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J. Bio. Env. Sci. 18(5), 80-92, May 2021. 2021
E-ISSN: 2222-3045, p-ISSN: 2220-6663
Performance assessment of
water filtration plants in
Pakistan
By: Talat Farid Ahmed, Hashim Nisar Hashmi, Ali Salman Saeed, Ashfaq Ahmed Sheikh,
Muhammad Attiqullah Khan, Muhammad Azeem Afzal
Journal of biodiversity and
environmental sciences
international network for
natural sciences
Research Paper
Journal Name
Publisher Name
J. Bio. & Env. Sci. 2021
80 | Ahmed et al.
RESEARCH PAPER OPEN ACCESS
Performance assessment of water filtration plants in Pakistan
Talat Farid Ahmed*1
, Hashim Nisar Hashmi2
, Ali Salman Saeed2
, Ashfaq Ahmed Sheikh3
,
Muhammad Attiqullah Khan1
, Muhammad Azeem Afzal1
1
Farm Operations & Services, National Agricultural Research Centre, Park Road, Islamabad, Pakistan
2
Civil Engineering Department, University of Engineering & Technology, Taxila, Pakistan
3
CPD, Pakistan Engineering Council, Islamabad, Pakistan
Article published on May 30, 2021
Key words: Uplift anaerobic sludge blanket, Power of hydrogen ions, Organic loading role, Hydraulic retention time,
Chemical oxygen demand, Biological oxygen demand
Abstract
A study was carried out to evaluate the water quality of filtration plants installed at six different places of
Cantonment Board Sialkot, Pakistan to suggest and recommend guidelines for their improvement. Water
samples from six Treatment plants and their respective twelve connections (two from each treatment plants)
were collected before and after treatment. In this way, total samples were collected and tested. Values of these
samples before and after treatment were used for comparison with World Health Organization (WHO)
guidelines for drinking water standards. Thirty three parameters including physical, chemical and
bacteriological were determined for each sample. The results were satisfactory both chemically and
bacteriologically according to WHO guidelines for water quality of treatment plants. The results showed that
the samples of water were fit, both before and after treatment plant except for water sample of treatment plant
No. IV & V (Before treatment). Total and faecal coliform were found in these samples. Various causes of faecal
contamination before treatment may be due to leakage of pipelines, operation at tubewells, layout of
freshwater pipes parallel or beneath the sewerage pipes or channels. Disinfection of water at source is
recommended to deal with the faecal contamination; otherwise there is no need of filtration plant.
*Corresponding Author: Talat Farid Ahmed  tafa367@gmail.com
Journal of Biodiversity and Environmental Sciences (JBES)
ISSN: 2220-6663 (Print) 2222-3045 (Online)
Vol. 18, No. 5, p. 80-92, 2021
http://www.innspub.net
J. Bio. & Env. Sci. 2021
81 | Ahmed et al.
Introduction
Water is blessing of Allah and is very precious
resource of this planet as it is an established source of
life and civilization. Over other planets and even
galaxies, the constituent parts of water are searched
as emblem of life. It is well known that human health
and survival depends on use of uncontaminated and
clean water for drinking and other domestic purposes.
Nature has blessed Pakistan with adequate surface
and groundwater resources. Both of these sources are
used for water supplies, however, 70% of water
supplies are based on groundwater and 30% on surface
waters. Pakistan’s population has current water supply
coverage of 79%.This inadequate supply of water also
poses health risks to the consumers because of its poor
quality. Faecally contaminated water is a major
contributor to waterborne diseases. It is estimated that
in Pakistan around 30% of all diseases and 40% of all
deaths are attributed to poor water quality. Moreover,
the leading cause of deaths in infants and children up
to 10 years age as well as mortality rate of 136 per
1,000 live births due to diarrhea is reported.
Furthermore, every fifth citizen suffers from illness and
disease caused by polluted water.
With rapid urbanization, the chemical aspects of
water quality have also become a cause of increasing
concern as toxic chemicals in industrial effluents pose
a high risk to human health. Unfortunately, little
attention is being paid to drinking-water quality
issues and quantity remains the priority focus of
water supply agencies. There is a lack of drinking-
water quality monitoring and surveillance
programmes in the country. Weak institutional
arrangements, lack of well-equipped laboratories and
the absence of a legal framework for drinking-water
quality issues have aggravated the situation. Above all
public awareness of the issue of water quality is
dismally low. The water shortage and increasing
competition for multiple uses of water adversely
affected the water quality.
Keeping in view the above mentioned facts an attempt
has been made to evaluate the water quality in some
of the already installed water filtration plant with set
goals i.e. water quality evaluation before and after
treatment of water, water filtration plants
Performance assessment and Suggest and
recommend guidelines for their improvement.
A research study was started to evaluate the energy
efficiency of a sample of drinking water treatment
plants (DWTPs) using the data envelopment analysis
(DEA) tolerance method. The results showed that,
even in the best-case situation, most of the DWTPs
evaluated were inefficient and might be able to reduce
the energy used to treat raw water. As policy
perspective the results revealed that omitting data
variability in benchmarking would involve critical
repercussions when efficiency scores were used by
regulators to set water tariffs. Omitting the degree of
data uncertainty was likely to result in biased
conclusions; in the scenarios evaluated, the inclusion
of this information altered the rankings of some
energy-efficient DWTPs [Sala-Garrido, R., & Molinos-
Senante, M., 2020].
A quantitative microbial risk assessment (QMRA)
study was conducted on Cryptosporidium using
actual pathogen density to know the performance
conventional water treatment plant (WTP). To control
the excess risk, three QMRA-based disinfection
scenarios were examined; (1) employing chlorine
dioxide instead of chlorine (2) ozonation with a
concentration of 0.75mg/L (3) UV irradiation with a
dose of 10mJ/cm2. The results showed that use of
ozone or UV as alternative disinfectants could
enhance the disinfection efficacy and provide
sufficient additional treatment against the excess risk
of parasite. QMRA could make it easier applying
appropriate improvement to conventional WTPs in
order to increase the system performance in terms of
health-based measures [Hadi, M et al., 2019].
A study was started with aimed to evaluate the
efficacy of real-time bacteriological counters for
continuously assessing the performance of a full-scale
sand filter to remove bacteria of a drinking water
treatment plant. Periodic variations were found with
J. Bio. & Env. Sci. 2021
82 | Ahmed et al.
online bacterial counts in the sand filter influent
because of the changes in the performance of
flocculation and sedimentation processes. Overall,
online removal rates of bacteria determined during
the full-scale test were 95.2-99.3%. Real-time
bacteriological counting technology could be a useful
tool for assessing variability and detecting bacterial
breakthrough. It could be integrated with other online
water quality measurements to evaluate underlying
trends and the performance of sand filters for
bacterial removal, which could enhanced the safety of
drinking water [Fujioka, T et al., 2019].
A hybrid statistic model named HANN was
established by combining artificial neural network
(ANN) with genetic algorithm (GA) aiming at
forecasting the overall performance of drinking water
treatment plants (DWTPs) was carried out. Water
quality parameters like temperature, chemical oxygen
demand (COD) and operational parameters like
electricity consumption and chemical consumption
were selected as input variables while drinking water
production was employed as the output. The scenario
analysis showed that the HANN model was capable of
predicting water production variation based on the
parameter variations. It was found that the HANN
model could be a general management tool for
decision makers and DWTP managers to make plans
in advance of regulatory changes, source water quality
variations and market demand [Zhang, Y et al., 2019].
Adequacy analysis of drinking water treatment
technologies in regard to the parameter turbidity,
considering the quality of natural waters treated by
large-scale water treatment plants (WTPs) was
initiated. Nonparametric and multivariate statistical
tools were used to analyze raw water and treated
water turbidity of a large on-line monitoring
databank for the period of two years of six large-
scale treatment plants utilizing different
technologies. The results depicted that selection of
the technology to be applied must be well studied to
always seek the best solution, and that other factors
than only the raw water characteristics should be
evaluated. It was also found that utilization of the
same treatment technology did not always resulted
in the same effluent quality, since there were many
factors related to operation, maintenance, raw water
variability, climatic interferences, and others [Melo,
L. D. V., et al., 2019].
A study was started with the objective to evaluate the
drinking water treatment plant (DWTP) by life cycle
assessment (LCA) and to identify and characterize its
environmental impacts. DWTP involved the scheme;
pre-oxidation (chlorine dioxide), coagulation/
flocculation, sedimentation, pH correction (calcium
hydroxide), rapid sand filtration, granular activated
carbon filtration and disinfection (chlorine gas). Life
cycle impact assessment showed that the lower the
pollutant concentration, the higher the specific
environmental impacts would be, which prompts for
further detailed analysis of water treatment plant
environmental performance in at least two directions
i.e. removal of emerging contaminants (present in
very low concentrations) and a more detailed analysis
on the individual performance of each treatment
stage [Barjoveanu, et al., 2019].
