155, 3522-3529
            Paint Industry                       3521
            Electrical equipment + machines      383 except 383902
            Energy (power plants)                4101
            Food-beverage-tobacco                31
            Leather                              322-324
            Metal production (Iron and steel)    371
            Metal production (Others)            372
            Metal working                        381, 382, 384,385
            Mineral production (e.g. cement,
                                                 36 except 3692
            glass)
            Paper production and products        341
            Petrol refineries                    354
            Plastics and rubber                  355, 356
            Printing                             342
            Textile                              321
            Wood and furniture                   33


Table 5.3 Sample waste sector sheet for metal working industry

                    SHAPING AND PHYSICAL AND MECHANICAL
   SECTOR:                                                                    "METWORK"
                    SURFACE TREATMENT OF METALS
                                                                                 t per
   EWC              Waste type
                                                                              1.000 empl.
   ...
                    waste paint and paint sludges containing organic
   080111and13                                                                    10
                    solvents or other dangerous substances
   ...
   110105to07       pickling acids and basis and other acids                      30
   110108           phosphatising sludges                                         10
   ...
   120107and10      machining oils free of halogens                               40
   120109           machining emulsions and solutions free of halogens
                                                                                 150
   ...



                                                                                        38
fluorescent tubes and other mercury-containing
  200121                                                                 0,2
                 waste
  ...



A single waste sector sheet only gives the statistically averaged data for this
sector. The waste situation in single companies can differ significantly. Thus a
waste sector sheet is not at all suitable to compare the included data with the
waste types and amounts of single companies. For example in metal working
some companies conduct galvanization while others don't (no 1101xx-wastes),
some apply lacquering whereas some don't (no 0801-wastes).

Results

By entering the number of employees per sector and province into a waste sector
sheet one receives the amount of waste that is produced in a sector and a
province. By adding all waste sector sheets together the amount of waste in a
province is received, and by adding these values from all provinces together
amount of waste for Turkey is received. Because some of the 100 wastes and
waste groups that are included in the waste sector sheets partly overlap, 28 waste
groups were formed for displaying the result.

Total hazardous waste generation under covered industrial and non-industrial
sources turned out to be 1.35 million tons/yr. This amount of hazardous waste
comes from the Turkish Industry – but it is only a part of the total hazardous
waste amount in Turkey.

        Hazardous waste generation from industrial sectors

Distribution of hazardous waste generation in general economic sectors are
   o Metal industry:             548,800 tons/yr
   o Chemical industry:          396,900 tons/yr
   o Other industrial sectors:   151,300 tons/yr
   o Non-industrial groups:      253,400 tons/yr
These figures indicate that wastes from the industrial sectors add up to 1,1
million tons. In Appendix, from Table A. 5 to Table A. 8 more detailed
information on distribution hazardous wastes among main sectors, industrial
branches and provinces can be found.

        Hazardous waste generation according to waste types

                                                                               39
As mentioned before, 28 waste groups were identified for reporting purposes.
Table 5.4 lists the amount of hazardous waste generation according to these waste
groups. In Appendix, Table A. 9 gives information distribution of waste types to
provinces in more detail.




                                                                              40
Table 5.4 Description and amount of hazardous waste groups in tons/yr

  ID                                                      SUBSUMES EWC
                            GROUPS                                               AMOUNT
NUMBER                                                          CODES
   1        Pesticides and agrochemical waste          020108, 200119                5,926
                                                       030201, 030202, 030303,
    2       Wood preservatives                                                       1,780
                                                       030204
                                                       040103, 040214, 040216,
    3       Hazardous waste from tanneries                                          31,739
                                                       040219
                                                       050102, 050103, 050104,
    4       Hazardous waste from petroleum refining    050105, 050106, 050107,      65,631
                                                       050108, 050109, 050115
                                                       060101, 060102, 060103,
                                                       060104, 060105, 060106,
    5       Acidic and alkaline hazardous wastes                                    62,477
                                                       060201, 060203, 060204,
                                                       060205, 200114, 200115
                                                       060404, 060405, 060502,
    6       Hazardous waste from inorganic processes                                48,646
                                                       061002
                                                       070101, 070103, 070104,
                                                       070107, 070108, 070109,
                                                       070110, 070111, 070201,
                                                       070203, 070204, 070207,
                                                       070208, 070209, 070210,
                                                       070211, 070301, 070303,
                                                       070304, 070307, 070308,
                                                       070309, 070310, 070311,
                                                       070401, 070403, 070404,
                                                       070407, 070408, 070409,
    7       Hazardous waste from organic processes                                 212,870
                                                       070410, 070411, 070501,
                                                       070503, 070504, 070507,
                                                       070508, 070509, 070510,
                                                       070511, 070601, 070603,
                                                       070604, 070607, 070608,
                                                       070609, 070610, 070611,
                                                       070701, 070703, 070704,
                                                       070707, 070708, 070709,
                                                       070710, 070711, 160506,
                                                       200129, 200131
                                                       080111, 080113, 080115,
                                                       080117, 080119, 080121,
            Hazardous waste from paint and sealant
    8                                                  080312, 080314, 080409,      54,719
            production
                                                       080411, 080413, 080415,
                                                       200127
                                                       090101, 090102, 090103,
    9       Hazardous waste from printing processes    090104, 090105, 090106,       4,908
                                                       200117
                                                       100104, 100109, 100114,
   10       Hazardous waste from energy production     100116, 100118, 100120,      32,531
                                                       100122




                                                                                       41
Table 5.4 Continued

  ID                                                        SUBSUMES EWC
                              GROUPS                                               AMOUNT
NUMBER                                                            CODES
                                                         100207, 100211, 100213,
                                                         100304, 100308, 100309,
                                                         100319, 100321, 100323,
                                                         100325, 100329, 100401,
                                                         100402, 100403, 100404,
                                                         100405, 100406, 100407,
   11      Hazardous waste from metal production                                     114,586
                                                         100503, 100505, 100506,
                                                         100603, 100606, 100607,
                                                         100808, 100815, 100817,
                                                         100905, 100907, 100909,
                                                         100911, 101005, 101007,
                                                         101009, 101011
                                                         101109, 101111, 101113,
           Hazardous waste from mineral and glass        101115, 101117, 101119,
   12                                                                                 18,983
           production                                    101209, 101211, 101309,
                                                         101312
                                                         110105, 110106, 110107,
           Hazardous     waste      from   galvanizing   110108, 110109, 110115,
   13                                                                                 44,763
           processes                                     110116, 110198, 110202,
                                                         110205, 110301
                                                         120107, 120109, 120110,
   14      Non-halogenated waste oils                    130205, 130206, 130307,     208,344
                                                         130208
   15      Halogenated waste oils                        120106, 120108, 130204        2,466
                                                         120109, 130502, 130503,
   16      Waste oil emulsions                                                        80,075
                                                         130802
                                                         120112, 120114, 120301,
   17      Other oily waste                                                           53,266
                                                         120302, 130501, 200126
   18      Halogenated solvents                          140601, 140602, 140604       12,228
   19      Non-halogenated solvents                      140601, 140605               36,059
   20      Contaminated packaging’s                      150110                       48,235
   21      Spent adsorbents and filtering material       150202                       32,859
   22      Spent oil filters                             160107                        2,507
   23      Spent brake fluids and antifreeze             160113, 160114                3,971
   24      Spent batteries                               160601, 160606, 210133       47,613
   25      Spent catalysts                               160802                          180
   26      Sludges from CPT of wastes                    190813                       99,433
   27      Mercury contaminated waste                    200121                        2,398
   28      Contaminated wood                             200137                       21,176




                                                                                         42
Geographic distribution of hazardous wastes

Table 5.5 below, summarizes the geographic distribution hazardous wastes in
terms of regions. According to this table, Đstanbul itself generates highest amount
of hazardous wastes. Figure 5.2 gives a survey of the overall hazardous waste
situation in Turkey. It shows the waste generation centres and the waste amount,
aggregated on the 81 provinces of Turkey. The map shows three main gravity
centres of hazardous waste generation – all located in the western part of Turkey:
   o Đstanbul
   o Kocaeli
   o Izmir,
followed by Bursa and Ankara.
Table 5.5 Geographic distribution of hazardous wastes (1000 tons/yr)

                             NUTS1-REGION            AMOUNT
                                  TR1                  314.2
                                  TR2                   83.6
                                  TR3                  207.2
                                  TR4                  303.6
                                  TR5                  125.4
                                  TR6                  123.0
                                  TR7                   54.2
                                  TR8                   73.5
                                  TR9                   13.9
                                 TRA                     6.7
                                 TRB                    11.6
                                 TRC                    33.5
                                 Total                 1,350



As expected, Figure 5.2 shows a distinct west-east divide of hazardous waste
generation in Turkey, with white spots in the eastern regions. Since the waste
generation factors used are based on employee numbers, these findings
correspond with the employee map (Figure 1.6), which looks similar to the
hazardous waste map (Figure 5.2).




                                                                                43
Figure 5.2 Hazardous waste generation in Turkey, total

The next two maps give some rough information about the two origins of
hazardous waste generation in Turkey that are industrial sources (Figure 5.3) and
non-industrial sources (Figure 5.4).




Figure 5.3 Hazardous Waste Generation in Industry (81 %)

                                                                              44
Figure 5.4 Hazardous Waste Generation from separately collected waste (19 %)

With its more than 80% share, it is obvious that the major amount of hazardous
waste arises from Industry (Figures 5.3 and 5.4). Generation centres for industrial
and non-industrial hazardous wastes does not show any difference.

As mentioned in above discussions, metal industry represents the major part of
hazardous waste generation in Turkey. Centres of hazardous waste generation in
the metal industry are mainly situated in Đstanbul, Kocaeli and Bursa, followed
by Izmir, Manisa, Eskisehir, Ankara, Konya, Kayseri, Adana and Hatay. These
regions also stand for automotive industry and metal works. The west-east divide
is obvious. Nearly no hazardous waste of that kind is generated in Eastern
Turkey.

Figure A. 2 to Figure A. 28 display geographical distribution of hazardous waste
groups on maps. Moreover, Table A. 5 contains numerical information on
provincial distribution of total hazardous wastes. Following tables in Appendix
contains provincial information as well.




                                                                                45
5.1.3      Comparison and validation of results

Comparison with Germany

In 2006, 150 million tons of waste was generated in Germany. Of this amount 18.7
million was hazardous. 3.9 million was treated in company and 14.7 million ton
was treated in treatment plants. When wastes from
      o EWC 01 Mining
      o EWC 17 Construction / Demolition (6 Million tons)
      o EWC 18 Health Care
      o EWC 19 Waste + Waste Water Treatment (3 Million tons)
      o EWC 160104 End-of-live-vehicles
       o EWC 200123/135 Electrical Equipment
were excluded from this total amount generated from industry, car repair and
separately collected fractions disposed or recovered in treatment plants was 5.3
million tons of hazardous waste.

Comparison of hazardous waste generation will be based on GNP. To compare
the Turkish with the German industrial hazardous waste situation by GNP, the
industrial fractions of the GNP have to be compared, and because of the different
purchasing power in Turkey and Germany, this values have to be adjusted by
power parity. Table 5.6 gives the values obtained for comparison. It can be
concluded that results obtained as 1.35 million tons/yr fits very good to the value
referring to industrial employees. 1.35 million tons/yr also fits very good to the
value referring to the industrial GNP adjusted by power parity

Table 5.6 Comparison of Turkish and German hazardous waste generation

                                                             HAZARDOUS WASTE
                                 GERMANY TURKEY               EXTRAPOLATED
                                                              (MILLION TONS)
Capita (Million)                       82             74            4.7
GNP (Billion US$) of
                                     3,200            593               1.0
industry
    of industry                       960             142               0.8
GNP “power parity”                   2,780            870               1.7
    of industry                       834             208               1.3
Employee numbers in
                                       ≈9             2.17              1.3
industry ∗


∗
    Includes companies with more than 10 employees.

                                                                                46
There are some factors of influence, which may diminish or increase these values:

   1. In Germany the key sectors are the waste relevant sectors metal and
      chemistry, in Turkey besides metal industry the non-waste relevant sectors
      textile/leather and food.
   2. In Turkey productivity per employee is lower than in Germany.
   3. In Germany the "dirty", waste relevant production declines, assembling
      prefabricated parts produced abroad increases. In Turkey the "dirty",
      waste relevant production increases.
Items 1 and 2 have a reducing affect whereas item 3 an increasing effect on the
waste amounts of Turkey.

Comparison with other countries

Figure 5.5 shows the hazardous waste amounts of several countries. The data of
the European countries originate from EU-statistics (pink dots) from the years
around 2000, the data of the other countries from studies (estimated data, blue
dots). The dots with waste amounts lower than 400.000 tons/yr, which are not
named, are related to the countries Botswana, Colombia (Region Bogota), Cyprus,
Denmark, Finland, Iceland, Ireland, Luxembourg, Norway and Tunisia.

For Turkey we entered the GNP-value “power parity“ from 2006 on the trendline
(big red dot). For Turkey would result a value of about 2 million tons for all
hazardous wastes.

It is important that in this case the data covers all kinds of hazardous waste, and
not only the ones of the industry, that is that this in this way determined value
can't be compared to ours. The values of some countries deviate by the factor 2
from the trendline. In some countries and years great site remediation projects
have caused more than 50% of the amount of hazardous waste.




                                                                                47
hazardous waste amounts
                                 3.500


                                 3.000
  hazardous wastes [1.000 t/a]




                                                                                                               Italy

                                 2.500

                                                                                                                UK
                                 2.000
                                                                                            Turkey

                                 1.500
                                                      Portugal
                                                                   Taiwan

                                 1.000                                 Netherlands
                                                       Belgium
                                             Norway
                                                         Austria
                                  500                 Greece



                                    0
                                         0       200               400         600   800     1.000     1.200   1.400
                                                                      GNP "power parity" [Bill. US$]

Figure 5.5 Hazardous waste amounts in several countries versus GNP “power parity”




                                                                                                                       48
5.2     ASSIGMENT OF HAZARDOUS WASTE TYPES TO DISPOSAL OPTIONS

Next step on the concept development is classification and allocation of the
hazardous waste to distinct disposal routes in order to estimate capacity
requirement for disposal alternatives. A suitable national hazardous waste
management system requires reasonable design data, in particular appropriate
prognoses on;

o the future amounts and types of hazardous waste produced in the period of
      commissioning the waste treatment and disposal facilities to be set-up, on;
o the types and capacities of the treatment and disposal facilities needed to
      eliminate the future hazardous waste amounts and on;
o the regional distribution of the amounts and types of hazardous waste
      produced in the country in order to identify suitable areas for erection of the
      necessary central or decentralized treatment and disposal facilities.
In Section 5.1, hazardous waste generation amounts were estimated for the year
2007. This estimation does not include any prognosis for future hazardous waste
quantities and qualities, which will change due economic development or
structural changes in industry etc. This point was also underlined as the
approach used for estimation was introduced. However, for the year 2007,
regional distribution was obtained for types of wastes and economic sectors,
which lead to hazardous waste generation.

This section involves information on methodology of hazardous waste allocation
between possible disposal alternatives as well as the results obtained.

5.2.1    Methodology

The methodology of allocation for the HAWAMAN Project is based on an
assignment of the relevant hazardous waste types (according to European Waste
List - EWL) to principally suitable treatment, recovery and disposal options. The
EWL exhibits 405 types of hazardous waste of which 232 are “absolute”
hazardous waste types and 173 “mirror” waste types which can be either
hazardous or not, depending on whether it contains dangerous substances at or
above certain levels.

Assignment to suitable treatment, recovery and disposal options in this context
means suitable according to prior experience of project team on hazardous waste
management practices in EU and information specific to Turkey in terms of

                                                                                    49
disposal alternatives; for instance probably no underground hazardous waste
repository. During application this methodology was adjusted to the recent waste
disposal praxis according to the DESTATIS 2006 evaluation of Federal Statistical
Office of Germany.

In order to clearly arrange the assignment list and to facilitate the application for
the prognoses the total number of hazardous waste types according to the EWL
was reduced by considering hazardous waste only from
   o manufacturing industries and post consumer waste from
   o car repair services and
   o households and micro enterprises.
Thus the assignment list does not consider waste from
         o exploration and mining,
         o construction and demolition,
         o health care,
         o waste and waste water treatment,
         o end-of-live-vehicles and
         o electric and electronic equipment.
Furthermore, “exotic” waste types have been omitted which are considered not to
be relevant concerning amounts (about “pro-mille” range).

As result, the assignment list exhibits 87 individual types of waste and 17 groups
of waste types according to the “waste sector data sheets” prepared for defining
relevant industry sectors, grouping of waste and disposal areas. Each group
comprise two or more waste types (from one generic source), which are assigned
by same fractions to the same treatment/disposal options. (Table A. 10 to Table
A. 12)

Assignment to treatment, recovery and disposal options

The annexed Table A. 13 exhibits in Column 1 and 2, the codes and the
denomination according to the EWL of the 87 individual hazardous waste types
as well as of the hazardous waste types compiled in the 17 waste groups.




                                                                                  50
The right hand columns provide the fractions of each waste type and of each
waste group assigned to the 6 options of treatment, recovery and disposal that
are;
   o material recovery
   o thermal recovery
   o physicochemical treatment
   o incineration
   o direct landfill
   o solidification for landfilling

As emphasized in Legislative Framework section the fundamentals of hazardous
waste management in Turkish RCHW is built upon waste hierarchy policy as
does their EU counterparts. Priority is given to waste minimization, which is
followed by recycling/recovery option. Going down the hierarchy, thermal
recovery and treatment are applicable if all other alternatives are unsuitable. The
least desired option turns out to be landfilling. Following discussion introduces
the six destination technologies considered for concept development ordered
according to waste hierarchy policy. Moreover, prices for disposal options are
given in Appendix (Table A. 10 to Table A. 13) for the information of reader.



Material recovery is for waste, which is suited for reuse or valorisation and
generally meets the acceptance criteria of alternative raw materials for primary
raw material substitution in commonly available industrial processes in
industrialized countries, e. g.
   o in used oil regeneration processes
   o solvent distillation processes
   o in cement industry for substituting clinker reaction raw material
   o for melting processes in metallurgical industry.
Thermal recovery is for calorific waste which is suited for heat recovery and
generally meets the acceptance criteria for primary fuel substitution in commonly
available industrial thermal processes in industrialised countries, e. g. as
alternative fuel in cement, chalk stone and brick industry. There is no typical
allocation     criteria    reported   in     the    Literature     for    material
recovery/recycling/thermal recovery

                                                                                51
Examples of waste types suitable for recycling and material/thermal recovery
are:
   o spent oil emulsions
   o aqueous solutions with dissolved organic or inorganic hazardous
       substances (acids, alkalines, heavy metals, cyanide, chromate, nitrite,
       fluoride, sulphide)
   o industrial process water with AOX-causing compounds
   o industrial process water with persistent TOC-causing compounds
   o landfill leachates
   o sludges, thin muds and aqueous solutions with suspended hazardous
       solids

Chemical-physical treatment (CPT) is suited for
   o waste sludge, which does not meet the EC acceptance criteria of above
       ground landfills without dewatering and physicochemical detoxification
   o aqueous waste, which does not meet the acceptance criteria of municipal
       or industrial waste water treatment stations without physicochemical
       detoxification
   o oil/water mixtures and emulsions, which oil content < ~10 % and which
       does not require thermal treatment for separation.
Typical physicochemical process reactions are
   o mechanical separation of solids, oily and aqueous phases by settling and
       decantation,
   o neutralisation of acids and alkalis
   o precipitation of sulphates and fluorides
   o oxidation of cyanides and nitrites, reduction of chromates and
   o dewatering of precipitates and sludge.

Allocation criterion:

                             Water content:     > 50 %

Examples of waste types suitable for CPT are:
   o spent oil emulsions




                                                                                52
o aqueous solutions with dissolved organic or inorganic hazardous
       substances (acids, alkalines, heavy metals, cyanide, chromate, nitrite,
       fluoride, sulphide)
   o industrial process water with AOX-causing compounds
   o industrial process water with persistent TOC-causing compounds
   o landfill leachates
   o sludges, thin muds and aqueous solutions with suspended hazardous
       solids

Incineration is required for waste, which does not meet the acceptance criteria
for the above disposal option, and generally for waste with organic content above
8–10 %.

Allocation criteria:

                             Water content:        < 50 %
                             Ignition loss:    no limit

Examples of waste suitable for incineration are:
   o oily and tarry stuff
   o spent solvents, laquers, paint, varnish, ink
   o organic residues from chemical processes
   o contaminated packaging materials of all kinds
   o soils, contaminated with organic compounds
   o demolition material, contaminated with organic compounds
   o carbonaceous material and spent organic adsorbents
   o expired goods (chemicals, pharmaceuticals, pesticides, food)
   o impregnated wood

Solidification for landfilling is required for waste, which meets the EC above
ground landfill acceptance criteria except the criteria for mechanical stability.
Solidification is a stabilisation of the waste performed by mixing with cement,
lime, fly ash from coal-fired power plants or other suitable waste material before
landfilling. In countries like Turkey, where an underground repository for
hazardous waste is not available or will not be an economical feasible disposal
option, solidification may be a disposal option for waste also, which meets the EC
above ground landfill acceptance criteria except the criteria for leachability of

                                                                               53
hazardous components. However, solidification does not prevent from long term
leaching of hazardous components. Solidified waste with leachable hazardous
components, therefore, should be prevented from water access by an additional
containment (e. g. reinforced big bag and/or bentonite layer) and disposed of
separately from other waste (e. g. separate landfill boxes).

Direct landfill means disposal on above ground hazardous waste landfills
according to the EC landfill directive 1999/31/EC and to the EC landfill
acceptance criteria (Decision 2003/33/EC). As commonly comprehensive and
easily verifiable waste acceptance criteria for above ground landfilling was
assumed as:

Allocation criteria:
                             Water content        < 60 %
                        (> 50 % dry matter - THOMANETZ)
                    organic matter content    < 8 % ignition loss.
                       (< 10 % ignition loss – THOMANETZ)

Examples of waste types suitable for direct landfilling are:
   o slags, ashes, sands, filter dusts, contaminated with inorganic compounds
   o soils, contaminated with inorganic compounds
   o demolition material, contaminated with inorganic compounds (e.g.
        asbestos)
   o inorganic residues from chemical processes
   o spent catalysts and inorganic adsorbents
   o filter cakes of different kinds (e.g. from galvanizing industry or CPT)

5.2.2   Allocation to Different Disposal Routes

Figure 5.6 shows the results of the hazardous waste allocation to disposal routes
of recycling/recovery,      CPT,   thermal treatment       and controlled landfill.
Distributions of disposal allocations are given in Figure 5.7 to Figure 5.10. In
Appendix (Figure A. 29 to Figure A. 32) exact amount of allocations are listed.




                                                                                  54
Figure 5.6 Recommended hazardous waste disposal routes for Turkey – overview




Figure 5.7 Recommended hazardous waste disposal routes to recycling/recovery


                                                                               55
Figure 5.8 Recommended hazardous waste disposal routes to CPT




Figure 5.9 Recommended hazardous waste disposal routes to thermal treatment




                                                                              56
Figure 5.10 Recommended hazardous waste disposal routes to controlled landfill

An important aspect to be considered during capacity determination is that about
20-30 % of the above mentioned input amount of the CPT-facilities has to be –
after CPT-treatment as CPT-output - treated thermally, another 20-30 % has to be
landfilled and about 50 % is water. Moreover, after solidification for landfilling
the amount to be landfilled is bigger than the solidified amount. From the other
waste treatment processes also result some hazardous waste.




5.3. Promotion of Target Waste Hierarchy in the Management System

Although Turkish legislations include waste hierarchy, discussion on promotion
of waste hierarchy is summarized in following discussion.

       5.3.1. Waste Avoidance/Prevention

Typical examples for hazardous waste prevention measures are:
   o Paint sludge-free paint techniques
   o Metal degreasing with alkalines instead of chlorinated solvents


                                                                                 57
o Ban on hazardous matter like POP’s, mercury, asbestos

Waste avoidance sometimes means cost-intensive change of well-proven
production techniques. On the other hand waste avoidance can often be achieved
by simple internal organisational measures, such as
    o Lifetime prolongation by maintenance of cutting oil emulsions
    o Intelligent water management to reduce the amount of galvanic sludges

Recommendation: Advised by an expert committee*, specific waste avoidance
measures should be implemented by law, resp. by administrative regulations.

        5.3.2 Waste Recovery

Main goal of recovery practices is saving resources. Typical examples for
hazardous waste recovery measures are:
    o Secondary aluminum production with dross treatment for salt recovery
    o Co-incineration of oil sludges for energy-saving in the cement industry
    o Zinc recovery from steelwork dust by advanced thermal processes
    o TiO2-production with recovery of iron salt as a sellable by-product

Waste recovery often means higher investment for supplementary techniques.

Recommendation: Advised by an expert committee*, specific waste recovery
measures should be implemented by law, resp. by administrative regulations.

        5.3.3. Waste disposal

Main goal is to handle non-avoidable and non-recoverable hazardous waste by
“End-of-Pipe techniques”, according to the state of the art. The well-known
hazardous waste disposal measures are:
    o Controlled Landfilling
    o Thermal Treatment



5.3.4. Recommendations for hazardous waste facilities




*in Germany, the expert committees were composed of Government representatives, public authorities and
the corresponding industry – often with the involvement of external experts


                                                                                                   58
It is advantageous if the mentioned disposal techniques are combined within an
integrated hazardous waste treatment facility such as shown on Figure 5.11,
because the waste output of one plant part can be treated or landfilled on site.
The figure depicts an ideal. But there are also other possibilities, e.g. thermal
treatment plus CPT, situated in an industrial centre, with a landfill in some
distance – far from residencies and well connected by roads without crossing
villages.




Figure 5.11 Scheme of a fully integrated hazardous waste treatment / disposal facility

Because the hazardous waste management in Turkey is still developing, the
treatment facilities should be erected step by step – according to the waste
delivery. Therefore enough free space should be kept in reserve. The facilities can
be constructed and operated privately and are supervised by the State.




                                                                                         59
6   CONCLUSIONS

Based on the hazardous waste quantity estimation approach given in Section
5.1, the following findings can be stated:

    o The overall hazardous waste generation in Turkey has been estimated
       as approximately 1,350,000 tons/yr based on the 2007 data.
    o The main gravity centres of hazardous waste generation are all located
       in the western part of Turkey: Istanbul, Kocaeli, Izmir, followed by
       Bursa and Ankara.
    o There is a distinct west-east divide of hazardous waste generation,
       with white spots in the eastern regions.
    o About 81 % of hazardous waste is generated in Industry – 19 % comes
       from other sources.
    o The major hazardous waste originators in Turkey are the Metal
       Industry (41 %), the Chemical Industry (29 %) and the Car Repair
       branch (15 %), followed by various other originators (together 15 %).


Based on hazardous waste allocation studies given in Section 5.2, following
findings can be stated:
    o About 1.35 million tons/yr (2007) of hazardous waste are to be
       disposed    of     in   Turkey   by   the     following   four   advanced
       disposal/recycling routes:
          o controlled landfill
          o thermal treatment
          o CPT
          o recycling/recovery
    o The waste amount per disposal route was determined approximately
      by use of the following allocation criteria:
          o waste to controlled landfilling: with water content not more than
             50 % on dry mass basis, and with ignition loss not more than 10
             % on dry mass basis.
          o waste to thermal treatment: with water content not more than
             50% on mass basis; no limit for ignition loss
          o waste to CPT: with water content more than 50% on mass basis

                                                                               60
o waste for recycling/recovery: following the experiences in other
             countries.


   o The allocation delivered the following results:
      o waste amount for controlled landfill: approx. 251,000 tons/yr
                                                                  (18.5 %)
      o waste amount for thermal treatment: approx. 476,000 tons/yr
                                                                  (35.0 %)
      o waste amount for CPT: approx. 446,000 tons/yr             (33.5 %)
      o waste amount for recycling/recovery: approx. 178,000 tons/yr
                                                                  (13.1 %)
   o With a view to the Turkish province map, the highest demand for
      disposal facilities is, by far, Đstanbul – followed by Kocaeli, Izmir,
      Ankara and Bursa. About one-third of the 81 Turkish provinces are
      arranged behind these gravity points on a much lower level. More than
      two-thirds of the 81 Turkish provinces have presently no need for
      advanced disposal facilities.


With regard to the waste gravity centres in Turkey, five bigger integrated
hazardous waste treatment facilities should be stipulated as similarly
recommended by “Technical Assistance for Environmental Heavy-Cost
Investment Planning” Project :

   o for Đstanbul. It should be the biggest facility with highest priority.
      Thrace area would be a favourable location with good roads (and also
      rail connection).
   o for Kocaeli region. The existing Đzaydas facilities should be enlarged
      and equipped with CPT plants
   o for Izmir region and adjacent regions
   o for Ankara region and adjacent regions
   o for Adana region and adjacent south-eastern regions

These centres with their coverage area are shown on Figure 6.1.




                                                                             61
Figure 6.1 Five recommended planning areas for integrated hazardous waste treatment
facilities

Furthermore, numerous smaller and larger sized hazardous waste facilities in
Turkey should be included into the developing management concept.




Figure 6.2 Locations of 189 mostly private operating hazardous waste treatment facilities in
Turkey




                                                                                         62
7. RECOMMENDATONS

Aside from general hazardous waste management concept, recommendations
on specific issues is given in this Section.
The current information status should be updated:
   o waste throughput capacity (licensed and in reality)
   o waste storage capacity (licensed and in reality)
   o type of treated waste
   o waste treatment techniques
   o waste input
   o waste output
   o wastewater output
   o groundwater protection measures

Recommendations for a hazardous waste disposal structure of the low
industrialized areas in Turkey

Due to the wide Turkish countryside with marginal industry and due to the
large distances between low-waste regions and the big waste treatment
centres, there is a need for a multitude of small-sized hazardous waste
collecting points, particularly equipped with a dewatering facility (settling
tank and filter press) and a waste packaging station – with storage capacities
of some 100 tons – e.g. located on site of a sewage treatment plant. The
accruing filtrates should be collected and treated from time to time by
alkaline/iron precipitation and by activated carbon. The facility should have
a suitable floor to avoid groundwater pollution and the waste should be
stored and packed under roof. These small intermediate facilities should be
managed privately and supervised by the local authorities. It should be
verified if the existing treatment facilities are suitable for this purpose.

Recommendations for a peripheral problem concerning CPT

A special problem in Turkey is the disposal of aqueous liquids and thin
sludges (rep. industrial wastewater) with hazardous constituents like acids,
lyes, heavy metals, chromates, nitrites, cyanides and a multitude of persistent
organics.




                                                                               63
Because of the wide lack of CPT plants in Turkey, most of these liquid wastes
are discharged today into municipal sewage treatment plants. Therefore, the
resulting sewage sludge is more or less loaded with hazardous matter and
must be landfilled because it is not utilizable for agriculture.

Today, about 158 municipal mechanical-biological sewage treatment plants
(plus 26 solely mechanical plants) are working in Turkey (Figure 7.1) –
producing approximately 700,000 tons/yr (dry matter), with a calorific value
of about 15 MJ/kg (dry matter). Besides these municipal sewage treatment
plants, there are a lot of industrial sewage treatment plants with similar
sludge problems.




