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C3b                           How atoms combine - Ionic Bonding

Revision (you MUST know these definitions)
• An atom is the smallest particle that exists on its own. It is neutral (no charge).

       e.g.



•   A molecule is made from 2 or more atoms chemically joined

       e.g.



New definitions to learn:

•   An ion is a ____________ atom or group of atoms

       e.g. a magnesium ion,

              a carbonate ion,

•   Ions can be _______________ charged (+) or _________________ charged (-)


•   For your exam you must be able to recognise an ion, an atom and a molecule

    from given formulae.


                   Formulae                           Atom, Molecule or Ion?
                      Cu
                     Cu2+
                    CuSO4
                     Al3+
                      O2-
                      N
                      Cl2



Why are ions formed?

Atoms are “happiest” (most _______ ) when they have a full outer shell of electrons.

They __________ to complete their shells. Metals transfer electrons to non-metals.
How are Ions formed?
   •   Remember that electrons are ________________ charges (e-)

   •   So, positive ions are formed by the __________ of electrons from atoms

          e.g:



   •   Negative ions form by atoms ________________ electrons

          e.g.


   •   When a metal and a non-metal ________________ electrons in this way to form

       positive and negative ions, the opposite charges ______________ and an

       ____________________________ forms between the metal and the non-metal.




          “dot and cross” models
   We use these diagrams to show the ionic bonding in ionic compounds. You need to
   know 4 dot and cross models really well:

sodium chloride




magnesium oxide




sodium oxide




magnesium chloride
Deducing the formula of an ionic compound

•    If we know the ions that a compound is made from, we can work out the chemical

     _________________ of that compound.

•    Compounds have no overall charge so the + and – charges must ______________



e.g.    What is the formula for aluminium chloride?

        An aluminium ion =          Al3+                  you need three negative charges
                                                          to cancel out the three positive
        A chloride ion =            Cl-                   charges

        So, aluminium chloride =




        Task
In the table below is a list of some ions. Use them to work out the formulae of the
compounds under the table (the last few are quite difficult but you need to be able to
complete the first 7 at least).


                   Positive ions                 Negative Ions
                        Na+                           Cl-
                       Ca2+                            I-
                       Al3+                           O2-
                       Fe2+                  OH-    (hydroxide ion)
                       Fe3+                  SO4 2-
                                                     (sulphate ion)



1. Sodium chloride     =     NaCl                     6. Iron (III) chloride*

2. Calcium chloride                                   7. Iron (II) chloride*

3. Aluminium iodide                                   8. Sodium hydroxide

4. Calcium oxide                                      9. Sodium sulphate

5. Sodium oxide                                       10. Iron (III) sulphate*


    *Note: II is the roman numeral for 2     III is the roman numeral for 3
What Properties do Ionic Compounds have?

•    Ionic compounds are always made from a _____________ and a _____________

        e.g.

•    Due to the strong electrostatic forces of attraction between the positive (+) and

     negative (-) ions, ionic compounds:



        1.




        2.

        3.

        4.



        5. conduct electricity when ________________ or in _________________

             because the ions are ________________________________.



      Exam question: Explain why solid sodium chloride, NaCl does not conduct

electricity but a when it is molten or in solution (dissolved in water) it will conduct.



Answer:

1.




2.

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How atoms combine through ionic bonding

  • 1. C3b How atoms combine - Ionic Bonding Revision (you MUST know these definitions) • An atom is the smallest particle that exists on its own. It is neutral (no charge). e.g. • A molecule is made from 2 or more atoms chemically joined e.g. New definitions to learn: • An ion is a ____________ atom or group of atoms e.g. a magnesium ion, a carbonate ion, • Ions can be _______________ charged (+) or _________________ charged (-) • For your exam you must be able to recognise an ion, an atom and a molecule from given formulae. Formulae Atom, Molecule or Ion? Cu Cu2+ CuSO4 Al3+ O2- N Cl2 Why are ions formed? Atoms are “happiest” (most _______ ) when they have a full outer shell of electrons. They __________ to complete their shells. Metals transfer electrons to non-metals.
  • 2. How are Ions formed? • Remember that electrons are ________________ charges (e-) • So, positive ions are formed by the __________ of electrons from atoms e.g: • Negative ions form by atoms ________________ electrons e.g. • When a metal and a non-metal ________________ electrons in this way to form positive and negative ions, the opposite charges ______________ and an ____________________________ forms between the metal and the non-metal. “dot and cross” models We use these diagrams to show the ionic bonding in ionic compounds. You need to know 4 dot and cross models really well: sodium chloride magnesium oxide sodium oxide magnesium chloride
  • 3. Deducing the formula of an ionic compound • If we know the ions that a compound is made from, we can work out the chemical _________________ of that compound. • Compounds have no overall charge so the + and – charges must ______________ e.g. What is the formula for aluminium chloride? An aluminium ion = Al3+ you need three negative charges to cancel out the three positive A chloride ion = Cl- charges So, aluminium chloride = Task In the table below is a list of some ions. Use them to work out the formulae of the compounds under the table (the last few are quite difficult but you need to be able to complete the first 7 at least). Positive ions Negative Ions Na+ Cl- Ca2+ I- Al3+ O2- Fe2+ OH- (hydroxide ion) Fe3+ SO4 2- (sulphate ion) 1. Sodium chloride = NaCl 6. Iron (III) chloride* 2. Calcium chloride 7. Iron (II) chloride* 3. Aluminium iodide 8. Sodium hydroxide 4. Calcium oxide 9. Sodium sulphate 5. Sodium oxide 10. Iron (III) sulphate* *Note: II is the roman numeral for 2 III is the roman numeral for 3
  • 4. What Properties do Ionic Compounds have? • Ionic compounds are always made from a _____________ and a _____________ e.g. • Due to the strong electrostatic forces of attraction between the positive (+) and negative (-) ions, ionic compounds: 1. 2. 3. 4. 5. conduct electricity when ________________ or in _________________ because the ions are ________________________________. Exam question: Explain why solid sodium chloride, NaCl does not conduct electricity but a when it is molten or in solution (dissolved in water) it will conduct. Answer: 1. 2.