A study was conducted to analyze the presence of
antibiotics in potable water from two treatment
plants. The collected samples were separated using a
solid-phase extraction method with hydrophilic-
lipophilic balance cartridge before being analyzed.
The detected antibiotics in the raw and finished
drinking water were analyzed and assessed using
high-performance liquid chromatography with
fluorometric detector and UV detector. The results
proved that different antibiotics including
fluoroquinolones and B-lactams were detected in the
raw and finished water. It was suggested that due to
presence of antibiotic drugs in raw and finished
water, the planners should include it in the respective
country standard for drinking water quality
assessment [Mahmood, A. R et al., 2019].
A study was conducted to assess the efficiency of two
natural-based coagulants, namely calcium lactate and
tannic acid, and compare it with conventional
coagulants polyaluminium chloride and ferric
J. Bio. & Env. Sci. 2021
83 | Ahmed et al.
chloride in a water treatment plant. The comparison
between the performances of the coagulants showed no
significant difference in turbidity removal. However
sludge volume produced as well as the impact on PH
alteration after coagulation-flocculation were lower
when using natural coagulants than with conventional
coagulants. The results showed that the natural
coagulants could be preferable to the conventional
coagulants if the concerns regarding disinfection by-
product formation due to their residual organics were
resolved [Kaji, A et al., 2019].
Performance Evaluation of a Drinking Water
Treatment Plant in terms of performance, design,
operation, and maintenance was carried out. A
Microbial Barrier Analysis (MBA) and Quantitative
Microbial Risk Assessment (QMRA) were performed
to assess the health risk based on the Water Safety Plan
concept. The results revealed that less source
protection, lack of skilled expertise in operation,
deficiency of guidance from the administration,
insufficient design and equipment, and incomplete
technologies were the main issues. Recommendations
in a two-step implementation plan were presented to
provide of an adequate water supply [Braun, M., 2019].
Evaluation of energy performance of drinking water
treatment plants was initiated by Using energy
intensity and energy efficiency metrics. The
metafrontier data was used in envelopment analysis
to evaluate and compare the energy performance of
four types of treatment technologies. This approach
integrates energy intensity with pollutant removal
efficiency into a single, synthetic index to deliver an
energy-efficiency score. The results showed that
facilities using rapid-gravity filtration and
coagulation-flocculation processes provided the
highest energy efficiencies. But energy intensity and
energy efficiency metrics delivered contradictory
results that showed the importance of including
pollutant removal efficiency data in performance
assessments. It was found that this study gave
valuable information for policy-makers when
planning and developing new drinking water
treatment plants and for water utility managers when
identifying energy reduction opportunities in plants
[Molinos-Senante, M., & Sala-Garrido, R., 2018].
A complete review of research efforts related to the
occurrence, fate, health effects and impacts of
emerging pollutants on advanced drinking water
treatment and the environmental performance
evaluation of different technological options, with a
focus on pilot and full-scale installations was carried
out. A full analysis of environmental assessment
instruments like life cycle assessment, carbon, water
footprints, other type of assessments was done that
would be used for selecting sustainable advanced
drinking water treatment processes and able to
removed emerging pollutants. this study vitally
reviewed the emerging pollutants included
classification, legislative framework, up-to-date
removal processes and their environmental
performances assessment and to offer a detailed
analysis of the strategic issues that might constitute
future research directions for sustainable water
supply [Teodosiu, C et al., 2018].
A study was initiated for Prediction of operation
efficiency of water treatment plant with the help a
new index-based method for evaluation of the
performance of the surface water treatment plants.
The index was developed with compensatory Multi-
criteria decision-making methods to make the index
relative as well as objective. The results showed that
labor efficiency, length and density of pipelines were
found to be the most and least significant parameter
in regulating the performance of water treatment
plants. The new method was applied to evaluate the
performance of a densely populated urban surface
water treatment plant and suggested for further
application of the method [Choudhury S et al., 2018].
An Overview of the main disinfection processes for
wastewater and drinking water treatment plants was
carried out to know the conventional processes, the
action mechanism, the possible formation of by-
products, the operative conditions, the advantages
and disadvantages. The action mechanisms were
found for advanced and natural processes.
J. Bio. & Env. Sci. 2021
84 | Ahmed et al.
Advanced technologies were interesting but were still
in the research state, while conventional technologies
were the most used. It was found that there was a
tendency to use chlorine-based disinfectant, although
some forms could lead to production of disinfection
by-products [Collivignarelli et al., 2018].
A study was conducted to know the Spatial
Assessment and the Most Significant Parameters for
Drinking Water Quality Using Chemometric
Technique in Water Treatment Plants. The results
showed that Discriminant Analysis and One- Way
Analysis of variance successfully reduced the physico
and inorganic pollutants concentration with
significant value 98.63% and 96.90%. principle
component analysis revealed six most significant
drinking water quality parameters for pesticides
parameters, nine significant parameters for Inorganic
parameters, fourteen parameters on heavy metals and
organic parameters and four significant of PPs with
the p value less than 0.05 (p < 0.05). Therefore, this
study proved chemometric method was the
alternative way to explain the characteristic of the
drinking water quality and could reduce several
parameters and sampling points in the future
sampling strategy [Zolkipli, H. M et al., 2018].
A study was conducted to know the Performance
management of small water treatment plant
operations by means of a decision support system. A
decision support system (DSS) was developed to
optimize the performance of different operations
related to a small water treatment system to improve
its day‐to‐day decisions. It includes a data
management system, knowledge‐based system,
performance assessment of different unit processes,
fault tree analyses, preventive and corrective actions
and event tree analysis (ETA).
ETA was used to identify the potential health outcomes
which were further integrated with the quantitative
microbial risk assessment. The developed DSS was an
automated user friendly program which could be used
by treatment plant operators to assess system
performance [Stein, D et al., 2017].
A research study was initiated for assessment
framework using performance-based water quality
indices (P WQI) was developed to facilitate senior
management of ground WTPs for effective decision-
making. Five most important water quality
parameters (WQPs) had been selected to assess the
performance of different components of the WTP,
including raw water, pre-treatment, ultrafiltration,
sand filtration, reverse osmosis, and final product.
The results showed that all the units consistently
performed “high,” and the plant was meeting
drinking water quality standards throughout the
year. Hypothetical scenario analysis revealed
robustness of the developed framework by showing
lacking performance in case failure of different units
[Haider, H et al., 2017].
An Evaluation of water quality and performance for a
water treatment plant was done to assess the
efficiency of water treatment plant and to evaluate the
treated water quality of distributed to city residents.
Under this several physicochemical and
bacteriological parameters of both the raw and
treated water samples were analyzed according to
Standard Methods and Procedures to evaluate the
performance and quality of treated water from Water
Treatment Plant. The results showed that the source
raw water was moderately of poor quality, while the
treated water was relatively satisfactory. The treatment
process units were also evaluated. On the whole
removal efficiency of water turbidity was 97.88%. it
was suggested that the water treatment plant units and
process operation needed to be improved, rescaled,
and redesigned to enhance the plant efficiency and
reduce the possibilities of waterborne diseases and
contamination that might occur in future in City
drinking water [Issa, H. M et al., 2017].
Comparison of in vitro estrogenic activity and
estrogen concentrations in source and treated waters
from 25 US drinking water treatment plants were
investigated under this study. treated water samples
were tested for estrogenic activity using T47D-KBluc
cells and analyzed by liquid chromatography-Fourier
transform mass spectrometry for natural and
synthetic estrogens (including estrone, 17β-estradiol,
J. Bio. & Env. Sci. 2021
85 | Ahmed et al.
estriol, and ethinyl estradiol). It was concluded that
using in vitro techniques in addition to analytical
chemical determinations was displayed by the
sensitivity of the T47D-KBluc bioassay, coupled with
the ability to measure cumulative effects of mixtures,
specifically when unknown chemicals might be
present [Conley, J. M et al., 2017].