Figure 7.1 Locations and numbers of municipal sewage treatment plants in Turkey

Besides the planning and realisation of hazardous waste treatment centres
with CPT, a medium-term strategy for this problem is recommended:
   o Sludge dewatering with filter press or decanter centrifuge
   o Solar supported sludge drying, e.g. with low temperature waste heat
       utilisation from cement production plants
   o Heat utilisation of dried sludge in cement kilns or coal fired power
       stations


                                                                                  64
This alternative should be stipulated, because landfilling of sewage sludge is
not state of the art.




                                                                           65
APPENDIX

Table A. 1 List of NUTS codes for Turkey

 NUTS 1 : REGIONS                                   NUTS 3: PROVINCES     TR811   Zonguldak
 TR1     Đstanbul                                   TR100    Đstanbul     TR812   Karabük
 TR2     Western Marmara                            TR211    Tekirdağ     TR813   Bartın
 TR3     Aegean                                     TR212    Edirne       TR821   Kastamonu
 TR4     Eastern Marmara                            TR213    Kırklareli   TR822   Çankırı
 TR5     West Anatolia                              TR221    Balıkesir    TR823   Sinop
 TR6     Mediterranean                              TR222    Çanakkale    TR831   Samsun
 TR7     Central Anatolia                           TR310    Đzmir        TR832   Tokat
 TR8     Western Black Sea                          TR321    Aydın        TR833   Çorum
 TR9     Eastern Black Sea                          TR322    Denizli      TR834   Amasya
 TRA     Northeastern Anatolia                      TR323    Muğla        TR901   Trabzon
 TRB     Central Eastern Anatolia                   TR331    Manisa       TR902   Ordu
 TRC     Southeastern Anatolia                      TR332    Afyon        TR903   Giresun
 NUTS 2: SUB-REGIONS                                TR333    Kütahya      TR904   Rize
 TR10    Đstanbul                                   TR334    Uşak         TR905   Artvin
 TR21    Tekirdağ, Edirne, Kırklareli               TR411    Bursa        TR906   Gümüşhane
 TR22    Balıkesir, Çanakkale                       TR412    Eskişehir    TRA11   Erzurum
 TR31    Đzmir                                      TR413    Bilecik      TRA12   Erzincan
 TR32    Aydın, Denizli, Muğla                      TR421    Kocaeli      TRA13   Bayburt
 TR33    Manisa, Afyon, Kütahya, Uşak               TR422    Sakarya      TRA21   Ağrı
 TR41    Bursa, Eskişehir, Bilecik                  TR423    Düzce        TRA22   Kars
         Kocaeli, Sakarya, Düzce,           Bolu,
 TR42                                               TR424    Bolu         TRA23   Iğdır
         Yalova
 TR51    Ankara                                     TR425    Yalova       TRA24   Ardahan
 TR52    Konya, Karaman                             TR510    Ankara       TRB11   Malatya
 TR61    Antalya, Isparta, Burdur                   TR521    Konya        TRB12   Elazığ
 TR62    Adana, Mersin                              TR522    Karaman      TRB13   Bingöl
 TR63    Hatay, Kahramanmaraş, Osmaniye             TR611    Antalya      TRB14   Tunceli
         Kırıkkale,     Aksaray,  Niğde,
 TR71                                               TR612    Isparta      TRB21   Van
         Nevşehir, Kırşehir
 TR72    Kayseri, Sivas, Yozgat                     TR613    Burdur       TRB22   Muş
 TR81    Zonguldak, Karabük, Bartın                 TR621    Adana        TRB23   Bitlis
 TR82    Kastamonu, Çankırı,Sinop                   TR622    Mersin       TRB24   Hakkari
 TR83    Samsun, Tokat, Çorum, Amasya               TR631    Hatay        TRC11   Gaziantep
         Trabzon, Ordu, Giresun, Rize,
 TR90                                               TR632    K.maraş      TRC12   Adıyaman
         Artvin, Gümüşhane
 TRA1    Erzurum, Erzincan, Bayburt                 TR633    Osmaniye     TRC13   Kilis
 TRA2    Ağrı, Kars, Iğdır, Ardahan                 TR711    Kırıkkale    TRC21   Şanlıurfa
 TRB1    Malatya, Elazığ, Bingöl, Tunceli           TR712    Aksaray      TRC22   Diyarbakır
 TRB2    Van, Muş, Bitlis, Hakkari                  TR713    Niğde        TRC31   Mardin
 TRC1    Gaziantep, Adıyaman, Kilis                 TR714    Nevşehir     TRC32   Batman
 TRC2    Şanlıurfa, Diyarbakır                      TR715    Kırşehir     TRC33   Şırnak
 TRC3    Mardin, Batman, Şırnak, Siirt              TR721    Kayseri      TRC34   Siirt




                                                                                              66
Table A. 2 Turkish population (2007)




                                       67
Figure A. 1 Number of employees in Turkish Industry (2007)




                                                             68
Figure A. 1 continued




                        69
Table A. 3 Number of employees in Turkish industry (2007)




                                                            70
Table A. 4 Additional information for provinces

                                                          EMPLOYEE
       PROVINCE       NUTS3    CAPITA      VEHICLES                       GNP2001[%]
                                                        (AGRICULTURE)
     Đstanbul         TR100   12,573,836    2,612,379            30,279         21.30
     Tekirdağ         TR211      728,396      121,355            45,672          1.08
     Edirne           TR212      396,462       93,425            49,681          0.65
     Kırklareli       TR213      333,256       70,620            35,306          0.80
     Balıkesir        TR221    1,118,313      280,672           134,679          1.47
     Çanakkale        TR222      476,128      122,891            75,282          0.74
     Đzmir            TR310    3,739,353      879,957           119,157          7.50
     Aydın            TR321      946,971      257,138           112,105          1.31
     Denizli          TR322      907,325      240,595           120,367          1.23
     Muğla            TR323      766,156      277,692           115,346          1.64
     Manisa           TR331    1,319,920      358,306           150,970          2.11
     Afyonkarahisar   TR332      701,572      129,884           103,688          0.70
     Kütahya          TR333      583,910      130,192            82,396          0.81
     Uşak             TR334      334,115       77,577            44,754          0.32
     Bursa            TR411    2,439,876      480,896            99,586          3.65
     Eskişehir        TR412      724,849      166,424            33,814          1.21
     Bilecik          TR413      203,777       37,801            22,081          0.34
     Kocaeli          TR421    1,437,926      195,888            43,170          5.13
     Sakarya          TR422      835,222      153,659            67,199          1.07
     Düzce            TR423      323,328       57,570            41,810          0.25
     Bolu             TR424      270,417       66,843            33,845          0.77
     Yalova           TR425      181,758       26,760            10,991          0.40
     Ankara           TR510    4,466,756    1,159,660            89,724          7.59
     Konya            TR521    1,959,082      416,365           182,829          2.38
     Karaman          TR522      226,049       55,052            36,464          0.33
     Antalya          TR611    1,789,295      612,069           134,873          2.64
     Isparta          TR612      419,845      107,608            52,067          0.53
     Burdur           TR613      251,181       81,303            46,086          0.34
     Adana            TR621    2,006,650      388,269            80,207          2.98
     Mersin           TR622    1,595,938      340,355            95,445          2.82
     Hatay            TR631    1,386,224      277,293           114,813          1.48
     Kahramanmaraş    TR632    1,004,414      117,892            91,834          1.08
     Osmaniye         TR633      452,880       87,890            29,670          0.37
     Kırıkkale        TR711      280,234       30,546            21,897          0.71
     Aksaray          TR712      366,109       60,429            45,288          0.27
     Niğde            TR713      331,677       56,409            41,668          0.42
     Nevşehir         TR714      280,058       63,651            53,532          0.45
     Kırşehir         TR715      223,170       34,740            28,941          0.25
     Kayseri          TR721    1,165,088      209,592            86,814          1.31
     Sivas            TR722      638,464       85,733            79,584          0.71
     Yozgat           TR723      492,127       61,858            78,328          0.40
     Zonguldak        TR811      615,890       99,146            65,098          1.23
     Karabük          TR812      218,463       39,954            26,375          0.24
     Bartın           TR813      182,131       28,223            33,895          0.13
     Kastamonu        TR821      360,366       74,575            73,682          0.45
     Çankırı          TR822      174,012       24,293            29,456          0.21
     Sinop            TR823      198,412       30,789            43,723          0.22
     Samsun           TR831    1,228,959      201,755           132,988          1.37
     Tokat            TR832      620,722      105,556            79,741          0.78
     Çorum            TR833      549,828      107,075            80,064          0.67


                                                                                        71
Table A. 4 continued

                                                         EMPLOYEE
       PROVINCE     NUTS3   CAPITA       VEHICLES                         GNP2001[%]
                                                       (AGRICULTURE)
       Amasya       TR834      328,674        63,846             39,023          0.36
       Trabzon      TR901      740,569        91,594            115,476          1.01
       Ordu         TR902      715,409        69,940            129,023          0.64
       Giresun      TR903      417,505        45,501             98,222          0.51
       Rize         TR904      316,252        37,854             80,800          0.47
       Artvin       TR905      168,092        19,871             45,297          0.28
       Gümüşhane    TR906      130,825        12,407             21,602          0.14
       Erzurum      TRA11      784,941        65,151             81,387          0.68
       Erzincan     TRA12      213,538        34,166             34,360          0.25
       Bayburt      TRA13       76,609         7,827             11,411          0.07
       Ağrı         TRA21      530,879        21,651             47,943          0.21
       Kars         TRA22      312,205        25,242             38,586          0.19
       Iğdır        TRA23      181,866        14,214             18,982          0.10
       Ardahan      TRA24      112,721         8,104             24,100          0.08
       Malatya      TRB11      722,065        89,354             63,033          0.83
       Elazığ       TRB12      541,258        62,420             47,497          0.66
       Bingöl       TRB13      251,552         8,669             33,537          0.14
       Tunceli      TRB14       84,022         3,974             12,171          0.10
       Van          TRB21      979,671        53,091             58,906          0.52
       Muş          TRB22      405,509        17,105             46,339          0.18
       Bitlis       TRB23      327,886        12,335             29,346          0.17
       Hakkari      TRB24      246,469         6,498             17,709          0.14
       Gaziantep    TRC11    1,560,023       265,241             44,361          1.42
       Adıyaman     TRC12      582,762        52,952             54,864          0.39
       Kilis        TRC13      118,457        23,518              9,245          0.14
       Şanlıurfa    TRC21    1,523,099       149,783             90,618          1.01
       Diyarbakır   TRC22    1,460,714        78,030             72,374          1.23
       Mardin       TRC31      745,778        39,950             44,911          0.48
       Batman       TRC32      472,487        26,182             23,232          0.38
       Şırnak       TRC33      416,001        24,440             18,133          0.16
       Siirt        TRC34      291,528        10,457             20,248          0.20
       TOTAL                70,586,256    13,237,971          5,000,000        100.00




                                                                                        72
Table A. 5 Hazardous waste in Turkey, from industry and other sources in tons/yr

     PROVINCE         NUTS 3   TOTAL      FROM INDUSTRY      FROM OTHER SOURCES
     Đstanbul         TR100     314,249            265,627                    48,621
     Tekirdağ         TR211      32,285             29,910                     2,374
     Edirne           TR212       2,921              1,189                     1,732
     Kırklareli       TR213      14,942             13,613                     1,329
     Balıkesir        TR221      15,532             10,383                     5,149
     Çanakkale        TR222      17,877             15,622                     2,255
     Đzmir            TR310     104,692             88,568                    16,123
     Aydın            TR321      10,459              5,797                     4,662
     Denizli          TR322      23,151             18,767                     4,384
     Muğla            TR323       6,947              2,079                     4,868
     Manisa           TR331      40,363             33,870                     6,493
     Afyonkarahisar   TR332       6,872              4,350                     2,522
     Kütahya          TR333       8,354              5,913                     2,441
     Uşak             TR334       6,333              4,890                     1,443
     Bursa            TR411      92,391             83,310                     9,082
     Eskişehir        TR412      25,330             22,264                     3,067
     Bilecik          TR413       9,349              8,619                         729
     Kocaeli          TR421     130,577            126,595                     3,982
     Sakarya          TR422      24,283             21,326                     2,957
     Düzce            TR423       8,863              7,739                     1,123
     Bolu             TR424       6,897              5,667                     1,230
     Yalova           TR425       5,895              5,358                         538
     Ankara           TR510      89,027             68,109                    20,919
     Konya            TR521      34,549             26,730                     7,819
     Karaman          TR522       1,859               839                      1,020
     Antalya          TR611      18,830              8,101                    10,729
     Isparta          TR612       4,663              2,695                     1,969
     Burdur           TR613       2,693              1,243                     1,449
     Adana            TR621      30,511             23,155                     7,355
     Mersin           TR622      18,083             11,725                     6,358
     Hatay            TR631      37,242             31,987                     5,255
     Kahramanmaraş    TR632       7,523              5,002                     2,521
     Osmaniye         TR633       3,421              1,750                     1,670
     Kırıkkale        TR711       8,474              7,809                         665
     Aksaray          TR712       4,643              3,446                     1,197
     Niğde            TR713       3,759              2,648                     1,111
     Nevşehir         TR714       2,327              1,130                     1,197
     Kırşehir         TR715       4,403              3,705                         698
     Kayseri          TR721      22,871             18,825                     4,046
     Sivas            TR722       5,160              3,378                     1,782
     Yozgat           TR723       2,600              1,283                     1,317
     Zonguldak        TR811      25,242             23,274                     1,968
     Karabük          TR812      14,457             13,683                         774
     Bartın           TR813       1,205               632                          573


                                                                                         73
Kastamonu         TR821       2,577              1,148                   1,429
Table A. 5 Continued

      PROVINCE     NUTS 3      TOTAL       FROM INDUSTRY      FROM OTHER SOURCES
      Çankırı      TR822         2,003              1,498                    504
      Sinop        TR823         1,396               768                     629
      Samsun       TR831        13,531              9,541                   3,990
      Tokat        TR832         3,454              1,375                   2,079
      Çorum        TR833         6,992              4,934                   2,058
      Amasya       TR834         2,639              1,416                   1,223
      Trabzon      TR901         4,160              2,202                   1,958
      Ordu         TR902         3,474              1,861                   1,612
      Giresun      TR903         1,788               762                    1,026
      Rize         TR904         2,301              1,468                    834
      Artvin       TR905         1,688              1,248                    441
      Gümüşhane    TR906          486                198                     288
      Erzurum      TRA11         3,287              1,731                   1,556
      Erzincan     TRA12          942                256                     686
      Bayburt      TRA13          221                 44                     177
      Ağrı         TRA21          806                106                     700
      Kars         TRA22          879                268                     612
      Iğdır        TRA23          357                 10                     347
      Ardahan      TRA24          215                  5                     211
      Malatya      TRB11         3,458              1,576                   1,882
      Elazığ       TRB12         3,410              2,069                   1,340
      Bingöl       TRB13          349                 36                     313
      Tunceli      TRB14          144                 22                     122
      Van          TRB21         2,638              1,159                   1,479
      Muş          TRB22          763                215                     549
      Bitlis       TRB23          516                100                     416
      Hakkari      TRB24          293                 26                     267
      Gaziantep    TRC11        14,128              8,988                   5,139
      Adıyaman     TRC12         2,204               980                    1,223
      Kilis        TRC13          644                198                     446
      Şanlıurfa    TRC21         4,908              1,563                   3,345
      Diyarbakır   TRC22         3,702              1,523                   2,180
      Mardin       TRC31         2,171              1,052                   1,119
      Batman       TRC32         3,533              2,814                    720
      Şırnak       TRC33         1,514               860                     654
      Siirt        TRC34          678                320                     359




                                                                                      74
Table A. 6 Hazardous waste from main industrial sectors in tons/yr

  PROVINCE       NUTS 3    METAL INDUSTRY       CHEMICAL INDUSTRY      OTHER INDUSTRIES
Đstanbul         TR100           152,871                 83,003              29,753
Tekirdağ         TR211           11,833                  10,960              7,117
Edirne           TR212             243                    329                 617
Kırklareli       TR213            1,561                  7,074               4,978
Balıkesir        TR221            2,866                  6,486               1,030
Çanakkale        TR222            2,921                  9,614               3,087
Đzmir            TR310           47,813                  32,251              8,505
Aydın            TR321            3,035                  1,393               1,370
Denizli          TR322            4,840                  7,294               6,633
Muğla            TR323             610                    726                 744
Manisa           TR331           23,190                  7,258               3,422
Afyonkarahisar   TR332             624                   2,648               1,077
Kütahya          TR333            1,018                  3,462               1,434
Uşak             TR334             727                   3,028               1,135
Bursa            TR411           55,367                  17,585              10,358
Eskişehir        TR412           13,454                  6,987               1,823
Bilecik          TR413            3,997                  2,479               2,143
Kocaeli          TR421           54,034                  62,149              10,412
Sakarya          TR422           14,186                  5,801               1,339
Düzce            TR423            2,933                  3,869                938
Bolu             TR424            4,046                   908                 713
Yalova           TR425             928                   4,239                191
Ankara           TR510           46,851                  9,599               11,659
Konya            TR521           18,486                  4,817               3,427
Karaman          TR522             277                    190                 372
Antalya          TR611            3,286                  3,380               1,435
Isparta          TR612             191                    525                1,979
Burdur           TR613             677                     17                 549
Adana            TR621           10,547                  9,345               3,263
Mersin           TR622            3,993                  6,292               1,440
Hatay            TR631           10,606                  20,900               480
Kahramanmaraş    TR632            2,353                   361                2,287
Osmaniye         TR633             853                    674                 223
Kırıkkale        TR711            2,667                  5,046                96
Aksaray          TR712            2,582                   629                 235
Niğde            TR713             629                   1,644                375
Nevşehir         TR714             412                    397                 321
Kırşehir         TR715             411                   3,171                124
Kayseri          TR721           10,879                  2,658               5,288
Sivas            TR722            2,547                   424                 406
Yozgat           TR723             473                    280                 529
Zonguldak        TR811            6,035                  16,703               536
Karabük          TR812            3,938                  9,629                116
Bartın           TR813             63                     178                 391


                                                                                      75
Kastamonu       TR821           430                    98                  620
  Table A. 6 Continued

   PROVINCE     NUTS 3   METAL INDUSTRY   CHEMICAL INDUSTRY   OTHER INDUSTRIES
   Çankırı      TR822         1,065              246                 188
   Sinop        TR823          267               105                 395
   Samsun       TR831         3,674              4,608              1,259
   Tokat        TR832          310               403                 662
   Çorum        TR833         1,876              2,060               998
   Amasya       TR834          794               254                 368
   Trabzon      TR901         1,566              163                 472
   Ordu         TR902          380               1,012               469
   Giresun      TR903          199               332                 231
   Rize         TR904          46                420                1,002
   Artvin       TR905          290               192                 766
   Gümüşhane    TR906          68                 78                 52
   Erzurum      TRA11          465               993                 274
   Erzincan     TRA12          61                 44                 151
   Bayburt      TRA13           0                 0                  44
   Ağrı         TRA21           0                 39                 68
   Kars         TRA22          139                29                 100
   Iğdır        TRA23           0                 0                  10
   Ardahan      TRA24           0                 0                  5
   Malatya      TRB11          472               225                 879
   Elazığ       TRB12         1,321              298                 450
   Bingöl       TRB13           0                 0                  36
   Tunceli      TRB14           0                 0                  22
   Van          TRB21          63                799                 296
   Muş          TRB22          109                34                 72
   Bitlis       TRB23           9                 62                 28
   Hakkari      TRB24           0                 0                  26
   Gaziantep    TRC11         1,996              3,022              3,971
   Adıyaman     TRC12          107               239                 634
   Kilis        TRC13           0                170                 28
   Şanlıurfa    TRC21          601               204                 758
   Diyarbakır   TRC22          409               564                 549
   Mardin       TRC31          150               674                 229
   Batman       TRC32           0                2,640               174
   Şırnak       TRC33           0                403                 458
   Siirt        TRC34          83                 54                 182




                                                                                 76
Table A. 7 Hazardous waste from non-industrial sources in tons/yr

     PROVINCE       NUTS 3   SEPARATE COLLECTION        CAR REPAIR   AGRICULTURE
   Đstanbul         TR100              7,972               40,633         17
   Tekirdağ         TR211               462                 1,888         25
   Edirne           TR212               251                 1,453         27
   Kırklareli       TR213               211                 1,098         19
   Balıkesir        TR221               709                 4,366         74
   Çanakkale        TR222               302                 1,911         41
   Đzmir            TR310              2,371               13,687         66
   Aydın            TR321               600                 4,000         62
   Denizli          TR322               575                 3,742         66
   Muğla            TR323               486                 4,319         63
   Manisa           TR331               837                 5,573         83
   Afyonkarahisar   TR332               445                 2,020         57
   Kütahya          TR333               370                 2,025         45
   Uşak             TR334               212                 1,207         25
   Bursa            TR411              1,547                7,480         55
   Eskişehir        TR412               460                 2,589         19
   Bilecik          TR413               129                 588           12
   Kocaeli          TR421               912                 3,047         24
   Sakarya          TR422               530                 2,390         37
   Düzce            TR423               205                 895           23
   Bolu             TR424               171                 1,040         19
   Yalova           TR425               115                 416           6
   Ankara           TR510              2,832               18,037         49
   Konya            TR521              1,242                6,476        101
   Karaman          TR522               143                 856           20
   Antalya          TR611              1,134                9,520         74
   Isparta          TR612               266                 1,674         29
   Burdur           TR613               159                 1,265         25
   Adana            TR621              1,272                6,039         44
   Mersin           TR622              1,012                5,294         52
   Hatay            TR631               879                 4,313         63
   Kahramanmaraş    TR632               637                 1,834         51
   Osmaniye         TR633               287                 1,367         16
   Kırıkkale        TR711               178                 475           12
   Aksaray          TR712               232                 940           25
   Niğde            TR713               210                 877           23
   Nevşehir         TR714               178                 990           29
   Kırşehir         TR715               141                 540           16
   Kayseri          TR721               739                 3,260         48
   Sivas            TR722               405                 1,333         44
   Yozgat           TR723               312                 962           43
   Zonguldak        TR811               390                 1,542         36
   Karabük          TR812               139                 621           15
   Bartın           TR813               115                 439           19


                                                                                   77
Kastamonu       TR821              228                1,160            41
Table A. 7 Continued

  PROVINCE     NUTS 3   SEPARATE COLLECTION   CAR REPAIR         AGRICULTURE
  Çankırı      TR822            110               378                 16
  Sinop        TR823            126               479                 24
  Samsun       TR831            779              3,138                73
  Tokat        TR832            394              1,642                44
  Çorum        TR833            349              1,665                44
  Amasya       TR834            208               993                 21
  Trabzon      TR901            470              1,425                64
  Ordu         TR902            454              1,088                71
  Giresun      TR903            265               708                 54
  Rize         TR904            201               589                 44
  Artvin       TR905            107               309                 25
  Gümüşhane    TR906            83                193                 12
  Erzurum      TRA11            498              1,013                45
  Erzincan     TRA12            135               531                 19
  Bayburt      TRA13            49                122                 6
  Ağrı         TRA21            337               337                 26
  Kars         TRA22            198               393                 21
  Iğdır        TRA23            115               221                 10
  Ardahan      TRA24            71                126                 13
  Malatya      TRB11            458              1,390                35
  Elazığ       TRB12            343               971                 26
  Bingöl       TRB13            159               135                 18
  Tunceli      TRB14            53                62                  7
  Van          TRB21            621               826                 32
  Muş          TRB22            257               266                 25
  Bitlis       TRB23            208               192                 16
  Hakkari      TRB24            156               101                 10
  Gaziantep    TRC11            989              4,126                24
  Adıyaman     TRC12            369               824                 30
  Kilis        TRC13            75                366                 5
  Şanlıurfa    TRC21            966              2,330                50
  Diyarbakır   TRC22            926              1,214                40
  Mardin       TRC31            473               621                 25
  Batman       TRC32            300               407                 13
  Şırnak       TRC33            264               380                 10
  Siirt        TRC34            185               163                 11




                                                                               78
Table A. 8A Hazardous waste from industrial branches in tons/yr

                          BATTERY     CEMENT      INORGANIC         FERTILIZER   ORGANIC      OTHER      PAINT   ELECTRICAL     ENERGY
  PROVINCE       NUTS 3
                            IND.        IND.      CHEMISTRY            IND.      CHEMISTRY   CHEMISTRY   IND.       IND.      GENERATION
Đstanbul         TR100      5,976        25           641              274         9,433       63,455    5,579     21,393        400
Tekirdağ         TR211        0           0            31               0          1,317       8,896      285       1,905        1,601
Edirne           TR212        0          16            0                0            0          329        0         0            0
Kırklareli       TR213        0          11            11              744          341        5,945      11         81          3,492
Balıkesir        TR221       57           8           752              781         3,378       1,444      75        346           0
Çanakkale        TR222        0          20            50               0           114        9,438      12         3           1,639
Đzmir            TR310       289         30           170              622         7,189       13,812    1,738      4,958        1,445
Aydın            TR321       30          10            0                0           338         979        0         51          358
Denizli          TR322        0          10           188               0           980        5,495      54        460          1,142
Muğla            TR323        0           3            97               0           229         131        0         0           177
Manisa           TR331      1,324         1            0                87          489        4,175      121       3,595        621
Afyonkarahisar   TR332        0          14            70               21          886        1,671       0         0            0
Kütahya          TR333       49           5           373              170         1,418        691       48         20           0
Uşak             TR334        0           0            14               0          1,651        844        6         27           0
Bursa            TR411        0          22            0                77         2,328       12,842     230       3,506        872
Eskişehir        TR412        0          11          1,692              0          2,704       2,147      233       681          122
Bilecik          TR413        0           1            36               0           90         2,337      16         56           21
Kocaeli          TR421       235         34           932              1,124       11,021      36,378    3,872      3,810        6,925
Sakarya          TR422        0           2           176               0           204        5,052      31        1,102         0
Düzce            TR423        0           0            0                0           105        3,726       0         55           0
Bolu             TR424        0          12            17               0            0          444        0        1,086         0
Yalova           TR425       130          0            11               0          4,199        29         0         6            0
Ankara           TR510       467         62           269              173          128        5,365      715       4,399        6,814
Konya            TR521        0           8           887              389          109        2,794      115       285          1,279




                                                                                                                                         79
Karaman        TR522        0         0            0            0            161          29        0             7             0
 Table A. 8A Continued

                           BATTERY    CEMENT     INORGANIC   FERTILIZER   ORGANIC      OTHER      PAINT   ELECTRICAL    ENERGY
    PROVINCE      NUTS 3
                            IND.          IND.   CHEMISTRY      IND.      CHEMISTRY   CHEMISTRY   IND.       IND.      GENERATION
  Antalya         TR611         85         16          166      705          331        1,220      128       245           40
  Isparta         TR612          0         11          0            0        51          474        0         0           1,335
  Burdur          TR613         45         26          0            0         0          17         0         21           0
  Adana           TR621          0         30          34       431         6,704       1,545      174       115          1,264
  Mersin          TR622          0         22      1,281        295         2,028       2,182      65         68          242
  Hatay           TR631          0         9           148      2,665       4,984        648       85         7            0
  Kahramanmaraş   TR632          0         9           0            23        0          166        0         3           413
  Osmaniye        TR633          0         2           0            19       29          203       17         18           0
  Kırıkkale       TR711          0         0           0            0        704        1,761      27         0            0
  Aksaray         TR712          0         0           0            89       59          472        9         21           0
  Niğde           TR713          0         8           10           0        55         1,481       0         6            0
  Nevşehir        TR714          0         8           0            0        36          361        0         0            0
  Kırşehir        TR715          0         1           0            0         0         3,148      23         0            0
  Kayseri         TR721         138        6           708          0        24         1,364      91        778          392
  Sivas           TR722          0         23          0            33        0          185        8         3            0
  Yozgat          TR723          0         13          9            25        0          198        0         42           0
  Zonguldak       TR811          0         5       4,182            0         0          462        0         20           21
  Karabük         TR812          0         2           0            0       4,337         0         0         9            0
  Bartın          TR813          0         11          0            0         0          161       17         0            0
  Kastamonu       TR821          0         0           0            0        63          35         0         95           0
  Çankırı         TR822          0         2           0            0         0          198        0        346           0
  Sinop           TR823          0         3           0            0         0           0         0         0            0
  Samsun          TR831          0         22          0        705         2,008       1,444      29        216          569




                                                                                                                                    80
Tokat          TR832       0        17         0           0           41          300        0         0            0



Table A. 8A Continued

                        BATTERY   CEMENT   INORGANIC   FERTILIZER   ORGANIC      OTHER      PAINT   ELECTRICAL    ENERGY
  PROVINCE     NUTS 3
                         IND.      IND.    CHEMISTRY      IND.      CHEMISTRY   CHEMISTRY   IND.       IND.      GENERATION
Çorum          TR833       0        9         40           19           0          227        0         15           0
Amasya         TR834       0        0         30           19          71          134        0        154           0
Trabzon        TR901       0        8          0           0            0          163        0         57           0
Ordu           TR902       0        13         0           0            0          515       42         30           0
Giresun        TR903       0        0          0           54           0           0         0         7            0
Rize           TR904       0        0          0           0            0           0        25         0            0
Artvin         TR905       0        0          0           0            0           0         0         0           632
Gümüşhane      TR906       0        2          0           0            0          57        22         0            0
Erzurum        TRA11       0        13         0           0           63          38        36         0            0
Erzincan       TRA12       0        0          0           0            0          44         0         0            67
Bayburt        TRA13       0        0          0           0            0           0         0         0            0
Ağrı           TRA21       0        2          0           0            0          15         0         0            0
Kars           TRA22       0        10         0           0            0          29         0         0            0
Iğdır          TRA23       0        0          0           0            0           0         0         0            0
Ardahan        TRA24       0        0          0           0            0           0         0         0            0
Malatya        TRB11       0        4          0           0           18          73        33        164           80
Elazığ         TRB12       0        15         0           0           185         114        0         71           0
Bingöl         TRB13       0        0          0           0            0           0         0         0            0
Tunceli        TRB14       0        0          0           0            0           0         0         0            0
Van            TRB21       0        16         0           0            0          47         0         6           143
Muş            TRB22       0        0          0           0           22           0        12         0            0




                                                                                                                           81
Bitlis         TRB23       0        0          0           0            0           0         0         2            0
Hakkari        TRB24       0        0          0           0            0           0         0         0            0
Gaziantep      TRC11      57        15         9           52          628        1,440      135        17           24



Table A. 8A Continued

                        BATTERY   CEMENT   INORGANIC   FERTILIZER   ORGANIC      OTHER      PAINT   ELECTRICAL    ENERGY
  PROVINCE     NUTS 3
                         IND.      IND.    CHEMISTRY      IND.      CHEMISTRY   CHEMISTRY   IND.       IND.      GENERATION
Adıyaman       TRC12       0        7          0           48           0          191        0         37           0
Kilis          TRC13       0        0          0           0            0          41         0         0            0
Şanlıurfa      TRC21       0        9          0           21           0          73         0        126          413
Diyarbakır     TRC22       0        26         0           0            0          232       93         49           0
Mardin         TRC31       0        24         0          108          63          98         0         16          122
Batman         TRC32       0        5          0           0            0          120       18         0            0
Şırnak         TRC33       0        0          0           0            0           0         0         0           436
Siirt          TRC34       0        23         0           0            0           0        54         0           122




                                                                                                                           82
Table A. 8B Hazardous waste from industrial branches in tons/yr

                 NUTS    FOOD     LEATHER           METAL          METAL     MINERAL       NON-FERROUS      PAPER   PETROLEUM
 PROVINCE
                   3     IND.        IND.       PRODUCTION         WORK     PRODUCTION   METAL PRODUCTION   IND.    RAFINATION
Đstanbul         TR100   1,139       1,307          11,353         99,606      2,692           14,543       1,263      3,620
Tekirdağ         TR211    150         197            1,243         5,395       384             3,290         171       431
Edirne           TR212    70          32               0            243         77               0            9         0
Kırklareli       TR213    98          45              825           656        460               0           29         22
Balıkesir        TR221    313         13              442          1,871       243              150          18         56
Çanakkale        TR222    87           8             1,653         1,266       1,154             0            0         0
Đzmir            TR310    874         232            8,332         30,987      1,187           3,246         532       8,719
Aydın            TR321    240          9              52           2,804       314              98            6         77
Denizli          TR322    61          46             1,246         2,033       1,044           1,100         106       577
Muğla            TR323    29           0               0            610        423               0            7        268
Manisa           TR331    302         23              428          17,170      1,191            675          70        2,387
Afyonkarahisar   TR332    94           5              10            601        781              14            3         0
Kütahya          TR333    52           9              99            217        1,077            633          17        762
Uşak             TR334    62          12              15            227        270              458           3        513
Bursa            TR411    462         96             4,299         47,003      518              558          99        2,109
Eskişehir        TR412    107         53              482          11,697      924              594          52        211
Bilecik          TR413    22           6              969          2,318       1,742            655          58         0
Kocaeli          TR421    203         12            11,380         33,213      507             5,396         320       8,821
Sakarya          TR422    170         15              671          12,008      135              405           9        338
Düzce            TR423    47          22             1,137         1,670       106              72           10         38
Bolu             TR424    78          22              810          2,016        50              134          15        447
Yalova           TR425    11           8               0            792         11               0           53         0
Ankara           TR510    434         93             4,624         36,078      1,125           1,283         104       2,949
Konya            TR521    343         41             2,580         13,877      496             1,745         68        523




                                                                                                                               83
Karaman         TR522       199          3             0            269             40               0             10                0
Table A. 8B Continued

                                  FOOD       LEATHER       METAL      METAL        MINERAL       NON-FERROUS      PAPER   PETROLEUM
      PROVINCE          NUTS 3
                                  IND.        IND.     PRODUCTION     WORK        PRODUCTION   METAL PRODUCTION   IND.    RAFINATION
    Antalya             TR611      116         16           148           2,704          397         104           21        831
    Isparta             TR612      20           5            0            191            138          0            18         0
    Burdur              TR613      46           9           15            596            390          0             0         0
    Adana               TR621      175         36          1,153          8,989          190         290           92        458
    Mersin              TR622      131         57           585           3,283          472          57           69        441
    Hatay               TR631      66           3          7,601          2,820          40          178           12       12,370
    Kahramanmaraş       TR632      63          32           121           1,780          114         450           23        173
    Osmaniye            TR633      22           6           370           465            26           0            12        407
    Kırıkkale           TR711      9            1           392           2,267          28           8             6        2,553
    Aksaray             TR712      35           7           37            2,523          68           0             2         0
    Niğde               TR713      42           1           21            528            84           74            0         98
    Nevşehir            TR714      25           2           113           291            197          7             0         0
    Kırşehir            TR715      32           3           200           211            41           0             0         0
    Kayseri             TR721      116          9          1,105          8,032          317         825           46        472
    Sivas               TR722      26           9          1,132          1,155          114         257            2        198
    Yozgat              TR723      97          16            0            420            177          11           14         48
    Zonguldak           TR811      39          16          4,921          1,094          205          0            42       12,058
    Karabük             TR812      6           21          3,521          408            11           0             0        5,293
    Bartın              TR813      8           22            6             57            119          0             7         0
    Kastamonu           TR821      34          20            5            330            87           0            10         0
    Çankırı             TR822      24          10           44            675            40           0             0         48
    Sinop               TR823      15          18           34            182            238          51            0        105
    Samsun              TR831      165         17           768           1,663          155         1,027         30        421




                                                                                                                                         84
Tokat          TR832    94      18          43        241        269             25            1         62



Table A. 8B Continued

                           FOOD   LEATHER     METAL      METAL    MINERAL       NON-FERROUS      PAPER   PETROLEUM
     PROVINCE     NUTS 3
                           IND.    IND.     PRODUCTION   WORK    PRODUCTION   METAL PRODUCTION   IND.    RAFINATION
    Çorum         TR833     68      47         194       1,430      639             237           60        1,774
    Amasya        TR834     36       4          61        408        88             172            0         0
    Trabzon       TR901     185      6         113       1,215       97             182            4         0
    Ordu          TR902     117     14          0         350       109              0            26        455
    Giresun       TR903     61       3          0         178        15              14           33        278
    Rize          TR904     916      0          0         46         58              0             2        395
    Artvin        TR905     65       0          0         290        55              0             0        192
    Gümüşhane     TR906     7        3          0         19         19              49            0         0
    Erzurum       TRA11     50       1          10        455        81              0             1        856
    Erzincan      TRA12     43       0          0         61         29              0             0         0
    Bayburt       TRA13     2        1          0          0         19              0             0         0
    Ağrı          TRA21     37       2          0          0         25              0             0         24
    Kars          TRA22     27      13          45        93         44              0             0         0
    Iğdır         TRA23     6        0          0          0         0               0             0         0
    Ardahan       TRA24     1        0          0          0         0               0             0         0
    Malatya       TRB11     105     14          0         308        57              0            20        101
    Elazığ        TRB12     44       1         833        418       211              0             3         0
    Bingöl        TRB13     6        1          0          0         27              0             0         0
    Tunceli       TRB14     4        0          0          0         19              0             0         0
    Van           TRB21     59       0          0         57         37              0             1        753
    Muş           TRB22     60       0          0         109        11              0             0         0




