The Law of Equi-marginal Utility, also known as Gossen's Second Law, states that consumers will allocate their budget in a way that equalizes the marginal utility per rupee spent across different goods. When making purchasing decisions, consumers will continue to buy more units of a good until the last rupee spent on that good yields the same marginal utility as a rupee spent on any other good. This ensures consumers reach the highest possible total utility from their budget.