A study of Microbial risk assessment of drinking
water to fix health-based performance issues to
improve water quality and treatment plant operations
was done by a country organization. The investigating
organization had examined by adopting the
Australian Guidelines for Water Recycling (AGWR)
methodology for drinking water risk management,
and spent in the development of a convenient and
practical quantitative microbial risk assessment
(QMRA) tool for rapid assessment and reporting of
the microbial safety of its drinking water systems.
This action resulted in the identification of several
drinking water system performance deficiencies, and
recommendations for system improvements and
optimization to improve health risk management to
customers [Shea, A et al., 2016].
For evaluation of water treatment plants
performance, Applicability of statistical tools was
applied under this study. The results found during the
wet and dry season were set apart. The results depicted
the feasibility of these statistical tools while considering
the effluent turbidity as the main parameter. Statistical
analysis showed that performance level of the plants
was not dependent on their sizes or raw water quality.
It was found that plants performance was reduced
during the wet season as compared to the dry season
[Melo, L. V et al., 2016].
Invariably ground waters are supplied for human
consumption without any treatment at all or after
disinfection only. From the reported results it is
evident that the contamination of groundwater
sources, if not controlled, may cause substantial
damage or irreversible deterioration of the
groundwater quality in future. Drinking-water quality
is largely influenced by the source water quality, the
extent and efficacy of the treatment rendered and the
integrity of the distribution system. Poor microbial
quality of drinking-water from both ground and
surface waters is the most pressing issue. No water
supply in urban areas of Pakistan meets WHO
drinking-water quality guidelines. The major reasons
for this include: (1) leakage of pipelines; (2) layout of
freshwater pipes parallel or beneath the sewerage
pipes or channels; (3) overloading of sewerage
channels and pipelines which remained in most cases
blocked and overflow into surface drains and natural
water channels; and (4) disposal of untreated
wastewater into major rivers. Over-pumping of
groundwater due to extended draught has also
affected the water quality adversely.
The present study has been planned to evaluate the
quality of water after treatment at different filtration
plants sites of cantonment board Sialkot. Cantonment
board Sialkot is the responsible authority for water
supply and sanitation of the area. Treatment plants
work according to a set timetable. Chlorination is
being carried out at almost every source.
The comparison of test results clarifies the potential
sources of contamination in water filtration plants, if any.
In this research, water quality both before and after
treatment is evaluated. It helps in identifying the problem
areas for initiating appropriate corrective solutions.
Material and methods
Introduction to Study Area
The study area is Sialkot, which is located near the
River Chenab and close to the Pakistan-India border.
It is comparatively a flat area. Its weather is extreme
during the months of May, June, and July, when the
temperatures rise to 40–45 °C. In August, the
monsoon seasons starts, with heavy rainfall
throughout the province. December, January, and
February are the coldest months, when temperatures
can drop to -1 °C.
Sampling Plan
Water samples from source i.e. treatment plant (In
and out) were collected and analyzed for physical,
J. Bio. & Env. Sci. 2021
86 | Ahmed et al.
chemical and bacteriological quality from research
laboratories. For this purpose, six treatment plants
were selected. Sampling from each location was done
before and after treatment as per WHO guidelines.
For the statistical significance of the testing results,
samples from each sampling location were collected
and tested. In this way, total Twelve (12) samples
were collected and tested. Thirty three parameters
(physical, chemical and bacteriological) were
determined for each sample.
Sampling and Preservation
All the sampling and preservation procedures for water
samples were performed according to Standard Methods
for the Examination of Water and Wastewater, 1998 and
Guidelines for drinking water quality (WHO).
Sampling for bacteriological analysis was done aseptically
with care, ensuring that there was no external
contamination of the samples. For bacteriological
analysis sampling, sterilized plastic Poly Ethylene (PET)
bottles of 1.5 litre capacity were used, cleaned and rinsed
carefully, given a final rinse with distilled water, and
sterilized at 121°C for 15 minutes, as directed in section
9030 & 9040 of standard methods. For physicochemical
analysis, samples were collected in Poly Ethylene (PET)
bottles of 1.5 litre capacity, properly washed with the
sampling water for three times. Sample bottles were
marked with date and sample ID using indelible ink.
During sample collection, ample air space was left in the
bottle (at least 2.5 cm) to facilitate mixing by shaking,
before examination. Sample bottles were kept closed
until filled (without rinsing) and caps were replaced
immediately. In case of water samples from distribution
network, un-rusted taps supplying water from a service
pipe, directly connected with the main and not served
from a storage tank, were selected. Tap was opened fully,
and water was let run to waste for 2 or 3 minutes, and
then water flow was reduced to permit the filling of bottle
without splashing.
Samples were not taken from those taps, which were
leaking between the spindle and gland to avoid
outside contamination. All the samples were fetched
to the research laboratory within the recommended
time period.
Examination of Water Quality Parameters
The water samples were analyzed for physical, chemical
and bacteriological parameters by using standard
methods (W.H.O Guidelines for Drinking Water).
Physical, Chemical and Bacteriological Examination
Water samples from source i.e. treatment plants (In
and out) were collected and analyzed for physical (i.e.
colour, taste, odour, Turbidity) chemical( i.e. pH,
Conductivity at 25 oC, Total dissolved solids, Total
suspended solids, Total Hardness as CaCo3, Calcium,
Magnesium, Calcium as Ca2+, Magnesium asmg2+,
Total alkalinity as CaCo3, Bicarbonate as CaCo3,
Carbonate as CaCo3, Bicarbonate as HCO3
1-,
Carbonate as CO3
2-, Chloride as Cl1-, Sulphate as SO4
2-
,Sodium as Na1+, Potassium as K1+, Iron as Fe2+,
Nitrite as No2
1-, Nitrate as NO3
1-, Silica as SiO2 and
bacteriological ( i.e. coliforms, faecal coliforms, E. coli
etc) quality from PCSIR Laboratories Pakistan.
Sampling from each location was done before and
after treatment as per WHO guidelines. For the
statistical significance of the testing results, samples
from each sampling location were collected and
tested. In this way, total Twelve (12) samples were
collected and tested.
Results and discussion
The test results of physical, chemical and bacteriological
parameters of total 12 samples taken from six treatment
plants are being discussed individually, in comparison
with others and in overall basis their performance in the
below mentioned sections.
Physical Chemical and Biological Parameters
Treatment Plant No. 1
Test results of treatment plant No. 1 depicted that all
the parameters tested were fallen within WHO
guideline values, although Conductivity at 25oC and
Total Dissolved Solids had a little bit higher value but
remained in the limit. The water at source was
satisfactory before and after treatment. This
treatment plant was performing well.
Treatment Plant No. 2
Test results of treatment plant No. 2 showed that all
the parameters tested for Treatment were laid within
J. Bio. & Env. Sci. 2021
87 | Ahmed et al.
WHO guideline values and the water at source was
satisfactory before and after treatment. The treatment
plant was performing well.
Treatment Plant No. 3
Test results of treatment plant No. 3 was evidenced
that all the parameters tested were fallen within WHO
guideline values and the water at source was
satisfactory before and after treatment. The treatment
plant was performing well.
Treatment Plant No. 4
Water samples of this Treatment plant before
treatment was found unsafe for drinking, both
chemically and biologically as Total alkalinity as
CaCO3, Total and Fecal Coliforms were greater than
WHO guideline values. The good thing was what the
treatment plant was working well and it removes
these contaminations present before treatment. The
water at source was satisfactory only after treatment.
Treatment Plant No. 5
Test results of treatment plant No. 5 before treatment
was found unsafe for drinking, biologically as Total
and Fecal Coliforms were greater than WHO
guideline values. The water at source was satisfactory
only after treatment. The plant was performing well.
Treatment Plant No. 6
Test results of treatment plant No. 6 was evidenced that
all the parameters tested for this Treatment Plant were
fallen within WHO guideline values and the water at
source was satisfactory before and after treatment.
Comparison of Different Water Quality Parameters
Physical and chemical parameters
As for as Colour, Taste and Odour of collected water
samples from all six filtration plants were found
colourless, tasteless and odourless, which were the
most common symptoms for the assessment of water
quality. For Total Suspended solids, Carbonate as
CaCO3, Carbonate as CO3
1-, it was found that these
parameters were not present in all these samples
taken from the treatment plants, although total
dissolved solids were present.