                                                                                                                      85
Bitlis        TRB23      9        1           0         8          14              0             0         62
    Hakkari       TRB24      6        0           0         0           6              0             0          0
    Gaziantep     TRC11      68      47          194       1,430       639            237           60        1,774



Table A. 8B Continued

                            FOOD   LEATHER     METAL      METAL     MINERAL       NON-FERROUS      PAPER   PETROLEUM
      PROVINCE     NUTS 3
                            IND.    IND.     PRODUCTION   WORK     PRODUCTION   METAL PRODUCTION   IND.    RAFINATION
    Adıyaman       TRC12     216      6          42       1,749        90             131           94        757
    Kilis          TRC13     15      10          0          70         46              0             8         0
    Şanlıurfa      TRC21     6        0          0          0          0               0             0        129
    Diyarbakır     TRC22     34       0         310        165         55              0             2        110
    Mardin         TRC31     92       0          10        351        228              0             1        240
    Batman         TRC32     14       0          0          77         44              56            0        405
    Şırnak         TRC33     28       1          0          0          77              0             1        2,502
    Siirt          TRC34     4        0          0          0          16              0             0        403




                                                                                                                        86
Table A. 8C Hazardous waste from industrial branches in tons/yr

                 NUTS          PLASTICS             PRINTING       TEXTILE   WOOD
  PROVINCE
                   3        MANUFACTURE                IND.         IND.     IND
Đstanbul         TR100            4,588                3,834        12,162   2,343
Tekirdağ         TR211             392                 200          3,784     240
Edirne           TR212              7                   4            402      0
Kırklareli       TR213             38                   34           719      51
Balıkesir        TR221             44                   17           79       296
Çanakkale        TR222             66                   0            19       95
Đzmir            TR310            1,125                512          1,309    1,258
Aydın            TR321             17                   4            308      103
Denizli          TR322             214                  43          3,863     104
Muğla            TR323              8                   5            16       76
Manisa           TR331             334                 174           172      531
Afyonkarahisar   TR332             30                   6            56       90
Kütahya          TR333             44                   8            68       155
Uşak             TR334             15                   2            717      52
Bursa            TR411             797                 204          5,155    2,132
Eskişehir        TR412             224                  32           40       257
Bilecik          TR413             45                   0            95       152
Kocaeli          TR421            1,226                 53           337      795
Sakarya          TR422             185                  14           396      413
Düzce            TR423             71                   29           295      358
Bolu             TR424             59                   6            136      335
Yalova           TR425             20                   0            81       7
Ankara           TR510             467                 821           383     1,356
Konya            TR521             341                 185           268      397
Karaman          TR522             24                   29           32       34
Antalya          TR611             195                  55           254      325
Isparta          TR612             13                   16           212      210
Burdur           TR613              7                   0             4       66
Adana            TR621             258                  98           772      348
Mersin           TR622             64                   11           134      238
Hatay            TR631             54                   23           189      85
Kahramanmaraş    TR632             29                   0           1,576     29
Osmaniye         TR633             15                   4            122      14
Kırıkkale        TR711              4                   0             1       47
Aksaray          TR712             43                   0            58       22
Niğde            TR713              3                   0            212      25
Nevşehir         TR714              3                   0            81       5
Kırşehir         TR715              6                   0            16       23
Kayseri          TR721             312                  70          1,106    2,913
Sivas            TR722             24                   6            50       151
Yozgat           TR723             25                   0            107      80
Zonguldak        TR811             15                   2            90       102
Karabük          TR812              1                   0            35       41


                                                                                   87
Bartın              TR813           19                 0              139          67
 Table A. 8C Continued

                                  PLASTICS    PRINTING                      WOOD
         PROVINCE      NUTS 3                              TEXTILE IND.
                                MANUFACTURE     IND.                        IND
    Kastamonu          TR821         10          0              60           400
    Çankırı            TR822         11          0              77           24
    Sinop              TR823         23          0              50           49
    Samsun             TR831        105          13             38           146
    Tokat              TR832         16          5             125           116
    Çorum              TR833         13          10             44           109
    Amasya             TR834         31          9              81           118
    Trabzon            TR901         47          32             11           82
    Ordu               TR902         18          0              62           110
    Giresun            TR903         6           3              21           89
    Rize               TR904         5           0              0            21
    Artvin             TR905         1           0              0            14
    Gümüşhane          TR906         4           0              14            4
    Erzurum            TRA11         11          8              94           13
    Erzincan           TRA12         3           0              0             8
    Bayburt            TRA13         18          0              2             3
    Ağrı               TRA21         1           0              0             0
    Kars               TRA22         0           0              0             7
    Iğdır              TRA23         0           4              0             0
    Ardahan            TRA24         0           0              0             3
    Malatya            TRB11         29          9             525           35
    Elazığ             TRB12         49          0              22           104
    Bingöl             TRB13         0           0              3             0
    Tunceli            TRB14         0           0              0             0
    Van                TRB21         8           0              27            3
    Muş                TRB22         1           0              0             0
    Bitlis             TRB23         1           0              4             0
    Hakkari            TRB24         0           0              13            0
    Gaziantep          TRC11        395         197           2,901          34
    Adıyaman           TRC12         3           3             526           16
    Kilis              TRC13         8           0              14            0
    Şanlıurfa          TRC21         19          0             225            0
    Diyarbakır         TRC22         31          0             133           39
    Mardin             TRC31         11          0              12            2
    Batman             TRC32         13          0              45            3
    Şırnak             TRC33         1           0              0             0
    Siirt              TRC34         3           0              18            0




                                                                                        88
Table A. 9A Hazardous waste groups in Turkish provinces in tons/yr

                                                                                          WASTE GROUP ID
 PROVINCES       1     2        3       4          5          6          7        8       9        10        11        12        13       14      15     16       17       18      19
Đstanbul         582   232     9,619   3,033     14,538     15,003     54,064   15,583   2,543     392      28,424    2,157     13,858   49,758   507   17,876   12,331   3,312   10,211
Tekirdağ          58    24     2,884    361       1,970      1,071      7,364    1,381    144     1,568      4,221     304        952     3,207    42     967      708     222      752
Edirne            45       0    312         0          75         15     229      100         5         0         3     76         21      721     6      279      139      20       65
Kırklareli        34       5    552         19    1,289       903       4,380     216      26     3,419       741      375         77      880     19     291      170      30      110
Balıkesir        124    29       65         47    1,003      1,029      3,935     466      18           0     590      200        246     2,518    31     991      532     105      270
Çanakkale         63       9     18         0     2,073       247       6,581     222         2   1,605      1,484     933        111     1,398    33     518      311      44      127
Đzmir            234   125     1,083   7,305      3,704      3,856     16,526    4,509    390     1,415     10,984     968       3,898   15,880   206    6,173    4,257    957     2,876
Aydın            104    10      231         64     224        143        971      310         8    351        191      258        255     2,540    27    1,005     566      91      287
Denizli          107    10     2,864    483       1,393       361       4,647     804      42     1,118      2,152     836        296     2,766    31     926      546      97      427
Muğla             98       8     12     225        140            26     294      185         8    173            8    338         53     1,912    9      816      410      44      140
Manisa           142    53      139    2,000      1,060      2,549      3,378    1,728    121      608       2,020     946       2,349    7,774    92    2,924    1,982    539     1,594
Afyonkarahisar    89       9     44         0      428            79    1,912     175         8         0      30      631         52     1,119    18     441      217      42       91
Kütahya           72    15       55     639        539        226       1,726     228      10           0     706      858         29     1,057    19     444      219      35       74
Uşak              40       5    534     430        229            36    2,010     143         3         0     440      214         30      698     9      271      141      21       77
Bursa            165   211     3,840   1,766      2,911      3,179     10,953    4,356    148      854       4,949     430       4,905   17,514   207    6,412    4,742   1,130    3,759
Eskişehir         51    25       57     177       2,007       743       3,901     940      29      120       1,131     743       1,178    4,574    61    1,728    1,221    265      863
Bilecik           21    15       73         0      535        148       1,689     277         7     21       1,497    1,383       220     1,190    36     413      281      55      174
Kocaeli           88    79      254    7,390      9,214      4,485     36,164    4,187     74     6,780     15,678     432       3,837   11,941   193    4,584    3,705    824     2,544
Sakarya           75    41      299     283       1,272       914       3,665     981      13           0    1,128     110       1,304    4,603    55    1,711    1,237    302      940
Düzce             38    35      228         32     804        155       2,649     382      20           0    1,098      84        159      965     15     352      249      58      165
Bolu              31    33      111     375        141        476        313      451         7         0     870       50        436     1,215    15     428      292     112      278
Yalova            14       1     64         0          18         77    3,629     107         7         0      88           8      70      414     5      166      103      21       64
Ankara           250   134      330    2,470      1,625      3,267      4,151    3,692    535     6,672      6,045     947       4,183   18,226   176    7,075    4,730   1,046    3,236
Konya            189    39      219     438       1,452      1,031      2,079    1,332    130     1,252      4,088     400       1,283    6,843    83    2,648    1,809    336     1,081




                                                                                                                                                                                           89
Table A. 9A Continued

                                                                                          WASTE GROUP ID
 PROVINCES      1     2        3         4         5         6         7         8        9        10       11       12    13       14      15   16      17      18    19
Karaman          30       3     25           0         9         12    163           89   20            0        4    32    25       529    12    196      93     15    43
Antalya         155     32     195       696       482       929      1,194      761      45        39       314     330   293      4,643   22   1,944   1,030   142   441
Isparta          48     21     159           0     106           16    371       209      14      1,308          3   119    17       767     4    310     153     29    73
Burdur           37       7        8         0         6         44        14        99       1         0     48     332    56       736    10    293     153     24    72
Adana           134     34     587       384       411       790      6,909     1,091     80      1,238     1,410    177   807      5,146   49   2,031   1,303   248   763
Mersin          124     24     128       369      1,667      514      3,281      561      23       237       615     394   301      3,171   29   1,293    740    131   348
Hatay           126       8    140     10,364     1,070     2,708     4,941      455      22            0   6,952     40   254      2,841   44   1,629   1,167   105   287
Kahramanmaraş    96       3   1,176      145           56        85    120       317          8    404       547      99   158      1,433   12    514     317     71   219
Osmaniye         37       1     93       341           74        44    179       112          6         0    335      22    45       704     4    301     173     27    67
Kırıkkale        25       5        2    2,139      542       112      1,862      141          2         0    385      22   196       841    11    433     313     50   153
Aksaray          41       2     46           0     105       187       380       174          2         0     66      54   223      1,101   11    428     290     58   182
Niğde            38       2    156           82    336           52   1,067          83       2         0     93      74    48       551     6    215     121     23    63
Nevşehir         42       1     61           0         80        17    280           55       1         0    111     163    25       516     5    206     109     16    44
Kırşehir         26       2     13           0     677           74   2,171          56       1         0    180      34    18       313     5    121      68     13    27
Kayseri         100   289      818       396       972       656      1,006     2,375     54       384      1,933    257   888      4,018   42   1,487    999    340   870
Sivas            73     15      42       166           59        75    135       221          7         0   1,259    112   104       927    11    372     250     51   113
Yozgat           65       8     87           40        59        58    140       147          4         0     16     152    46       588     9    225     116     32    61
Zonguldak        64     10      74     10,102     4,642      210       489       253          9     21      4,384    167   104      1,184   29    939     703     48   114
Karabük          24       4     36      4,434      338           17   3,801      102          1         0   3,133     10    41       511    15    414     340     18    44
Bartın           27       7    113           0         36        5     118           93       2         0        6   104        5    226     2     85      41     11    23
Kastamonu        57     40      54           0         11        47        80    293          3         0        9    69    51       606     4    241     123     41    82
Çankırı          24       2     62           40        47    154       138       100          1         0     48      33   141       406     4    141      90     36    88




                                                                                                                                                                             90
Sinop           33       5    46          88       9        6         2        78       1        0     80     191       16       285     5   114    59       13       27
Samsun         128      14    36      353      349      851      2,742     409      17      557      1,655    143      205      1,898   22   760   449       93      205



Table A. 9A Continued

                                                                                    WASTE GROUP ID
 PROVINCES      1    2       3        4        5        6         7        8        9       10       11       12       13       14      15   16    17       18       19
Tokat           72      11   102          52       74       14    246      163          6        0     65     229       21       810    10   324   159       34       64
Çorum           69      11    56     1,486     203          77    184      234      15           0    410     515      129      1,185   18   535   316       51      136
Amasya          36      12    62          0        59       93    155      159          7        0    218      70       74       570     5   219   120       32       74
Trabzon         97       8    11          0        42       64    118      210      24           0    285      84      120      1,024   16   392   226       56      121
Ordu           103      11    53      382      146          33    381      187          6        0        5    98       37       616     9   256   133       40       58
Giresun         73       9    17      233          22       61        7    122          8        0     16      12       17       368     4   157    82       24       34
Rize            59       2       0    331          28       1         37       55       2        0        1    46           4    752    51   223    64       14       17
Artvin          32       1       0    161          14       9         5        34       1   619           4    43       25       244     5    99    55       12       26
Gümüşhane       18       0    12          0        13       2         48       24       1        0     46      17           2     89     1    36    18           6        6
Erzurum         80       1    70      717          70       16    111      119          9        0     14      76       39       567     5   262   148       39       56
Erzincan        29       1       0        0        12       3         32       31       1    66           1    23           5    250     3   101    49       10       16
Bayburt         10       0       2        0        1        0         0        23       0        0        0    15           0     52     0    21    10           3        3
Ağrı            50       0       1        20       10       0         13       46       3        0        0    22           0    154     2    62    30       21           8
Kars            35       1       7        0        9        4         22       38       2        0     41      44           8    200     3    80    42       14       15
Iğdır           19       0       0        0        2        0         1        17       3        0        0        0        0     89     0    38    19           7        5
Ardahan         18       0       0        0        1        0         0        12       1        0        0        0        0     50     0    21    11           5        3
Malatya         67       4   393          84       29       72        85   197      12       78           4    48       66       769     8   283   144       44       91
Elazığ          50      10    17          0        30       42    239      177          3        0    745     180       54       595    10   227   140       36       61
Bingöl          30       0       2        0        3        0         1        21       1        0        0    21           0     59     1    24    12       10           3
Tunceli         10       0       0        0        1        0         0        7        0        0        0    15           0     28     0    11        5        3        1




                                                                                                                                                                              91
Van             76       0     20      631          67       5         47       97       5   140           1    44           6    378     4   184    97       41       24
Muş             44       0        0        0        4        4         26       41       2        0        1        8        9    167     4    63    33       18       13
Bitlis          31       0        3        52       7        1         2        29       2        0        0    11           1     84     1    37    19       13           5
Hakkari         21       0     10          0        2        0         1        21       1        0        0        5        0     44     0    18        9    10           3




Table A. 9A Continued

                                                                                     WASTE GROUP ID
 PROVINCES      1    2        3        4        5        6         7        8        9       10       11       12       13       14      15   16    17       18       19
Gaziantep       95       3   2,136     634      381      166      1,604     867      138      23      216       85      156      2,571   20   936   511       93      348
Adıyaman        56       2    392          0        47       67    133      112          6        0        1    43       15       414     2   149    75       27       50
Kilis           10       0     10      108          18       1         30       21       1        0        0        0        0    147     0    67    34           5        9
Şanlıurfa      118       0    165          92       38       74        57   194          8   404      277       52       45      1,025    4   420   221       70       84
Diyarbakır     106       4     98      201          79       34    207      215          7        0    13      203       42       672     9   268   141       68       61
Mardin          58       0        9    339          54   116       129          78       4   120       53       56       11       283     2   133    72       32       21
Batman          34       0     34     2,096     189          3     127          60       3        0        0    65           0    189     3   179   106       19       11
Şırnak          29       0        0    337          30       0         7        37       2   427           0    13           0    152     0    81    44       17           9
Siirt           24       0     14          0        3        3         23       43       1   120           1    28           7     94     1    37    21       13       10




                                                                                                                                                                               92
Table A. 9B Hazardous waste groups in Turkish provinces in tons/yr

                                                WASTE GROUP ID
       PROVINCES
                       19       20       21     22    23     24     25    26      27     28
     Đstanbul         10,211   11,689   7,319   572   784   9,282   20   26,276   512   3,772
     Tekirdağ           752     1,177    646     35    36    471    3     1,434    64    219
     Edirne              65      115     135     10    28    324    0       63     14    119
     Kırklareli         110      546     269     12    21    262    1      177     19    100
     Balıkesir          270      889     470     36    84    964    2      519     33    335
     Çanakkale          127      779     333     20    37    426    2      340     16    143
     Đzmir             2,876    3,920   2,398   187   264   3,073   16    8,227   141   1,122
     Aydın              287      378     401     33    77    876    0      743     29    284
     Denizli            427      827     594     36    72    839    2      542     59    272
     Muğla              140      276     333     31    83    912    1      167     18    230
     Manisa            1,594     982     975     81   107   1,230   4     4,542    48    396
     Afyonkarahisar      91      354     220     17    39    464    0      166     19    210
     Kütahya             74      391     237     17    39    453    2       72     16    175
     Uşak                77      357     159     10    23    272    1       65     15    100
     Bursa             3,759    2,408   2,129   162   144   1,746   6    12,501   130    732
     Eskişehir          863      934     570     48    50    583    4     3,084    26    217
     Bilecik            174      252     205     13    11    139    1      621     10     61
     Kocaeli           2,544    5,984   1,888   128    59    782    22    8,763    66    431
     Sakarya            940      688     551     44    46    556    2     3,181    31    251
     Düzce              165      360     193     12    17    210    1      472     13     97
     Bolu               278      158     184     14    20    233    1      560     12     81
     Yalova              64      575      84     6     8     100    0      208     6      55
     Ankara            3,236    2,190   2,467   209   348   3,979   6     9,568   130   1,340
     Konya             1,081     877     950     80   125   1,466   3     3,668    59    588
     Karaman             43       96      95     7     17    193    0       74     10     68
     Antalya            441      743     801     72   184   2,023   2      739     45    537
     Isparta             73      145     172     12    32    371    0       71     12    126
     Burdur              72       81     122     10    24    271    0      162     7      75
     Adana              763     1,511    798     66   116   1,382   1     2,385    58    602
     Mersin             348      829     561     46   102   1,190   3      882     42    479
     Hatay              287     1,146    618     47    83    978    18     746     37    416
     Kahramanmaraş      219      167     252     17    35    465    0      468     37    301
     Osmaniye            67      113     124     11    26    311    1      123     11    136
     Kırıkkale          153      282     127     9     9     121    4      597     7      84
     Aksaray            182      126     134     12    18    220    0      662     10    110
     Niğde               63      164     103     7     17    205    0      141     10    100
     Nevşehir            44       88      91     8     19    220    0       77     7      84
     Kırşehir            27      249      79     5     10    128    1       57     6      67
     Kayseri            870      597     738     45    63    762    2     2,389    44    350
     Sivas              113      126     158     13    26    323    0      317     16    192
     Yozgat              61       91     111     8     19    238    0      118     14    148
     Zonguldak          114      411     343     23    30    365    25     296     19    185
     Karabük             44      658     159     11    12    144    7      111     8      66


                                                                                                93
Bartın              23    49    52    4    8    104   0     21   6     55
Table A. 9B Continued

                                          WASTE GROUP ID
      PROVINCES
                         19    20    21    22   23    24   25    26   27    28
     Kastamonu           82    99   130    9    22   262   0    126   10   108
     Çankırı             88    51    56    4    7     92   0    179   6     52
     Sinop               27    37    57    4    9    114   0     52   6     60
     Samsun             205   604   364    29   61   736   1    449   32   369
     Tokat               64   136   159    12   32   383   0     75   17   186
     Çorum              136   152   212    16   32   381   3    385   17   165
     Amasya              74    92   103    8    19   226   0    118   9     99
     Trabzon            121   133   166    13   27   354   0    326   20   222
     Ordu                58   138   128    9    21   285   1    103   19   215
     Giresun             34    57    76    6    14   180   0     55   10   125
     Rize                17   146   151    4    11   166   1     14   27    95
     Artvin              26    31    48    3    6     80   0     77   5     50
     Gümüşhane           6     24    19    2    4     51   0     5    3     39
     Erzurum             56   100   106    9    20   276   1    120   18   235
     Erzincan            16    38    46    4    10   125   0     17   5     64
     Bayburt             3     9     11    1    2     31   0     0    2     23
     Ağrı                8     30    35    3    6    119   0     0    12   159
     Kars                15    31    39    3    8    108   0     25   7     94
     Iğdır               5     14    18    2    4     61   0     0    4     55
     Ardahan             3     8     10    1    2     36   0     0    2     34
     Malatya             91   125   148    11   27   346   0     84   22   217
     Elazığ              61   113   113    9    19   243   0    120   13   162
     Bingöl              3     11    14    1    3     51   0     0    5     75
     Tunceli             1     5     6     1    1     20   0     0    2     25
     Van                 24    70    86    7    16   259   1     15   21   294
     Muş                 13    33    33    2    5     93   0     29   10   122
     Bitlis              5     16    20    2    4     70   0     2    7     98
     Hakkari             3     9     11    1    2     44   0     0    5     74
     Gaziantep          348   561   503    37   80   972   1    461   63   468
     Adıyaman            50    72    89    6    16   220   0     20   17   175
     Kilis               9     24    28    3    7     83   0     0    3     36
     Şanlıurfa           84   156   201    18   45   605   0     43   34   457
     Diyarbakır          61   147   139    11   23   384   0     96   33   438
     Mardin              21    63    65    5    12   195   1     20   16   224
     Batman              11    60    60    4    8    127   4     0    11   142
     Şırnak              9     29    40    3    7    116   1     0    9    125
     Siirt               21    2     3     61   0     22   6     87   21    2




                                                                                 94
Figure A. 2 Provincial distribution of pesticides and agrochemical hazardous wastes (ID No:1)




Figure A. 3 Provincial distribution of wood preservative wastes (ID No:2)




                                                                                                95
Figure A. 4 Provincial distribution of hazardous tannery wastes (ID No:3)




Figure A. 5 Provincial distribution of hazardous petroleum refining wastes (ID No:4)




                                                                                       96
Figure A. 6 Provincial distribution of acidic and alkaline wastes (ID No:5)




Figure A. 7 Provincial distribution of hazardous inorganic chemistry wastes (ID No:6)




                                                                                        97
Figure A. 8 Provincial distribution of hazardous organic chemistry wastes (ID No:7)




Figure A. 9 Provincial distribution of hazardous paint and sealant production wastes (ID No:8)




                                                                                             98
Figure A. 10 Provincial distribution of hazardous printing wastes (ID No:9)




Figure A. 11 Provincial distribution of hazardous energy production wastes (ID No:10)




                                                                                        99
Figure A. 12 Provincial distribution of hazardous metal production wastes (ID No:11)




Figure A. 13 Provincial distribution of hazardous mineral and glass production wastes (ID
No:12)




                                                                                       100
Figure A. 14 Provincial distribution of hazardous galvanizing wastes (ID No:13)




Figure A. 15 Provincial distribution of non-halogenated waste oil (ID No:14)




                                                                                  101
Figure A. 16 Provincial distribution of halogenated waste oil (ID No:15)




Figure A. 17 Provincial distribution of waste oil emulsions (ID No:16)




                                                                           102
Figure A. 18 Provincial distribution of other oily wastes (ID No:17)




Figure A. 19 Provincial distribution of halogenated solvents (ID No:18)




                                                                          103
Figure A. 20 Provincial distribution of non-halogenated solvents (ID No:19)




Figure A. 21 Provincial distribution of contaminated packagings (ID No:20)




                                                                              104
Figure A. 22 Provincial distribution of spent adsorbents and filter materials (ID No:21)




Figure A. 23 Provincial distribution of spent oil filters (ID No:22)




                                                                                           105
Figure A. 24 Provincial distribution of spent brake fluids and antifreeze (ID No:23)




Figure A. 25 Provincial distribution of spent batteries (ID No:24)




                                                                                       106
Figure A. 26 Provincial distribution of sludges from CPT (ID No:26)




Figure A. 27 Provincial distribution of mercury containing waste (ID No:27)




                                                                              107
Figure A. 28 Provincial distribution of contaminated wood (ID No:28)




Table A. 10 Range of disposal market prices (€/ton) - (Germany 2002 and Turkey 2007)

                DISPOSAL OPTION                                PRICE
         Hazardous waste landfills                    50 – 140 (Đzaydaş 70 – 120)
         Solidification and landfilling                        80 – 100
         CPT                                                   45 – 60
         Hazardous waste incineration                        100 – 1,200
             Liquid and pasty waste                           100 – 350
             Solid waste                                      200 – 300
             Drums and canisters                 300 – 1,200 (lab chemicals < 5,000)
             Total average                          200 – 300 (Turkey: 300 – 500)
         Cement kilns, Power station/plants           < 150 (Turkey: 200 – 300)
         Municipal solid waste incineration                     ≈ 100




                                                                                       108
Table A. 11 Structure of the price list for hazardous waste incineration in Turkey (2007)

                                                                            ĐZAYDAŞ      PETKĐM    EKOLOJĐK ENERJĐ
                                   WASTE TYPES
                                                                         TL/TON €/TON TL/TON €/TON TL/TON   €/TON
                LIQUID WASTES (Sludge ratio < 10%)
                Calorific value > 36,000 kj/kg                              70         40    70     40     --    --
                Calorific value > 32,000 kj/kg                              175        100   175    100    --    --
                Calorific value > 25,000 kj/kg                              300        170   300    170    --    --
                Calorific value > 18,000 kj/kg                              330        187   330    187    --    --
                Calorific value > 10,000 kj/kg                              710        403   710    403    --    --
                Calorific value < 10,000 kj/kg                              815        463   815    463    --    --
                Special liquid waste                                        980        557    --     --    --    --
                PASTY WASTE (Sludge ratio % 25 – 75)
                Calorific value > 18,000 kj/kg                              600        341   600    341   550    312
                Calorific value > 10,000 kj/kg                              775        440   775    440   700    398
                Calorific value < 10,000 kj/kg                              890        506   890    506   850    483
                Paint and phosphate sludges                                 540        307   540    307   500    284
                Treatment sludge
                SOLID WASTES (Sludge ratio >75%)
                Calorific value > 18,000 kj/kg                             1055        599   1055   599   1000   568
                Calorific value > 10,000 kj/kg                             1370        778   1370   778   1200   682
                Calorific value < 10,000 kj/kg                             1500        852   1500   852   1300   739
                Waste car cycle                                             --                --
                Mastic                                                      --                --
                Contaminated wastes (packages, cloth, toner etc.)          1000        568   1000   568    900   511
                Drums which contained isocyanide                           1610        915    --          1600   909
                Pharmaceutical wastes ( product – same product)            1370        778    --          1250   710
                Wastes which will be burned within drums                   1610        915    --            --



                                                                                                                       109
Table A. 11 Continued

                                                                           ĐZAYDAŞ      PETKĐM    EKOLOJĐK ENERJĐ
                              WASTE TYPES
                                                                        TL/TON €/TON TL/TON €/TON TL/TON   €/TON
        EXTRA COST FOR WASTES SHICH WILL BE BURNED
        Extra costs for halogen and phosphorus
        Between 1 – 5 %                                                   77     44     77     44    --
        Up to 10 %                                                       120    68     120     68    --
        Up to 20 %                                                       320    182    320    182    --
        Up to 30 %                                                       540    307    540    307    --
        Up to 40 %                                                       760    432    760    432    --
        Up to 50 %                                                       955    543    955    543    --
        Extra costs for sulphur
        Between 2 – 5 %                                                  165    94     165     94    --
        Up to 10 %                                                       418    237    418    237    --
        HAZARDOUS WASTE LANDFILL
        Dangerous solid wastes                                           200    114    --            --
        Inert industrial wastes                                          130    74     --            --
        Industrial wastes which can be depoined with municipal wastes    150     85    --            --
        Municipal wastes from industry                                    35     20    --            --
        Surface deponie                                                  220    125    --            --
        SPECIAL PROCESSES
        Fluorescent lamps                                                380    216    --            --
        Accumulators                                                     380    216    --            --
        Batteries                                                        380    216    --            --
        Pressure cups                                                    1240   705    --            --




                                                                                                                    110
Table A. 12 Structure of disposal prices for CPT treatment from Germany (HIM 2002)

   OIL WATER MIXTURES (CHEMICALLY SEPARABLE):                              UNIT        €
   Sludge content < 2%                                                      t         60
   Sludge content < 10%                                                     t         85
   Sludge content < 20%                                                     t        150
   Sludge content < 30%                                                     t        220
   Photo chemicals                                                          t        190
   OIL/WATER SEPARATOR CONTENTS, WASTES FROM GRIT/SAND CHAMBERS:
   Sludge content < 5%                                 t      70
   Sludge content < 15%                                t      90
   Sludge content < 30%                                t     120
   Sludge content < 50%                                t     290
   Sludge content > 50%                                t     450
   INORGANIC CONTAMINATED WASTE WATER:
   Waste water ph 6-9                                  t      60
   Waste water ph 2-6 and 9-12,5                       t      75
   Acids and alkaline solutions < 5%                   t      95
   Acids and alkaline solutions < 20%                  t     160
   Acids and alkaline solutions < 30%                  t     200
   Acids and alkaline solutions > 30% per expenditure  t
   SURCHARGES FOR DETOXIFICATION OF CYANIDE, CHROMATE, NITRITE:
   < 100 mg/l                                          t      25
   < 500 mg/l                                          t      40
   < 1 g/l                                             t      70
   < 10 g/l                                            t     120
   > 10 mg/l per expenditure                           t
   SURCHARGES FOR SULPHATE TREATMENT:
   > 1,5 g/l                                           t      40
   > 3 g/l                                             t      60
   > 10 g/l                                            t      80
   > 20 g/l                                            t     170
   > 50 g/l per expenditure                            t
   SURCHARGES FOR SLUDGE AFTER NEUTRALISATION:
   < 10%                                               t      60
   < 25%                                               t     130
   < 50%                                               t     200
   < 75%                                               t     280
   > 75%                                               t     370
   SURCHARGES FOR TREATMENT OF ORGANIC SOLVENTS (INCL. HALOGENATED):
   > 1 mg/l                                                                  t        30
   > 10 mg/l                                                                 t        40
   > 20 mg/l                                                                 t        90
   50 mg/l – 100 mg/l                                                        t       170
   > 50 mg/l per expenditure                                                 t


                                                                                           111
Table A. 13 Assignment of hazardous waste to disposal options 11

                            HAZARDOUS WASTE                                                           DISPOSAL / RECOVERY OPTION [%]

                                                                                Direct    Solidification for                         Material   Thermal
     EWC                                Type of waste                                                          CPT    Incineration
                                                                               Landfill     Landfilling                              Recovery   Recovery

     020108     agrochemical waste containing dangerous substances               10               0              0        90            0          0
030201to03      organic wood preservatives                                        0               0              0        100           0          0
     030204     inorganic wood preservatives                                      0               0             100        0            0          0
                degreasing wastes containing solvents without a liquid
     040103                                                                       0               0              0        100           0
                phase
     040214     wastes from finishing containing organic solvents                 0               0              0        50            0          50
     040216     dyestuffs and pigments containing dangerous substances            0               0              0        50            0          50
                sludges from on-site effluent treatment containing dangerous
     040219                                                                       0               0              0        100           0          0
                substances
050102to09      oil sludges from petroleum refining                               0               0             50        50            0          0
     050115     spent filter clays                                               20               0              0        80            0          0
     060101     sulphuric acid and sulphurous acid                                0               0             100        0            0          0
     060404     wastes containing mercury                                         0               0             100        0            0          0
     060405     wastes containing other heavy metals                              0               0             100        0            0          0
                sludges from on-site effluent treatment containing dangerous
     060502                                                                       0               0             100        0            0          0
                substances
                Wastes from Inorganic Chemical Processes (without 060101
     060xxx                                                                      15              20             60         5            0          0
                and 060502)
     061002     wastes containing dangerous substances                           20              20             60         0            0          0
                wastes from the manufacture, formulation, supply and use
070101to10                                                                        0               0             25        50            0          25
                (MFSU) of basic organic chemicals




11   Destatis Federal Statistical Office of Germany and other sources.



                                                                                                                                                        112
sludges containing dangerous substances from other
 070111                                                                              0                0              50          50              0            0
              treatment of industrial waste water

Table A. 13 Continued

                                HAZARDOUS WASTE                                                               DISPOSAL / RECOVERY OPTION [%]
                                                                                            Direct    Solidification for                         Material   Thermal
   EWC                                       Type of waste                                                                 CPT    Incineration
                                                                                           Landfill     Landfilling                              Recovery   Recovery
0703nonhalog    wastes from the MFSU of organic dyes and pigments (non halogenated)           0               0            50         50             0            0
   070701       aqueous washing liquids and mother liquors                                    0               0            100         0             0            0

                Wastes from Organic Chemical Processes: MFSU of plastics, synthetic
                rubber, pharmaceuticals, fats, grease, soaps, detergents, disinfectants,
 070x01to10                                                                                   0               0            10         50             10        30
                cosmetics, fine chemicals and chemical products not otherwise specified
                (0702, 0704, 0705, 0706, 070701-10)

                sludges containing dangerous substances from other treatment of
   070x11                                                                                     0              35            40         25             0            0
                industrial waste water (0702, 0704, 0705, 0706, 070711)

                waste paint and varnish containing organic solvents or other dangerous
   080111                                                                                     0               0            35         40             15        10
                substances

                sludges from paint or varnish containing organic solvents or other
   080113                                                                                     0               0            15         75             5            5
                dangerous substances

                wastes from paint or varnish removal containing organic solvents or
   080117                                                                                     0               0            60         25             10           5
                other dangerous substances
   080312       waste ink containing dangerous substances                                     0               0            50         35             10           5
   080314       ink sludges containing dangerous substances                                   0               0            30         30             20        20
                waste adhesives and sealants containing organic solvents or other
   080409                                                                                     0               0            30         40             15        15
                dangerous substances

                adhesive and sealant sludges containing organic solvents or other
   080411                                                                                     0               0            45         45             5            5
                dangerous substances
   090101       water-based developer and activator solutions                                 0               0            90         10             0            0
   090102       water-based offset plate developer solutions                                  0               0            75         25             0            0



