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Controlled Atmosphere and Modified
Atmosphere Storage
By
Nungleppam Monica
Food Process Engineering
Indian Institute of Technology KharagpurIndian Institute of Technology Kharagpur
CONTROL ATMOSPHERE and
MODIFIED ATMOSPHERE
 Control atmosphere (CA):
 generally refers to decreased O2 and increased
CO2 concentrations, by a precise control of the
gas composition.
 Modified atmosphere (MA):
 is used when the control of the storage
atmosphere is not closely controlled, such as in
plastic film packaging.
DIFFERENCE
MA:
Gas composition is modified initially and it changes
dynamically depending on the respiration rate of
produce and permeability of film or storage structure
surrounding the produce
CA:
Gas atmosphere is continuously controlled throughout
the storage period
 Scrubbers are
used in controlled
atmosphere storage
to absorb the extra
amount gases
present inside the
packaging
material.
Scrubbers
 Air contains:
 21% O2
 0.03% CO2.
 Modification of the atmosphere:
 O2 ↓
 CO2 ↑
 Increased the shelf-life of perishable foods
Main crop
potatoes
Celery
Lettuces
Carrots
Leeks
Soft fruit
Asparagus
Broccoli
Spinach Banana Mushroom
Respiration rate HighLow
Short
Long
Shelf
Life
Minimum O2
concentration
tolerated(%)
Commodities
0.5 Tree nuts,dried fruits,and vegetables
1.0 Some cultivars of apples and pears,brocolli,mushroom,garlic,onion,most
cutor sliced(minimally processed)fruits and vegetables
2.0 Most cultivars of apples and
pears,kiwifruits,apricot,cherry,nectarine,peach,plum,strawbery,papaya,pi
neapple,olive,cantaloupe,sweet corn,green
bean,celery,lettuce,cabbage,cauliflower.brussels sprouts
3.0 Avocado,persimmon,tomato,pepper,cucumber,artichoke
5.0 Citrus fruits,green pea,asparagus,potato,sweet potato
Table 1: Fruits and Vegetables classified according to their
tolerance to low O2 concentrations
Fruits and vegetables differ in their tolerance to low O2 and to
high CO2 concentrations.
Table 2: Fruits and Vegetables classified according to their
tolerance to elevated CO2 concentrations
Maximum CO2
concentration
tolerated(%)
Commodities
2 Apple(Golden Delicious),Asian pear,European
pear,apricot,grape,olive,tomato,pepper(sweet),lettuce,endive,Chinese
cabbage,celery,artichoke,sweet potato
5 Apple(most
cultivars),peach,nectarine,plum,orange,avogado,banana,mango,papaya,
kiwifruit,cranberry,pea,pepper(chilli),eggplant,cauliflower,cabbage,Bru
ssels sprouts,radish,carrot
10 Grapefruits,lemon,lime,persimmon,pineapple,cucumber,summer
squash,snap bean,okra,asparagus,broccoli,parsley,leek,green onion,dry
onion,garlic,potato
15 Strawberry,raspberry,blakberry,blueberry,cherry,fig,cantaloupe,sweet
corn,mushroom,spinach,kale,Swiss chard
Table 3: Controlled atmosphere conditions for some fruit species
Species Best
Temp.
(°C)
RH(%) O2 (%) CO2 (%) Time
Avocado 7 90 2-3 3-10 2 months
Cherry 0 95 3-10 10-12 30 days
Kiwi 0 98 2 4-5 7 months
Nectarine -0.5 95 2 5 50 days
Peach -0.5 95 2 4-5 40 days
Plum 0 95 2 5 45 days
Table 4: Controlled atmosphere conditions for some vegetable
species
BENEFICIAL EFFECTS OF PROPER
CA STORAGE:
 delayed softening and mealiness (apples, pears,
tomatoes),
 delayed toughening (asparagus),
 chlorophyll retention (apples, pears, leaf vegetables),
 insect control- O2(< 1%) and/or elevated CO2(40 to
60%)
BENEFICIAL EFFECTS OF PROPER
CA STORAGE:
 inhibition of the browning of cut surface(cut fruits
and vegetables),
 better flavour retention (pineapple, cabbage),
 reduction of disorders and decay (berries),
 Higher nutritional value after storage (vitamin C).
DETRIMENTAL EFFECTS OF CA
(above or below optimum composition
for the commodity):
 May cause irregular ripening of fruits (banana, mango,
pear, and tomato, at O2 below 2%, CO2 above 5% for >
1 month).
 May cause certain physiological disorders.
 May enhance anaerobic respiration and development
of off-flavors.
 May cause susceptibility to decay.