The pH was within WHO Guidelines for drinking
water for all samples taken from water filtration plants
(Fig. 1). For Calcium all the samples seemed to be
within the limits of PCSIR laboratories, as no WHO
guidelines was available for this parameter of Drinking
(Fig. 2).
Fig. 1. pH of water samples.
Fig. 2. Calcium of water samples.
As for Total alkalinity as CaCO3, all the water samples
were within the permissible limits of WHO guidelines
for total alkalinity (500 PPM) expect at inlet of water
treatment plant No.4 (Fig. 3). For Sulphate as SO4
2-,
all the water samples were within the permissible
limits of WHO guidelines for Sulphate as SO4
2-i.e.
400 PPM (Fig. 4).
Fig. 3. Total alkalinity as CaCO3 of water sample.
pH
6
7
8
9
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in out WHO
Calcium
0
50
100
150
200
250
300
350
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Total alkalinity as CaCo3
0
100
200
300
400
500
600
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
J. Bio. & Env. Sci. 2021
88 | Ahmed et al.
Fig. 4. Sulphate as SO4
2- of water sample.
All the water samples were within the permissible limits
of WHO guidelines (0.5) for Nitrate as NO21- (Fig. 5).
For Conductivity at 25oC, all the samples seemed to be
within the limits provided by PCSIR laboratories
Pakistan, as no WHO guidelines available for this
parameter of Drinking Water (Fig. 6).
Fig. 5. Nitrate as NO2
1- of water samples.
Fig. 6. Conductivity at 25oC of water samples.
All the water samples were found within the
permissible limits for Total Dissolved Solids as per
WHO guidelines for Nitrate (1500) as total dissolved
solids (Fig. 7). For Total Hardness as CaCO3, all the
water samples were within the permissible limits
given by WHO guidelines (500) shown in Fig. 8.
For Magnesium asmg2+, all the water samples were
within the permissible limits 200 given by WHO
guidelines (Fig. 9). Results showed that Calcium as
Ca2+, for all the water samples were within the
permissible limits as per WHO guidelines i.e. 200
(Fig. 10).
Fig. 7. TDS of water samples.
Fig. 8. Total Hardness as CaCO3 of water samples.
Fig. 9. Magnesium asmg2+ of water samples.
Fig. 10. Calcium as Ca2+ of water samples.
Sulphate as SO4
2-
0
50
100
150
200
250
300
350
400
450
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Nitrite
0
0.05
0.1
0.15
0.2
0.25
0.3
0.35
0.4
0.45
0.5
0.55
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Conductivity at 25C
0
200
400
600
800
1000
1200
1400
1600
1800
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Total Dissolved Solids
200
400
600
800
1000
1200
1400
1600
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Total Hardness as CaCo3
100
200
300
400
500
600
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Magnesium
100
110
120
130
140
150
160
170
180
190
200
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Calcium as Ca2+
40
60
80
100
120
140
160
180
200
220
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
J. Bio. & Env. Sci. 2021
89 | Ahmed et al.
The results showed that Bicarbonate as CaCO3 was
seemed within the limit provided by PCSIR
laboratories Pakistan for all samples. As there were
no WHO guidelines available for this parameter of
Drinking Water. All the samples were seemed to be
within the limits for Bicarbonate as HCO3
1- according
to the results provided by PCSIR laboratories
Pakistan. For this parameter WHO guidelines for
Drinking Water was not available.
Fig. 11. Bicarbonate as CaCO3 of water samples.
Fig. 12. Bicarbonate as HCO3
1- of water samples.
The results showed that all water samples were within
the permissible limits for Chloride as Cl1-as per WHO
guidelines i.e. 200 (Fig. 13). For Sodium as Na1+, all
the samples were seemed in within the limits as per
results provided by PCSIR laboratories Pakistan (Fig.
14). For this parameter of Drinking water WHO
guidelines was not available.
Fig. 13. Chloride as Cl1- of water samples.
Fig. 14. Sodium as Na1+ of water samples.
The results depicted that Potassium as K1+, were
found within the limit, according to the results
provided by PCSIR laboratories Pakistan (Fig. 15). As
no WHO guidelines was available for this parameter
of Drinking Water. All the water samples were within
the permissible limits as per WHO guidelines for Iron
as Fe2+ (Fig. 16).
Fig. 15. Potassium as K1+ of water samples.
Fig. 16. Iron as Fe2+ of water samples.
Although there were no WHO guidelines available for
Nitrate as NO3
1- parameter of Drinking Water, but
according to the results provided by PCSIR
laboratories Pakistan, all the samples were seemed
within the limits (Fig. 17). For Silica as SiO2, results
showed that all the water samples were within the
permissible limits provided by WHO guidelines for
Silica as SiO2 i.e. 14 (Fig. 18).
Bicarbonate as CaCo3
0
100
200
300
400
500
600
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Bicarbonate as HCO3
1-
0
100
200
300
400
500
600
700
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Chloride as Cl1-
0
50
100
150
200
250
300
350
400
450
500
550
600
650
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Sodium as Na1+
0
20
40
60
80
100
120
140
160
180
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Potassium as K1+
0
1
2
3
4
5
6
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Iron as Fe2+
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
J. Bio. & Env. Sci. 2021
90 | Ahmed et al.
Fig. 17. Nitrate as NO3
1- of water samples.
Fig. 18. Silica as SiO2 of water samples.
Biological Parameters
All of the water samples taken from different
treatment plants were found safe for drinking water,
expect water of treatment plants No. 4 & 5 before
treatment. Total and Fecal coloform was present in it.
It was interesting to note that treatment plants were
working well and they removed the bacteriological
load as well.
Discussion
Thirty three parameters (physical, chemical and
bacteriological) were determined for each sample. All
the sampling and preservation procedures for water
samples were performed according to Standard
Methods for the Examination of Water and
Wastewater, 1998 and Guidelines for drinking water
quality (WHO). The water samples were analyzed for
physical, chemical and bacteriological parameters by
using standard methods.
The physicochemical and bacteriological parameters
for all treatment plants were within the desirable
limit for drinking water quality recommended by
WHO except Treatment plant No. 4 and No. 5 before
Treatment. Water filtration plants were installed
because the water available from the network supply
lines were not good for drinking, but it was evident
from the results that mostly the water at the source
was almost fit for drinking water purpose without
filtration plants except for treatment plant No. 4 & 5
for which some biological parameters were not
according to standards. This shows that before the
installation of filtration plants a water sample test of
physical, chemical and bacteriological parameters
must be conducted and compared with the WHO
standards to avoid unnecessary installation of water
filtration plants. In this case if test was conducted
beforehand out of six only two filtration plants were
necessary and the money spent on unnecessary
filtration plants could have been used for betterment
of water supply system. Chlorination was one of the
most effective and popular method practiced
throughout the world for disinfection of water supply
lines. It could be used instead of these treatment
plants as it is much more cost effective.
Conclusion
The physiochemical and bacteriological parameters for
all treatment plants were within the desirable limit for
drinking water quality recommended by WHO except
for the treatment plant No 4 & 5, before treatment,
which contained Total and Fecal coloform in it.
Recommendations
• Periodic evaluation of some important parameters
like bacterial load especially indicating faecal
pollution (coliforms, faecal coliforms, E. coli etc.),
free residual chlorine, turbidity, pH and TDS should
be carried out both before and after treatment to
ensure safe water supplies for drinking.
• To prevent biological contamination water and
sewerage pipelines should always be laid in separate
trenches preferably at some distance from water
source. Also the sewerage water should not be
injected into the groundwater through seepage pits.
• There is a need for Public awareness campaigns,
which should be launched to educate people about the
importance of safe drinking water. Potable water
safety and its hazards should be publicized. Media
and nongovernmental organizations can play a
pivotal role in this aspect.
Nitrate as NO3
1-
0
0.02
0.04
0.06
0.08
0.1
0.12
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
Silica as SiO2
-1
1
3
5
7
9
11
13
15
Treatment
Plant 1
Treatment
Plant 2
Treatment
Plant 3
Treatment
Plant 4
Treatment
Plant 5
Treatment
Plant 6
in
out
J. Bio. & Env. Sci. 2021
91 | Ahmed et al.