                                                                                                                                                                      113
090103        solvent-based developer solutions                                   0                0          0         100           0            0
   090104        fixer solutions                                                     0                0          0          0            100          0
Table A. 13 Continued

                          HAZARDOUS WASTE                                                        DISPOSAL / RECOVERY OPTION [%]
                                                                           Direct    Solidification for                          Material      Thermal
    EWC                                 Type of waste                                                     CPT    Incineration
                                                                          Landfill     Landfilling                               Recovery      Recovery
   090105         bleach solutions and bleach fixer solutions                0               0             100        0             0             0
                  wastes containing silver from on-site treatment of
   090106                                                                    0               0              0         0            100            0
                  photographic wastes
   100104         oil fly ash and boiler dust                               20              80              0         0             0             0
   100109         sulphuric acid                                             0               0             100        0             0             0
                  bottom ash, slag and boiler dust from co-incineration
   100114                                                                   100              0              0         0             0             0
                  containing dangerous substances
                  fly ash from co-incineration containing dangerous
   100116                                                                   100              0              0         0             0             0
                  substances
                  wastes from gas cleaning containing dangerous
   100118                                                                   100              0              0         0             0             0
                  substances
                  sludges from on-site effluent treatment containing
 100120and22                                                                 0              50             50         0             0             0
                  dangerous substances
   1002xx         wastes from the iron and steel industry                   40              30             30         0             0             0
   1003xx         wastes from aluminium thermal metallurgy                  50              45              0         0             5             0
                  slags, dross and skimmings from primary and
  100401to02                                                                20               0              0         0             80            0
                  secondary production
   100404         flue-gas dust                                              0               0              0         0            100            0
   1004xx         wastes from lead thermal metallurgy                       20               0              0         0             80            0
   1005xx         wastes from zinc thermal metallurgy                       100              0              0         0             0             0
   1006xx         wastes from copper thermal metallurgy                     100              0              0         0             0             0
   1007xx         wastes from other non-ferrous thermal metallurgy          100              0              0         0             0             0
                  casting cores and moulds which have (not) undergone
100905,07and09    pouring containing                                        70              10              0         0             20            0
                  dangerous substances



                                                                                                                                                          114
casting cores and moulds which have (not) undergone
101005,07and09   pouring containing                                        100             0            0        0             0          0
                 dangerous substances
Table A. 13 Continued

                         HAZARDOUS WASTE                                                        DISPOSAL / RECOVERY OPTION [%]
                                                                            Direct    Solidification for                    Material   Thermal
   EWC                                Type of waste                                                       CPT Incineration
                                                                           Landfill     Landfilling                         Recovery   Recovery
              wastes from asbestos-cement manufacture containing
101309and12                                                                  100               0         0        0            0          0
              asbestos and solid wastes from gas treatment
110105to07    pickling acids and basis and other acids                        0                0        100       0            0          0
  110108      phosphatising sludges                                           5             80           15       0            0          0
  110109      sludges and filter cakes containing dangerous substances        5             80           15       0            0          0
              sludges from zinc hydrometallurgy (including jarosite,
  110202                                                                     90             10           0        0            0          0
              goethite)
              wastes from copper hydrometallurgical processes containing
  110205                                                                     50                0         0        0            50         0
              dangerous substances
  110301      wastes containing cyanide                                      80                0         20       0            0          0
              mineral-based machining oils containing halogens (except
  120106                                                                      0                0         50       30           20         0
              emulsions and solutions)
              mineral-based machining oils free of halogens (except
  120107                                                                      0                0         0        0            50         50
              emulsions and solutions)
  120108      machining emulsions and solutions containing halogens
  120109      machining emulsions and solutions free of halogens              0                0        100       0            0          0
  120110      synthetic machining oils                                        0                0         0        0            50         50
  120112      spent waxes and fats                                            0                0         0        50           0          50
  120114      machining sludges containing dangerous substances               5             25           25       25           0          20
  120301      aqueous washing liquids                                         0                0        100       0            0          0
  120302      steam degreasing wastes                                         0                0        100       0            0          0
  13 01 01    hydraulic oils, containing PCBs                                 0                0         0        70           30         0
  13 01 04    chlorinated emulsions                                           0                0         0        70           30         0




                                                                                                                                               115
13 01 05      non-chlorinated emulsions                                           0               0              0         0            50         50
  13 01 09      mineral-based chlorinated hydraulic oils                            0               0              0        70            30          0
  13 01 10      mineral based non-chlorinated hydraulic oils                        0               0              0         0            50         50
Table A. 13 Continued

                             HAZARDOUS WASTE                                                            DISPOSAL / RECOVERY OPTION [%]
                                                                                    Direct    Solidification for                        Material   Thermal
   EWC                                     Type of waste                                                           CPT   Incineration
                                                                                   Landfill     Landfilling                             Recovery   Recovery
  13 01 11      synthetic hydraulic oils                                                0               0           0         0            50         50
  13 01 12      readily biodegradable hydraulic oils                                    0               0           0         0            50         50
  13 01 13      other hydraulic oils                                                    0               0           0         0            50         50
  13 02 04      mineral-based chlorinated engine, gear and lubricating oils             0               0           0        70            30         0
                mineral-based non-chlorinated, synthetic, readily biodegradable
130205to08                                                                              0               0          10         0            50         40
                and other engine, gear and lubricating oils
  13 03 01      insulating or heat transmission oils containing PCBs                    0               0           0        70            30         0
                mineral-based chlorinated insulating and heat transmission oils
  13 03 06                                                                              0               0           0        70            30         0
                other than those mentioned in 13 03 01

                mineral-based, synthetic, readily biodegradable and other non-
13 03 07to 10                                                                           0               0           0         0            50         50
                chlorinated insulating and heat transmission oils
                bilge oils from inland navigation, jetty sewers and from other
13 04 01to 03                                                                           0               0           0         0            50         50
                navigation
   130501       solids from grit chambers and oil/water separators                      15              0          85         0            0          0
130502to03      sludges from oil/water separators and interceptor sludges               0               0          100        0            0          0
                oil and oily water from oil/water separators, mixtures of wastes
13 05 06to08                                                                            0               0           0         0            50         50
                from grit chambers and oil/water separators
13 07 01to 03   fuel oil, diesel, petrol and other fuels (including mixtures)           0               0           0         0            50         50
   130802       other emulsions                                                         0               0          100        0            0          0
   140601       chlorofluorocarbons, HCFC, HFC                                          0               0           0        10            90         0
   140602       other halogenated solvents and solvent mixtures                         0               0           0        50            50         0




                                                                                                                                                           116
140603         other solvents and solvent mixtures                                      0               0              0        20            30         50
  140604         sludges or solid wastes containing halogenated solvents                  0               0              0        70            30          0
  140605         sludges or solid wastes containing other solvents                        0               0              0        70            0          30
Table A. 13 Continued

                              HAZARDOUS WASTE                                                                 DISPOSAL / RECOVERY OPTION [%]
                                                                                          Direct    Solidification for                        Material   Thermal
EWC                                     Type of waste                                                                    CPT   Incineration
                                                                                         Landfill     Landfilling                             Recovery   Recovery
         packaging containing residues of or contaminated by dangerous
150110                                                                                        10              0           0        80            10         0
         substances
         absorbents, filter materials (including oil filters not otherwise specified),
150202   wiping cloths, protective clothing contaminated by dangerous                         10              0           0        90            0          0
         substances
160107   oil filters                                                                          0               0           0         0           100         0
160113   brake fluids                                                                         0               0           0         0           100         0
160114   antifreeze fluids containing dangerous substances                                    0               0           0         0           100         0
         laboratory chemicals, consisting of or containing dangerous substances,
160506                                                                                        0               0          30        70            0          0
         including mixtures of laboratory chemicals
160601   lead batteries                                                                       0               0           0         0           100         0
160606   separately collected electrolyte from batteries and accumulators                     0               0          100        0            0          0
         spent catalysts containing dangerous transition metals or dangerous
160802                                                                                        10              0           0         5            85         0
         transition metal compounds

         sludges containing dangerous substances from other treatment of
190813                                                                                        20           50             0        30            0          0
         industrial waste water
200113   solvents                                                                             0               0           0        100           0          0
200114   acids                                                                                0               0          100        0            0          0
200115   alkalines                                                                            0               0          100        0            0          0
200117   photochemicals                                                                       0               0          100        0            0          0
200119   pesticides                                                                           0               0           0        100           0          0
200121   fluorescent tubes and other mercury-containing waste                                 0               0           0         0           100         0




                                                                                                                                                                117
200123   discarded equipment containing chlorofluorocarbons                             0               0         0          0           100        0
200126   oil and fat other than those mentioned in 20 01 25                             0               0         0          0           50         50
200127   paint, inks, adhesives and resins containing dangerous substances              0               0         0         100           0         0




Table A. 13 Continued

                           HAZARDOUS WASTE                                                           DISPOSAL / RECOVERY OPTION [%]
                                                                                  Direct    Solidification for                        Material   Thermal
EWC                                  Type of waste                                                               CPT   Incineration
                                                                                 Landfill     Landfilling                             Recovery   Recovery
200129   detergents containing dangerous substances                                 0               0             0        100           0          0
200131   cytotoxic and cytostatic medicines                                         0               0             0        100           0          0
         batteries and accumulators included in 16 06 01, 16 06 02 or 16 06 03
200133                                                                             50               0             0         0            50         0
         and unsorted batteries and accumulators containing these batteries

         discarded electrical and electronic equipment other than those
200135                                                                              0               0             0         0            0          0
         mentioned in 20 01 21 and 20 01 23 containing hazardous components
200137   wood containing dangerous substances                                       0               0             0         0            0         100




                                                                                                                                                         118
119
Figure A. 29 Recommended hazardous waste disposal routes to recycling/recovery – amount per
province




                                                                                       120
Figure A. 29 Continued




                         121
Figure A. 30 Recommended hazardous waste disposal routes to CPT – amount per province




                                                                                        122
Figure A. 30 Continued




                         123
Figure A. 31 Recommended hazardous waste disposal routes to thermal treatment – amount per
province




                                                                                      124
Figure A. 31 Continued




                         125
Figure A. 32 Recommended hazardous waste disposal routes to controlled landfill – amount per
province




                                                                                        126
Figure A. 32 Continued



                         127
128
 
Tehlikeli Atıkların Sınıflandırılması Kılavuzu          Cilt I 

    




