This document discusses pyrophoric iron fires, which occur when iron sulfide deposits inside refinery equipment are exposed to oxygen during maintenance. Iron sulfide forms as a corrosion product when iron oxide reacts with hydrogen sulfide. When iron sulfide is exposed to air, it rapidly oxidizes back to iron oxide in an exothermic reaction that generates enough heat to ignite nearby flammable gases. Distillation columns are most prone to these fires due to iron sulfide deposits accumulating on trays and packings. Proper cleaning of equipment before opening is needed to prevent pyrophoric iron oxidation from igniting combustible materials and causing fires or explosions during maintenance.