Table 5: Examples of CA injury
STORAGE DISORDER
Low O injury₂
Internal CO injury₂
(Brown heart)
Low temp. breakdown
External CO injury₂
DISADVANTAGES
 It is quite expensive.
 Temp. control required.
 Different gas composition for each type of product.
 Special operation and operator training required.
 Once pack opens or leaks the benefits are lost.
RECENT DEVELOPMENTS IN CA
STORAGE
 Recent improvements include maintaining CA
during transport in refrigerated marine containers.
 CA transport of banana permits the harvest at a more
fully-mature stage.
 In addition to CA, there is also a continuing increase
in the use of plastic films and MAP.
MODIFIED ATMOSPHERE
PACKAGING (MAP)
 Modified Atmosphere Packaging (MAP) involves the
modification of the head space gas in a package in
order to prolong the shelf life of the product it
contains.
 The greatest use of MAP is for fresh-cut products (to
maintain 2-5% O2 and 8-12% CO2).
 It is possible to improve gas control in MAP by
adding absorbers of ethylene, carbon dioxide and
oxygen.
 O absorber:-₂ Iron powder is used commercially as
the active ingredient. Ex. FeO, Fe O , Fe O₂ ₃ ₃ ₄
 CO absorber:-₂ Lime(freshly hydrated high
calcium lime (Ca(OH) ),activated charcoal,₂
magnesium oxide)
 Ethylene absorber:- Potassium permanganate,
builder clay powder, hydrocarbons, silicones
TWO TYPES
Active modification
The atmosphere is modified by pulling a slight
vacuum and replacing the packaging atmophere within
the desired gas mixture.
Passive modification
Modification is achieved by respiration of
commodity within the package and depends on the
characteristics of the commodity and the packaging
film.
 Passive modification
 Product packaged with selected film
 Desired atmosphere develops naturally over time
 Takes longer to achieve desired atmosphere in package
 Active modification
  Displace or remove gases in package
 Replace with mix of desired gases and seal
 Better shelf life is achieved with Active Modification
CONCLUSIONS
 A strong preservation of quality and nutritional value
is demonstrated by CA storage with a lowering of O2
and an enhancement of the CO2 concentrations. This
results in:
 better quality after storage
 a longer storage period
 a longer shelf-life period after storage
 a higher nutritional value after storage(vitamin C)
 a more environmental friendly storage(no
postharvest chemical treatments against scald are
needed).
Thank you

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Controlled atmosphere and modified atmosphere storage

  • 1. Controlled Atmosphere and Modified Atmosphere Storage By Nungleppam Monica Food Process Engineering Indian Institute of Technology KharagpurIndian Institute of Technology Kharagpur
  • 2. CONTROL ATMOSPHERE and MODIFIED ATMOSPHERE  Control atmosphere (CA):  generally refers to decreased O2 and increased CO2 concentrations, by a precise control of the gas composition.  Modified atmosphere (MA):  is used when the control of the storage atmosphere is not closely controlled, such as in plastic film packaging.
  • 3. DIFFERENCE MA: Gas composition is modified initially and it changes dynamically depending on the respiration rate of produce and permeability of film or storage structure surrounding the produce CA: Gas atmosphere is continuously controlled throughout the storage period
  • 4.  Scrubbers are used in controlled atmosphere storage to absorb the extra amount gases present inside the packaging material. Scrubbers
  • 5.  Air contains:  21% O2  0.03% CO2.  Modification of the atmosphere:  O2 ↓  CO2 ↑  Increased the shelf-life of perishable foods
  • 6. Main crop potatoes Celery Lettuces Carrots Leeks Soft fruit Asparagus Broccoli Spinach Banana Mushroom Respiration rate HighLow Short Long Shelf Life
  • 7. Minimum O2 concentration tolerated(%) Commodities 0.5 Tree nuts,dried fruits,and vegetables 1.0 Some cultivars of apples and pears,brocolli,mushroom,garlic,onion,most cutor sliced(minimally processed)fruits and vegetables 2.0 Most cultivars of apples and pears,kiwifruits,apricot,cherry,nectarine,peach,plum,strawbery,papaya,pi neapple,olive,cantaloupe,sweet corn,green bean,celery,lettuce,cabbage,cauliflower.brussels sprouts 3.0 Avocado,persimmon,tomato,pepper,cucumber,artichoke 5.0 Citrus fruits,green pea,asparagus,potato,sweet potato Table 1: Fruits and Vegetables classified according to their tolerance to low O2 concentrations Fruits and vegetables differ in their tolerance to low O2 and to high CO2 concentrations.