                                                              
                                                            1 

A3 concept final_version

  • 1.
                                            TASK A3    HAZARDOUS WASTE MANAGEMENT  CONCEPT FOR TURKEY     
  • 2.
    IMPROVEMENT OF INDUSTRIALHAZARDOUS WASTE MANAGEMENT IN TURKEY LIFE “HAWAMAN” PROJECT LIFE06/TCY/TR/000292 TASK A3 HAZARDOUS WASTE MANAGEMENT CONCEPT FOR TURKEY
  • 3.
    TABLE OF CONTENTS 1INTRODUCTION ..................................................................................................... 1 2 LEGISLATIVE FRAMEWORK AND STAKEHOLDERS OF HAZARDOUS WASTE MANAGEMENT ...................................................................................... 9 2.1 LEGISLATIVE FRAMEWORK ................................................................................. 9 2.2 STAKEHOLDERS OF HAZARDOUS WASTE MANAGEMENT ..................... 17 3 DEVELOPMENT OF HAZARDOUS WASTE MANAGEMENT SYSTEM IN TURKEY ................................................................................................................. 19 4 CURRENT SITUATION OF HAZARDOUS WASTE MANAGEMENT IN TURKEY ................................................................................................................. 24 5 HAZARDOUS WASTE MANAGEMENT CONCEPT ....................................... 28 5.1 HAZARDOUS WASTE QUANTITY ESTIMATION ........................................... 28 5.1.1 Methodology ..................................................................................................................... 29 5.1.2 Waste estimation .............................................................................................................. 34 5.1.3 Comparison and validation of results .............................................................................. 45 5.2 ASSIGMENT OF HAZARDOUS WASTE TYPES TO DISPOSAL OPTIONS . 48 5.2.1 Methodology ..................................................................................................................... 48 5.2.2 Allocation to Different Disposal Routes .......................................................................... 53 6 CONCLUSIONS...................................................................................................... 59 7 . RECOMMENDATONS........................................................................................ 62 APPENDIX ................................................................................................................. 65 ii
  • 4.
    LIST OF TABLES Table1.1: Contribution of basic economic sectors to GDP (based on current prices) 2 .............................. 5 Table 2.1 List of Turkish legislation on hazardous wastes .................................................................................... 9 Table 4.1 Number of plants and recycle/recovery activities (June 2007)......................................................25 Table 4.2 Types of recyclable wastes admitted to licensed recycling facilities and their capacities... 25 Table 4.3 Wastes used as alternative fuels in cement factories .........................................................................26 Table 4.4 Current capacities of disposal facilities ...................................................................................................27 Table 4.5 Integrated Waste Disposal Facilities ........................................................................................................27 Table 5.1 Covered and omitted waste types and producers ................................................................................34 Table 5.2 List of industrial sector groups ...................................................................................................................37 Table 5.3 Sample waste sector sheet for metal working industry ....................................................................37 Table 5.4 Description and amount of hazardous waste groups in tons/yr ...................................................40 Table 5.5 Geographic distribution of hazardous wastes (1000 tons/yr) .......................................................42 Table 5.6 Comparison of Turkish and German hazardous waste generation ..............................................45 Table A. 1 List of NUTS codes for Turkey ....................................................................................................................65 Table A. 2 Turkish population (2007) ..........................................................................................................................66 Table A. 3 Number of employees in Turkish industry (2007) ..............................................................................69 Table A. 4 Additional information for provinces ......................................................................................................70 Table A. 5 Hazardous waste in Turkey, from industry and other sources in tons/yr ................................72 Table A. 6 Hazardous waste from main industrial sectors in tons/yr .............................................................74 Table A. 7 Hazardous waste from non-industrial sources in tons/yr ..............................................................76 Table A. 8 Hazardous waste from industrial branches in tons/yr ....................................................................78 Table A. 9 Hazardous waste groups in Turkish provinces in tons/yr ..............................................................88 Table A. 10 Range of disposal market prices (€/ton) - (Germany 2002 and Turkey 2007)................. 107 Table A. 11 Assignment of hazardous waste to disposal options .................................................................. 111 Table A. 12 Structure of the price list for hazardous waste incineration in Turkey (2007) ................ 108 Table A. 13 Structure of disposal prices for CPT treatment from Germany (HIM 2002) ...................... 110 iii
  • 5.
    LIST OF FIGURES Figure1.1: Chronology of Population Growth, Turkey ............................................................................................ 2 Figure 1.2: Population Pyramid, Turkey (2006) ........................................................................................................ 2 Figure 1.3 Distribution of Population in Turkey ....................................................................................................... 3 Figure 1.4 Chronology of GNP of Turkey ....................................................................................................................... 4 Figure 1.5 Chronology of Inflation Rate of Turkey .................................................................................................... 4 Figure 1.6 Employees in Turkish Industry, total ........................................................................................................ 6 Figure 1.7 Employees in Turkish Metal Industry ....................................................................................................... 7 Figure 1.8 Employees in Turkish Chemical Industry ................................................................................................ 7 Figure 1.9 Employees in Turkish Other Industries .................................................................................................... 8 Figure 2.1 Steps to be followed to determine a hazardous waste according to RCHW ............................12 Figure 2.2 Main duties, responsibilities and jurisdiction in the hazardous waste management system .....................................................................................................................................................................................................18 Figure 3.1 Hazardous waste management regions ................................................................................................20 Figure 5.1 Production in 1 or 3 facilities: material balance differs by factor three ...................................30 Figure 5.2 Hazardous waste generation in Turkey, total .....................................................................................43 Figure 5.3 Hazardous Waste Generation in Industry (81 %) .............................................................................43 Figure 5.4 Hazardous Waste Generation from separately collected waste (19 %) ...................................44 Figure 5.5 Hazardous waste amounts in several countries versus GNP “power parity” ..........................47 Figure 5.6 Recommended hazardous waste disposal routes for Turkey – overview .................................54 Figure 5.7 Recommended hazardous waste disposal routes to recycling/recovery ..................................54 Figure 5.8 Recommended hazardous waste disposal routes to CPT ................................................................55 Figure 5.9 Recommended hazardous waste disposal routes to thermal treatment ..................................55 Figure 5.10 Recommended hazardous waste disposal routes to controlled landfill .................................56 Figure 5.11 Scheme of a fully integrated hazardous waste treatment / disposal facility .......................58 Figure 6.1 Five recommended planning areas for integrated hazardous waste treatment facilities 61 Figure 6.2 Locations of 189 mostly private operating hazardous waste treatment facilities in Turkey .....................................................................................................................................................................................................61 Figure 7.1 Locations and numbers of municipal sewage treatment plants in Turkey ..............................63 Figure A. 1 Number of employees in Turkish Industry (2007) ...........................................................................67 Figure A. 2 Provincial distribution of pesticides and agrochemical hazardous wastes (ID No:1) .......94 Figure A. 3 Provincial distribution of wood preservative wastes (ID No:2) ..................................................94 Figure A. 4 Provincial distribution of hazardous tannery wastes (ID No:3) .................................................95 Figure A. 5 Provincial distribution of hazardous petroleum refining wastes (ID No:4) ...........................95 Figure A. 6 Provincial distribution of acidic and alkaline wastes (ID No:5) .................................................96 Figure A. 7 Provincial distribution of hazardous inorganic chemistry wastes (ID No:6) ........................96 Figure A. 8 Provincial distribution of hazardous organic chemistry wastes (ID No:7) ............................97 Figure A. 9 Provincial distribution of hazardous paint and sealant production wastes (ID No:8) ......97 Figure A. 10 Provincial distribution of hazardous printing wastes (ID No:9)..............................................98 Figure A. 11 Provincial distribution of hazardous energy production wastes (ID No:10) ......................98 Figure A. 12 Provincial distribution of hazardous metal production wastes (ID No:11) ........................99 Figure A. 13 Provincial distribution of hazardous mineral and glass production wastes (ID No:12) 99 Figure A. 14 Provincial distribution of hazardous galvanizing wastes (ID No:13) ................................. 100 Figure A. 15 Provincial distribution of non-halogenated waste oil (ID No:14) ........................................ 100 iv
  • 6.
    Figure A. 16Provincial distribution of halogenated waste oil (ID No:15).................................................. 101 Figure A. 17 Provincial distribution of waste oil emulsions (ID No:16) ....................................................... 101 Figure A. 18 Provincial distribution of other oily wastes (ID No:17) ............................................................ 102 Figure A. 19 Provincial distribution of halogenated solvents (ID No:18) ................................................... 102 Figure A. 20 Provincial distribution of non-halogenated solvents (ID No:19) .......................................... 103 Figure A. 21 Provincial distribution of contaminated packagings (ID No:20) ......................................... 103 Figure A. 22 Provincial distribution of spent adsorbents and filter materials (ID No:21) ................... 104 Figure A. 23 Provincial distribution of spent oil filters (ID No:22) ................................................................ 104 Figure A. 24 Provincial distribution of spent brake fluids and antifreeze (ID No:23)............................ 105 Figure A. 25 Provincial distribution of spent batteries (ID No:24) ................................................................ 105 Figure A. 26 Provincial distribution of sludges from CPT (ID No:26) ........................................................... 106 Figure A. 27 Provincial distribution of mercury containing waste (ID No:27) ......................................... 106 Figure A. 28 Provincial distribution of contaminated wood (ID No:28)...................................................... 107 Figure A. 29 Recommended hazardous waste disposal routes to recycling/recovery – amount per province ................................................................................................................................................................................. 119 Figure A. 30 Recommended hazardous waste disposal routes to CPT – amount per province .......... 121 Figure A. 31 Recommended hazardous waste disposal routes to thermal treatment – amount per province ................................................................................................................................................................................. 123 Figure A. 32 Recommended hazardous waste disposal routes to controlled landfill – amount per province ................................................................................................................................................................................. 125 v
  • 7.
    1 INTRODUCTION Fundamentals of hazardous waste management are laid down on various policy and legislative documents. International principles on which hazardous waste management concept is developed include “Precautionary Principle”, “Waste Hierarchy” and “Polluter Pays”. These principles are embedded in legislative documents according to which modern hazardous waste management systems are developed and successfully established. Turkish Regulation on Control of Hazardous Wastes (RCHW)1, harmonized with Directive of European Commission on hazardous wastes (91/689/EEC), being the core regulation on hazardous waste management, also includes these principles of hazardous waste management. Even though baseline of hazardous waste management is presented, it is essential to develop an elaborate hazardous waste management concept for Turkey in order for the waste management system to be realistic and efficient. This concept should especially consider practical aspects unique to Turkey. Hazardous waste management concept presented in this report is developed under Task A and Task C of LIFE HAWAMAN Project by German Experts, Turkish Experts and Ministry of Environment and Forestry (MoEF). In the context of this report, in Chapter 2, legislative framework concerning hazardous wastes, in Chapter 3, current situation of hazardous waste management and stakeholders of the system and in Chapter 4, hazardous waste management concept as developed by LIFE Team are introduced. Before presenting hazardous waste management concept, it is quite useful for the reader to acquire some background information on Turkey. These include demographic and economic information both of which influences hazardous waste generation amounts and distribution. Population of Turkey shows a rapid increase since the 1960s. As seen in Figure 1.1, population increased from about 30 Million in 1960s to about 71 Million in 2007 with a smooth turning range in the 1980s. Simple statistical analysis proves that population growth of Turkey resembles arithmetic growth model with a nice linear fit of r2= 0.997. 1 Official Gazette, 14/3/2005, No. 25755. 1
  • 8.
    Figure 1.1: Chronologyof Population Growth, Turkey In Figure 1.2, population pyramid of Turkey is given. The shape of the population pyramid looks sustainable at present with a high percentage of younger people compared with a small percentage of older people. This shape of the pyramid suggests high potential for productivity as result of high number of younger people thus high number of work force. Figure 1.2: Population Pyramid, Turkey (2006) 2
  • 9.
    Figure 1.3 belowand Table A. 2 in Appendix present the countrywide distribution of population. The major center of gravity of the Turkish population by far is Đstanbul, with more than 12 Million people. Very low populated districts are to be found in the eastern part of Turkey, like Tunceli or Bayburt (each much less than 100 000 people). Figure 1.3 Distribution of Population in Turkey 2 As mentioned before another important set of background information is the economic figures. Gross National Product (GNP) is the total monetary value of all final goods and services produced for consumption in society during a particular time period and a very strong parameter indicating economic activity. Within the last decade there is a remarkable increase in GNP (Figure 1.4), along with a strong decrease of the inflation rate (consumer prices) (Figure 1.5). Apparent from Figure 1.4 and Figure 1.5, Turkish economy between the years 2002-2007 has shown significant improvement. Average growth of economy reached up to 7% and increase in export reached 23% 3. 2 List of NUTS codes used throughout the report is given in Table A. 1 in Appendix. 3 The Union of Chambers and Commodity Exchanges of Turkey (TOBB), Economy Report 2008, Available from http://www.tobb.org.tr/yayinlar/64gk/ekonomik%20rapor.pdf , Data retrieved May 22, 2009 3
  • 10.
    Figure 1.4 Chronologyof GNP of Turkey Turkey - Inflation Rate in % 70 60 50 40 30 20 10 8.5% Source: Index Mundi (2008) 0 2000 2002 2004 2006 2008 Figure 1.5 Chronology of Inflation Rate of Turkey This rapid development in economy has ceased in 2007 due to the effects of global economic crisis. As a result, the average growth in the economy was 4.7% in 2007, 3.6% in the first nine months of 2008, and 1.1% in whole year of 2008 3. In Table 1.1, contribution of economic sectors to gross domestic product (GDP) is given. 4
  • 11.
    Table 1.1: Contributionof basic economic sectors to GDP (based on current prices) 3 CONTRIBUTION TO GDP SECTOR (%) 2006 2007 2008 Agriculture, hunting and forestry 8.0 7.4 7.6 Fishing 0.2 0.2 0.2 Mining and quarrying 1.2 1.2 1.4 Manufacturing Industry 17.2 16.8 16.1 Electricity, gas, steam and hot water generation and 1.8 1.9 2.1 distribution Construction 4.7 4.9 4.7 Wholesale and retail commerce 12.5 12.2 12.2 Hotels and restaurants 2.2 2.3 2.3 Transportation, storage and communication 13.7 13.9 14.2 Activities of financial factors 2.9 3.2 3.5 Residence ownership 9.8 10.8 11.2 Real estate renting and other activities 3.7 4.1 4.3 Public administration, defense and mandatory social 3.9 3.9 3.8 security Education 2.8 2.9 2.9 Health and social services 1.6 1.6 1.6 Other social, public and individual services 1.7 1.7 1.7 Domestic employment 0.2 0.2 0.2 Indirect factoring and taxes 14.6 13.6 13.3 TOTAL 100 100 100 Among the manufacturing industry, food and beverage sector and textile sector have the highest share in Turkey. According to Turkish Prime Ministry State Planning Organization (SPO) food industry has a share of 18 – 20% in the overall manufacturing industry in terms of production value4. Whereas the textile industry occupies 10% of the GNP of Turkey that is 319 billions US $ 5. With regard to population, the quota of employees in the Turkish industry is overall about 3 % which is about 4.6 % in Đstanbul. Relating to the total number of employees in Turkey, the biggest number of employees can be ascertained in 4 T.R. Prime Ministry State Planning Organization (SPO). IXth Development Plan Food Industry Special Commission Report. Ankara: 2007 5 T.R. Prime Ministry State Planning Organization (SPO). IXth Development Plan Textile, Leather and Clothing Industry Special Commission Report. Ankara: 2007 5
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    Đstanbul - about27 %, followed by Bursa (8.3 %), Đzmir (7.1 %), Kocaeli (5.1 %) and Ankara (5.0 %). All other districts are below 5 %. From Figure 1.6 to Figure 1.9, the distribution of employees according to provinces (NUTS3 level) is given. Moreover, in Table A. 3 and Figure A. 1 in Appendix exact numbers of employees in every province and according to major industrial braches can be found. The number of employees is a measure of industrial activity – and is therefore a rough measure of hazardous waste generation. Hence it is most likely to find the hazardous waste centers in the high-industrialized districts – especially in the Metal Industry and the Chemical Industry. Figure 1.6 Employees in Turkish Industry, total 6
  • 13.
    Figure 1.7 Employeesin Turkish Metal Industry Figure 1.8 Employees in Turkish Chemical Industry 7
  • 14.
    Figure 1.9 Employeesin Turkish Other Industries 8
  • 15.
    2 LEGISLATIVE FRAMEWORK AND STAKEHOLDERS OF HAZARDOUS WASTE MANAGEMENT 2.1 LEGISLATIVE FRAMEWORK International framework for hazardous wastes is shaped by Basel Convention on Control and Supervision of the Transboundary Shipment of Hazardous Waste that has been ratified by Turkey. National legislative framework regarding hazardous wastes is comprised of legislations regarding general rules for waste management and hazardous wastes and legislations regarding management of specific types of wastes. Legislations on specific types of wastes are in compliance with the fundamental rules laid down in legislations handling general management concepts. In Table 2.1, a list of legislations related to hazardous wastes and their counterparts in European Union (EU) Acquis is provided Table 2.1 List of Turkish legislation on hazardous wastes TURKISH LEGISLATION EU COUNTERPART Regulation on General Principles of Waste Directive 2006/12/EC on waste Management Regulation on Control of Hazardous Directive 91/689/EEC on hazardous waste Wastes Directive 75/439/EEC on the disposal of Regulation on Control of Waste Oils waste oils Regulation on Control of Waste Vegetable Oils Directive 2006/66/EC on batteries and Regulation on the Control of Used accumulators and waste batteries and Batteries and Accumulators accumulators Regulation on the Control of Packaging Directive 94/62/EC on packaging and and Packaging Waste packaging waste Regulation for Control of the Tyres Which Have Completed Their Life-Cycles (TCL) Regulation on the Restriction of the use of Directive 2002/95/EC on the restriction of the Certain Hazardous Substances in use of certain hazardous substances in Electrical and Electronic Equipment electrical and electronic equipment Regulation for Control of Medical Waste Regulation on Control of Polychlorinated Directive 96/59/EC on the disposal of Biphenyls and Polychlorinated polychlorinated biphenyls and Terphenyls polychlorinated terphenyls (PCB/PCT) Regulation on Control of End-Of-Life Directive 2000/53/EC on End-Of-Life Vehicles (Draft) Vehicles Regulation on Landfill of Waste (Draft) Directive 1999/31/EC on the landfill of waste Regulation on Incineration of Waste Directive 2000/76/EC on the incineration of (Draft) waste. 9
  • 16.
    Among these regulationslisted in Table 2.1, Regulation on General Principles of Waste Management and RCHW are the core regulations covering main aspects of waste management practices while the rest deals with specific types of waste. Last two regulations that are on landfilling and incineration lays down general measures for these two disposal activities. According to RCHW, main principles of waste management is as follows: o Except for the cases in which hazardous wastes present an economic value to the importer and import of the hazardous waste is allowed by the edicts of MoEF, import of all types of hazardous wastes are forbidden. o In accordance with waste hierarchy, waste prevention and waste minimization is the most desired option. Reuse, recovery or recycling (especially waste oils, organic solvents, accumulators) and whenever prior options are not applicable, treatment options follow prevention and minimization respectively. The least desired option is final disposal. Whenever feasible, energy recovery during disposal should be evaluated and applied. o Waste generators, transporters and disposers are held responsible for the dangers created by hazardous wastes and “polluter pays” principle is adopted. o Companies that store, sell and dispose hazardous wastes are obliged to have a license from MoEF and companies without proper licenses are prohibited to operate and mix hazardous wastes with other fuels. o Segregation of hazardous wastes is mentioned and mixing of hazardous wastes with non-hazardous wastes is forbidden in all cases. This rule also holds for the commingled wastes arriving at disposal facilities. o In case of interim storage, priority should be given to storage at the point of generation. Main components of the hazardous waste management system consists of generation, storage, collection, transportation, treatment (whenever possible) and disposal of hazardous wastes. Generation of hazardous wastes should involve the waste prevention and waste minimization activities aside from the hazardous waste generating processes. Storage involves temporary storage of hazardous wastes either in the location of generation or specially designed temporary storage facilities suitable for hazardous wastes. Storage should not be confused with landfilling of hazardous wastes. Collection by definition means to gather objects together which in the context of hazardous waste management refer to the 10
  • 17.
    step where hazardouswastes are accumulated before being sent to temporary storage facilities, treatment or disposal sites. Transportation part of hazardous waste management system is the one where the wastes are conveyed to temporary storage, treatment or disposal facilities following collection of wastes. Treatment also involves the recycling processes. It is important to note that not all the hazardous wastes are suitable for treatment or recycle. Disposal is the ultimate fate of most of the hazardous wastes. Rules outlined by RCHW regarding the abovementioned components are as follows: Determination and classification of hazardous wastes Steps that should be followed by waste generator in order to determine whether a waste is hazardous or not is given in Figure 2.1. Step 1: Is the substance described as waste in RCHW? For a substance to be “waste” it should have waste properties given in RCHW Annex 1. If the substance does not have those properties it cannot be described as hazardous waste. Step 2: Are there any specific provisions in RCHW for the waste in question? Step 3: Does the waste listed in Annex 7? RCHW Annex 7 is adopted from Commission Decision as regards the list of wastes (2001/118/EC) and contains the marked entries as hazardous wastes. Complete list of waste is presented in Regulation on General Principles of Waste Management. Annex 7 contains 20 chapters that relate to the process that generated the waste or to specific waste types. If the waste is listed in Annex 7, Step 4a should be followed. If not Step 4b should be followed. Step 4a: How is the waste coded and classified in Annex 7? The chapters are given a two-digit number. Each Chapter contains sub-chapters that are identified by four-digits. Within each sub-chapter is a list of unique six digit codes for each waste. Annex 7 contains two types of wastes: Absolute entries: hazardous regardless of their composition or concentration of any dangerous substance within the waste. 11
  • 18.
    Mirror entries: wastesthat have the potential to be either hazardous or not, depending on whether they contain “dangerous substances” at or above certain thresholds. For the mirror entries Annex 3b should be considered and Step 4b should be followed. Figure 2.1 Steps to be followed to determine a hazardous waste according to RCHW 12
  • 19.
    Step 4b: Isthe waste produced as a result of processes listed in RCHW Annex 3? RCHW Annex 3 lists activities that can generate hazardous wastes. Annex 3 is comprised of two sections; Annexes 3a and 3b. If no specific entry could be found in Annex 7 regarding the waste or if the waste is a mirror entry, Annexes should be checked whether Annex 3a or Annex 3b applies based on the process from which the waste is generated. For the wastes that are in context of Annex 3a, Step 5 should be followed. If the waste generating process is not listed in Annex 3a, Annex 3b should be checked. This section lists the waste that can be hazardous only if certain components are present within the waste. Step 4c: Is the waste listed in Annex 3b contains the constituents listed in Annex 4? The constituents that can render a waste hazardous are listed in Annex 4 and if the waste listed in Annex 3b contains any of the constituents given in Annex 4; Step 5 should be applied. If the waste listed in Annex 3b does not contain any of the constituents of Annex 4, it cannot be classified as hazardous waste. Step 5: Does the waste have the properties listed in Annex 5? For the following classes of wastes to be hazardous, they must have at least one property given in Annex 5: o Wastes classified as mirror waste in Annex 7 o Wastes generated as a result of processes given in Annex 3a o Wastes listed in Annex 3b and contain at least one component of Annex 4. For these types of wastes there are two methods to determine whether they are hazardous or not: o Estimation of presence of hazardous properties by checking threshold concentrations associated with certain risk phrases o Testing for hazardous properties For mirror entries, as long as the composition of the waste is known, presence of “dangerous materials” can be confirmed. If none of the constituents of the waste are “dangerous” and if the waste itself does not show any hazardous properties from H1 to H14, this waste cannot be classified as hazardous. If a mirror waste possess a property from H1 to H14 due to its “dangerous” constituent concentrations exceeding the threshold concentrations specified for any hazardous property, this waste should be classified as hazardous and should be given code accordingly. 13
  • 20.
    Step 6a: Doesthe waste possess hazardous properties of H1,2,9,12-14? When a waste posses hazardous properties of H1,2,9,12-14, this waste must be classified as hazardous For these properties no threshold concentrations are specified. Step 6b: Does the waste possess hazardous properties of H3-8, H10,11? For some hazardous properties listed in RCHW Annex 5, threshold concentrations are specified. If any of the constituents of the waste show hazardous properties of H3-8, H10, 11 Step 7 should be followed. Step 7: Does the constituents or waste itself above the threshold concentrations specified in Annex 6? The hazardous properties for which threshold concentrations are specified are H3-8, H10, 11. For this reason, concentrations of constituents that render a waste hazardous should be checked whether they are above these threshold concentrations. If a waste contains dangerous constituents below these threshold concentrations, this waste cannot be classified as hazardous and waste codes should be given accordingly. Waste Generation As mentioned before, priority should be given to prevention and minimization of wastes at the location of generation. Hazardous waste generators should prepare a waste management plan and have this plan approved by governorship. Moreover, if the wastes are going to be stored temporarily within the facility premises, a permit is required to be taken from governorship. The most important aspect of temporary storage is to achieve proper and safe conditions for storage. Waste generator is obliged to take records of the amounts and types of wastes generated within the facility and to report these records annually to MoEF through waste declaration forms. If the generated waste is a mirror entry according to the abovementioned procedures hazardous nature of wastes should be confirmed by generator. Another important responsibility of the waste generator is to ensure that hazardous wastes generated are transported by licensed companies and disposed 14
  • 21.
    of in licensedfacilities. Throughout these processes, waste generator shall provide labeling and packaging in a proper and safe manner. Waste generator is held responsible for submitting a detailed report (on types, amounts etc.) to governorship in case of an accidental or deliberate illegal spill and remediation of the contaminated site no later than one month based on the type of the waste. Moreover, all the expenses related to remediation must be paid by the waste generator. Transportation of the wastes Transportation companies are obliged to obtain a license from MoEF for transportation of the wastes to recycling, recovery and disposal facilities. Licensed waste transporters must use vehicles suitable for the types of wastes they are carrying. Another important aspect is that the wastes that are being carried in a vehicle must have the same waste codes. Waste transportation is followed up via various transportation forms. These forms are categorized as national and international transportation forms and the required ones need to be present in the vehicle during transportation. Interim storage Main objective of interim storage is to collect wastes so that the amount of wastes reaches sufficient capacity for transportation before they are sent to recovery or disposal facilities. Such interim storage facilities are again subject to a license obtained from MoEF. However, for all types of wastes temporary storage duration cannot exceed one year that means interim storage facilities cannot act as final disposal sites. In order to get a license, interim storage facilities need to show presence of contingency equipments and necessary systems to control hazardous wastes in case of an accident. Waste recovery In order to obtain economic income and to decrease the amount of waste destined for final disposal, recovery of wastes is promoted. Possible recovery processes are listed in RCHW (Annex 2b). The most important aspect of recovery is that an accredited laboratory must confirm that waste becomes a product as a result of recovery processes. In the same manner, when chemical, physical and biological treatment is applied on a waste; there is a necessity to confirm that waste is no longer hazardous according to Annex 11a. 15
  • 22.
    Waste Disposal Liquid wastessuitable for pumping can be disposed of by injection into geologically and hydrogeologically suitable wells, salt rocks and natural cavities. Moreover, in abandoned mining sites wastes can be disposed of inside containers. For these two methods to be applied a feasibility report should be prepared and a permit should be obtained from MoEF. In Annex 2a of RCHW, some other possible final disposal methods are listed. When incineration is used as a disposal method, complete combustion should be achieved as much as possible. RCHW lists operation requirements for incinerators. Incineration plants should be designed, equipped and operated so that the flue gas composition does not violate the emission limits specified in RCHW. Combustion gases are discharged to atmosphere via the stack in a controlled manner. Stack height should be designed and applied according to Industrial Air Pollution Control Regulation. Incineration facilities perform trial burns before they acquire their permits from MoEF and take license according to the results of these trial burns. Second mostly used final disposal method after combustion is landfilling. Proven that there exist enough precautions or there are no negative impacts on environment due to the nature of the waste, hazardous wastes can be landfilled and permit can be taken from MoEF for establishment of landfills. Criteria for landfilling are presented in Annex 11a of RCHW. Aside from this Annex, the most important criterion for landfilling is that the water content of the waste to be landfilled should not exceed 65%. Site selection for landfills is also very important. According to RCHW, possible sites for establishment of landfills are listed. In RCHW, there are specifications about landfill liners, drainage systems, embankments and top cover that will be applied when the landfill site can no longer accept waste. Hazardous waste landfill must have an operational plan and submit it to MoEF. Transboundary movement of wastes Transboundary movement of wastes into the country is allowed if and only if the imported wastes have an economically significant value and this is subject to a permit taken from MoEF. Export of wastes is allowed if and only if there is no established facility that has sufficient technical waste disposal capacity in Turkey and the responsible authority of the importing country permits the 16
  • 23.
    transboundary movement ofwaste into that country. Neither transit passages nor transshipments and transfer of wastes are allowed within the area of national jurisdiction without the consent of MoEF. 2.2 STAKEHOLDERS OF HAZARDOUS WASTE MANAGEMENT Parties involved in hazardous waste management system are MoEF, administrative chiefs (governors), local administrations (municipalities in smaller provinces and greater municipalities in bigger provinces), hazardous waste generators, and companies that are responsible for transportation, treatment, recovery and disposal of hazardous wastes. Among these parties, rules valid for companies responsible for transportation, treatment, recovery and disposal of hazardous wastes are given in RCHW. Duties, responsibilities and jurisdiction of MoEF, administrative chiefs, local administrations and waste generators are shown in Figure 2.2. In the hazardous waste management system, main duties of MoEF are policy setting, giving permits to disposal, transportation, recovery companies that have the obligation to have license and inspect them. Application of hazardous waste management system according to the plans and programs of MoEF on province-scale is achieved by administrative chiefs and local administrations. However, the biggest responsibilities on hazardous waste management systems lie upon hazardous waste generators. From classification to disposal of hazardous wastes in the context of “polluter pays” principle, the generator is held financially responsible. Proper transportation, recovery and disposal of the hazardous waste generated through licensed companies are also the responsibilities of waste generator. Waste declaration, that has great importance in inspection mechanisms of MoEF should be carried out by waste generator with accuracy. It can be seen that for the hazardous waste management system to function properly waste generators have great responsibility. 17
  • 24.
    Figure 2.2 Mainduties, responsibilities and jurisdiction in the hazardous waste management system 18
  • 25.
