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WETTABILITY OF SOUTHERN PINE
 SUBJECTED TO BARK BEETLE
    FUNGAL ASSOCIATES
                      By

   Eric McConnell, Nathan Little, Nate Irby,
        John Riggins, and Sheldon Shi

     Forest Products Society, Portland OR
Primary Species of the Southern Pine Bark Beetle Guild
                       3 species of Ips
            Black Turpentine Beetle (D. terebrans)
              Southern Pine Beetle (D. frontalis)
Southern Pine Beetle
               (D. frontalis)
• Last Major Outbreak in   • $1 billion in damages
  South ~10 years ago      • Environmental and social
                             impacts as well
• Initially overcomes
  oloeresin
• Inoculating a variety of
  fungi
• O. minus most prolific
  early
• Death occurs through
  many factors
   – Gallery and fungal
     proliferation
• Timely salvaging can
  produce lumber
   – LRF
   – Grade
• Decay fungi and
  termites soon after
What About Composites?
• Kelly et al (1982)
  utilized SPB-killed trees
  in mixture with healthy
• MOR, IB, & SW
• 2 & 24 hour
  TS & WA
• No proposed
  explanation
What About Composites?

• Adhesive must
  adequately penetrate for
  effective bonding
• Wicking occurs via
  capillary forces
• Provides intimate
  contact
• Better understanding
  resin-wood interface
  may provide economic
  uses for biologically
  attacked timber
• MS overdue for an
  outbreak
Goals
• Determine DCA of
   – Green and Kiln-dried SYP
   – With and without blue
     stain present
   – Wilhelmy Plate
• Calculate surface energy
   – Geometric mean
Avg. Dynamic Contact Angles
                       Probe Liquid [Surface tension]
                                       α-
                 Water                             Formamide      Ethylene Glycol
                               Bromonapthalene
             [72.8 mJ/M2]                         [58.0 mJ/M2]     [48.0 mJ/M2]
                                 [44.4 mJ/M2]
Wood Type                  Average contact angle (standard deviation)

Green SPB
              51.1 (2.6)          29.4 (3.5)        52.7 (1.5)          41.4 (1.6)
blue-stain

Kiln-dried
              45.4 (4.1)           9.4 (9.1)        45.1 (2.6)          42.0 (1.7)
 control
 Green
              47.0 (8.3)          16.1 (11.5)      42.8 (10.5)          39.3 (3.0)
 control
Kiln-dried
               0.0 (0.0)           0.0 (0.0)        52.8 (0.3)          34.4 (4.6)
blue-stain
Geometric Mean
                                        p 0.5
(1  cos  ) *

  2 * ( d )
            0.5
                  L
                       ( )
                          S     0.5 
                          d  p * L
                            0.5

                                S  d
                                       
         L                             L

      
    Y   x
                                     1
Surface Energies
                        Dispersive   Polar     Total surface
     Treatment
                           forces     forces       energy

     Green
                          28.42      17.92        46.34
  SPB blue-stain

 Kiln-dried control       31.37      18.84        50.21
   Green control          31.86      18.40        50.26

Kiln-dried blue-stain     25.03      34.46        59.49
• Once beetle attack
  occurs, various changes
  take place
   –   Anatomical
   –   Morphological
   –   Chemical
   –   Physical
• All affect surface
  energy
• O. minus initially
  confined to ray
  parenchyma in sapwood
• Cause water-conducting
  blockages through
  internal wounding
• Resin formation results
  to slow fungal spread
• Subsequent penetration
  of tracheids results in
  movement across cells
  via pit pairs

• Permeability

• “Stained” areas suffer
  moisture loss
• Increased permeability would allow for
  increase liquid transport across the grain
• KD/BS wood would have had a greater degree
  of fluid flow in 3 directions
• Chemicals from tree’s wound response may
  have disrupted liquid movement in Gr/BS
  wood
• One possible mechanism
  described for improving
  board properties
• Future studies
  – Other processes
  – Various sized wood
    elements
Conclusions

• Little change in non-
  stained wood following
  drying
• KD/BS wood surface
  energy higher than
  others
  – >15% over each wood
    type
Conclusions

