This document discusses personal protective equipment (PPE) used at hazardous materials incidents, including the types, purposes, advantages and limitations of structural fire-fighting protective clothing, high-temperature protective clothing, chemical-protective clothing, respiratory protection equipment, and the limitations wearers and equipment may face. Specifically, it outlines different types of chemical-protective clothing like liquid-splash and vapor-protective clothing and factors that can reduce the effectiveness of chemical-protective clothing through permeation, chemical degradation and penetration.