    3 DEVELOPMENT OF HAZARDOUS WASTE MANAGEMENT SYSTEM IN TURKEY MoEF has participated in and completed a number of projects towards development of hazardous waste management practices in Turkey. First one of these major projects is the In Hazardous Waste Management Project 6 carried out by TÇT-Zinerji Consortium in 2001. In this project, hazardous waste generation and disposal practices, institutional structure and legal framework are covered and possible sources of problems are investigated. Suggestions were made on legal framework related to management of hazardous wastes and harmonization with EU directives. In Hazardous Waste Management Project, the hazardous waste generation in Turkey was evaluated based on the total number of employees working in hazardous waste generating industries adopting a method from Germany. MoEF’s approach for locating new hazardous waste facilities is towards concerning with both cost and effectiveness of the system shaped as a result of the “Technical Assistance for Environmental Heavy-Cost Investment Planning” Project 7. According to “economy of scale” principle, building large scale and regional hazardous waste processing and disposal facilities reduce disposal costs (per ton). On the other hand, establishing fewer but large-scale plants increases transportation distances and hence transportation costs. However, transportation costs can be reduced by establishing interim storage network where hazardous wastes originating from small sized companies will be stored safely until reaching necessary amount for transportation by larger vehicles or railway. In this EU project carried out by an international consortium in coordination with MoEF, three scenarios were evaluated. First scenario includes establishment of a number of large scale incineration and disposal facilities along with collection network and transfer stations at the locations where industrial activity is high. According to this scenario transfer stations should be able to perform basic physical and chemical treatment processes in order to decrease the volume of 6 Management o Hazardous Wastes, Ministry of Environment and Forestry General Directorate of Waste Management, Department of Waste Management, 2001, Ankara 7 Technical Assistance for Environmental Heavy-Cost Investment Planning, Turkey Directive-Specific Investment Plan for Council Directive on Hazardous Waste (91/689/EEC), Ministry of Environment and Forestry, 2005, Ankara 19
  • 26.
    waste. The regionsfor which the hazardous waste incineration and disposal facilities will serve are shown in Figure 3.1. Figure 3.1 Hazardous waste management regions Second scenario is similar to the first one however, in this one instead of low number of large scale facilities to serve for regions, high number of smaller scale facilities serving for smaller areas is considered. This scenario also includes the network and transfer station but again in smaller number and scale. Third scenario involves implementation of first or second scenario along with co- incineration practices in cement kilns. Among these three scenarios first one was chosen by technical working group involved in the project, which will be referred as regional hazardous waste management plan from now on. In the first phase, regional hazardous waste management systems will be realized in highly industrialized regions; o Thrace Region o Eastern Marmara Region o Aegean Region o Central Anatolia Region o Mediterranean Region Number and capacities of facilities planned to be constructed according to regional planning may increase as a result of rate of industrialization. In addition to that, it should be kept in mind that as the awareness of waste producers increase; technological developments will be installed for waste minimization purposes at the source. Construction, installation and operation of hazardous waste disposal facilities require special technology and training. Moreover, these 20
  • 27.
    facilities need tobe inspected by Ministry of Environment and Forest thoroughly. In this context, these facilities are obliged to use BAT (Best available Techniques) specified in Reference documents on BAT (BREFs). These facilities are expected to be constructed by private sector on “built-operate” basis. In the second phase, interim storage facilities including physical-chemical pretreatment units are planned to be installed at less industrialized regions. Also, transfer network to integrated facilities will be developed. There is already an incineration plant in Marmara Region, which is Đzaydaş having 35.000 t/yr of waste incineration capacity. A capacity increase of 70.000 t/yr was foreseen for Đzaydaş. Other newly established facilities is planned to be as given below: o Thrace Region: an incinerator (60.000 t/yr) and a landfill (90.000 t/yr) to be installed in 2013 – for the orange region shown in Figure 3.1. o Đzmir: an incinerator (40.000 + 30.000 t/yr) to be installed at 2015 and 2020 in two phase and a landfill (120.000 t/yr) to be installed in 2014 – for the blue region shown in Figure 3.1. o Adana/Mersin: an incinerator (45.000 + 40.000 t/yr) to be installed at 2016 and 2021 in two phase and a landfill (140.000 t/yr) to be installed in 2015 – for the purple region shown in Figure 3.1. “Technical Assistance for Environmental Heavy-Cost Investment Planning” Project was followed by two Twinning Projects namely Waste Management Twinning Project, (TR/2003/EN/01)8 and Special Waste Twinning Project (TR/2004/IB/EN/01) 9. In Waste Management Twinning Project, hazardous waste management concept was developed aiming to determine mid-term and long-term measures and ways to establish a sufficient hazardous waste management structure all over Turkey. Emphasis was given to waste minimization and recovery operations. Requirement for self-sufficiency of disposal and recovery operations in terms of capacity was underlined. Moreover, waste specific handling of hazardous wastes was covered under establishment of dedicated waste recovery and disposal facilities towards handling of specific wastes. In addition, branch-specific measures were listed management of wastes originating from selected sectors. 8 Waste Management Twinning Project, (TR/2003/EN/01 9 Special Waste Twinning Project (TR/2004/IB/EN/01) 21
  • 28.
    Measures for wasteavoidance recommended by Waste Management Twinning Project were listed as: o Cooperation between production plants and research institutions for development of new equipments o Construction of a network to spread the relevant technical information between good’s producers, chambers and associations, responsible environmental authorities as well as institutions o Promotion of public relations on hazardous waste management as well as education and training programs o Establishment of a special working unit (task force) subordinated the governmental level or subordinated the level of the environmental agencies which is responsible as an advisory board to give advices for suited measures to the private enterprises in terms of waste avoidance and waste recycling/recovery Highlights for waste recovery and recycling are: o Supporting establishment of waste recycling exchange to manage and broke with valuable goods and secondary raw material o Promotion of recycling-friendly designs o Promotion of high-level and emission-free recovery by o Immediate reuse of waste, devices and parts out of waste for the further production without any treatment o Recycling of the immanent raw materials and material use of hazardous components out of waste immediately or after treatment as secondary raw material for the same or for other production purposes o Recycling of the immanent raw material and material use (for the same or for other production purposes) of all non-hazardous waste parts after separation, elimination and disposal of hazardous components and compartments 22
  • 29.
    o Recycling ofthe immanent raw materials of waste and material use for other purposes than production o Energy recovery of hazardous waste in production plants In order to realize abovementioned measures creation of a special tax /fee /levy for waste generation and tax privileges given to the enterprises for investments in waste minimized production processes are suggested. In the light of outcomes of these projects and following the rules laid down by legislative framework, current hazardous waste management system in Turkey is shaped. However, in terms of practical aspects, hazardous waste management system should be further studied and improved. Following this motivation LIFE HAWAMAN Project on Improvement of Industrial Hazardous Waste Management in Turkey (LIFE06/TCY/TR/000292) was started. The project’s objective is to improve the management of industrial hazardous waste in Turkey and to tackle the increase in hazardous waste generation and environmental risks that such waste may cause. In order to reach this goal, the following items were worked out: 1. Estimation of the amount of industrial hazardous waste in Turkey 2. Allocation of hazardous waste to disposal routes according to the state of the art 3. Recommendations concerning a hazardous waste management concept for Turkey . 23
  • 30.
    4 CURRENT SITUATION OF HAZARDOUS WASTE MANAGEMENT IN TURKEY Rising environmental awareness, legislative obligations, increasing costs because of capacity constraints of waste disposal operations and increasing importance of environmental protection measures especially in foreign trade lead to an increase in implementation of pollution prevention technologies and waste minimization activities. In implementation of recycle/recovery and reuse activities the priority is given to the wastes easy to collect, manage and require simpler technologies. Wastes of packing materials such as IBC, barrels and other packing wastes is a good example for easy to handle type of wastes as those wastes pose lower risk for the environment. Another example can be recovery of silver, which is simple in terms of technology to be used. Furthermore, waste exchange system implemented within the scope of chamber of industries by Turkish Union of Chambers and Commodity Exchanges supported by Ministry of Environment and Forestry (MoEF). Waste exchange is an intermediary system aiming recovery and reuse of production wastes from the industries to be used as a secondary raw material in other industries. With the implementation of waste exchange, amount of wastes to be ultimately disposed of is reduced. However, effective implementation and operation of this system is predicted to take some time. According to the data of November 2007, number of recycle plants with ad-hoc working permit and license reached up to 89. Currently, 52 of those plants are operating with the license. The classification of those plants according to recycling methods indicated in Annex 2 of Turkish RCHW can be seen in Table 4.1. As can be seen, metals are recycled as priority in 33% of recycling plants. Metals are of priority as installed capacity for recycling of metals consists half of the overall recycling capacity in Turkey. Waste oils follow metals in terms of number of plants (21%) and installed capacity (35%). The distribution and amount of recovered materials can be seen in Table 4.2. 24
  • 31.
    Table 4.1 Numberof plants and recycle/recovery activities (June 2007) CODE OF NUMBER OF PLANTS TOTAL CAPACITY RECYCLE/RECOVERY WITH LICENSE (TON/YEAR) R2 (Recovery of solvents) 3 9,350 R3 (Reclaim of organics other than 7 17,477 solvents) R4 (Reclaim of metals and metal 17 113,442 compounds) R5(Reclaim of inorganic materials) 4 1,955 R9 (Refinement of waste oils) 11 82,452 R11 (Use of wastes from R1-R10 3 14,570 operations) R12 (Change of one of R1-R11 7 24,415 operations) TOTAL 52 263,661 Table 4.2 Types of recyclable wastes admitted to licensed recycling facilities and their capacities ANNUAL CONSUMPTION SHARE IN OVERALL WASTE TYPE CAPACITY (TONE/YEAR) CAPACITY (%) Dye sludge 4,503 1.01 Oily waste (wastes 86,618 19.48 including heavy metals) Chemical wastes 21,106 4.75 Contaminated cloth and 7,978 1.80 cotton waste Waste solvent 1,990 0.44 Waste barrel 656,400 -- Battery accumulator 192,439 43.30 Industrial sludge 7,360 1.65 Waste tyres 51,979 11.70 Waste oil (1st Category) 33,762 7.60 Waste oil (2nd Category) 36,735 8.27 TOTAL 445,000 (+656,400 barrels) 100 Recently, a pilot scale hazardous waste recovery plant with gasification has come into operation in Istanbul Kemerburgaz with 29,000 tons/year capacity. The facility was established by Ecological Energy Limited Company (Ekolojik Enerji Ltd. Şti.). Energy recovery indicated in Annex 2 of RCHW is another method for waste recovery. This type of recovery can be implemented in cement industry. Wastes from cement industry are utilized as alternative fuels for energy recovery 25
  • 32.
    in factories. Wastetyres, 1st and 2nd type of waste oils, dye sludge, solvents and plastic wastes can be disposed in cement factories. Additionally, two cement factories got permission for utilization of grit and domestic sludge as alternative raw material. Currently, 22 cement plants have license in R1 category. In Table 4.3, amount of waste types used as fuel in licensed cement factories are given. Table 4.3 Wastes used as alternative fuels in cement factories WASTE TYPES AMOUNT LICENSED (TONE/YEAR) 1st and 2nd type Waste oils 214,226 Waste tyres 106,458 Contaminated waste 61,884 Waste plastic 51,866 Petroleum refinery waste 24,120 Petroleum bottom mud 18,902 Dye sludge 16,964 Liquid fuel sludge 4,020 Total 498,440 Currently, there are three landfills and three incinerators licensed by MoEF for disposal of industrial wastes in Turkey. TÜPRAŞ has established a rotary kiln for their own wastes while Erdemir and Đsken have build disposal facilities for their own wastes. Information related to current waste disposal facilities is provided in Table 4.4. Capacities given in Table 4.4 are the installed capacities and almost 80% of the total capacity is utilized currently. Following the regional waste management plan developed in “Technical Assistance for Environmental Heavy-Cost Investment Planning” Project, establishment of certain hazardous waste facilities are underway. List of these facilities along with their location and capacities are given in Table 4.5. 26
  • 33.
    Table 4.4 Wasteincineration capacity of PETKĐM is 17.500 tones/year. Less than half of the capacity (7500 tones/year) is utilized by PETKĐM, while the rest is for other industries. Following the regional waste management plan developed in “Technical Assistance for Environmental Heavy-Cost Investment Planning” Project, establishment of certain hazardous waste facilities are underway. List of these facilities along with their location and capacities are given in Table 4.5. Table 4.4 Current capacities of disposal facilities COMPANY NAME CAPACITY ∗ ĐZAYDAS(storage) 790.000 m3 (occupancy ratio %20) ĐZAYDAS (incineration) 35.000 tons/year PETKĐM (incineration) 17.500 tons/year TÜPRAŞ (incineration) (for the facilities own wastes) 7.750 tons/year ERDEMĐR (storage) (for the facilities own wastes) 6.084 tons/year ISKEN (storage)∗ (for the facilities own wastes) 115.000 m3 Table 4.5 Integrated Waste Disposal Facilities PRESENT NAME OF THE PROJECT AND LOCATION CAPACITY SITUATION Kiplasma Sanayi ve Ticaret A.Ş. – Integrated Industrial Waste Disposal Facility Incineration: EIA Phase 48.000 tons/yr Gebze Organized Industry Zone Kocaeli Aegean Region Industrial Waste Disposal Landfilling: Landfill brought in line Complex 3.230.000 m3 on March 2009. Incineration: ∗ Total capacity 27
  • 34.
    Kırtıllı Tepe MevkiiSandal Beldesi 20.000 tons/yr Incinerator in Kula - Manisa planning stage. ITC Invest Trading & Consulting AG – Gasification: Feasibility Integrated Waste Disposal Facility 20-30 thousand ton/yr study Çadırtepe Mevkii (100 thousand ton/yr completed Sincan - Ankara with expansion) Türkiye Metal Sanayiciler Sendikası Planning Bursa phase 28
  • 35.
    5 HAZARDOUS WASTE MANAGEMENT CONCEPT 5.1 HAZARDOUS WASTE QUANTITY ESTIMATION The Twinning project "TR03/EN/IB-01 Waste" activities on hazardous waste regarded the lack of reliable data as one obstacle to base any kind of concept on. Due to this the estimation of quantities and types of waste for certain industrial activities was a basic task of the HAWAMAN-Project to base the hazardous waste management concept on. This section gives the outline of hazardous waste generation estimation methodology and its basic findings. The realistic estimation of kind, amount and geographic origin of the currently produced hazardous waste is the most important basis for the introduction of a waste management system that includes the implementation of waste transportation, interim storage and treatment facilities and the optimal organization of waste transportation – where appropriate via interim storage facilities - to treatment facilities. A too imprecise evaluation of the amount of waste could either lead to expensive bad investments in oversized waste treatment plants or to insufficient capacities for a proper and environmental sound waste treatment. The following work steps for the estimation of quantities and types of waste were planned: o Definition of industry sectors generating hazardous waste o Compilation of basic data for estimation of hazardous waste amounts o Population per province o GNP per province o Industry structure with list of enterprises with employees, sector and province o Number of motor vehicles etc. o Estimation of amount of hazardous industrial waste for selected industry sectors based on international experiences and the above mentioned basic data from Turkey o Report on the methodology, used experiences/data, results and compilation/development of maps The estimation is using a heuristic method based on long year international experiences. It does not include any prognosis for future hazardous waste 29
  • 36.
    quantities and qualities,which will change due economic development or structural changes in industry etc. Moreover, it does not cover all waste streams. The hazardous waste generation estimation outlined in this section with its data amount per type of waste per province gives the basis for the following project tasks on waste logistics and waste management treatment concept. 5.1.1 Methodology There are several methods in order to estimate the types, amounts and regional distribution of the hazardous waste in a country in which exists no working hazardous waste management system so far. Data from waste generators a) Direct information from waste generators: This approach will lead to no reliable data with very high aberration from real situation, because waste types and waste amounts often are unknown, especially in countries with no hazardous waste management system; participation << 100 %; this method is labor and time intensive. Even in countries with long-time existing hazardous waste management system the data given by the companies are not very reliable; they just can give a qualitative, but not quantitative statement, if the waste amounts will in- or decrease. b) Material balances from companies: Input/output balances from companies or processes are not existing normally, this method is not practicable and very labor and time intensive. c) Internal notification / waste declaration forms: Because waste types and waste amounts often are unknown in the companies at present, the waste types and amounts given in the Internal Notification often are wrong resp. consciously bigger or smaller than in reality. Even with a long-time existing hazardous waste management system Internal Notification will not give reliable data. Data from waste transportation Because a hazardous waste management system is not covering the whole country the current situation needs to be improved, only partial data about waste transportation exist. An extrapolation of this data is not possible, because only a part of the waste types are transported to treatment facilities, for the other part no treatment facilities exist. 30
  • 37.
    But even witha long time existing hazardous waste management system the Waste Transportation Forms will not give 100% reliable data: There is always a gap between the waste mounts from waste generators to waste transportation service and from waste transportation service to waste facilities. Possible reasons for the situation are thought as mistakes in m³ to ton conversion, partly filled transportation units and loss of some part of water evaporation of water. Data based on material and product amounts Material input and product output data and the associated waste ratios are not available for all industrial sectors, so only a part of the waste amounts can be estimated by this approach. Even if these data were known; the following points will remain as possible problems: o the material efficiency = waste ratios can differ by magnitudes o statistical problems can falsify the data: o production of product in one or more companies (Figure 5.1)? o waste per produced item, e.g. vehicle: truck or compact car? o complete production at facility or import of parts? Production in 1 facility Production in 3 facilities input output input output input output input output 1 Material/Product 3 1 Employees/Sales 3*1/3=1 Figure 5.1 Production in 1 or 3 facilities: material balance differs by factor three Data based on inhabitants/employees and GNP/sales per region 31
  • 38.
    This method givesa rough estimation about hazardous waste generation in a country or in a region. Large amount of such data is available from many different countries with long-time existing hazardous waste management systems. This is a very cheap and simple method. Problem of this approach is that some of the industrial sectors are waste intensive, others not. Without considering the employees per sector, the aberration from the real data may be high. For instance, the main industry in Turkey are the textile and food industry (with only small amounts of hazardous waste) plus metal industry; in Germany are the metal and chemical sector, which are very waste relevant, are the two main industrial sectors. Data based on employees/sales per sector and region Data based on employees/sales per industrial sector and per region gives a good estimation about waste situation per region, not very labor and time intensive, but the waste ratios are not available in studies/literature up to now and have to be developed with experience from a lot of waste management projects in a lot of countries knowing the situation in the waste generating industries. The development of waste amounts in regions without a long time existing hazardous waste management system depends on: o the presence of waste facilities o the possibility of waste recycling o the costs for waste treatment (disposal and recycling) o the authorities (surveillance, penalties) o the laws and regulations, judgement o the limits for gas emissions (filter dust and sludges from flue gas cleaning) and sewage (waste water sludges) and their implementation o achievements in waste minimisation / material efficiency o development of industry However, the „Delinking“ between GNP/employees and waste amounts should be considered in a way that a higher production will not lead to similar higher waste amounts. Therefore, every hazardous waste management system has to be built up in a manner, that it can react flexible on changes in waste types and amounts. 32
  • 39.
    While comparing wastefactors from other countries following items should be kept in mind: o big waste ratios are mainly caused by mineral wastes (e.g. Luxemburg > 50% contaminated soils!) o hazardous waste, which is recycled, sometimes is included and sometimes excluded o sometimes hazardous waste, which is treated by the waste generator, is in/excluded o some regional waste balances are worked out by consultants, who are interested in big waste amounts, so there is more work for planning more and bigger treatment facilities o waste factors for countries with no (long time) existing hazardous waste management system are often copied one by one without being proofed and are based on inhabitants/employee and GNP/sales. As a conclusion; waste balances based on o regional data (employees/GNP per province) and o employees or sales per industrial sector will give as a kind of best available technique not exceeding cost (BATNEC)- method the best estimation for a hazardous waste investment planning. It is based on long time and multi-region experience. Following the discussion presented above; for the HAWAMAN-Project a method should be used that gives a waste quantities estimation with low effort that is sufficiently accurate to plan kinds, capacities and locations of waste treatment facilities. Heuristic method used for HAWAMAN Project is based upon waste ratios per employee and sector. For this purpose the industrial sectors were merged to 21 sector groups whose companies have a similar spectrum of waste types. For each of those 21 sector groups a waste sector sheet was created that contains the typical waste types of this sector group and their waste ratios per employee. The waste ratios used in the waste sector sheets have not yet been published. They mainly base on data from countries with long-time existing hazardous waste management systems. The result of calculations gives an estimation of the waste situation in Turkey how it would be if there were already waste surveillance institutions and waste treatment facilities existing for several years. 33
  • 40.
    This result withthe distribution of the amounts of the different types of hazardous waste is exactly the result that is required in order to plan kinds, capacities and locations of the needed waste treatment facilities. This approach covers some of the factors of influence on the waste amounts listed previously. It is obvious, that in the years of the launch phase of a hazardous waste management system significant fluctuations and variations from the estimated values will occur. Waste ratios were developed based upon our long-year experiences in various institutions and countries and also from consideration of studies and balances like o numerous waste inventories of EU-countries and regions o data from world-bank and other institutions o BREF-documents (Sevilla process) Due to this information and experience it is possible to create waste sector sheets and to calculate the amount of waste per industrial sector and per province with the waste sector sheets and the basic data (employees per sector and province). By summating these results the waste amounts for Turkey can be calculated. This heuristic method has already been utilized successfully in other countries and verified with data from regions with long-time existing hazardous waste management systems. The accuracy of the approach is estimated as the final result to plus/minus 25%. This is sufficiently exact in order to base a hazardous waste management system on. It is believed that this uncertainty will be incorporated into design of hazardous waste management system since the system itself should be flexible in order to cover deviations due to unpredictable developments. It should be noted that on analysing and discussing the data it has to be considered that this method is a statistic approach that is only able to achieve realistic results for a great number of companies. The smaller the number of the regarded companies is, the greater the differences from reality can be. This applies for example to the consideration on the level of provinces with few employees or even single or few companies per group. The waste situation in single companies can deviate significantly from the used statistic waste ratios. Thus it can be reasonable to analyse the waste situation of individual exceptionally waste relevant companies respectively of companies 34
  • 41.
    with very bigamounts of hazardous waste and to integrate these values in results obtained from current approach. It's essential to make sure that these additional data are real data, that means data from wastes, which are occurring and are treated in reality, and not estimated data. 5.1.2 Waste estimation According to the assignment only certain sources and types of waste were to be considered at our waste quantity estimation. The focus is on the hazardous waste produced in the industry. List of considered and disregarded waste producers and waste types are given in Table 5.1. Disregarded waste producers are the ones either covered by special directives or the ones that produce “mirror” type hazardous wastes. Table 5.1 Covered and omitted waste types and producers COVERED OMITTED (TOBB-Codes 3000 to 4101) Food, beverage and tobacco Mining Textile and leather Construction Wood products and furniture Contaminated soils / sites Paper production and paper products End-of-live-vehicles Printing Service sector like hotels, commerce and Chemistry, chemical products offices (partly included in sep. collected Petroleum refineries fractions) Rubber and plastic products Logistics/Transportation (but car repair Mineral products (e.g. cement, glass) service as a.m.) Metal production Health care Metal working PCBs and PCTs Electrical machines and equipment Waste electrical and electronic equipment Electricity Public services (e.g. sewage sludge or and in addition: wastes from waste management o Separately collected fractions facilities, but power-plants) o Car repair service o Agriculture That means the wastes and waste groups o EWC 01 Mining o EWC 17 Construction / Demolition o EWC 18 Health Care o EWC 19 Waste + Waste Water Treatment o EWC 160104 End-of-live-vehicles 35
  • 42.
    o EWC 200123/135Electrical Equipment are excluded in our waste quantity estimation. In order to estimate the waste quantities per province on the basis of statistic ratios certain basic data from a as current as possible year are needed: o For the waste quantity estimation from the considered TOBB industrial sectors the number of employees per industrial sector per province is required as basic data. o For the waste quantity estimation of the separately collected fractions the capita per province are required as basic data. o For the waste quantity estimation of the car repair services the quantity of vehicles per province is required as basic data. o For the waste quantity estimation of the agricultural sector the agricultural employees per province are required as basic data. o For a comparison with general waste ratios on basis of the GNP information about the GNP of Turkey is required. Basic data for employee number was received from TOBB industrial sectors from TOBB via the Turkish MoEF. The data have been surveyed in 2007 and thus are very up-to-date. The TOBB database contains information of about approximately 66,000 companies, 38,000 of which have 10 or more employees. 35,800 of those companies are among the industrial sectors covered in this study and contain altogether 2.17 million employees. The other basic data like capita, vehicles, agricultural employees and GNP are taken from current publications of TurkStat 10. They were surveyed in years 2004 and 2005. As the basic data was obtained following procedure was followed: Step one: Deletion of all data sets with companies that come from other TOBB- sectors than No. 3000-4101. Step two: Deletion of all data sets with companies with less than 10 employees. Step three: Approximately 13,000 companies had assignments to more than one TOBB-code. Their employees were prorated on the different sectors. Step four: Addition of the numbers of employees per province of those TOBB- codes that are assigned to a waste sector sheet for every waste sector sheet. 10 Turkish Statistical Institute (TurkStat), statistics available from www.turkstat.gov.tr . 36
  • 43.
    Step five: Creationof Table A. 3 given in Appendix. The basic data for capita, vehicles, agricultural employees and GNP per province were available at TurkStat in the required form. They were summarized in Table A. 4 in Appendix. Waste sector sheets As mentioned before 21 industrial sector groups, whose allocated companies each have a similar waste situation and differ relevantly from other groups, were selected (Table 5.2). For these sectors waste sector sheets were generated. The sector 39 “not otherwise specified products” is split to plastics, metalworking and wood. These 21 sector groups were supplemented by the following three non-industrial groups: o Agriculture o Separately collected fractions o Car repair services For each of these sector groups, a list of hazardous waste that can occur in this sector group has been created according to European Waste Catalogue (EWC). Because it's not always possible to give the waste ratios in every sector for each single waste type, some waste types were partly united to groups with similar waste composition: acids, waste oil, halogenated solvents, non-halogenated solvents etc. The waste sector sheets contain from a few to over 30 different waste types and waste type groups depending on the waste situation of this sector group. The waste sector sheets cover 200 hazardous waste types of the EWC. The other missing about 200 hazardous waste types originate from the disregarded sectors like mining, construction/demolition, health care and waste water/waste treatment or are related to waste types that only occur in a few companies or just in small amounts. For each of these waste types and for each sector group specific waste amounts in tons per 1.000 employees and year are given. Depending on the stage of development of the industry and the foci within a sector group the ratios of the situation in the country were adjusted specifically. Thereto data for the Turkish 37
  • 44.
    economy as givenin Introduction section of this report were considered. In Table 5.3, a sample waste sector sheet is presented for metal working industry. Table 5.2 List of industrial sector groups WASTE SECTOR SHEET TOBB-CODES Batteries production 383902 Cement 3692 Inorganic chemistry 351112-351131 Fertilizer manufacture 3512 Organic chemistry. 351101-11, 351140-50, 3513 Other chemical industries 351155, 3522-3529 Paint Industry 3521 Electrical equipment + machines 383 except 383902 Energy (power plants) 4101 Food-beverage-tobacco 31 Leather 322-324 Metal production (Iron and steel) 371 Metal production (Others) 372 Metal working 381, 382, 384,385 Mineral production (e.g. cement, 36 except 3692 glass) Paper production and products 341 Petrol refineries 354 Plastics and rubber 355, 356 Printing 342 Textile 321 Wood and furniture 33 Table 5.3 Sample waste sector sheet for metal working industry SHAPING AND PHYSICAL AND MECHANICAL SECTOR: "METWORK" SURFACE TREATMENT OF METALS t per EWC Waste type 1.000 empl. ... waste paint and paint sludges containing organic 080111and13 10 solvents or other dangerous substances ... 110105to07 pickling acids and basis and other acids 30 110108 phosphatising sludges 10 ... 120107and10 machining oils free of halogens 40 120109 machining emulsions and solutions free of halogens 150 ... 38
  • 45.
    fluorescent tubes andother mercury-containing 200121 0,2 waste ... A single waste sector sheet only gives the statistically averaged data for this sector. The waste situation in single companies can differ significantly. Thus a waste sector sheet is not at all suitable to compare the included data with the waste types and amounts of single companies. For example in metal working some companies conduct galvanization while others don't (no 1101xx-wastes), some apply lacquering whereas some don't (no 0801-wastes). Results By entering the number of employees per sector and province into a waste sector sheet one receives the amount of waste that is produced in a sector and a province. By adding all waste sector sheets together the amount of waste in a province is received, and by adding these values from all provinces together amount of waste for Turkey is received. Because some of the 100 wastes and waste groups that are included in the waste sector sheets partly overlap, 28 waste groups were formed for displaying the result. Total hazardous waste generation under covered industrial and non-industrial sources turned out to be 1.35 million tons/yr. This amount of hazardous waste comes from the Turkish Industry – but it is only a part of the total hazardous waste amount in Turkey. Hazardous waste generation from industrial sectors Distribution of hazardous waste generation in general economic sectors are o Metal industry: 548,800 tons/yr o Chemical industry: 396,900 tons/yr o Other industrial sectors: 151,300 tons/yr o Non-industrial groups: 253,400 tons/yr These figures indicate that wastes from the industrial sectors add up to 1,1 million tons. In Appendix, from Table A. 5 to Table A. 8 more detailed information on distribution hazardous wastes among main sectors, industrial branches and provinces can be found. Hazardous waste generation according to waste types 39
  • 46.
    As mentioned before,28 waste groups were identified for reporting purposes. Table 5.4 lists the amount of hazardous waste generation according to these waste groups. In Appendix, Table A. 9 gives information distribution of waste types to provinces in more detail. 40
  • 47.
    Table 5.4 Descriptionand amount of hazardous waste groups in tons/yr ID SUBSUMES EWC GROUPS AMOUNT NUMBER CODES 1 Pesticides and agrochemical waste 020108, 200119 5,926 030201, 030202, 030303, 2 Wood preservatives 1,780 030204 040103, 040214, 040216, 3 Hazardous waste from tanneries 31,739 040219 050102, 050103, 050104, 4 Hazardous waste from petroleum refining 050105, 050106, 050107, 65,631 050108, 050109, 050115 060101, 060102, 060103, 060104, 060105, 060106, 5 Acidic and alkaline hazardous wastes 62,477 060201, 060203, 060204, 060205, 200114, 200115 060404, 060405, 060502, 6 Hazardous waste from inorganic processes 48,646 061002 070101, 070103, 070104, 070107, 070108, 070109, 070110, 070111, 070201, 070203, 070204, 070207, 070208, 070209, 070210, 070211, 070301, 070303, 070304, 070307, 070308, 070309, 070310, 070311, 070401, 070403, 070404, 070407, 070408, 070409, 7 Hazardous waste from organic processes 212,870 070410, 070411, 070501, 070503, 070504, 070507, 070508, 070509, 070510, 070511, 070601, 070603, 070604, 070607, 070608, 070609, 070610, 070611, 070701, 070703, 070704, 070707, 070708, 070709, 070710, 070711, 160506, 200129, 200131 080111, 080113, 080115, 080117, 080119, 080121, Hazardous waste from paint and sealant 8 080312, 080314, 080409, 54,719 production 080411, 080413, 080415, 200127 090101, 090102, 090103, 9 Hazardous waste from printing processes 090104, 090105, 090106, 4,908 200117 100104, 100109, 100114, 10 Hazardous waste from energy production 100116, 100118, 100120, 32,531 100122 41
  • 48.