• Wound response
  possibly contributed to
  lower surface energy in
  Gr/BS wood
• BS wood from beetle-
  killed trees may yield
  properties for wood
  composites
• Timely utilization is key
Thank You


   For More Information
nathanlittle.msu@gmail.com
  mcconnell.213@osu.edu

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Session 13 ic2011 mc connell

  • 1. WETTABILITY OF SOUTHERN PINE SUBJECTED TO BARK BEETLE FUNGAL ASSOCIATES By Eric McConnell, Nathan Little, Nate Irby, John Riggins, and Sheldon Shi Forest Products Society, Portland OR
  • 2. Primary Species of the Southern Pine Bark Beetle Guild 3 species of Ips Black Turpentine Beetle (D. terebrans) Southern Pine Beetle (D. frontalis)
  • 3. Southern Pine Beetle (D. frontalis) • Last Major Outbreak in • $1 billion in damages South ~10 years ago • Environmental and social impacts as well
  • 4. • Initially overcomes oloeresin • Inoculating a variety of fungi • O. minus most prolific early • Death occurs through many factors – Gallery and fungal proliferation
  • 5. • Timely salvaging can produce lumber – LRF – Grade • Decay fungi and termites soon after
  • 6. What About Composites? • Kelly et al (1982) utilized SPB-killed trees in mixture with healthy • MOR, IB, & SW • 2 & 24 hour TS & WA • No proposed explanation
  • 7. What About Composites? • Adhesive must adequately penetrate for effective bonding • Wicking occurs via capillary forces • Provides intimate contact
  • 8. • Better understanding resin-wood interface may provide economic uses for biologically attacked timber • MS overdue for an outbreak
  • 9. Goals • Determine DCA of – Green and Kiln-dried SYP – With and without blue stain present – Wilhelmy Plate • Calculate surface energy – Geometric mean
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  • 12. Avg. Dynamic Contact Angles Probe Liquid [Surface tension] α- Water Formamide Ethylene Glycol Bromonapthalene [72.8 mJ/M2] [58.0 mJ/M2] [48.0 mJ/M2] [44.4 mJ/M2] Wood Type Average contact angle (standard deviation) Green SPB 51.1 (2.6) 29.4 (3.5) 52.7 (1.5) 41.4 (1.6) blue-stain Kiln-dried 45.4 (4.1) 9.4 (9.1) 45.1 (2.6) 42.0 (1.7) control Green 47.0 (8.3) 16.1 (11.5) 42.8 (10.5) 39.3 (3.0) control Kiln-dried 0.0 (0.0) 0.0 (0.0) 52.8 (0.3) 34.4 (4.6) blue-stain
  • 13. Geometric Mean p 0.5 (1  cos  ) * 2 * ( d ) 0.5 L  ( ) S  0.5  d  p * L 0.5 S  d   L  L  Y   x  1
  • 14. Surface Energies Dispersive Polar Total surface Treatment forces forces energy Green 28.42 17.92 46.34 SPB blue-stain Kiln-dried control 31.37 18.84 50.21 Green control 31.86 18.40 50.26 Kiln-dried blue-stain 25.03 34.46 59.49
  • 15. • Once beetle attack occurs, various changes take place – Anatomical – Morphological – Chemical – Physical • All affect surface energy
  • 16. • O. minus initially confined to ray parenchyma in sapwood • Cause water-conducting blockages through internal wounding • Resin formation results to slow fungal spread
  • 17. • Subsequent penetration of tracheids results in movement across cells via pit pairs • Permeability • “Stained” areas suffer moisture loss
  • 18. • Increased permeability would allow for increase liquid transport across the grain • KD/BS wood would have had a greater degree of fluid flow in 3 directions • Chemicals from tree’s wound response may have disrupted liquid movement in Gr/BS wood
  • 19. • One possible mechanism described for improving board properties • Future studies – Other processes – Various sized wood elements
  • 20. Conclusions • Little change in non- stained wood following drying • KD/BS wood surface energy higher than others – >15% over each wood type
  • 21. Conclusions • Wound response possibly contributed to lower surface energy in Gr/BS wood • BS wood from beetle- killed trees may yield properties for wood composites • Timely utilization is key
  • 22. Thank You For More Information nathanlittle.msu@gmail.com mcconnell.213@osu.edu