Novelty Statement
The present study has been planned to evaluate the
quality of water after treatment at different filtration
plants installed at various sites of Pakistan.
Treatment plants work according to a set timetable.
Chlorination was being carried out at almost every
source. The comparison of test results clarifies the
potential sources of contamination in water filtration
plants, if any. In this research, water quality both
before and after treatment is evaluated. It helps in
identifying the problem areas for initiating
appropriate corrective solutions.
References
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Choudhury S, Saha AK. 2018. ‘‘Prediction of
operation efficiency of water treatment plant with the
help of multi-criteria decision-making.’’ Water
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Collivignarelli MC, Abbà A, Benigna I, Sorlini
S, Torretta V. 2018. ‘‘Overview of the main
disinfection processes for wastewater and drinking
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Conley JM, Evans N, Mash H, Rosenblum L,
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Fujioka T, Ueyama T, Mingliang F, Leddy M.
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treatment plant.’’ Chemosphere 229, 509-514.
Hadi M, Mesdaghinia A, Yunesian M, Nasseri S,
Nodehi RN, Smeets PW, ... Jalilzadeh E. 2019.
‘‘Optimizing the performance of conventional water
treatment system using quantitative microbial risk
assessment’’ Tehran, Iran. Water research 162, 394-408.
Haider H. 2017. “Performance assessment framework
for groundwater treatment plants in Arid Environments:
a case of Buraydah, Saudi Arabia”. Environmental
Monitoring and Assessment 189(11), 544.
Issa HM. 2017. “Evaluation of water quality and
performance for a water treatment plant: Khanaqin
city as a case study”. Journal of Garmian University
3, 802-821.
Kaji A, Taheriyoun M, Taebi A, Nazari-
Sharabian M. 2019. ‘‘Comparison and optimization
of the performance of natural-based non-
conventional coagulants in a water treatment plant.’’
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Performance assessment of water filtration plants in pakistan - JBES

  • 1. J. Bio. Env. Sci. 18(5), 80-92, May 2021. 2021 E-ISSN: 2222-3045, p-ISSN: 2220-6663 Performance assessment of water filtration plants in Pakistan By: Talat Farid Ahmed, Hashim Nisar Hashmi, Ali Salman Saeed, Ashfaq Ahmed Sheikh, Muhammad Attiqullah Khan, Muhammad Azeem Afzal Journal of biodiversity and environmental sciences international network for natural sciences Research Paper Journal Name Publisher Name
  • 2.
  • 3. J. Bio. & Env. Sci. 2021 80 | Ahmed et al. RESEARCH PAPER OPEN ACCESS Performance assessment of water filtration plants in Pakistan Talat Farid Ahmed*1 , Hashim Nisar Hashmi2 , Ali Salman Saeed2 , Ashfaq Ahmed Sheikh3 , Muhammad Attiqullah Khan1 , Muhammad Azeem Afzal1 1 Farm Operations & Services, National Agricultural Research Centre, Park Road, Islamabad, Pakistan 2 Civil Engineering Department, University of Engineering & Technology, Taxila, Pakistan 3 CPD, Pakistan Engineering Council, Islamabad, Pakistan Article published on May 30, 2021 Key words: Uplift anaerobic sludge blanket, Power of hydrogen ions, Organic loading role, Hydraulic retention time, Chemical oxygen demand, Biological oxygen demand Abstract A study was carried out to evaluate the water quality of filtration plants installed at six different places of Cantonment Board Sialkot, Pakistan to suggest and recommend guidelines for their improvement. Water samples from six Treatment plants and their respective twelve connections (two from each treatment plants) were collected before and after treatment. In this way, total samples were collected and tested. Values of these samples before and after treatment were used for comparison with World Health Organization (WHO) guidelines for drinking water standards. Thirty three parameters including physical, chemical and bacteriological were determined for each sample. The results were satisfactory both chemically and bacteriologically according to WHO guidelines for water quality of treatment plants. The results showed that the samples of water were fit, both before and after treatment plant except for water sample of treatment plant No. IV & V (Before treatment). Total and faecal coliform were found in these samples. Various causes of faecal contamination before treatment may be due to leakage of pipelines, operation at tubewells, layout of freshwater pipes parallel or beneath the sewerage pipes or channels. Disinfection of water at source is recommended to deal with the faecal contamination; otherwise there is no need of filtration plant. *Corresponding Author: Talat Farid Ahmed  tafa367@gmail.com Journal of Biodiversity and Environmental Sciences (JBES) ISSN: 2220-6663 (Print) 2222-3045 (Online) Vol. 18, No. 5, p. 80-92, 2021 http://www.innspub.net
  • 4. J. Bio. & Env. Sci. 2021 81 | Ahmed et al. Introduction Water is blessing of Allah and is very precious resource of this planet as it is an established source of life and civilization. Over other planets and even galaxies, the constituent parts of water are searched as emblem of life. It is well known that human health and survival depends on use of uncontaminated and clean water for drinking and other domestic purposes. Nature has blessed Pakistan with adequate surface and groundwater resources. Both of these sources are used for water supplies, however, 70% of water supplies are based on groundwater and 30% on surface waters. Pakistan’s population has current water supply coverage of 79%.This inadequate supply of water also poses health risks to the consumers because of its poor quality. Faecally contaminated water is a major contributor to waterborne diseases. It is estimated that in Pakistan around 30% of all diseases and 40% of all deaths are attributed to poor water quality. Moreover, the leading cause of deaths in infants and children up to 10 years age as well as mortality rate of 136 per 1,000 live births due to diarrhea is reported. Furthermore, every fifth citizen suffers from illness and disease caused by polluted water. With rapid urbanization, the chemical aspects of water quality have also become a cause of increasing concern as toxic chemicals in industrial effluents pose a high risk to human health. Unfortunately, little attention is being paid to drinking-water quality issues and quantity remains the priority focus of water supply agencies. There is a lack of drinking- water quality monitoring and surveillance programmes in the country. Weak institutional arrangements, lack of well-equipped laboratories and the absence of a legal framework for drinking-water quality issues have aggravated the situation. Above all public awareness of the issue of water quality is dismally low. The water shortage and increasing competition for multiple uses of water adversely affected the water quality. Keeping in view the above mentioned facts an attempt has been made to evaluate the water quality in some of the already installed water filtration plant with set goals i.e. water quality evaluation before and after treatment of water, water filtration plants Performance assessment and Suggest and recommend guidelines for their improvement. A research study was started to evaluate the energy efficiency of a sample of drinking water treatment plants (DWTPs) using the data envelopment analysis (DEA) tolerance method. The results showed that, even in the best-case situation, most of the DWTPs evaluated were inefficient and might be able to reduce the energy used to treat raw water. As policy perspective the results revealed that omitting data variability in benchmarking would involve critical repercussions when efficiency scores were used by regulators to set water tariffs. Omitting the degree of data uncertainty was likely to result in biased conclusions; in the scenarios evaluated, the inclusion of this information altered the rankings of some energy-efficient DWTPs [Sala-Garrido, R., & Molinos- Senante, M., 2020]. A quantitative microbial risk assessment (QMRA) study was conducted on Cryptosporidium using actual pathogen density to know the performance conventional water treatment plant (WTP). To control the excess risk, three QMRA-based disinfection scenarios were examined; (1) employing chlorine dioxide instead of chlorine (2) ozonation with a concentration of 0.75mg/L (3) UV irradiation with a dose of 10mJ/cm2. The results showed that use of ozone or UV as alternative disinfectants could enhance the disinfection efficacy and provide sufficient additional treatment against the excess risk of parasite. QMRA could make it easier applying appropriate improvement to conventional WTPs in order to increase the system performance in terms of health-based measures [Hadi, M et al., 2019]. A study was started with aimed to evaluate the efficacy of real-time bacteriological counters for continuously assessing the performance of a full-scale sand filter to remove bacteria of a drinking water treatment plant. Periodic variations were found with