  • 8. Table 2: Fruits and Vegetables classified according to their tolerance to elevated CO2 concentrations Maximum CO2 concentration tolerated(%) Commodities 2 Apple(Golden Delicious),Asian pear,European pear,apricot,grape,olive,tomato,pepper(sweet),lettuce,endive,Chinese cabbage,celery,artichoke,sweet potato 5 Apple(most cultivars),peach,nectarine,plum,orange,avogado,banana,mango,papaya, kiwifruit,cranberry,pea,pepper(chilli),eggplant,cauliflower,cabbage,Bru ssels sprouts,radish,carrot 10 Grapefruits,lemon,lime,persimmon,pineapple,cucumber,summer squash,snap bean,okra,asparagus,broccoli,parsley,leek,green onion,dry onion,garlic,potato 15 Strawberry,raspberry,blakberry,blueberry,cherry,fig,cantaloupe,sweet corn,mushroom,spinach,kale,Swiss chard
  • 9. Table 3: Controlled atmosphere conditions for some fruit species Species Best Temp. (°C) RH(%) O2 (%) CO2 (%) Time Avocado 7 90 2-3 3-10 2 months Cherry 0 95 3-10 10-12 30 days Kiwi 0 98 2 4-5 7 months Nectarine -0.5 95 2 5 50 days Peach -0.5 95 2 4-5 40 days Plum 0 95 2 5 45 days
  • 10. Table 4: Controlled atmosphere conditions for some vegetable species
  • 11. BENEFICIAL EFFECTS OF PROPER CA STORAGE:  delayed softening and mealiness (apples, pears, tomatoes),  delayed toughening (asparagus),  chlorophyll retention (apples, pears, leaf vegetables),  insect control- O2(< 1%) and/or elevated CO2(40 to 60%)
  • 12. BENEFICIAL EFFECTS OF PROPER CA STORAGE:  inhibition of the browning of cut surface(cut fruits and vegetables),  better flavour retention (pineapple, cabbage),  reduction of disorders and decay (berries),  Higher nutritional value after storage (vitamin C).
  • 13. DETRIMENTAL EFFECTS OF CA (above or below optimum composition for the commodity):  May cause irregular ripening of fruits (banana, mango, pear, and tomato, at O2 below 2%, CO2 above 5% for > 1 month).  May cause certain physiological disorders.  May enhance anaerobic respiration and development of off-flavors.  May cause susceptibility to decay.
  • 14. Table 5: Examples of CA injury
  • 15. STORAGE DISORDER Low O injury₂ Internal CO injury₂ (Brown heart) Low temp. breakdown External CO injury₂
  • 16. DISADVANTAGES  It is quite expensive.  Temp. control required.  Different gas composition for each type of product.  Special operation and operator training required.  Once pack opens or leaks the benefits are lost.
  • 17. RECENT DEVELOPMENTS IN CA STORAGE  Recent improvements include maintaining CA during transport in refrigerated marine containers.  CA transport of banana permits the harvest at a more fully-mature stage.  In addition to CA, there is also a continuing increase in the use of plastic films and MAP.
  • 18. MODIFIED ATMOSPHERE PACKAGING (MAP)  Modified Atmosphere Packaging (MAP) involves the modification of the head space gas in a package in order to prolong the shelf life of the product it contains.  The greatest use of MAP is for fresh-cut products (to maintain 2-5% O2 and 8-12% CO2).  It is possible to improve gas control in MAP by adding absorbers of ethylene, carbon dioxide and oxygen.
  • 19.  O absorber:-₂ Iron powder is used commercially as the active ingredient. Ex. FeO, Fe O , Fe O₂ ₃ ₃ ₄  CO absorber:-₂ Lime(freshly hydrated high calcium lime (Ca(OH) ),activated charcoal,₂ magnesium oxide)  Ethylene absorber:- Potassium permanganate, builder clay powder, hydrocarbons, silicones
  • 20. TWO TYPES Active modification The atmosphere is modified by pulling a slight vacuum and replacing the packaging atmophere within the desired gas mixture. Passive modification Modification is achieved by respiration of commodity within the package and depends on the characteristics of the commodity and the packaging film.
  • 21.  Passive modification  Product packaged with selected film  Desired atmosphere develops naturally over time  Takes longer to achieve desired atmosphere in package  Active modification   Displace or remove gases in package  Replace with mix of desired gases and seal  Better shelf life is achieved with Active Modification
  • 22. CONCLUSIONS  A strong preservation of quality and nutritional value is demonstrated by CA storage with a lowering of O2 and an enhancement of the CO2 concentrations. This results in:  better quality after storage  a longer storage period  a longer shelf-life period after storage  a higher nutritional value after storage(vitamin C)  a more environmental friendly storage(no postharvest chemical treatments against scald are needed).