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L- 28
Pulp and paper mill
Industrial Waste Treatment
Introduction
• The manufacture of pulp and paper is a
resource-intensive industry that consumes
large amounts of energy, water, and trees.
• It is one of the oldest and one of the• It is one of the oldest and one of the
largest industry in our country.
• Waste water contains very high COD and
colour.
• Presence of lignin in the waste is very
high which is not easily biodegradable.
• Because of this COD/ BOD ratio is very
highhigh
• Pulp mill causes more pollution than
paper mills.
Manufacturing process
1. Pulp Making
• Chipped cellulose materials are digested
with different chemicals in one tank under
high temp and pressure.
• The process thus loosens the cellulose• The process thus loosens the cellulose
fibers and dissolves the lignin, resin in
the raw material.
• Chemicals used are- sodium sulphate,
sodium hydroxide and sodium sulphide
• Spent black liquor is produced from
digestion process.
• This black liquor is very rich in
chemicals therefore it is separated and
treated for recovery of chemicals.
• Cellulosic fibers are washed and
dewatered in ‘decker’ screen.
• Washed cellulosic fibers are sent for
bleaching in three stages where
chlorine, caustic and hypochlorite are
used in successive stages.used in successive stages.
• The bleached pulp is sent for paper
mill
2. Paper mill
• In paper mill pulp is mixed with
Alum, talc and dyes in a tank known
as ‘beater’
• After beating pulp is refined in a• After beating pulp is refined in a
machine known as ‘jordan’.
• Refined paper is then diluted for
consistency and passed through
screen to remove lumps and knots
• The pulp is then passed through belt
of fine screens to a series of rolls,
where the product paper is produced.
• The drained water is called as white• The drained water is called as white
water
Characteristics of combined effluent
Item Small mill Large mill
capacity 20 tonnes of
paper/day
2000 tonnes of
paper/day
Flow per day 330 m3/tonne 222 m3/tonne
Colour 7800 units
pH 8.2-8.5 8.5-9.5
TS mg/l --- 4410
SS mg/lit 900-2000 3300
COD mg/lit 3400-5780 716
BOD mg/lit 680-1250 155
COD/BOD ratio 3.9 - 5 4.6
Treatment alternatives
Massive lime treatment
Objective Questions
Theory questions

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L 28 pulp and paper mill

  • 1. L- 28 Pulp and paper mill Industrial Waste Treatment
  • 2. Introduction • The manufacture of pulp and paper is a resource-intensive industry that consumes large amounts of energy, water, and trees. • It is one of the oldest and one of the• It is one of the oldest and one of the largest industry in our country. • Waste water contains very high COD and colour.
  • 3. • Presence of lignin in the waste is very high which is not easily biodegradable. • Because of this COD/ BOD ratio is very highhigh • Pulp mill causes more pollution than paper mills.
  • 4. Manufacturing process 1. Pulp Making • Chipped cellulose materials are digested with different chemicals in one tank under high temp and pressure. • The process thus loosens the cellulose• The process thus loosens the cellulose fibers and dissolves the lignin, resin in the raw material. • Chemicals used are- sodium sulphate, sodium hydroxide and sodium sulphide
  • 5. • Spent black liquor is produced from digestion process. • This black liquor is very rich in chemicals therefore it is separated and treated for recovery of chemicals. • Cellulosic fibers are washed and dewatered in ‘decker’ screen.
  • 6. • Washed cellulosic fibers are sent for bleaching in three stages where chlorine, caustic and hypochlorite are used in successive stages.used in successive stages. • The bleached pulp is sent for paper mill
  • 7. 2. Paper mill • In paper mill pulp is mixed with Alum, talc and dyes in a tank known as ‘beater’ • After beating pulp is refined in a• After beating pulp is refined in a machine known as ‘jordan’. • Refined paper is then diluted for consistency and passed through screen to remove lumps and knots
  • 8. • The pulp is then passed through belt of fine screens to a series of rolls, where the product paper is produced. • The drained water is called as white• The drained water is called as white water
  • 9.
  • 10. Characteristics of combined effluent Item Small mill Large mill capacity 20 tonnes of paper/day 2000 tonnes of paper/day Flow per day 330 m3/tonne 222 m3/tonne Colour 7800 units pH 8.2-8.5 8.5-9.5 TS mg/l --- 4410 SS mg/lit 900-2000 3300
  • 11. COD mg/lit 3400-5780 716 BOD mg/lit 680-1250 155 COD/BOD ratio 3.9 - 5 4.6
  • 14.