  • 5. J. Bio. & Env. Sci. 2021 82 | Ahmed et al. online bacterial counts in the sand filter influent because of the changes in the performance of flocculation and sedimentation processes. Overall, online removal rates of bacteria determined during the full-scale test were 95.2-99.3%. Real-time bacteriological counting technology could be a useful tool for assessing variability and detecting bacterial breakthrough. It could be integrated with other online water quality measurements to evaluate underlying trends and the performance of sand filters for bacterial removal, which could enhanced the safety of drinking water [Fujioka, T et al., 2019]. A hybrid statistic model named HANN was established by combining artificial neural network (ANN) with genetic algorithm (GA) aiming at forecasting the overall performance of drinking water treatment plants (DWTPs) was carried out. Water quality parameters like temperature, chemical oxygen demand (COD) and operational parameters like electricity consumption and chemical consumption were selected as input variables while drinking water production was employed as the output. The scenario analysis showed that the HANN model was capable of predicting water production variation based on the parameter variations. It was found that the HANN model could be a general management tool for decision makers and DWTP managers to make plans in advance of regulatory changes, source water quality variations and market demand [Zhang, Y et al., 2019]. Adequacy analysis of drinking water treatment technologies in regard to the parameter turbidity, considering the quality of natural waters treated by large-scale water treatment plants (WTPs) was initiated. Nonparametric and multivariate statistical tools were used to analyze raw water and treated water turbidity of a large on-line monitoring databank for the period of two years of six large- scale treatment plants utilizing different technologies. The results depicted that selection of the technology to be applied must be well studied to always seek the best solution, and that other factors than only the raw water characteristics should be evaluated. It was also found that utilization of the same treatment technology did not always resulted in the same effluent quality, since there were many factors related to operation, maintenance, raw water variability, climatic interferences, and others [Melo, L. D. V., et al., 2019]. A study was started with the objective to evaluate the drinking water treatment plant (DWTP) by life cycle assessment (LCA) and to identify and characterize its environmental impacts. DWTP involved the scheme; pre-oxidation (chlorine dioxide), coagulation/ flocculation, sedimentation, pH correction (calcium hydroxide), rapid sand filtration, granular activated carbon filtration and disinfection (chlorine gas). Life cycle impact assessment showed that the lower the pollutant concentration, the higher the specific environmental impacts would be, which prompts for further detailed analysis of water treatment plant environmental performance in at least two directions i.e. removal of emerging contaminants (present in very low concentrations) and a more detailed analysis on the individual performance of each treatment stage [Barjoveanu, et al., 2019]. A study was conducted to analyze the presence of antibiotics in potable water from two treatment plants. The collected samples were separated using a solid-phase extraction method with hydrophilic- lipophilic balance cartridge before being analyzed. The detected antibiotics in the raw and finished drinking water were analyzed and assessed using high-performance liquid chromatography with fluorometric detector and UV detector. The results proved that different antibiotics including fluoroquinolones and B-lactams were detected in the raw and finished water. It was suggested that due to presence of antibiotic drugs in raw and finished water, the planners should include it in the respective country standard for drinking water quality assessment [Mahmood, A. R et al., 2019]. A study was conducted to assess the efficiency of two natural-based coagulants, namely calcium lactate and tannic acid, and compare it with conventional coagulants polyaluminium chloride and ferric
  • 6. J. Bio. & Env. Sci. 2021 83 | Ahmed et al. chloride in a water treatment plant. The comparison between the performances of the coagulants showed no significant difference in turbidity removal. However sludge volume produced as well as the impact on PH alteration after coagulation-flocculation were lower when using natural coagulants than with conventional coagulants. The results showed that the natural coagulants could be preferable to the conventional coagulants if the concerns regarding disinfection by- product formation due to their residual organics were resolved [Kaji, A et al., 2019]. Performance Evaluation of a Drinking Water Treatment Plant in terms of performance, design, operation, and maintenance was carried out. A Microbial Barrier Analysis (MBA) and Quantitative Microbial Risk Assessment (QMRA) were performed to assess the health risk based on the Water Safety Plan concept. The results revealed that less source protection, lack of skilled expertise in operation, deficiency of guidance from the administration, insufficient design and equipment, and incomplete technologies were the main issues. Recommendations in a two-step implementation plan were presented to provide of an adequate water supply [Braun, M., 2019]. Evaluation of energy performance of drinking water treatment plants was initiated by Using energy intensity and energy efficiency metrics. The metafrontier data was used in envelopment analysis to evaluate and compare the energy performance of four types of treatment technologies. This approach integrates energy intensity with pollutant removal efficiency into a single, synthetic index to deliver an energy-efficiency score. The results showed that facilities using rapid-gravity filtration and coagulation-flocculation processes provided the highest energy efficiencies. But energy intensity and energy efficiency metrics delivered contradictory results that showed the importance of including pollutant removal efficiency data in performance assessments. It was found that this study gave valuable information for policy-makers when planning and developing new drinking water treatment plants and for water utility managers when identifying energy reduction opportunities in plants [Molinos-Senante, M., & Sala-Garrido, R., 2018]. A complete review of research efforts related to the occurrence, fate, health effects and impacts of emerging pollutants on advanced drinking water treatment and the environmental performance evaluation of different technological options, with a focus on pilot and full-scale installations was carried out. A full analysis of environmental assessment instruments like life cycle assessment, carbon, water footprints, other type of assessments was done that would be used for selecting sustainable advanced drinking water treatment processes and able to removed emerging pollutants. this study vitally reviewed the emerging pollutants included classification, legislative framework, up-to-date removal processes and their environmental performances assessment and to offer a detailed analysis of the strategic issues that might constitute future research directions for sustainable water supply [Teodosiu, C et al., 2018]. A study was initiated for Prediction of operation efficiency of water treatment plant with the help a new index-based method for evaluation of the performance of the surface water treatment plants. The index was developed with compensatory Multi- criteria decision-making methods to make the index relative as well as objective. The results showed that labor efficiency, length and density of pipelines were found to be the most and least significant parameter in regulating the performance of water treatment plants. The new method was applied to evaluate the performance of a densely populated urban surface water treatment plant and suggested for further application of the method [Choudhury S et al., 2018]. An Overview of the main disinfection processes for wastewater and drinking water treatment plants was carried out to know the conventional processes, the action mechanism, the possible formation of by- products, the operative conditions, the advantages and disadvantages. The action mechanisms were found for advanced and natural processes.