    Table 5.4 Continued ID SUBSUMES EWC GROUPS AMOUNT NUMBER CODES 100207, 100211, 100213, 100304, 100308, 100309, 100319, 100321, 100323, 100325, 100329, 100401, 100402, 100403, 100404, 100405, 100406, 100407, 11 Hazardous waste from metal production 114,586 100503, 100505, 100506, 100603, 100606, 100607, 100808, 100815, 100817, 100905, 100907, 100909, 100911, 101005, 101007, 101009, 101011 101109, 101111, 101113, Hazardous waste from mineral and glass 101115, 101117, 101119, 12 18,983 production 101209, 101211, 101309, 101312 110105, 110106, 110107, Hazardous waste from galvanizing 110108, 110109, 110115, 13 44,763 processes 110116, 110198, 110202, 110205, 110301 120107, 120109, 120110, 14 Non-halogenated waste oils 130205, 130206, 130307, 208,344 130208 15 Halogenated waste oils 120106, 120108, 130204 2,466 120109, 130502, 130503, 16 Waste oil emulsions 80,075 130802 120112, 120114, 120301, 17 Other oily waste 53,266 120302, 130501, 200126 18 Halogenated solvents 140601, 140602, 140604 12,228 19 Non-halogenated solvents 140601, 140605 36,059 20 Contaminated packaging’s 150110 48,235 21 Spent adsorbents and filtering material 150202 32,859 22 Spent oil filters 160107 2,507 23 Spent brake fluids and antifreeze 160113, 160114 3,971 24 Spent batteries 160601, 160606, 210133 47,613 25 Spent catalysts 160802 180 26 Sludges from CPT of wastes 190813 99,433 27 Mercury contaminated waste 200121 2,398 28 Contaminated wood 200137 21,176 42
  • 49.
    Geographic distribution ofhazardous wastes Table 5.5 below, summarizes the geographic distribution hazardous wastes in terms of regions. According to this table, Đstanbul itself generates highest amount of hazardous wastes. Figure 5.2 gives a survey of the overall hazardous waste situation in Turkey. It shows the waste generation centres and the waste amount, aggregated on the 81 provinces of Turkey. The map shows three main gravity centres of hazardous waste generation – all located in the western part of Turkey: o Đstanbul o Kocaeli o Izmir, followed by Bursa and Ankara. Table 5.5 Geographic distribution of hazardous wastes (1000 tons/yr) NUTS1-REGION AMOUNT TR1 314.2 TR2 83.6 TR3 207.2 TR4 303.6 TR5 125.4 TR6 123.0 TR7 54.2 TR8 73.5 TR9 13.9 TRA 6.7 TRB 11.6 TRC 33.5 Total 1,350 As expected, Figure 5.2 shows a distinct west-east divide of hazardous waste generation in Turkey, with white spots in the eastern regions. Since the waste generation factors used are based on employee numbers, these findings correspond with the employee map (Figure 1.6), which looks similar to the hazardous waste map (Figure 5.2). 43
  • 50.
    Figure 5.2 Hazardouswaste generation in Turkey, total The next two maps give some rough information about the two origins of hazardous waste generation in Turkey that are industrial sources (Figure 5.3) and non-industrial sources (Figure 5.4). Figure 5.3 Hazardous Waste Generation in Industry (81 %) 44
  • 51.
    Figure 5.4 HazardousWaste Generation from separately collected waste (19 %) With its more than 80% share, it is obvious that the major amount of hazardous waste arises from Industry (Figures 5.3 and 5.4). Generation centres for industrial and non-industrial hazardous wastes does not show any difference. As mentioned in above discussions, metal industry represents the major part of hazardous waste generation in Turkey. Centres of hazardous waste generation in the metal industry are mainly situated in Đstanbul, Kocaeli and Bursa, followed by Izmir, Manisa, Eskisehir, Ankara, Konya, Kayseri, Adana and Hatay. These regions also stand for automotive industry and metal works. The west-east divide is obvious. Nearly no hazardous waste of that kind is generated in Eastern Turkey. Figure A. 2 to Figure A. 28 display geographical distribution of hazardous waste groups on maps. Moreover, Table A. 5 contains numerical information on provincial distribution of total hazardous wastes. Following tables in Appendix contains provincial information as well. 45
  • 52.
    5.1.3 Comparison and validation of results Comparison with Germany In 2006, 150 million tons of waste was generated in Germany. Of this amount 18.7 million was hazardous. 3.9 million was treated in company and 14.7 million ton was treated in treatment plants. When wastes from o EWC 01 Mining o EWC 17 Construction / Demolition (6 Million tons) o EWC 18 Health Care o EWC 19 Waste + Waste Water Treatment (3 Million tons) o EWC 160104 End-of-live-vehicles o EWC 200123/135 Electrical Equipment were excluded from this total amount generated from industry, car repair and separately collected fractions disposed or recovered in treatment plants was 5.3 million tons of hazardous waste. Comparison of hazardous waste generation will be based on GNP. To compare the Turkish with the German industrial hazardous waste situation by GNP, the industrial fractions of the GNP have to be compared, and because of the different purchasing power in Turkey and Germany, this values have to be adjusted by power parity. Table 5.6 gives the values obtained for comparison. It can be concluded that results obtained as 1.35 million tons/yr fits very good to the value referring to industrial employees. 1.35 million tons/yr also fits very good to the value referring to the industrial GNP adjusted by power parity Table 5.6 Comparison of Turkish and German hazardous waste generation HAZARDOUS WASTE GERMANY TURKEY EXTRAPOLATED (MILLION TONS) Capita (Million) 82 74 4.7 GNP (Billion US$) of 3,200 593 1.0 industry of industry 960 142 0.8 GNP “power parity” 2,780 870 1.7 of industry 834 208 1.3 Employee numbers in ≈9 2.17 1.3 industry ∗ ∗ Includes companies with more than 10 employees. 46
  • 53.
    There are somefactors of influence, which may diminish or increase these values: 1. In Germany the key sectors are the waste relevant sectors metal and chemistry, in Turkey besides metal industry the non-waste relevant sectors textile/leather and food. 2. In Turkey productivity per employee is lower than in Germany. 3. In Germany the "dirty", waste relevant production declines, assembling prefabricated parts produced abroad increases. In Turkey the "dirty", waste relevant production increases. Items 1 and 2 have a reducing affect whereas item 3 an increasing effect on the waste amounts of Turkey. Comparison with other countries Figure 5.5 shows the hazardous waste amounts of several countries. The data of the European countries originate from EU-statistics (pink dots) from the years around 2000, the data of the other countries from studies (estimated data, blue dots). The dots with waste amounts lower than 400.000 tons/yr, which are not named, are related to the countries Botswana, Colombia (Region Bogota), Cyprus, Denmark, Finland, Iceland, Ireland, Luxembourg, Norway and Tunisia. For Turkey we entered the GNP-value “power parity“ from 2006 on the trendline (big red dot). For Turkey would result a value of about 2 million tons for all hazardous wastes. It is important that in this case the data covers all kinds of hazardous waste, and not only the ones of the industry, that is that this in this way determined value can't be compared to ours. The values of some countries deviate by the factor 2 from the trendline. In some countries and years great site remediation projects have caused more than 50% of the amount of hazardous waste. 47
  • 54.
    hazardous waste amounts 3.500 3.000 hazardous wastes [1.000 t/a] Italy 2.500 UK 2.000 Turkey 1.500 Portugal Taiwan 1.000 Netherlands Belgium Norway Austria 500 Greece 0 0 200 400 600 800 1.000 1.200 1.400 GNP "power parity" [Bill. US$] Figure 5.5 Hazardous waste amounts in several countries versus GNP “power parity” 48
  • 55.
    5.2 ASSIGMENT OF HAZARDOUS WASTE TYPES TO DISPOSAL OPTIONS Next step on the concept development is classification and allocation of the hazardous waste to distinct disposal routes in order to estimate capacity requirement for disposal alternatives. A suitable national hazardous waste management system requires reasonable design data, in particular appropriate prognoses on; o the future amounts and types of hazardous waste produced in the period of commissioning the waste treatment and disposal facilities to be set-up, on; o the types and capacities of the treatment and disposal facilities needed to eliminate the future hazardous waste amounts and on; o the regional distribution of the amounts and types of hazardous waste produced in the country in order to identify suitable areas for erection of the necessary central or decentralized treatment and disposal facilities. In Section 5.1, hazardous waste generation amounts were estimated for the year 2007. This estimation does not include any prognosis for future hazardous waste quantities and qualities, which will change due economic development or structural changes in industry etc. This point was also underlined as the approach used for estimation was introduced. However, for the year 2007, regional distribution was obtained for types of wastes and economic sectors, which lead to hazardous waste generation. This section involves information on methodology of hazardous waste allocation between possible disposal alternatives as well as the results obtained. 5.2.1 Methodology The methodology of allocation for the HAWAMAN Project is based on an assignment of the relevant hazardous waste types (according to European Waste List - EWL) to principally suitable treatment, recovery and disposal options. The EWL exhibits 405 types of hazardous waste of which 232 are “absolute” hazardous waste types and 173 “mirror” waste types which can be either hazardous or not, depending on whether it contains dangerous substances at or above certain levels. Assignment to suitable treatment, recovery and disposal options in this context means suitable according to prior experience of project team on hazardous waste management practices in EU and information specific to Turkey in terms of 49
  • 56.
    disposal alternatives; forinstance probably no underground hazardous waste repository. During application this methodology was adjusted to the recent waste disposal praxis according to the DESTATIS 2006 evaluation of Federal Statistical Office of Germany. In order to clearly arrange the assignment list and to facilitate the application for the prognoses the total number of hazardous waste types according to the EWL was reduced by considering hazardous waste only from o manufacturing industries and post consumer waste from o car repair services and o households and micro enterprises. Thus the assignment list does not consider waste from o exploration and mining, o construction and demolition, o health care, o waste and waste water treatment, o end-of-live-vehicles and o electric and electronic equipment. Furthermore, “exotic” waste types have been omitted which are considered not to be relevant concerning amounts (about “pro-mille” range). As result, the assignment list exhibits 87 individual types of waste and 17 groups of waste types according to the “waste sector data sheets” prepared for defining relevant industry sectors, grouping of waste and disposal areas. Each group comprise two or more waste types (from one generic source), which are assigned by same fractions to the same treatment/disposal options. (Table A. 10 to Table A. 12) Assignment to treatment, recovery and disposal options The annexed Table A. 13 exhibits in Column 1 and 2, the codes and the denomination according to the EWL of the 87 individual hazardous waste types as well as of the hazardous waste types compiled in the 17 waste groups. 50
  • 57.
    The right handcolumns provide the fractions of each waste type and of each waste group assigned to the 6 options of treatment, recovery and disposal that are; o material recovery o thermal recovery o physicochemical treatment o incineration o direct landfill o solidification for landfilling As emphasized in Legislative Framework section the fundamentals of hazardous waste management in Turkish RCHW is built upon waste hierarchy policy as does their EU counterparts. Priority is given to waste minimization, which is followed by recycling/recovery option. Going down the hierarchy, thermal recovery and treatment are applicable if all other alternatives are unsuitable. The least desired option turns out to be landfilling. Following discussion introduces the six destination technologies considered for concept development ordered according to waste hierarchy policy. Moreover, prices for disposal options are given in Appendix (Table A. 10 to Table A. 13) for the information of reader. Material recovery is for waste, which is suited for reuse or valorisation and generally meets the acceptance criteria of alternative raw materials for primary raw material substitution in commonly available industrial processes in industrialized countries, e. g. o in used oil regeneration processes o solvent distillation processes o in cement industry for substituting clinker reaction raw material o for melting processes in metallurgical industry. Thermal recovery is for calorific waste which is suited for heat recovery and generally meets the acceptance criteria for primary fuel substitution in commonly available industrial thermal processes in industrialised countries, e. g. as alternative fuel in cement, chalk stone and brick industry. There is no typical allocation criteria reported in the Literature for material recovery/recycling/thermal recovery 51
  • 58.
    Examples of wastetypes suitable for recycling and material/thermal recovery are: o spent oil emulsions o aqueous solutions with dissolved organic or inorganic hazardous substances (acids, alkalines, heavy metals, cyanide, chromate, nitrite, fluoride, sulphide) o industrial process water with AOX-causing compounds o industrial process water with persistent TOC-causing compounds o landfill leachates o sludges, thin muds and aqueous solutions with suspended hazardous solids Chemical-physical treatment (CPT) is suited for o waste sludge, which does not meet the EC acceptance criteria of above ground landfills without dewatering and physicochemical detoxification o aqueous waste, which does not meet the acceptance criteria of municipal or industrial waste water treatment stations without physicochemical detoxification o oil/water mixtures and emulsions, which oil content < ~10 % and which does not require thermal treatment for separation. Typical physicochemical process reactions are o mechanical separation of solids, oily and aqueous phases by settling and decantation, o neutralisation of acids and alkalis o precipitation of sulphates and fluorides o oxidation of cyanides and nitrites, reduction of chromates and o dewatering of precipitates and sludge. Allocation criterion: Water content: > 50 % Examples of waste types suitable for CPT are: o spent oil emulsions 52
  • 59.
    o aqueous solutionswith dissolved organic or inorganic hazardous substances (acids, alkalines, heavy metals, cyanide, chromate, nitrite, fluoride, sulphide) o industrial process water with AOX-causing compounds o industrial process water with persistent TOC-causing compounds o landfill leachates o sludges, thin muds and aqueous solutions with suspended hazardous solids Incineration is required for waste, which does not meet the acceptance criteria for the above disposal option, and generally for waste with organic content above 8–10 %. Allocation criteria: Water content: < 50 % Ignition loss: no limit Examples of waste suitable for incineration are: o oily and tarry stuff o spent solvents, laquers, paint, varnish, ink o organic residues from chemical processes o contaminated packaging materials of all kinds o soils, contaminated with organic compounds o demolition material, contaminated with organic compounds o carbonaceous material and spent organic adsorbents o expired goods (chemicals, pharmaceuticals, pesticides, food) o impregnated wood Solidification for landfilling is required for waste, which meets the EC above ground landfill acceptance criteria except the criteria for mechanical stability. Solidification is a stabilisation of the waste performed by mixing with cement, lime, fly ash from coal-fired power plants or other suitable waste material before landfilling. In countries like Turkey, where an underground repository for hazardous waste is not available or will not be an economical feasible disposal option, solidification may be a disposal option for waste also, which meets the EC above ground landfill acceptance criteria except the criteria for leachability of 53
  • 60.
    hazardous components. However,solidification does not prevent from long term leaching of hazardous components. Solidified waste with leachable hazardous components, therefore, should be prevented from water access by an additional containment (e. g. reinforced big bag and/or bentonite layer) and disposed of separately from other waste (e. g. separate landfill boxes). Direct landfill means disposal on above ground hazardous waste landfills according to the EC landfill directive 1999/31/EC and to the EC landfill acceptance criteria (Decision 2003/33/EC). As commonly comprehensive and easily verifiable waste acceptance criteria for above ground landfilling was assumed as: Allocation criteria: Water content < 60 % (> 50 % dry matter - THOMANETZ) organic matter content < 8 % ignition loss. (< 10 % ignition loss – THOMANETZ) Examples of waste types suitable for direct landfilling are: o slags, ashes, sands, filter dusts, contaminated with inorganic compounds o soils, contaminated with inorganic compounds o demolition material, contaminated with inorganic compounds (e.g. asbestos) o inorganic residues from chemical processes o spent catalysts and inorganic adsorbents o filter cakes of different kinds (e.g. from galvanizing industry or CPT) 5.2.2 Allocation to Different Disposal Routes Figure 5.6 shows the results of the hazardous waste allocation to disposal routes of recycling/recovery, CPT, thermal treatment and controlled landfill. Distributions of disposal allocations are given in Figure 5.7 to Figure 5.10. In Appendix (Figure A. 29 to Figure A. 32) exact amount of allocations are listed. 54
  • 61.
    Figure 5.6 Recommendedhazardous waste disposal routes for Turkey – overview Figure 5.7 Recommended hazardous waste disposal routes to recycling/recovery 55
  • 62.
    Figure 5.8 Recommendedhazardous waste disposal routes to CPT Figure 5.9 Recommended hazardous waste disposal routes to thermal treatment 56
  • 63.
    Figure 5.10 Recommendedhazardous waste disposal routes to controlled landfill An important aspect to be considered during capacity determination is that about 20-30 % of the above mentioned input amount of the CPT-facilities has to be – after CPT-treatment as CPT-output - treated thermally, another 20-30 % has to be landfilled and about 50 % is water. Moreover, after solidification for landfilling the amount to be landfilled is bigger than the solidified amount. From the other waste treatment processes also result some hazardous waste. 5.3. Promotion of Target Waste Hierarchy in the Management System Although Turkish legislations include waste hierarchy, discussion on promotion of waste hierarchy is summarized in following discussion. 5.3.1. Waste Avoidance/Prevention Typical examples for hazardous waste prevention measures are: o Paint sludge-free paint techniques o Metal degreasing with alkalines instead of chlorinated solvents 57
  • 64.
    o Ban onhazardous matter like POP’s, mercury, asbestos Waste avoidance sometimes means cost-intensive change of well-proven production techniques. On the other hand waste avoidance can often be achieved by simple internal organisational measures, such as o Lifetime prolongation by maintenance of cutting oil emulsions o Intelligent water management to reduce the amount of galvanic sludges Recommendation: Advised by an expert committee*, specific waste avoidance measures should be implemented by law, resp. by administrative regulations. 5.3.2 Waste Recovery Main goal of recovery practices is saving resources. Typical examples for hazardous waste recovery measures are: o Secondary aluminum production with dross treatment for salt recovery o Co-incineration of oil sludges for energy-saving in the cement industry o Zinc recovery from steelwork dust by advanced thermal processes o TiO2-production with recovery of iron salt as a sellable by-product Waste recovery often means higher investment for supplementary techniques. Recommendation: Advised by an expert committee*, specific waste recovery measures should be implemented by law, resp. by administrative regulations. 5.3.3. Waste disposal Main goal is to handle non-avoidable and non-recoverable hazardous waste by “End-of-Pipe techniques”, according to the state of the art. The well-known hazardous waste disposal measures are: o Controlled Landfilling o Thermal Treatment 5.3.4. Recommendations for hazardous waste facilities *in Germany, the expert committees were composed of Government representatives, public authorities and the corresponding industry – often with the involvement of external experts 58
  • 65.
    It is advantageousif the mentioned disposal techniques are combined within an integrated hazardous waste treatment facility such as shown on Figure 5.11, because the waste output of one plant part can be treated or landfilled on site. The figure depicts an ideal. But there are also other possibilities, e.g. thermal treatment plus CPT, situated in an industrial centre, with a landfill in some distance – far from residencies and well connected by roads without crossing villages. Figure 5.11 Scheme of a fully integrated hazardous waste treatment / disposal facility Because the hazardous waste management in Turkey is still developing, the treatment facilities should be erected step by step – according to the waste delivery. Therefore enough free space should be kept in reserve. The facilities can be constructed and operated privately and are supervised by the State. 59
  • 66.
    6 CONCLUSIONS Based on the hazardous waste quantity estimation approach given in Section 5.1, the following findings can be stated: o The overall hazardous waste generation in Turkey has been estimated as approximately 1,350,000 tons/yr based on the 2007 data. o The main gravity centres of hazardous waste generation are all located in the western part of Turkey: Istanbul, Kocaeli, Izmir, followed by Bursa and Ankara. o There is a distinct west-east divide of hazardous waste generation, with white spots in the eastern regions. o About 81 % of hazardous waste is generated in Industry – 19 % comes from other sources. o The major hazardous waste originators in Turkey are the Metal Industry (41 %), the Chemical Industry (29 %) and the Car Repair branch (15 %), followed by various other originators (together 15 %). Based on hazardous waste allocation studies given in Section 5.2, following findings can be stated: o About 1.35 million tons/yr (2007) of hazardous waste are to be disposed of in Turkey by the following four advanced disposal/recycling routes: o controlled landfill o thermal treatment o CPT o recycling/recovery o The waste amount per disposal route was determined approximately by use of the following allocation criteria: o waste to controlled landfilling: with water content not more than 50 % on dry mass basis, and with ignition loss not more than 10 % on dry mass basis. o waste to thermal treatment: with water content not more than 50% on mass basis; no limit for ignition loss o waste to CPT: with water content more than 50% on mass basis 60
  • 67.
    o waste forrecycling/recovery: following the experiences in other countries. o The allocation delivered the following results: o waste amount for controlled landfill: approx. 251,000 tons/yr (18.5 %) o waste amount for thermal treatment: approx. 476,000 tons/yr (35.0 %) o waste amount for CPT: approx. 446,000 tons/yr (33.5 %) o waste amount for recycling/recovery: approx. 178,000 tons/yr (13.1 %) o With a view to the Turkish province map, the highest demand for disposal facilities is, by far, Đstanbul – followed by Kocaeli, Izmir, Ankara and Bursa. About one-third of the 81 Turkish provinces are arranged behind these gravity points on a much lower level. More than two-thirds of the 81 Turkish provinces have presently no need for advanced disposal facilities. With regard to the waste gravity centres in Turkey, five bigger integrated hazardous waste treatment facilities should be stipulated as similarly recommended by “Technical Assistance for Environmental Heavy-Cost Investment Planning” Project : o for Đstanbul. It should be the biggest facility with highest priority. Thrace area would be a favourable location with good roads (and also rail connection). o for Kocaeli region. The existing Đzaydas facilities should be enlarged and equipped with CPT plants o for Izmir region and adjacent regions o for Ankara region and adjacent regions o for Adana region and adjacent south-eastern regions These centres with their coverage area are shown on Figure 6.1. 61
  • 68.
    Figure 6.1 Fiverecommended planning areas for integrated hazardous waste treatment facilities Furthermore, numerous smaller and larger sized hazardous waste facilities in Turkey should be included into the developing management concept. Figure 6.2 Locations of 189 mostly private operating hazardous waste treatment facilities in Turkey 62
  • 69.
    7. RECOMMENDATONS Aside fromgeneral hazardous waste management concept, recommendations on specific issues is given in this Section. The current information status should be updated: o waste throughput capacity (licensed and in reality) o waste storage capacity (licensed and in reality) o type of treated waste o waste treatment techniques o waste input o waste output o wastewater output o groundwater protection measures Recommendations for a hazardous waste disposal structure of the low industrialized areas in Turkey Due to the wide Turkish countryside with marginal industry and due to the large distances between low-waste regions and the big waste treatment centres, there is a need for a multitude of small-sized hazardous waste collecting points, particularly equipped with a dewatering facility (settling tank and filter press) and a waste packaging station – with storage capacities of some 100 tons – e.g. located on site of a sewage treatment plant. The accruing filtrates should be collected and treated from time to time by alkaline/iron precipitation and by activated carbon. The facility should have a suitable floor to avoid groundwater pollution and the waste should be stored and packed under roof. These small intermediate facilities should be managed privately and supervised by the local authorities. It should be verified if the existing treatment facilities are suitable for this purpose. Recommendations for a peripheral problem concerning CPT A special problem in Turkey is the disposal of aqueous liquids and thin sludges (rep. industrial wastewater) with hazardous constituents like acids, lyes, heavy metals, chromates, nitrites, cyanides and a multitude of persistent organics. 63
  • 70.
    Because of thewide lack of CPT plants in Turkey, most of these liquid wastes are discharged today into municipal sewage treatment plants. Therefore, the resulting sewage sludge is more or less loaded with hazardous matter and must be landfilled because it is not utilizable for agriculture. Today, about 158 municipal mechanical-biological sewage treatment plants (plus 26 solely mechanical plants) are working in Turkey (Figure 7.1) – producing approximately 700,000 tons/yr (dry matter), with a calorific value of about 15 MJ/kg (dry matter). Besides these municipal sewage treatment plants, there are a lot of industrial sewage treatment plants with similar sludge problems. Figure 7.1 Locations and numbers of municipal sewage treatment plants in Turkey Besides the planning and realisation of hazardous waste treatment centres with CPT, a medium-term strategy for this problem is recommended: o Sludge dewatering with filter press or decanter centrifuge o Solar supported sludge drying, e.g. with low temperature waste heat utilisation from cement production plants o Heat utilisation of dried sludge in cement kilns or coal fired power stations 64
  • 71.
    This alternative shouldbe stipulated, because landfilling of sewage sludge is not state of the art. 65
  • 72.
    APPENDIX Table A. 1List of NUTS codes for Turkey NUTS 1 : REGIONS NUTS 3: PROVINCES TR811 Zonguldak TR1 Đstanbul TR100 Đstanbul TR812 Karabük TR2 Western Marmara TR211 Tekirdağ TR813 Bartın TR3 Aegean TR212 Edirne TR821 Kastamonu TR4 Eastern Marmara TR213 Kırklareli TR822 Çankırı TR5 West Anatolia TR221 Balıkesir TR823 Sinop TR6 Mediterranean TR222 Çanakkale TR831 Samsun TR7 Central Anatolia TR310 Đzmir TR832 Tokat TR8 Western Black Sea TR321 Aydın TR833 Çorum TR9 Eastern Black Sea TR322 Denizli TR834 Amasya TRA Northeastern Anatolia TR323 Muğla TR901 Trabzon TRB Central Eastern Anatolia TR331 Manisa TR902 Ordu TRC Southeastern Anatolia TR332 Afyon TR903 Giresun NUTS 2: SUB-REGIONS TR333 Kütahya TR904 Rize TR10 Đstanbul TR334 Uşak TR905 Artvin TR21 Tekirdağ, Edirne, Kırklareli TR411 Bursa TR906 Gümüşhane TR22 Balıkesir, Çanakkale TR412 Eskişehir TRA11 Erzurum TR31 Đzmir TR413 Bilecik TRA12 Erzincan TR32 Aydın, Denizli, Muğla TR421 Kocaeli TRA13 Bayburt TR33 Manisa, Afyon, Kütahya, Uşak TR422 Sakarya TRA21 Ağrı TR41 Bursa, Eskişehir, Bilecik TR423 Düzce TRA22 Kars Kocaeli, Sakarya, Düzce, Bolu, TR42 TR424 Bolu TRA23 Iğdır Yalova TR51 Ankara TR425 Yalova TRA24 Ardahan TR52 Konya, Karaman TR510 Ankara TRB11 Malatya TR61 Antalya, Isparta, Burdur TR521 Konya TRB12 Elazığ TR62 Adana, Mersin TR522 Karaman TRB13 Bingöl TR63 Hatay, Kahramanmaraş, Osmaniye TR611 Antalya TRB14 Tunceli Kırıkkale, Aksaray, Niğde, TR71 TR612 Isparta TRB21 Van Nevşehir, Kırşehir TR72 Kayseri, Sivas, Yozgat TR613 Burdur TRB22 Muş TR81 Zonguldak, Karabük, Bartın TR621 Adana TRB23 Bitlis TR82 Kastamonu, Çankırı,Sinop TR622 Mersin TRB24 Hakkari TR83 Samsun, Tokat, Çorum, Amasya TR631 Hatay TRC11 Gaziantep Trabzon, Ordu, Giresun, Rize, TR90 TR632 K.maraş TRC12 Adıyaman Artvin, Gümüşhane TRA1 Erzurum, Erzincan, Bayburt TR633 Osmaniye TRC13 Kilis TRA2 Ağrı, Kars, Iğdır, Ardahan TR711 Kırıkkale TRC21 Şanlıurfa TRB1 Malatya, Elazığ, Bingöl, Tunceli TR712 Aksaray TRC22 Diyarbakır TRB2 Van, Muş, Bitlis, Hakkari TR713 Niğde TRC31 Mardin TRC1 Gaziantep, Adıyaman, Kilis TR714 Nevşehir TRC32 Batman TRC2 Şanlıurfa, Diyarbakır TR715 Kırşehir TRC33 Şırnak TRC3 Mardin, Batman, Şırnak, Siirt TR721 Kayseri TRC34 Siirt 66
  • 73.
    Table A. 2Turkish population (2007) 67
  • 74.
    Figure A. 1Number of employees in Turkish Industry (2007) 68
  • 75.
    Figure A. 1continued 69
  • 76.
    Table A. 3Number of employees in Turkish industry (2007) 70
  • 77.
    Table A. 4Additional information for provinces EMPLOYEE PROVINCE NUTS3 CAPITA VEHICLES GNP2001[%] (AGRICULTURE) Đstanbul TR100 12,573,836 2,612,379 30,279 21.30 Tekirdağ TR211 728,396 121,355 45,672 1.08 Edirne TR212 396,462 93,425 49,681 0.65 Kırklareli TR213 333,256 70,620 35,306 0.80 Balıkesir TR221 1,118,313 280,672 134,679 1.47 Çanakkale TR222 476,128 122,891 75,282 0.74 Đzmir TR310 3,739,353 879,957 119,157 7.50 Aydın TR321 946,971 257,138 112,105 1.31 Denizli TR322 907,325 240,595 120,367 1.23 Muğla TR323 766,156 277,692 115,346 1.64 Manisa TR331 1,319,920 358,306 150,970 2.11 Afyonkarahisar TR332 701,572 129,884 103,688 0.70 Kütahya TR333 583,910 130,192 82,396 0.81 Uşak TR334 334,115 77,577 44,754 0.32 Bursa TR411 2,439,876 480,896 99,586 3.65 Eskişehir TR412 724,849 166,424 33,814 1.21 Bilecik TR413 203,777 37,801 22,081 0.34 Kocaeli TR421 1,437,926 195,888 43,170 5.13 Sakarya TR422 835,222 153,659 67,199 1.07 Düzce TR423 323,328 57,570 41,810 0.25 Bolu TR424 270,417 66,843 33,845 0.77 Yalova TR425 181,758 26,760 10,991 0.40 Ankara TR510 4,466,756 1,159,660 89,724 7.59 Konya TR521 1,959,082 416,365 182,829 2.38 Karaman TR522 226,049 55,052 36,464 0.33 Antalya TR611 1,789,295 612,069 134,873 2.64 Isparta TR612 419,845 107,608 52,067 0.53 Burdur TR613 251,181 81,303 46,086 0.34 Adana TR621 2,006,650 388,269 80,207 2.98 Mersin TR622 1,595,938 340,355 95,445 2.82 Hatay TR631 1,386,224 277,293 114,813 1.48 Kahramanmaraş TR632 1,004,414 117,892 91,834 1.08 Osmaniye TR633 452,880 87,890 29,670 0.37 Kırıkkale TR711 280,234 30,546 21,897 0.71 Aksaray TR712 366,109 60,429 45,288 0.27 Niğde TR713 331,677 56,409 41,668 0.42 Nevşehir TR714 280,058 63,651 53,532 0.45 Kırşehir TR715 223,170 34,740 28,941 0.25 Kayseri TR721 1,165,088 209,592 86,814 1.31 Sivas TR722 638,464 85,733 79,584 0.71 Yozgat TR723 492,127 61,858 78,328 0.40 Zonguldak TR811 615,890 99,146 65,098 1.23 Karabük TR812 218,463 39,954 26,375 0.24 Bartın TR813 182,131 28,223 33,895 0.13 Kastamonu TR821 360,366 74,575 73,682 0.45 Çankırı TR822 174,012 24,293 29,456 0.21 Sinop TR823 198,412 30,789 43,723 0.22 Samsun TR831 1,228,959 201,755 132,988 1.37 Tokat TR832 620,722 105,556 79,741 0.78 Çorum TR833 549,828 107,075 80,064 0.67 71
  • 78.
    Table A. 4continued EMPLOYEE PROVINCE NUTS3 CAPITA VEHICLES GNP2001[%] (AGRICULTURE) Amasya TR834 328,674 63,846 39,023 0.36 Trabzon TR901 740,569 91,594 115,476 1.01 Ordu TR902 715,409 69,940 129,023 0.64 Giresun TR903 417,505 45,501 98,222 0.51 Rize TR904 316,252 37,854 80,800 0.47 Artvin TR905 168,092 19,871 45,297 0.28 Gümüşhane TR906 130,825 12,407 21,602 0.14 Erzurum TRA11 784,941 65,151 81,387 0.68 Erzincan TRA12 213,538 34,166 34,360 0.25 Bayburt TRA13 76,609 7,827 11,411 0.07 Ağrı TRA21 530,879 21,651 47,943 0.21 Kars TRA22 312,205 25,242 38,586 0.19 Iğdır TRA23 181,866 14,214 18,982 0.10 Ardahan TRA24 112,721 8,104 24,100 0.08 Malatya TRB11 722,065 89,354 63,033 0.83 Elazığ TRB12 541,258 62,420 47,497 0.66 Bingöl TRB13 251,552 8,669 33,537 0.14 Tunceli TRB14 84,022 3,974 12,171 0.10 Van TRB21 979,671 53,091 58,906 0.52 Muş TRB22 405,509 17,105 46,339 0.18 Bitlis TRB23 327,886 12,335 29,346 0.17 Hakkari TRB24 246,469 6,498 17,709 0.14 Gaziantep TRC11 1,560,023 265,241 44,361 1.42 Adıyaman TRC12 582,762 52,952 54,864 0.39 Kilis TRC13 118,457 23,518 9,245 0.14 Şanlıurfa TRC21 1,523,099 149,783 90,618 1.01 Diyarbakır TRC22 1,460,714 78,030 72,374 1.23 Mardin TRC31 745,778 39,950 44,911 0.48 Batman TRC32 472,487 26,182 23,232 0.38 Şırnak TRC33 416,001 24,440 18,133 0.16 Siirt TRC34 291,528 10,457 20,248 0.20 TOTAL 70,586,256 13,237,971 5,000,000 100.00 72
  • 79.
    Table A. 5Hazardous waste in Turkey, from industry and other sources in tons/yr PROVINCE NUTS 3 TOTAL FROM INDUSTRY FROM OTHER SOURCES Đstanbul TR100 314,249 265,627 48,621 Tekirdağ TR211 32,285 29,910 2,374 Edirne TR212 2,921 1,189 1,732 Kırklareli TR213 14,942 13,613 1,329 Balıkesir TR221 15,532 10,383 5,149 Çanakkale TR222 17,877 15,622 2,255 Đzmir TR310 104,692 88,568 16,123 Aydın TR321 10,459 5,797 4,662 Denizli TR322 23,151 18,767 4,384 Muğla TR323 6,947 2,079 4,868 Manisa TR331 40,363 33,870 6,493 Afyonkarahisar TR332 6,872 4,350 2,522 Kütahya TR333 8,354 5,913 2,441 Uşak TR334 6,333 4,890 1,443 Bursa TR411 92,391 83,310 9,082 Eskişehir TR412 25,330 22,264 3,067 Bilecik TR413 9,349 8,619 729 Kocaeli TR421 130,577 126,595 3,982 Sakarya TR422 24,283 21,326 2,957 Düzce TR423 8,863 7,739 1,123 Bolu TR424 6,897 5,667 1,230 Yalova TR425 5,895 5,358 538 Ankara TR510 89,027 68,109 20,919 Konya TR521 34,549 26,730 7,819 Karaman TR522 1,859 839 1,020 Antalya TR611 18,830 8,101 10,729 Isparta TR612 4,663 2,695 1,969 Burdur TR613 2,693 1,243 1,449 Adana TR621 30,511 23,155 7,355 Mersin TR622 18,083 11,725 6,358 Hatay TR631 37,242 31,987 5,255 Kahramanmaraş TR632 7,523 5,002 2,521 Osmaniye TR633 3,421 1,750 1,670 Kırıkkale TR711 8,474 7,809 665 Aksaray TR712 4,643 3,446 1,197 Niğde TR713 3,759 2,648 1,111 Nevşehir TR714 2,327 1,130 1,197 Kırşehir TR715 4,403 3,705 698 Kayseri TR721 22,871 18,825 4,046 Sivas TR722 5,160 3,378 1,782 Yozgat TR723 2,600 1,283 1,317 Zonguldak TR811 25,242 23,274 1,968 Karabük TR812 14,457 13,683 774 Bartın TR813 1,205 632 573 73
  • 80.
    Kastamonu TR821 2,577 1,148 1,429 Table A. 5 Continued PROVINCE NUTS 3 TOTAL FROM INDUSTRY FROM OTHER SOURCES Çankırı TR822 2,003 1,498 504 Sinop TR823 1,396 768 629 Samsun TR831 13,531 9,541 3,990 Tokat TR832 3,454 1,375 2,079 Çorum TR833 6,992 4,934 2,058 Amasya TR834 2,639 1,416 1,223 Trabzon TR901 4,160 2,202 1,958 Ordu TR902 3,474 1,861 1,612 Giresun TR903 1,788 762 1,026 Rize TR904 2,301 1,468 834 Artvin TR905 1,688 1,248 441 Gümüşhane TR906 486 198 288 Erzurum TRA11 3,287 1,731 1,556 Erzincan TRA12 942 256 686 Bayburt TRA13 221 44 177 Ağrı TRA21 806 106 700 Kars TRA22 879 268 612 Iğdır TRA23 357 10 347 Ardahan TRA24 215 5 211 Malatya TRB11 3,458 1,576 1,882 Elazığ TRB12 3,410 2,069 1,340 Bingöl TRB13 349 36 313 Tunceli TRB14 144 22 122 Van TRB21 2,638 1,159 1,479 Muş TRB22 763 215 549 Bitlis TRB23 516 100 416 Hakkari TRB24 293 26 267 Gaziantep TRC11 14,128 8,988 5,139 Adıyaman TRC12 2,204 980 1,223 Kilis TRC13 644 198 446 Şanlıurfa TRC21 4,908 1,563 3,345 Diyarbakır TRC22 3,702 1,523 2,180 Mardin TRC31 2,171 1,052 1,119 Batman TRC32 3,533 2,814 720 Şırnak TRC33 1,514 860 654 Siirt TRC34 678 320 359 74
  • 81.
    Table A. 6Hazardous waste from main industrial sectors in tons/yr PROVINCE NUTS 3 METAL INDUSTRY CHEMICAL INDUSTRY OTHER INDUSTRIES Đstanbul TR100 152,871 83,003 29,753 Tekirdağ TR211 11,833 10,960 7,117 Edirne TR212 243 329 617 Kırklareli TR213 1,561 7,074 4,978 Balıkesir TR221 2,866 6,486 1,030 Çanakkale TR222 2,921 9,614 3,087 Đzmir TR310 47,813 32,251 8,505 Aydın TR321 3,035 1,393 1,370 Denizli TR322 4,840 7,294 6,633 Muğla TR323 610 726 744 Manisa TR331 23,190 7,258 3,422 Afyonkarahisar TR332 624 2,648 1,077 Kütahya TR333 1,018 3,462 1,434 Uşak TR334 727 3,028 1,135 Bursa TR411 55,367 17,585 10,358 Eskişehir TR412 13,454 6,987 1,823 Bilecik TR413 3,997 2,479 2,143 Kocaeli TR421 54,034 62,149 10,412 Sakarya TR422 14,186 5,801 1,339 Düzce TR423 2,933 3,869 938 Bolu TR424 4,046 908 713 Yalova TR425 928 4,239 191 Ankara TR510 46,851 9,599 11,659 Konya TR521 18,486 4,817 3,427 Karaman TR522 277 190 372 Antalya TR611 3,286 3,380 1,435 Isparta TR612 191 525 1,979 Burdur TR613 677 17 549 Adana TR621 10,547 9,345 3,263 Mersin TR622 3,993 6,292 1,440 Hatay TR631 10,606 20,900 480 Kahramanmaraş TR632 2,353 361 2,287 Osmaniye TR633 853 674 223 Kırıkkale TR711 2,667 5,046 96 Aksaray TR712 2,582 629 235 Niğde TR713 629 1,644 375 Nevşehir TR714 412 397 321 Kırşehir TR715 411 3,171 124 Kayseri TR721 10,879 2,658 5,288 Sivas TR722 2,547 424 406 Yozgat TR723 473 280 529 Zonguldak TR811 6,035 16,703 536 Karabük TR812 3,938 9,629 116 Bartın TR813 63 178 391 75
  • 82.
    Kastamonu TR821 430 98 620 Table A. 6 Continued PROVINCE NUTS 3 METAL INDUSTRY CHEMICAL INDUSTRY OTHER INDUSTRIES Çankırı TR822 1,065 246 188 Sinop TR823 267 105 395 Samsun TR831 3,674 4,608 1,259 Tokat TR832 310 403 662 Çorum TR833 1,876 2,060 998 Amasya TR834 794 254 368 Trabzon TR901 1,566 163 472 Ordu TR902 380 1,012 469 Giresun TR903 199 332 231 Rize TR904 46 420 1,002 Artvin TR905 290 192 766 Gümüşhane TR906 68 78 52 Erzurum TRA11 465 993 274 Erzincan TRA12 61 44 151 Bayburt TRA13 0 0 44 Ağrı TRA21 0 39 68 Kars TRA22 139 29 100 Iğdır TRA23 0 0 10 Ardahan TRA24 0 0 5 Malatya TRB11 472 225 879 Elazığ TRB12 1,321 298 450 Bingöl TRB13 0 0 36 Tunceli TRB14 0 0 22 Van TRB21 63 799 296 Muş TRB22 109 34 72 Bitlis TRB23 9 62 28 Hakkari TRB24 0 0 26 Gaziantep TRC11 1,996 3,022 3,971 Adıyaman TRC12 107 239 634 Kilis TRC13 0 170 28 Şanlıurfa TRC21 601 204 758 Diyarbakır TRC22 409 564 549 Mardin TRC31 150 674 229 Batman TRC32 0 2,640 174 Şırnak TRC33 0 403 458 Siirt TRC34 83 54 182 76
  • 83.