  • 7. J. Bio. & Env. Sci. 2021 84 | Ahmed et al. Advanced technologies were interesting but were still in the research state, while conventional technologies were the most used. It was found that there was a tendency to use chlorine-based disinfectant, although some forms could lead to production of disinfection by-products [Collivignarelli et al., 2018]. A study was conducted to know the Spatial Assessment and the Most Significant Parameters for Drinking Water Quality Using Chemometric Technique in Water Treatment Plants. The results showed that Discriminant Analysis and One- Way Analysis of variance successfully reduced the physico and inorganic pollutants concentration with significant value 98.63% and 96.90%. principle component analysis revealed six most significant drinking water quality parameters for pesticides parameters, nine significant parameters for Inorganic parameters, fourteen parameters on heavy metals and organic parameters and four significant of PPs with the p value less than 0.05 (p < 0.05). Therefore, this study proved chemometric method was the alternative way to explain the characteristic of the drinking water quality and could reduce several parameters and sampling points in the future sampling strategy [Zolkipli, H. M et al., 2018]. A study was conducted to know the Performance management of small water treatment plant operations by means of a decision support system. A decision support system (DSS) was developed to optimize the performance of different operations related to a small water treatment system to improve its day‐to‐day decisions. It includes a data management system, knowledge‐based system, performance assessment of different unit processes, fault tree analyses, preventive and corrective actions and event tree analysis (ETA). ETA was used to identify the potential health outcomes which were further integrated with the quantitative microbial risk assessment. The developed DSS was an automated user friendly program which could be used by treatment plant operators to assess system performance [Stein, D et al., 2017]. A research study was initiated for assessment framework using performance-based water quality indices (P WQI) was developed to facilitate senior management of ground WTPs for effective decision- making. Five most important water quality parameters (WQPs) had been selected to assess the performance of different components of the WTP, including raw water, pre-treatment, ultrafiltration, sand filtration, reverse osmosis, and final product. The results showed that all the units consistently performed “high,” and the plant was meeting drinking water quality standards throughout the year. Hypothetical scenario analysis revealed robustness of the developed framework by showing lacking performance in case failure of different units [Haider, H et al., 2017]. An Evaluation of water quality and performance for a water treatment plant was done to assess the efficiency of water treatment plant and to evaluate the treated water quality of distributed to city residents. Under this several physicochemical and bacteriological parameters of both the raw and treated water samples were analyzed according to Standard Methods and Procedures to evaluate the performance and quality of treated water from Water Treatment Plant. The results showed that the source raw water was moderately of poor quality, while the treated water was relatively satisfactory. The treatment process units were also evaluated. On the whole removal efficiency of water turbidity was 97.88%. it was suggested that the water treatment plant units and process operation needed to be improved, rescaled, and redesigned to enhance the plant efficiency and reduce the possibilities of waterborne diseases and contamination that might occur in future in City drinking water [Issa, H. M et al., 2017]. Comparison of in vitro estrogenic activity and estrogen concentrations in source and treated waters from 25 US drinking water treatment plants were investigated under this study. treated water samples were tested for estrogenic activity using T47D-KBluc cells and analyzed by liquid chromatography-Fourier transform mass spectrometry for natural and synthetic estrogens (including estrone, 17β-estradiol,
  • 8. J. Bio. & Env. Sci. 2021 85 | Ahmed et al. estriol, and ethinyl estradiol). It was concluded that using in vitro techniques in addition to analytical chemical determinations was displayed by the sensitivity of the T47D-KBluc bioassay, coupled with the ability to measure cumulative effects of mixtures, specifically when unknown chemicals might be present [Conley, J. M et al., 2017]. A study of Microbial risk assessment of drinking water to fix health-based performance issues to improve water quality and treatment plant operations was done by a country organization. The investigating organization had examined by adopting the Australian Guidelines for Water Recycling (AGWR) methodology for drinking water risk management, and spent in the development of a convenient and practical quantitative microbial risk assessment (QMRA) tool for rapid assessment and reporting of the microbial safety of its drinking water systems. This action resulted in the identification of several drinking water system performance deficiencies, and recommendations for system improvements and optimization to improve health risk management to customers [Shea, A et al., 2016]. For evaluation of water treatment plants performance, Applicability of statistical tools was applied under this study. The results found during the wet and dry season were set apart. The results depicted the feasibility of these statistical tools while considering the effluent turbidity as the main parameter. Statistical analysis showed that performance level of the plants was not dependent on their sizes or raw water quality. It was found that plants performance was reduced during the wet season as compared to the dry season [Melo, L. V et al., 2016]. Invariably ground waters are supplied for human consumption without any treatment at all or after disinfection only. From the reported results it is evident that the contamination of groundwater sources, if not controlled, may cause substantial damage or irreversible deterioration of the groundwater quality in future. Drinking-water quality is largely influenced by the source water quality, the extent and efficacy of the treatment rendered and the integrity of the distribution system. Poor microbial quality of drinking-water from both ground and surface waters is the most pressing issue. No water supply in urban areas of Pakistan meets WHO drinking-water quality guidelines. The major reasons for this include: (1) leakage of pipelines; (2) layout of freshwater pipes parallel or beneath the sewerage pipes or channels; (3) overloading of sewerage channels and pipelines which remained in most cases blocked and overflow into surface drains and natural water channels; and (4) disposal of untreated wastewater into major rivers. Over-pumping of groundwater due to extended draught has also affected the water quality adversely. The present study has been planned to evaluate the quality of water after treatment at different filtration plants sites of cantonment board Sialkot. Cantonment board Sialkot is the responsible authority for water supply and sanitation of the area. Treatment plants work according to a set timetable. Chlorination is being carried out at almost every source. The comparison of test results clarifies the potential sources of contamination in water filtration plants, if any. In this research, water quality both before and after treatment is evaluated. It helps in identifying the problem areas for initiating appropriate corrective solutions. Material and methods Introduction to Study Area The study area is Sialkot, which is located near the River Chenab and close to the Pakistan-India border. It is comparatively a flat area. Its weather is extreme during the months of May, June, and July, when the temperatures rise to 40–45 °C. In August, the monsoon seasons starts, with heavy rainfall throughout the province. December, January, and February are the coldest months, when temperatures can drop to -1 °C. Sampling Plan Water samples from source i.e. treatment plant (In and out) were collected and analyzed for physical,
  • 9. J. Bio. & Env. Sci. 2021 86 | Ahmed et al. chemical and bacteriological quality from research laboratories. For this purpose, six treatment plants were selected. Sampling from each location was done before and after treatment as per WHO guidelines. For the statistical significance of the testing results, samples from each sampling location were collected and tested. In this way, total Twelve (12) samples were collected and tested. Thirty three parameters (physical, chemical and bacteriological) were determined for each sample. Sampling and Preservation All the sampling and preservation procedures for water samples were performed according to Standard Methods for the Examination of Water and Wastewater, 1998 and Guidelines for drinking water quality (WHO). Sampling for bacteriological analysis was done aseptically with care, ensuring that there was no external contamination of the samples. For bacteriological analysis sampling, sterilized plastic Poly Ethylene (PET) bottles of 1.5 litre capacity were used, cleaned and rinsed carefully, given a final rinse with distilled water, and sterilized at 121°C for 15 minutes, as directed in section 9030 & 9040 of standard methods. For physicochemical analysis, samples were collected in Poly Ethylene (PET) bottles of 1.5 litre capacity, properly washed with the sampling water for three times. Sample bottles were marked with date and sample ID using indelible ink. During sample collection, ample air space was left in the bottle (at least 2.5 cm) to facilitate mixing by shaking, before examination. Sample bottles were kept closed until filled (without rinsing) and caps were replaced immediately. In case of water samples from distribution network, un-rusted taps supplying water from a service pipe, directly connected with the main and not served from a storage tank, were selected. Tap was opened fully, and water was let run to waste for 2 or 3 minutes, and then water flow was reduced to permit the filling of bottle without splashing. Samples were not taken from those taps, which were leaking between the spindle and gland to avoid outside contamination. All the samples were fetched to the research laboratory within the recommended time period. Examination of Water Quality Parameters The water samples were analyzed for physical, chemical and bacteriological parameters by using standard methods (W.H.O Guidelines for Drinking Water). Physical, Chemical and Bacteriological Examination Water samples from source i.e. treatment plants (In and out) were collected and analyzed for physical (i.e. colour, taste, odour, Turbidity) chemical( i.e. pH, Conductivity at 25 oC, Total dissolved solids, Total suspended solids, Total Hardness as CaCo3, Calcium, Magnesium, Calcium as Ca2+, Magnesium asmg2+, Total alkalinity as CaCo3, Bicarbonate as CaCo3, Carbonate as CaCo3, Bicarbonate as HCO3 1-, Carbonate as CO3 2-, Chloride as Cl1-, Sulphate as SO4 2- ,Sodium as Na1+, Potassium as K1+, Iron as Fe2+, Nitrite as No2 1-, Nitrate as NO3 1-, Silica as SiO2 and bacteriological ( i.e. coliforms, faecal coliforms, E. coli etc) quality from PCSIR Laboratories Pakistan. Sampling from each location was done before and after treatment as per WHO guidelines. For the statistical significance of the testing results, samples from each sampling location were collected and tested. In this way, total Twelve (12) samples were collected and tested. Results and discussion The test results of physical, chemical and bacteriological parameters of total 12 samples taken from six treatment plants are being discussed individually, in comparison with others and in overall basis their performance in the below mentioned sections. Physical Chemical and Biological Parameters Treatment Plant No. 1 Test results of treatment plant No. 1 depicted that all the parameters tested were fallen within WHO guideline values, although Conductivity at 25oC and Total Dissolved Solids had a little bit higher value but remained in the limit. The water at source was satisfactory before and after treatment. This treatment plant was performing well. Treatment Plant No. 2 Test results of treatment plant No. 2 showed that all the parameters tested for Treatment were laid within
  • 10. J. Bio. & Env. Sci. 2021 87 | Ahmed et al. WHO guideline values and the water at source was satisfactory before and after treatment. The treatment plant was performing well. Treatment Plant No. 3 Test results of treatment plant No. 3 was evidenced that all the parameters tested were fallen within WHO guideline values and the water at source was satisfactory before and after treatment. The treatment plant was performing well. Treatment Plant No. 4 Water samples of this Treatment plant before treatment was found unsafe for drinking, both chemically and biologically as Total alkalinity as CaCO3, Total and Fecal Coliforms were greater than WHO guideline values. The good thing was what the treatment plant was working well and it removes these contaminations present before treatment. The water at source was satisfactory only after treatment. Treatment Plant No. 5 Test results of treatment plant No. 5 before treatment was found unsafe for drinking, biologically as Total and Fecal Coliforms were greater than WHO guideline values. The water at source was satisfactory only after treatment. The plant was performing well. Treatment Plant No. 6 Test results of treatment plant No. 6 was evidenced that all the parameters tested for this Treatment Plant were fallen within WHO guideline values and the water at source was satisfactory before and after treatment. Comparison of Different Water Quality Parameters Physical and chemical parameters As for as Colour, Taste and Odour of collected water samples from all six filtration plants were found colourless, tasteless and odourless, which were the most common symptoms for the assessment of water quality. For Total Suspended solids, Carbonate as CaCO3, Carbonate as CO3 1-, it was found that these parameters were not present in all these samples taken from the treatment plants, although total dissolved solids were present. The pH was within WHO Guidelines for drinking water for all samples taken from water filtration plants (Fig. 1). For Calcium all the samples seemed to be within the limits of PCSIR laboratories, as no WHO guidelines was available for this parameter of Drinking (Fig. 2). Fig. 1. pH of water samples. Fig. 2. Calcium of water samples. As for Total alkalinity as CaCO3, all the water samples were within the permissible limits of WHO guidelines for total alkalinity (500 PPM) expect at inlet of water treatment plant No.4 (Fig. 3). For Sulphate as SO4 2-, all the water samples were within the permissible limits of WHO guidelines for Sulphate as SO4 2-i.e. 400 PPM (Fig. 4). Fig. 3. Total alkalinity as CaCO3 of water sample. pH 6 7 8 9 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out WHO Calcium 0 50 100 150 200 250 300 350 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Total alkalinity as CaCo3 0 100 200 300 400 500 600 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out
  • 11. J. Bio. & Env. Sci. 2021 88 | Ahmed et al. Fig. 4. Sulphate as SO4 2- of water sample. All the water samples were within the permissible limits of WHO guidelines (0.5) for Nitrate as NO21- (Fig. 5). For Conductivity at 25oC, all the samples seemed to be within the limits provided by PCSIR laboratories Pakistan, as no WHO guidelines available for this parameter of Drinking Water (Fig. 6). Fig. 5. Nitrate as NO2 1- of water samples. Fig. 6. Conductivity at 25oC of water samples. All the water samples were found within the permissible limits for Total Dissolved Solids as per WHO guidelines for Nitrate (1500) as total dissolved solids (Fig. 7). For Total Hardness as CaCO3, all the water samples were within the permissible limits given by WHO guidelines (500) shown in Fig. 8. For Magnesium asmg2+, all the water samples were within the permissible limits 200 given by WHO guidelines (Fig. 9). Results showed that Calcium as Ca2+, for all the water samples were within the permissible limits as per WHO guidelines i.e. 200 (Fig. 10). Fig. 7. TDS of water samples. Fig. 8. Total Hardness as CaCO3 of water samples. Fig. 9. Magnesium asmg2+ of water samples. Fig. 10. Calcium as Ca2+ of water samples. Sulphate as SO4 2- 0 50 100 150 200 250 300 350 400 450 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Nitrite 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Conductivity at 25C 0 200 400 600 800 1000 1200 1400 1600 1800 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Total Dissolved Solids 200 400 600 800 1000 1200 1400 1600 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Total Hardness as CaCo3 100 200 300 400 500 600 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Magnesium 100 110 120 130 140 150 160 170 180 190 200 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Calcium as Ca2+ 40 60 80 100 120 140 160 180 200 220 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out
  • 12. J. Bio. & Env. Sci. 2021 89 | Ahmed et al. The results showed that Bicarbonate as CaCO3 was seemed within the limit provided by PCSIR laboratories Pakistan for all samples. As there were no WHO guidelines available for this parameter of Drinking Water. All the samples were seemed to be within the limits for Bicarbonate as HCO3 1- according to the results provided by PCSIR laboratories Pakistan. For this parameter WHO guidelines for Drinking Water was not available. Fig. 11. Bicarbonate as CaCO3 of water samples. Fig. 12. Bicarbonate as HCO3 1- of water samples. The results showed that all water samples were within the permissible limits for Chloride as Cl1-as per WHO guidelines i.e. 200 (Fig. 13). For Sodium as Na1+, all the samples were seemed in within the limits as per results provided by PCSIR laboratories Pakistan (Fig. 14). For this parameter of Drinking water WHO guidelines was not available. Fig. 13. Chloride as Cl1- of water samples. Fig. 14. Sodium as Na1+ of water samples. The results depicted that Potassium as K1+, were found within the limit, according to the results provided by PCSIR laboratories Pakistan (Fig. 15). As no WHO guidelines was available for this parameter of Drinking Water. All the water samples were within the permissible limits as per WHO guidelines for Iron as Fe2+ (Fig. 16). Fig. 15. Potassium as K1+ of water samples. Fig. 16. Iron as Fe2+ of water samples. Although there were no WHO guidelines available for Nitrate as NO3 1- parameter of Drinking Water, but according to the results provided by PCSIR laboratories Pakistan, all the samples were seemed within the limits (Fig. 17). For Silica as SiO2, results showed that all the water samples were within the permissible limits provided by WHO guidelines for Silica as SiO2 i.e. 14 (Fig. 18). Bicarbonate as CaCo3 0 100 200 300 400 500 600 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Bicarbonate as HCO3 1- 0 100 200 300 400 500 600 700 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Chloride as Cl1- 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Sodium as Na1+ 0 20 40 60 80 100 120 140 160 180 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Potassium as K1+ 0 1 2 3 4 5 6 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Iron as Fe2+ 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out
  • 13. J. Bio. & Env. Sci. 2021 90 | Ahmed et al. Fig. 17. Nitrate as NO3 1- of water samples. Fig. 18. Silica as SiO2 of water samples. Biological Parameters All of the water samples taken from different treatment plants were found safe for drinking water, expect water of treatment plants No. 4 & 5 before treatment. Total and Fecal coloform was present in it. It was interesting to note that treatment plants were working well and they removed the bacteriological load as well. Discussion Thirty three parameters (physical, chemical and bacteriological) were determined for each sample. All the sampling and preservation procedures for water samples were performed according to Standard Methods for the Examination of Water and Wastewater, 1998 and Guidelines for drinking water quality (WHO). The water samples were analyzed for physical, chemical and bacteriological parameters by using standard methods. The physicochemical and bacteriological parameters for all treatment plants were within the desirable limit for drinking water quality recommended by WHO except Treatment plant No. 4 and No. 5 before Treatment. Water filtration plants were installed because the water available from the network supply lines were not good for drinking, but it was evident from the results that mostly the water at the source was almost fit for drinking water purpose without filtration plants except for treatment plant No. 4 & 5 for which some biological parameters were not according to standards. This shows that before the installation of filtration plants a water sample test of physical, chemical and bacteriological parameters must be conducted and compared with the WHO standards to avoid unnecessary installation of water filtration plants. In this case if test was conducted beforehand out of six only two filtration plants were necessary and the money spent on unnecessary filtration plants could have been used for betterment of water supply system. Chlorination was one of the most effective and popular method practiced throughout the world for disinfection of water supply lines. It could be used instead of these treatment plants as it is much more cost effective. Conclusion The physiochemical and bacteriological parameters for all treatment plants were within the desirable limit for drinking water quality recommended by WHO except for the treatment plant No 4 & 5, before treatment, which contained Total and Fecal coloform in it. Recommendations • Periodic evaluation of some important parameters like bacterial load especially indicating faecal pollution (coliforms, faecal coliforms, E. coli etc.), free residual chlorine, turbidity, pH and TDS should be carried out both before and after treatment to ensure safe water supplies for drinking. • To prevent biological contamination water and sewerage pipelines should always be laid in separate trenches preferably at some distance from water source. Also the sewerage water should not be injected into the groundwater through seepage pits. • There is a need for Public awareness campaigns, which should be launched to educate people about the importance of safe drinking water. Potable water safety and its hazards should be publicized. Media and nongovernmental organizations can play a pivotal role in this aspect. Nitrate as NO3 1- 0 0.02 0.04 0.06 0.08 0.1 0.12 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out Silica as SiO2 -1 1 3 5 7 9 11 13 15 Treatment Plant 1 Treatment Plant 2 Treatment Plant 3 Treatment Plant 4 Treatment Plant 5 Treatment Plant 6 in out
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