    Table A. 7Hazardous waste from non-industrial sources in tons/yr PROVINCE NUTS 3 SEPARATE COLLECTION CAR REPAIR AGRICULTURE Đstanbul TR100 7,972 40,633 17 Tekirdağ TR211 462 1,888 25 Edirne TR212 251 1,453 27 Kırklareli TR213 211 1,098 19 Balıkesir TR221 709 4,366 74 Çanakkale TR222 302 1,911 41 Đzmir TR310 2,371 13,687 66 Aydın TR321 600 4,000 62 Denizli TR322 575 3,742 66 Muğla TR323 486 4,319 63 Manisa TR331 837 5,573 83 Afyonkarahisar TR332 445 2,020 57 Kütahya TR333 370 2,025 45 Uşak TR334 212 1,207 25 Bursa TR411 1,547 7,480 55 Eskişehir TR412 460 2,589 19 Bilecik TR413 129 588 12 Kocaeli TR421 912 3,047 24 Sakarya TR422 530 2,390 37 Düzce TR423 205 895 23 Bolu TR424 171 1,040 19 Yalova TR425 115 416 6 Ankara TR510 2,832 18,037 49 Konya TR521 1,242 6,476 101 Karaman TR522 143 856 20 Antalya TR611 1,134 9,520 74 Isparta TR612 266 1,674 29 Burdur TR613 159 1,265 25 Adana TR621 1,272 6,039 44 Mersin TR622 1,012 5,294 52 Hatay TR631 879 4,313 63 Kahramanmaraş TR632 637 1,834 51 Osmaniye TR633 287 1,367 16 Kırıkkale TR711 178 475 12 Aksaray TR712 232 940 25 Niğde TR713 210 877 23 Nevşehir TR714 178 990 29 Kırşehir TR715 141 540 16 Kayseri TR721 739 3,260 48 Sivas TR722 405 1,333 44 Yozgat TR723 312 962 43 Zonguldak TR811 390 1,542 36 Karabük TR812 139 621 15 Bartın TR813 115 439 19 77
  • 84.
    Kastamonu TR821 228 1,160 41 Table A. 7 Continued PROVINCE NUTS 3 SEPARATE COLLECTION CAR REPAIR AGRICULTURE Çankırı TR822 110 378 16 Sinop TR823 126 479 24 Samsun TR831 779 3,138 73 Tokat TR832 394 1,642 44 Çorum TR833 349 1,665 44 Amasya TR834 208 993 21 Trabzon TR901 470 1,425 64 Ordu TR902 454 1,088 71 Giresun TR903 265 708 54 Rize TR904 201 589 44 Artvin TR905 107 309 25 Gümüşhane TR906 83 193 12 Erzurum TRA11 498 1,013 45 Erzincan TRA12 135 531 19 Bayburt TRA13 49 122 6 Ağrı TRA21 337 337 26 Kars TRA22 198 393 21 Iğdır TRA23 115 221 10 Ardahan TRA24 71 126 13 Malatya TRB11 458 1,390 35 Elazığ TRB12 343 971 26 Bingöl TRB13 159 135 18 Tunceli TRB14 53 62 7 Van TRB21 621 826 32 Muş TRB22 257 266 25 Bitlis TRB23 208 192 16 Hakkari TRB24 156 101 10 Gaziantep TRC11 989 4,126 24 Adıyaman TRC12 369 824 30 Kilis TRC13 75 366 5 Şanlıurfa TRC21 966 2,330 50 Diyarbakır TRC22 926 1,214 40 Mardin TRC31 473 621 25 Batman TRC32 300 407 13 Şırnak TRC33 264 380 10 Siirt TRC34 185 163 11 78
  • 85.
    Table A. 8AHazardous waste from industrial branches in tons/yr BATTERY CEMENT INORGANIC FERTILIZER ORGANIC OTHER PAINT ELECTRICAL ENERGY PROVINCE NUTS 3 IND. IND. CHEMISTRY IND. CHEMISTRY CHEMISTRY IND. IND. GENERATION Đstanbul TR100 5,976 25 641 274 9,433 63,455 5,579 21,393 400 Tekirdağ TR211 0 0 31 0 1,317 8,896 285 1,905 1,601 Edirne TR212 0 16 0 0 0 329 0 0 0 Kırklareli TR213 0 11 11 744 341 5,945 11 81 3,492 Balıkesir TR221 57 8 752 781 3,378 1,444 75 346 0 Çanakkale TR222 0 20 50 0 114 9,438 12 3 1,639 Đzmir TR310 289 30 170 622 7,189 13,812 1,738 4,958 1,445 Aydın TR321 30 10 0 0 338 979 0 51 358 Denizli TR322 0 10 188 0 980 5,495 54 460 1,142 Muğla TR323 0 3 97 0 229 131 0 0 177 Manisa TR331 1,324 1 0 87 489 4,175 121 3,595 621 Afyonkarahisar TR332 0 14 70 21 886 1,671 0 0 0 Kütahya TR333 49 5 373 170 1,418 691 48 20 0 Uşak TR334 0 0 14 0 1,651 844 6 27 0 Bursa TR411 0 22 0 77 2,328 12,842 230 3,506 872 Eskişehir TR412 0 11 1,692 0 2,704 2,147 233 681 122 Bilecik TR413 0 1 36 0 90 2,337 16 56 21 Kocaeli TR421 235 34 932 1,124 11,021 36,378 3,872 3,810 6,925 Sakarya TR422 0 2 176 0 204 5,052 31 1,102 0 Düzce TR423 0 0 0 0 105 3,726 0 55 0 Bolu TR424 0 12 17 0 0 444 0 1,086 0 Yalova TR425 130 0 11 0 4,199 29 0 6 0 Ankara TR510 467 62 269 173 128 5,365 715 4,399 6,814 Konya TR521 0 8 887 389 109 2,794 115 285 1,279 79
  • 86.
    Karaman TR522 0 0 0 0 161 29 0 7 0 Table A. 8A Continued BATTERY CEMENT INORGANIC FERTILIZER ORGANIC OTHER PAINT ELECTRICAL ENERGY PROVINCE NUTS 3 IND. IND. CHEMISTRY IND. CHEMISTRY CHEMISTRY IND. IND. GENERATION Antalya TR611 85 16 166 705 331 1,220 128 245 40 Isparta TR612 0 11 0 0 51 474 0 0 1,335 Burdur TR613 45 26 0 0 0 17 0 21 0 Adana TR621 0 30 34 431 6,704 1,545 174 115 1,264 Mersin TR622 0 22 1,281 295 2,028 2,182 65 68 242 Hatay TR631 0 9 148 2,665 4,984 648 85 7 0 Kahramanmaraş TR632 0 9 0 23 0 166 0 3 413 Osmaniye TR633 0 2 0 19 29 203 17 18 0 Kırıkkale TR711 0 0 0 0 704 1,761 27 0 0 Aksaray TR712 0 0 0 89 59 472 9 21 0 Niğde TR713 0 8 10 0 55 1,481 0 6 0 Nevşehir TR714 0 8 0 0 36 361 0 0 0 Kırşehir TR715 0 1 0 0 0 3,148 23 0 0 Kayseri TR721 138 6 708 0 24 1,364 91 778 392 Sivas TR722 0 23 0 33 0 185 8 3 0 Yozgat TR723 0 13 9 25 0 198 0 42 0 Zonguldak TR811 0 5 4,182 0 0 462 0 20 21 Karabük TR812 0 2 0 0 4,337 0 0 9 0 Bartın TR813 0 11 0 0 0 161 17 0 0 Kastamonu TR821 0 0 0 0 63 35 0 95 0 Çankırı TR822 0 2 0 0 0 198 0 346 0 Sinop TR823 0 3 0 0 0 0 0 0 0 Samsun TR831 0 22 0 705 2,008 1,444 29 216 569 80
  • 87.
    Tokat TR832 0 17 0 0 41 300 0 0 0 Table A. 8A Continued BATTERY CEMENT INORGANIC FERTILIZER ORGANIC OTHER PAINT ELECTRICAL ENERGY PROVINCE NUTS 3 IND. IND. CHEMISTRY IND. CHEMISTRY CHEMISTRY IND. IND. GENERATION Çorum TR833 0 9 40 19 0 227 0 15 0 Amasya TR834 0 0 30 19 71 134 0 154 0 Trabzon TR901 0 8 0 0 0 163 0 57 0 Ordu TR902 0 13 0 0 0 515 42 30 0 Giresun TR903 0 0 0 54 0 0 0 7 0 Rize TR904 0 0 0 0 0 0 25 0 0 Artvin TR905 0 0 0 0 0 0 0 0 632 Gümüşhane TR906 0 2 0 0 0 57 22 0 0 Erzurum TRA11 0 13 0 0 63 38 36 0 0 Erzincan TRA12 0 0 0 0 0 44 0 0 67 Bayburt TRA13 0 0 0 0 0 0 0 0 0 Ağrı TRA21 0 2 0 0 0 15 0 0 0 Kars TRA22 0 10 0 0 0 29 0 0 0 Iğdır TRA23 0 0 0 0 0 0 0 0 0 Ardahan TRA24 0 0 0 0 0 0 0 0 0 Malatya TRB11 0 4 0 0 18 73 33 164 80 Elazığ TRB12 0 15 0 0 185 114 0 71 0 Bingöl TRB13 0 0 0 0 0 0 0 0 0 Tunceli TRB14 0 0 0 0 0 0 0 0 0 Van TRB21 0 16 0 0 0 47 0 6 143 Muş TRB22 0 0 0 0 22 0 12 0 0 81
  • 88.
    Bitlis TRB23 0 0 0 0 0 0 0 2 0 Hakkari TRB24 0 0 0 0 0 0 0 0 0 Gaziantep TRC11 57 15 9 52 628 1,440 135 17 24 Table A. 8A Continued BATTERY CEMENT INORGANIC FERTILIZER ORGANIC OTHER PAINT ELECTRICAL ENERGY PROVINCE NUTS 3 IND. IND. CHEMISTRY IND. CHEMISTRY CHEMISTRY IND. IND. GENERATION Adıyaman TRC12 0 7 0 48 0 191 0 37 0 Kilis TRC13 0 0 0 0 0 41 0 0 0 Şanlıurfa TRC21 0 9 0 21 0 73 0 126 413 Diyarbakır TRC22 0 26 0 0 0 232 93 49 0 Mardin TRC31 0 24 0 108 63 98 0 16 122 Batman TRC32 0 5 0 0 0 120 18 0 0 Şırnak TRC33 0 0 0 0 0 0 0 0 436 Siirt TRC34 0 23 0 0 0 0 54 0 122 82
  • 89.
    Table A. 8BHazardous waste from industrial branches in tons/yr NUTS FOOD LEATHER METAL METAL MINERAL NON-FERROUS PAPER PETROLEUM PROVINCE 3 IND. IND. PRODUCTION WORK PRODUCTION METAL PRODUCTION IND. RAFINATION Đstanbul TR100 1,139 1,307 11,353 99,606 2,692 14,543 1,263 3,620 Tekirdağ TR211 150 197 1,243 5,395 384 3,290 171 431 Edirne TR212 70 32 0 243 77 0 9 0 Kırklareli TR213 98 45 825 656 460 0 29 22 Balıkesir TR221 313 13 442 1,871 243 150 18 56 Çanakkale TR222 87 8 1,653 1,266 1,154 0 0 0 Đzmir TR310 874 232 8,332 30,987 1,187 3,246 532 8,719 Aydın TR321 240 9 52 2,804 314 98 6 77 Denizli TR322 61 46 1,246 2,033 1,044 1,100 106 577 Muğla TR323 29 0 0 610 423 0 7 268 Manisa TR331 302 23 428 17,170 1,191 675 70 2,387 Afyonkarahisar TR332 94 5 10 601 781 14 3 0 Kütahya TR333 52 9 99 217 1,077 633 17 762 Uşak TR334 62 12 15 227 270 458 3 513 Bursa TR411 462 96 4,299 47,003 518 558 99 2,109 Eskişehir TR412 107 53 482 11,697 924 594 52 211 Bilecik TR413 22 6 969 2,318 1,742 655 58 0 Kocaeli TR421 203 12 11,380 33,213 507 5,396 320 8,821 Sakarya TR422 170 15 671 12,008 135 405 9 338 Düzce TR423 47 22 1,137 1,670 106 72 10 38 Bolu TR424 78 22 810 2,016 50 134 15 447 Yalova TR425 11 8 0 792 11 0 53 0 Ankara TR510 434 93 4,624 36,078 1,125 1,283 104 2,949 Konya TR521 343 41 2,580 13,877 496 1,745 68 523 83
  • 90.
    Karaman TR522 199 3 0 269 40 0 10 0 Table A. 8B Continued FOOD LEATHER METAL METAL MINERAL NON-FERROUS PAPER PETROLEUM PROVINCE NUTS 3 IND. IND. PRODUCTION WORK PRODUCTION METAL PRODUCTION IND. RAFINATION Antalya TR611 116 16 148 2,704 397 104 21 831 Isparta TR612 20 5 0 191 138 0 18 0 Burdur TR613 46 9 15 596 390 0 0 0 Adana TR621 175 36 1,153 8,989 190 290 92 458 Mersin TR622 131 57 585 3,283 472 57 69 441 Hatay TR631 66 3 7,601 2,820 40 178 12 12,370 Kahramanmaraş TR632 63 32 121 1,780 114 450 23 173 Osmaniye TR633 22 6 370 465 26 0 12 407 Kırıkkale TR711 9 1 392 2,267 28 8 6 2,553 Aksaray TR712 35 7 37 2,523 68 0 2 0 Niğde TR713 42 1 21 528 84 74 0 98 Nevşehir TR714 25 2 113 291 197 7 0 0 Kırşehir TR715 32 3 200 211 41 0 0 0 Kayseri TR721 116 9 1,105 8,032 317 825 46 472 Sivas TR722 26 9 1,132 1,155 114 257 2 198 Yozgat TR723 97 16 0 420 177 11 14 48 Zonguldak TR811 39 16 4,921 1,094 205 0 42 12,058 Karabük TR812 6 21 3,521 408 11 0 0 5,293 Bartın TR813 8 22 6 57 119 0 7 0 Kastamonu TR821 34 20 5 330 87 0 10 0 Çankırı TR822 24 10 44 675 40 0 0 48 Sinop TR823 15 18 34 182 238 51 0 105 Samsun TR831 165 17 768 1,663 155 1,027 30 421 84
  • 91.
    Tokat TR832 94 18 43 241 269 25 1 62 Table A. 8B Continued FOOD LEATHER METAL METAL MINERAL NON-FERROUS PAPER PETROLEUM PROVINCE NUTS 3 IND. IND. PRODUCTION WORK PRODUCTION METAL PRODUCTION IND. RAFINATION Çorum TR833 68 47 194 1,430 639 237 60 1,774 Amasya TR834 36 4 61 408 88 172 0 0 Trabzon TR901 185 6 113 1,215 97 182 4 0 Ordu TR902 117 14 0 350 109 0 26 455 Giresun TR903 61 3 0 178 15 14 33 278 Rize TR904 916 0 0 46 58 0 2 395 Artvin TR905 65 0 0 290 55 0 0 192 Gümüşhane TR906 7 3 0 19 19 49 0 0 Erzurum TRA11 50 1 10 455 81 0 1 856 Erzincan TRA12 43 0 0 61 29 0 0 0 Bayburt TRA13 2 1 0 0 19 0 0 0 Ağrı TRA21 37 2 0 0 25 0 0 24 Kars TRA22 27 13 45 93 44 0 0 0 Iğdır TRA23 6 0 0 0 0 0 0 0 Ardahan TRA24 1 0 0 0 0 0 0 0 Malatya TRB11 105 14 0 308 57 0 20 101 Elazığ TRB12 44 1 833 418 211 0 3 0 Bingöl TRB13 6 1 0 0 27 0 0 0 Tunceli TRB14 4 0 0 0 19 0 0 0 Van TRB21 59 0 0 57 37 0 1 753 Muş TRB22 60 0 0 109 11 0 0 0 85
  • 92.
    Bitlis TRB23 9 1 0 8 14 0 0 62 Hakkari TRB24 6 0 0 0 6 0 0 0 Gaziantep TRC11 68 47 194 1,430 639 237 60 1,774 Table A. 8B Continued FOOD LEATHER METAL METAL MINERAL NON-FERROUS PAPER PETROLEUM PROVINCE NUTS 3 IND. IND. PRODUCTION WORK PRODUCTION METAL PRODUCTION IND. RAFINATION Adıyaman TRC12 216 6 42 1,749 90 131 94 757 Kilis TRC13 15 10 0 70 46 0 8 0 Şanlıurfa TRC21 6 0 0 0 0 0 0 129 Diyarbakır TRC22 34 0 310 165 55 0 2 110 Mardin TRC31 92 0 10 351 228 0 1 240 Batman TRC32 14 0 0 77 44 56 0 405 Şırnak TRC33 28 1 0 0 77 0 1 2,502 Siirt TRC34 4 0 0 0 16 0 0 403 86
  • 93.
    Table A. 8CHazardous waste from industrial branches in tons/yr NUTS PLASTICS PRINTING TEXTILE WOOD PROVINCE 3 MANUFACTURE IND. IND. IND Đstanbul TR100 4,588 3,834 12,162 2,343 Tekirdağ TR211 392 200 3,784 240 Edirne TR212 7 4 402 0 Kırklareli TR213 38 34 719 51 Balıkesir TR221 44 17 79 296 Çanakkale TR222 66 0 19 95 Đzmir TR310 1,125 512 1,309 1,258 Aydın TR321 17 4 308 103 Denizli TR322 214 43 3,863 104 Muğla TR323 8 5 16 76 Manisa TR331 334 174 172 531 Afyonkarahisar TR332 30 6 56 90 Kütahya TR333 44 8 68 155 Uşak TR334 15 2 717 52 Bursa TR411 797 204 5,155 2,132 Eskişehir TR412 224 32 40 257 Bilecik TR413 45 0 95 152 Kocaeli TR421 1,226 53 337 795 Sakarya TR422 185 14 396 413 Düzce TR423 71 29 295 358 Bolu TR424 59 6 136 335 Yalova TR425 20 0 81 7 Ankara TR510 467 821 383 1,356 Konya TR521 341 185 268 397 Karaman TR522 24 29 32 34 Antalya TR611 195 55 254 325 Isparta TR612 13 16 212 210 Burdur TR613 7 0 4 66 Adana TR621 258 98 772 348 Mersin TR622 64 11 134 238 Hatay TR631 54 23 189 85 Kahramanmaraş TR632 29 0 1,576 29 Osmaniye TR633 15 4 122 14 Kırıkkale TR711 4 0 1 47 Aksaray TR712 43 0 58 22 Niğde TR713 3 0 212 25 Nevşehir TR714 3 0 81 5 Kırşehir TR715 6 0 16 23 Kayseri TR721 312 70 1,106 2,913 Sivas TR722 24 6 50 151 Yozgat TR723 25 0 107 80 Zonguldak TR811 15 2 90 102 Karabük TR812 1 0 35 41 87
  • 94.
    Bartın TR813 19 0 139 67 Table A. 8C Continued PLASTICS PRINTING WOOD PROVINCE NUTS 3 TEXTILE IND. MANUFACTURE IND. IND Kastamonu TR821 10 0 60 400 Çankırı TR822 11 0 77 24 Sinop TR823 23 0 50 49 Samsun TR831 105 13 38 146 Tokat TR832 16 5 125 116 Çorum TR833 13 10 44 109 Amasya TR834 31 9 81 118 Trabzon TR901 47 32 11 82 Ordu TR902 18 0 62 110 Giresun TR903 6 3 21 89 Rize TR904 5 0 0 21 Artvin TR905 1 0 0 14 Gümüşhane TR906 4 0 14 4 Erzurum TRA11 11 8 94 13 Erzincan TRA12 3 0 0 8 Bayburt TRA13 18 0 2 3 Ağrı TRA21 1 0 0 0 Kars TRA22 0 0 0 7 Iğdır TRA23 0 4 0 0 Ardahan TRA24 0 0 0 3 Malatya TRB11 29 9 525 35 Elazığ TRB12 49 0 22 104 Bingöl TRB13 0 0 3 0 Tunceli TRB14 0 0 0 0 Van TRB21 8 0 27 3 Muş TRB22 1 0 0 0 Bitlis TRB23 1 0 4 0 Hakkari TRB24 0 0 13 0 Gaziantep TRC11 395 197 2,901 34 Adıyaman TRC12 3 3 526 16 Kilis TRC13 8 0 14 0 Şanlıurfa TRC21 19 0 225 0 Diyarbakır TRC22 31 0 133 39 Mardin TRC31 11 0 12 2 Batman TRC32 13 0 45 3 Şırnak TRC33 1 0 0 0 Siirt TRC34 3 0 18 0 88
  • 95.
    Table A. 9AHazardous waste groups in Turkish provinces in tons/yr WASTE GROUP ID PROVINCES 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 Đstanbul 582 232 9,619 3,033 14,538 15,003 54,064 15,583 2,543 392 28,424 2,157 13,858 49,758 507 17,876 12,331 3,312 10,211 Tekirdağ 58 24 2,884 361 1,970 1,071 7,364 1,381 144 1,568 4,221 304 952 3,207 42 967 708 222 752 Edirne 45 0 312 0 75 15 229 100 5 0 3 76 21 721 6 279 139 20 65 Kırklareli 34 5 552 19 1,289 903 4,380 216 26 3,419 741 375 77 880 19 291 170 30 110 Balıkesir 124 29 65 47 1,003 1,029 3,935 466 18 0 590 200 246 2,518 31 991 532 105 270 Çanakkale 63 9 18 0 2,073 247 6,581 222 2 1,605 1,484 933 111 1,398 33 518 311 44 127 Đzmir 234 125 1,083 7,305 3,704 3,856 16,526 4,509 390 1,415 10,984 968 3,898 15,880 206 6,173 4,257 957 2,876 Aydın 104 10 231 64 224 143 971 310 8 351 191 258 255 2,540 27 1,005 566 91 287 Denizli 107 10 2,864 483 1,393 361 4,647 804 42 1,118 2,152 836 296 2,766 31 926 546 97 427 Muğla 98 8 12 225 140 26 294 185 8 173 8 338 53 1,912 9 816 410 44 140 Manisa 142 53 139 2,000 1,060 2,549 3,378 1,728 121 608 2,020 946 2,349 7,774 92 2,924 1,982 539 1,594 Afyonkarahisar 89 9 44 0 428 79 1,912 175 8 0 30 631 52 1,119 18 441 217 42 91 Kütahya 72 15 55 639 539 226 1,726 228 10 0 706 858 29 1,057 19 444 219 35 74 Uşak 40 5 534 430 229 36 2,010 143 3 0 440 214 30 698 9 271 141 21 77 Bursa 165 211 3,840 1,766 2,911 3,179 10,953 4,356 148 854 4,949 430 4,905 17,514 207 6,412 4,742 1,130 3,759 Eskişehir 51 25 57 177 2,007 743 3,901 940 29 120 1,131 743 1,178 4,574 61 1,728 1,221 265 863 Bilecik 21 15 73 0 535 148 1,689 277 7 21 1,497 1,383 220 1,190 36 413 281 55 174 Kocaeli 88 79 254 7,390 9,214 4,485 36,164 4,187 74 6,780 15,678 432 3,837 11,941 193 4,584 3,705 824 2,544 Sakarya 75 41 299 283 1,272 914 3,665 981 13 0 1,128 110 1,304 4,603 55 1,711 1,237 302 940 Düzce 38 35 228 32 804 155 2,649 382 20 0 1,098 84 159 965 15 352 249 58 165 Bolu 31 33 111 375 141 476 313 451 7 0 870 50 436 1,215 15 428 292 112 278 Yalova 14 1 64 0 18 77 3,629 107 7 0 88 8 70 414 5 166 103 21 64 Ankara 250 134 330 2,470 1,625 3,267 4,151 3,692 535 6,672 6,045 947 4,183 18,226 176 7,075 4,730 1,046 3,236 Konya 189 39 219 438 1,452 1,031 2,079 1,332 130 1,252 4,088 400 1,283 6,843 83 2,648 1,809 336 1,081 89
  • 96.
    Table A. 9AContinued WASTE GROUP ID PROVINCES 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 Karaman 30 3 25 0 9 12 163 89 20 0 4 32 25 529 12 196 93 15 43 Antalya 155 32 195 696 482 929 1,194 761 45 39 314 330 293 4,643 22 1,944 1,030 142 441 Isparta 48 21 159 0 106 16 371 209 14 1,308 3 119 17 767 4 310 153 29 73 Burdur 37 7 8 0 6 44 14 99 1 0 48 332 56 736 10 293 153 24 72 Adana 134 34 587 384 411 790 6,909 1,091 80 1,238 1,410 177 807 5,146 49 2,031 1,303 248 763 Mersin 124 24 128 369 1,667 514 3,281 561 23 237 615 394 301 3,171 29 1,293 740 131 348 Hatay 126 8 140 10,364 1,070 2,708 4,941 455 22 0 6,952 40 254 2,841 44 1,629 1,167 105 287 Kahramanmaraş 96 3 1,176 145 56 85 120 317 8 404 547 99 158 1,433 12 514 317 71 219 Osmaniye 37 1 93 341 74 44 179 112 6 0 335 22 45 704 4 301 173 27 67 Kırıkkale 25 5 2 2,139 542 112 1,862 141 2 0 385 22 196 841 11 433 313 50 153 Aksaray 41 2 46 0 105 187 380 174 2 0 66 54 223 1,101 11 428 290 58 182 Niğde 38 2 156 82 336 52 1,067 83 2 0 93 74 48 551 6 215 121 23 63 Nevşehir 42 1 61 0 80 17 280 55 1 0 111 163 25 516 5 206 109 16 44 Kırşehir 26 2 13 0 677 74 2,171 56 1 0 180 34 18 313 5 121 68 13 27 Kayseri 100 289 818 396 972 656 1,006 2,375 54 384 1,933 257 888 4,018 42 1,487 999 340 870 Sivas 73 15 42 166 59 75 135 221 7 0 1,259 112 104 927 11 372 250 51 113 Yozgat 65 8 87 40 59 58 140 147 4 0 16 152 46 588 9 225 116 32 61 Zonguldak 64 10 74 10,102 4,642 210 489 253 9 21 4,384 167 104 1,184 29 939 703 48 114 Karabük 24 4 36 4,434 338 17 3,801 102 1 0 3,133 10 41 511 15 414 340 18 44 Bartın 27 7 113 0 36 5 118 93 2 0 6 104 5 226 2 85 41 11 23 Kastamonu 57 40 54 0 11 47 80 293 3 0 9 69 51 606 4 241 123 41 82 Çankırı 24 2 62 40 47 154 138 100 1 0 48 33 141 406 4 141 90 36 88 90
  • 97.
    Sinop 33 5 46 88 9 6 2 78 1 0 80 191 16 285 5 114 59 13 27 Samsun 128 14 36 353 349 851 2,742 409 17 557 1,655 143 205 1,898 22 760 449 93 205 Table A. 9A Continued WASTE GROUP ID PROVINCES 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 Tokat 72 11 102 52 74 14 246 163 6 0 65 229 21 810 10 324 159 34 64 Çorum 69 11 56 1,486 203 77 184 234 15 0 410 515 129 1,185 18 535 316 51 136 Amasya 36 12 62 0 59 93 155 159 7 0 218 70 74 570 5 219 120 32 74 Trabzon 97 8 11 0 42 64 118 210 24 0 285 84 120 1,024 16 392 226 56 121 Ordu 103 11 53 382 146 33 381 187 6 0 5 98 37 616 9 256 133 40 58 Giresun 73 9 17 233 22 61 7 122 8 0 16 12 17 368 4 157 82 24 34 Rize 59 2 0 331 28 1 37 55 2 0 1 46 4 752 51 223 64 14 17 Artvin 32 1 0 161 14 9 5 34 1 619 4 43 25 244 5 99 55 12 26 Gümüşhane 18 0 12 0 13 2 48 24 1 0 46 17 2 89 1 36 18 6 6 Erzurum 80 1 70 717 70 16 111 119 9 0 14 76 39 567 5 262 148 39 56 Erzincan 29 1 0 0 12 3 32 31 1 66 1 23 5 250 3 101 49 10 16 Bayburt 10 0 2 0 1 0 0 23 0 0 0 15 0 52 0 21 10 3 3 Ağrı 50 0 1 20 10 0 13 46 3 0 0 22 0 154 2 62 30 21 8 Kars 35 1 7 0 9 4 22 38 2 0 41 44 8 200 3 80 42 14 15 Iğdır 19 0 0 0 2 0 1 17 3 0 0 0 0 89 0 38 19 7 5 Ardahan 18 0 0 0 1 0 0 12 1 0 0 0 0 50 0 21 11 5 3 Malatya 67 4 393 84 29 72 85 197 12 78 4 48 66 769 8 283 144 44 91 Elazığ 50 10 17 0 30 42 239 177 3 0 745 180 54 595 10 227 140 36 61 Bingöl 30 0 2 0 3 0 1 21 1 0 0 21 0 59 1 24 12 10 3 Tunceli 10 0 0 0 1 0 0 7 0 0 0 15 0 28 0 11 5 3 1 91
  • 98.
    Van 76 0 20 631 67 5 47 97 5 140 1 44 6 378 4 184 97 41 24 Muş 44 0 0 0 4 4 26 41 2 0 1 8 9 167 4 63 33 18 13 Bitlis 31 0 3 52 7 1 2 29 2 0 0 11 1 84 1 37 19 13 5 Hakkari 21 0 10 0 2 0 1 21 1 0 0 5 0 44 0 18 9 10 3 Table A. 9A Continued WASTE GROUP ID PROVINCES 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 Gaziantep 95 3 2,136 634 381 166 1,604 867 138 23 216 85 156 2,571 20 936 511 93 348 Adıyaman 56 2 392 0 47 67 133 112 6 0 1 43 15 414 2 149 75 27 50 Kilis 10 0 10 108 18 1 30 21 1 0 0 0 0 147 0 67 34 5 9 Şanlıurfa 118 0 165 92 38 74 57 194 8 404 277 52 45 1,025 4 420 221 70 84 Diyarbakır 106 4 98 201 79 34 207 215 7 0 13 203 42 672 9 268 141 68 61 Mardin 58 0 9 339 54 116 129 78 4 120 53 56 11 283 2 133 72 32 21 Batman 34 0 34 2,096 189 3 127 60 3 0 0 65 0 189 3 179 106 19 11 Şırnak 29 0 0 337 30 0 7 37 2 427 0 13 0 152 0 81 44 17 9 Siirt 24 0 14 0 3 3 23 43 1 120 1 28 7 94 1 37 21 13 10 92
  • 99.
    Table A. 9BHazardous waste groups in Turkish provinces in tons/yr WASTE GROUP ID PROVINCES 19 20 21 22 23 24 25 26 27 28 Đstanbul 10,211 11,689 7,319 572 784 9,282 20 26,276 512 3,772 Tekirdağ 752 1,177 646 35 36 471 3 1,434 64 219 Edirne 65 115 135 10 28 324 0 63 14 119 Kırklareli 110 546 269 12 21 262 1 177 19 100 Balıkesir 270 889 470 36 84 964 2 519 33 335 Çanakkale 127 779 333 20 37 426 2 340 16 143 Đzmir 2,876 3,920 2,398 187 264 3,073 16 8,227 141 1,122 Aydın 287 378 401 33 77 876 0 743 29 284 Denizli 427 827 594 36 72 839 2 542 59 272 Muğla 140 276 333 31 83 912 1 167 18 230 Manisa 1,594 982 975 81 107 1,230 4 4,542 48 396 Afyonkarahisar 91 354 220 17 39 464 0 166 19 210 Kütahya 74 391 237 17 39 453 2 72 16 175 Uşak 77 357 159 10 23 272 1 65 15 100 Bursa 3,759 2,408 2,129 162 144 1,746 6 12,501 130 732 Eskişehir 863 934 570 48 50 583 4 3,084 26 217 Bilecik 174 252 205 13 11 139 1 621 10 61 Kocaeli 2,544 5,984 1,888 128 59 782 22 8,763 66 431 Sakarya 940 688 551 44 46 556 2 3,181 31 251 Düzce 165 360 193 12 17 210 1 472 13 97 Bolu 278 158 184 14 20 233 1 560 12 81 Yalova 64 575 84 6 8 100 0 208 6 55 Ankara 3,236 2,190 2,467 209 348 3,979 6 9,568 130 1,340 Konya 1,081 877 950 80 125 1,466 3 3,668 59 588 Karaman 43 96 95 7 17 193 0 74 10 68 Antalya 441 743 801 72 184 2,023 2 739 45 537 Isparta 73 145 172 12 32 371 0 71 12 126 Burdur 72 81 122 10 24 271 0 162 7 75 Adana 763 1,511 798 66 116 1,382 1 2,385 58 602 Mersin 348 829 561 46 102 1,190 3 882 42 479 Hatay 287 1,146 618 47 83 978 18 746 37 416 Kahramanmaraş 219 167 252 17 35 465 0 468 37 301 Osmaniye 67 113 124 11 26 311 1 123 11 136 Kırıkkale 153 282 127 9 9 121 4 597 7 84 Aksaray 182 126 134 12 18 220 0 662 10 110 Niğde 63 164 103 7 17 205 0 141 10 100 Nevşehir 44 88 91 8 19 220 0 77 7 84 Kırşehir 27 249 79 5 10 128 1 57 6 67 Kayseri 870 597 738 45 63 762 2 2,389 44 350 Sivas 113 126 158 13 26 323 0 317 16 192 Yozgat 61 91 111 8 19 238 0 118 14 148 Zonguldak 114 411 343 23 30 365 25 296 19 185 Karabük 44 658 159 11 12 144 7 111 8 66 93
  • 100.
    Bartın 23 49 52 4 8 104 0 21 6 55 Table A. 9B Continued WASTE GROUP ID PROVINCES 19 20 21 22 23 24 25 26 27 28 Kastamonu 82 99 130 9 22 262 0 126 10 108 Çankırı 88 51 56 4 7 92 0 179 6 52 Sinop 27 37 57 4 9 114 0 52 6 60 Samsun 205 604 364 29 61 736 1 449 32 369 Tokat 64 136 159 12 32 383 0 75 17 186 Çorum 136 152 212 16 32 381 3 385 17 165 Amasya 74 92 103 8 19 226 0 118 9 99 Trabzon 121 133 166 13 27 354 0 326 20 222 Ordu 58 138 128 9 21 285 1 103 19 215 Giresun 34 57 76 6 14 180 0 55 10 125 Rize 17 146 151 4 11 166 1 14 27 95 Artvin 26 31 48 3 6 80 0 77 5 50 Gümüşhane 6 24 19 2 4 51 0 5 3 39 Erzurum 56 100 106 9 20 276 1 120 18 235 Erzincan 16 38 46 4 10 125 0 17 5 64 Bayburt 3 9 11 1 2 31 0 0 2 23 Ağrı 8 30 35 3 6 119 0 0 12 159 Kars 15 31 39 3 8 108 0 25 7 94 Iğdır 5 14 18 2 4 61 0 0 4 55 Ardahan 3 8 10 1 2 36 0 0 2 34 Malatya 91 125 148 11 27 346 0 84 22 217 Elazığ 61 113 113 9 19 243 0 120 13 162 Bingöl 3 11 14 1 3 51 0 0 5 75 Tunceli 1 5 6 1 1 20 0 0 2 25 Van 24 70 86 7 16 259 1 15 21 294 Muş 13 33 33 2 5 93 0 29 10 122 Bitlis 5 16 20 2 4 70 0 2 7 98 Hakkari 3 9 11 1 2 44 0 0 5 74 Gaziantep 348 561 503 37 80 972 1 461 63 468 Adıyaman 50 72 89 6 16 220 0 20 17 175 Kilis 9 24 28 3 7 83 0 0 3 36 Şanlıurfa 84 156 201 18 45 605 0 43 34 457 Diyarbakır 61 147 139 11 23 384 0 96 33 438 Mardin 21 63 65 5 12 195 1 20 16 224 Batman 11 60 60 4 8 127 4 0 11 142 Şırnak 9 29 40 3 7 116 1 0 9 125 Siirt 21 2 3 61 0 22 6 87 21 2 94
  • 101.
    Figure A. 2Provincial distribution of pesticides and agrochemical hazardous wastes (ID No:1) Figure A. 3 Provincial distribution of wood preservative wastes (ID No:2) 95
  • 102.
    Figure A. 4Provincial distribution of hazardous tannery wastes (ID No:3) Figure A. 5 Provincial distribution of hazardous petroleum refining wastes (ID No:4) 96
  • 103.
    Figure A. 6Provincial distribution of acidic and alkaline wastes (ID No:5) Figure A. 7 Provincial distribution of hazardous inorganic chemistry wastes (ID No:6) 97
  • 104.
    Figure A. 8Provincial distribution of hazardous organic chemistry wastes (ID No:7) Figure A. 9 Provincial distribution of hazardous paint and sealant production wastes (ID No:8) 98
  • 105.
    Figure A. 10Provincial distribution of hazardous printing wastes (ID No:9) Figure A. 11 Provincial distribution of hazardous energy production wastes (ID No:10) 99
  • 106.
    Figure A. 12Provincial distribution of hazardous metal production wastes (ID No:11) Figure A. 13 Provincial distribution of hazardous mineral and glass production wastes (ID No:12) 100
  • 107.
    Figure A. 14Provincial distribution of hazardous galvanizing wastes (ID No:13) Figure A. 15 Provincial distribution of non-halogenated waste oil (ID No:14) 101
  • 108.
    Figure A. 16Provincial distribution of halogenated waste oil (ID No:15) Figure A. 17 Provincial distribution of waste oil emulsions (ID No:16) 102
  • 109.
    Figure A. 18Provincial distribution of other oily wastes (ID No:17) Figure A. 19 Provincial distribution of halogenated solvents (ID No:18) 103
  • 110.
    Figure A. 20Provincial distribution of non-halogenated solvents (ID No:19) Figure A. 21 Provincial distribution of contaminated packagings (ID No:20) 104
  • 111.
    Figure A. 22Provincial distribution of spent adsorbents and filter materials (ID No:21) Figure A. 23 Provincial distribution of spent oil filters (ID No:22) 105
  • 112.
    Figure A. 24Provincial distribution of spent brake fluids and antifreeze (ID No:23) Figure A. 25 Provincial distribution of spent batteries (ID No:24) 106
  • 113.
    Figure A. 26Provincial distribution of sludges from CPT (ID No:26) Figure A. 27 Provincial distribution of mercury containing waste (ID No:27) 107
  • 114.
    Figure A. 28Provincial distribution of contaminated wood (ID No:28) Table A. 10 Range of disposal market prices (€/ton) - (Germany 2002 and Turkey 2007) DISPOSAL OPTION PRICE Hazardous waste landfills 50 – 140 (Đzaydaş 70 – 120) Solidification and landfilling 80 – 100 CPT 45 – 60 Hazardous waste incineration 100 – 1,200 Liquid and pasty waste 100 – 350 Solid waste 200 – 300 Drums and canisters 300 – 1,200 (lab chemicals < 5,000) Total average 200 – 300 (Turkey: 300 – 500) Cement kilns, Power station/plants < 150 (Turkey: 200 – 300) Municipal solid waste incineration ≈ 100 108
  • 115.
    Table A. 11Structure of the price list for hazardous waste incineration in Turkey (2007) ĐZAYDAŞ PETKĐM EKOLOJĐK ENERJĐ WASTE TYPES TL/TON €/TON TL/TON €/TON TL/TON €/TON LIQUID WASTES (Sludge ratio < 10%) Calorific value > 36,000 kj/kg 70 40 70 40 -- -- Calorific value > 32,000 kj/kg 175 100 175 100 -- -- Calorific value > 25,000 kj/kg 300 170 300 170 -- -- Calorific value > 18,000 kj/kg 330 187 330 187 -- -- Calorific value > 10,000 kj/kg 710 403 710 403 -- -- Calorific value < 10,000 kj/kg 815 463 815 463 -- -- Special liquid waste 980 557 -- -- -- -- PASTY WASTE (Sludge ratio % 25 – 75) Calorific value > 18,000 kj/kg 600 341 600 341 550 312 Calorific value > 10,000 kj/kg 775 440 775 440 700 398 Calorific value < 10,000 kj/kg 890 506 890 506 850 483 Paint and phosphate sludges 540 307 540 307 500 284 Treatment sludge SOLID WASTES (Sludge ratio >75%) Calorific value > 18,000 kj/kg 1055 599 1055 599 1000 568 Calorific value > 10,000 kj/kg 1370 778 1370 778 1200 682 Calorific value < 10,000 kj/kg 1500 852 1500 852 1300 739 Waste car cycle -- -- Mastic -- -- Contaminated wastes (packages, cloth, toner etc.) 1000 568 1000 568 900 511 Drums which contained isocyanide 1610 915 -- 1600 909 Pharmaceutical wastes ( product – same product) 1370 778 -- 1250 710 Wastes which will be burned within drums 1610 915 -- -- 109
  • 116.
    Table A. 11Continued ĐZAYDAŞ PETKĐM EKOLOJĐK ENERJĐ WASTE TYPES TL/TON €/TON TL/TON €/TON TL/TON €/TON EXTRA COST FOR WASTES SHICH WILL BE BURNED Extra costs for halogen and phosphorus Between 1 – 5 % 77 44 77 44 -- Up to 10 % 120 68 120 68 -- Up to 20 % 320 182 320 182 -- Up to 30 % 540 307 540 307 -- Up to 40 % 760 432 760 432 -- Up to 50 % 955 543 955 543 -- Extra costs for sulphur Between 2 – 5 % 165 94 165 94 -- Up to 10 % 418 237 418 237 -- HAZARDOUS WASTE LANDFILL Dangerous solid wastes 200 114 -- -- Inert industrial wastes 130 74 -- -- Industrial wastes which can be depoined with municipal wastes 150 85 -- -- Municipal wastes from industry 35 20 -- -- Surface deponie 220 125 -- -- SPECIAL PROCESSES Fluorescent lamps 380 216 -- -- Accumulators 380 216 -- -- Batteries 380 216 -- -- Pressure cups 1240 705 -- -- 110
  • 117.
    Table A. 12Structure of disposal prices for CPT treatment from Germany (HIM 2002) OIL WATER MIXTURES (CHEMICALLY SEPARABLE): UNIT € Sludge content < 2% t 60 Sludge content < 10% t 85 Sludge content < 20% t 150 Sludge content < 30% t 220 Photo chemicals t 190 OIL/WATER SEPARATOR CONTENTS, WASTES FROM GRIT/SAND CHAMBERS: Sludge content < 5% t 70 Sludge content < 15% t 90 Sludge content < 30% t 120 Sludge content < 50% t 290 Sludge content > 50% t 450 INORGANIC CONTAMINATED WASTE WATER: Waste water ph 6-9 t 60 Waste water ph 2-6 and 9-12,5 t 75 Acids and alkaline solutions < 5% t 95 Acids and alkaline solutions < 20% t 160 Acids and alkaline solutions < 30% t 200 Acids and alkaline solutions > 30% per expenditure t SURCHARGES FOR DETOXIFICATION OF CYANIDE, CHROMATE, NITRITE: < 100 mg/l t 25 < 500 mg/l t 40 < 1 g/l t 70 < 10 g/l t 120 > 10 mg/l per expenditure t SURCHARGES FOR SULPHATE TREATMENT: > 1,5 g/l t 40 > 3 g/l t 60 > 10 g/l t 80 > 20 g/l t 170 > 50 g/l per expenditure t SURCHARGES FOR SLUDGE AFTER NEUTRALISATION: < 10% t 60 < 25% t 130 < 50% t 200 < 75% t 280 > 75% t 370 SURCHARGES FOR TREATMENT OF ORGANIC SOLVENTS (INCL. HALOGENATED): > 1 mg/l t 30 > 10 mg/l t 40 > 20 mg/l t 90 50 mg/l – 100 mg/l t 170 > 50 mg/l per expenditure t 111
  • 118.
    Table A. 13Assignment of hazardous waste to disposal options 11 HAZARDOUS WASTE DISPOSAL / RECOVERY OPTION [%] Direct Solidification for Material Thermal EWC Type of waste CPT Incineration Landfill Landfilling Recovery Recovery 020108 agrochemical waste containing dangerous substances 10 0 0 90 0 0 030201to03 organic wood preservatives 0 0 0 100 0 0 030204 inorganic wood preservatives 0 0 100 0 0 0 degreasing wastes containing solvents without a liquid 040103 0 0 0 100 0 phase 040214 wastes from finishing containing organic solvents 0 0 0 50 0 50 040216 dyestuffs and pigments containing dangerous substances 0 0 0 50 0 50 sludges from on-site effluent treatment containing dangerous 040219 0 0 0 100 0 0 substances 050102to09 oil sludges from petroleum refining 0 0 50 50 0 0 050115 spent filter clays 20 0 0 80 0 0 060101 sulphuric acid and sulphurous acid 0 0 100 0 0 0 060404 wastes containing mercury 0 0 100 0 0 0 060405 wastes containing other heavy metals 0 0 100 0 0 0 sludges from on-site effluent treatment containing dangerous 060502 0 0 100 0 0 0 substances Wastes from Inorganic Chemical Processes (without 060101 060xxx 15 20 60 5 0 0 and 060502) 061002 wastes containing dangerous substances 20 20 60 0 0 0 wastes from the manufacture, formulation, supply and use 070101to10 0 0 25 50 0 25 (MFSU) of basic organic chemicals 11 Destatis Federal Statistical Office of Germany and other sources. 112
  • 119.
    sludges containing dangeroussubstances from other 070111 0 0 50 50 0 0 treatment of industrial waste water Table A. 13 Continued HAZARDOUS WASTE DISPOSAL / RECOVERY OPTION [%] Direct Solidification for Material Thermal EWC Type of waste CPT Incineration Landfill Landfilling Recovery Recovery 0703nonhalog wastes from the MFSU of organic dyes and pigments (non halogenated) 0 0 50 50 0 0 070701 aqueous washing liquids and mother liquors 0 0 100 0 0 0 Wastes from Organic Chemical Processes: MFSU of plastics, synthetic rubber, pharmaceuticals, fats, grease, soaps, detergents, disinfectants, 070x01to10 0 0 10 50 10 30 cosmetics, fine chemicals and chemical products not otherwise specified (0702, 0704, 0705, 0706, 070701-10) sludges containing dangerous substances from other treatment of 070x11 0 35 40 25 0 0 industrial waste water (0702, 0704, 0705, 0706, 070711) waste paint and varnish containing organic solvents or other dangerous 080111 0 0 35 40 15 10 substances sludges from paint or varnish containing organic solvents or other 080113 0 0 15 75 5 5 dangerous substances wastes from paint or varnish removal containing organic solvents or 080117 0 0 60 25 10 5 other dangerous substances 080312 waste ink containing dangerous substances 0 0 50 35 10 5 080314 ink sludges containing dangerous substances 0 0 30 30 20 20 waste adhesives and sealants containing organic solvents or other 080409 0 0 30 40 15 15 dangerous substances adhesive and sealant sludges containing organic solvents or other 080411 0 0 45 45 5 5 dangerous substances 090101 water-based developer and activator solutions 0 0 90 10 0 0 090102 water-based offset plate developer solutions 0 0 75 25 0 0 113
  • 120.
    090103 solvent-based developer solutions 0 0 0 100 0 0 090104 fixer solutions 0 0 0 0 100 0 Table A. 13 Continued HAZARDOUS WASTE DISPOSAL / RECOVERY OPTION [%] Direct Solidification for Material Thermal EWC Type of waste CPT Incineration Landfill Landfilling Recovery Recovery 090105 bleach solutions and bleach fixer solutions 0 0 100 0 0 0 wastes containing silver from on-site treatment of 090106 0 0 0 0 100 0 photographic wastes 100104 oil fly ash and boiler dust 20 80 0 0 0 0 100109 sulphuric acid 0 0 100 0 0 0 bottom ash, slag and boiler dust from co-incineration 100114 100 0 0 0 0 0 containing dangerous substances fly ash from co-incineration containing dangerous 100116 100 0 0 0 0 0 substances wastes from gas cleaning containing dangerous 100118 100 0 0 0 0 0 substances sludges from on-site effluent treatment containing 100120and22 0 50 50 0 0 0 dangerous substances 1002xx wastes from the iron and steel industry 40 30 30 0 0 0 1003xx wastes from aluminium thermal metallurgy 50 45 0 0 5 0 slags, dross and skimmings from primary and 100401to02 20 0 0 0 80 0 secondary production 100404 flue-gas dust 0 0 0 0 100 0 1004xx wastes from lead thermal metallurgy 20 0 0 0 80 0 1005xx wastes from zinc thermal metallurgy 100 0 0 0 0 0 1006xx wastes from copper thermal metallurgy 100 0 0 0 0 0 1007xx wastes from other non-ferrous thermal metallurgy 100 0 0 0 0 0 casting cores and moulds which have (not) undergone 100905,07and09 pouring containing 70 10 0 0 20 0 dangerous substances 114
  • 121.
    casting cores andmoulds which have (not) undergone 101005,07and09 pouring containing 100 0 0 0 0 0 dangerous substances Table A. 13 Continued HAZARDOUS WASTE DISPOSAL / RECOVERY OPTION [%] Direct Solidification for Material Thermal EWC Type of waste CPT Incineration Landfill Landfilling Recovery Recovery wastes from asbestos-cement manufacture containing 101309and12 100 0 0 0 0 0 asbestos and solid wastes from gas treatment 110105to07 pickling acids and basis and other acids 0 0 100 0 0 0 110108 phosphatising sludges 5 80 15 0 0 0 110109 sludges and filter cakes containing dangerous substances 5 80 15 0 0 0 sludges from zinc hydrometallurgy (including jarosite, 110202 90 10 0 0 0 0 goethite) wastes from copper hydrometallurgical processes containing 110205 50 0 0 0 50 0 dangerous substances 110301 wastes containing cyanide 80 0 20 0 0 0 mineral-based machining oils containing halogens (except 120106 0 0 50 30 20 0 emulsions and solutions) mineral-based machining oils free of halogens (except 120107 0 0 0 0 50 50 emulsions and solutions) 120108 machining emulsions and solutions containing halogens 120109 machining emulsions and solutions free of halogens 0 0 100 0 0 0 120110 synthetic machining oils 0 0 0 0 50 50 120112 spent waxes and fats 0 0 0 50 0 50 120114 machining sludges containing dangerous substances 5 25 25 25 0 20 120301 aqueous washing liquids 0 0 100 0 0 0 120302 steam degreasing wastes 0 0 100 0 0 0 13 01 01 hydraulic oils, containing PCBs 0 0 0 70 30 0 13 01 04 chlorinated emulsions 0 0 0 70 30 0 115
  • 122.
    13 01 05 non-chlorinated emulsions 0 0 0 0 50 50 13 01 09 mineral-based chlorinated hydraulic oils 0 0 0 70 30 0 13 01 10 mineral based non-chlorinated hydraulic oils 0 0 0 0 50 50 Table A. 13 Continued HAZARDOUS WASTE DISPOSAL / RECOVERY OPTION [%] Direct Solidification for Material Thermal EWC Type of waste CPT Incineration Landfill Landfilling Recovery Recovery 13 01 11 synthetic hydraulic oils 0 0 0 0 50 50 13 01 12 readily biodegradable hydraulic oils 0 0 0 0 50 50 13 01 13 other hydraulic oils 0 0 0 0 50 50 13 02 04 mineral-based chlorinated engine, gear and lubricating oils 0 0 0 70 30 0 mineral-based non-chlorinated, synthetic, readily biodegradable 130205to08 0 0 10 0 50 40 and other engine, gear and lubricating oils 13 03 01 insulating or heat transmission oils containing PCBs 0 0 0 70 30 0 mineral-based chlorinated insulating and heat transmission oils 13 03 06 0 0 0 70 30 0 other than those mentioned in 13 03 01 mineral-based, synthetic, readily biodegradable and other non- 13 03 07to 10 0 0 0 0 50 50 chlorinated insulating and heat transmission oils bilge oils from inland navigation, jetty sewers and from other 13 04 01to 03 0 0 0 0 50 50 navigation 130501 solids from grit chambers and oil/water separators 15 0 85 0 0 0 130502to03 sludges from oil/water separators and interceptor sludges 0 0 100 0 0 0 oil and oily water from oil/water separators, mixtures of wastes 13 05 06to08 0 0 0 0 50 50 from grit chambers and oil/water separators 13 07 01to 03 fuel oil, diesel, petrol and other fuels (including mixtures) 0 0 0 0 50 50 130802 other emulsions 0 0 100 0 0 0 140601 chlorofluorocarbons, HCFC, HFC 0 0 0 10 90 0 140602 other halogenated solvents and solvent mixtures 0 0 0 50 50 0 116
  • 123.
    140603 other solvents and solvent mixtures 0 0 0 20 30 50 140604 sludges or solid wastes containing halogenated solvents 0 0 0 70 30 0 140605 sludges or solid wastes containing other solvents 0 0 0 70 0 30 Table A. 13 Continued HAZARDOUS WASTE DISPOSAL / RECOVERY OPTION [%] Direct Solidification for Material Thermal EWC Type of waste CPT Incineration Landfill Landfilling Recovery Recovery packaging containing residues of or contaminated by dangerous 150110 10 0 0 80 10 0 substances absorbents, filter materials (including oil filters not otherwise specified), 150202 wiping cloths, protective clothing contaminated by dangerous 10 0 0 90 0 0 substances 160107 oil filters 0 0 0 0 100 0 160113 brake fluids 0 0 0 0 100 0 160114 antifreeze fluids containing dangerous substances 0 0 0 0 100 0 laboratory chemicals, consisting of or containing dangerous substances, 160506 0 0 30 70 0 0 including mixtures of laboratory chemicals 160601 lead batteries 0 0 0 0 100 0 160606 separately collected electrolyte from batteries and accumulators 0 0 100 0 0 0 spent catalysts containing dangerous transition metals or dangerous 160802 10 0 0 5 85 0 transition metal compounds sludges containing dangerous substances from other treatment of 190813 20 50 0 30 0 0 industrial waste water 200113 solvents 0 0 0 100 0 0 200114 acids 0 0 100 0 0 0 200115 alkalines 0 0 100 0 0 0 200117 photochemicals 0 0 100 0 0 0 200119 pesticides 0 0 0 100 0 0 200121 fluorescent tubes and other mercury-containing waste 0 0 0 0 100 0 117
  • 124.
    200123 discarded equipment containing chlorofluorocarbons 0 0 0 0 100 0 200126 oil and fat other than those mentioned in 20 01 25 0 0 0 0 50 50 200127 paint, inks, adhesives and resins containing dangerous substances 0 0 0 100 0 0 Table A. 13 Continued HAZARDOUS WASTE DISPOSAL / RECOVERY OPTION [%] Direct Solidification for Material Thermal EWC Type of waste CPT Incineration Landfill Landfilling Recovery Recovery 200129 detergents containing dangerous substances 0 0 0 100 0 0 200131 cytotoxic and cytostatic medicines 0 0 0 100 0 0 batteries and accumulators included in 16 06 01, 16 06 02 or 16 06 03 200133 50 0 0 0 50 0 and unsorted batteries and accumulators containing these batteries discarded electrical and electronic equipment other than those 200135 0 0 0 0 0 0 mentioned in 20 01 21 and 20 01 23 containing hazardous components 200137 wood containing dangerous substances 0 0 0 0 0 100 118
  • 125.
  • 126.
    Figure A. 29Recommended hazardous waste disposal routes to recycling/recovery – amount per province 120
  • 127.
    Figure A. 29Continued 121
  • 128.
    Figure A. 30Recommended hazardous waste disposal routes to CPT – amount per province 122
  • 129.
    Figure A. 30Continued 123
  • 130.
    Figure A. 31Recommended hazardous waste disposal routes to thermal treatment – amount per province 124
  • 131.
    Figure A. 31Continued 125
  • 132.
    Figure A. 32Recommended hazardous waste disposal routes to controlled landfill – amount per province 126
  • 133.
    Figure A. 32Continued 127
  • 134.
  • 135.